NZ626933B2 - Starting a smelting process - Google Patents

Starting a smelting process Download PDF

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Publication number
NZ626933B2
NZ626933B2 NZ626933A NZ62693312A NZ626933B2 NZ 626933 B2 NZ626933 B2 NZ 626933B2 NZ 626933 A NZ626933 A NZ 626933A NZ 62693312 A NZ62693312 A NZ 62693312A NZ 626933 B2 NZ626933 B2 NZ 626933B2
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NZ
New Zealand
Prior art keywords
forehearth
slag
main chamber
smelting
connection
Prior art date
Application number
NZ626933A
Other versions
NZ626933A (en
Inventor
Rodney James Dry
Hendrikus Koenraad Albertus Meijer
Jacques Pilote
Original Assignee
Tata Steel Limited
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Filing date
Publication date
Application filed by Tata Steel Limited filed Critical Tata Steel Limited
Priority claimed from PCT/AU2012/001487 external-priority patent/WO2013082659A1/en
Publication of NZ626933A publication Critical patent/NZ626933A/en
Publication of NZ626933B2 publication Critical patent/NZ626933B2/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B11/00Making pig-iron other than in blast furnaces
    • C21B11/08Making pig-iron other than in blast furnaces in hearth-type furnaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/0006Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state
    • C21B13/0013Making spongy iron or liquid steel, by direct processes obtaining iron or steel in a molten state introduction of iron oxide into a bath of molten iron containing a carbon reductant
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/28Increasing the gas reduction potential of recycled exhaust gases by separation
    • C21B2100/282Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/40Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
    • C21B2100/42Sulphur removal
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60Process control or energy utilisation in the manufacture of iron or steel
    • C21B2100/66Heat exchange
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/56Manufacture of steel by other methods
    • C21C5/567Manufacture of steel by other methods operating in a continuous way
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0087Treatment of slags covering the steel bath, e.g. for separating slag from the molten metal
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B5/00General methods of reducing to metals
    • C22B5/02Dry methods smelting of sulfides or formation of mattes
    • C22B5/10Dry methods smelting of sulfides or formation of mattes by solid carbonaceous reducing agents
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B5/00General methods of reducing to metals
    • C22B5/02Dry methods smelting of sulfides or formation of mattes
    • C22B5/12Dry methods smelting of sulfides or formation of mattes by gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B3/00Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
    • F27B3/10Details, accessories, or equipment peculiar to hearth-type furnaces
    • F27B3/105Slag chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B3/00Hearth-type furnaces, e.g. of reverberatory type; Tank furnaces
    • F27B3/10Details, accessories, or equipment peculiar to hearth-type furnaces
    • F27B3/22Arrangements of air or gas supply devices
    • F27B3/225Oxygen blowing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/15Tapping equipment; Equipment for removing or retaining slag
    • F27D3/1509Tapping equipment
    • F27D3/1536Devices for plugging tap holes, e.g. plugs stoppers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/16Introducing a fluid jet or current into the charge
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/18Charging particulate material using a fluid carrier
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27MINDEXING SCHEME RELATING TO ASPECTS OF THE CHARGES OR FURNACES, KILNS, OVENS OR RETORTS
    • F27M2003/00Type of treatment of the charge
    • F27M2003/13Smelting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/122Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Abstract

Disclosed is a method of starting a smelting process in a smelting vessel that includes a main chamber for smelting a metalliferous material and producing molten metal and a forehearth connected to the main smelting chamber via a forehearth connection. The smelting vessel contains frozen slag that blocks at least the forehearth connection. The method of starting the process includes heating frozen slag and forming molten slag and draining molten slag from the forehearth connection via the forehearth and establishing a clear flow path through the forehearth connection. Thereafter the smelting process is hot started by a series of steps including supplying a charge of molten metal into the main chamber via the forehearth connection and supplying feed materials to the process and smelting the metalliferous material and producing molten metal. The molten slag is removed via a forehearth end-drain taphole in a lowest region of the forehearth. The frozen slag in the forehearth connection is heated and melted via oxygen-enriched gas burners and/or oxygen lances. Where there is frozen slag in the main chamber, as well as frozen slag in the forehearth connection, the method includes heating and melting frozen slag in the main chamber and the forehearth connection. The frozen slag in the main chamber is heated and melted via heat from a burner system for the main chamber. locks at least the forehearth connection. The method of starting the process includes heating frozen slag and forming molten slag and draining molten slag from the forehearth connection via the forehearth and establishing a clear flow path through the forehearth connection. Thereafter the smelting process is hot started by a series of steps including supplying a charge of molten metal into the main chamber via the forehearth connection and supplying feed materials to the process and smelting the metalliferous material and producing molten metal. The molten slag is removed via a forehearth end-drain taphole in a lowest region of the forehearth. The frozen slag in the forehearth connection is heated and melted via oxygen-enriched gas burners and/or oxygen lances. Where there is frozen slag in the main chamber, as well as frozen slag in the forehearth connection, the method includes heating and melting frozen slag in the main chamber and the forehearth connection. The frozen slag in the main chamber is heated and melted via heat from a burner system for the main chamber.

Description

STARTING A SMELTING PROCESS TECHNICAL FIELD The present invention relates to a method of starting a process for smelting a metalliferous material.
The term "metalliferous material" is understood herein to include solid feed material and molten feed material. The term also includes within its scope partially reduced metalliferous material.
BACKGROUND ART The present invention relates more particularly, although by no means exclusively, to a method of starting a molten bath-based smelting process for producing molten metal from a metalliferous feed material in a smelting vessel that has a strong bath/slag fountain generated by gas evolution in the molten bath, with the gas evolution being at least partly the result of devolatilisation of carbonaceous material into the molten bath.
In particular, although by no means exclusively, the present invention relates to a method of starting a process for smelting an iron-containing material, such as an iron ore, and producing molten iron.
The present invention relates particularly, although by no means exclusively, to a method of starting a smelting process in a smelting vessel that includes a main chamber for smelting metalliferous material.
A known molten bath-based smelting process is generally referred to as the HIsmelt process, is described in a considerable number of patents and patent applications in the name of the applicant. 5414919_1 (GHMatters) P88706.NZ 7/09/15 Another molten bath-based smelting process is referred to hereinafter as the "HIsarna" process. The HIsarna process and apparatus are described in International application PCT/AU99/00884 (WO 00/022176) in the name of the applicant.
The HIsmelt process and the HIsarna processes are associated particularly with producing molten iron from iron ore or another iron-containing material.
In the context of producing molten iron, the HIsmelt process includes the steps (a) forming a bath of molten iron and slag in a main chamber of a smelting vessel; (b) injecting into the bath: (i) iron ore, typically in the form of fines; and (ii) a solid carbonaceous material, typically coal, which acts as a reductant of the iron ore feed material and a source of energy; and (c) smelting iron ore to iron in the bath.
The term "smelting" is herein understood to mean thermal processing wherein chemical reactions that reduce metal oxides take place to produce molten metal.
In the HIsmelt process solid feed materials in the form of metalliferous material and solid carbonaceous material are injected with a carrier gas into the molten bath through a number of lances which are inclined to the vertical so as to extend downwardly and inwardly through the side wall of the main chamber of the smelting vessel and into a lower region of the vessel so as to deliver at least part of the solid feed materials into the metal layer in the bottom of the main chamber. The solid feed materials and the carrier gas penetrate the molten bath and cause molten metal and/or slag to be projected into a space above the surface of the bath and form a transition zone. A blast of oxygen-containing gas, typically oxygen-enriched air or pure oxygen, is injected into an upper region of the main chamber of the vessel through a 5414919_1 (GHMatters) P88706.NZ 7/09/15 downwardly extending lance to cause post-combustion of reaction gases released from the molten bath in the upper region of the vessel. In the transition zone there is a favourable mass of ascending and thereafter descending droplets or splashes or streams of molten metal and/or slag which provide an effective medium to transfer to the bath the thermal energy generated by post-combusting reaction gases above the bath.
Typically, in the case of producing molten iron, when oxygen-enriched air is used, it is fed at a temperature of the order of 1200 °C and is generated in hot blast stoves. If technically pure cold oxygen is used, it is typically fed at or close to ambient temperature.
Off-gases resulting from the post-combustion of reaction gases in the smelting vessel are taken away from the upper region of the smelting vessel through an off-gas duct.
The smelting vessel includes refractory-lined sections in the lower hearth and water cooled panels in the side walls and the roof of the main chamber of the vessel, and water is circulated continuously through the panels in a continuous circuit.
The HIsmelt process enables large quantities of molten iron, typically at least 0.5 Mt/a, to be produced by smelting in a single compact vessel.
The HIsarna process is carried out in a smelting apparatus that includes (a) a smelting vessel that includes a main smelting chamber and lances for injecting solid feed materials and oxygen-containing gas into the main chamber and is adapted to contain a bath of molten metal and slag and (b) a smelt cyclone for pre-treating a metalliferous feed material that is positioned above and communicates directly with the smelting vessel.
The term "smelt cyclone" is understood herein to mean a vessel that typically defines a vertical cylindrical chamber and is constructed so that feed materials supplied to the chamber move in a path around a vertical central axis of the chamber and can 5414919_1 (GHMatters) P88706.NZ 7/09/15 withstand high operating temperatures sufficient to at least partially melt metalliferous feed materials.
In one form of the HIsarna process, carbonaceous feed material (typically coal) and optionally flux (typically calcined limestone) are injected into a molten bath in the main chamber of the smelting vessel. The carbonaceous material is provided as a source of a reductant and a source of energy. Metalliferous feed material, such as iron ore, optionally blended with flux, is injected into and heated and partially melted and partially reduced in the smelt cyclone. This molten, partly reduced metalliferous material flows downwardly from the smelt cyclone into the molten bath in the smelting vessel and is smelted to molten metal in the bath. Hot reaction gases (typically CO, CO , H , and H O) produced in the molten bath is partially combusted by oxygen- 2 2 2 containing gas (typically technical-grade oxygen) in an upper part of the main chamber.
Heat generated by the post-combustion is transferred to molten droplets in the upper section that fall back into the molten bath to maintain the temperature of the bath. The hot, partially-combusted reaction gases flow upwardly from the main chamber and enter the bottom of the smelt cyclone. Oxygen-containing gas (typically technical-grade oxygen) is injected into the smelt cyclone via tuyeres that are arranged in such a way as to generate a cyclonic swirl pattern in a horizontal plane, i.e. about a vertical central axis of the chamber of the smelt cyclone. This injection of oxygen-containing gas leads to further combustion of smelting vessel gases, resulting in very hot (cyclonic) flames.
Finely divided incoming metalliferous feed material is injected pneumatically into these flames via tuyeres in the smelt cyclone, resulting in rapid heating and partial melting accompanied by partial reduction (roughly 10-20% reduction). The reduction is due to both thermal decomposition of hematite and the reducing action of CO/H in the reaction gases from the main chamber. The hot, partially melted metalliferous feed material is thrown outwards onto the walls of the smelt cyclone by cyclonic swirl action and, as described above, flows downwardly into the smelting vessel below for smelting in the main chamber of that vessel.
The net effect of the above-described form of the HIsarna process is a two-step countercurrent process. Metalliferous feed material is heated and partially reduced by 5414919_1 (GHMatters) P88706.NZ 7/09/15 outgoing reaction gases form the smelting vessel (with oxygen-containing gas addition) and flows downwardly into the smelting vessel and is smelted to molten iron in the smelting vessel. In a general sense, this countercurrent arrangement increases productivity and energy efficiency.
The HIsmelt and the HIsarna processes include solids injection into molten baths in smelting vessels via water-cooled solids injection lances.
In addition, a key feature of both processes is that the processes operate in smelting vessels that include a main chamber for smelting metalliferous material and a forehearth connected to the main chamber via a forehearth connection that allows continuous metal product outflow from the vessels. A forehearth operates as a molten metal-filled siphon seal, naturally "spilling" excess molten metal from the smelting vessel as it is produced. This allows the molten metal level in the main chamber of the smelting vessel to be known and controlled to within a small tolerance – this is essential for plant safety. Molten metal level must (at all times) be kept at a safe distance below water-cooled elements such as solids injection lances extending into the main chamber, otherwise steam explosions become possible. It is for this reason that the forehearth is considered an inherent part of a smelting vessel for the HIsmelt and the HIsarna processes.
The term "forehearth" is understood herein to mean a chamber of a smelting vessel that is open to the atmosphere and is connected to a main smelting chamber of the smelting vessel via a passageway (referred to herein as a "forehearth connection") and, under standard operating conditions, contains molten metal in the chamber, with the forehearth connection being completely filled with molten metal.
The above description is not to be taken as an admission of the common general knowledge in Australia or elsewhere.
During the course of pilot plant trials of the HIsarna process it became necessary for the applicant to make an unscheduled end-tap of the smelting vessel used in the 5414919_1 (GHMatters) P88706.NZ 7/09/15 trials. Molten metal was removed successfully from the main chamber of the smelting vessel in the end-tap, but substantially all of the molten slag remained behind and solidified in the smelting vessel. This resulted in the main chamber, the forehearth connection and the forehearth of the smelting vessel being filled with cold (frozen) slag to a level above the level of the forehearth connection between the forehearth and the main chamber of the smelting vessel.
Standard process start-up for the HIsmelt process and the proposed process start-up for the HIsarna process involve establishing a molten metal bath in the smelting vessel by pouring a charge of fresh molten metal into the vessel via the forehearth and the forehearth connection. Before the pilot plant could be started again, it was therefore necessary to re-establish a clear connection between the forehearth and the smelting vessel. A standard option of allowing the entire system to cool down and then mechanically digging out frozen slag was considered by the applicant to be too time- consuming and therefore not a preferred option.
SUMMARY OF THE DISCLOSURE The present invention is based on a realisation that it is possible, in a shorter time than that associated with the cooling/mechanical slag removal option described above, to recover from such a frozen slag/blocked forehearth connection situation by using heat sources to melt slag and drain it out of the system via the forehearth and establish a clear flow path through the forehearth to make it possible to supply a charge of molten metal to the main chamber via the forehearth to re-start the process.
The present invention provides a method of starting (which term includes "re- starting") a smelting process in a smelting vessel that includes a main chamber for smelting a metalliferous material and producing molten metal and a forehearth connected to the main smelting chamber via a forehearth connection, and which smelting vessel contains frozen slag that blocks at least the forehearth connection, the method of starting the process including heating frozen slag and forming molten slag and draining molten slag from the forehearth connection via the forehearth and establishing a clear flow path through the forehearth connection and thereafter hot starting the smelting process by a series of steps including supplying a charge of molten 5414919_1 (GHMatters) P88706.NZ 7/09/15 metal into the main chamber via the forehearth connection and supplying feed materials to the process and smelting the metalliferous material and producing molten metal.
The method may include removing molten slag via a forehearth end-drain taphole in a lowest region of the forehearth.
The method may include pressurising the main chamber to facilitate draining molten slag from the forehearth connection.
The method may include heating and melting frozen slag in the forehearth connection via oxygen-enriched gas burners and/or oxygen lances.
In a situation in which there is frozen slag in the main chamber, as well as frozen slag in the forehearth connection, the method may include heating and melting frozen slag in the main chamber and the forehearth connection.
The method may include heating and melting frozen slag in the main chamber via heat from a burner system for the main chamber. The burner system may be a fuel gas burner system using either air or and oxygen-air mixture. The burner system may be a system used to pre-heat the main chamber during a standard process start-up.
In a situation in which there is frozen slag in the forehearth, as well as frozen slag in the forehearth connection, the method may include heating and melting frozen slag in the forehearth and the forehearth connection. The method may include using gas burners and/or oxygen lances to melt frozen slag in the forehearth.
In a situation in which there is frozen slag in the main chamber, the forehearth connection, and the forehearth, the method may include heating and melting frozen slag in the main chamber, the forehearth and the forehearth connection. The sequence of the heating steps may be selected as required depending on factors such as the amount of frozen slag in the main chamber and the size of the main chamber. For example, it may be preferable form a timing perspective to start heating and melting frozen slag in the main chamber before starting heating frozen slag in the forehearth. This may not always be the case.
For example, a situation in which there is frozen slag in the main chamber, the forehearth connection, and the forehearth, the method may include the steps of: 5414919_1 (GHMatters) P88706.NZ 7/09/15 (a) heating and melting frozen slag in the main chamber; (b) heating and melting frozen slag in the forehearth; (c) draining molten slag from the forehearth, (d) heating and melting frozen slag in the forehearth connection; (e) draining molten slag from the forehearth connection and the main chamber via the forehearth and establishing a clear flow path through the forehearth connection; and (f) hot starting the smelting process by a series of steps including supplying a charge of molten material into the main chamber via the forehearth connection and supplying feed materials to the process and smelting the metalliferous material and producing molten metal.
More particularly, the method may include the following steps. (i) Heating the main chamber (typically by the same means used to preheat it prior to initially charging hot metal) and melting frozen slag in the main chamber. This will usually involve a fuel gas burner system using either air or and oxygen-air mixture in the main chamber. The purpose of this heating step, under current conditions, is to create molten slag in the main chamber for later discharge via the forehearth. Since melting slag is relatively slow, this step is typically initiated first and executed in parallel with steps (ii) to (iv) below of heating and melting frozen slag in the forehearth and the forehearth connection. However, this may not always be the case, and there may be situations in which it is preferable to clear frozen slag from the forehearth and the forehearth connection before melting frozen slag in the main chamber. (ii) Heating a top (i.e. open) part of the forehearth using gas burners and/or oxygen lances. The purpose of this step is to generate molten slag in the main part of the forehearth. 5414919_1 (GHMatters) P88706.NZ 7/09/15 (iii) Draining molten slag from the forehearth end-drain taphole (i.e. a taphole at the lowest point in the forehearth cavity), thereby creating a substantially empty forehearth which allows direct access to the blocked forehearth connection between the forehearth and the main chamber. (iv) Applying heat to the blocked forehearth connection using oxygen- enriched gas burners and/or oxygen lances positioned to generate heat from the forehearth side of the forehearth connection, with the aim of melting and removing slag (via the forehearth end-drain taphole) from the forehearth connection area. This results in establishment of a path for molten slag in the main chamber to be drained. (v) Draining molten slag generated in step (i) from the main chamber via the forehearth end-drain taphole in sufficient quantity to re-establish a clear flow path through the forehearth connection and within the main chamber and the forehearth for charging fresh hot metal into the smelting vessel via the forehearth and the forehearth connection. This step may include pressurising the main chamber to facilitate draining molten slag from the forehearth connection. (vi) Starting the process by charging fresh hot metal into the main chamber via the forehearth and the forehearth connection and subsequent steps to re-start smelting in the main chamber.
The method may include adding lime or other materials to the main chamber and/or the forehearth to control the liquidus temperature of molten slag formed in the main chamber and/or the forehearth.
The steps to start the process in a situation in which the process is the HIsarna process may include: (a) preheating at least the main chamber of the smelting vessel, (b) adding a charge of a molten metal to the main chamber, (c) commencing supplying an oxygen-containing gas to the main chamber, (d) commencing supplying a carbonaceous material to the main chamber, 5414919_1 (GHMatters) P88706.NZ 7/09/15 (e) monitoring for ignition of the carbonaceous material, and (f) after establishing that ignition has occurred, commencing supplying a metalliferous feed material and an oxygen-containing gas into a smelt cyclone and generating a circulating flow of material in the cyclone and combusting a combustible gas flowing upwardly into the cyclone from the main chamber and partially reducing and melting the metalliferous feed material in the cyclone, whereby the partially reduced molten metalliferous feed material flows downwardly from the cyclone into the molten bath of metal and slag in the vessel and is smelted to molten metal in the bath.
After establishing that ignition has occurred, the steps to start the HIsarna process may include commencing supplying slag or a slag forming material to the main chamber to form a slag on the molten metal BRIEF DESCRIPTION OF THE DRAWINGS An embodiment of the method of starting a smelting process in a smelting vessel that contains molten slag at least in a forehearth connection of the vessel in accordance with the present invention is described with reference to the accompanying drawings, of which: Figure 1 is a diagrammatic view of a HIsarna apparatus for smelting a metalliferous material and producing molten metal in accordance with one embodiment of the HIsarna process; Figure 2 is a cross-sectional view of the smelting vessel shown in Figure 1 which illustrates molten metal and molten slag levels in the vessel when the HIsarna process is operating normally and producing molten metal; Figure 3 is a cross-sectional view of the smelting vessel shown in Figure 1 which illustrates schematically the condition of the smelting vessel when an end-tap of 5414919_1 (GHMatters) P88706.NZ 7/09/15 the smelting vessel has not been successful with respect to slag removal and the vessel contains frozen slag; Figure 4 is a cross-sectional view of the smelting vessel shown in Figure 1 which illustrates schematically the condition of the vessel during a step of reheating the main chamber of the vessel via a heat source in the main chamber to melt frozen slag in accordance with one embodiment of a method of re-starting the HIsarna process in accordance with the present invention; and Figure 5 is a cross-sectional view of the smelting vessel shown in Figure 1 which illustrates schematically the condition of the vessel during a later step of the method of re-starting the HIsarna process in accordance with one embodiment of the present invention.
DESCRIPTION OF EMBODIMENT(S) The HIsarna process smelts metalliferous feed material and produces process outputs of molten metal, molten slag, and an off-gas. The following description of the HIsarna process is in the context of smelting metalliferous material in the form of iron ore. The present invention is not limited to this type of metalliferous material.
The HIsarna apparatus shown in Figure 1 includes a smelt cyclone 2 and a molten bath-based smelting vessel 4 having a main chamber 19 located directly beneath the smelt cyclone 2, with direct communication between the chambers of the smelt cyclone 2 and the smelting vessel 4.
With reference to Figure 1, during steady-state operation of a smelting campaign, a blend of magnetite-based ore (or other iron ore) with a top size of 6 mm and flux such as limestone 1 is fed, via an ore dryer, and with a pneumatic conveying gas 1a, into the smelt cyclone 2. Limestone represents roughly 8-10 wt% of the combined stream of ore and limestone. Oxygen 8 is injected into the smelt cyclone 2 via tuyeres to preheat and partly melt and partly reduce the ore. The oxygen 8 also 5414919_1 (GHMatters) P88706.NZ 7/09/15 combusts combustible gas flowing upwardly into the smelt cyclone 2 from the smelting vessel 4. The partly melted and partly reduced ore flows downwardly from the smelt cyclone 2 into a molten bath 25 of metal and slag in the main chamber 19 in the smelting vessel 4. The partly melted and partly reduced ore is smelted to form molten iron in the molten bath 25. Coal 3 is fed, via a separate dryer, to the main chamber 19 of the smelting vessel 4. The coal 3 and a conveying gas 2a are injected via lances 35 into the molten bath 25 of metal and slag in the main chamber 19. The coal provides a source of a reductant and a source of energy. Figures 1-5 show the molten bath 25 as comprising two layers, of which layer 25a is a molten metal layer and layer 25b is a molten slag layer. The Figures illustrate the layers as being of uniform depth. This is for illustration purposes only and is not an accurate representation of what would be a highly agitated and well-mixed bath in operation of the HIsarna process. The mixing of the molten bath 25 is due to devolatilisation of coal in the bath, which generates gas, such as CO and H , and results in upward movement of gas and entrained material from the molten bath into a top space of the main chamber 19 that is above the molten bath . Oxygen 7 is injected into the main chamber 19 via lances 37 to post-combust some of these gases, typically CO and H , generated in and released from the molten bath 25 in the top space of the main chamber 19 and provide the necessary heat for the smelting process in the bath.
Normal operation of the HIsarna process during a smelting campaign involves (a) coal injection via lances 35 and cold oxygen injection via lances 37 into the main chamber 19 of the smelting vessel 4 and (b) ore injection 7 and additional oxygen injection 8 into the smelt cyclone 2.
The operating conditions, including but not limited to, coal and oxygen feed rates into the main chamber 19 of the smelting vessel 4 and ore and oxygen feed rates into the smelt cyclone 2 and heat losses from the main chamber 19, are selected so that offgas leaving the smelt cyclone 2 via an offgas outlet duct 9 has a post-combustion degree of at least 90%. 5414919_1 (GHMatters) P88706.NZ 7/09/15 Offgas from the smelt cyclone 2 passes via an offgas duct 9 to an offgas incinerator 10, where additional oxygen 11 is injected to burn residual CO/H and provide a degree of free oxygen (typically 1-2%) in the fully combusted flue gas.
Fully combusted offgas then passes through a waste heat recovery section 12 where the gas is cooled and steam is generated. Flue gas then passes through a wet scrubber 13 where cooling and dust removal are achieved. The resulting sludge 14 is available for recycle to the smelter via the ore feed stream 1.
Cool flue gas leaving the scrubber 13 is fed to a flue gas desulphurisation unit Clean flue gas is then vented via a stack 16. This gas consists mainly of CO and, if appropriate, it can be compressed and geo-sequestered (with appropriate removal of residual non-condensable gas species).
With particular reference to Figure 2, the smelting vessel 4 includes a refractory-lined hearth 33 and side walls 41 defined predominantly by water-cooled panels that define the main chamber 19. The smelting vessel 4 also includes a forehearth 21 which is connected to the main chamber 19 via a forehearth connection During the course of a smelting campaign of the HIsarna process, molten metal produced in the main chamber 19 discharges from the main chamber 19 via the forehearth connection 23 and the forehearth 21.
In addition, the forehearth 21 and the forehearth connection 23 provide a passageway for the supply of a charge of molten metal to the main chamber 19 during hot start-up of the HIsarna process.
The process and the apparatus shown in Figure 2 illustrate normal operation of the HIsarna smelting process in the smelting vessel 4, subject to the qualification that in 5414919_1 (GHMatters) P88706.NZ 7/09/15 normal operation the molten bath 25 is highly agitated, as described above. Under steady-state normal operating conditions, the forehearth 21 and the forehearth connection 23 contain molten metal. The normal manometer overflow system functions via "excess" metal (from production) spilling over forehearth lip 5 to keep the molten metal level in the main chamber 19 substantially constant.
With reference to Figure 2, normal end-tapping of the smelting vessel 4, for example at the end of a smelting campaign, involves first draining molten slag 25b out of the main chamber 19 via a slag-drain taphole 41 (the tap-hole 41 is oriented out of the page toward the reader in Figure 2). Molten metal 25a is then drained from the main chamber 19, the forehearth connection 23, and the forehearth 21 via the end-drain taphole 36 in the main chamber 19 (also oriented out of the page), leaving the main chamber 19 substantially clear of both metal and slag and, in particular, leaving the forehearth 23 empty and the forehearth connection 23 clear. The forehearth end-drain taphole 39 is not normally used under these conditions.
Figure 3 illustrates the condition of the smelting vessel 4 when an end-tap has not been successful with respect to slag removal. In this situation, partly or completely frozen slag 27 occupies a lower part of the main chamber 19 and fills the forehearth connection 23 and a lower part of the forehearth 21.
In order to re-start the HIsarna process when the smelting vessel 4 contains frozen slag 27 as shown in Figure 3, it is necessary to remove the frozen slag from the main chamber 19, the forehearth connection 23, and the forehearth 21. This is achieved in accordance with the present invention by using heat sources to melt frozen slag and drain it from the smelting vessel 4 via the forehearth 21 and establish a clear flow path through the forehearth connection 23 and the forehearth 21 to make it possible to supply a charge of molten metal to the main chamber via the forehearth 21 and the forehearth connection 23 as one of a series of steps to hot start the process.
One embodiment of the method of re-starting the HIsarna process in this situation, which is illustrated partly in Figures 4 and 5, includes the following steps: 5414919_1 (GHMatters) P88706.NZ 7/09/15 (a) heating and melting frozen slag 27 in the main chamber 19; (b) at the same time or after the commencement of step (a) heating and melting frozen slag 27 in the forehearth 21; (c) draining molten slag from the forehearth via the forehearth end-drain taphole 39 (also oriented out of the page), (d) heating and melting frozen slag 27 in the forehearth connection 23; (e) draining molten slag from the forehearth connection 23 and the main chamber 19 via the forehearth end-drain taphole 39 and establishing a clear flow path through the forehearth connection 23; and (f) hot starting the HIsarna process by a series of steps including supplying a charge of molten metal into the main chamber 19 via the forehearth 21 and the forehearth connection 23 and other steps to supply feed materials and re- commence smelting the metalliferous material and producing molten metal.
Figure 4 shows the smelting vessel 4 during the course of step (a) set out above of heating and melting frozen slag in the main chamber 19 via a heat source 33 to progressively produce a pool of molten slag 29.
Figure 4 also shows the smelting vessel 4 during the course of step (b) set out above of heating and melting frozen slag in the forehearth 23 via a heat source 43 to progressively produce a pool 45 of molten slag in the forehearth 21.
In step (c) set out above, molten slag 45 may be drained from the forehearth 21 by tapping via the forehearth end-drain taphole 39. Figure 5 shows the forehearth 21 after the molten slag is tapped form the forehearth 21. In this state, with the forehearth empty, access to the frozen slag in the forehearth connection 23 is possible. 5414919_1 (GHMatters) P88706.NZ 7/09/15 Figure 5 illustrates step (d) set out above of applying a heat source 37 to the frozen slag in the forehearth connection 23 in order to melt the frozen slag and establish a clear forehearth connection 23. The heat source 37 may be an air-oxygen-fuel burner and/or oxygen lances. If necessary, line-of-sight access can be made available through the right-hand wall of the forehearth 21 (not shown).
Upon establishing a clear forehearth connection 23 between the forehearth 21 and the molten slag 29 in the main chamber 19, step (e) set out above may be executed.
This step involves bulk removal of molten slag from the main chamber 19. This leads to establishment of suitable conditions for step (f) set out above, namely re-starting the HIsarna process by a series of steps including supplying a charge of hot metal into the main chamber 19 via the forehearth 21 and the forehearth connection 23 and thereafter supplying feed materials, such as slag forming agents, coal and oxygen into the main chamber and generating molten slag and agitation of the molten bath and off-gases and heat via post-combustion of off-gases and thereafter and supplying feed materials, such as metalliferous material and oxygen, into the smelt cyclone and partially melting and reducing the metalliferous material.
Many modifications may be made to the embodiment of the process of the present invention described above without departing from the spirit and scope of the invention.
The above-described embodiment focuses on the HIsarna process. The present invention is not limited to the HIsarna process and extends to any molten bath-based process in a direct smelting vessel that includes a forehearth for removing molten metal.
By way of example, the present invention extends to the HIsmelt process. As is indicated above, the HIsmelt process is described in a considerable number of patents and patent applications in the name of the applicant. By way of example, the HIsmelt process is described in International application PCT/AU96/00197 in the name of the applicant. The disclosure in the patent specification lodged with the International application is incorporated herein by cross-reference. 5414919_1 (GHMatters) P88706.NZ 7/09/15

Claims (6)

1. A method of starting a smelting process in a smelting vessel that includes a main chamber for smelting a metalliferous material and producing molten metal and a 5 forehearth connected to the main smelting chamber via a forehearth connection, and which smelting vessel contains frozen slag that blocks at least the forehearth connection, the method of starting the process including heating frozen slag and forming molten slag and draining molten slag from the forehearth connection via the forehearth and establishing a clear flow path through the forehearth connection and 10 thereafter hot starting the smelting process by a series of steps including supplying a charge of molten metal into the main chamber via the forehearth connection and supplying feed materials to the process and smelting the metalliferous material and producing molten metal. 15
2. The method defined in claim 1 includes removing molten slag via a forehearth end-drain taphole in a lowest region of the forehearth.
3. The method defined in claim 1 or claim 2 includes heating and melting frozen slag in the forehearth connection via oxygen-enriched gas burners and/or oxygen 20 lances.
4. The method defined in any one of the preceding claims wherein, in a situation in which there is frozen slag in the main chamber, as well as frozen slag in the forehearth connection, the method includes heating and melting frozen slag in the main 25 chamber and the forehearth connection.
5. The method defined in claim 4 includes heating and melting frozen slag in the main chamber via heat from a burner system for the main chamber. 30
6. The method defined in any one of the preceding claims wherein, in a situation in which there is frozen slag in the forehearth, as well as frozen slag in the forehearth 5414919_1 (GHMatters) P88706.NZ
NZ626933A 2011-12-06 2012-12-06 Starting a smelting process NZ626933B2 (en)

Applications Claiming Priority (3)

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AU2011905076A AU2011905076A0 (en) 2011-12-06 Starting a Smelting Process
AU2011905076 2011-12-06
PCT/AU2012/001487 WO2013082659A1 (en) 2011-12-06 2012-12-06 Starting a smelting process

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NZ626933B2 true NZ626933B2 (en) 2016-05-03

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