Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
  • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
  • A61K8/00—Cosmetics or similar toiletry preparations
  • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
  • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
  • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
  • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
  • A61K8/362—Polycarboxylic acids
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q19/00—Preparations for care of the skin
  • A61Q19/10—Washing or bathing preparations
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
  • A61Q5/00—Preparations for care of the hair
  • A61Q5/02—Preparations for cleaning the hair
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/04—Carboxylic acids or salts thereof
  • C11D1/08—Polycarboxylic acids containing no nitrogen or sulfur
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
  • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/08—Liquid soap, e.g. for dispensers; capsuled
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/20—Organic compounds containing oxygen
  • C11D3/2075—Carboxylic acids-salts thereof
  • C11D3/2082—Polycarboxylic acids-salts thereof
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D9/00—Compositions of detergents based essentially on soap
  • C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D9/00—Compositions of detergents based essentially on soap
  • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
  • C11D9/045—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps containing substances which prevent the deterioration of soaps, e.g. light or heat stabilisers or antioxidants
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D9/00—Compositions of detergents based essentially on soap
  • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
  • C11D9/22—Organic compounds, e.g. vitamins
  • C11D9/26—Organic compounds, e.g. vitamins containing oxygen

Definitions

• the present invention relates to a liquid or pasty cosmetic cleaning preparation containing alkali soaps and dicarboxylic acids.
• Soaps are formed during the reaction (“saponification") of a fat or of fatty acids or fatty acid methyl esters obtained therefrom with sodium hydroxide or potassium hydroxide solution, and chemically they represent the alkali salt of fatty acids.
• Soap-containing liquid or pasty cleaning preparations are particularly popular in South-East Asia, since the preparations leave a dry, clean feeling on the skin. Especially in the subtropical-tropical latitudes, the temperature stability of soap-containing cleaning preparations plays a special role.
• liquid or pasty cosmetic cleaning preparation comprising a) one or more alkali soaps, b) one or more compounds from the group of dicarboxylic acids, in addition to any other cosmetic or dermatological active ingredients, auxiliaries and additives.
• liquid or pasty cleaning preparation means that the preparation has a viscosity of 800 to 10,000 mPas.
• the viscosity values of the preparations and individual substances listed in the context of the present specification were determined with the aid of a Viscotester VT 02 viscometer from Haake (temperature: 25 ° C., spindle diameter 24 mm, rotor speed 62.5 1 / min).
• the cosmetic cleaning preparation according to the invention advantageously contains one or more alkali soaps in a total concentration of 10 to 50 % By weight, preferably in a total concentration of 15 to 30% by weight, based in each case on the total weight of the preparation.
• the soaps according to the invention are formed from the corresponding fatty acids by reaction with bases.
• the fatty acids lauric acid (dodecanecarboxylic acid), myristic acid (tetradecanecarboxylic acid), palmitic acid (hexadecanecarboxylic acid), stearic acid (octadecanecarboxylic acid) are preferred according to the invention.
• Bases preferred according to the invention are, for example, sodium hydroxide, potassium hydroxide and / or triethanolamine.
• one or more soaps are selected from the group of the salts of the fatty acids of natural oils and the like.
• Fats preferably of chain lengths C12-C18 such as stearic acid, myristic acid, palmitic acid and lauric acid.
• Sodium hydroxide solution, potassium hydroxide solution, triethanolamine and diethanolamine are advantageous for saponification.
• Cosmetic cleaning preparations which are advantageous according to the invention are characterized in that they contain one or more compounds from the group of dicarboxylic acids in a total concentration of from 0.01 to 5.0% by weight, preferably from 0.1 to 2.0% by weight, in each case based on the total weight of the preparation.
• Dicarboxylic acids with a chain length of 8 to 24 carbon atoms are preferred according to the invention.
• particularly preferred is the use of dicarboxylic acid 9-octadecenedicarboxylic acid, which has the following structure:
• preparations according to the invention can advantageously contain further active ingredients, auxiliaries and additives.
• Advantageous embodiments of the present invention contain, for example, one or more thickeners. It is preferred according to the invention to use one or more polymeric thickeners selected from the group of cellulose derivatives and / or polyacrylates.
• Polyacrylates advantageous according to the invention are polymers of acrylic acid, in particular those selected from the group of so-called carbomers or carbopols (Carbopol® is actually a registered trademark of the B.F. Goodrich Company). Polyacrylates are compounds of the general structural formula
• the group of polyacrylates also includes acrylate-alkyl acrylate copolymers, for example those which are distinguished by the following structure:
• R ' represents a long chain alkyl radical and x and y numbers which symbolize the respective stoichiometric proportion of the respective comonomers.
• Advantageous carbopoles are, for example, types 907, 910, 934, 940, 941, 951, 954, 980, 981, 1342, 1382, 2984 and 5984 or types ETD (Easy-to-disperse) 2001, 2020, 2050, where these compounds can be present individually or in any combination with one another.
• ETD Easy-to-disperse
• Carbopol 981, 1382 and ETD 2020 are particularly preferred.
• the acrylate-alkyl acrylate copolymers copolymers of comparable polymeric C ⁇ 0 - 3. o-alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or esters thereof.
• the INCI name for such compounds are, for example, "Acrylates / C 10-30 Alkyl Acrylate Crosspolymer” or "Acrylates Copolymer”.
• Particularly advantageous are those available under the trade names Pemulen TR1 and Pemulen TR2 and Carbopol Aqua-SF 1 polymer from NOVEON.
• one or more polyacrylates from the group of acrylate-alkyl acrylate copolymers.
• one or more polyacrylates in a total concentration of 0.3 to 5.0% by weight, preferably in a concentration of 1.0 to 2.0% by weight, in each case based on the total weight of the preparation ,
• cellulose derivatives are also preferred according to the invention to use cellulose derivatives as polymeric thickeners.
• the preparation according to the invention advantageously contains the cellulose derivatives in a total concentration of 0.1 to 1.0% by weight, preferably in a total concentration of 0.2 to 0.5% by weight, based in each case on the total weight of the preparation.
• Preferred cellulose derivatives for the purposes of the present invention are hydroxyalkyl celluloses. It is particularly preferred if one or more
• Hydroxyalkyl celluloses can be selected, such as. B. carboxymethyl cellulose and other cellulose ethers, hydroxyethyl and propyl cellulose and hydroxypropyl methyl cellulose.
• Xanthan (CAS No. 11138-66-2), also called xanthan gum, which is an anionic
• Heteropolysaccharide is that which is usually formed by fermentation from corn sugar and is isolated as the potassium salt. It is produced by Xanthomonas campestris and some other species under aerobic conditions with a molecular weight of 2x106 to 24x106. Xanthan is formed from a chain with ß-1, 4-bound glucose (cellulose) with side chains. The structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate. Xanthan is the name for the first microbial anionic heteropolysaccharide. It is produced by Xanthomonas campestris and some other species under aerobic conditions with a molecular weight of 2-15 106.
• Xanthan is formed from a chain with ß-1, 4-bound glucose (cellulose) with side chains.
• the structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate. The number of pyruvate units determines the viscosity of the xanthane.
• Xanthan is produced in two-day batch cultures with a yield of 70-90%, based on the carbohydrate used. Yields of 25-30 g / l are achieved. The work-up takes place after killing the culture by precipitation with z.
• B. 2-propanol. Xanthan is then dried and ground.
• the cosmetic preparations according to the invention can advantageously contain one or more surfactants. It is advantageous according to the invention if anionic, cationic, nonionic and / or photere surfactants are used as surfactants.
• wash-active anionic surfactants for the purposes of the present invention are, for example, acylamino acids and their salts, such as
• acylglutamates especially sodium acylglutamate
• Sarcosinates for example myristoyl sarcosin, TEA-lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,
• Acyl isethionates for example sodium / ammonium cocoyl isethionate
• Sulfosuccinates for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate and disodium undecylenamido MEA sulfosuccinate, disodium PEG-5 lauryl citrate sulfosuccinate and derivatives,
• sulfuric acid esters such as
• alkyl ether sulfate for example sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium and sodium C ⁇ 2 - ⁇ 3 pareth,
• Alkyl sulfates for example sodium, ammonium and TEA lauryl sulfate.
• Other advantageous anionic surfactants are sodium, ammonium and TEA lauryl sulfate.
• ⁇ taurates for example sodium lauroyl taurate and sodium methyl cocoyl taurate
• ⁇ ether carboxylic acids for example sodium laureth-13 carboxylate and sodium PEG-6 cocamide carboxylate, sodium PEG-7 olive oil carboxylate
• Phosphoric acid esters and salts such as, for example, DEA-Oleth-10 phosphate and Dilureth-4 phosphate,
• alkylsulfonates for example sodium, sodium C1 2 -14 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate, ⁇ acyl glutamates such as di-TEA-palmitoyl aspartate and sodium caprylic / capric glutamate,
• carboxylic acid derivatives such as, for example, lauric acid, aluminum stearate, magnesium alkanolate and zinc decylene,
• Ester carboxylic acids for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate,
• Advantageous wash-active cationic surfactants for the purposes of the present invention are quaternary surfactants. Quaternary surfactants contain at least one N atom that is covalently linked to 4 alkyl or aryl groups. For example, alkyl betaine, alkyl amidopropyl betaine and alkyl amidopropyl hydroxysultain are advantageous. Further advantageous cationic surfactants for the purposes of the present invention are also
• washing-active amphoteric surfactants for the purposes of the present invention are acyl / dialkylethylenediamines, for example sodium, Dinatriumacylamphodi- propionate, umacylamphodiacetat disodium, Natriumacylamphohydroxypropylsulfonat, disodium, sodium acyl, and N-Kokosfettklastedoethyl-N- hydroxyethylglycinate sodium salts.
• Further advantageous amphoteric surfactants are N-alkylamino acids, for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.
• alkanolamides such as cocamide MEA / DEA / MIPA
• esters formed by esterification of carboxylic acids with ethylene oxide, glycerol, sorbitan or other alcohols,
• ⁇ ethers for example ethoxylated alcohols, ethoxylated lanolin, ethoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside, decyl glycoside and cocoglycoside.
• Further advantageous non-ionic surfactants are alcohols and amine oxides, such as cocoamidopropylamine oxide.
• wash-active surfactant or surfactants according to the invention from the group of surfactants which have an HLB value of more than 25, particularly advantageous are those which have an HLB value of more than 35.
• the preparation according to the invention can advantageously contain one or more surfactants in a total concentration of 1.0 to 10.0% by weight, preferably in a total concentration of 2.0 to 5.0% by weight, in each case based on the total weight of the preparation.
• the preparation may also contain abrasives, e.g. Polymer beads or powder made of polyethylene, polypropylene or inorganic oxides or silicates. According to the invention, these have an average particle size of less than 400 ⁇ m, preferably less than 300 ⁇ m, particularly preferably between 250 to 75 ⁇ m, in an amount of 0.1 to 3% by weight, based on the total weight of the formulation, individually or as a mixture of several abrasives.
• abrasives e.g. Polymer beads or powder made of polyethylene, polypropylene or inorganic oxides or silicates. According to the invention, these have an average particle size of less than 400 ⁇ m, preferably less than 300 ⁇ m, particularly preferably between 250 to 75 ⁇ m, in an amount of 0.1 to 3% by weight, based on the total weight of the formulation, individually or as a mixture of several abrasives.
• the preparation according to the invention can also contain, according to the invention, other ingredients, for example alcohols, diols or polyols of low C number, and also their ethers, preferably ethanol, isopropanol, propylene glycol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ether and analog products.
• the preparation according to the invention can also advantageously contain an oil phase according to the invention, which can be formed from one or more lipophilic components.
• Such an oil phase of the preparation according to the invention ie the lipophilic organic constituents, are advantageously chosen from the group of polar oils, for example from the group of lecithins and fatty acid triglycerides, especially the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids of a chain length from 8 to 24, in particular 12 to 18, carbon atoms.
• the fatty acid triglycerides can for example be advantageously selected from the group of synthetic, semi-synthetic and natural oils, such as. B.
• cocoglyceride olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grape seed oil, safflower oil, evening primrose oil, macadamia nut oil and the like.
• z. B natural waxes of animal and vegetable origin, such as beeswax and other insect waxes and berry wax, shea butter and / or lanolin (wool wax).
• further advantageous polar oil components can also be selected from the group of esters from saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids with a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 C atoms and from the group of esters from aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols with a chain length of 3 to 30 C atoms.
• ester oils can then advantageously be selected from the group octyl palmitate, octyl cocoate, octyl isostearate, octyl dodeceyl myristate, octyl dodekanol, cetearyl isononanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-butyl stearate, n-butyl stearate, n-butyl stearate, n-butyl stearate, n-butyl stearate, n , Isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate,
• the oil phase can advantageously be selected from the group of dialkyl ethers and dialkyl carbonates.
• Myritol® 331 by Henkel C ⁇ 2-13 - Alkyl lactate, Di-C ⁇ 2 - 13 alkyl tartrate, triisostearin, dipentaerythrityl hexacaprylate / hexacaprate, propylene glycol monoisostearate, tricaprylin, dimethyl isosorbide. It is particularly advantageous if the oil phase of the formulations according to the invention contains or consists entirely of C 12-15 alkyl benzoate.
• Advantageous oil components are also z.
• the lipid phase can contain the polar oil components in a concentration of up to 40% by weight based on the total weight of the lipid phase.
• the oil phase can also advantageously also contain non-polar oils, for example those which are selected from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, petroleum jelly (petrolatum), paraffin oil, squalane and squalene, polyolefins, hydrogenated polyisobutenes and isohexadecane.
• non-polar oils for example those which are selected from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, petroleum jelly (petrolatum), paraffin oil, squalane and squalene, polyolefins, hydrogenated polyisobutenes and isohexadecane.
• non-polar oils for example those which are selected from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, petroleum jelly (petrolatum), paraffin oil, squalane and squalene, polyolefins, hydrogenated polyisobutenes and
• the oil phase can advantageously also have a content of cyclic or linear silicone oils or consist entirely of such oils, although it is preferred to use an additional content of other oil phase components in addition to the silicone oil or the silicone oils.
• Silicone oils are high-molecular synthetic polymeric compounds in which silicon atoms are linked in a chain and / or network-like manner via oxygen atoms and the remaining valences of silicon by hydrocarbon residues (mostly methyl, more rarely ethyl, propyl, phenyl groups etc.) are saturated.
• the silicone oils are systematically referred to as polyorganosiloxanes.
• the methyl-substituted polyorganosiloxanes which are the most important compounds of this group in terms of quantity and are characterized by the following structural formula are also known as polydimethylsiloxane or dimethicone (INCI). Dimethicone is available in different chain lengths or with different molecular weights.
• Advantageous polyorganosiloxanes for the purposes of the present invention are, for example, dimethylpolysiloxanes [poly (dimethylsiloxane)], which are available, for example, under the trade names Abil 10 to 10,000 from Th. Goldschmidt.
• phenylmethylpolysiloxanes INCI: phenyl dimethicone, phenyl trimethicone
• cyclic silicones octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane
• INCI cyclomethicones
• amino-modified silicones INCI: amodimethicone
• Polysiloxane-polyalkylene copolymers (INCI: Stearyl Dimethicone and Cetyl Dimethicone) and Dialkoxydimethylpolysiloxane (Stearoxy Dimethicone and Behenoxy Stearyl Dimethicone), which are available as different Abil-Wax types from Th. Goldschmidt.
• silicone oils can also be used advantageously for the purposes of the present invention, for example cetyldimethicone, hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane).
• a preparation according to the invention it is advantageous according to the invention to use the lipophilic components of a preparation according to the invention as refatting substances.
• moisturizing substances are used advantageously to choose, for example, such as Purcellinol, Eucerit ® and Neocerit® ®.
• the preparation according to the invention can advantageously contain moisturizing or moisturizing agents (so-called moisturizers).
• Moisturizing or moisturizing agents for the purposes of the present invention are, for example, glycerol, lactic acid and / or lactates, in particular sodium lactate, butylene glycol, propylene glycol, biosaccaride gum-1, glycine soy, ethylhexyloxyglycerol, pyrrolidone carboxylic acid and urea.
• polymeric moisturizers from the group of water-soluble and / or water-swellable and / or water-gelable polysaccharides.
• hyaluronic acid chitosan and / or a fucose-rich polysaccharide
• chitosan and / or a fucose-rich polysaccharide
• the preparation according to the invention advantageously contains one or more conditioners.
• Preferred conditioners according to the invention are, for example, all compounds which are described in Section 4 below in the International Cosmetic Engineering Dictionary and Handbook (Volume 4, publisher: RC Pepe, JA Wenninger, GN McEwen, The Cosmetic, Toiletry, and Fragrance Association, 9th edition, 2002) the keywords Hair Conditioning Agents, Humectants, Skin-Conditioning Agents, Skin-Conditioning Agents- Emollient, Skin-Conditioning Agents-Humactant, Skin-Conditioning Agents-Miscellaneous, Skin-Conditioning Agents-Occlusive and Skin Protectans are all listed in the EP 0934956 (p.11-13) under water soluble conditioning agent and oil soluble conditioning agent.
• Further conditioners which are advantageous according to the invention are, for example, the compounds named polyquaternium according to the international nomenclature for cosmetic ingredients (INCI).
• polyquaternium-1 to polyquaternium-56 but also the polyethylene glycols and polyproylene glycols which are advantageous according to the invention.
• compositions optionally contain the additives customary in cosmetics, for example perfume, dyes, antimicrobial substances, refatting agents, complexing and sequestering agents, pearlescent agents, plant extracts, vitamins, active ingredients, preservatives, bactericides, Repellents, self-tanners (e.g. DHA), depigmenting agents (e.g.
• 8-hexadecen-1, 16-dicarboxylic acid (dioic acid, CAS number 20701-68-2; provisional INCI name octadecendioic acid)), pigments that have a coloring effect, softening, moisturizing and / or moisturizing substances, or other usual components of a cosmetic or dermatological formulation such as emulsifiers, polymers, foam stabilizers, antiperspirant salts (e.g. acidic aluminum and / or aluminum / zirconium salts such as aluminum chlorohydrate and / or
• Aluminum / zirconium chlorohydrate and electrolytes (especially sodium and / or potassium chloride in a total concentration of 0.1 to 50% by weight).
• the cosmetic preparations according to the invention can contain a number of pigments and / or dyes.
• the preparation according to the invention can advantageously be applied to a substrate as an impregnation.
• the substrates according to the invention can be smooth or also surface structured. Surface-structured substrates are preferred according to the invention.
• the combination of the cosmetic preparation according to the invention and an insoluble substrate is also according to the invention.
• the fabric formation can take place by warp and weft, by stitch formation or by interlacing, and / or cohesive and / or adhesive connection of textile fibers. It is preferred according to the invention if the substrate is a composite.
• substrates in the form of cloths which consist of nonwoven, in particular of water-jet bonded and / or water-jet-embossed nonwoven.
• the substrates can advantageously also be designed as a bulk, perforated fleece or mesh.
• Such substrates can have macro embossments of any desired pattern.
• the selection to be made depends on the one hand on the impregnation to be applied and on the other hand on the field of application in which the subsequent cloth is to be used.
• the cloth has a weight of 20 to 120 g / m 2 , preferably 30 to 80 g / m 2, particularly preferably 40 to 60 g / m 2 (measured at 20 ⁇ C ⁇ 2 ° C and with a humidity of 65% ⁇ 5% for 24 hours).
• the thickness of the substrate is preferably 0.2 mm to 2 mm, in particular 0.4 mm to 1.5 mm, very particularly preferably 0.6 mm to 0.9 mm.
• All organic and inorganic fiber materials on a natural and synthetic basis can generally be used as starting materials for the nonwoven fabric of the cloth.
• examples include viscose, cotton, cellulose, jute, hemp, sisal, silk, wool, polypropylene, polyester, polyethylene terephthalate (PET), aramid, nylon, polyvinyl derivatives, polyurethane, polylactide, polyhydroxyalkanoate, cellulose esters and / or polyethylene as well as mineral fibers such as glass fibers or carbon fibers.
• PET polyethylene terephthalate
• aramid nylon
• polyvinyl derivatives polyurethane
• polylactide polyhydroxyalkanoate
• cellulose esters polyhydroxyalkanoate
• cellulose esters polyhydroxyalkanoate
• the present invention is not limited to the materials mentioned, but a large number of further fibers can be used for the formation of nonwovens. For the purposes of the present invention, it is particularly advantageous if the fibers used are not water-soluble.
• the fibers consist of a mixture of 60% to 80% viscose with 40% to 20% PET, in particular 70% viscose and 30% PET.
• a mixture of 70% viscose and 30% PET is particularly advantageous.
• a fleece according to the invention can have a mixture of three different fiber materials. In such a case, a mixture of 40% to 80% viscose with 50% to 20% PET and 1 to 30% cotton is preferred. A mixture of 40% viscose and 50% PET and 10% cotton is particularly preferred according to the invention.
• Fibers made of high-strength polymers such as polyamide, polyester and / or highly stretched polyethylene are also particularly advantageous.
• the fibers can also be colored in order to emphasize and / or increase the visual attractiveness of the fleece.
• the fibers can additionally contain UV stabilizers and / or preservatives.
• the fibers used to form the cloth preferably have a water absorption rate of more than 60 mm / [10 min] (measured with the EDANA test 10.1-72), in particular more than 80 mm / [10 min].
• the fibers used to form the cloth preferably have a water absorption capacity of more than 5 g / g (measured with the EDANA test 10.1-72), in particular more than 8 g / g.
• Advantageous wipes in the sense of the present invention have a tensile strength of in particular [N / 50mm] in the dry state machine direction> 60, preferably> 80 transverse direction> 20, preferably> 30 in the soaked state machine direction> 4, preferably> 60 transverse direction> 10, preferably> 20
• the stretchability of advantageous cloth is preferably 15% to 100%, preferably 20% and 50% in the transverse direction, 40% to 120%, preferably 50% and 85% in the soaked state, machine direction 15% to 100%, preferably in the dry state 20% and 40% transverse direction 40% to 120%, preferably 50% and 85%
• the substrate in a particular dosage form according to the invention of such substrates according to the invention, can be dried after impregnation with the preparation in order to subsequently be presented to the user in the form of a dry cleaning cloth.
• the preparation according to the invention can advantageously be stored in a foam dispenser and used therefrom.
• the foam dispenser can advantageously be a mechanical pump dispenser (pump donor) or an aerosol can.
• the preparations according to the invention can advantageously be foamed according to the invention with a propellant gas. According to the invention, this is used in an amount of 0.5 to 20% by weight, particularly advantageously in an amount of 5 to 15 and very particularly advantageously in an amount of 8 to 11% by weight, based in each case on the total weight of the formulation.
• Propellants which are particularly advantageous according to the invention are propane, isobutane and n-butane and mixtures thereof.
• the preparations according to the invention can also advantageously be stored in double-chamber packaging.
• dicarboxylic acids to increase the temperature stability of soap-containing liquid or pasty cosmetic cleaning preparations.
• the preparation according to the invention is used as a shampoo, shower gel, foam or bath bath and as a hand wash lotion or shaving cream.
• the use of the cosmetic and / or dermatological preparation according to the invention for cleaning and washing clothes and textiles (“detergent”) is in accordance with the invention.
• the use of the cosmetic and / or dermatological preparation according to the invention for cleaning objects of everyday life eg dishes, table and cabinet surfaces, cars
• the use of the cosmetic and / or dermatological preparation according to the invention for the cleaning and care of the fur and coat of mammals, in particular of domestic and farm animals.

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• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Veterinary Medicine (AREA)
• Emergency Medicine (AREA)
• Animal Behavior & Ethology (AREA)
• General Health & Medical Sciences (AREA)
• Public Health (AREA)
• Birds (AREA)
• Epidemiology (AREA)
• Biochemistry (AREA)
• Dispersion Chemistry (AREA)
• Dermatology (AREA)
• Cosmetics (AREA)
• Detergent Compositions (AREA)

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• 2003
  • 2003-10-09 DE DE2003146954 patent/DE10346954A1/de not_active Withdrawn
• 2004
  • 2004-09-21 CN CN 200480018165 patent/CN1813049A/zh active Pending
  • 2004-09-21 WO PCT/EP2004/052254 patent/WO2005037971A1/de active Application Filing

Patent Citations (7)

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