AU2006239733B2 - Forehearth - Google Patents
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- AU2006239733B2 AU2006239733B2 AU2006239733A AU2006239733A AU2006239733B2 AU 2006239733 B2 AU2006239733 B2 AU 2006239733B2 AU 2006239733 A AU2006239733 A AU 2006239733A AU 2006239733 A AU2006239733 A AU 2006239733A AU 2006239733 B2 AU2006239733 B2 AU 2006239733B2
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- Australia
- Prior art keywords
- vessel
- forehearth
- channel
- molten metal
- open connection
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- 239000002184 metal Substances 0.000 claims abstract description 72
- 229910052751 metal Inorganic materials 0.000 claims abstract description 72
- 238000003723 Smelting Methods 0.000 claims abstract description 50
- 238000000034 method Methods 0.000 claims abstract description 43
- 230000008569 process Effects 0.000 claims abstract description 43
- 238000010079 rubber tapping Methods 0.000 claims abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 109
- 239000007789 gas Substances 0.000 claims description 73
- 229910052742 iron Inorganic materials 0.000 claims description 54
- 239000000463 material Substances 0.000 claims description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 239000001301 oxygen Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 239000002893 slag Substances 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 239000011449 brick Substances 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 6
- 239000003575 carbonaceous material Substances 0.000 claims description 4
- 238000011065 in-situ storage Methods 0.000 claims description 2
- 239000003245 coal Substances 0.000 description 9
- 230000007423 decrease Effects 0.000 description 7
- 239000002737 fuel gas Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 238000003801 milling Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000003595 mist Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000010908 plant waste Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000011064 split stream procedure Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Abstract
A direct smelting vessel (3) for operating a molten bath-based direct smelting process under pressure conditions in the vessel is disclosed. The vessel includes a forehearth (67) for tapping molten metal continuously from the vessel. The forehearth includes an open connection (97) that extends through a side wall of the vessel into the interior of the vessel. The open connection is formed to dampen the impact of sudden changes in pressure in the vessel on molten metal flow in the forehearth that could result in an undesirable surge of molten metal from the forehearth. The open connection is also formed so that molten metal does not freeze in the connection for at least 6 hours when molten metal is not being discharged from the vessel into the forehearth via the open connection.
Description
WO 2006/113969 PCT/AU2006/000545 1 FOREHEARTH The present invention relates to a direct 5 smelting vessel that includes a forehearth for tapping molten metal continuously from the vessel while the process is operating in the vessel. In particular, the present invention relates to 10 the construction of the forehearth of the direct smelting vessel. The present invention relates particularly, although by no means exclusively, to a direct smelting 15 vessel that can operate a molten bath-based direct smelting process for producing molten iron from iron-containing metalliferous feed material, such as iron ores, partly reduced iron ores and iron-containing waste streams (for example, from steelmaking plants). 20 A known molten bath-based direct smelting process is generally referred to as the HIsmelt process. In the context of producing molten iron, the HIsmelt process includes the steps of: 25 (a) forming a bath of molten iron and slag in a direct smelting vessel; (b) injecting into the bath: (i) a metalliferous 30 feed material, typically iron ore in the form of fines; and (ii) a solid carbonaceous material, typically coal, which acts as a reductant of the metalliferous feed material and a source of energy; and 35 (c) smelting metalliferous feed material to iron in the bath.
WO 2006/113969 PCT/AU2006/000545 2 The term "smelting" is herein understood to mean thermal processing wherein chemical reactions that reduce metal oxides take place to produce molten metal. 5 In the HIsmelt process metalliferous feed material and solid carbonaceous material are injected into a molten bath contained in a direct smelting vessel through a number of water-cooled lances/tuyeres which are inclined to the vertical so as to extend downwardly and inwardly 10 through a side wall of the vessel and into a lower region of the vessel so as to deliver at least part of the solids material into the metal layer in the bottom of the vessel. A blast of hot oxygen-containing gas, typically air or oxygen-enriched air, is injected into an upper region of 15 the vessel through a water-cooled lance that extends downwardly into the vessel to cause post-combustion of reaction gases released from the molten bath in the upper region of the vessel. Typically, in the case of producing molten iron, the hot air or oxygen-enriched air is at a 20 temperature of the order of 1200 0 C and is generated in hot blast stoves. Off-gas resulting from the post-combustion of reaction gases in the vessel is taken away from the upper region of the vessel through an off-gas duct. The vessel includes refractory-lined water-cooled panels in the 25 side wall and a roof of the vessel, and water is circulated continuously through the panels in a continuous circuit. The HIsmelt process enables large quantities of molten iron, typically at least 0.5 Mt/a, to be produced by 30 direct smelting in a single compact vessel. In order to achieve high molten iron production rates in the HIsmelt process it is necessary to (a) generate and transport large quantities of hot air or 35 oxygen-enriched air and carrier gas (for solids injection) to the direct smelting vessel, (b) transport large quantities of the metalliferous feed material, such as WO 2006/113969 PCT/AU2006/000545 3 iron-containing feed materials, to the vessel, including generating and transporting large quantities of carrier gas to the vessel (c) transport large quantities of hot off-gas from the vessel, (d) transport large quantities of molten 5 iron and slag produced in the process away from the vessel, and (e) circulate large quantities of water through the water cooled panels - all within a relatively confined area. 10 In view of the above, high molten iron production rates require a HIsmelt process that operates under pressure conditions and a HIsmelt plant that includes (a) a pressurised direct smelting vessel and ancillary equipment such as lock hoppers for supplying solid feed materials to 15 the vessel and pressure control equipment on the off-gas duct of the vessel, (b) stoves that produce the high flow rate of hot air or oxygen-enriched air for the vessel, and (c) off-gas treatment equipment that is capable of processing large quantities of off-gas discharged from the 20 vessel. A current design of a direct smelting vessel for the HIsmelt process includes a forehearth for tapping molten metal on a continuous basis from the vessel and a 25 slag tap-hole for tapping molten slag on a periodic basis from the vessel. The forehearth includes an open connection through the side wall of the vessel into the interior of the vessel. 30 The use of the forehearth, with the open connection to the interior of the vessel, and operation of the vessel under pressure conditions, typically 0.8 bar gauge, means that variations in pressure in the vessel will translate directly to variations in molten metal levels in 35 the vessel and the forehearth. It can be appreciated from the above that WO 2006/113969 PCT/AU2006/000545 4 operating the HIsmelt process with an open forehearth, particularly under pressure conditions, presents potentially serious safety issues that need to be addressed. 5 One such potentially serious safety issue arises if there is an unexpected increase in pressure within the vessel. Under such over-pressure conditions there is a risk of molten metal surging from the vessel into the 10 forehearth and overflowing the forehearth in an uncontrolled and dangerous manner. The present invention provides a forehearth construction that addresses the issue of limiting the 15 extent of surges of hot metal flowing from the forehearth in over pressure situations while taking into account other factors that are relevant to the operation of the forehearth. 20 In general terms the present invention provides a direct smelting vessel for operating a molten bath-based direct smelting process under pressure conditions in the vessel is disclosed. The vessel includes a forehearth for tapping molten metal continuously from the vessel. The 25 forehearth includes an open connection that extends through a side wall of the vessel into the interior of the vessel. The open connection is formed to dampen the impact of sudden changes in pressure in the vessel on molten metal flow in the forehearth that could result in an undesirable 30 surge of molten metal from the forehearth. The open connection is also formed so that molten metal does not freeze in the connection for at least 6 hours when molten metal is not being discharged from the vessel into the forehearth via the open connection. 35 According to the present invention there is provided a direct smelting vessel for operating a molten - 5 bath-based direct smelting process for smelting a metalliferous feed material and producing molten metal under pressure conditions in the vessel, which vessel includes: 5 (a) a hearth adapted to contain a metal layer of the molten bath, the hearth having a base and a side wall; 10 (b) a side wall that extends upwardly from the side wall of the hearth; (c) a plurality of water-cooled solids injection lances extending downwardly and inwardly into 15 the vessel for injecting solids feed materials such as metalliferous feed material and/or carbonaceous material, into the vessel; (d) one or more than one water-cooled oxygen 20 containing gas injection lances extending downwardly into the vessel for injecting an oxygen-containing gas into the vessel; and (e) a forehearth for tapping molten metal 25 continuously from the vessel, the forehearth including (i) a chamber that can hold a volume of molten metal and has an outlet for discharging molten metal from the chamber and (ii) an open connection that extends through the side wall of the hearth into the interior of the vessel and 30 thereby interconnects the chamber and the interior of the vessel, the open connection including a first channel having a length of 200-600mm that extends from the vessel, a uniform transverse cross-section along its length and a minimum transverse cross-sectional area, as defined 35 herein, that is selected to limit molten metal flow into the forehearth in over-pressure conditions in the vessel and thereby dampen the impact of sudden changes in 2772254_1 (GHMatters) PS6696.AU. I 15/08/111 - 5A pressure in the vessel on molten metal flow in the forehearth that could result in an undesirable surge of molten metal from the forehearth, and the open connection also being formed so that molten metal does not freeze in 5 the connection for at least 6 hours when molten metal is not being discharged from the vessel into the forehearth via the open connection. 2772254_1 (GHMatters) P566%.AU 115/08/11 WO 2006/113969 PCT/AU2006/000545 6 The term "dampen" is understood herein to mean that a sudden increase in pressure in the vessel does not translate immediately to a corresponding increase in the velocity and/or the flowrate (volume or mass) of molten 5 metal from the vessel into the forehearth that could result in an undesirable surge of molten metal from the forehearth. The requirements for the forehearth connection 10 described in paragraph (e) above are the result of research and development work of the applicant that has identified and recognised the significance of factors, which include competing factors, that are important to the design of a forehearth for a molten bath-based direct smelting process 15 operating under pressure in a direct smelting vessel with continuous flow of molten metal from the vessel via the forehearth. One factor is that the extent of refractory wear 20 increases as the area of a vertical cross-section that is transverse to the length of the forehearth connection at the narrowest part of the forehearth connection decreases. The term "minimum transverse cross-sectional area" is understood herein to mean the area of a vertical cross 25 section transverse to the length of the forehearth connection at the narrowest part of the forehearth connection. A competing factor is that the extent to which the flowrate (volume or mass) of molten metal from the vessel into the forehearth can be limited increases as the 30 minimum transverse cross-sectional area of the forehearth connection decreases. Thus, a larger minimum transverse cross-sectional area is preferable from a wear viewpoint but is less preferred from a flowrate limitation viewpoint. Moreover, a smaller minimum transverse cross-sectional area 35 is preferable from a flowrate limitation viewpoint but is less preferred from a wear viewpoint.
WO 2006/113969 PCT/AU2006/000545 7 Another factor is that, for a given minimum transverse cross-sectional area of the forehearth connection, the risk of freezing molten metal in the forehearth connection decreases as the length of the 5 forehearth connection decreases. A competing factor is that, for a given minimum transverse cross-sectional area of the forehearth connection, the extent to which flow rate of molten metal from the vessel into the forehearth can be limited decreases as the length of the forehearth 10 connection decreases. Thus, a longer length is preferable from a flowrate limitation viewpoint but is less preferred from a viewpoint of molten metal freezing in the forehearth connection. Moreover, a shorter length is preferable from a molten metal freezing viewpoint but is less preferred 15 from a flowrate limitation viewpoint. Another factor is that, for a given minimum transverse cross-sectional area of the forehearth connection, the velocity of molten metal flowing through 20 the forehearth connection increases and the wear of the connection increases as the pressure change in the vessel increases. A related factor is that, for a given pressure increase within the vessel, the velocity of molten metal flowing through the forehearth connection increases and the 25 wear of the connection increases as the minimum transverse cross-sectional area of the forehearth connection decreases. Preferably the open connection is formed so that 30 the maximum velocity of molten metal through the open connection is 1 m/s while the process is operating under pressure in the vessel and producing molten iron at a full production rate. 35 The term "full production rate" is understood herein to mean a rate required to produce the annual design production for the vessel.
- 8 The annual design production may vary considerably for different vessels. Typically, for vessels designed to produce molten iron, the annual design production is at least 800,000 tonnes and may be up to or 5 greater than 2 million tonnes. It is preferred particularly that the open connection is formed so that the maximum velocity of molten metal through the open connection be 0.6 m/s. 10 Typically, the operating pressure in the vessel while the process is operating in the vessel is at least 0.5 bar gauge. 15 Typically, the operating pressure in the vessel while the process is operating in the vessel is less than 1.5 bar gauge, and more typically less than 1.0 bar gauge. Preferably a major width dimension of the first 20 channel is 75-200 mm. 2772254_1 (GHMatters) P56696.AU.115/08/11 WO 2006/113969 PCT/AU2006/000545 9 It is preferred particularly that the length of the first channel be 300-500 mm. 5 The first channel may be any suitable shape in transverse cross-section. Suitable shapes include tunnel shaped, circular, and square. Preferably the transverse cross-section of the 10 first channel is tunnel-shaped with a flat base, parallel side walls extending perpendicularly to the base, and a curved roof. Preferably the open connection also includes a 15 second channel that extends from the first channel to the forehearth chamber and has a transverse cross-sectional area that increases with distance from the first channel. The width or the height of the second channel may 20 increase with distance from the first channel. Preferably the height of the second channel increases with distance from the first channel. 25 Preferably the second channel is generally frusto-conical when viewed in vertical cross-section along the length of the second channel. Preferably the second channel has a lower wall 30 and an upper wall. Preferably the upper wall of the second channel is more inclined to the horizontal than the lower wall of the second channel. 35 Preferably the upper wall of the second channel has an angle of inclination of the upper wall of the second WO 2006/113969 PCT/AU2006/000545 10 channel to the horizontal of at least 150. It is preferred particularly that the angle of inclination to the horizontal be at least 200. 5 Preferably the width of the second channel section initially increases with distance from the first channel and thereafter remains constant along the remainder of the length of the second channel to the forehearth 10 chamber. Preferably the ratio of the volume of the second channel to the volume of the first channel is at least 3:1. 15 More preferably the ratio of the volume of the second channel to the volume of the first channel is at least 4:1. Typically, the forehearth connection is designed 20 to dampen sudden increases in vessel pressure of up to 50% of the operating pressure in the vessel. Preferably the forehearth includes pre-cast bricks/blocks or bricks/blocks that are cast in-situ that 25 define the open connection. Preferably the forehearth includes pressed bricks/blocks that define the forehearth chamber. 30 Preferably the forehearth includes a tap hole for discharging molten metal when there is a need to drain molten metal from the forehearth and the vessel. The tap hole is closed when the vessel is operating and producing metal and can be opened selectively as required if it is 35 necessary to drain molten metal from the vessel and the forehearth.
WO 2006/113969 PCT/AU2006/000545 11 Preferably the vessel includes pressure release valves that vent the vessel to atmosphere in the event that the vessel pressure increases to a predetermined pressure. 5 According to the present invention there is provided a direct smelting plant that includes the above described direct smelting vessel for operating a molten bath-based direct smelting process under pressure for smelting a metalliferous feed material and producing molten 10 metal. According to the present invention there is also provided a molten bath-based direct smelting process for smelting a metalliferous feed material and producing molten 15 metal under pressure conditions in the above-described direct smelting vessel. The present invention is described in more detail hereinafter with reference to the accompanying drawings, of 20 which: Figure 1 is a diagrammatic view of one embodiment of a direct smelting plant that includes a direct smelting vessel in accordance with the present invention; 25 Figure 2 is an enlarged vertical cross-section of the direct smelting vessel shown in Figure 1 which illustrates the forehearth in more detail; 30 Figure 3 is an enlarged vertical cross-section that illustrates the forehearth in more detail; Figure 4 is an enlarged horizontal cross-section that illustrates the forehearth in more detail; and 35 Figure 5 is an end view of the forehearth as viewed in the direction of the arrow A in Figure 3.
WO 2006/113969 PCT/AU2006/000545 12 The following description of the plant shown in the figures is in the context of using the plant to smelt iron-containing feed material to produce molten iron in 5 accordance with the HIsmelt process as described in International application PCT/AU96/00197 in the name of the applicant. The disclosure in the patent specification lodged with the International application is incorporated herein by cross-reference. 10 The process is based on the use of a direct smelting vessel 3. The vessel 3 is of the type described in detail 15 in International applications PCT/AU2004/000472 and PCT/AU2004/000473 in the name of the applicant. The disclosure in the patent specifications lodged with these applications is incorporated herein by cross-reference. 20 With reference to Figure 2, the vessel 3 has a hearth that includes a base 81 and a side wall 83 formed from refractory bricks, a side wall 85 which forms a generally cylindrical barrel extending upwardly from the sides of the hearth, and a roof 87 that includes a central 25 off-gas chamber 89, an off-gas duct 9 extending from the off-gas chamber 89, a forehearth 67 for discharging molten metal continuously from the vessel 3, and a tap hole 71 for discharging molten slag periodically from the vessel 3. 30 The forehearth 67 includes an outer steel shell 75 and an internal lining 77 of refractory material. The forehearth 67 includes a main chamber or well 91 that has an outlet 93 for molten iron in an upper end of 35 the chamber. In use, molten iron flows via the outlet 91 from the forehearth 67 and into a launder (not shown).
WO 2006/113969 PCT/AU2006/000545 13 The forehearth 67 also includes a tap hole 95 in a lower section of the main chamber 91. In use, the tap hole 95 is closed under normal operating conditions of the process. The tap hole 95 can be opened as required to 5 drain molten iron from the forehearth 67 and the vessel 3. The forehearth 67 also includes a forehearth connection generally identified by the numeral 97 that interconnects the main chamber 91 and the interior of the 10 vessel 3. As can best be seen in Figures 3 to 5, the forehearth connection 97 includes: 15 (a) a first, relatively narrow and short, horizontal channel 99 that extends outwardly from the vessel interior, and (b) a second, increasingly wider and relatively 20 long channel 101 that extends outwardly from the first channel 99 and opens into the main chamber 91. The first channel 99 extends a short distance only (300 mm) into the side wall 83 of the hearth. As can 25 best be seen in Figure 5, the first channel 99 is tunnel shaped in transverse section and includes a base 103, parallel side walls 103, and a curved roof 107. The first channel 99 has a height and a width of 150 mm. 30 The first channel 99 is formed to act as a throttle to and thereby to dampen the impact of any uncontrolled outward flow of molten iron from the vessel 3 on flow of molten iron in the main chamber 91 of the forehearth 67 in over-pressure conditions in the vessel 3. 35 The second channel 102 is formed to provide a transition for the flow of molten iron from the first WO 2006/113969 PCT/AU2006/000545 14 channel 99 into the main chamber 91. The first channel 99 and the second channel 101 are also formed having regard to the thermal requirements 5 of the forehearth connection 97. In particular, the first channel 99 and the second channel 101 are formed so that there is sufficient heat transfer into the first channel 99 from the vessel interior and the forehearth chamber 91 (via the second channel 101) to maintain the temperature of 10 molten iron in the first channel 99 above the liquidus temperature for at least 6 hours during an off-wind situation, i.e. when there is no molten iron being produced in the vessel 3 and being discharged via the forehearth 67. 15 In particular, the shape and size of the second channel 101 facilitates heat transfer into the first channel 99. With reference to Figure 3, the second channel 101 is generally frusto-conical in vertical cross-section with a generally horizontal lower wall 107 and an upwardly 20 inclined upper wall 109 extending at an angle of 200 to the horizontal. In particular, the second channel 101 has (a) a substantially frusto-conical first section 111 that extends for a length of 600 mm and increases in width from 150 mm to 500 mm and (b) a constant-width second section 25 113 that extends to the main chamber 91 of the forehearth 67. The size of the second channel 101 is such that it contains a volume of molten iron that is relatively large compared to that contained by the first channel 99. 30 In addition, the overall shape and size of the forehearth connection 97 and the shape, materials, and layout of the refractory lining that forms the forehearth connection 97 are selected to (a) withstand significant wear that occurs during the process due to molten iron flow 35 through the forehearth connection 97 and (b) expand relative to the vessel 3 so that the expansion places minimal if any load on the vessel 3. With regard to the WO 2006/113969 PCT/AU2006/000545 15 refractory lining, the lining of the forehearth connection 97 is made from pre-cast blocks of refractory material. Figure 5 shows the ends of two such pre-cast blocks 117a and 117b. With regard to item (b), the first channel 99 is 5 sized so that the maximum velocity of molten iron in the channel 99 is in the range 0.2-0.6 m/s when the vessel is producing molten iron at a full production rate. Typically, a full production rate corresponds with a nominal metal production rate in the range 800,000 tonnes 10 per annum to 1,600,000 tonnes per annum for vessels having a hearth diameter in the range 6m to 8m respectively and operating at a pressure of the order of 0.8 bar gauge. Such production rates correspond with the processing primarily of haematite iron ore fines that have been pre 15 heated and are supplied to the hearth at a temperature in the order of 700 0 C at a reduction degree of up to 11%. The precast blocks that form the forhearth connection 97 provide a thermal gradient away from the 20 molten iron in the connection 97 that is sufficient to limit propagation of cracks that may develop in these blocks during operation. A thermal gradient that limits crack propagation is advantageous due to the large size compared with typical pressed refractory bricks. 25 The vessel 3 is fitted with a downwardly extending water-cooled hot air blast ("HAB") lance 7 extending into a top space of the vessel 3 and eight water cooled solids injection lances 5 extending downwardly and 30 inwardly through the side wall 85. In use, the vessel 3 contains a molten iron bath. Under quiescent conditions, i.e. while a direct smelting process is not operating in the vessel 3, the molten bath 35 includes a metal layer 91 and a slag layer 93 on top of the metal layer.
WO 2006/113969 PCT/AU2006/000545 16 In use, while a direct smelting process is operating in the vessel 3, iron-containing feed material (such as iron ore fines, iron-bearing steel plant wastes or DRI fines), coal and fluxes (lime and dolomite) are 5 directly injected into the bath via the solids injection lances 5. Specifically, one set of lances 5 is used for injecting iron-containing feed material and fluxes and 10 another set of lances 5 is used for injecting coal and fluxes. The lances 5 are water-cooled to protect them from the high temperatures inside the vessel 3 and are 15 lined with a high wear resistant material in order to protect them from abrasion by the gas/solids mixture being injected at high velocity. The lances extend inwardly through a side wall of the vessel and downwardly toward a hearth region of the vessel. The ends of the lances are 20 positioned above the metal layer that exits in the herath during operation and within a portion of the hearth that contains slag. In use, while a direct smelting process is 25 operating in the vessel 3, iron-containing feed material is pretreated before being supplied to the vessel 3 by being preheated to a temperature in the range of 600-700 0 C and prereduced in a fluidised bed preheater 17 before being injected into the bath. In one form of pre-treatment 30 process, the iron ore is pre-treated by off-gas from the process alone or in conjunction with natural gas. The pre reduction under these conditions may be in the order of and is typically less than 11%. 35 Coal and fluxes are stored in a series of lock hoppers 25 before being injected at ambient temperatures into the bath. The coal is supplied to the lock hoppers 25 WO 2006/113969 PCT/AU2006/000545 17 via a coal drying and milling plant 71. The injected coal de-volatilises in the bath, thereby liberating H 2 and CO. These gases act as S reductants and sources of energy. The carbon in the coal is rapidly dissolved in the bath. The dissolved carbon and the solid carbon also act as reductants, producing CO as a product of reduction. The injected iron-containing feed material is smelted to molten iron in the bath and is 10 discharged continuously via the forehearth 67. Molten slag produced in the process is discharged periodically via the slag tap hole 71. The process operates under pressure conditions, 15 typically 0.8 bar gauge, in the vessel 3. Operating the process under pressure conditions in the vessel 3 with the open connection to the exterior of the vessel 3 (via the forehearth 67) presents safety risks 20 in both under-pressure and over-pressure conditions in the vessel 3 caused by unexpected perturbations in the process. In over-pressure conditions in the vessel 3 the safety risk arises from the possibility of a surge of 25 molten iron flowing from the vessel 3 into and from the forehearth 67 in an uncontrolled manner. The above described first channel 99 of the forehearth connection 97 acts as a throttle to and thereby dampens the impact of any such uncontrolled outward flow of molten iron on the flow 30 of molten iron in the forehearth 67. In particular, the first channel 99 ensures that a sudden increase in pressure in the vessel 3 does not translate immediately to a corresponding increase in the velocity and/or the flowrate (volume or mass) of molten iron from the vessel 3 into the 35 forehearth 67 that could result in an undesirable surge of molten metal from the forehearth 67.
WO 2006/113969 PCT/AU2006/000545 18 The typical reduction reactions involved in smelting injected iron-containing feed material to molten iron that occur in the bath are endothermic. The energy required to sustain the process and, more particularly 5 these endothermic reactions, is provided by reacting CO and
H
2 released from the bath with oxygen-enriched air injected at high temperatures, typically 1200 0 C, into the vessel 3 via the HAB lance 7. 10 Energy released from the above-described post combustion reactions in the vessel top space is transferred to the molten iron bath via a "transition zone" in the form of highly turbulent regions above the bath that contain droplets of slag and iron. The droplets are heated in the 15 transition zone by the heat generated from post combustion reactions and return to the slag/iron bath thereby transferring energy to the bath. The hot, oxygen-enriched air injected into the 20 vessel 3 via the HAB lance 7 is generated in a pair of hot blast stoves 11 by passing a stream of oxygen-enriched air (nominally containing 30 to 35% by volume 02) through the stoves 11 and heating the air and thereafter transferring the hot oxygen-enriched air to the HAB lance 7 via a hot 25 blast main 41. Off-gas is released from the vessel 3 via the off-gas duct 9 in the upper section of the vessel 3 and passes initially through a radiation cooler, hereinafter 30 referred to as an "off-gas hood", 15. Typically, the off gas is at a temperature of the order of 1450 0 C. The off-gas is cooled as it passes through the off-gas hood 15 and thereby results in the generation of 35 steam which accumulates in steam drum 35. The off-gas hood may be of a type described in US patent 6,585,929 that cools and partially cleans off-gas.
WO 2006/113969 PCT/AU2006/000545 19 The off-gas stream leaving the off-gas hood 15 is at a temperature of approximately 1000 0 C and is split into two streams. 5 One split off-gas stream leaving the off-gas hood 15, which comprises between 55-65% of the off-gas from the vessel 3, passes first through a wet cone scrubber 21. 10 The scrubber 21 quenches and removes particulate material and soluble gaseous species and metal vapours from off-gas flowing through the scrubber. The off-gas temperature drop in the scrubber is from approximately 1000*C to below 100 0 C and typically between 65 0 C and 90 0 C. 15 The off-gas from the scrubber 21 leaves the scrubber 21 passes through an off-gas cooler 23 that further cools the off-gas to below 50 0 C, typically between 30'C and 454C, to remove sufficient moisture from the off 20 gas for it to be used as a fuel gas. Typically the off-gas leaving the cooler has 5% or less H 2 0 and a mist content of less than 10 mg/Nm 3 and typically 5.0 mg/Nm 3 . The resulting off-gas is suitable for use as a 25 fuel gas in (a) the stoves 11 (as described above) and (b) the WHR system 25. In addition, the scrubbed and cooled off-gas is suitable for drying coal in the drying and milling plant 71. 30 For the above purposes, the off-gas from the off gas cooler 23 is split into three streams, with one stream being passed to the stoves 11, another stream being passed to the WHR system 25, and the third stream being passed to the drying and milling plant 71. 35 The off-gas stream from off-gas cooler 23 is a relatively rich off-gas. The stream that is passed to the WO 2006/113969 PCT/AU2006/000545 20 WHR system 25 is mixed with cooled and cleaned off-gas that has passed through the preheater 17 as described hereinafter, which is a relatively lean off-gas, due to some pre-reduction of the ferrous feed material in the pre 5 heater by CO and H 2 in the off-gas. The combined off-gas stream has a calorific value that makes it suitable for combustion as a fuel gas. 10 The combined off-gas stream, an additional source of fuel gas in the form of natural gas (indicated by the numeral 83 in Figure 1), and air are supplied to and combusted in the WHR system 25. 15 The combined off-gas stream is combusted within the WHR system 25 in a manner that maximises CO destruction, while minimising NOx formation. The off-gas released from the WHR system 25 is 20 combined with off-gas gas from the stoves 11 and then passes to the FGD system 13. SO 2 is removed in the FGD system 23 and the exhaust gas is released to the atmosphere via a stack 45. 25 The other split stream, which contains approximately 35-45% by volume of the off-gas stream, is passed through the fluidised bed preheater 17 for iron containing feed material. The preheater 17 removes moisture from and preheats and prereduces the iron 30 containing feed material. The off-gas is a source of energy and a fluidising gas in the preheater 17. The off-gas released from the preheater 17 is passed through a cyclone 61 and entrained dust is separated 35 from the off-gas. The off-gas then passes through a wet cone - 21 scrubber 63 that removes particulate material and soluble gaseous species and metal vapours from the off-gas and cools the off-gas from between 500*C and 200 0 C to below 100 0 C and typically between 65 0 C and 90 0 C. 5 The off-gas from the scrubber 63 then passes through an off-gas cooler 65 that further cools the off gas to below 50 0 C, typically between 30 0 C and 45 0 C, to remove sufficient moisture from the off-gas for it to be 10 used as a fuel gas. Typically the off-gas leaving the cooler has 5% or less H 2 0 and a mist content of less than 10 mg/Nm 3 and typically 5.0 mg/Nm 3 . As is described above, the cooled and cleaned is off-gas is then used as a fuel gas in a waste heat recovery (WHR) system 25. The use of the off-gas as a fuel gas within a plant offsets an amount of electrical power that would 20 otherwise need to be obtained from an external electricity supply grid, which makes the plant generally self sufficient in terms of electrical power. Many modifications may be made to the embodiment 25 of the present invention described above without departing from the spirit and scope of the invention By way of example, whilst the first channel 99 of the forehearth connection 97 of the vessel 3 shown in the 30 Figures is tunnel-shaped in transverse cross-section, it can readily be appreciated that the present invention is not so limited and extends to any suitable shapes, including circular and square. 35 It is to be understood that, if any prior art publication is referred to herein, such reference does not constitute an admission that the publication forms a part 2772254_1 (GHMatters)P56696.AU.115/08/11 - 22 of the common general knowledge in the art, in Australia or any other country. In the claims which follow and in the preceding s description of the invention, except where the context requires otherwise due to express language or necessary implication, the word "comprise" or variations such as "comprises" or "comprising" is used in an inclusive sense, i.e. to specify the presence of the stated features but 10 not to preclude the presence or addition of further features in various embodiments of the invention. 2772254_1 (GHMatters) P56696 AU.115/08/11
Claims (26)
1. A direct smelting vessel for operating a molten bath-based direct smelting process for smelting a 5 metalliferous feed material and producing molten metal under pressure conditions in the vessel, which vessel includes: (a) a hearth adapted to contain a metal layer io of the molten bath, the hearth having a base and a side wall; (b) a side wall that extends upwardly from the side wall of the hearth; is (c) a plurality of water-cooled solids injection lances extending downwardly and inwardly into the vessel for injecting solids feed materials such as metalliferous feed material and/or carbonaceous material, 20 into the vessel; (d) one or more than one water-cooled oxygen containing gas injection lances extending downwardly into the vessel for injecting an oxygen-containing gas into the 25 vessel; and (e) a forehearth for tapping molten metal continuously from the vessel, the forehearth including (i) a chamber that can hold a volume of molten metal and has 30 an outlet for discharging molten metal from the chamber and (ii) an open connection that extends through the side wall of the hearth into the interior of the vessel and thereby interconnects the chamber and the interior of the vessel, the open connection including a first channel 35 having a length of 200-600mm that extends from the vessel, a uniform transverse cross-section along its length and a minimum transverse cross-sectional area, as defined 2772254_1 (GHMatte) P56696 AU 115/08/11 - 24 herein, that is selected to limit molten metal flow into the forehearth in over-pressure conditions in the vessel and thereby dampen the impact of sudden changes in pressure in the vessel on molten metal flow in the 5 forehearth that could result in an undesirable surge of molten metal from the forehearth, and the open connection also being formed so that molten metal does not freeze in the connection for at least 6 hours when molten metal is not being discharged from the vessel into the forehearth 10 via the open connection.
2. The vessel defined in claim 1 wherein the open connection is formed so that the maximum velocity of molten metal through the open connection is 1 m/s while 15 the process is operating under pressure in the vessel and producing molten iron at a full production rate, as defined herein.
3. The vessel defined in claim 1 wherein the open 20 connection is formed so that the maximum velocity of molten metal through the open connection be 0.6 m/s while the process is operating under pressure in the vessel and producing molten iron at a full production rate, as defined herein. 25
4. The vessel defined in any one of the preceding claims wherein a major width dimension of the first channel is 75-200 mm. 30
5. The vessel defined in any one of the preceding claims wherein the length of the first channel is 300-500 mm.
6. The vessel defined in any one of the preceding 35 claims wherein the first channel, in transverse cross section, is any one of tunnel-shaped, circular, or square. 2772254_1 (GHMatters) PS6696.AU. 115/08/11 - 25
7. The vessel defined in any one of the preceding claims wherein the open connection also includes a second channel that extends from the first channel to the forehearth chamber and has a transverse cross-sectional 5 area that increases with distance from the first channel.
8. The vessel defined in claim 7 wherein the width or the height of the second channel increases with distance from the first channel. 10
9. The vessel defined in claim 7 wherein the height of the second channel increases with distance from the first channel. is
10. The vessel defined in claim 9 wherein the second channel is generally frusto-conical when viewed in vertical cross-section along the length of the second channel. 20
11. The vessel defined in claim 9 or claim 10 wherein the second channel has a lower wall and an upper wall.
12. The vessel defined in claim 11 wherein the upper wall of the second channel is more inclined to the 25 horizontal than the lower wall of the second channel.
13. The vessel defined in claim 12 wherein the upper wall of the second channel has an angle of inclination to the horizontal of at least 15*. 30
14. The vessel defined in claim 12 wherein the angle of inclination of the upper wall of the second channel to the horizontal is at least 200. 35
15. The vessel defined in any one of claims 7 to 14 wherein the width of the second channel section initially increases with distance from the first channel and 2772254_1 (GHMatters) P56696. AU. 115/08111 - 26 thereafter remains constant along the remainder of the length of the second channel to the forehearth chamber.
16. The vessel defined in any one of the preceding 5 claims wherein the forehearth connection is designed to dampen sudden increases in vessel pressure of up to 50% of the operating pressure in the vessel.
17. The vessel defined in any one of the preceding 10 claims wherein the forehearth includes pre-cast bricks/blocks or bricks/blocks that are cast in-situ that define the open connection.
18. The vessel defined in any one of the preceding 15 claims wherein the forehearth includes pressed bricks/blocks that define the forehearth chamber.
19. The vessel defined in any one of the preceding claims wherein the forehearth is formed to expand relative 20 to the vessel so that the expansion places minimal if any load on the vessel.
20. The vessel defined in any one of the preceding claims wherein the forehearth includes a tap hole for 25 discharging molten metal when there is a need to drain molten metal from the forehearth and the vessel.
21. The vessel defined in any one of the preceding claims includes pressure release valves that vent the 30 vessel to atmosphere in the event that the vessel pressure increases to a predetermined pressure.
22. A direct smelting plant that includes the direct smelting vessel defined in any one of the preceding claims 35 for operating a molten bath-based direct smelting process under pressure conditions for smelting a metalliferous feed material and producing molten metal. 2772254_1 (GHMatters) P56696.AU. 115/08/11 - 27
23. A molten bath-based direct smelting process for smelting a metalliferous feed material and producing molten metal under pressure in the direct smelting vessel 5 defined in any one of claims 1 to 22, the direct smelting process comprising the steps of: (a) providing a molten bath having the metal layer and a slag layer; 10 (b) injecting the solids feed materials into the vessel via the plurality of water-cooled solids injection lances; 15 (c) injecting an oxygen-containing gas into the vessel through the one or more than one water-cooled oxygen-containing gas injection lance; (d) smelting the metalliferous materials and 20 producing molten metal; and (e) tapping molten metal from the vessel through the forehearth via the 200-600mm long first channel of the open connection. 25
24. The process defined in claim 23 wherein the operating pressure in the vessel is at least 0.5 bar gauge. 30
25. The process defined in claim 23 or claim 24 wherein the operating pressure in the vessel is less than 1.5 bar gauge.
26. A direct smelting vessel substantially as herein 35 described with reference to the accompanying drawings. 2772254_ I (GHMatters) PS6696.AU.115/08/11
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2006239733A AU2006239733B2 (en) | 2005-04-26 | 2006-04-26 | Forehearth |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2005902093A AU2005902093A0 (en) | 2005-04-26 | Forehearth | |
AU2005902093 | 2005-04-26 | ||
AU2006239733A AU2006239733B2 (en) | 2005-04-26 | 2006-04-26 | Forehearth |
PCT/AU2006/000545 WO2006113969A1 (en) | 2005-04-26 | 2006-04-26 | Forehearth |
Publications (2)
Publication Number | Publication Date |
---|---|
AU2006239733A1 AU2006239733A1 (en) | 2006-11-02 |
AU2006239733B2 true AU2006239733B2 (en) | 2011-09-22 |
Family
ID=39410406
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2006239733A Ceased AU2006239733B2 (en) | 2005-04-26 | 2006-04-26 | Forehearth |
Country Status (1)
Country | Link |
---|---|
AU (1) | AU2006239733B2 (en) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0595103A1 (en) * | 1992-10-14 | 1994-05-04 | ABBPATENT GmbH | Compressible crucible with refractory lining and attached pouring basin |
WO2002008471A1 (en) * | 2000-07-20 | 2002-01-31 | Technological Resources Pty Ltd | A direct smelting process and apparatus |
US6565798B2 (en) * | 2000-01-25 | 2003-05-20 | Technological Resources Pty. Ltd. | Method of relining a vessel |
-
2006
- 2006-04-26 AU AU2006239733A patent/AU2006239733B2/en not_active Ceased
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0595103A1 (en) * | 1992-10-14 | 1994-05-04 | ABBPATENT GmbH | Compressible crucible with refractory lining and attached pouring basin |
US6565798B2 (en) * | 2000-01-25 | 2003-05-20 | Technological Resources Pty. Ltd. | Method of relining a vessel |
WO2002008471A1 (en) * | 2000-07-20 | 2002-01-31 | Technological Resources Pty Ltd | A direct smelting process and apparatus |
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