WO2005084441A2 - Concentres en suspension a base d'huile - Google Patents

Concentres en suspension a base d'huile Download PDF

Info

Publication number
WO2005084441A2
WO2005084441A2 PCT/EP2005/002294 EP2005002294W WO2005084441A2 WO 2005084441 A2 WO2005084441 A2 WO 2005084441A2 EP 2005002294 W EP2005002294 W EP 2005002294W WO 2005084441 A2 WO2005084441 A2 WO 2005084441A2
Authority
WO
WIPO (PCT)
Prior art keywords
alkyl
substituted
optionally
methyl
alkoxy
Prior art date
Application number
PCT/EP2005/002294
Other languages
German (de)
English (en)
Other versions
WO2005084441A3 (fr
Inventor
Reiner Fischer
Udo Reckmann
Ronald Vermeer
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DK05731791T priority Critical patent/DK1725105T3/da
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Priority to US10/591,128 priority patent/US8664259B2/en
Priority to CA2558421A priority patent/CA2558421C/fr
Priority to EP05731791A priority patent/EP1725105B1/fr
Priority to DE502005004114T priority patent/DE502005004114D1/de
Priority to BRPI0508526-8A priority patent/BRPI0508526B1/pt
Priority to JP2007501227A priority patent/JP4705627B2/ja
Priority to AU2005220024A priority patent/AU2005220024B2/en
Priority to PL05731791T priority patent/PL1725105T3/pl
Publication of WO2005084441A2 publication Critical patent/WO2005084441A2/fr
Publication of WO2005084441A3 publication Critical patent/WO2005084441A3/fr
Priority to IL177742A priority patent/IL177742A0/en
Priority to KR1020067020378A priority patent/KR101217667B1/ko

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof

Definitions

  • the present invention relates to novel, oil-based suspension concentrates of cyclic ketoenols, to a process for the preparation of these formulations and to their use for the application of the cyclic ketoenols present.
  • EP-A 0 789 999 describes formulations of this type which, in addition to active ingredient and oil, contain a mixture of various surfactants, including those which serve as penetrating agents, and a hydrophobized aluminum silicate as thickener.
  • the stability of these preparations is good.
  • the disadvantage is that a thickening agent is necessarily present, because this makes the production more complicated.
  • the thickening agent absorbs in each case a part of the added amount of Penetrationsforderer, which is therefore not available for its actual function.
  • non-aqueous suspension concentrates are known from US Pat. No. 6,165,940, in which, apart from the agrochemical active ingredient, penetrant and surfactant or surfactant mixture, an organic solvent is present, parafin oil or vegetable oil esters being suitable as such solvents ,
  • an organic solvent is present, parafin oil or vegetable oil esters being suitable as such solvents .
  • the crop plant compatibility and / or biological effectiveness and / or the stability of the spray liquors which can be prepared from these formulations by dilution with water are not always sufficient.
  • V is oxygen or N-D
  • X is halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano
  • W, Y and Z independently of one another represent hydrogen, halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano
  • A is hydrogen, in each case optionally halogen-substituted alkyl, alkoxyalkyl, saturated, optionally substituted cycloalkyl in which optionally at least one ring atom is replaced by a heteroatom,
  • B is hydrogen or alkyl
  • a and B together with the carbon atom to which they are attached, represent a saturated or unsaturated unsubstituted or substituted cycle, optionally containing at least one heteroatom,
  • D is hydrogen or an optionally substituted radical from the group consisting of alkyl, alkenyl, alkoxyalkyl, saturated cycloalkyl, in which optionally one or more ring members are replaced by heteroatoms,
  • a and D together with the atoms to which they are bonded represent a saturated or unsaturated and optionally at least one heteroatom-containing, unsubstituted or substituted in the A, D-part cycle,
  • G is hydrogen (a) or one of the groups
  • E is a metal ion or an ammonium ion
  • L is oxygen or sulfur
  • M is oxygen or sulfur
  • Rl is in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally substituted by halogen, alkyl or alkoxy-substituted cycloalkyl which is replaced by at least one heteroatom each optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl,
  • R 2 is in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or in each case optionally substituted cycloalkyl, phenyl or benzyl,
  • R 3 is optionally halogen-substituted alkyl or optionally substituted phenyl
  • R 1 and R 5 independently of one another are each optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio or in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio and
  • R 6 and R 7 are each independently hydrogen, in each case optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, optionally substituted phenyl, optionally substituted benzyl or together with the N-atom to which they are attached, for a optionally substituted by oxygen or sulfur interrupted optionally substituted ring and at least one penetration promoter, at least one vegetable oil, at least one nonionic surfactant and / or at least one anionic surfactant and optionally one or more additives from the groups of emulsifiers, the foam-inhibiting agent, the preservative , the antioxidants, the dyes and / or the inert fillers
  • oil-based suspension concentrates according to the invention can be prepared by reacting at least one compound of the formula (I 1 ) which is solid at room temperature, at least one penetration requester, at least one vegetable oil, at least one nonionic surfactant and / or at least one anionic surfactant and optionally one or more additives from the groups of emulsifiers, antifoaming agents, preservatives, antioxidants, dyes and / or inert fillers
  • oil-based suspension concentrates according to the invention plant very well for application of the compounds of the formula (V) present and / or are suitable for their habitat.
  • oil-based suspension concentrates according to the invention show markedly better crop plant compatibility, although the biological effect / uptake of foreign substances in the plant tissue is clearly higher in comparison with the most closely matched, previously known formulations. This effect was unpredictable due to the above-described prior art.
  • the oil-based suspension concentrates according to the invention are also distinguished by a number of advantages. Thus, their preparation is less expensive than the preparation of appropriate formulations in which thickening agents are present. A further advantage is that when diluting the concentrates according to the invention with water neither a significant creaming nor a disturbing flocculation occurs, which is often the case with corresponding prior art preparations. Finally, the formulations according to the invention favor the plant-plant compatibility and / or the biological effectiveness of the active components contained, so that, in comparison to conventional preparations, either a higher activity is achieved or less active ingredient is required.
  • V is preferably oxygen or N-D
  • W is preferably hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, chlorine, bromine or fluorine,
  • X is preferably C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkyl, fluorine, chlorine or bromine
  • Y and Z are each independently of the other preferably hydrogen, C 1 -C 4 -alkyl, halogen, C 1 -C 4 -alkoxy or C 1 -C 4 -haloalkyl
  • A is preferably hydrogen or in each case optionally halogen-substituted C 1 -C 6 -alkyl or C 3 -C -cycloalkyl,
  • B is preferably hydrogen, methyl or ethyl
  • A, B and the carbon atom to which they are attached preferably represent saturated C3-C6 - cycloalkyl, wherein optionally one ring member is replaced by oxygen or sulfur and which is optionally monosubstituted or disubstituted by C ⁇ -C 4 -alkyl, trifluoromethyl or C C 1 -C 4 -alkoxy is substituted,
  • D is preferably hydrogen, in each case optionally fluorine- or chlorine-substituted C 1 -C 6 -alkyl, C 3 -C 4 -alkenyl or C 3 -C 6 -cycloalkyl,
  • a and D together preferably represent in each case optionally methyl-substituted C 3 -C -alkanediyl, in which optionally a methylene group is replaced by sulfur,
  • G is preferably hydrogen (a) or one of the groups
  • E is a metal ion or an ammonium ion
  • M is oxygen or sulfur
  • R 1 preferably represents in each case optionally halogen-substituted Ci-Cio-alkyl, C2 - Cio-alkenyl, C ⁇ -C4-alkoxy-C ⁇ -C 4 -alkyl, C 4 alkylthio-C, -C 4 - C 3 -C 6 -cycloalkyl optionally substituted by fluorine, chlorine, C 1 -C 4 -alkyl or C 1 -C 2 -alkoxy, optionally substituted by fluorine, chlorine, bromine, cyano, nitro, CC 4 alkyl, -CC alkoxy, trifluoromethyl or trifluoromethoxy phenyl, each optionally substituted by chlorine or methyl pyridyl or thienyl,
  • R 2 preferably represents in each case optionally substituted by fluorine or chlorine, C, -C ⁇ 0 - alkyl, C 2 -C 10 -alkenyl, CC 4 -alkoxy-C 2 -C 4 -alkyl, represents optionally methyl- or methoxy-substituted C 5 C 6 -Cycloalkyl or phenyl, in each case optionally substituted by fluorine, chlorine, bromine, cyano, nitro, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, trifluoromethyl or trifluoromethoxy,
  • R 3 preferably represents optionally substituted by fluorine C ⁇ -C 4 alkyl, or is optionally substituted by fluorine, chlorine, bromine, CC 4 alkyl, CC 4 -alkoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro,
  • R 4 preferably represents in each case optionally fluorine- or chlorine-substituted CC 4 -alkyl, -CC 4 -alkoxy, CC 4 -alkylamino, CC 4 -alkylthio or in each case optionally by fluorine, chlorine, bromine, nitro, cyano, CC 4 alkoxy, trifluoromethoxy, C ⁇ -C 4 alkylthio, C ⁇ -C4-haloalkylthio, CC 4 alkyl or trifluoromethyl-substituted phenyl, phenoxy or phenylthio,
  • R 5 is preferably C 1 -C 4 -alkoxy or C 1 -C 4 -thioalkyl
  • R 6 is preferably C, -C 6 alkyl, C 3 -C 6 cycloalkyl, CC 6 alkoxy, C 3 -C 6 alkenyl, QC 4 - alkoxy-C ⁇ -C 4 alkyl,
  • R 7 preferably represents CC ö alkyl, C 3 -C 6 alkenyl or C 4 -alkoxy-C C 4 alkyl,
  • V is particularly preferably oxygen or N-D
  • W is particularly preferably hydrogen, methyl, ethyl, chlorine, bromine or methoxy
  • X is particularly preferably chlorine, bromine, methyl, ethyl, propyl, isopropyl, methoxy, ethoxy or trifluoromethyl
  • Y and Z are more preferably independently of one another hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or methoxy
  • B is particularly preferably hydrogen, methyl or ethyl
  • A, B and the carbon atom to which they are attached are particularly preferably saturated C 6 -cycloalkyl in which optionally one ring member is replaced by oxygen and which is optionally monosubstituted by methyl, ethyl, trifluoromethyl, methoxy, ethoxy, propoxy or butoxy .
  • D is particularly preferably hydrogen, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, allyl, cyclopropyl, cyclopentyl or cyclohexyl,
  • a and D together are particularly preferably C 3 -C 4 -alkanediyl optionally substituted by methyl,
  • G is particularly preferably hydrogen (a) or one of the groups
  • M is oxygen or sulfur
  • R 1 particularly preferably represents C 1 -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl, ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl, optionally substituted by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, Methoxy, trifluoromethyl or trifluoromethoxy-substituted phenyl, in each case optionally substituted by chlorine or methyl-substituted pyridyl or thienyl,
  • R 2 particularly preferably represents C 1 -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxyethyl, ethoxyethyl or phenyl or benzyl,
  • R 6 and R 7 independently of one another particularly preferably represent methyl, ethyl or together represent a C 5 -alkylene radical in which the C 3 -methylene group is replaced by oxygen.
  • V is most preferred for ND,
  • W is very particularly preferably hydrogen or methyl
  • X very particularly preferably represents chlorine, bromine or methyl
  • Y and Z are very particularly preferably each independently hydrogen, chlorine, bromine or methyl
  • A, B and the carbon atom to which they are attached very particularly preferably represent saturated C 6 -Cycloalkyl, in which optionally a ring member is replaced by oxygen and which is optionally monosubstituted by methyl, trifluoromethyl, methoxy, ethoxy, propoxy or butoxy .
  • D is very particularly preferably hydrogen
  • G is very particularly preferably hydrogen (a) or one of the groups
  • M is oxygen or sulfur
  • R 1 very particularly preferably represents C -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxymethyl, ethoxymethyl, ethylmethylthio, cyclopropyl, cyclopentyl, cyclohexyl or optionally by fluorine, chlorine, bromine, methyl, methoxy, trifluoromethyl, trifluoromethoxy , Cyano or nitro substituted phenyl, each optionally substituted by chlorine or methyl pyridyl or thienyl,
  • R 2 very particularly preferably represents C -C 8 -alkyl, C 2 -C 4 -alkenyl, methoxyethyl, ethoxyethyl, phenyl or benzyl,
  • R 6 and R 7 independently of one another very particularly preferably represent methyl, ethyl or together represent a C 5 -alkylene radical in which the C 3 -methylene group is replaced by oxygen. Particular preference is given to oil-based suspension concentrates containing compounds of the formula (I ")
  • alkanol alkoxylates are generally defined by the above formula. These substances are mixtures of substances of the specified type with different chain lengths. For the indices, therefore, average values are calculated, which can also differ from whole numbers.
  • u stands for the average 8.4.
  • alkanol alkoxylates of the formulas given are known and available commercially under the trade names: Genapol, Marlipal, Lutensol, Renex.
  • EP-A-0 262 399 and GB-A-2 266 888 disclose similarly structured compounds (3-arylpyrrolidine-2,4-diones). Unsubstituted, bicyclic 3-arylpyrrolidine-2,4-dione derivatives (EP-A-355 599, EP-A-415 211 and JP-A-12-053 670) and substituted monocyclic 3-aryl are known -pyrrolidine-2,4-dione derivatives (EP-A-377 893 and EP-A-442 077).
  • EP-A-442 073 polycyclic 3-arylpyrrolidm-2,4-dione derivatives
  • EP-A-456 063 EP-A-521 334, EP-A- 596,298, EP-A-613,884, EP-A-613,885, WO 94/01 997, WO 95/26954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/16748, WO 99 / 24437, WO 99/43649, WO 99/48869 and WO 99/55673, WO 01/17972, WO 01/23354, WO 01/74
  • ⁇ 3 -dihydrofuran-2-one derivatives are known (compare DE-A-4 014 420).
  • the synthesis of the tetronic acid derivatives used as starting compounds (such as, for example, 3- (2-methylphenyl) -4-hydroxy-5- (4-fluorophenyl) - ⁇ 3 -dihydrofuranone- (2)) is likewise disclosed in DE-A- 4 014 420.
  • structured compounds are known from the publication Campbell et al., J.Chem.Soc, Perkin Trans. 1, 1985, (8) 1567-76.
  • oils are all commonly used in agrochemical means, recoverable from plants oils in question. Examples include sunflower oil, rapeseed oil, corn oil, olive oil and soybean oil.
  • the oil-based suspension concentrates according to the invention contain at least one nonionic surfactant and / or at least one anionic surfactant.
  • Suitable nonionic surfactants are all substances of this type conventionally usable in agrochemical compositions.
  • polyethylene oxide-polypropylene oxide block copolymers polyethylene glycol ethers of linear alcohols, reaction products of fatty acids with ethylene oxide and / or propylene oxide, furthermore polyvinyl alcohol, polyvinylpyrrolidone, copolymers of polyvinyl alcohol and polyvinylpyrrolidone and copolymers of (meth) acrylic acid and (meth) acrylic acid esters, furthermore alkylethoxylates and Alkylaryl ethoxylates which may optionally be phosphated and optionally neutralized with bases, wherein sorbitol ethoxylates may be mentioned as examples.
  • Suitable anionic surfactants are all substances of this type conventionally usable in agrochemical compositions. Preference is given to alkali metal and alkaline earth metal salts of alkyl sulfonic acids or alkylaryl sulfonic acids.
  • Suitable additives which may be present in the formulations according to the invention are emulsifiers, spreading agents, foam-inhibiting agents, preservatives, antioxidants, dyes and inert fillers.
  • emulsifiers As Spreitstoff come all commonly used for this purpose in agro-chemical agents substances into consideration. Preference is given to alkylsiloxanes.
  • Preferred emulsifiers are ethoxylated nonylphenols, reaction products of alkylphenols with ethylene oxide and / or propylene oxide, ethoxylated arylalkylphenols, furthermore ethoxylated and propoxylated arylalkylphenols, and sulfated or phosphated arylalkyl ethoxylates or ethoxy-propoxylates, where sorbitan derivatives, polyethylene oxide sorbitan fatty acid esters and sorbitan Fatty acid esters, may be mentioned as examples.
  • Suitable foam-inhibiting substances are all substances customarily usable for this purpose in agrochemical compositions.
  • Preferred are silicone oils and magnesium stearate.
  • Suitable preservatives are all substances customarily usable for this purpose in agrochemical compositions of this type. Examples which may be mentioned are Preventol® (Bayer AG) and Proxel®.
  • Suitable antioxidants are all substances customarily used for this purpose in agrochemical compositions. Preference is given to 2,6-di-tert-butyl-4-methylphenol.
  • Suitable dyes are all substances customarily usable for this purpose in agrochemical compositions. Examples include titanium dioxide, carbon black, zinc oxide and blue pigments as well as permanent red FGR.
  • Suitable inert fillers are all substances customarily usable for this purpose in agrochemical compositions which do not function as thickeners. Preference is given to inorganic particles, such as carbonates, silicates and oxides, as well as organic substances, such as urea-formaldehyde condensates. Examples include kaolin, rutile, silicon dioxide, so-called highly disperse silica, silica gels, and natural and synthetic silicates, as well as talc.
  • the content of the individual components can be varied within a relatively wide range in the oil-based suspension concentrates according to the invention.
  • concentrations of compound of the formula (I 1 ) are generally between 5 and 30% by weight, preferably between 10 and 25% by weight,
  • Penetrations brokeer generally between 5 and 30 wt .-%, preferably between 15 and 25 wt .-%, of vegetable oil generally between 20 and 55 wt .-%, preferably between 25 and 50 wt .-%, of surfactants in general between 2.5 and 30 wt .-%, preferably between 5.0 and 25 wt .-% and of additives generally between 0 and 25 wt .-%, preferably between 0 and 20 wt .-%.
  • the oil-based suspension concentrates according to the invention are prepared in such a way that the components are mixed together in the ratios desired in each case.
  • the order in which the ingredients are mixed together is arbitrary. expediently wise, one uses the solid components in finely ground state. However, it is also possible first to subject the suspension formed after mixing the constituents to a coarse and then to a fine grinding so that the mean particle size is less than 20 ⁇ m. Preference is given to suspension concentrates in which the solid particles have an average particle size of between 1 and 10 ⁇ m.
  • the temperatures can be varied in carrying out the method according to the invention in a certain range. It generally works at temperatures between 10 ° C and 60 ° C, preferably between 15 ° C and 40 ° C.
  • customary mixing and grinding devices which are used for the production of agrochemical formulations are suitable.
  • the oil-based suspension concentrates according to the invention are formulations which remain stable even after prolonged storage at elevated temperatures or in the cold, since no crystal growth is observed. They can be converted by dilution with water into homogeneous spray liquids. The application of these spray liquids by conventional methods, so for example by spraying, pouring or injecting.
  • the application rate of the oil-based suspension concentrates according to the invention can be varied within a relatively wide range. It depends on the particular agrochemical active ingredients and their content in the formulations.
  • agrochemical active substances can be applied in a particularly advantageous manner to plants and / or their habitat.
  • the agrochemical active ingredients contained develop a better biological activity (in particular a better insecticidal activity and / or a better crop plant compatibility) than when applied in the form of the corresponding conventional formulations.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
  • Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes be listed.
  • the plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.
  • the treatment according to the invention of the plants and plant parts with the suspension concentrates is carried out directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, spraying, vaporizing, atomizing, brushing and in propagating material, in particular in seeds, further by single or multi-layer wrapping.
  • plants and their parts can be treated.
  • wild species or plant species obtained by conventional biological breeding methods such as crossing or protoplast fusion
  • plant cultivars and their parts are treated.
  • transgenic plants and plant cultivars which have been obtained by genetic engineering methods if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated.
  • the term “parts” or “parts of plants” or “plant parts” has been explained above.
  • Plant varieties are understood as meaning plants having new traits which have been bred by conventional breeding, by mutagenesis or by recombinant DNA techniques. These can be varieties, biotypes and genotypes.
  • the treatment according to the invention may also give rise to superadditive ("synergistic") effects.
  • superadditive for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.
  • transgenic plants or plant species include all plants that received genetic material by the genetic engineering modification, which these plants particularly advantageous valuable Properties ("traits").
  • traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms, increased flowering, easier harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value the harvested products, higher shelf life and / or workability of the harvested products.
  • Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances.
  • transgenic plants include the important crops such as cereals (wheat, rice), corn, soybean, potato, cotton, oilseed rape, beets, sugarcane and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybean Potato, cotton and oilseed rape are particularly emphasized.
  • Traits that are particularly emphasized are the increased defense of the plants against insects by toxins produced in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (eg by the genes Cry ⁇ A (a), Cry ⁇ A (b), Cry ⁇ A (c), CryDA, Cry-HA, Cry-HB2, Cry9c Cry2Ab, Cry3Bb and Cry-F and combinations thereof) are produced in the plants (hereinafter "Bt plants”). Traits also highlight the increased resistance of plants to fungi, bacteria and viruses by systemic acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins.
  • SAR systemic acquired resistance
  • Traits that are further emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
  • the genes which confer the desired properties (“traits") can also occur in combinations with one another in the transgenic plants.
  • Examples of “Bt plants” are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato).
  • herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties, which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance to imidazolinone) and STS® (tolerance to sulfonylureas eg corn).
  • Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also the varieties marketed under the name Clearfield® (eg corn) mentioned. Of course, these statements also apply to future developments or, in the future, to the Market-leading plant varieties with these or future developed genetic traits.
  • the listed plants can be treated particularly advantageously with the suspension concentrates according to the invention.
  • the preferred ranges given above for the suspension concentrates also apply to the treatment of these plants. Particularly emphasized is the plant treatment with the suspension concentrates specifically listed herein.
  • R is straight-chain or branched alkyl having 12 to 15 carbon atoms
  • Bush bean plants Phaseolus vulgaris
  • cucumber plants Cucumis sativus
  • soybean plants Glycine max
  • the spray mixture is applied to the leaf top side with an active ingredient concentration of 400 ppm. At least 2 replicates are used.
  • the plant damage is determined in%. 100% means that the plant has completely died, 0% means that the plant is not damaged compared to the untreated control.
  • Cotton and cabbage plants in the 2-leaf stage each infected with Aphis gossypii (APHIGO) and Myzus persicae (MYZUPE), are treated with the drug solution (for quantities see table).
  • the amount of water used is equivalent to 300 1 / ha.
  • the cabbages are incubated in the greenhouse at 20 ° C and the cotton plants at 25 ° C. After the desired time, the efficacy is evaluated compared to the untreated control.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Indole Compounds (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne de nouveaux concentrés en suspension à base d'huile qui sont constitués d'au moins un composé solide à température ambiante, de formule (I'), d'au moins un promoteur de pénétration, d'au moins une huile végétale, d'au moins un agent tensioactif non ionique et/ou d'au moins un agent tensioactif anionique et éventuellement d'un ou de plusieurs additifs issus du groupe formé par les émulsifiants, les agents antimousse, les conservateurs, les antioxydants, les colorants et/ou les matières de charge inertes. La présente invention concerne également un procédé pour produire ces concentrés en suspension, ainsi que leur utilisation pour appliquer les substances actives contenues.
PCT/EP2005/002294 2004-03-06 2005-03-04 Concentres en suspension a base d'huile WO2005084441A2 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
BRPI0508526-8A BRPI0508526B1 (pt) 2004-03-06 2005-03-04 Concentrados em suspensão à base de óleo, seus empregos e seu processo de preparação, e agente
US10/591,128 US8664259B2 (en) 2004-03-06 2005-03-04 Oil-based suspension concentrates
CA2558421A CA2558421C (fr) 2004-03-06 2005-03-04 Concentres en suspension a base d'huile
EP05731791A EP1725105B1 (fr) 2004-03-06 2005-03-04 Concentres en suspension a base d'huile
DE502005004114T DE502005004114D1 (de) 2004-03-06 2005-03-04 Suspensionskonzentrate auf ölbasis
DK05731791T DK1725105T3 (da) 2004-03-06 2005-03-04 Suspensionskoncentrater på oliegrundlag
JP2007501227A JP4705627B2 (ja) 2004-03-06 2005-03-04 油性懸濁液濃縮物
AU2005220024A AU2005220024B2 (en) 2004-03-06 2005-03-04 Oil-based suspension concentrates
PL05731791T PL1725105T3 (pl) 2004-03-06 2005-03-04 Oparte na olejach koncentraty zawiesinowe
IL177742A IL177742A0 (en) 2004-03-06 2006-08-29 Oil-based suspension concentrates
KR1020067020378A KR101217667B1 (ko) 2004-03-06 2006-09-29 오일-기제 현탁 농축물

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004011006A DE102004011006A1 (de) 2004-03-06 2004-03-06 Suspensionskonzentrate auf Ölbasis
DE102004011006.9 2004-03-06

Publications (2)

Publication Number Publication Date
WO2005084441A2 true WO2005084441A2 (fr) 2005-09-15
WO2005084441A3 WO2005084441A3 (fr) 2005-11-24

Family

ID=34877481

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2005/002294 WO2005084441A2 (fr) 2004-03-06 2005-03-04 Concentres en suspension a base d'huile

Country Status (21)

Country Link
US (1) US8664259B2 (fr)
EP (1) EP1725105B1 (fr)
JP (1) JP4705627B2 (fr)
KR (1) KR101217667B1 (fr)
CN (1) CN100548124C (fr)
AR (2) AR048748A1 (fr)
AT (1) ATE394927T1 (fr)
AU (1) AU2005220024B2 (fr)
BR (1) BRPI0508526B1 (fr)
CA (1) CA2558421C (fr)
DE (2) DE102004011006A1 (fr)
DK (1) DK1725105T3 (fr)
EC (1) ECSP066828A (fr)
ES (1) ES2306129T3 (fr)
IL (1) IL177742A0 (fr)
MA (1) MA28521B1 (fr)
PL (1) PL1725105T3 (fr)
PT (1) PT1725105E (fr)
TW (1) TWI350141B (fr)
WO (1) WO2005084441A2 (fr)
ZA (1) ZA200607335B (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1905302A1 (fr) * 2006-09-30 2008-04-02 Bayer CropScience AG Suspensions concentrées
WO2008037379A1 (fr) * 2006-09-30 2008-04-03 Bayer Cropscience Aktiengesellschaft Concentrés de suspension destinés à améliorer la prise des racines d'agents actifs agrochimiques
EP2092822A1 (fr) 2008-02-25 2009-08-26 Bayer CropScience AG Suspensions concentrées à base d'huile
WO2009118027A1 (fr) * 2008-03-27 2009-10-01 Bayer Cropscience Aktiengesellschaft Concentrés en suspension pour améliorer l’absorption par les racines de composés agrochimiques actifs
WO2011147766A2 (fr) 2010-05-27 2011-12-01 Bayer Cropscience Ag Utilisation de suspensions concentrées à base d'huile pour réduire la dérive lors de l'application par pulvérisation
JP2013028613A (ja) * 2006-03-28 2013-02-07 Bayer Cropscience Ag 灌注、滴下施用、浸漬施用又は土壌注入によって有害生物を駆除するためのテトラミン酸誘導体の使用
EP3153503A1 (fr) * 2009-03-11 2017-04-12 Bayer Intellectual Property GmbH Intermédiaires pour cétoénols substitués par un halogénoalkylméthylènoxy-phényle
WO2019197637A1 (fr) * 2018-04-13 2019-10-17 Bayer Aktiengesellschaft Formulations fortement chargées renfermant des insecticides de la classe céto-énol, destinées à être utilisées dans des applications par goutte-à-goutte et par arrosage
EP3878279A1 (fr) 2020-03-10 2021-09-15 Bayer Aktiengesellschaft Utilisation de concentrés de suspo-émulsion à base d'huile pour réduire la diffusion pendant une application par vaporisation

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004011007A1 (de) * 2004-03-06 2005-09-22 Bayer Cropscience Ag Suspensionskonzentrate auf Ölbasis
DE102004044827A1 (de) 2004-09-16 2006-03-23 Bayer Cropscience Ag Jod-phenylsubstituierte cyclische Ketoenole
DE102004053192A1 (de) * 2004-11-04 2006-05-11 Bayer Cropscience Ag 2-Alkoxy-6-alkyl-phenyl substituierte spirocyclische Tetramsäure-Derivate
DE102004053191A1 (de) * 2004-11-04 2006-05-11 Bayer Cropscience Ag 2,6-Diethyl-4-methyl-phenyl substituierte Tetramsäure-Derivate
DE102005048539A1 (de) * 2005-10-11 2007-04-12 Bayer Cropscience Ag Suspensionskonzentrate auf Ölbasis
DE102006025874A1 (de) 2006-06-02 2007-12-06 Bayer Cropscience Ag Alkoxyalkyl-substituierte cyclische Ketoenole
DE102006027730A1 (de) * 2006-06-16 2007-12-20 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102006027731A1 (de) 2006-06-16 2007-12-20 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102006033154A1 (de) 2006-07-18 2008-01-24 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102006057037A1 (de) * 2006-12-04 2008-06-05 Bayer Cropscience Ag cis-Alkoxyspirocyclische biphenylsubstituierte Tetramsäure-Derivate
DE102007009957A1 (de) * 2006-12-27 2008-07-03 Bayer Cropscience Ag Verfahren zur verbesserten Nutzung des Produktionsptentials transgener Pflanzen
DE102007001866A1 (de) * 2007-01-12 2008-07-17 Bayer Cropscience Ag Spirocyclische Tetronsäure-Derivate
EP2011394A1 (fr) * 2007-07-03 2009-01-07 Bayer CropScience AG Utilisation de dérivés d'acide tétramique pour combattre les vecteurs transmettant des virus
WO2011100424A1 (fr) * 2010-02-12 2011-08-18 Bayer Croscience Lp Procédés de réduction des dommages provoqués par les nématodes sur les plantes
CN107484767A (zh) * 2017-08-14 2017-12-19 江苏龙灯化学有限公司 一种油基悬浮剂及其制备方法和用途
WO2019197621A1 (fr) * 2018-04-13 2019-10-17 Bayer Cropscience Aktiengesellschaft Concentré de matières en suspension à base d'huile
CN113749089B (zh) * 2020-06-02 2023-11-03 江苏龙灯化学有限公司 一种具有改善的稳定性的油分散组合物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997036868A1 (fr) * 1996-04-02 1997-10-09 Bayer Aktiengesellschaft Phenylceto-enols substitues utilises comme pesticides et herbicides
WO1998005638A2 (fr) * 1996-08-05 1998-02-12 Bayer Aktiengesellschaft Phenylcetoenols substitues a la position 2 ou aux positions 2 et 5
WO2002098230A2 (fr) * 2001-04-11 2002-12-12 Bayer Cropscience Ag Utilisation d'ethoxylates d'alcools gras en tant que promoteurs de penetration
WO2003000053A1 (fr) * 2001-06-21 2003-01-03 Bayer Cropscience Ag Suspensions concentrees a base d'huile

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4416303A1 (de) * 1994-05-09 1995-11-16 Bayer Ag Schaumarmes Netzmittel und seine Verwendung
GB9817354D0 (en) * 1998-08-11 1998-10-07 Agrevo Env Health Ltd Liquid formulation
AR029677A1 (es) * 2000-06-29 2003-07-10 Bayer Ag Combinaciones de compuestos activos con propiedades insecticidas y acaricidas
DE10216737A1 (de) * 2002-04-16 2003-10-30 Bayer Ag Bekämpfung von Parasiten bei Tieren
DE10330724A1 (de) * 2003-07-08 2005-01-27 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE10331674A1 (de) * 2003-07-14 2005-02-10 Bayer Cropscience Ag Verwendung von 2,2-Dimethyl-3(2,4-dichlorophenyl)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-yl butanoat zur Bekämpfung von Akariden
DE10337497A1 (de) * 2003-08-14 2005-03-10 Bayer Cropscience Ag 4-Biphenylsubstituierte-Pyrazolidin-3,5-dion-Derivate
DE10351646A1 (de) * 2003-11-05 2005-06-09 Bayer Cropscience Ag 2-Halogen-6-alkyl-phenyl substituierte spirocyclische Tetramsäure-Derivate
DE10353281A1 (de) * 2003-11-14 2005-06-16 Bayer Cropscience Ag Wirkstoffkombination mit insektiziden und akariziden Eigenschaften
DE10354629A1 (de) * 2003-11-22 2005-06-30 Bayer Cropscience Ag 2-Ethyl-4,6-dimethyl-phenyl substituierte spirocyclische Tetramsäure-Derivate
WO2005053405A1 (fr) * 2003-12-04 2005-06-16 Bayer Cropscience Aktiengesellschaft Combinaisons d'agents a proprietes insecticides et acaricides
DE102004001433A1 (de) * 2004-01-09 2005-08-18 Bayer Cropscience Ag cis-Alkoxyspiro-substituierte Tetramsäure-Derivate
DE102004030753A1 (de) * 2004-06-25 2006-01-19 Bayer Cropscience Ag 3'-Alkoxy spirocyclische Tetram- und Tretronsäuren
DE102004032420A1 (de) * 2004-07-05 2006-01-26 Bayer Cropscience Ag Verwendung von 3-(2,4,6-Trimethylphenyl)-4-neopentylcarbonyloxy-5,5-tetramethylen-Δ3-dihydrofuran-2-on zur Bekämpfung von Psylliden
DE102004035133A1 (de) * 2004-07-20 2006-02-16 Bayer Cropscience Ag Selektive Insektizide auf Basis von substituierten, cyclischen Ketoenolen und Safenern
US20080200499A1 (en) * 2004-07-20 2008-08-21 Reiner Fischer Selective Insecticides and/or Acaricides Based on Substituted Cyclic Dicarbonyl Compounds and Safeners
DE102004041529A1 (de) * 2004-08-27 2006-03-02 Bayer Cropscience Gmbh Herbizid-Kombinationen mit speziellen Ketoenolen
DE102004053192A1 (de) * 2004-11-04 2006-05-11 Bayer Cropscience Ag 2-Alkoxy-6-alkyl-phenyl substituierte spirocyclische Tetramsäure-Derivate
DE102004053191A1 (de) * 2004-11-04 2006-05-11 Bayer Cropscience Ag 2,6-Diethyl-4-methyl-phenyl substituierte Tetramsäure-Derivate
DE102005003076A1 (de) * 2005-01-22 2006-07-27 Bayer Cropscience Ag Verwendung von Tetramsäurederivaten zur Bekämpfung von Insekten aus der Gattung der Pflanzenläuse (Sternorrhyncha)
DE102005008021A1 (de) * 2005-02-22 2006-08-24 Bayer Cropscience Ag Spiroketal-substituierte cyclische Ketoenole
DE102005008033A1 (de) * 2005-02-22 2006-08-24 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102005051325A1 (de) * 2005-10-27 2007-05-03 Bayer Cropscience Ag Alkoxyalkyl spirocyclische Tetram- und Tetronsäuren
DE102006025874A1 (de) * 2006-06-02 2007-12-06 Bayer Cropscience Ag Alkoxyalkyl-substituierte cyclische Ketoenole
US20090281157A1 (en) * 2006-07-11 2009-11-12 Bayer Cropscience Ag Active Ingredient Combinations With Insecticidal and Acaricidal Properties

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997036868A1 (fr) * 1996-04-02 1997-10-09 Bayer Aktiengesellschaft Phenylceto-enols substitues utilises comme pesticides et herbicides
WO1998005638A2 (fr) * 1996-08-05 1998-02-12 Bayer Aktiengesellschaft Phenylcetoenols substitues a la position 2 ou aux positions 2 et 5
WO2002098230A2 (fr) * 2001-04-11 2002-12-12 Bayer Cropscience Ag Utilisation d'ethoxylates d'alcools gras en tant que promoteurs de penetration
WO2003000053A1 (fr) * 2001-06-21 2003-01-03 Bayer Cropscience Ag Suspensions concentrees a base d'huile

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013028614A (ja) * 2006-03-28 2013-02-07 Bayer Cropscience Ag 灌注、滴下施用、浸漬施用又は土壌注入によって有害生物を駆除するためのテトラミン酸誘導体の使用
JP2013028613A (ja) * 2006-03-28 2013-02-07 Bayer Cropscience Ag 灌注、滴下施用、浸漬施用又は土壌注入によって有害生物を駆除するためのテトラミン酸誘導体の使用
US7977278B2 (en) 2006-09-30 2011-07-12 Bayer Cropscience Ag Suspension concentrates
WO2008037379A1 (fr) * 2006-09-30 2008-04-03 Bayer Cropscience Aktiengesellschaft Concentrés de suspension destinés à améliorer la prise des racines d'agents actifs agrochimiques
WO2008037375A2 (fr) * 2006-09-30 2008-04-03 Bayer Cropscience Ag Concentrés de suspension
WO2008037375A3 (fr) * 2006-09-30 2008-05-29 Bayer Cropscience Ag Concentrés de suspension
EP1905302A1 (fr) * 2006-09-30 2008-04-02 Bayer CropScience AG Suspensions concentrées
EP2092822A1 (fr) 2008-02-25 2009-08-26 Bayer CropScience AG Suspensions concentrées à base d'huile
US20110003875A1 (en) * 2008-02-25 2011-01-06 Bayer Cropscience Ag Oil-Based Suspension Concentrates
WO2009106247A1 (fr) * 2008-02-25 2009-09-03 Bayer Cropscience Ag Suspensions concentrées à base d'huile
WO2009118027A1 (fr) * 2008-03-27 2009-10-01 Bayer Cropscience Aktiengesellschaft Concentrés en suspension pour améliorer l’absorption par les racines de composés agrochimiques actifs
EP3153503A1 (fr) * 2009-03-11 2017-04-12 Bayer Intellectual Property GmbH Intermédiaires pour cétoénols substitués par un halogénoalkylméthylènoxy-phényle
WO2011147766A2 (fr) 2010-05-27 2011-12-01 Bayer Cropscience Ag Utilisation de suspensions concentrées à base d'huile pour réduire la dérive lors de l'application par pulvérisation
WO2019197637A1 (fr) * 2018-04-13 2019-10-17 Bayer Aktiengesellschaft Formulations fortement chargées renfermant des insecticides de la classe céto-énol, destinées à être utilisées dans des applications par goutte-à-goutte et par arrosage
EP3878279A1 (fr) 2020-03-10 2021-09-15 Bayer Aktiengesellschaft Utilisation de concentrés de suspo-émulsion à base d'huile pour réduire la diffusion pendant une application par vaporisation
WO2021180640A1 (fr) 2020-03-10 2021-09-16 Bayer Aktiengesellschaft Utilisation de concentrés de suspo-émulsion à base d'huile pour réduire la dérive pendant l'application par pulvérisation

Also Published As

Publication number Publication date
ZA200607335B (en) 2008-04-30
DK1725105T3 (da) 2008-09-01
DE502005004114D1 (de) 2008-06-26
IL177742A0 (en) 2006-12-31
US20070276023A1 (en) 2007-11-29
JP2007527426A (ja) 2007-09-27
AU2005220024A1 (en) 2005-09-15
CN1929742A (zh) 2007-03-14
JP4705627B2 (ja) 2011-06-22
CN100548124C (zh) 2009-10-14
KR101217667B1 (ko) 2013-01-02
ATE394927T1 (de) 2008-05-15
CA2558421A1 (fr) 2005-09-15
AR048810A1 (es) 2006-05-31
PT1725105E (pt) 2008-07-24
AU2005220024B2 (en) 2010-04-22
ES2306129T3 (es) 2008-11-01
US8664259B2 (en) 2014-03-04
PL1725105T3 (pl) 2008-10-31
KR20070004000A (ko) 2007-01-05
AR048748A1 (es) 2006-05-24
TW200540151A (en) 2005-12-16
MA28521B1 (fr) 2007-04-03
WO2005084441A3 (fr) 2005-11-24
BRPI0508526A (pt) 2007-08-14
EP1725105A2 (fr) 2006-11-29
BRPI0508526B1 (pt) 2014-09-23
CA2558421C (fr) 2013-04-30
ECSP066828A (es) 2006-11-24
EP1725105B1 (fr) 2008-05-14
DE102004011006A1 (de) 2005-09-22
TWI350141B (en) 2011-10-11

Similar Documents

Publication Publication Date Title
EP1725105B1 (fr) Concentres en suspension a base d'huile
EP1725104B1 (fr) Concentres en suspension a base d'huile
EP2092822A1 (fr) Suspensions concentrées à base d'huile
EP2564702B1 (fr) Combinaisons de matière active nématicide comprenant comprenant du fluopyram et une autre matière active
EP1322160B1 (fr) Combinaison de substances actives ayant des proprietes insecticides et acaricides
EP1330161B1 (fr) Combinaisons de principes actifs a proprietes insecticides et acaricides
DE102005008033A1 (de) Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102005003076A1 (de) Verwendung von Tetramsäurederivaten zur Bekämpfung von Insekten aus der Gattung der Pflanzenläuse (Sternorrhyncha)
EP3001905A1 (fr) Combinaisons d'agents actifs a proprietes insecticides et acaricides
WO2005004603A1 (fr) Combinaisons de principes actifs a proprietes insecticides et acaricides
DE102006022821A1 (de) Verwendung von Tetramsäurederivaten zur Bekämpfung von Insekten aus der Ordnung der Käfer (Coleoptera), Thrips (Tysanoptera), Wanzen (Hemiptera), Fliegen (Diptera) und Zikaden (Auchenorrhynchae)
DE10141618A1 (de) Fungizide Wirkstoffkombinationen
EP2175723A1 (fr) Utilisation de dérivés d'acide tétramique pour lutter contre des vecteurs transmettant des virus
WO2011131623A1 (fr) Composition insecticide et/ou herbicide à action améliorée, à base de dérivés d'acide tétramique à substituants spirohétérocycliques
CH666990A5 (de) Verfahren zur herstellung eines pflanzenbehandlungsmittels.
EP2242363A1 (fr) Utilisation de dérivés d acide tétramique pour la lutte contre les animaux nuisibles par des traitements du tronc, des branches, de l inflorescence et des bourgeons
DE102004021566A1 (de) Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
MXPA06010031A (en) Oil-based suspension concentrates

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2005731791

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 4936/DELNP/2006

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 177742

Country of ref document: IL

WWE Wipo information: entry into national phase

Ref document number: CR2006-008589

Country of ref document: CR

WWE Wipo information: entry into national phase

Ref document number: 2006/07335

Country of ref document: ZA

Ref document number: 2558421

Country of ref document: CA

Ref document number: 200607335

Country of ref document: ZA

WWE Wipo information: entry into national phase

Ref document number: PA/a/2006/010031

Country of ref document: MX

Ref document number: 12006501721

Country of ref document: PH

WWE Wipo information: entry into national phase

Ref document number: 2007501227

Country of ref document: JP

Ref document number: 2005220024

Country of ref document: AU

Ref document number: 06088728

Country of ref document: CO

WWE Wipo information: entry into national phase

Ref document number: 200580007232.9

Country of ref document: CN

NENP Non-entry into the national phase

Ref country code: DE

WWW Wipo information: withdrawn in national office

Ref document number: DE

ENP Entry into the national phase

Ref document number: 2005220024

Country of ref document: AU

Date of ref document: 20050304

Kind code of ref document: A

WWP Wipo information: published in national office

Ref document number: 2005220024

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 1020067020378

Country of ref document: KR

WWP Wipo information: published in national office

Ref document number: 2005731791

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1020067020378

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 10591128

Country of ref document: US

ENP Entry into the national phase

Ref document number: PI0508526

Country of ref document: BR

WWP Wipo information: published in national office

Ref document number: 10591128

Country of ref document: US

WWG Wipo information: grant in national office

Ref document number: 2005731791

Country of ref document: EP