WO2006004141A1 - 廃熱回収装置、廃熱回収システム及び廃熱回収方法 - Google Patents
廃熱回収装置、廃熱回収システム及び廃熱回収方法 Download PDFInfo
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- WO2006004141A1 WO2006004141A1 PCT/JP2005/012440 JP2005012440W WO2006004141A1 WO 2006004141 A1 WO2006004141 A1 WO 2006004141A1 JP 2005012440 W JP2005012440 W JP 2005012440W WO 2006004141 A1 WO2006004141 A1 WO 2006004141A1
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- dimethyl ether
- heat exchanger
- waste heat
- heat recovery
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
- F02C3/22—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being gaseous at standard temperature and pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas- turbine plants for special use
- F02C6/18—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas- turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C7/00—Features, components parts, details or accessories, not provided for in, or of interest apart form groups F02C1/00 - F02C6/00; Air intakes for jet-propulsion plants
- F02C7/22—Fuel supply systems
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D21/0001—Recuperative heat exchangers
- F28D21/0003—Recuperative heat exchangers the heat being recuperated from exhaust gases
- F28D21/001—Recuperative heat exchangers the heat being recuperated from exhaust gases for thermal power plants or industrial processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00176—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00038—Processes in parallel
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
- C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0822—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel the fuel containing hydrogen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/14—Combined heat and power generation [CHP]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- Waste heat recovery device waste heat recovery system, and waste heat recovery method
- the present invention relates to a method for recovering waste heat discharged from various industrial sectors, and more particularly to a waste heat recovery device and method for recovering waste heat of exhaust gas discharged from a combustion device such as a furnace, an internal combustion engine or a power generation facility.
- a waste heat recovery device such as a furnace, an internal combustion engine or a power generation facility.
- a method for recovering waste heat from exhaust gas as heat energy is being used.
- a heat exchanger is installed in the exhaust system of the combustion device, and the sensible heat of the exhaust gas is recovered as thermal energy by passing the heat recovery medium through the heat exchanger and heating the heat recovery medium with the exhaust gas.
- waste heat boilers use water as a heat exchange medium and recover the sensible heat of exhaust gas as thermal energy for low-pressure steam and hot water.
- Recuperators and regenerative burners use air as the heat exchange medium and recover the sensible heat of the exhaust gas as the heat energy of the preheated air.
- One of the features of waste heat that affects waste heat recovery technology is its low energy density.
- the temperature of the exhaust gas may be lower than 300 ° C, and in this case, if heat is exchanged from the exhaust gas to the heat exchange medium with a heat exchanger, only a maximum of 200 to 2500 ° C of heat energy will be generated. It cannot be recovered. Thermal energy with low energy density cannot be used as a low-temperature heating source. To overcome this problem and to recover waste heat with high efficiency, a heat exchanger with a large heat transfer area is required, and the waste heat recovery device tends to be large.
- waste heat recovery technology is limited to combustion air and low-temperature heating sources, etc., and the use destination is limited to the vicinity of the recovery heat source (heating air and steam are connected to piping) When transported far away, etc., the heat dissipation increases and the recovered heat is effectively used. May not be used). For these reasons, it has been extremely difficult to establish waste heat recovery technology economically, especially when the temperature of the exhaust gas is low.
- the present invention provides a new waste heat recovery device, waste heat recovery system, and waste heat recovery that can recover sensible heat of exhaust gas discharged from a combustion device such as a furnace, an internal combustion engine, or a power generation facility as fuel such as H 2 fuel. It aims to provide a method.
- the present invention provides a waste heat recovery apparatus, a waste heat recovery system, and a waste heat recovery method described below.
- a heat exchanger filled with a catalyst for reforming dimethyl ether is installed in the exhaust system of a combustion apparatus such as a furnace, an internal combustion engine, or a power generation facility, and dimethyl ether and H 2 O are installed in the heat exchanger.
- a waste heat recovery apparatus wherein dimethyl ether is thermally decomposed by passing a mixed gas, and sensible heat of exhaust gas from the combustion apparatus is recovered as H 2 fuel.
- a heat exchanger filled with a catalyst for reforming dimethyl ether is installed in the exhaust system of a combustion apparatus such as a furnace, an internal combustion engine or a power generation facility, and a mixture of dimethyl ether and CO 2 is installed in the heat exchanger.
- a waste heat recovery apparatus characterized in that dimethyl ether is thermally decomposed by passing a gas, and sensible heat of exhaust gas from the combustion apparatus is recovered as H 2 and CO fuel.
- a first heat exchanger filled with a catalyst for reforming dimethyl ether is installed in the exhaust system of a combustion apparatus such as a furnace, an internal combustion engine, or a power generation facility, and dimethyl ether is installed in the first heat exchanger.
- a combustion apparatus such as a furnace, an internal combustion engine, or a power generation facility
- dimethyl ether is installed in the first heat exchanger.
- a second heat exchanger is installed, and by passing a mixed gas of dimethyl ether and H 2 0 through the second heat exchanger, dimethyl ether is thermally decomposed, and the sensible heat of the exhaust gas from the combustion device is reduced.
- a waste heat recovery system that collects it as H 2 fuel.
- the H 2 and CO fuel recovered by the first heat exchanger are used to increase the temperature of the exhaust gas of the combustion device that is input to the second heat exchanger.
- the combustion device is a gas turbine, a gas engine, or a diesel engine, and the recovered H 2 fuel or the H 2 and CO fuel is used as fuel for the gas turbine, the gas engine, or the diesel engine.
- the waste heat recovery apparatus according to any one of (1) to (7), characterized in that it is used.
- a waste heat recovery system comprising: a combustion device such as a furnace, an internal combustion engine, or a power generation facility; and a waste heat recovery device that recovers sensible heat of exhaust gas from the combustion device, wherein the waste heat recovery device includes: A heat exchanger filled with a catalyst for reforming dimethyl ether is installed in the exhaust system of the combustion apparatus, and dimethyl ether is thermally decomposed by passing a mixed gas of dimethyl ether and H 2 0 through the heat exchanger.
- a waste heat recovery system that recovers sensible heat of exhaust gas from the combustion device as H 2 fuel.
- a waste heat recovery system comprising: a combustion device such as a furnace, an internal combustion engine or a power generation facility; and a waste heat recovery device that recovers sensible heat of exhaust gas from the combustion device, wherein the waste heat recovery device comprises: A heat exchanger filled with a catalyst for reforming dimethyl ether is installed in the exhaust system of the combustion apparatus, and dimethyl ether is pyrolyzed by passing a mixed gas of dimethyl ether and CO 2 through the heat exchanger, and the combustion A waste heat recovery system that recovers the sensible heat of exhaust gas from the equipment as H 2 and CO fuel.
- a waste heat recovery system comprising: a combustion device such as a furnace, an internal combustion engine or a power generation facility; and a waste heat recovery device that recovers sensible heat of exhaust gas from the combustion device, wherein the waste heat recovery device comprises: A first heat exchanger filled with a catalyst for reforming dimethyl ether is installed in the exhaust system of the combustion apparatus, and dimethyl ether is heated by passing a mixed gas of dimethyl ether and CO 2 through the first heat exchanger. A second heat exchanger filled with a catalyst for reforming dimethyl ether is installed in the exhaust system, the sensible heat of the exhaust gas from the combustion device is recovered as H 2 and CO fuel, and the second heat exchanger is installed.
- the waste heat recovery system further includes a waste heat boiler installed downstream of the second heat exchanger of the exhaust system, and the steam recovered by the waste heat boiler is recovered from the second heat exchanger.
- the waste heat recovery system according to any one of (13) to (15), wherein the waste heat recovery system is supplied to a heat exchanger.
- a heat exchanger filled with a catalyst for reforming dimethyl ether is installed in the exhaust system of a combustion apparatus such as a furnace, internal combustion engine, or power generation facility, and dimethyl ether and H 2 are installed in the heat exchanger.
- a waste heat recovery method characterized in that dimethyl ether is thermally decomposed by passing a mixed gas of 0 and sensible heat of exhaust gas from the combustion apparatus is recovered as H 2 fuel.
- a heat exchanger filled with a catalyst for reforming dimethyl ether is installed in the exhaust system of a combustion apparatus such as a furnace, an internal combustion engine or a power generation facility, and a mixture of dimethyl ether and CO 2 is installed in the heat exchanger.
- a waste heat recovery method characterized in that dimethyl ether is thermally decomposed by passing a gas, and sensible heat of exhaust gas from the combustion device is recovered as H 2 and CO fuel.
- a first heat exchanger filled with a catalyst for reforming dimethyl ether is installed in an exhaust system of a combustion apparatus such as a furnace, an internal combustion engine, or a power generation facility, and dimethyl ether is installed in the first heat exchanger.
- a combustion apparatus such as a furnace, an internal combustion engine, or a power generation facility
- dimethyl ether is installed in the first heat exchanger.
- a catalyst for reforming dimethyl ether is filled in an exhaust system of a combustion apparatus such as a furnace, an internal combustion engine, or a power generation facility, and dimethyl ether is thermally decomposed by blowing dimethyl ether into the exhaust system.
- a waste heat recovery method that recovers the sensible heat of exhaust gas as H 2 fuel.
- a catalyst for reforming dimethyl ether is filled in an exhaust system of a combustion apparatus such as a furnace, an internal combustion engine, or a power generation facility, and dimethyl ether is thermally decomposed by blowing dimethyl ether into the exhaust system.
- a waste heat recovery method that recovers sensible heat from exhaust gas as H 2 and CO fuel.
- the waste heat of the combustion apparatus is not recovered as simple steam, hot water, heated air, etc., but instead of H 2 fuel or H 2 and Since it is recovered as CO fuel, the use of the recovered energy is not limited (that is, it is recovered as the combustion heat of the fuel, so the recovered energy will not decrease even if transported far away. )
- the energy conversion efficiency when dimethyl ether is converted to H 2 can be increased (for example, the exhaust gas temperature is 250 to 300). Even at a low temperature of ° C, the energy conversion efficiency reaches 90% or more).
- waste heat can be recovered as a fuel with high added value
- economical heat recovery can be performed even if the exhaust gas temperature is low (for example, even if the exhaust gas temperature is 300 ° C or less).
- H 2 fuel can be generated, so a general-purpose H 2 fuel hard-working device is obtained, and a large amount of H 2 fuel is consumed. Social system can be realized. .
- H 2 fuel or H 2 and CO fuel can be used as fuel for a gas turbine, a gas engine, or a diesel engine.
- the H 2 fuel or H 2 and CO fuel obtained has a composition and a calorific value close to those of the by-product gas of the steelworks, so that the by-product gas is not generated by blast furnace off-air or the like.
- the existing combustion equipment can be used without modification, and the operation efficiency of the by-product gas at the steelworks can be improved.
- the obtained H 2 fuel or H 2 and CO fuel can be used as fuel for the fuel cell.
- a waste heat recovery system capable of recovering the waste heat of the combustion apparatus as H 2 fuel or H 2 and CO fuel is obtained.
- the C0 2 that occur with H 2 fuel recovered in the second heat exchanger are separated, so to supply the separated C_ ⁇ 2 to the first heat exchanger, CO 2 is circulated, thus reducing CO 2 emissions.
- the recovered H 2 and CO fuel can be used as fuel for a furnace or boiler combustion device.
- the steam supplied to the second heat exchanger can be recovered by the waste heat boiler.
- the waste heat is not recovered as mere steam, hot water, heated air, etc., but is recovered as H 2 fuel or H 2 and CO fuel.
- the use of collected energy is not limited (ie, it will be recovered as the combustion heat of fuel, so the recovered energy will not decrease even if transported far away).
- CO 2 generated together with the H 2 fuel recovered by the second heat exchanger is separated, and the separated CO 2 is supplied to the first heat exchanger. 2 circulation is performed, thus reducing the emissions of CO 2.
- FIG. 1 is a view showing a waste heat recovery apparatus according to a first embodiment of the present invention.
- Figure 2 shows a tubular heat exchanger (recuperator).
- Fig. 3 shows a heat storage type heat exchanger (switching type).
- Fig. 4 shows a heat storage type heat exchanger (rotary type).
- FIG. 5 is a diagram showing a fluidized bed type and heat medium circulation type heat exchanger
- FIG. 5 a shows a fluidized bed type heat exchanger
- FIG. 5 b shows a heat medium circulation type heat exchanger.
- FIG. 6 shows the hydrogen reforming characteristics of DME.
- Figure 7 is a view to view an example of estimated energy conversion efficiency when converting DME to H 2.
- FIG. 8 is a view showing a waste heat recovery apparatus in the second embodiment of the present invention.
- FIG. 9 is a view showing a waste heat recovery apparatus in the third embodiment of the present invention.
- FIG. 10 is a view showing a waste heat recovery apparatus in the fourth embodiment of the present invention.
- FIG. 11 is a system diagram of a waste heat recovery system according to the first embodiment of the present invention (a combined waste heat recovery system of LNG and DME).
- Figure 12 is a system diagram of a waste heat recovery system that uses all LNG.
- Fig. 1 2 a is a system diagram of a waste heat recovery system using LNG as fuel for the furnace
- Fig. 1 2 b is a system diagram of a waste heat recovery system using LNG as fuel for the gas engine generator.
- Fig. 12 c is a system diagram of a waste heat recovery system that uses LNG for the reforming furnace.
- FIG. 13 is a system diagram of a waste heat recovery system according to the second embodiment of the present invention.
- FIG. 1 shows a waste heat recovery apparatus in a first embodiment of the present invention.
- a heat exchanger 2 the heat exchanger 2 (hereinafter referred to as DME) dimethyl ether and water vapor (hereinafter H 2 0 and serial to) passing a mixed gas of.
- DME dimethyl ether and water vapor
- the heat exchanger 2 may have various structures such as a tube type, a plate type, an enlarged heat transfer surface, a heat storage type, a fluidized bed type, and a heat medium circulation type.
- Fig. 2 shows an example of a tubular heat exchanger (a recovery heat exchanger called a recuperator), Figs. 3 and 4 show a heat storage type heat exchanger, and Fig. 5 shows a fluidized bed type and heat medium circulation type. The heat exchanger of is shown.
- recuperator In the recuperator shown in FIG. 2, they are separated by heat transfer tubes 3 as a solid wall and a mixed gas of exhaust gas and DME ⁇ Pi 11 2 0. Inside the heat transfer tube 3, the DME And a mixed gas of H 2 O flows, and the exhaust gas of the high-temperature fluid flows outside the heat transfer tube 3, and these are indirectly contacted to exchange heat. Sensible heat of the exhaust gas radiation is transferred to the mixed gas of DME and H 2 0 through the heat transfer tubes 3 by conduction.
- FIG. 3 shows a switchable regenerative heat exchanger.
- heat storage material A made of alumina balls, honeycomb material, etc. is flowed with exhaust gas of high-temperature fluid to heat storage material A.
- the valve is switched when the heat accumulator A is warmed to some extent, and a mixed gas of low temperature fluid DME and H 2 O is passed through the heat accumulator A.
- the valve is switched to stop the flow of exhaust gas to the heat storage body A and flow the exhaust gas to the heat storage body B.
- heat storage body B has warmed to some extent, switch the valve again and repeat the same operation.
- the valve is switched every predetermined time.
- Figure 4 shows a rotary heat storage heat exchanger.
- the flow paths on both outer sides are divided into a flow path for the exhaust gas of the high temperature fluid and a flow path for the mixed gas of the low temperature fluid DME and H 2 O.
- the central heat accumulator is designed to be able to rotate, and after a predetermined time has passed, the part warmed by the high temperature fluid moves to the low temperature fluid side. Since the low temperature fluid flows warmed parts partial heat storage body, heat is exchanged between the mixed gas of exhaust gas and DME and H 2 0.
- the heat exchanger shown in Fig. 3 or Fig. 4 is placed on the exhaust gas downstream side of the heat exchanger shown in Fig. 2, and the heated mixed gas of DME and H 2 O is transferred to the heat exchange shown in Fig. 2. You may guide. As a result, exhaust gas sensible heat can be efficiently recovered and heated to a temperature range where DME can be thermally decomposed.
- the side of the heat exchanger 2 where the mixed gas of DME and H 2 O flows is filled with a catalyst that converts DME into hydrogen.
- a catalyst that converts DME into hydrogen.
- known catalysts such as alumina, silica, and titania can be used.
- the type of catalyst is not particularly limited, and any type of catalyst may be used as long as DME can be reformed into hydrogen.
- the mixed gas of DME 6 and H 2 0 is passed through, and the mixed gas is thermally decomposed into H 2 and CO to reveal the exhaust gas from the combustion furnace 1.
- Heat may be recovered as H 2 and CO fuel.
- the reaction for reforming DME and CO 2 into H 2 and CO fuel will be described in detail in the second embodiment shown in FIG. Fig. 5a shows a fluidized bed type heat exchanger, and Fig. 5b shows a heat medium circulation type heat exchanger.
- DME and H 2 0 or A mixed gas of C0 2 flows.
- High temperature exhaust gas flows outside the fluidized bed 2a, and heat exchange is performed between the exhaust gas and the mixed gas through the wall surface of the fluidized bed 2a.
- the fluidized bed 2a is filled with the catalyst 2b, and the catalyst 2b flows along with the flow of the mixed gas.
- the mixed gas that has passed through the fluidized bed 2 a is reformed to H 2 or CO + 11 2 by the action of the catalyst 2 b.
- a mixed gas of DME and H 2 O or C0 2 flows in the circulating layer 2 c.
- the circulating layer 2 c is also filled with a catalyst 2 e.
- the mixed gas and the catalyst 2 e circulate in the circulating layer 2 c through the heat transfer tube 2 d.
- High temperature exhaust gas flows outside the heat transfer tube 2d, and heat exchange is performed between the exhaust gas and the mixed gas through the wall surface of the heat transfer tube 2d.
- the mixed gas that has passed through the circulating layer 2 a is reformed to H 2 or CO + H 2 by the action of the catalyst 2 e.
- Figure 6 shows the hydrogen reforming characteristics of DME.
- DME + 3 H 2 0 before the reaction DME is reformed after the reaction to 6H 2 + 2C0 2 .
- the amount of heat increases by 29 kca 1 for 9%, indicating that low-temperature waste heat can be recovered as hydrogen fuel.
- the mixed gas of DME and H 2 0 is less likely to occur is decomposed reaction H 2.
- the reaction in which DME and H 2 0 are decomposed into H 2 and C 0 2 is an endothermic reaction, so the exhaust gas temperature may decrease further.
- a part of the DME used for heat recovery is introduced into the exhaust system so as to increase the amount of heat of the exhaust gas (for example, the temperature of the exhaust gas is increased to 300 ° C or higher) (so-called superheat )
- the exhaust gas may be heated by the combustion heat of the input DME.
- FIG. 7 shows an example of estimated energy conversion efficiency when converting DME to H 2.
- the temperature of exhaust gas 7 is assumed to be 300 ° C. If the exhaust gas 7 at 300 ° C is 20 Nm 3 / h, the heat value of the exhaust gas 7 is 2100 kcal / h.
- DME5 as a heat source is superheated to the exhaust system 4 by 0. lk gZh (688 kca 1 / h).
- the amount of superheated DME 5 is an amount that supplements the reaction heat of the endothermic reaction that decomposes DME 5 into H 2 fuel. Due to the DME5 superheat, the temperature of exhaust gas 10 is 394. Become C.
- Heat exchanger 2 is supplied with DME 6 and H 2 08 at a room temperature of 30 ° C.
- the sensible heat of exhaust gas 7 is used to raise the temperature of DME 6 and H 2 08 to 300 ° C. Since the temperature of exhaust gas 11 discharged from the heat exchanger is 248 ° C, about 50 ° C of exhaust gas 11 is 300 ° C (temperature of exhaust gas 7) 248 ° C (temperature of exhaust gas 11)). Used to warm 6 and H 2 O 8.
- the exhaust gas 10 and the mixed gas of DME 6 and H 2 08 are subjected to heat exchange, and DME 6 is reformed to H 2 fuel 9.
- DME 6 is introduced into heat exchange «2 at 1.05 kg / h (7224 kca 1 / h).
- the resulting H 2 fuel 9 is 2.9 IN mh (7499 kca 1 /).
- DME is burned and the DME is pyrolyzed with the heat.
- the energy conversion efficiency in this case is 7499Z (7224 + 278 8)
- X 100 74.9%, which is reduced to 80% or less. This is because a heat source for pyrolyzing DME is obtained by burning another DME.
- FIG. 8 shows a waste heat recovery apparatus according to the second embodiment of the present invention.
- the waste heat recovery device is installed in the exhaust system of the gas turbine combined system.
- the fuel gas is compressed by the fuel gas compressor 13 and combusted in the combustor 15 together with the air compressed by the air compressor 14.
- the generated high-temperature and high-pressure fuel gas is expanded in the gas turbine 16, and the output is taken out to the external generator 17.
- the exhaust gas from the gas turbine 16 is a high-temperature large stream *.
- a heat exchanger 18 is installed in the exhaust system of the gas turbine 16.
- the mixed gas passing Succoth of DME and C0 2 in heat exchanger 18, the DME is thermally decomposed to recover the sensible heat of the exhaust gas as H 2 and CO fuel.
- the recovered H 2 and CO fuel is mixed with, for example, by-product gas of a steel mill and used as fuel for the gas turbine 16.
- the heat exchanger 18 is filled with a catalyst that reforms DME into H 2 and CO fuel.
- a catalyst that reforms DME into H 2 and CO fuel.
- known catalysts such as ruthenium and nickel can be used.
- the type of catalyst is not particularly limited, and any type of catalyst may be used as long as DME can be reformed to H 2 and CO.
- FIG. 9 shows a waste heat recovery apparatus in the third embodiment of the present invention.
- the waste heat recovery apparatus of this embodiment has a heat exchanger 18 installed in the exhaust system of the combustion apparatus such as the gas turbine 16, and the heat exchanger 18 by passing a mixed gas of DM E and C0 2, the DME was pyrolyzed to recover the sensible heat of the exhaust gas of the combustion apparatus as H 2 and CO fuel.
- the waste heat recovery apparatus of this embodiment dehydrated with the second Unlike the waste heat recovery apparatus of the embodiment, the ⁇ Ga scan comprising C0 2 of the combustion device, a dehydrator ⁇ Pi de 0 2 21 . de 0 2 is passed through the dehydration. de 0 2 was exhaust gas to the heat exchanger 18.
- FIG. 10 shows a waste heat recovery apparatus in the fourth embodiment of the present invention.
- a first heat exchanger 25 that recovers DME as H 2 and CO fuel is installed upstream of the exhaust system of the combustion furnace, and DME is recovered as H 2 fuel downstream.
- 2 heat exchanger 26 is installed.
- the reaction heat of the endothermic reaction in the first heat exchanger 25 is larger than the reaction heat of the endothermic reaction in the second heat exchanger 26.
- the first and second heat exchangers 25 and 26 are arranged in tandem, and the first heat exchanger 25 is arranged upstream and the second heat exchanger 26 is arranged downstream. It is desirable to place it on the side.
- the first heat exchanger 25 is filled with a catalyst for reforming DME into H 2 and CO fuel.
- the first heat exchanger ⁇ 25 collects the sensible heat of the exhaust gas as H 2 and CO fuel.
- the recovered H 2 and CO fuel is supplied to by-product gas systems such as steelworks. W
- DME DME 14 A portion of DME is introduced into the exhaust system between the first heat exchanger 25 and the second heat exchanger 26 so as to increase the temperature of the exhaust gas input to the second heat exchanger 26. It may be burned (so-called super heat).
- the second heat exchanger 26 is filled with a catalyst for reforming DME into H 2 fuel.
- the second heat exchanger 26 is charged with a mixed gas of DME and H 2 O.
- the second heat exchange m3 ⁇ 426 collects the sensible heat of the exhaust gas as H 2 fuel.
- C0 2 discharged from the second heat exchanger 26 together with the H 2 fuel is separated in the separation device 28.
- the separated CO 2 is supplied to the first heat exchanger 25 as a raw material. Since the separated C0 2 has a high concentration, it is not necessary to warm gas other than CO 2 in the first heat exchanger 25, and the DME decomposition reaction can be performed efficiently.
- the H 2 and CO fuels obtained by this embodiment are similar in composition and calorific value to the by-product gas of the steelworks, so as a by-product gas alternative fuel when the by-product gas is insufficient due to blast furnace blast, etc.
- the existing combustion equipment can be used without modification, and the operation efficiency of by-product gas at the steelworks can be improved. This will be described below.
- By-product gas is coke oven gas: 4500 kca 1 / Nm Blast furnace gas: 750 kca 1 / Nm Converter gas: 2000 kca 1 Nm 3 mixed gas, mainly H 2 and CO.
- the fuel gas obtained in this embodiment is H 2 and CO fuel: 2800 kcal / Nm 3 , H 2 fuel: 1800 to 2580 kca 1 / Nm 3 . Since the by-product gas and the fuel gas of the present embodiment are similar in composition and power, the present embodiment is applied to an exhaust gas system of a combustion furnace at a steelworks, and the obtained H 2 fuel, H 2 and If CO fuel is mixed into the by-product gas system, it can be used as an alternative fuel for by-product gas without modifying existing combustion equipment.
- FIG. 11 shows a system diagram of the waste heat recovery system in the first embodiment of the present invention.
- a gas engine generator 31 is used as a combustion device, and the first heat exchanger 25 and the second heat are connected to the exhaust system of the gas engine generator 31 as in the third embodiment.
- Exchange 26 is arranged.
- the first heat exchanger 25 is filled with a catalyst for reforming DME into H 2 and CO fuel.
- the first heat exchanger 25 collects the sensible heat of the exhaust gas as H 2 and CO fuel.
- the second heat exchanger 26 is filled with a catalyst for reforming DME into H 2 fuel.
- the second heat exchanger 26 is charged with a mixed gas of DME and H 2 O.
- the second heat exchanger 26 recovers the sensible heat of the exhaust gas as H 2 fuel.
- C0 2 discharged from the second heat exchanger 26 together with the H 2 fuel is separated in the separation device 28.
- the separated C0 2 is supplied as raw material to the first heat exchanger ⁇ 25.
- the H 2 and CO fuel recovered by the first heat exchanger 25 is used as fuel for the heating furnace 32.
- a combustion apparatus such as a boiler can be used in place of the heating furnace 32.
- a waste heat boiler 33 is installed downstream of the second heat exchanger 26, and the steam recovered by the waste heat boiler 33 is supplied to the second heat exchanger 26.
- a gas engine generator 31 is used for the combustion device, and LNG (liquefied natural gas) is used for the fuel of the gas engine generator instead of DME.
- LNG liquefied natural gas
- DME was supplied to the first and second heat exchangers 25 and 26, it was thought that DME should be used as fuel for the gas engine generator 31.
- DME has about 18% more CO 2 emissions when it is burned as fuel than LNG (the unit of fuel carbon emissions is LNG: 64 .06 gC / Mc a 1 vs. DME: 75.60 gC / Mc a 1), the carbon emission increases due to the carbon emission intensity of the fuel.
- LNG is used as the fuel for the generator 31 in order to reduce carbon emissions.
- this waste heat recovery system is called a combined waste heat recovery system of LNG and DME
- a comparison with a waste heat recovery system using LNG will be explained.
- the two waste heat recovery systems are common in the condition that they generate the same output power with a generator, obtain the same amount of heat in a heating furnace, and produce the same amount of hydrogen.
- Figure 12 shows a system diagram of a system that uses all LNG as a comparative example.
- LNG is used as fuel for the heating furnace 41
- LNG is used as fuel for the generator 42
- LNG is reformed in the reforming furnace 43 to obtain hydrogen
- a waste heat boiler 44 is installed in the exhaust system of the generator 42, and the waste heat of the generator 42 is recovered with steam.
- the heating furnace obtains a calorific value of 3278Mc a 1 / hr
- the generator produces 5500 kw output, and produces 666Nm 3 Zhr of hydrogen. Heat of these values, the output, in order to obtain a quantity of hydrogen is only consumed LNG the amount shown in Table 1 below, also C0 2 is discharged.
- Table 1 shows a calorific value of 3278Mc a 1 / hr
- Case 1 is a waste heat recovery system that uses LNG
- Case 2 is a waste heat recovery system that uses LNG and DME together.
- Case 2 shows that fuel can be reduced by 9% and CO 2 emissions can be reduced by 4%.
- Fuel reduction rate base (17,641 Mcal / h) -9% (16,082 Mcal / h) Total co 2 emission reduction rate base (4,144Kg-C0 2 / h) -4% (3,987Kg-C0 2 /)
- biomass-derived DME DME obtained from coal
- Biomass-derived DME can be distributed in the form of DME mixed with DME derived from several percent of biomass. The spread of DME derived from biomass can further reduce CO 2 emissions from society as a whole.
- FIG. 13 shows a system diagram of the waste heat recovery system in the second embodiment of the present invention.
- the waste heat recovery system of this embodiment includes a power generation facility 51 that generates electricity using existing fuels such as LNG and heavy oil, and a waste heat recovery and hydrogen production device that recovers sensible heat from the exhaust gas of the power generation facility 51.
- Waste heat recovery ⁇ Hydrogen production device 52 reforms the supplied DME into H 2 + C 0 2 or H 2 + CO fuel, similar to the waste heat recovery device described above.
- the produced H 2 fuel is separated by the hydrogen separation device 53 and then supplied to the fuel cell 54 or used as fuel for a fuel cell vehicle.
- This waste heat recovery system is controlled as follows, for example. When electricity is in high demand (daytime), all the hydrogen produced by the waste heat recovery and hydrogen production device 52 is sent to the fuel cell 54, where it is converted into energy. On the other hand, when electricity demand is low (nighttime), the hydrogen produced by the waste heat recovery / hydrogen production device 52 is stored as fuel for fuel cell vehicles. In this way, a power generation system having a load adjustment function (that is, hydrogen production and power generation can be selected) can be realized by recovering power generation waste heat with hydrogen.
- the waste heat recovery device of the present invention is not limited to the power generation and mining fields, but includes various industrial fields such as petrochemicals, paper / pulp, non-ferrous metals, cement, ceramics, and transportation, internal combustion engines or power generation facilities. It can also be installed in the exhaust system of combustion equipment for consumer and commercial air conditioning, kitchens, and hot water heaters. Furthermore, the waste heat recovery apparatus of the present invention is preferably an exhaust system having an exhaust gas temperature of 300 ° C. or higher, but is also effectively applied to an exhaust system having an exhaust gas temperature of 300 ° C. or lower. can do.
- the waste heat recovery system of the present invention is not limited to the case where there is a generator, a heating furnace, or hydrogen reforming, but a waste heat recovery device is incorporated in the exhaust system of the furnace, the internal combustion engine, or the power generation equipment. If it exists, it can be applied to various types of waste heat recovery systems. For example, a waste heat boiler is not necessary in situations where steam is not required.
- the heating furnace in the waste heat recovery system of the present invention may be an industrial heating furnace, a combustion device for air conditioning, a kitchen, or a hot water supply, or may be replaced with a fuel cell.
- DME may be directly blown into the exhaust system filled with the catalyst to reform DME into H 2 fuel, or H 2 and CO fuel without providing heat exchange.
Abstract
Description
Claims
Priority Applications (2)
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US11/629,590 US20070183966A1 (en) | 2004-06-30 | 2005-06-29 | Waste heat recovery apparatus, waste heat recovery system, and method of recovering waste heat |
EP05758119A EP1780388A1 (en) | 2004-06-30 | 2005-06-29 | Waste heat recovering apparatus, waste heat recovering system and waste heat recovering method |
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JP2004193249 | 2004-06-30 | ||
JP2004-193249 | 2004-06-30 | ||
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JP2005116222A JP2006046319A (ja) | 2004-06-30 | 2005-04-13 | 廃熱回収装置、廃熱回収システム及び廃熱回収方法 |
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US (1) | US20070183966A1 (ja) |
EP (1) | EP1780388A1 (ja) |
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JP2006050887A (ja) * | 2004-07-02 | 2006-02-16 | Jfe Holdings Inc | エネルギー供給方法及びシステム |
JP4921871B2 (ja) * | 2006-06-28 | 2012-04-25 | 関西電力株式会社 | ジメチルエーテル改質発電システム |
US20090162268A1 (en) * | 2007-12-19 | 2009-06-25 | Air Products And Chemicals, Inc. | Carbon Dioxide Separation Via Partial Pressure Swing Cyclic Chemical Reaction |
JP5154968B2 (ja) * | 2008-02-14 | 2013-02-27 | Jfeスチール株式会社 | 二酸化炭素を含有する混合ガスの改質・分離方法 |
DE102008014799A1 (de) * | 2008-03-18 | 2009-09-24 | Karl-Heinz Tetzlaff | Verfahren und Vorrichtung zur Herstellung von Synthesegas aus Biomasse |
DE102009020268B4 (de) * | 2009-05-07 | 2011-05-26 | Siemens Aktiengesellschaft | Verfahren zur Erzeugung elektrischer Energie sowie Verwendung eines Arbeitsmittels |
JP2011102658A (ja) * | 2009-11-10 | 2011-05-26 | Jfe Steel Corp | 冶金炉発生排ガスからの顕熱回収方法および冶金炉発生排ガスの冷却方法 |
US7963257B2 (en) * | 2010-04-15 | 2011-06-21 | Scott Houtz | Sustainable waste heat management system |
CN101871731A (zh) * | 2010-06-02 | 2010-10-27 | 昆明理工大学 | 二甲醚规模化工业燃烧的方法 |
US9216905B2 (en) | 2011-06-03 | 2015-12-22 | Ronald G. Presswood, Jr. | Gasification or liquefaction of coal using a metal reactant alloy composition |
KR101351318B1 (ko) * | 2011-12-13 | 2014-02-13 | 재단법인 포항산업과학연구원 | 수소 제조를 위한 용융 슬래그 입자의 현열 회수 장치 및 방법 |
WO2014122894A1 (en) * | 2013-02-08 | 2014-08-14 | Toyo Engineering Corporation | Process for recovering carbon dioxide from combustion exhaust gas |
DE102013224257A1 (de) * | 2013-11-27 | 2015-05-28 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren und Vorrichtung zur thermochemischen Wasserstofferzeugung mit einem Verbrennungsmotor |
JP6132317B2 (ja) * | 2014-03-24 | 2017-05-24 | 寛治 泉 | 温室効果ガス排出削減方法。 |
WO2015146368A1 (ja) * | 2014-03-24 | 2015-10-01 | 寛治 泉 | 温室効果ガス排出削減策の内燃機関及び/又は機器 |
JP2016151179A (ja) * | 2015-02-16 | 2016-08-22 | 寛治 泉 | 温室効果ガス排出削減方法。 |
US10427192B2 (en) | 2015-05-15 | 2019-10-01 | Ronald G. Presswood, Jr. | Method to recycle plastics, electronics, munitions or propellants using a metal reactant alloy composition |
US10112860B1 (en) * | 2016-07-15 | 2018-10-30 | Praxair Technology, Inc. | Thermochemical regeneration with fuel additions |
DE102016012669B4 (de) * | 2016-10-22 | 2020-03-19 | LaRoSe GmbH | Verfahren zum Betreiben eines Antriebsaggregates mit hohem Wirkungsgrad und Antriebsaggregat |
WO2022181619A1 (ja) * | 2021-02-26 | 2022-09-01 | 京セラ株式会社 | 水素製造装置及び水素製造方法 |
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- 2005-06-29 EP EP05758119A patent/EP1780388A1/en not_active Withdrawn
- 2005-06-29 US US11/629,590 patent/US20070183966A1/en not_active Abandoned
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