WO2005083819A3 - Batterie au lithium protegee dans le cas d’une utilisation inappropriee - Google Patents

Batterie au lithium protegee dans le cas d’une utilisation inappropriee Download PDF

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Publication number
WO2005083819A3
WO2005083819A3 PCT/FR2005/000252 FR2005000252W WO2005083819A3 WO 2005083819 A3 WO2005083819 A3 WO 2005083819A3 FR 2005000252 W FR2005000252 W FR 2005000252W WO 2005083819 A3 WO2005083819 A3 WO 2005083819A3
Authority
WO
WIPO (PCT)
Prior art keywords
additive
battery
lithium battery
protected
case
Prior art date
Application number
PCT/FR2005/000252
Other languages
English (en)
Other versions
WO2005083819A2 (fr
Inventor
Audrey Martinent
Sebastien Martinet
Helene Lignier
Djamel Mourzagh
Original Assignee
Commissariat Energie Atomique
Audrey Martinent
Sebastien Martinet
Helene Lignier
Djamel Mourzagh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat Energie Atomique, Audrey Martinent, Sebastien Martinet, Helene Lignier, Djamel Mourzagh filed Critical Commissariat Energie Atomique
Priority to EP05717555A priority Critical patent/EP1714340A2/fr
Priority to JP2006552653A priority patent/JP2007522628A/ja
Priority to US10/585,922 priority patent/US20070259259A1/en
Publication of WO2005083819A2 publication Critical patent/WO2005083819A2/fr
Publication of WO2005083819A3 publication Critical patent/WO2005083819A3/fr
Priority to US12/852,183 priority patent/US20100297480A1/en

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/16Cells with non-aqueous electrolyte with organic electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566Liquid materials
    • H01M10/0567Liquid materials characterised by the additives
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/08Selection of materials as electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581Chalcogenides or intercalation compounds thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/58Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/14Cells with non-aqueous electrolyte
    • H01M6/16Cells with non-aqueous electrolyte with organic electrolyte
    • H01M6/162Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
    • H01M6/168Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by additives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Une batterie au lithium comporte au moins une électrode positive comportant un matériau ayant un potentiel d'insertion et de désinsertion du lithium inférieur ou égal à 3,5 Volts par rapport au potentiel du couple Li+/Li, une électrode négative et un électrolyte non-aqueux disposé entre les électrodes positive et négative. L'électrolyte comporte au moins un sel de lithium dissous dans un solvant organique aprotique dans lequel est ajouté un additif polymérisable choisi parmi le carbazole et ses dérivés et destiné à bloquer le fonctionnement de la batterie dès que la tension aux bornes de la batterie atteint une valeur provoquant la polymérisation de l'additif.
PCT/FR2005/000252 2004-02-12 2005-02-04 Batterie au lithium protegee dans le cas d’une utilisation inappropriee WO2005083819A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP05717555A EP1714340A2 (fr) 2004-02-12 2005-02-04 BATTERIE AU LITHIUM PROTEGEE DANS LE CAS D’UNE UTILISATION INAPPROPRIEE
JP2006552653A JP2007522628A (ja) 2004-02-12 2005-02-04 不適切使用時に保護されるリチウム電池
US10/585,922 US20070259259A1 (en) 2004-02-12 2005-02-04 Lithium Battery Which is Protected in Case of Inappropriate Use
US12/852,183 US20100297480A1 (en) 2004-02-12 2010-08-06 Lithium battery which is protected in case of inappropriate use

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0401404A FR2866478A1 (fr) 2004-02-12 2004-02-12 Batterie au lithium protegee dans le cas d'une utilisation inappropriee
FR0401404 2004-02-12

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/852,183 Continuation US20100297480A1 (en) 2004-02-12 2010-08-06 Lithium battery which is protected in case of inappropriate use

Publications (2)

Publication Number Publication Date
WO2005083819A2 WO2005083819A2 (fr) 2005-09-09
WO2005083819A3 true WO2005083819A3 (fr) 2006-06-01

Family

ID=34803317

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2005/000252 WO2005083819A2 (fr) 2004-02-12 2005-02-04 Batterie au lithium protegee dans le cas d’une utilisation inappropriee

Country Status (7)

Country Link
US (2) US20070259259A1 (fr)
EP (1) EP1714340A2 (fr)
JP (1) JP2007522628A (fr)
KR (1) KR20070001129A (fr)
CN (2) CN1918733A (fr)
FR (1) FR2866478A1 (fr)
WO (1) WO2005083819A2 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9444120B2 (en) * 2005-12-21 2016-09-13 Samsung Sdi Co., Ltd. Rechargeable lithium battery and method for manufacturing the same
JP2009272170A (ja) * 2008-05-08 2009-11-19 Sanyo Electric Co Ltd 非水電解質二次電池
EP2629353A1 (fr) * 2012-02-17 2013-08-21 Belenos Clean Power Holding AG Batterie secondaire non aqueuse dotée d'un matériau actif à cathode mélangée
KR101507305B1 (ko) * 2013-03-07 2015-04-01 두산중공업 주식회사 원통형 멤브레인 월 제작 방법
DE112015003328T5 (de) 2014-07-18 2017-04-13 Board Of Trustees Of Michigan State University Wiederaufladbare Lithiumionenzelle mit einem Redox-Shuttle-Additiv
US11094964B2 (en) 2016-11-22 2021-08-17 Board Of Trustees Of Michigan State University Rechargeable electrochemical cell
US11545691B2 (en) 2017-07-20 2023-01-03 Board Of Trustees Of Michigan State University Redox flow battery
CN114899478A (zh) * 2022-05-18 2022-08-12 湖南大学 一种咔唑非水电解液及其制备方法及锂离子电池

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0827230A2 (fr) * 1996-09-03 1998-03-04 Fuji Photo Film Co., Ltd. Batterie secondaire à ions lithium contenant un électrolyte non-aqueux
CN1385918A (zh) * 2002-05-22 2002-12-18 哈尔滨光宇电源集团股份有限公司 用于锂离子电池的新型电解液
US20030099886A1 (en) * 2001-10-20 2003-05-29 Samsung Sdi Co., Ltd. Nonaqueous electrolyte composition for improving overcharge safety and lithium battery using the same
EP1317013A1 (fr) * 2001-07-10 2003-06-04 Mitsubishi Chemical Corporation Electrolyte non aqueux et cellule secondaire faisant appel a cet electrolyte

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4857423A (en) * 1987-11-30 1989-08-15 Eic Labotatories, Inc. Overcharge protection of secondary, non-aqueous batteries
EP0614239A3 (fr) * 1993-03-01 1996-10-16 Tadiran Ltd Pile secondaire non-aqueuse à dispositif de sécurité.
JP3787923B2 (ja) * 1996-11-07 2006-06-21 宇部興産株式会社 非水電解液二次電池
CA2205683C (fr) * 1997-05-16 2001-05-15 Moli Energy (1990) Limited Additifs polymerisables pour rendre securitaires apres surcharge les batteries au lithium rechargeables a electrolyte non aqueux
CA2216898C (fr) * 1997-09-26 2005-03-22 Moli Energy (1990) Limited Additifs ameliores pour la protection contre la surcharge des piles rechargeables au lithium, non aqueuses
JP4211124B2 (ja) * 1998-12-16 2009-01-21 株式会社日本自動車部品総合研究所 点火プラグ
JP3402237B2 (ja) * 1999-01-20 2003-05-06 日本電池株式会社 非水電解質二次電池
JP4296580B2 (ja) * 2000-01-11 2009-07-15 株式会社ジーエス・ユアサコーポレーション 非水電解質リチウム二次電池
JP4151210B2 (ja) * 2000-08-30 2008-09-17 ソニー株式会社 正極活物質及びその製造方法、並びに非水電解質電池及びその製造方法
CA2327370A1 (fr) * 2000-12-05 2002-06-05 Hydro-Quebec Nouvelle methode de fabrication de li4ti5o12 pur a partir du compose ternaire tix-liy-carbone: effet du carbone sur la synthese et la conductivite de l'electrode
JP2002359002A (ja) * 2001-05-30 2002-12-13 Mitsubishi Chemicals Corp 非水系電解液二次電池及びそれに用いる非水系電解液

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0827230A2 (fr) * 1996-09-03 1998-03-04 Fuji Photo Film Co., Ltd. Batterie secondaire à ions lithium contenant un électrolyte non-aqueux
EP1317013A1 (fr) * 2001-07-10 2003-06-04 Mitsubishi Chemical Corporation Electrolyte non aqueux et cellule secondaire faisant appel a cet electrolyte
US20030099886A1 (en) * 2001-10-20 2003-05-29 Samsung Sdi Co., Ltd. Nonaqueous electrolyte composition for improving overcharge safety and lithium battery using the same
CN1385918A (zh) * 2002-05-22 2002-12-18 哈尔滨光宇电源集团股份有限公司 用于锂离子电池的新型电解液

Non-Patent Citations (1)

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Also Published As

Publication number Publication date
FR2866478A1 (fr) 2005-08-19
US20100297480A1 (en) 2010-11-25
CN102299379A (zh) 2011-12-28
KR20070001129A (ko) 2007-01-03
EP1714340A2 (fr) 2006-10-25
JP2007522628A (ja) 2007-08-09
CN1918733A (zh) 2007-02-21
US20070259259A1 (en) 2007-11-08
WO2005083819A2 (fr) 2005-09-09

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