WO2005080608A1 - Direct smelting plant and process - Google Patents

Direct smelting plant and process Download PDF

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Publication number
WO2005080608A1
WO2005080608A1 PCT/AU2005/000236 AU2005000236W WO2005080608A1 WO 2005080608 A1 WO2005080608 A1 WO 2005080608A1 AU 2005000236 W AU2005000236 W AU 2005000236W WO 2005080608 A1 WO2005080608 A1 WO 2005080608A1
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WO
WIPO (PCT)
Prior art keywords
stove
air
during
stoves
hot blast
Prior art date
Application number
PCT/AU2005/000236
Other languages
English (en)
French (fr)
Inventor
Philip James Ions
Original Assignee
Technological Resources Pty. Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AU2004900893A external-priority patent/AU2004900893A0/en
Application filed by Technological Resources Pty. Limited filed Critical Technological Resources Pty. Limited
Priority to BRPI0507975-6A priority Critical patent/BRPI0507975B1/pt
Priority to AU2005215826A priority patent/AU2005215826B2/en
Priority to UAA200609900A priority patent/UA83543C2/ru
Publication of WO2005080608A1 publication Critical patent/WO2005080608A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L15/00Heating of air supplied for combustion
    • F23L15/02Arrangements of regenerators
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B11/00Making pig-iron other than in blast furnaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B9/00Stoves for heating the blast in blast furnaces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/34Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/32Technologies related to metal processing using renewable energy sources

Definitions

  • the present invention relates to a direct smelting plant and a direct smelting process for producing molten metal from a metalliferous feed material such as ores , partly reduced ores and me al-containing waste streams.
  • melting is herein understood to mean thermal processing wherein chemical reactions that reduce metalliferous feed material take place to produce molten metal.
  • a known direct smelting process which relies principally on a molten bath as a reaction medium, and is generally referred to as the Hlsmelt process, is described in International application PCT/AU96/00197 (WO 96/31627) and other patent applications , such as the more recently filed International applications PCT/AU2004/000473 (WO2004/090174) and PCT/AU2004/000472 (WO2004/090173) (which focuses on producing molten iron from iron ore fines) in the name of the applicant.
  • the Hlsmelt process includes the steps of:
  • a metalliferous feed material typically metal oxides
  • a solid carbonaceous material typically coal, which acts as a reductant of the metalliferous feed material and a source of energy; and (c) smelting the metalliferous feed material to metal in the metal layer.
  • the metalliferous feed material and solid carbonaceous material are injected into the molten bath through solids delivery means in the form of lances which are inclined to the vertical so as to extend downwardly and inwardly through the side wall of the direct smelting vessel and into a lower region of the vessel so as to deliver at least part of the solids material into the metal layer in the bottom of the vessel.
  • the Hlsmelt process also includes post-combusting reaction gases, such as CO and H 2 released from the bath, with a blast of hot air, which may be oxygen-enriched, that is injected into an upper region of the vessel through at least one downwardly extending hot air injection lance and transferring the heat generated by the post-combustion to the bath to contribute to the thermal energy required to smelt the metalliferous feed materials .
  • reaction gases such as CO and H 2 released from the bath
  • the hot air is produced in stoves and is supplied to the lance or lances via a refractory brick-lined hot blast main.
  • the stoves consist of at least two individual stoves that cycle between two phases, a heating phase and a heat exchange phase.
  • a stove provides hot air at greater than 1000°C (herein after called "pre-heated air") to the hot air injection lance, and in the heating phase the stove regenerates the heat within its internal construction via combustion of a fuel and passing combustion products through the stove.
  • pre-heated air the hot air injection lance
  • the operation of the stoves is coordinated so that there is always at least one stove in its heat exchange phase and providing pre-heated air at any point in time.
  • Off-gases resulting from the post-combustion of reaction gases in the vessel are taken away from the upper part of the vessel through an off-gas duct.
  • the vessel includes refractory-lined water cooled panels in the side wall and the roof of the vessel, and water is circulated continuously through the panels in a continuous circuit.
  • the Hlsmelt process enables large quantities of molten metal, such as molten iron, to be produced by direct smelting in a single compact vessel.
  • the supply of solid feed materials and pre-heated air to the direct smelting vessel must continue throughout a smelting campaign, which desirably is at least 12 months, and it is important that the supply of these materials be provided reliably during the period of a smelting campaign.
  • the direct smelting vessel is shut-down to allow maintenance work, which typically includes a partial re-line or a complete re-line of the internal refractory lining of the vessel.
  • the shut-down period may vary considerably depending on the circumstances, ranging from periods as short as 1 month to considerably longer periods. Typically, the shut-down periods will be 8 weeks . Preferably the shut-down period is the shortest possible time.
  • the gas used as a fuel during normal operation of stoves is usually off-gas from the smelting vessel, and this is typically not available during a shutdown.
  • the present invention provides a cost effective and reliable process and plant for maintaining the stoves and the hot blast main during a shut-down of a direct smelting vessel.
  • the present invention provides a process and an apparatus that maintains stoves and a hot blast main that connects the stoves to a hot air (or hot oxygen-enriched air) injection lance or lances of a direct smelting vessel during the course of a shut-down of the vessel .
  • the process maintains the temperatures of the stoves and the hot blast main within temperature ranges that minimise damage to the stoves and the hot blast main.
  • a process for maintaining stoves and a hot blast main that connects the stoves to a hot air (or hot oxygen- enriched air) injection lance or lances of a direct smelting vessel in a hot state during the course of a shutdown of the vessel, which process comprises:
  • the main objective is to ensure that the stoves and the hot blast main are maintained within operating temperature ranges that avoid damage to the stoves and the hot blast main.
  • this objective can be achieved by operating the stoves during a shut-down to create significantly different heat transfer conditions than the heat transfer conditions that are required during normal operation of the stoves to supply a hot air blast to the direct smelting vessel.
  • the applicant has realised further that the volumetric flow rates of combustion products and hot air through the stoves are important factors in creating the required heat transfer conditions during a shut-down.
  • the volumetric flow rates of combustion products and hot air through the stoves can be delivered by the combustion air fan that is used conventionally to supply combustion air to the burner of a stove for the heating phase of the stove.
  • the combustion air fan can be used advantageously as a dual function fan to supply air for the heating phase and the heat exchange phase during a shut-down.
  • a modified construction of the hot blast main is advantageous to optimise maintaining the stoves and the hot blast main during a shut-down.
  • the process includes coordinating operation of the heating phase and the heat exchange phase of each stove during the shut-down so that the stoves supply a continuous hot air stream to the hot blast main during the shut-down.
  • the volumetric flow rate of the combustion products produced in step (b) during the shutdown is relatively small compared to the volumetric flow rate of the combustion products produced during heating phases of the stoves when the stoves are operating under normal operating conditions with the hot blast main connected to the hot air injection lance or lances.
  • the volumetric flow rate of the combustion products produced in step (b) during the shutdown is 50% or less of the volumetric flow rate of the combustion products produced during the normal heating phases of the stoves .
  • volumetric flow rate of the combustion products produced in step (b) during the shut- down is 40% or less of the volumetric flow rate of the combustion products produced during the normal heating phases of the stoves .
  • the volumetric flow rate of the hot air produced in step (c) during the shut-down is relatively small compared to the volumetric flow rate of the hot air produced during heat exchange phases of the stoves when the stoves are operating under normal operating conditions with the hot blast main connected to the hot air injection lance or lances.
  • the volumetric flow rate of the hot air produced in step (c) during the shut-down is 50% or less of the volumetric flow rate of the hot air produced during the normal heat exchange phases of the stoves . More preferably the volumetric flow rate of the hot air produced in step (c) during the shut-down is 40% or less of the volumetric flow rate of the hot air produced during the normal heat exchange phases of the stoves .
  • the process includes using the same fan or fans to supply the streams of air to each stove during the heating and the heat exchange phases of the stove during the shutdown.
  • the hot air produced in step (c) vents through a vent means connected to the hot blast main.
  • vent means is located proximate a forward end of the hot blast main, ie the end that is connected to the hot air injection lance or lances.
  • the fuel gas is natural gas .
  • the process may comprise additional steps during the shut-down to the above-described steps.
  • the process may comprise a further step of transferring heat from one or more of the stoves by supplying a stream of air to the opposite end of the gas pathway of the stove or stoves and thereafter successively passing the air stream through the gas pathway and thereafter venting the air stream without passing the air stream through the hot blast main, whereby the air stream is heated by heat exchange with refractory checkerwork of the stove or stoves and the stove or stoves is cooled by such heat exchange.
  • This process step is appropriate in situations where the temperature of the hot blast main is within a suitable temperature range and further heat transfer to the main is not required and the stove or stoves in question are above a minimum shut-down temperature and can accommodate further heat transfer to the air stream.
  • this process step includes venting the hot air stream from the stove or stoves by passing the stream through off gas supply mains for the stove or stoves .
  • the process may comprise a further step of "bottling" one or more of the stoves altogether for a time period during the shut-down.
  • this process step is appropriate in situations where the temperature of the hot blast main is within a suitable temperature range and further heat transfer to the main is not required at that time and the stove or stoves in question are above a minimum shut-down temperature .
  • the duration of the above- described process steps during the shut-down will be determined by reference to a range of factors , including the factors discussed in the following paragraphs .
  • each stove has a main heat exchange chamber that is packed with refractory checkerwork and the said opposite end section of the gas pathway is in a lower section of the chamber and extends in a tortuous path upwardly through the checkerwork.
  • the checkerwork is supported on a metal grid in the lower section of the chamber .
  • the process includes operating the heating phase of each stove during the shut-down until the temperature in the lower section of the main chamber, and more preferably the checkerwork support grid, approaches but does not reach a temperature at which the checkerwork support grid loses appreciable mechanical strength.
  • the checkerwork support grid is formed from cast iron. Cast iron starts to lose mechanical strength to an extent that is cause for concern at temperatures above 350°C.
  • the process includes operating the heating phase of each stove during the shut-down until the temperature in the lower section of the main chamber of the stove approaches but does not reach 350°C.
  • each stove typically includes a dome section that is lined with silica bricks .
  • Silica bricks undergo a phase change at 875°C that results in a volume change and is undesirable on this basis to cool the dome section to temperatures at or below the phase change temperature during the shut-down.
  • the process includes controlling the process during the shut-down so that the temperature of the dome section of the stove or stoves remains above the phase change temperature .
  • the hot blast main includes a plurality of refractory brick lined sections and a plurality of expansion joints that interconnect the bricked sections.
  • thermal cycling can cause damage to the brickwork and the joints and is undesirable on this basis.
  • the process includes controlling the process during the shut-down so that there is minimal temperature cycling within the hot blast main.
  • an apparatus for pre-heating air for a direct smelting plant for producing molten metal from a metalliferous feed material which apparatus comprises : (a) a plurality of stoves for producing streams of pre-heated air for a direct smelting plant;
  • a hot blast main for supplying pre-heated air from the stoves to a gas injection means extending into a direct smelting vessel when the plant is operating and producing molten metal from a metalliferous feed material in the vessel when the plant is operating under normal operating conditions;
  • a fuel gas supply means for supplying fuel gas to a burner of each stove during normal operating conditions of the plant and during a shut-down of the vessel;
  • a first air supply means for supplying air (i) to the burner of each stove during a heating phase of the stove during normal operating conditions of the plant, and (ii) to the burner of each stove during a heating phase of the stove during a shut-down of the vessel ;
  • the vent includes an end plug that closes an outlet end of the vent when a direct smelting process is operating and is removed from the vent when there is a shut-down of the vessel.
  • the vent defines a serpentine pathway between the hot blast main and the outlet end of the vent.
  • the purpose of the serpentine pathway is to avoid straight line exposure of the end plug to radiant heat from the hot blast main during operation of a direct smelting process when the plug is in place and closes the outlet end.
  • the vent extends horizontally outwardly from the hot blast main and then upwardly and inwardly to a position above the hot blast main and thereafter upwardly to the outlet end.
  • the vent is located proximate a forward end of the hot blast main, ie the end that is connected to the hot air injection lance or lances.
  • the first air supply means is adapted to supply air to a separate inlet of each stove during a heat exchange phase of the stove during a shut-down of the vessel when the second air supply means is not operational .
  • the apparatus comprises a valve means enables the first air supply means to switch from supplying air to the burner of each stove to the separate inlet of the stove as required during a shut-down of the vessel .
  • a direct smelting plant for producing molten metal from a metalliferous feed material which comprises : (a) a direct smelting vessel to hold a molten bath of metal and slag and a gas space above the bath;
  • an off-gas duct means for facilitating flow of off-gas from the vessel away from the vessel ;
  • a metal and slag tapping means for tapping molten metal and slag from the bath and transporting that molten metal away from the vessel; and
  • the above-described apparatus for preheating air or the vessel .
  • Figure 1 is a diagram that illustrates the main components of one embodiment of a direct smelting plant in accordance with the present invention that are relevant to the description of the embodiment;
  • Figure 2 is a side elevation of the direct smelting vessel of the above plant
  • Figure 3 is a vertical section through the hot blast main and the vent of the main of the above plant, with the vent arranged for operation of a direct smelting process
  • Figure 4 is a vertical section through the hot blast main and the vent of the main of the above plant, with the vent arranged for shut-down of the plant;
  • Figure 5 is a vertical section through the stove of the above plant.
  • Figure 6 is a diagram that illustrates the main components of another embodiment of a direct smelting plant in accordance with the present invention that are relevant to the description of the embodiment.
  • the direct smelting plant shown in the Figures includes a direct smelting vessel 11, two stoves 27 for producing streams of hot air, a hot blast main 29 for supplying the hot air streams from the stoves 27 to the vessel 11, a cold blast blower 31, cold blast supply main 38 and cold blast transfer lines 37 for supplying air at pressure to the stoves 27 during normal operation of the stoves 27, two combustion air fans 35 and combustion air transfer lines 39a and 39b for supplying air at ambient temperature and pressure to the stoves 27 during both normal operation of the vessel and also during a shut-down of the vessel 11.
  • the transfer lines 37, 39a and 39b include control valves to control flow of air through the lines .
  • the vessel 11 is of the type described in detail in the above-mentioned International applications PCT/AU2004/000473 (WO2004/090174) and PCT/AU2004/000472 (WO2004/090173) , and the disclosure in the patent specifications lodged with these applications is incorporated herein by cross-reference.
  • the vessel 11 has a hearth 13 , a generally cylindrical barrel 15 extending upwardly from the hearth, an annular roof 17, an off-gas chamber 19, an off-gas duct 21 for discharging off- gases, a forehearth 23 for discharging molten metal continuously, and a tap-hole (not shown) for discharging molten slag during smelting.
  • the vessel 11 also includes a hot air injection lance 41 for delivering a hot air blast into an upper region of the vessel 11.
  • the lance is positioned centrally to extend downwardly through the off-gas chamber 19 into an upper region of the barrel 15. Only an upper section of the hot air injection lance 41 is visible in Figure 2.
  • the lance is connected to the hot blast main 29.
  • the vessel 11 also includes a plurality of solids injection lances (not shown) extending downwardly and inwardly through openings (not shown) in the side walls of the lower barrel 15 for injecting iron ore fines, solid carbonaceous material, and fluxes entrained in an oxygen-deficient carrier gas into the vessel.
  • the off-gas duct 21 of the vessel 11 transports the off-gas away from the vessel 11.
  • the off-gas is split into two streams, with one stream going to the stoves 27 and the other stream going to a treatment station (not shown) for preheating the iron ore fed to the vessel 11.
  • the off-gas duct 21 includes a gently inclined first section 21a extending from the upper barrel 19 of the vessel 11 and a vertically extending second section 21b that extends from the first section 21a.
  • the hot blast main 29 is a refractory brick lined main that, typically at least is 75m long, of circular cross-section - as shown in Figures 2 to 4.
  • the hot blast main 29 includes a vent 61 near the downstream end thereof, proximate the hot air injection lance 41.
  • Figure 3 illustrates the vent 61 as it is arranged for operation of the Hlsmelt process and Figure 4 illustrates the vent 61 as it is arranged during a shut- down of the Hlsmelt process.
  • the Figure 3 arrangement includes an end plug 91 that seals the vent 61 during operation of the Hlsmelt process and the Figure 4 arrangement includes an elbow section 93 that replaces the end plug 91 during a shut-down period.
  • the purpose of the elbow section 93 is to direct hot air flow from the vent 61 away from equipment in the vicinity of the vent and to prevent water flow into the vent 61.
  • a blanking plate (not shown) is typically installed into the hot blast main 29 adjacent the hot air blast lance 41 during a shut down of the Hlsmelt process.
  • the blanking plate serves to isolate the hot blast main 29 from the hot air blast lance 41 and thereby ensures that the entire hot air flow supplied to the hot blast main during a shut-down of the vessel, as described hereinafter, flows through vent 61.
  • the vent 61 defines a serpentine pathway for hot air to flow from the hot blast main 29 to atmosphere during non-operation of the vessel .
  • the purpose of the serpentine pathway is to avoid straight line exposure of the end plug 91 to radiant heat from the hot blast main 29 during operation of the Hlsmelt process when the plug 91 is in place.
  • the vent 61 includes a U-shaped section that has one arm 68 that extends horizontally outwardly from the hot blast main 27, a base 65 that extends vertically upwardly, and another arm 67 that extends horizontally inwardly to a position above the hot blast main 27.
  • the vent 61 also includes a vertical section 69 that extends upwardly from the arm 67 of the U-shaped section.
  • the arm 68 and half of the base 65 of the U-shaped section of the vent 61 are lined with refractory bricks .
  • the remainder of the vent 61 includes a lining of a castable material .
  • the vessel 11 contains a molten bath of iron and slag which includes a layer of molten metal and a layer of molten slag on the metal layer.
  • a suitable carrier gas transports iron ore fines , coal and flux into the molten bath through the solids injection lances.
  • the momentum of the solid materials and the carrier gas causes the solid materials to penetrate the metal layer in the vessel 11.
  • the coal is devolatilised and thereby produces gas in the metal layer. Carbon partially dissolves in the metal and partially remains as solid carbon.
  • the ore fines are smelted to metal and the smelting reaction generates carbon monoxide.
  • the gases transported into the metal layer and generated by devolatilisation and smelting reactions produce significant buoyancy uplift of molten metal, solid carbon and slag (drawn into the metal layer as a consequence of solid/gas injection) that generates upward movement of splashes, droplets and streams of molten metal, solid carbon, and slag. These splashes, droplets and streams entrain slag as they move through the slag layer.
  • the buoyancy uplift of molten metal, solid carbon and slag causes substantial agitation of the slag layer in the vessel, with the result that the slag layer expands in volume.
  • the upward movement of splashes, droplets and streams of molten metal, solid carbon and slag extend into the space above the molten bath and form a transition zone.
  • Injection of the hot air via the hot air injection lance 41 post-combusts reaction gases, such as carbon monoxide and hydrogen (which are liberated during coal devolatilisation and smelting reactions) , in the upper part of the vessel.
  • reaction gases such as carbon monoxide and hydrogen (which are liberated during coal devolatilisation and smelting reactions)
  • Off-gases resulting from the post- combustion of reaction gases in the vessel are taken away from the upper part of the vessel through the off-gas duct 21.
  • Hot metal produced during a smelting operation is discharged from the vessel 11 through a metal tapping system that includes the forehearth 23.
  • Post-combustion of reaction gases generates substantial heat and a proportion of the heat transfers to the splashes, droplets and streams of molten metal, solid carbon and slag and the heat transfers to the molten bath when the splashes droplets and streams return to the bath.
  • the transferred heat to the bath facilitates the endothermic smelting reactions in the bath.
  • each stove 27 is of a conventional form and includes a burner (not shown) and an upright cylindrical structure (with a domed top 81) formed from an outer metal shell 83 and a refractory brick internal lining 85 and an internal vertical partition 87 that divides the structure into a combustion chamber 51 on one side of the partition and a main heat exchange chamber 57 on the other side of the partition .
  • the heat exchange chamber 57 and the combustion chamber 51 are interconnected by a domed section 55. Together, the heat exchange chamber 57, the domed section 55, and the combustion chamber 51 define a gas pathway through the stove.
  • each stove 27 when the vessel 11 is smelting, the burner produces a stream of combustion products which pass to the combustion chamber 51 and flow upwardly through the combustion chamber 51 into the domed section 55 of the stove 27.
  • the combustion products then flow downwardly through a network of refractory checkerwork in the main heat exchange chamber 57 of the stove 27 and heat the checkers.
  • the now-cooler combustion products flow from the stove 27 via an opening 59 in a lower section of the heat exchange chamber 57.
  • the lower section of the heat exchange chamber 57 is formed as a plenum chamber 64 to facilitate gas flow.
  • the stove 27 includes a horizontally- disposed grid 63 supported by columns 65 that supports the checkers .
  • the grid 63 and the columns 65 are formed from cast iron.
  • each stove 27 In a heat exchange phase of each stove 27 when the vessel 11 is smelting, the burner is not operated and a stream of air is directed through the stove 27 in the opposite direction to the stream of combustion products .
  • air is supplied to the opening 59 in the stove 27 and flows upwardly from the plenum chamber 64 through the heat exchange chamber 57.
  • the air stream is heated by heat exchange with the checkers as the air stream flows through the heat exchange chamber 57.
  • the hot air flows around the dome section 55 and downwardly through the combustion chamber 51 and leaves the chamber via hot blast opening 71 in a lower section of the combustion chamber 51.
  • the hot blast opening 71 is connected to the hot blast main 29.
  • cold blast air under pressure
  • Figure 1 air under pressure
  • hot blast air under pressure
  • the resulting stream of heated air that exits the stove 27 through hot blast opening 71 is referred to as “hot blast” or “hot air blast”.
  • the hot blast flows along the hot blast main 29 to the hot air injection lance 41 in the direct smelting vessel 11.
  • the Hlsmelt process requires a constant flow of hot blast at a temperature of 1200°C when the vessel 11 is smelting.
  • the refractory in the domed section 55 of each stove 27 is heated to temperatures above 1200°C during heating phases of each stove 27 so that the initial hot blast from the stove 7 has a temperature above the required 1200°C.
  • the cold blast is supplied to the stove 27 until its temperature drops to 1200°C, whereupon the stove re-enters the heating phase and hot blast is obtained from the other stove 27.
  • some of the cold blast is mixed with the hot blast via a mixing valve 43 (see the Figure 6 embodiment) so that the average temperature of the hot blast is the required 1200°C.
  • the cold blast blower 31 must be capable of producing a substantial flow rate of air to and then through the stoves 27 and along the hot blast main 29 to the hot air injection lance 41.
  • the stoves 27 and the hot blast main 29 must be substantial in size in order to accommodate the large flow rate of air.
  • the cold blast blower 31 delivers approximately 110,000 Nm 3 /h of air pressurised at approximately 170kPa (gauge) .
  • the cold blast may be enriched with approximately 30,000 Nm 3 /h of Oxygen so that the stoves produce approximately 140,000 Nm 3 /h of hot air that is supplied to the hot blast main and smelt reduction vessel during normal operation.
  • the combustion air fans deliver approximately 74,000 Nm 3 /h of air at a pressure of approximately 13kPa (gauge) .
  • the stoves 27 apso operate during a shut-down of the vessel 11 in order to maintain the temperature in the stoves 27 and the hot blast main 29.
  • each stove 27 operates with heating and heat exchange phases during a shut-down of the vessel. These phases maintain the temperature of the stoves 27 within a required temperature range and transfer heat to the hot blast main 29 to maintain the temperature of the hot blast main 29 within a required temperature range.
  • each stove 27 when the vessel 11 is shut-down (and there is no off-gas available as a source of energy) , natural gas is supplied to the burner from a source (not shown) via natural gas main 91 and a transfer line 93 and ambient temperature combustion air is supplied to the burner via the combustion air fan 35 and the transfer line 39b ( Figure 1) and the combustion products produced by the burner heat the stove 27.
  • the combustion products heat the domed section 55 of the stove 27 to temperatures of the order of 1250°C.
  • the heating phase continues until the temperature of the cast iron horizontally-disposed checker support grid 63 and columns 65 approaches but does not reach 350°C .
  • the basis for the selection of the temperature of 350°C is that cast iron starts to lose appreciable mechanical strength above this temperature .
  • each stove 27 during a shut-down of the vessel 11 the cold blast supplied to the opening 59 of the stove 27 via the cold blast blower 31 when the vessel 11 is smelting is replaced by air at ambient temperature and pressure.
  • This air is supplied to the transfer line 37 from the combustion air fan 35 for the stove 27 via the transfer line 39a ( Figure 1) .
  • the resulting hot air stream exits the stoves 27, via hot blast opening 71, and flows along the hot blast main 29 to the vent 61 from which it discharges .
  • the hot air stream heats the main 29 so that the temperature in the main 29 is above a predetermined minimum temperature.
  • the combustion air fan 35 delivers a sufficient flow rate of air to meet the heat transfer requirements during a shut-down.
  • the heat exhange phase continues until the dome section 55 of the stove cools to 900°C. At temperatures below this temperature silica bricks in the domed section 55 undergo a phase changes that results in an undesirable volume change of the bricks .
  • the timing of the heating and heat exchange phases for both stoves 27 during a shut-down are controlled so that there is no overlap of these phases and one stove 27 operates in the heating phase while the other stove operates in the heat exchange phase and vice versa.
  • the process also includes an optional step of diverting the heated air streams produced in the heat exchange phases of the stoves 27 away from the hot blast main 29 in situations where the main is within a required temperature range and further heating is not required.
  • the process also includes an optional step of bottling the stoves 27 altogether, again in situations where the stoves and the hot blast main 29 are within a required temperature range and further heating is not required.
  • Figure 6 illustrates an alternative, although not the only possible alternative embodiment, to the embodiment shown in Figure 1. Both embodiments include combustion air fans . However, in Figure 1 , the fans operate independently and supply separate combustion air transfer lines 39a and 39b. In Figure 6 the fans operate to supply a single combustion air main 42 which then feeds combustion air transfer lines 39a and 39b. This provides some redundancy in the combustion air system and allows for maintenance on the fans during a smelting campaign. It also allows the fans to operate in tandem so that a combined air flow can be provided.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Furnace Details (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
PCT/AU2005/000236 2004-02-23 2005-02-23 Direct smelting plant and process WO2005080608A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BRPI0507975-6A BRPI0507975B1 (pt) 2004-02-23 2005-02-23 Processo para manter regeneradores e um conduto principal de ar quente que conecta os regeneradores a uma ou mais lanças de injeção de ar quente de um vaso de fusão redutora direta e aparelho para pré-aquecer ar
AU2005215826A AU2005215826B2 (en) 2004-02-23 2005-02-23 Direct smelting plant and process
UAA200609900A UA83543C2 (ru) 2004-02-23 2005-02-23 Способ поддержания воздухонагревателей и трубопровода для горячего воздуха, устройство для предварительного нагревания воздуха и установка прямого плавления для получения жидкого металла из металлосодержащего плавильного материала

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AU2004900893A AU2004900893A0 (en) 2004-02-23 Stoves
AU2004900893 2004-02-23

Publications (1)

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WO2005080608A1 true WO2005080608A1 (en) 2005-09-01

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CN (1) CN100529109C (ru)
AU (1) AU2005215826B2 (ru)
BR (1) BRPI0507975B1 (ru)
RU (1) RU2368666C2 (ru)
UA (1) UA83543C2 (ru)
WO (1) WO2005080608A1 (ru)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007098551A1 (en) * 2006-03-01 2007-09-07 Technological Resources Pty. Limited Direct smelting plant

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5877513A (ja) * 1981-10-30 1983-05-10 Sumitomo Metal Ind Ltd 熱風炉の保温方法
JPS59193208A (ja) * 1983-04-14 1984-11-01 Nippon Steel Corp 熱風炉の保温方法
JPS59211516A (ja) * 1983-05-16 1984-11-30 Nippon Steel Corp 熱風炉の保温方法
JPS6256508A (ja) * 1985-09-06 1987-03-12 Kobe Steel Ltd 熱風炉保熱方法
JPH1112618A (ja) * 1997-06-20 1999-01-19 Kawasaki Steel Corp 高炉改修時の熱風弁保熱方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5877513A (ja) * 1981-10-30 1983-05-10 Sumitomo Metal Ind Ltd 熱風炉の保温方法
JPS59193208A (ja) * 1983-04-14 1984-11-01 Nippon Steel Corp 熱風炉の保温方法
JPS59211516A (ja) * 1983-05-16 1984-11-30 Nippon Steel Corp 熱風炉の保温方法
JPS6256508A (ja) * 1985-09-06 1987-03-12 Kobe Steel Ltd 熱風炉保熱方法
JPH1112618A (ja) * 1997-06-20 1999-01-19 Kawasaki Steel Corp 高炉改修時の熱風弁保熱方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007098551A1 (en) * 2006-03-01 2007-09-07 Technological Resources Pty. Limited Direct smelting plant
US8313690B2 (en) 2006-03-01 2012-11-20 Technological Resources Pty. Limited Direct smelting plant
US8318081B2 (en) 2006-03-01 2012-11-27 Technological Resources Pty. Limited Direct smelting plant
US8562903B2 (en) 2006-03-01 2013-10-22 Technological Resources Pty Limited Direct smelting plant
US8562902B2 (en) 2006-03-01 2013-10-22 Technologies Resources Pty Limited Direct smelting plant

Also Published As

Publication number Publication date
CN1922333A (zh) 2007-02-28
AU2005215826B2 (en) 2009-12-03
RU2368666C2 (ru) 2009-09-27
CN100529109C (zh) 2009-08-19
BRPI0507975A (pt) 2007-07-24
BRPI0507975B1 (pt) 2014-07-22
RU2006133907A (ru) 2008-03-27
UA83543C2 (ru) 2008-07-25
AU2005215826A1 (en) 2005-09-01

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