WO2006002610A1 - Verfahren zum abtragen einer beschichtung von einem bauteil - Google Patents
Verfahren zum abtragen einer beschichtung von einem bauteil Download PDFInfo
- Publication number
- WO2006002610A1 WO2006002610A1 PCT/DE2005/001090 DE2005001090W WO2006002610A1 WO 2006002610 A1 WO2006002610 A1 WO 2006002610A1 DE 2005001090 W DE2005001090 W DE 2005001090W WO 2006002610 A1 WO2006002610 A1 WO 2006002610A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coating
- removal
- compounds
- turbine blades
- added
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
- B08B3/12—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/16—Acidic compositions
- C23F1/26—Acidic compositions for etching refractory metals
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/44—Compositions for etching metallic material from a metallic material substrate of different composition
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
- C23G1/106—Other heavy metals refractory metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F5/00—Electrolytic stripping of metallic layers or coatings
Definitions
- the invention relates to a method for removing a coating containing chromium and / or chromium oxide compounds from a component by means of a decoating bath.
- Such a stripping process can be carried out according to EP 1 094 134 A1, for example by means of an electrochemical process.
- the component to be stripped is immersed in an electrolyte and thereby forms the working electrode.
- the layer to be stripped is dissolved on the component.
- EP 1 314 797, A2 Another method for stripping components is described in EP 1 314 797, A2. This is a chemical stripping process.
- the component to be stripped is immersed in a solution with hydrochloric acid and an inhibitor which reduces the attack on the base material of the component.
- the stripping bath formed by the hydrochloric acid causes the dissolution of the coating.
- turbine blades can be stripped off if they have reached the end of the stated service life. By a subsequent recoating a further life cycle of the turbine blades can be made possible, which is why there is a great interest in an effective stripping of turbine blades.
- the stripping of turbine blades not only the used coatings, such as MCrAlY coatings or even thermal protective layers (thus Thermal Barrier Coating, hereinafter referred to as TBC), but also impurities arising on the coating during the operating time of the turbine blade, which preferably consist of complex crystalline compounds.
- TBC thermal protective layers
- impurities arising on the coating during the operating time of the turbine blade which preferably consist of complex crystalline compounds.
- Ca-Mg-Al-Si-O system hereinafter referred to CMAS.
- TGO thermally grown oxides on the base material of the coated component
- TGO thermally grown oxides on the base material of the coated component
- B. Cr 2 ⁇ 3 or Cr x Co y O compounds These compounds have a high chemical stability, which is why they can be removed with the decoating only with great effort.
- such compounds can also be formed during the stripping process, which additionally delays the stripping process.
- the compounds increasingly occupy the surface of the component to be stripped, which is why the removal rate during stripping decreases with increasing treatment time.
- EP 1 314 797 A2 it is therefore proposed to carry out the stripping process in several steps, in each case mechanical treatment of the surfaces taking place between the treatment steps, so that the resulting or not yet removed impurities can be removed.
- the object of the invention is to specify a method for removing coatings containing chromium and / or chromium oxide compounds, which allows short treatment times for the stripping process.
- This object is achieved by a method for removing a chromium and / or chromium oxide compounds enthal ⁇ border coating of a component, wherein the be ⁇ coated component placed in a stripping bath and is removed again after the treatment time, wherein the decoating bath as an inhibitor an alkanolamine compound or a salt containing these are added.
- alkanolamine compounds and salts containing them as inhibitors that they not only reduce the attack of the base material of the coated component by the stripping bath, but also suppress the formation of TGO or the dissolution of TGO and CMAS accelerate. This advantageously makes it possible to maintain a stripping process with comparatively high removal rates over a longer treatment period than is possible with the inhibitors used according to the prior art.
- the method according to the invention can be used more economically, in particular, an interruption of the
- Decoating process for the purpose of interposition of a me ⁇ chanical processing step omitted or at least the treatment periods between these mechanical processing steps are extended. Overall, this advantageously reduces the process time required for the stripping process, which is why the process can be used more economically. Furthermore, damage to the base material of the coated component due to mechanical processing steps can be avoided, as a result of which the rejects during stripping are reduced, which additionally contributes to improved cost-effectiveness of the method.
- the use of triethanolamine or one of its salts, such as, for example, is particularly effective.
- the method according to the invention can be used particularly advantageously in the stripping of turbine blades, in which in particular MCrAlY coatings and / or thermal protective layers can be removed from the turbine blades.
- the MCrAlY coating often serves as an intermediate layer between the turbine blade and the thermal protection layer (TBC).
- TBC thermal protection layer
- the mentioned layer systems can also be removed from any other components, as far as this is necessary (eg of supply pipes for gas turbines).
- FIGURE shows a diagram which shows the course of various embodiments of the method according to the invention.
- the exemplary embodiment of the method consisted of removing an MCrAlY coating on turbine blades which had been claimed for operation, wherein a five percent hydrochloric acid was used as the stripping bath. Furthermore, triethanolamine in one percent or two percent concentration was added in parallelteur ⁇ conducted procedures. During the treatment time, the de-coating bath was subjected to ultrasound at a frequency of 36 kHz.
- the exemplary embodiments of the method according to the invention were an electrochemical stripping, the potential on the turbine blade being kept at 0.100 V SCE or 0.340 V SHE.
- the diagram shows over the treatment time t in hours h the at the turbine blade measured current I in amperes A. This current can be used as a direct measure of the removal rate at the turbine blade.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05770315A EP1761660A1 (de) | 2004-06-30 | 2005-06-13 | Verfahren zum abtragen einer beschichtung von einem bauteil |
US11/630,137 US20080277288A1 (en) | 2004-06-30 | 2005-06-13 | Method For Removing A Coating From A Component |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04015424A EP1612299B1 (de) | 2004-06-30 | 2004-06-30 | Verfahren und Vorrichtung zur Oberflächenbehandlung eines Bauteils |
EP04015424.7 | 2004-06-30 | ||
DE102004053135.8 | 2004-10-29 | ||
DE200410053135 DE102004053135A1 (de) | 2004-10-29 | 2004-10-29 | Verfahren zum Abtragen einer Beschichtung von einem Bauteil |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006002610A1 true WO2006002610A1 (de) | 2006-01-12 |
Family
ID=34972912
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE2005/001090 WO2006002610A1 (de) | 2004-06-30 | 2005-06-13 | Verfahren zum abtragen einer beschichtung von einem bauteil |
Country Status (3)
Country | Link |
---|---|
US (1) | US20080277288A1 (de) |
EP (1) | EP1761660A1 (de) |
WO (1) | WO2006002610A1 (de) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1870497A1 (de) * | 2006-06-23 | 2007-12-26 | Siemens Aktiengesellschaft | Verfahren zum elektrochemischen Entfernen einer metallischen Beschichtung von einem Bauteil |
WO2009037045A1 (de) * | 2007-09-14 | 2009-03-26 | Extrude Hone Gmbh | Elektrolyt für die elektrochemische bearbeitung |
US8673405B2 (en) | 2006-08-08 | 2014-03-18 | Siemens Aktiengesellschaft | Method for producing a wear layer |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006044416A1 (de) * | 2006-09-18 | 2008-03-27 | Siemens Ag | Verfahren zum elektrochemischen Be- oder Entschichten von Bauteilen |
FR3004735B1 (fr) * | 2013-04-23 | 2015-07-03 | Dourdin | Procede de vernissage de pieces metallisees |
US9926517B2 (en) | 2013-12-09 | 2018-03-27 | General Electric Company | Cleaning solution and methods of cleaning a turbine engine |
US20150159122A1 (en) * | 2013-12-09 | 2015-06-11 | General Electric Company | Cleaning solution and methods of cleaning a turbine engine |
BR102016021259B1 (pt) | 2015-10-05 | 2022-06-14 | General Electric Company | Método e soluções de limpeza de um motor de turbina e composição de reagente |
CN113106532B (zh) * | 2021-04-07 | 2023-04-11 | 江苏源清动力技术有限公司 | 一种航空发动机和燃气轮机热部件热障涂层去除工艺 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2254398A1 (de) * | 1972-11-07 | 1974-05-16 | Dillenberg Bergische Metall | Bad zum elektrolytischen abloesen von metallueberzuegen |
US4233124A (en) * | 1979-10-29 | 1980-11-11 | Oxy Metal Industries Corporation | Electrolytic stripping bath and process |
DE3420702A1 (de) * | 1984-06-02 | 1985-12-05 | Dico Gesellschaft für Galvanotechnik mbH & Co KG, 4020 Mettmann | Bad zum elektrolytischen abziehen von metallueberzuegen auf aluminium und magnesium |
JPH02285081A (ja) * | 1989-04-25 | 1990-11-22 | Sanyo Chem Ind Ltd | エッチング液 |
EP1094134A1 (de) | 1999-10-18 | 2001-04-25 | General Electric Company | Elektrochemische Vorrichtung und Verfahren zum Abziehen von metallischen Überzügen |
US6454870B1 (en) * | 2001-11-26 | 2002-09-24 | General Electric Co. | Chemical removal of a chromium oxide coating from an article |
US6878215B1 (en) * | 2004-05-27 | 2005-04-12 | General Electric Company | Chemical removal of a metal oxide coating from a superalloy article |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6165345A (en) * | 1999-01-14 | 2000-12-26 | Chromalloy Gas Turbine Corporation | Electrochemical stripping of turbine blades |
-
2005
- 2005-06-13 US US11/630,137 patent/US20080277288A1/en not_active Abandoned
- 2005-06-13 WO PCT/DE2005/001090 patent/WO2006002610A1/de active Application Filing
- 2005-06-13 EP EP05770315A patent/EP1761660A1/de not_active Withdrawn
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2254398A1 (de) * | 1972-11-07 | 1974-05-16 | Dillenberg Bergische Metall | Bad zum elektrolytischen abloesen von metallueberzuegen |
US4233124A (en) * | 1979-10-29 | 1980-11-11 | Oxy Metal Industries Corporation | Electrolytic stripping bath and process |
DE3420702A1 (de) * | 1984-06-02 | 1985-12-05 | Dico Gesellschaft für Galvanotechnik mbH & Co KG, 4020 Mettmann | Bad zum elektrolytischen abziehen von metallueberzuegen auf aluminium und magnesium |
JPH02285081A (ja) * | 1989-04-25 | 1990-11-22 | Sanyo Chem Ind Ltd | エッチング液 |
EP1094134A1 (de) | 1999-10-18 | 2001-04-25 | General Electric Company | Elektrochemische Vorrichtung und Verfahren zum Abziehen von metallischen Überzügen |
US6454870B1 (en) * | 2001-11-26 | 2002-09-24 | General Electric Co. | Chemical removal of a chromium oxide coating from an article |
EP1314797A2 (de) | 2001-11-26 | 2003-05-28 | General Electric Company | Chemische Entfernung von Chromoxidschichten von einem Gegenstand |
US6878215B1 (en) * | 2004-05-27 | 2005-04-12 | General Electric Company | Chemical removal of a metal oxide coating from a superalloy article |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 015, no. 056 (C - 0804) 8 February 1991 (1991-02-08) * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1870497A1 (de) * | 2006-06-23 | 2007-12-26 | Siemens Aktiengesellschaft | Verfahren zum elektrochemischen Entfernen einer metallischen Beschichtung von einem Bauteil |
WO2007147655A1 (de) * | 2006-06-23 | 2007-12-27 | Siemens Aktiengesellschaft | Verfahren zum elektrochemischen entfernen einer metallischen beschichtung von einem bauteil |
US8673405B2 (en) | 2006-08-08 | 2014-03-18 | Siemens Aktiengesellschaft | Method for producing a wear layer |
WO2009037045A1 (de) * | 2007-09-14 | 2009-03-26 | Extrude Hone Gmbh | Elektrolyt für die elektrochemische bearbeitung |
Also Published As
Publication number | Publication date |
---|---|
US20080277288A1 (en) | 2008-11-13 |
EP1761660A1 (de) | 2007-03-14 |
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