WO2005090327A1 - Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles - Google Patents

Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles Download PDF

Info

Publication number
WO2005090327A1
WO2005090327A1 PCT/US2004/008156 US2004008156W WO2005090327A1 WO 2005090327 A1 WO2005090327 A1 WO 2005090327A1 US 2004008156 W US2004008156 W US 2004008156W WO 2005090327 A1 WO2005090327 A1 WO 2005090327A1
Authority
WO
WIPO (PCT)
Prior art keywords
alkyl
chosen
mono
alkoxy
phenyl
Prior art date
Application number
PCT/US2004/008156
Other languages
English (en)
French (fr)
Inventor
Robert W. Walters
Anil Kumar
Clara E. Nelson
Anu Chopra
Original Assignee
Transitions Optical, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Transitions Optical, Inc. filed Critical Transitions Optical, Inc.
Priority to BRPI0408540-0B1A priority Critical patent/BRPI0408540B1/pt
Priority to ES04749405.9T priority patent/ES2688272T3/es
Priority to MXPA05009631A priority patent/MXPA05009631A/es
Priority to JP2005518823A priority patent/JP4160980B2/ja
Priority to EP04749405.9A priority patent/EP1606274B9/en
Priority to AU2004311372A priority patent/AU2004311372B8/en
Priority to KR1020057017368A priority patent/KR100752834B1/ko
Priority to CA 2512605 priority patent/CA2512605C/en
Priority to CN2004800075708A priority patent/CN1761660B/zh
Publication of WO2005090327A1 publication Critical patent/WO2005090327A1/en
Priority to HK06109470A priority patent/HK1089161A1/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/78—Ring systems having three or more relevant rings
    • C07D311/92—Naphthopyrans; Hydrogenated naphthopyrans
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02—Organic tenebrescent materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/259—Coating or impregnation provides protection from radiation [e.g., U.V., visible light, I.R., micscheme-change-itemave, high energy particle, etc.] or heat retention thru radiation absorption

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pyrane Compounds (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Optical Filters (AREA)
  • Eyeglasses (AREA)
  • Materials For Medical Uses (AREA)
PCT/US2004/008156 2003-03-20 2004-03-16 Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles WO2005090327A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
BRPI0408540-0B1A BRPI0408540B1 (pt) 2003-03-20 2004-03-16 Material fotocrômico da estrutura de indeno [2'.3':3.4] nafto[1,2-b] pirano, artigo fotocrômico, naftopirano e naftol
ES04749405.9T ES2688272T3 (es) 2003-03-20 2004-03-16 Naftopiranos fotocrómicos condensados con indeno, naftoles y artículos fotocrómicos
MXPA05009631A MXPA05009631A (es) 2003-03-20 2004-03-16 Naftopiranos fotocromicos indeno-fusionados, naftoles y articulos fotocromicos.
JP2005518823A JP4160980B2 (ja) 2003-03-20 2004-03-16 インデノ縮合フォトクロミックナフトピラン、ナフトールおよびフォトクロミック物品
EP04749405.9A EP1606274B9 (en) 2003-03-20 2004-03-16 Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles
AU2004311372A AU2004311372B8 (en) 2003-03-20 2004-03-16 Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles
KR1020057017368A KR100752834B1 (ko) 2003-03-20 2004-03-16 인데노-융합된 광변색성 나프토피란, 나프톨 및 광변색성제품
CA 2512605 CA2512605C (en) 2003-03-20 2004-03-16 Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles
CN2004800075708A CN1761660B (zh) 2003-03-20 2004-03-16 茚稠合的光致变色萘并吡喃类,萘酚类和光致变色制品
HK06109470A HK1089161A1 (en) 2003-03-20 2006-08-25 Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/393,177 US7262295B2 (en) 2003-03-20 2003-03-20 Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles
US10/393,177 2003-03-20

Publications (1)

Publication Number Publication Date
WO2005090327A1 true WO2005090327A1 (en) 2005-09-29

Family

ID=32988076

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/008156 WO2005090327A1 (en) 2003-03-20 2004-03-16 Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles

Country Status (13)

Country Link
US (3) US7262295B2 (US07517982-20090414-C00001.png)
EP (3) EP2345647A3 (US07517982-20090414-C00001.png)
JP (1) JP4160980B2 (US07517982-20090414-C00001.png)
KR (1) KR100752834B1 (US07517982-20090414-C00001.png)
CN (2) CN1761660B (US07517982-20090414-C00001.png)
AU (1) AU2004311372B8 (US07517982-20090414-C00001.png)
BR (1) BRPI0408540B1 (US07517982-20090414-C00001.png)
CA (1) CA2512605C (US07517982-20090414-C00001.png)
ES (2) ES2688272T3 (US07517982-20090414-C00001.png)
HK (1) HK1089161A1 (US07517982-20090414-C00001.png)
MX (1) MXPA05009631A (US07517982-20090414-C00001.png)
WO (1) WO2005090327A1 (US07517982-20090414-C00001.png)
ZA (1) ZA200508177B (US07517982-20090414-C00001.png)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010507699A (ja) * 2006-10-26 2010-03-11 チバ ホールディング インコーポレーテッド フォトクロミックシステム用光吸収層
JP2010508399A (ja) * 2006-10-30 2010-03-18 トランジションズ オプティカル， インコーポレイテッド 退色速度改善を示すフォトクロミック材料
WO2011078030A1 (ja) * 2009-12-22 2011-06-30 株式会社トクヤマ クロメン化合物
WO2012082381A1 (en) * 2010-12-16 2012-06-21 Transitions Optical, Inc. Indeno- fused ring compounds having photochromic properties
WO2012102410A1 (ja) 2011-01-28 2012-08-02 株式会社トクヤマ クロメン化合物
CN103339123B (zh) * 2010-12-16 2016-11-30 光学转变公司 具有光致变色性质的茚并稠环化合物

Families Citing this family (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050258408A1 (en) * 2001-12-20 2005-11-24 Molock Frank F Photochromic contact lenses and methods for their production
US7632540B2 (en) 2003-07-01 2009-12-15 Transitions Optical, Inc. Alignment facilities for optical dyes
US8518546B2 (en) 2003-07-01 2013-08-27 Transitions Optical, Inc. Photochromic compounds and compositions
US8211338B2 (en) * 2003-07-01 2012-07-03 Transitions Optical, Inc Photochromic compounds
US8698117B2 (en) 2003-07-01 2014-04-15 Transitions Optical, Inc. Indeno-fused ring compounds
US8545984B2 (en) 2003-07-01 2013-10-01 Transitions Optical, Inc. Photochromic compounds and compositions
WO2005059060A1 (en) * 2003-12-15 2005-06-30 Worcester Polytechnic Institute Films with photoresponsive wettability
US20060227287A1 (en) * 2005-04-08 2006-10-12 Frank Molock Photochromic ophthalmic devices made with dual initiator system
US9052438B2 (en) * 2005-04-08 2015-06-09 Johnson & Johnson Vision Care, Inc. Ophthalmic devices comprising photochromic materials with reactive substituents
US20060228557A1 (en) * 2005-04-08 2006-10-12 Beon-Kyu Kim Photochromic materials having extended pi-conjugated systems and compositions and articles including the same
US20060226402A1 (en) * 2005-04-08 2006-10-12 Beon-Kyu Kim Ophthalmic devices comprising photochromic materials having extended PI-conjugated systems
US9028728B2 (en) 2005-04-08 2015-05-12 Transitions Optical, Inc. Photochromic materials that include indeno-fused naphthopyrans
US8158037B2 (en) 2005-04-08 2012-04-17 Johnson & Johnson Vision Care, Inc. Photochromic materials having extended pi-conjugated systems and compositions and articles including the same
US8647538B2 (en) 2005-04-08 2014-02-11 Transitions Optical, Inc. Photochromic compounds having at least two photochromic moieties
US7556750B2 (en) * 2005-04-08 2009-07-07 Transitions Optical, Inc. Photochromic materials with reactive substituents
US8147725B2 (en) 2005-04-08 2012-04-03 Transitions Optical, Inc Photochromic materials having extended pi-conjugated systems and compositions and articles including the same
US9139552B2 (en) 2005-04-08 2015-09-22 Transitions Optical, Inc. Indeno-fused naphthopyrans having ethylenically unsaturated groups
WO2008033291A2 (en) * 2006-09-11 2008-03-20 Alphamicron, Inc. Photochromic devices and methods for making the same
US7667285B2 (en) * 2006-12-14 2010-02-23 Motorola, Inc. Printed electronic substrate havine photochromic barrier layer
JP5320722B2 (ja) * 2007-11-06 2013-10-23 東ソー株式会社 ベンゾフルオレノン誘導体及びその製造方法
US20090326186A1 (en) * 2008-06-27 2009-12-31 Transitions Optical, Inc. Mesogen containing compounds
US20100014010A1 (en) * 2008-06-27 2010-01-21 Transitions Optical, Inc. Formulations comprising mesogen containing compounds
US8431039B2 (en) 2008-06-27 2013-04-30 Transitions Optical, Inc. Mesogenic stabilizers
US7910020B2 (en) * 2008-06-27 2011-03-22 Transitions Optical, Inc. Liquid crystal compositions comprising mesogen containing compounds
US8613868B2 (en) 2008-06-27 2013-12-24 Transitions Optical, Inc Mesogenic stabilizers
US8628685B2 (en) 2008-06-27 2014-01-14 Transitions Optical, Inc Mesogen-containing compounds
US8349210B2 (en) 2008-06-27 2013-01-08 Transitions Optical, Inc. Mesogenic stabilizers
US8623238B2 (en) 2008-06-27 2014-01-07 Transitions Optical, Inc. Mesogenic stabilizers
US7910019B2 (en) 2008-06-27 2011-03-22 Transitions Optical, Inc. Mesogen containing compounds
US8217188B2 (en) * 2008-08-27 2012-07-10 Corning Incorporated 2H-chromenes annelated at C5-C6 and methods of making and using thereof
CN101503484B (zh) * 2009-03-04 2010-11-17 东北师范大学 含萘酚吡喃基团光致变色交联聚合物的合成方法
US8518305B2 (en) 2009-10-28 2013-08-27 Transitions Optical, Inc. Photochromic materials
US8920928B2 (en) 2010-12-16 2014-12-30 Transitions Optical, Inc. Photochromic compounds and compositions
US9034219B2 (en) * 2010-12-16 2015-05-19 Transitions Optical, Inc. Photochromic compounds and compositions
US8859097B2 (en) * 2010-12-16 2014-10-14 Transitions Optical, Inc. Photochromic compounds, compositions and articles
US9139571B2 (en) 2010-12-16 2015-09-22 Transitions Optical, Inc. Methods of making fused ring compounds
EP2966102B1 (en) * 2013-03-04 2019-03-27 Tokuyama Corporation Curable photochromic composition, cured product thereof, and laminate including cured product
US9206151B2 (en) 2013-11-20 2015-12-08 Transitions Optical, Inc. Method of preparing fused ring indeno compounds
US9051332B1 (en) 2013-11-20 2015-06-09 Transitions Optical, Inc. Photochromic indeno-fused ring pyran compounds
US9029565B1 (en) 2013-11-20 2015-05-12 Transitions Optical, Inc. Fused ring indeno compounds for preparation of photochromic compounds
WO2017047745A1 (ja) * 2015-09-16 2017-03-23 三井化学株式会社 光学材料用重合性組成物、該組成物から得られる光学材料およびプラスチックレンズ
CN106218172A (zh) * 2016-08-30 2016-12-14 常州山由帝杉防护材料制造有限公司 光致变色窗膜
CN108047008A (zh) * 2017-12-18 2018-05-18 蚌埠学院 一种3,4-二甲氧基二苯甲酮的制备方法
KR20210010455A (ko) * 2018-05-17 2021-01-27 가부시끼가이샤 도꾸야마 저수분량 폴리로탁산 모노머, 및 해당 모노머를 포함하는 경화성 조성물
CN113227259A (zh) 2018-12-21 2021-08-06 光学转变有限公司 吲哚萘并吡喃及包含吲哚萘并吡喃的光致变色组合物
WO2020126033A1 (en) 2018-12-21 2020-06-25 Transitions Optical, Ltd. Method for preparing indolenaphthopyrans
AU2018454271A1 (en) 2018-12-21 2021-07-08 Transitions Optical, Ltd. Articles comprising indolenaphthopyrans
AU2018454681B2 (en) 2018-12-21 2023-11-23 Transitions Optical, Ltd. Indolonaphthopyrans
JP2022151089A (ja) * 2021-03-26 2022-10-07 ホヤ レンズ タイランド リミテッド インデノ縮合ナフトピラン化合物の粒子、重合性組成物の製造方法及びフォトクロミック物品の製造方法
CN113735694A (zh) * 2021-09-14 2021-12-03 西安瑞联新材料股份有限公司 一种合成9-卤-7H-苯并[c]芴-7-酮的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19741705A1 (de) * 1997-09-22 1999-04-01 Rodenstock Optik G Naphtopyrane
EP1054010A1 (en) * 1999-05-20 2000-11-22 Tokuyama Corporation Chromene compound
WO2001019813A1 (en) * 1999-09-17 2001-03-22 Transitions Optical, Inc. Novel indeno-fused photochromic naphthopyrans
WO2001094336A1 (de) * 2000-06-07 2001-12-13 Optische Werke G. Rodenstock Photochrome pyranderivate

Family Cites Families (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3361706A (en) * 1964-03-06 1968-01-02 American Cyanamid Co Control of the photochromic return rate of (arylazo) thioformic arylhydrazidates
US4166043A (en) * 1974-12-23 1979-08-28 American Optical Corporation Stabilized photochromic materials
US4367170A (en) * 1975-01-24 1983-01-04 American Optical Corporation Stabilized photochromic materials
US4360653A (en) 1981-10-23 1982-11-23 Ppg Industries, Inc. Polymerizate of (allyl carbonate) and aliphatic polyurethane having acrylic unsaturation
US4720356A (en) 1982-03-22 1988-01-19 American Optical Corporation Photochromic composition resistant to fatigue
US4556605A (en) 1982-09-09 1985-12-03 Kabushiki Kaisha Suwa Seikosha Photochromic coating composition and photochromic synthetic resin ophthalmic lens
AU564689B2 (en) 1985-07-09 1987-08-20 Kureha Kagaku Kogyo K.K. Photochromic lens
CA1340939C (en) * 1987-02-02 2000-03-28 Ryojiro Akashi Photochromic compound
GB8712210D0 (en) 1987-05-22 1987-06-24 Pilkington Brothers Plc Photochromic articles
US4798745A (en) 1987-08-24 1989-01-17 Ppg Industries, Inc. Non-yellowing coating composition based on a hydroxy component and an anhydride component and utilization in a process of coating
US4798746A (en) 1987-08-24 1989-01-17 Ppg Industries, Inc. Basecoat/clearcoat method of coating utilizing an anhydride additive in the thermoplastic polymer-containing basecoat for improved repairability
US4873029A (en) 1987-10-30 1989-10-10 Blum Ronald D Method for manufacturing lenses
US4931220A (en) * 1987-11-24 1990-06-05 Ppg Industries, Inc. Organic photochromic pigment particulates
US5252742A (en) * 1989-02-28 1993-10-12 Otsuka Kagaku Kabushiki Kaisha Spiropyran compounds
US4994208A (en) 1989-04-18 1991-02-19 Ppg Industries, Inc. Photochromic polymeric article
EP0420397B1 (en) * 1989-07-28 1995-11-29 Wako Pure Chemical Industries Ltd Fulgimide derivatives
DE69119507T2 (de) * 1990-02-23 1996-10-02 Otsuka Kagaku Kk Benzoselenazolin-spiro-vinylpyranderivat und darauf basierendes polymer
US5373033A (en) 1990-04-20 1994-12-13 Sola International Holdings Limited Casting composition
US5239012A (en) 1991-02-21 1993-08-24 Ppg Industries, Inc. Ambient temperature curing compositions containing a hydroxy component and an anhydride component and an onium salt
US5200483A (en) 1991-11-07 1993-04-06 Ppg Industries, Inc. Polyol(allyl carbonate) composiitons and articles prepared there from
WO1994008260A1 (en) 1992-09-25 1994-04-14 Ppg Industries, Inc. Photochromic compositions of improved fatigue resistance
US5274132A (en) 1992-09-30 1993-12-28 Transitions Optical, Inc. Photochromic naphthopyran compounds
DE59304881D1 (de) * 1992-10-15 1997-02-06 Ciba Geigy Ag Polymerisierbare photochrome Napthacendione, Polymere dieser Monomeren, Verfahren zu deren Herstellung, und deren Verwendung
AU665480B2 (en) 1993-01-29 1996-01-04 Tokuyama Corporation Polymerizable composition, polymer, organic glass and ophthalmic lens
US5618586A (en) 1994-03-29 1997-04-08 Ppg Industries, Inc. N-alkoxymethyl (meth)acrylamide functional polymers and their use in self-crosslinkable coating compositions
FR2723218A1 (fr) * 1994-07-29 1996-02-02 Essilor Internal Cie Gle Optique Composes photochromiques de structure spiro (indoline-(2,3')-benzoxazine) a groupement cyano en 6', et leur utilisation dans le domaine de l'optique ophtalmique
US5760100B1 (en) 1994-09-06 2000-11-14 Ciba Vision Corp Extended wear ophthalmic lens
IL115803A (en) 1994-11-03 2000-02-17 Ppg Industries Inc Indeno-naphthopyran derivatives useful for photochromic articles
US5645767A (en) * 1994-11-03 1997-07-08 Transitions Optical, Inc. Photochromic indeno-fused naphthopyrans
US5658501A (en) * 1995-06-14 1997-08-19 Transitions Optical, Inc. Substituted naphthopyrans
AUPN443695A0 (en) 1995-07-28 1995-08-17 Sola International Holdings Ltd Photochromic polymer
US5753146A (en) * 1996-03-29 1998-05-19 Transitions Optical, Inc. Photochromic naphthopyran compositions of neutral color
US5770115A (en) 1996-04-19 1998-06-23 Ppg Industries, Inc. Photochromic naphthopyran compositions of improved fatigue resistance
US5723072A (en) 1996-06-17 1998-03-03 Ppg Industries, Inc. Photochromic heterocyclic fused indenonaphthopyrans
SG54538A1 (en) 1996-08-05 1998-11-16 Hoya Corp Soft contact lens with high moisture content and method for producing the same
US5821287A (en) * 1996-08-08 1998-10-13 National Science Council Photochromic pigment
BR9807733A (pt) 1997-02-21 2001-09-11 Ppg Ind Ohio Inc Artigo com revestimento fotocrÈmico
US6025026A (en) 1997-06-30 2000-02-15 Transitions Optical, Inc. Process for producing an adherent polymeric layer on polymeric substrates and articles produced thereby
US5961631A (en) * 1997-07-16 1999-10-05 Arm Limited Data processing apparatus and method for pre-fetching an instruction in to an instruction cache
EP0958288B1 (de) * 1997-09-22 2004-03-03 Rodenstock GmbH Photochrome naphthopyran-farbstoffe, verfahren zu ihrer herstellung, ihre verwendung sowie ein photochromer gegenstand
US6268055B1 (en) 1997-12-08 2001-07-31 Ppg Industries Ohio, Inc. Photochromic epoxy resin coating composition and articles having such a coating
US5869658A (en) * 1997-12-15 1999-02-09 Ppg Industries, Inc. Photochromic indeno-fused naptho 2,1-b!pyrans
EP0987260B1 (de) * 1998-05-29 2004-03-03 Rodenstock GmbH Photochrome Spirofluorenopyrane
ES2184474T3 (es) * 1998-07-10 2003-04-01 Transitions Optical Inc Nuevos naftopiranos fotocromicos condensados con nucleo heterociclico de seis elementos.
AU761180B2 (en) * 1998-09-11 2003-05-29 Transitions Optical, Inc Polymerizable polyalkoxylated naphthopyrans
US5961892A (en) 1998-09-11 1999-10-05 Ppg Industries Ohio, Inc. Polyalkoxylated naphthopyrans
US6555028B2 (en) * 1998-09-11 2003-04-29 Transitions Optical, Inc. Polymeric matrix compatibilized naphthopyrans
US6060001A (en) 1998-12-14 2000-05-09 Ppg Industries Ohio, Inc. Alkoxyacrylamide photochromic coatings compositions and photochromic articles
US6432544B1 (en) 1998-12-18 2002-08-13 Ppg Industries Ohio, Inc. Aminoplast resin photochromic coating composition and photochromic articles
US6506488B1 (en) 1998-12-18 2003-01-14 Ppg Industries Ohio, Inc. Aminoplast resin photochromic coating composition and photochromic articles
US6432522B1 (en) * 1999-02-20 2002-08-13 Saint-Gobain Vitrage Transparent acoustical and mechanical barrier
DE50000137D1 (en) * 1999-07-02 2002-05-16 Rodenstock Optik G Spirofluorenopyrane
AU769249B2 (en) 1999-07-02 2004-01-22 Ppg Industries Ohio, Inc. Poly(meth)acrylic photochromic coating
US6150430A (en) * 1999-07-06 2000-11-21 Transitions Optical, Inc. Process for adhering a photochromic coating to a polymeric substrate
US6348604B1 (en) * 1999-09-17 2002-02-19 Ppg Industries Ohio, Inc. Photochromic naphthopyrans
FR2800738B1 (fr) * 1999-11-04 2002-02-08 Corning Sa Naphtopyranes ayant un substituant perfluoroalkyle en position 5, preparation et compositions et matrices (co)polymeres les renfermant
CA2359046C (en) * 1999-11-10 2006-10-10 Optische Werke G. Rodenstock Heterocyclically anellated indenochromene derivatives
US6353102B1 (en) * 1999-12-17 2002-03-05 Ppg Industries Ohio, Inc. Photochromic naphthopyrans
JP4157245B2 (ja) 2000-02-21 2008-10-01 株式会社トクヤマ クロメン化合物
CN1152108C (zh) * 2000-06-12 2004-06-02 中国科学院感光化学研究所 芳杂环取代的萘并吡喃类光致变色化合物及其制法和用途
US7166357B2 (en) * 2003-03-20 2007-01-23 Transitions Optical, Inc. Photochromic articles that activate behind ultraviolet radiation blocking transparencies and methods for preparation
US20040186241A1 (en) * 2003-03-20 2004-09-23 Gemert Barry Van Photochromic ocular devices

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19741705A1 (de) * 1997-09-22 1999-04-01 Rodenstock Optik G Naphtopyrane
EP1054010A1 (en) * 1999-05-20 2000-11-22 Tokuyama Corporation Chromene compound
WO2001019813A1 (en) * 1999-09-17 2001-03-22 Transitions Optical, Inc. Novel indeno-fused photochromic naphthopyrans
WO2001094336A1 (de) * 2000-06-07 2001-12-13 Optische Werke G. Rodenstock Photochrome pyranderivate

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010507699A (ja) * 2006-10-26 2010-03-11 チバ ホールディング インコーポレーテッド フォトクロミックシステム用光吸収層
JP2010508399A (ja) * 2006-10-30 2010-03-18 トランジションズ オプティカル， インコーポレイテッド 退色速度改善を示すフォトクロミック材料
WO2011078030A1 (ja) * 2009-12-22 2011-06-30 株式会社トクヤマ クロメン化合物
WO2012082381A1 (en) * 2010-12-16 2012-06-21 Transitions Optical, Inc. Indeno- fused ring compounds having photochromic properties
CN103339123A (zh) * 2010-12-16 2013-10-02 光学转变公司 具有光致变色性质的茚并稠环化合物
JP2015044860A (ja) * 2010-12-16 2015-03-12 トランジションズ オプティカル， インコーポレイテッド フォトクロミック特性を有するインデノ縮合環化合物
AU2011341472B2 (en) * 2010-12-16 2015-07-09 Transitions Optical, Inc. Indeno- fused ring compounds having photochromic properties
KR101610450B1 (ko) * 2010-12-16 2016-04-07 트랜지션즈 옵티칼 인코포레이티드 광변색성을 갖는 인데노-융합된 고리 화합물
CN103339123B (zh) * 2010-12-16 2016-11-30 光学转变公司 具有光致变色性质的茚并稠环化合物
WO2012102410A1 (ja) 2011-01-28 2012-08-02 株式会社トクヤマ クロメン化合物
US8709308B2 (en) 2011-01-28 2014-04-29 Tokuyama Corporation Chromene compound

Also Published As

Publication number Publication date
US20070155964A1 (en) 2007-07-05
AU2004311372A1 (en) 2005-09-15
BRPI0408540A (pt) 2006-03-07
MXPA05009631A (es) 2006-08-25
EP1606274A1 (en) 2005-12-21
EP2345648B1 (en) 2012-10-24
ES2688272T3 (es) 2018-10-31
EP2345647A2 (en) 2011-07-20
AU2004311372A8 (en) 2009-03-05
CA2512605A1 (en) 2004-09-20
HK1089161A1 (en) 2006-11-24
JP2006525378A (ja) 2006-11-09
JP4160980B2 (ja) 2008-10-08
BRPI0408540B1 (pt) 2014-09-02
EP1606274B1 (en) 2018-08-08
US20090062533A1 (en) 2009-03-05
KR100752834B1 (ko) 2007-08-29
CN102532088A (zh) 2012-07-04
EP2345648A1 (en) 2011-07-20
CA2512605C (en) 2012-05-29
ZA200508177B (en) 2007-01-31
US7557208B2 (en) 2009-07-07
AU2004311372B8 (en) 2009-03-05
EP1606274B9 (en) 2019-01-16
ES2394446T3 (es) 2013-01-31
US7517982B2 (en) 2009-04-14
AU2004311372B2 (en) 2007-08-02
EP2345647A3 (en) 2011-11-23
CN102532088B (zh) 2016-10-12
US7262295B2 (en) 2007-08-28
CN1761660B (zh) 2012-01-11
KR20060061289A (ko) 2006-06-07
US20040185255A1 (en) 2004-09-23
CN1761660A (zh) 2006-04-19

Similar Documents

Publication Publication Date Title
AU2004311372B2 (en) Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles
JP4969005B2 (ja) 新規なフォトクロミックナフトピラン類
US6296785B1 (en) Indeno-fused photochromic naphthopyrans
EP1097155B1 (en) Photochromic six-membered heterocyclic-fused naphthopyrans
EP1360183B1 (en) Novel photochromic indenonaphthopyran compounds
AU2004303784B2 (en) Pyrano-quinolines, pyrano-quinolinones, combinations thereof, photochromic compositions and articles
AU2002231105A1 (en) Novel photochromic indenonaphthopyran compounds
KR101602588B1 (ko) 6-아미노 치환된 인데노-융합된 나프토피란을 포함하는 광변색성 물질
WO1999016765A1 (en) Fluoranthenopyrans
AU2007202187B2 (en) Indeno-fused photochromic naphthopyrans, naphthols and photochromic articles

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 1-2005-501613

Country of ref document: PH

WWE Wipo information: entry into national phase

Ref document number: 2512605

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2004311372

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2005518823

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: PA/a/2005/009631

Country of ref document: MX

ENP Entry into the national phase

Ref document number: 2004311372

Country of ref document: AU

Date of ref document: 20040316

Kind code of ref document: A

WWP Wipo information: published in national office

Ref document number: 2004311372

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 1020057017368

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 20048075708

Country of ref document: CN

AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

WWE Wipo information: entry into national phase

Ref document number: 2004749405

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2005/08177

Country of ref document: ZA

Ref document number: 200508177

Country of ref document: ZA

DPEN Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed from 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWP Wipo information: published in national office

Ref document number: 2004749405

Country of ref document: EP

ENP Entry into the national phase

Ref document number: PI0408540

Country of ref document: BR

WWG Wipo information: grant in national office

Ref document number: 2004311372

Country of ref document: AU