WO2005089970A1 - 有機系廃棄物の分解処理装置と消臭殺菌剤および消臭殺菌剤の製造方法 - Google Patents
有機系廃棄物の分解処理装置と消臭殺菌剤および消臭殺菌剤の製造方法 Download PDFInfo
- Publication number
- WO2005089970A1 WO2005089970A1 PCT/JP2004/003601 JP2004003601W WO2005089970A1 WO 2005089970 A1 WO2005089970 A1 WO 2005089970A1 JP 2004003601 W JP2004003601 W JP 2004003601W WO 2005089970 A1 WO2005089970 A1 WO 2005089970A1
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- WIPO (PCT)
- Prior art keywords
- intake passage
- heat treatment
- deodorant
- organic waste
- air
- Prior art date
Links
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L11/00—Methods specially adapted for refuse
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
Definitions
- the present invention is applied to garbage, magazines, cloth, paper waste, textile waste, rubber waste, waste
- the present invention relates to a device for decomposing organic waste having a novel structure that produces a deodorant germicide.
- waste including general waste and industrial waste is incinerated as intermediate treatment from collection to final disposal. Is commonly done. In some households, garbage may be incinerated.
- incineration of waste is carried out by burning the waste in an incinerator in any case, but the generation of harmful substances such as hydrocarbons, nitrogen oxides, and dioxins accompanying the combustion is also considered.
- the generation of offensive odors due to incineration has become a major environmental problem. Therefore, as one measure to cope with such a problem, for example, incomplete combustion is reduced by burning waste at a high temperature, and dioxins associated with the generation of chlorine gas and the like contained in the waste are reduced. It has been proposed to suppress the generation of.
- Patent No. 32111997 Publication No. No. 3,283,396 and the like disclose techniques for producing ceramics by melting and sintering waste.
- high-temperature treatment, multi-stage heat treatment, and the like are used as a treatment process for obtaining ceramics from waste.
- special consideration is given to the removal of harmful substances emitted during heat treatment of waste. Because of this, the negative impact on the environment could be a problem.
- Patent No. 3,037,688 discloses a method in which flammable organic substances including organic wastes are mixed with clay minerals such as zeolite. It is disclosed that a porous fired body in which a ceramic layer is coated on the surface of a carbide is formed by performing carbonization treatment, and dioxin is absorbed and removed using the porous fired body.
- a porous fired body in which a ceramic layer is coated on the surface of a carbide is formed by performing carbonization treatment, and dioxin is absorbed and removed using the porous fired body.
- it is necessary to prepare clay mineral ⁇ zeolite or the like specially and mix it with the waste and there is a problem that it is difficult to improve the efficiency and cost of the treatment process.
- Japanese Patent Application Laid-Open No. 2001-304450 discloses that an air inlet is provided in a wall of a heat-resistant container which is substantially isolated from an external space. And magnet means are provided on a passage for guiding combustion air from the inlet to the processing chamber inside the heat-resistant container, and the combustion air is magnetically treated, thereby suppressing the generation of dioxins and the like.
- An incinerator is shown in which waste is subjected to a carbonization treatment.
- An object of the present invention is to provide a novel deodorant bactericide and a method for producing the same, which can be exerted, are harmless to humans and animals, and can exhibit effective bactericidal properties against harmful bacteria and the like.
- the present invention is capable of safely and efficiently decomposing the waste by heat-treating the waste while suppressing the generation of dioxins and bad odors. It is another object of the present invention to provide an organic waste decomposing apparatus having a novel structure that can reuse and reuse the waste and can advantageously achieve pollution-free and recycling.
- a first aspect of the present invention relates to a method for producing a deodorant bactericide, wherein an organic waste is accommodated in a heat treatment chamber to which an intake passage and an exhaust passage are connected, respectively.
- a pair of permanent magnets are disposed on the intake passage in a substantially opposed state, and turbulent flow is actively generated in a region of the intake passage where the pair of permanent magnets are disposed.
- the outside air subjected to the magnetic treatment through the intake passage is applied to the heat treatment chamber as the heat treatment air, so that a small amount of the heat treatment air is discarded in the heat treatment chamber which is a substantially closed space.
- the substance can be efficiently and gently pyrolyzed (including combustion, oxidation, carbonization, incineration, etc .; the same applies hereinafter) to convert it into a deodorant sterilizer.
- the deodorant disinfectant obtained in this way is considered to be a powdery or porous block-like inorganic substance (including ceramics, etc.) mainly composed of CaO, SiO2, A1203, etc.
- the heat treatment air flowing through the intake passage is positively disturbed by the flow control means to generate a turbulent state, and the magnetic field formed by the permanent magnet is generated.
- the organic debris can be easily decomposed and treated in combination with the adsorption effect of dioxins and odor molecules as a source of offensive odor in such deodorant germicides. Excellent environmental performance can be realized.
- incineration doors with a structure in which permanent magnets are disposed in the intake passage to the combustion chamber have been proposed. It was nothing more than an incinerator, and it was only an incinerator of organic waste that was turned into carbon. In rare cases, the incineration of carbides further progresses, and ceramics-like substances are generated in rare cases when conditions such as the type and amount of organic waste to be treated, the amount of intake air, and the degree of magnetization treatment are well matched. In some cases, however, the yield was poor and stable treatment could not be achieved, and it was merely an incinerator that only remained carbonized.
- Incinerators that use a special wrench to advance carbonization to incineration while preventing the generation of dioxins have also been proposed. It has been pointed out that in addition to excessive running costs, high-temperature treatments can also produce unexpected harmful heavy metals. Under these circumstances, according to the heat treatment method of the first embodiment of the present invention or each of the embodiments described later, by performing extremely efficient magnetic treatment on the combustion air, it is possible to eliminate In both cases, the heat treatment from the carbonization to the incineration can proceed gently, and the obtained ceramic can be regarded as a deodorant fungicide with extremely useful properties that have never been seen before. It was newly found by the inventor.
- the deodorant germicide for the production of the deodorant germicide, it is possible to use a heat treatment apparatus in which a heat treatment furnace having a conventional structure and an intake passage provided with a permanent magnet and flow control means are formed.
- a heat treatment apparatus in which a heat treatment furnace having a conventional structure and an intake passage provided with a permanent magnet and flow control means are formed.
- an organic waste is accommodated in a heat treatment chamber to which an intake passage and an exhaust passage are connected, and the organic waste is thermally decomposed.
- At the time of the treatment at least a pair of permanent magnets are disposed on the intake passage so as to be displaceable substantially in opposition to each other, and the air supplied to the heat treatment chamber is subjected to a magnetic treatment, whereby the organic treatment is performed.
- an inorganic deodorant and germicide is obtained from the organic waste by generating an inorganic deodorant and germicide from the organic waste.
- the heat treatment air flowing through the intake passage or a mechanical action on the passage from an external device or the magnetic force or the electromagnetic force between the heat treatment air flowing through the intake passage and the permanent magnet.
- the permanent magnet is slightly displaced with respect to the intake passage due to various effects, the magnetic field acting on the intake passage is slightly changed, and as a result, the magnetic treatment is effective for the heat treatment air.
- Small inflow The mild oxidation reaction or carbonization is suitably maintained even by the heat treatment air, so that low-temperature combustion heat treatment is realized, waste combustion efficiency is improved, and deodorant disinfectants are efficiently used.
- the generation of harmful substances such as dioxins and odors can be effectively suppressed.
- the magnetically treated air guided to the combustion chamber has a significant effect. It is presumed that this is based on the enhancement of air activity by the magnetic treatment according to the present invention. This is because, for example, according to the present invention, when a magnetic processing apparatus having a structure according to a twentieth aspect described later is used and is arranged on a drying air introduction path in a wood drying apparatus, It is also understood that the fuel cost required for drying treatment to the specified moisture content could be reduced by more than 1/3.
- the method for producing a deodorant bactericide according to the second aspect further comprising: a flow adjusting means provided in a region where the permanent magnet is provided in the intake passage. In the arrangement region, turbulence is actively generated in the heat treatment air.
- the functions and effects of the first and second embodiments are synergistically exhibited, the efficiency of the magnetic treatment is further improved, and the intended deodorant germicide is further improved. It can be realized effectively.
- At least one of the flow control means has a widened portion in the intake passage. And / or a constriction is provided so as to actively generate turbulence with respect to the air supplied to the heat treatment chamber.
- a fifth aspect of the present invention is directed to any one of the first to fourth aspects.
- at least one of the flow control means is provided with a concave portion and / or a convex portion on an inner surface of the intake passage to generate a turbulent flow with respect to air supplied to the heat treatment chamber. Its characteristic is that it was actively produced.
- the flow control means is realized with a simple structure, and the turbulent state in the heat treatment air is further reduced. It is possible to generate it efficiently. In addition, there is a point J that the turbulence state and the fluid resistance exerted on the air for heat treatment by the flow control means can be easily adjusted.
- an opening amount adjusting means is provided in at least a part of the intake passage. The organic waste is thermally decomposed by appropriately adjusting and adjusting the ventilation opening area in the intake passage.
- the opening amount adjusting means for example, a slide-type opening / closing window is adopted, or two disk-shaped partition walls having small holes are slid with each other. If necessary, those having a window can be advantageously employed.
- the permanent magnets are substantially opposed to each other across the intake passage. At least one pair is provided, and the opposing surfaces of the permanent magnets facing each other in such a pair are mutually different in polarity.
- a larger magnetic flux density can be developed between the opposed permanent magnets, and a larger magnetic effect is exerted on the air for heat treatment which is caused to flow through the intake passage, so that the generation efficiency of the deodorant germicide is improved. Can be improved.
- the outer width dimension which is slightly smaller than the inner dimension of the hole is formed in the hole formed oppositely.
- the intake passage has a flat shape and the pair of permanent magnets Are arranged opposite to each other in the flat direction of the intake passage.
- the intake passage is formed in a flat shape, so that the permanent magnets opposed to each other are arranged as close as possible to suppress the leakage magnetic flux, and the magnetic force acts more efficiently on the air for heat treatment. It is possible to make it.
- the flatness of the intake passage allows the magnetic poles of the magnet to face the intake passage to have a larger area with respect to the sectional area of the intake passage. However, a greater magnetic force can be exerted per unit volume of the air for heat treatment.
- the flat direction refers to the direction in which the distance between the facing surfaces in the intake passage is the smallest.
- the inner dimension in the flat direction of the intake passage A and the inner dimension in the direction perpendicular thereto: B
- the maximum value of the ratio (AZ B) is set to be 2 or more, and more preferably 3 or more.
- a ninth aspect of the present invention is directed to the production of the deodorant bactericide according to the eighth aspect.
- a width direction dimension of the intake passage in a width direction of the intake passage which is orthogonal to a facing direction of the pair of permanent magnets, and is also orthogonal to an air flow direction in the intake passage.
- the magnetic pole surface of each of the permanent magnets faces the intake passage over at least a half of the range. In such an embodiment, it is possible to perform a more uniform and efficient magnetic treatment on the air guided to the heat treatment chamber through the intake passage, and the intended heat treatment can be more stably realized in the heat treatment chamber. It is possible. More preferably, the magnetic pole surface of each permanent magnet faces the intake passage in a range of 2 Z 3 or more of the width dimension of the intake passage.
- the atmosphere temperature in the heat treatment chamber is set at 300 ° C. or lower. That is the feature. In this embodiment, in particular, the generation of dioxins can be effectively suppressed.
- the reason why the atmosphere temperature in the heat treatment chamber can be kept extremely low as compared with that of a general incinerator is that combustion that emits a flame is not performed in the heat treatment chamber. This is because the slow oxidation reaction continues locally while inhibiting the combustion of flaming by restricting the intake air. This is obvious when the inside of the heat treatment furnace is directly seen. At the boundary between the carbonized layer and the incinerated layer, light is emitted from a very local part, such as a marauder. This is evident from the fact that it changes over time. In addition, when the atmosphere in the heat treatment furnace was measured, it was confirmed that a considerable amount of negative ions were filled.
- the method for producing a deodorant germicide according to any one of the first to ninth aspects, wherein (a) a through window having a shape corresponding to the intake passage is formed. (B) the internal passage is formed by overlapping and fixing the front and back surfaces of the passage forming plate to form the internal passage while covering the through-window, and being superposed on the passage forming plate.
- the intake passage is formed by a through window having a structure in which a passage forming plate is drawn out in the thickness direction, the shape of the intake passage is projected, for example, in a meandering shape ⁇ expanding / contracting shape, or into the passage inner surface.
- the shape having the concave portion and the protruding portion it is possible to design and change the shape extremely easily and with great design flexibility.
- a deodorant disinfectant produced from organic waste as a raw material according to the method for producing a deodorant disinfectant according to any one of the first to eleventh aspects Is the feature.
- the deodorant bactericide according to the present embodiment since organic waste is adopted as a raw material, cost reduction can be advantageously achieved, and excellent deodorization can be achieved by a simple method. Odor and sterilization performance can be realized. The efficacy of the obtained deodorant bactericide is clear from the data of Examples described later.
- a thirteenth aspect of the present invention is characterized by a paint containing the deodorant germicide according to the twelfth aspect as one of the raw materials.
- a fourteenth aspect of the present invention is characterized by a building material containing the deodorant disinfectant according to the twelfth aspect as one of the raw materials.
- the germicidal action of the deodorant germicide allows the human body such as Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Salmonella, etc. Harmful bacteria are significantly reduced
- harmful gases that cause malodor such as ammonia and formaldehyde can be adsorbed. Therefore, for example, by adopting it as a paint for buildings or furniture, or as a wall material of a room, it is possible to effectively improve the living environment and sanitation.
- the deodorant disinfectant according to the twelfth aspect is used as a raw material for decorative materials such as sanitary ware and tiles used for sanitary facilities such as water supply, hot water supply, and treatment of sewage and excrement in buildings. In the present embodiment, they can be employed in a wide range.
- a fifteenth aspect of the present invention is characterized by an agricultural spraying agent using the deodorant bactericide according to the twelfth aspect as a raw material.
- spraying on agricultural crops can prevent disease and promote the growth of agricultural crops. It has been clarified by experiments performed by the present inventors, and moreover, since the raw material is a processed organic waste, pesticide-free cultivation can be realized effectively at low cost. Prevention of plant diseases is related to bactericidal activity, and promotion of the growth of crops is thought to be completed by the supply of inorganic substances.
- the agricultural sprays in this embodiment include those used for raising livestock such as cattle, pigs, and chickens. For example, by spraying agricultural sprays applied to barns, it is possible to reduce the smell of manure and the like. It has been shown to be effective in controlling and preventing livestock diseases.
- the first aspect of the present invention relating to an organic waste decomposition treatment apparatus includes: (f) a heat-resistant container forming a heat treatment chamber; and (g) an external heat-resistant container provided through a wall of the heat-resistant container.
- An organic waste decomposition treatment device having an exhaust passage for discharging is featured.
- the outside air subjected to the magnetic treatment through the intake passage is supplied to the heat treatment chamber as the air for the heat treatment, so that the substantially closed space is formed.
- waste can be efficiently and gently heat treated with a small amount of air for heat treatment.
- the mild oxidation or carbonization proceeds over time not only on the surface of the waste, but also mainly in a wide area, without raising the flame so that the waste can be clearly recognized.
- the reaction can proceed to a state similar to that of almost complete combustion, and heat treatment can be performed while suppressing the generation of dioxins, while avoiding a remarkable high temperature in the furnace wall and the like in the furnace.
- the heat treatment air flowing through the intake passage is positively disturbed by the flow control means, and a turbulent flow state is developed.
- the action of the magnetic field formed by the permanent magnet can be made to act substantially uniformly and efficiently on molecules constituting the heat treatment air or on molecules contained in the heat treatment air as a whole. Since the moderate oxidation reaction or carbonization is suitably maintained even with a large inflow of air for heat treatment, the organic waste is effectively thermally decomposed and finally turned into a ceramic (ashed powder). Even the deodorant germicides in the form of odors and porous blocks can be treated efficiently.
- the arrangement position and the number of the intake passages are not particularly limited, and one or a plurality of the intake passages may be provided at an arbitrary position such as a wall or a lid of the heat-resistant container. It may be provided.
- natural intake is sufficient, but it is also possible to forcibly intake air with a fan or the like so that a clear flame does not appear in the combustion state.
- a ventilation pipe made of a non-magnetic material made of an acrylic resin, a chloride resin, a polypropylene resin, an aluminum alloy, or the like may be used as a member forming the intake passage.
- the flow control means of the intake passage in this embodiment a configuration in which the cross-sectional shape of the intake passage is changed in a region where the magnetic force of the permanent magnet is exerted is suitably adopted.
- the desired turbulence state can be efficiently generated without the need for energy such as an actuator.
- a flow control means for example, meanders, curves, or bends an intake passage near a region where a permanent magnet is provided, or installs an obstacle such as a block member or a sheet member in the passage.
- the second aspect of the present invention relating to an organic waste decomposition treatment apparatus includes: (k) a heat-resistant container forming a heat treatment chamber; and (1) an external device provided through a wall portion of the heat-resistant container. (M) at least one pair of: an intake passage that is introduced into the heat treatment chamber using the atmosphere as heat treatment air; and (m) at least a pair of magnetic poles formed on a surface facing the intake passage that is disposed so as to substantially oppose the intake passage. (11) magnet holding means for holding the permanent magnets in a displaceable manner, and (o) an exhaust passage provided on a wall of the heat treatment chamber for discharging exhaust gas generated by heat treatment.
- An organic waste decomposition treatment device having:
- the heat treatment air that is caused to flow through the intake passage or the mechanical action from the external device to the passage, the flow through the intake passage, Due to the magnetic force or electromagnetic action between the heat treatment air and the permanent magnet, The magnetic field acting on the intake passage is slightly changed due to the slight displacement of the heat treatment, and as a result, the magnetic treatment is effectively applied to the air for heat treatment, and the heat treatment with a small inflow amount is performed. Since the mild oxidation reaction or carbonization is suitably maintained even with the air for use, the organic waste is effectively thermally decomposed and finally turned into a ceramic-like deodorant and disinfectant.
- the support surface of the permanent magnet should be as smooth as possible in order to produce the micro-displacement of the permanent magnet more advantageously.
- the support surface of the permanent magnet should be lubricated. An agent or the like may be applied.
- a third aspect of the present invention relating to an organic waste decomposition apparatus is the organic waste decomposition apparatus according to the second aspect, wherein the permanent magnet is disposed in the intake passage.
- a flow adjusting means for positively generating a turbulent flow with respect to the heat treatment air flowing through the intake passage is provided.
- the effects of the first and second embodiments are synergistically exhibited, and the oxidation reaction, carbonization, incineration, etc. of the waste using the air for heat treatment are performed. It can be realized more stably and advantageously, and the efficiency of magnetic processing can be further improved.
- a fourth aspect of the present invention relating to the organic waste decomposition apparatus is the organic waste decomposition apparatus according to any one of the first to third aspects, wherein a plurality of resin plates are provided. Are overlapped with each other and fixed to each other to form a flat closed space extending along the overlapping surface at the overlapping portion of the resin plates, and a pair of extending from the closed space and opening to the outer peripheral surface. A pair of permanent magnets are accommodated and arranged in a buried state with respect to the resin plates on both sides which sandwich the closed space in the resin plate overlapping direction.
- the magnetic processing device is characterized in that the pair of connection holes are connected in series to the intake passage, and the magnetic processing device is disposed on the intake passage.
- a flat magnetic processing space capable of efficiently performing the magnetic processing by the permanent magnet on the intake air guided to the heat treatment chamber is advantageously provided on the intake passage with a simple structure. It can be formed.
- a fifth aspect of the present invention relating to an organic waste decomposition treatment apparatus is the organic waste decomposition treatment apparatus according to the fourth aspect, wherein in the resin plate, the resin plates are superposed.
- a permanent magnet having an outer peripheral shape slightly smaller than the inner peripheral shape of the accommodation hole is inserted into the accommodation hole and assembled in a non-adhesive manner. .
- the permanent magnet can be more easily assembled with a simple structure in a state where the permanent magnet can be minutely displaced.
- a sixth aspect of the present invention relating to an organic waste decomposition treatment apparatus is the organic waste decomposition treatment apparatus according to the fourth or fifth aspect, wherein the permanent magnet is disposed in the closed space side.
- Positioning means for restricting the protrusion of the permanent magnet is provided, and the permanent magnet is accommodated and arranged in a non-adhesive manner with respect to the resin plate, and the two permanent magnets arranged opposite to each other with the closed space interposed therebetween are arranged. It is characterized in that both permanent magnets are held at positions defined by the positioning means based on mutual magnetic attraction on the magnetic pole surface.
- the permanent magnet can be disposed and held at a target position by utilizing its own magnetic force, and the assembly structure of the permanent magnet can be further simplified.
- a seventh aspect of the present invention relating to an organic waste decomposition treatment apparatus
- the organic waste decomposition apparatus according to any one of the first to sixth aspects, at least a part of the exhaust passage is provided with the deodorant according to the twelfth aspect of the present invention as described above.
- a disinfectant is installed.
- the deodorizing bactericide effectively removes dioxins and bad odors contained in the exhaust gas by the molecule-adsorbing action of the gas and the like in the deodorant germicide, a more excellent environment Can be realized.
- the deodorant disinfectant is generated from the organic waste decomposition treatment apparatus having the structure according to the present embodiment, recycling and cost reduction can be realized more advantageously.
- an eighth aspect of the present invention relating to an organic waste decomposition treatment apparatus is the organic waste decomposition treatment apparatus according to any one of the first to seventh aspects, wherein the exhaust passage is reduced.
- a water storage tank is provided in a part thereof, and the treated water stored in the water storage layer is brought into contact with the exhaust gas guided by the exhaust passage.
- harmful substances such as dioxins, odors, and dust contained in the exhaust gas can be captured, and the harmful substances can be trapped in the air. Release can be advantageously suppressed.
- the treated water may be tap water, sewage, or water mixed with chemicals, impurities, and the like.
- a ninth aspect of the present invention relating to an organic waste decomposition treatment apparatus
- water mixed with a metal is used as the treatment water.
- a tenth aspect of the present invention relating to an organic waste decomposition treatment apparatus is the organic waste decomposition treatment apparatus according to the eighth or ninth aspect, wherein: An air introduction pipe is connected to a region leading to the water storage tank, and the exhaust gas through the exhaust passage is forced by forcibly introducing air from an external space into the exhaust passage through the air introduction pipe. And at least a pair of permanent magnets are disposed so as to be substantially opposed to each other with the air introduction pipe interposed therebetween, so that the external air introduced through the air introduction pipe can It is characterized in that magnetic treatment is applied to it.
- an eleventh aspect of the present invention relating to an organic waste decomposition treatment apparatus is the organic waste decomposition treatment apparatus according to any one of the first to tenth aspects, wherein The feature is that manganese is provided.
- compressed air magnetically treated through the intake passage of the magnetic treatment device is guided to the exhaust passage and combined with the exhaust gas. Exhaust by contact The release of dioxins and odors contained in the gas to the outside can be more effectively suppressed.
- the rationale for the suppression effect of dioxins and the like exerted by the above-mentioned magnetically treated compressed air has not been clarified, but in such an organic waste decomposition treatment apparatus, In compressed air that has been passed through the intake passage of the magnetic processing device and has been subjected to the action of a magnetic field by the permanent magnets, electrons collide with oxygen molecules and water molecules, etc., and are attached to the air.
- the organic waste decomposition treatment apparatus in any one of the first to eleventh aspects, wherein the exhaust passage And a water collecting means for capturing and collecting water contained in the exhaust gas.
- the moisture contained in the exhaust gas is safely and efficiently extracted from the exhaust gas.
- wood vinegar can be efficiently collected, and better recycling can be achieved.
- a collection box is provided below a position in the exhaust passage close to the heat treatment chamber, and water droplets falling downward due to cooling and liquefaction of the exhaust gas above the exhaust passage are provided.
- a collection box is provided below a position in the exhaust passage close to the heat treatment chamber, and water droplets falling downward due to cooling and liquefaction of the exhaust gas above the exhaust passage are provided.
- FIG. 1 is an explanatory cross-sectional view showing a heat treatment apparatus as a first embodiment of the present invention, and is a cross-sectional view taken along the line II in FIG.
- FIG. 2 is an explanatory front view of the heat treatment apparatus shown in FIG.
- FIG. 3 is a vertical sectional view of the heat treatment apparatus shown in FIG.
- FIG. 4 is a sectional view taken along the line IV-IV in FIG.
- FIG. 5 is a sectional view taken along line VV in FIG.
- FIG. 6 is an explanatory longitudinal sectional view showing an essential part of the present invention in an enlarged manner.
- FIG. 7 is a sectional view taken along the line VII-VII in FIG.
- FIG. 8 is an explanatory longitudinal sectional view showing another main part of the present invention in an enlarged manner.
- FIG. 9 is a sectional view taken along the line IX-IX in FIG.
- FIG. 10 is a sectional view taken along line XX in FIG.
- FIG. 11 is a cross-sectional explanatory view showing a main part of a heat treatment apparatus as another specific example of the present invention, and is a view corresponding to FIG.
- FIG. 12 is a cross-sectional explanatory view showing a main part of a heat treatment apparatus as still another specific example of the present invention, and is a view corresponding to FIG.
- FIG. 13 is an explanatory cross-sectional view showing a main part of a heat treatment apparatus as still another specific example of the present invention, and is a view corresponding to FIG. FIG.
- FIG. 14 is an explanatory model diagram schematically showing one embodiment in which the sterilization performance of the deodorant sterilizer produced using the heat treatment apparatus as shown in FIG. 1 was measured.
- FIG. 15 is an explanatory model diagram schematically showing one embodiment of measuring the deodorizing performance of the deodorant bactericide produced using the heat treatment apparatus as shown in FIG.
- FIG. 16 is a graph showing the results of measuring the deodorizing performance of the deodorant bactericide produced using the heat treatment apparatus as shown in FIG.
- FIG. 17 is a graph showing the results of measuring the deodorizing performance of the deodorant bactericide produced using the heat treatment apparatus as shown in FIG. BEST MODE FOR CARRYING OUT THE INVENTION
- FIGS. 1 to 5 show a heat treatment apparatus 10 as one embodiment of the present invention.
- the heat treatment apparatus 10 includes a treatment furnace 12 as a heat-resistant container and a flue water tank 14 as a water storage tank, and heat-treats a heat-treated material containing organic waste in the treatment furnace 12.
- the exhaust gas generated by the heat treatment is discharged to the outside through the flue water tank 14.
- the processing furnace 12 has a hollow substantially box-like shape, and has a front wall 16, a rear wall 18, and a pair of side walls 20, each having a substantially rectangular flat plate shape.
- top wall 22 and bottom wall 24 between front wall 16 and rear wall 18 are side walls 20 and 20, top wall 22 and bottom wall 24 They are arranged across the vertical direction (vertical direction in Fig. 1).
- a first vertical wall 26 and a second vertical wall 28 Vertical wall
- the first vertical wall 26 is provided inside the processing furnace 12 near the front wall 16, and the second vertical wall 28 and the third vertical wall 3 are provided. 0 is provided inside the processing furnace 12 close to the rear wall 18 while being close to each other, and the distance between the opposing surfaces of the first vertical wall 26 and the second vertical wall 28 is large. Have been.
- the heights of the first vertical wall 26 and the third vertical wall 30 are set to be substantially the same as the front wall 16 and the rear wall 18, while the second vertical wall 28 The height dimension is set smaller than the first and third vertical walls 26, 30. Further, between the opposing surfaces of the first vertical wall 26 and the second vertical wall 28,
- a pair of horizontal walls 32,2 having a substantially rectangular flat plate shape
- each lateral wall 32 are respectively opposed to one of the side walls 20 at a predetermined separation distance, and the outer peripheral edge of each lateral wall 32 is formed by the first vertical wall 26 and the second vertical wall 2. 8. It is fixed inside the treatment furnace 12 by being fixed to the bottom wall 24 and the like.
- these first, second and third vertical walls 26, 28, 30 are larger than the front wall 16, rear wall 18, side wall 20, etc., which constitute the outer peripheral portion of the processing furnace 12. It is arranged as a small wall in the processing furnace 12, whereby the processing furnace has a hollow substantially double-walled structure. Particularly, in the present embodiment, between the opposing surfaces of the first vertical wall 26 and the second vertical wall 28, between the opposing surfaces of the pair of horizontal walls 32, 32, and between the upper wall 22 and the bottom wall 24. A region surrounded by the opposing surfaces is formed as a heat treatment chamber 34 for heat-treating waste, which will be described later.
- the lower end of the first, second and third vertical walls 26, 28, 30 and the lower end of the pair of lateral walls 32, 32 have communication holes 35 having a rectangular shape in the longitudinal direction. Are formed to penetrate in the thickness direction.
- the direction above the second vertical wall 28, in other words, between the opposing surfaces of the second vertical wall 28 and the upper wall 22 is a direction inclining to the front wall 16 and the side wall 20 respectively.
- a pair of substantially rectangular flat plate-shaped reinforcing plates 36, 36 extending in the vertical direction are fixed by welding or the like, and both ends of these reinforcing plates 36, 36 are connected to the first vertical wall 26 and the third vertical wall.
- the wall 30 By being fixed to the wall 30 by welding or the like, the first, second and third vertical walls 26, 28, 30 and eventually the entire wall of the processing furnace 12 are reinforced.
- an input port 38 as an opening window is provided in the upper wall 22 located substantially above the heat treatment chamber 34, and the input port 38 has a substantially rectangular flat plate shape.
- a lid 40 is provided. The lid 40 is placed on the upper wall 22 at the opening edge of the input port 38, while Since the peripheral portion is connected to the upper wall 22 by the hinge 42, it is attached to the inlet 38 of the processing furnace 12 so as to be openable and closable.
- a lock arm 44 is attached to the lid 40.
- the lockarm 44 has an elongated plate shape, and one end of the lockarm 44 is attached to the lid 40 by a bolt 46 so as to be rotatable around one axis. Then, the other end of the lock arm 44 is gripped and the mouth arm 44 is rotated to be locked by the hook portion 48 provided on the upper wall 22 so that the lid 40 is closed. Is to be locked.
- a vent hole 50 as an exhaust gas outlet is formed.
- the ventilation holes 50 are formed, for example, by punching the upper wall 22 in the thickness direction, and the specific shape and size are determined by the required strength of the upper wall 22, It is set appropriately in consideration of the flow rate of the gas to be passed through the ventilation hole 50 and the like.
- an outlet 52 as an opening window having a substantially rectangular hole shape is provided below (below in FIG. 3) the front wall 16 and the rear wall 18.
- the outlet 52 is provided with a lid 54 having a substantially rectangular flat plate shape.
- the lid 54 is attached to the front wall 16 and the rear wall 18 via connection pins 56 so that one side edge can be opened and closed with respect to the outlet 52.
- a lid arm similar to the lid body 40 provided on the upper wall 22 is attached to the lid body 54 near the opposite side to the connection portion with the front wall 16 and the rear wall 18.
- the lid 54 is locked in a closed state by being locked to a catching portion 48 similar to the upper wall 22 provided on the front wall 16 and the rear wall 18. Has become.
- a flue water tank 14 is provided above the treatment furnace 12.
- the flue water tank 14 is fixedly disposed at a portion of the upper wall 22 other than the space for the inlet 38 and the lid 40.
- the More specifically, the flue water tank 14 has a hollow substantially long box shape as a whole, and a substantially middle portion of the hollow inside in a direction perpendicular to the axis (vertical direction in FIG. 4).
- a partition plate 58 is provided in the portion so as to extend in the longitudinal direction. The inside of the tank 14 is partitioned by the partition plate 58 so as to be divided into two parts, thereby forming a substantially meandering first portion.
- a flue 60 is formed inside.
- a first connection hole 62 having a substantially circular shape and opening to the lower wall of the tank 14 is provided at one end of the first flue 60.
- the hole 62 is positioned above the air hole 50 provided in the upper wall 22 of the processing furnace 1 2, and the first connection hole 62 and the air hole 50 are connected to the first connection pipe 6.
- the inside of the treatment furnace 12 and the inside of the flue water tank 14 are communicated with each other because the inside of the treatment furnace 12 is fixed.
- the first connection pipe 64 has a substantially cylindrical shape, and the lower end opening thereof is located above the inside of the processing furnace 12, while the upper end opening of the first connection pipe 64 is Is located approximately in the middle of the height of the first flue 60.
- a second connection pipe 66 having a substantially cylindrical shape is provided at the other end of the first flue 60 through the upper wall of the tank 14.
- a predetermined amount of treated water 68 is accommodated in a first flue 60 formed in the flue water tank 14.
- the treated water 68 flows over substantially the entire lower half of the first flue 60 in a state where the water level is set at a position lower than the upper end opening of the first connection pipe 64. It is housed throughout.
- a commercially available titanium oxide liquid is used as the treated water 68, but the treated water is not limited to this.
- tap water or activated carbon or caustic soda It is also possible to use an aqueous solution containing (sodium hydroxide) and others.
- the flue water tank 14 may be equipped with an injection pipe for treated water 68 and an overflow A pipe for low is provided at an appropriate position on the peripheral wall, and the treated water 68 is injected. The water is drained and replaced, and the water level of the treated water 68 is appropriately adjusted. It is like that.
- the processing furnace 12 is provided with a plurality of intake holes 70.
- the intake hole 70 has a substantially small hole shape, and one is provided at an intermediate portion in the height direction of the front wall 16, and one is provided at a lid 54 attached to the front wall 16.
- one is provided below each side wall 20.
- a magnetic processing device 76 is attached to these intake holes 70 via a substantially cylindrical intake cylinder 74 having an elbow 72 at one end.
- the magnetic processing device 76 is provided with a housing 78 as a housing having a substantially rectangular box shape, as also shown in an enlarged manner in FIGS.
- An intake passage 80 is formed inside the body 78.
- the housing 78 is made of a non-magnetic material such as acrylic resin or polypropylene resin, has a substantially rectangular box shape, and has a second plate 82 as a passage forming plate and a pair of magnet holding plates as a pair. It comprises a second plate 84, 84 and a pair of third plates 86, 86 as an outer lid plate.
- the first plate 82 has a substantially rectangular flat plate shape, and has a large through hole 88 as a through window at the center.
- the through-holes 88 are formed in a punched shape having a ⁇ shape corresponding to a planar shape of a target intake passage, and have a long hole shape elongated in the longitudinal direction of the first plate 82.
- a widened portion 90 At the center in the longitudinal direction of the through hole 88, there is provided a widened portion 90 whose width is made substantially constant over the entire length, and at both ends in the longitudinal direction, the widened portion 90 Constrictions 92, 92 whose widths decrease in order toward the edge of one plate 82 are provided.
- 98 are provided.
- the projections 96 and 98 are formed integrally with the first plate 82, but the present invention is not limited to this. And may be fixed to the plate 82 with an adhesive or the like.
- the second plates 84, 84 have a thick, substantially rectangular flat plate shape, and are provided with a circular recess 100, 100 force s as a magnet receiving hole in the center portion. .
- the circular recess 100 is open on one wide surface 102, which is the outer surface, of the second plate 84, and is formed on the other wide surface 104, which is the inner surface.
- the second plate 84 has a depth that does not reach, and thus has a concave shape that opens on one wide surface 102 of the second plate 84.
- the third plates 86, 86 have a thin, substantially rectangular flat plate shape, and the wide surface thereof has substantially the same size as the wide surfaces 102, 104 of the second plate 84. Is set to
- both wide surfaces of the first plate 82 in other words, both open end surfaces of the through hole 88 are formed on the bottom side of the circular recess 100 of each second plate 84.
- the through-holes 88 are covered with the second plates 84, 84 of the pair substantially airtightly by being superposed on the wide surface 104 located at The passage 80 is formed, and the wide surface 102 located on the opening side of the circular recess 100 of each second plate 84 is formed on the wide surface of the third plate 86, respectively.
- Each circular recess 100 is substantially airtightly covered with a third plate 86 by being superimposed and fixed with an adhesive, a bolt or the like, so that the intake passage 80 and the circular recess are formed.
- a substantially rectangular box-shaped housing 78 is provided.
- a plurality of plates made of a non-magnetic material are used for the first plate 82 and the pair of second plates 84, 84, The third plate 86, 86 is formed, and the plates 82, 84, 86 are laminated to form an intake passage 80 inside the housing 78.
- the circular recesses 100, 100 of the pair of second plates 84, 84 are arranged to face each other across the intake passage 80 in a direction substantially orthogonal to the direction of fluid flow.
- a suction port 106 having a female thread and a connection port 108 are formed, respectively, and these suction ports 106 and The connection ports 108 are connected to both ends of the intake passage 80.
- the intake passage 80 is communicated with the atmosphere through the intake port 106 or the connection port 108.
- a permanent magnet 110 is housed in the circular recess 100 of the second plate 84.
- the permanent magnet 110 is made of a well-known magnetic material such as Ferrite-Alnico alloy (trade name) and has a substantially disk shape, and has different magnetic poles at both ends in the axial direction. Have.
- a substantially bottomed cylindrical protective cover 112 made of non-magnetic material is fitted to the permanent magnet 110, and one magnetic pole (for example, N pole) is attached to the bottom of the protective cover 112. And the other magnetic pole (for example, the south pole) is positioned at the opening of the protective force bar 112 and is exposed to the outside.
- the outer diameter of the protective cover 112 is slightly smaller than the inner diameter of the circular recess 100 in the second plate 84, whereby the protective cover is protected.
- a permanent magnet 110 with a cover 112 attached thereto is displaceably housed in a circular recess 100.
- the step comprises a second plate 84 with a circular recess 100.
- the magnetic pole surface of the permanent magnet 110 exposed from the protective cover 112 under the housing 78 of the pair of permanent magnets 110, 110 is arranged.
- the pair of permanent magnets 110, 110 are disposed facing the intake passage 80 on different magnetic pole surfaces with the intake passage 80 interposed therebetween.
- the two permanent magnets 110 and 110 are supported by the bottom of the second plate 84 (circular recess 100) in a state in which the two permanent magnets 110 and 110 are almost in close contact with the intake passage 80 due to the action of being attracted to each other. ing.
- a chuck 114 is attached to the suction port 106 and the connection port 108.
- the chuck 1 14 has a substantially stepped cylindrical shape, and a screw portion is formed on the outer peripheral surface of the small diameter portion 1 16, and the small diameter portion 1 16 is connected to the suction port 106 and the connection.
- the outer diameter of the large-diameter portion 118 is set to be substantially the same as the inner diameter of the elbow 2 while being screwed to the mouth 108.
- the large-diameter portion 118 of the chuck 114 attached to the suction port 106 is open to the outside, while the large-diameter portion of the chuck 111 attached to the connection port 108 is open. 1 1 8 is fitted into the opening of the helper 72.
- an air valve 120 as an opening amount adjusting means is connected to an end of the elbow 72 opposite to the side where the magnetic processing device 76 is mounted, and the air valve 120 is further connected to the intake cylinder.
- the intake body 74 has a substantially cylindrical shape, and the end opposite to the mounting of the elbow 72 is inserted into the aforementioned plurality of intake holes 70 provided in the heat treatment furnace 12.
- a pair of intake cylinders 74 inserted in the intake holes 70 provided in the side wall 20 and the intake holes 70 provided in the intermediate portion of the front wall 16 are inserted.
- the intake cylinder 74 penetrates the horizontal wall 32 and the first vertical wall 26 forming the wall of the heat treatment chamber 34 and opens to the heat treatment chamber 34.
- the lid of the front wall 1 6 5 4 The opening end of the intake cylinder 74 inserted into the intake hole 70 provided in the first vertical wall 26 and the front wall 16 is opposed to each other.
- the wall 26 communicates with the heat treatment chamber 34 through the communication hole 35.
- a plurality of (four in the present embodiment) magnetic processing devices 76 as described above are assembled to the heat treatment device 10, and external air is supplied to the suction port 10 6 of the magnetic processing device 76.
- the air is then magnetically processed through the intake passage 80, and is guided to the heat treatment chamber 34 as combustion air, and the amount of combustion air taken in by the air valve 120 is adjusted. ing.
- an air treatment tank 122 is mounted on the flue water tank 14 as a part of the heat treatment apparatus 10 of the present embodiment.
- the air treatment tank 122 has a hollow, substantially rectangular box-like shape, and a partition plate 124 is provided at a substantially middle portion of the hollow inside in a direction perpendicular to the axis (vertical direction in FIG. 5). It is disposed so as to extend in the longitudinal direction, and the inside of the air treatment tank 1 2 2 is partitioned and divided into two by this partition plate 1 2 4, so that the second flue having a substantially meandering shape 1 2 6 Are formed inside.
- a second connection hole 1 28 of a substantially circular shape is provided which is opened on the lower wall of the air treatment tank 122. Since the second connection hole 1 2 8 is fixed to the outside of the second connection pipe 6 6 penetrating the upper wall of the flue water tank 14, the inside of the flue water tank 14 is And the insides of the air treatment tanks 122 are communicated with each other.
- the upper end opening of the second connection pipe 66 is substantially flush with the opening peripheral portion of the second connection hole 128.
- a third connection pipe 130 having a substantially bent pipe shape including an elbow straight pipe is provided with an air treatment tank. An external opening of the third connection pipe 130 extends upward while being provided so as to penetrate the side wall portion of the second connection pipe 132.
- a small hole-shaped air intake 1 32 is provided, and an air line 1 34 is connected to the air inlet 1 32.
- the air pipe 13 4 has a substantially bent pipe shape, and a blower 13 6 as air supply means is provided at the end opposite to the connection side of the air intake 13. And is placed in the flue water tank 14. Further, a magnetic processing device 76 is provided on the air line 134. As a result, the air blown from the blower 13 6 is magnetically processed through the intake passage 80 of the magnetic processing unit 76, and is guided to the second flue 1 26 in the air processing tank 122. It has become.
- the air treatment tank 122 is provided with a smoke elimination device 138 mounted as a part of the heat treatment device 10 of the present embodiment.
- the smoke eliminator 1338 has a hollow, substantially rectangular box shape, and is perpendicular to the axis (vertical direction in FIG. 9).
- a pair of first side walls 140, 140, extending in the axial direction (left and right direction in FIG. 9), a pair of second side walls 144, 142, the upper wall 144, and the bottom A wall 144 is provided.
- a pair of the first side walls 140 and the second side walls 142 are arranged in a substantially vertical direction (the eighth side). (The vertical direction in the figure).
- a partition plate 148 having a substantially rectangular flat plate shape is provided between the opposing surfaces of the first side walls 140, 140 in the smoke elimination device 1 38.
- the left side wall 140 in FIG. 8 is provided near the inner wall of each of the second side walls 142, 1.42 and the bottom wall 144. It is fixed by welding. As a result, the smoke removal device 1 3 8
- first processing chamber 150 and a second processing chamber 152 having approximately three times the size of the first processing chamber 150 are formed therein.
- the height of the partition plate 148 is set smaller than the first side wall 140 and the second side wall 144, whereby the first processing chamber is formed.
- the first processing chamber 150 and the second processing chamber 152 communicate with each other through the upper part of the partition plate 148.
- the bottom wall 1 46 i of the portion located below the first processing chamber 150 has a third connection hole 154 penetrating therethrough.
- a slide plate 156 is provided at an intermediate portion of the first processing chamber 150 in the height direction.
- the slide plate 156 has a substantially rectangular flat shape, is disposed so as to extend substantially parallel to the top wall 144 and the bottom wall 146, and has a large number of ventilation holes 156. 8 is provided penetrating in the thickness direction.
- the length of the slide plate 156 is set slightly larger than the width of the first processing chamber 150 (the left and right lengths in FIG. 9).
- the left end of Fig. 9 (left in Fig. 9) penetrates the first side wall 140 and is located outside the smoke elimination device 1 38, while the height of the first processing chamber 15O is high.
- Both ends in the width direction of the slide plate 156 are placed on the surface 160.
- the slide plate 156 holds the one minute projecting from the smoke elimination device 138 to the outside and operates the slide plate 156 in the horizontal direction of the first processing chamber 150 (No. 8). Or, the area of left and right in Fig. 10), and thus the opening of the third flue 162 described later, can be adjusted.
- an exhaust port: L64 is provided in the first side wall 140 on the second processing chamber 152 side, and a substantially bent as a chimney is provided around the opening of the exhaust port 164.
- An exhaust cylinder 166 having a tubular shape (in other words, an elpo shape) is illustrated.
- a first partition plate 1668 having a substantially rectangular flat plate shape is provided between the opposing surfaces of the upper wall 144 and the bottom wall 1_46.
- Cutting plates 170 are arranged in parallel from the top wall 144 to the bottom wall 144 in order, and are provided in parallel with the top wall 144 and the bottom wall 144.
- the first side wall 140, the second side wall 142, and the partition plate 148 are fixed to the respective inner surfaces of the partition plate 148 by welding or the like.
- the first partition plate 168 and the second partition plate 170 are provided in the second processing chamber 152 near the upper wall 144 while approaching each other. The distance between the opposing surfaces of the second partition plate 170 and the bottom wall 146 is increased.
- the first partition plate 168 is located at substantially the same height as the upper edge of the partition plate 148, and one of the first partition plates 168 (in FIG. 8, The left (left) end is fixed to the upper edge of the partition plate 148 by welding or the like, while the other (in FIG.
- the second partition plate 170 is located at substantially the same height as the upper end portion of the exhaust port 164, and one of the second partition plates 168 (FIG. 8). , Right) is fixed to the first side wall 140 near the upper end of the exhaust port 164 by welding or the like, while the other end (in FIG. 8, left) is a partition. It has a length that does not reach the plate 148.
- a treatment water tank 172 as a water storage tank is formed between the facing surfaces of the second partition plate 170 and the bottom wall 146.
- the treated water tank 17 2 contains the same treated water 68 as the flue water tank 14, and the treated water 68 has a water level higher than that of the second partition plate 170. Is positioned slightly below and not to cover the entire exhaust port 164, and the distance between the water surface of the treated water 68 and the opposing surface of the second partition plate 170 is reduced. At the same time, part of the treated water 68 flows into the lower end of the exhaust stack 166.
- a first treating agent 174 made of manganese is added to the first partition plate 170 and the second partition plate
- a large number of second treating agents 176 composed of a fungicide are arranged and fixed.
- the exhaust gas discharged from the third connection pipe 130 passes through the first processing chamber 150 and the second processing chamber 152 to the first and second processing chambers.
- the treated water tank 17 is provided with a treated water 68 so that the treated water is brought into contact with the treated water 68 and discharged from the exhaust cylinder to the outside (in the atmosphere).
- the third flue 162 is composed of the first processing chamber 150 and the second processing chamber 1552 in the smoke elimination device 1338, and the heat processing chamber
- the flue connected to the vent 50 provided in 34 and communicating with the heat treatment chamber 34 is composed of the first flue 60 of the flue water tank 14 and the second of the air treatment tank 1 2 2
- the exhaust channel is composed of the above-mentioned flue and the exhaust gas guided through the flue It is configured to include an exhaust pipe 166 to be released from the section to the atmosphere.
- the smoke elimination device 1 3 8 has an inspection window 17 through which an opening window is made through the second side wall 14 2 etc. and a transparent body such as acrylic glass is fitted into the window. 8 are provided so that the color and amount of the exhaust gas can be observed.
- the lid 40 of the processing furnace 12 is opened, and a heat-treated product as organic waste is charged from the charging port 38. After the heat treatment is ignited, the lid 40 is closed to seal the processing furnace 12, and the heat treatment is performed by magnetic treatment through a plurality of intake passages 80 formed in the front wall 16, the side wall 20, and the like. Air is taken into the heat treatment chamber 34 by natural suction with the air valve 120 open. In particular, in the present embodiment, the air to be magnetically treated is supplied to the area where the permanent magnets 110 and 110 are disposed.
- the turbulent flow is actively generated in the widened portion 90, narrowed portion 92, convex portions 94, 96, concave portion 94, and the like.
- the heat-treated product is heat-treated exclusively in the heat-treating chamber 34 on the bottom wall 24 to be oxidized, carbonized, or ashed.
- the ambient temperature in the heat treatment chamber 34 in the heat treatment state can be controlled by adjusting the amount of outside air (heat treatment air) sucked into the heat treatment chamber 34, for example.
- the temperature should be 300 ° C or less even in the region near the highest temperature carbide. It is preferable that the temperature be adjusted to 250 ° C. or less.
- the heat-treated material (organic waste) is converted into a deodorant disinfectant containing a large amount of ceramics or made of ceramics and taken out of the front wall 16 and the rear wall 18 outlet 5 2
- a part of the material is applied to raw materials such as a building paint, a building wall material, an agricultural spraying agent, and the other, and the rest is applied to the first smoke removing device 1
- the present invention is applied as a second treating agent 176 which is placed on a large number of partitions 168 and the second partition 170 at intervals.
- Exhaust gas generated by the heat treatment is generated between the opposing surfaces of the second vertical wall 26 and the third vertical wall 30 and between the opposing surfaces of the third vertical wall 30 and the rear wall 18. And the like, from the first connecting pipe 64 to the first flue 60 in the flue water tank 14, and contact with the treated water 68 of the first flue 60 to be cooled. Meanwhile, it is led to the second flue 1 26 in the air treatment tank 122 through the second connecting pipe 66. When passing through the second flue, the exhaust gas is sent out from the blower 13 6, and is brought into contact with the magnetically treated air through the magnetic processing device 76, and eventually through the air line 1 34. The third connection pipe 130 guides the third flue 162 of the smoke suppressor 1 38 to the second flue 162.
- the exhaust gas is brought into contact with the first treatment agent 17 2 and the second treatment agent 17 6, and the exhaust gas is brought under the second treatment chamber 15 2 (a treatment water tank). While being in contact with the treated water 68 stored in 172), it is discharged to the atmosphere from the exhaust stack 166.
- part of the exhaust gas that follows the above-mentioned discharge route is directly dissolved in the treated water tank 14 in the flue water tank 14 or the treated water tank 18 in the treated water tank 17 2, or before being discharged into the atmosphere. After being cooled, it flows down the inner surfaces of the first, second, and third flue 60, 126, 162, etc., and dissolves in the treated water 68 of the flue water tank 14. After dissolving the wood vinegar contained in the exhaust gas in the treated water 68, the wastewater is drained from the flue water tank 14 when replacing the treated water 68, etc. Extract the wood vinegar solution by distillation.
- the heat treatment apparatus 10 since the air subjected to the magnetism is sucked in as heat treatment air, the heat treatment apparatus 10 was in the processing furnace 12 before the heat treatment. Even after exhausting the air (oxygen) for the heat treatment, oxidation reaction such as gentle combustion that does not emit a large flame in a large area inside the heat treatment product by using the small amount of air sucked by natural aspiration. The carbonization is promoted, so that it is possible to perform heat treatment while avoiding remarkable high temperature in the furnace, especially in the furnace wall, and to suppress the generation of dioxins in a state close to almost complete combustion. The heat resistance required for the furnace wall and the like of 10 can be reduced, and a heat treatment apparatus 10 with excellent durability and maintainability can be realized.
- the atoms and ions of the fluid are moved in the magnetic field (magnetic field) generated by the permanent magnet 110, so that the fluid is affected by magnetic force and accompanying electromagnetic induction. Therefore, the magnetic treatment is performed, but the fluid is aggressive especially in the area where a large magnetic field is applied. Since the fluid is in a turbulent state, the magnetic action of the permanent magnet 110 can be applied to the fluid substantially uniformly and efficiently over the entirety.
- the permanent magnet 110 is not fixed to the housing 78 and has a small displacement (preferably 10 m or more, more preferably 1 (Displacement of 100 m / im or more, more preferably about 100 m to several mm), so that it is almost in a vibrating state due to vibration or force exerted mechanically from outside or flowing fluid. It can be displaced in a substantially vibrating state by the action of a magnetic force or an electromagnetic force exerted on molecules or the like existing in a fluid. Then, with the minute displacement of the permanent magnet 110, the magnetic field applied to the intake passage 80 is changed, and as a result, a magnetic effect is more effectively exerted on the heat treatment air flowing through the intake passage 80. Can be affected.
- a small displacement preferably 10 m or more, more preferably 1 (Displacement of 100 m / im or more, more preferably about 100 m to several mm)
- the deodorant germicide of the present embodiment effectively kills bacteria harmful to the human body such as Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and Salmonella, and removes bacteria harmless to the human body. It has a bactericidal action that does not kill it, and has a deodorizing action that adsorbs harmful gases that cause odors, such as ammonia-formaldehyde.For example, by applying it to building paints and building wall materials, In addition to being able to effectively improve the sanitization of agricultural products, it can be spread on planted soil such as fields, or on livestock breeding beds. By applying the composition to a spray or the like, it is possible to suppress diseases and suppress off-flavors, whereby cultivation and breeding with reduced or no pesticides can be advantageously achieved.
- bacteria harmful to the human body such as Escherichia coli, Pseudomonas aeruginosa, Staphylococcus
- the deodorant germicide can be obtained from the organic waste, and the cost can be advantageously reduced.
- the deodorant sterilizer is treated using the heat treatment apparatus 10 of the present embodiment.
- Deodorant consisting of organic waste was installed as a second treatment agent 176 in the smoke elimination device 13 8 to effectively achieve the effect of adsorbing dioxins and odors in exhaust gas. In addition to this, it is possible to decompose organic wastes with as little cost as possible.
- the arrangement position and number of the permanent magnets can be appropriately adjusted in consideration of the target heat treatment state, cost properties, and the like.
- the inlet and the outlet in the processing furnace, the arrangement portion of the lid, and the like can be appropriately changed.
- a lid that can be opened and closed may be provided only at the center of the front wall.
- the air intake holes for the heat treatment air are not limited to the structure, the arrangement position, the number, and the like described in the above embodiment.
- the widened portion and the constricted portion in the above embodiment are not always required.
- the entire length not including the widened portion and the constricted portion Therefore, it is also possible to employ a through hole having a substantially constant width.
- the shape and number of the concave groove and the convex portion, the arrangement position, and the like are not limited at all.
- the flow adjusting means such as the widened portion and the constricted portion has a length dimension of the magnetic pole surface in the flow direction of the heat treatment air with respect to the magnetic pole surface of the permanent magnet arranged and positioned facing the intake passage. It is desirable to set each of them in the area of twice or less on the upstream and downstream sides, and more preferably, it is formed on the upstream side of the pole face.
- the width of the magnetic pole of the permanent magnet facing the intake passage is 0.5 times or more the width of the intake passage, more preferably 0.75. More than double.
- the grooves and protrusions in the above embodiment are not essential.
- the flow of the fluid only at the widened portion and the constricted portion provided in the through hole. Can also be adjusted.
- the flow of the fluid only at the widened portion and the constricted portion provided in the through hole. Can also be adjusted.
- the concave groove provided in the through-hole is formed so as to penetrate the first plate in the plate thickness direction.
- the concave groove extending at a predetermined depth dimension without penetrating the first plate. (See FIG. 12).
- the first plate (through-hole) is provided with a concave groove and a convex portion.
- the second plate is provided with a concave groove and a convex portion at the bottom or the like to expand and contract the intake passage. Is also possible.
- the recess (circular recess) in which the permanent magnet is provided is not limited to the shape (circle) as illustrated, for example, the M location of a polygonal cross section and the like. May be adopted.
- the structure of the intake passage is not limited to the above-described embodiment.
- a cylinder body having a different cross section and extending at a predetermined length may be employed as the intake passage.
- an electromagnetic shield may be provided around the intake passage to prevent the adverse effects of external electromagnetic fields.
- a vibration means such as a vibrating speaker is provided in the housing forming the air intake passage so that the fluid flowing through the air intake passage or the housing supporting the permanent magnet is vibrated so that the fluid molecular motion due to the pressure fluctuation and the permanent vibration are generated.
- the displacement of the magnet may be generated more positively.
- a desiccant such as silica gel charcoal (charcoal or activated carbon) or a filter (including a filter and a strainer) may be disposed in the intake passage or the like, so that air or the like that can flow through the intake passage may be provided. It is also possible to control the humidity. Further, in the above-described embodiment, tourmaline, which is said to be effective for generating a reductant or the like, emitting far-infrared rays, generating a weak current, or the like, can be provided in the housing. .
- the first plate, the second plate, and the third plate are fixed with an adhesive, respectively.
- these plates are detachably fixed with bolts and pins. It is also possible to do so, depending on the required installation space and assembly conditions to other equipment. Depending on the situation, any one of these plates can be replaced with another plate having a different shape formed separately.
- N pole and N pole, or S pole and S pole may be placed opposite to each other across the fluid passage, thereby applying a magnetic field to a wide area. It becomes possible.
- the shape, structure, size, etc. of the intake passage are not limited at all.
- a large number of branch structures are employed, and permanent magnets are arranged in each branch channel. It is also possible to adopt the structure of the above-described embodiment, whereby a more uniform magnetic action can be exerted even on a large amount of fluid.
- the flue water tank, the air treatment tank, the smoke elimination device, and the like are provided above the treatment furnace.
- these are not necessarily essential.
- an exhaust pipe may be fixed to the vent hole provided in the processing furnace to decompose the organic waste or produce a deodorant sterilizer. May be realized.
- the present invention can be embodied in a form in which various changes, modifications, improvements, and the like are added based on the knowledge of those skilled in the art. It goes without saying that all of them are included in the scope of the present invention unless departing from the spirit of the present invention.
- a pair of permanent magnets 110 and 110 are displaceably arranged on a housing 78 provided with an intake passage 80 such that different poles are opposed to each other on both sides of the housing 78 sandwiching the intake passage 80.
- a heat treatment apparatus 10 having a concave groove 94 in the through hole 88 constituting the intake passage 80, a convex part 96, 98, a widened part 90, and a constricted part 92 is provided.
- the bacteria are cultured in an SA medium at 37 ° C for 24 hours, the yeasts are cultured in a PDA medium at 25 for 24 hours, and the power plants are cultured in a PDA medium for 7 to 14 hours. Incubate.
- the bacteria are adjusted to X107 CFU / ml using sterile saline, and the yeast is adjusted to X106-X using sterile saline.
- Each cell was adjusted to 107 CFU / ml using a surfactant (0.05% Tween80) and adjusted to 10 6 to 10 7 CFU / ml. Make liquid.
- the test pieces were separately prepared from the deodorant disinfectant obtained by the first heat treatment and the deodorant disinfectant obtained by the second heat treatment.
- Tables 1-5 the deodorant bactericide obtained by the first heat treatment was used for the test sample, and in Tables 7-11, the second sample was used for the test sample.
- Table 1 and Table 7 show the results of tests using Escherichia coli (E. coli) KEC-B-001 as the test bacteria.
- Table 3 and Table 9 show the test results using Pseudomonas aeruginosa (Pseudomonas aeruginosa) KEC-B-003 as the test bacterium.
- Tables 4 and 10 show the test results using Bacillus subtillus (Bacillus subtilis) KEC-B-007 as the test bacterium, and Table 5 and Table 11 To Shows the test results using Salmonella typhimurium (Salmonella typhimurium) KEC-B-009 as a test bacterium.
- [Table 6] shows the results based on the above [Table:! ⁇ 5].
- Table 15 The results are shown in Table 15 and the test results using Penicillium citrinum KEC-F-021 as the test bacteria.
- Table 16 shows f and Cladospormum as the test bacteria.
- Test results using cladosporioid.es KEC-F-018 are shown.
- [Table 17] shows a summary of the bactericidal concentrations of fungi including yeasts and power plants by the deodorant germicides based on the above test results.
- the deodorant germicide of the present embodiment effectively kills bacteria and the like harmful to the human body while inhabiting useful yeasts and vitreous bacteria.
- the deodorant germicide of the present embodiment effectively kills bacteria and the like harmful to the human body while inhabiting useful yeasts and vitreous bacteria.
- test apparatus As shown in FIG.
- a test apparatus has a hollow rectangular box shape having a vertical length of 30 Omm, a horizontal length of 30 Omm, and a height of 30 Omm, and is made of acryl resin.
- the main body 180 is included.
- a filling port 182 is provided on one of the side walls of the container body 180 facing each other, and a suction port 184 is provided on the other side wall, and the vertical length and the horizontal length are provided on the upper wall.
- Both are equipped with a 160 mm openable and closable inlet 186. Also, connect a detector tube to the suction port 184.
- This detection tube includes an air duct, a detector 188 and an air pump 190, and the air inside the container body 180 is sucked from the suction port 184 by the suction action of the air pump 190.
- a storage box 1994 having a cup shape and having a large number of air vents 1996 on the side wall is installed.
- a 1.2 m3 / min fan 198 is provided at the top opening of the housing box 194 so as to be detachable. This allows fan 1
- the container 194 was filled with the deodorant and germicide. 5 g of the test specimen 1992 and a fan 198 at the top opening of the storage box 1994.
- the container body 180 is put into the inside of the container body 180 through the inlet 186 to make the container body 180 substantially closed.
- ammonia with an initial concentration of 15 O ppm is injected from the Tedlar bag into the inside of the container body 180 using an air pump with an air inlet of 82.
- the decomposition treatment is slowly performed by the magnetically treated air for heat treatment, and is not stopped halfway until the final ceramic state is reached.
- dioxins and odors in the exhaust gas can be advantageously reduced or eliminated, and at the same time, are extremely available for reuse. And useful deodorant germicides can be produced efficiently.
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- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Organic Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Claims
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PCT/JP2004/003601 WO2005089970A1 (ja) | 2004-03-17 | 2004-03-17 | 有機系廃棄物の分解処理装置と消臭殺菌剤および消臭殺菌剤の製造方法 |
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JP2002138003A (ja) * | 2000-10-31 | 2002-05-14 | Kawasaki Steel Corp | 水中生物付着防止体および水中生物付着防止方法 |
JP2003117534A (ja) * | 2001-10-18 | 2003-04-22 | Katsuya Kihira | 廃棄物の熱処理炉 |
JP2003144845A (ja) * | 2001-11-16 | 2003-05-20 | Yyl:Kk | 除去対象物質の処理方法及び処理材と装置 |
JP2003342530A (ja) * | 2002-05-30 | 2003-12-03 | Ishitake:Kk | 水性塗料組成物 |
JP2004057984A (ja) * | 2002-07-30 | 2004-02-26 | Katsuya Kihira | 磁気処理装置 |
JP2004073982A (ja) * | 2002-08-15 | 2004-03-11 | Clay Baan Gijutsu Kenkyusho:Kk | セッコウ複合炭化物とその製造方法 |
JP2004091367A (ja) * | 2002-08-30 | 2004-03-25 | Katsuya Kihira | 消臭殺菌剤 |
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JPH0549923A (ja) * | 1991-08-08 | 1993-03-02 | Shinko Giken:Kk | 蚕糞の炭化物 |
JP2001161854A (ja) * | 1999-12-09 | 2001-06-19 | Chitoshi Fujiwara | ダイオキシン処理方法およびこの方法を使用するための装置 |
JP2001304520A (ja) * | 2000-04-18 | 2001-10-31 | Toshimi Hirozo | 焼却炉および焼却方法 |
JP2002138003A (ja) * | 2000-10-31 | 2002-05-14 | Kawasaki Steel Corp | 水中生物付着防止体および水中生物付着防止方法 |
JP2001321757A (ja) * | 2000-12-05 | 2001-11-20 | Chugoku Shii S K:Kk | 炭化加工品 |
JP2003117534A (ja) * | 2001-10-18 | 2003-04-22 | Katsuya Kihira | 廃棄物の熱処理炉 |
JP2003144845A (ja) * | 2001-11-16 | 2003-05-20 | Yyl:Kk | 除去対象物質の処理方法及び処理材と装置 |
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