WO2005035689B1 - Procede de conversion de gaz naturel en hydrocarbures liquides - Google Patents
Procede de conversion de gaz naturel en hydrocarbures liquidesInfo
- Publication number
- WO2005035689B1 WO2005035689B1 PCT/US2004/015292 US2004015292W WO2005035689B1 WO 2005035689 B1 WO2005035689 B1 WO 2005035689B1 US 2004015292 W US2004015292 W US 2004015292W WO 2005035689 B1 WO2005035689 B1 WO 2005035689B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- stream
- hydrogen
- reactive
- reactor
- natural gas
- Prior art date
Links
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract 40
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract 39
- 239000003345 natural gas Substances 0.000 title claims abstract 28
- 239000007788 liquid Substances 0.000 title claims abstract 27
- 238000000034 method Methods 0.000 title claims abstract 15
- 238000006243 chemical reaction Methods 0.000 title claims 7
- 239000001257 hydrogen Substances 0.000 claims abstract 31
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 31
- 239000007789 gas Substances 0.000 claims abstract 29
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 29
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims abstract 21
- 239000005977 Ethylene Substances 0.000 claims abstract 15
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract 15
- 230000003197 catalytic Effects 0.000 claims abstract 11
- 238000002485 combustion reaction Methods 0.000 claims abstract 7
- 238000010438 heat treatment Methods 0.000 claims abstract 3
- 239000000047 product Substances 0.000 claims 46
- 238000005984 hydrogenation reaction Methods 0.000 claims 16
- 239000001301 oxygen Substances 0.000 claims 14
- 229910052760 oxygen Inorganic materials 0.000 claims 14
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 14
- 239000000446 fuel Substances 0.000 claims 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 11
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 11
- 239000001569 carbon dioxide Substances 0.000 claims 11
- 239000007800 oxidant agent Substances 0.000 claims 8
- 230000001590 oxidative Effects 0.000 claims 8
- 230000005611 electricity Effects 0.000 claims 6
- 238000010791 quenching Methods 0.000 claims 6
- 238000002156 mixing Methods 0.000 claims 5
- 230000000171 quenching Effects 0.000 claims 5
- 229940117927 Ethylene Oxide Drugs 0.000 claims 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 4
- 239000000463 material Substances 0.000 claims 3
- 230000003134 recirculating Effects 0.000 claims 3
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 239000012263 liquid product Substances 0.000 claims 2
- 230000001737 promoting Effects 0.000 claims 2
- 238000004064 recycling Methods 0.000 claims 2
- 239000003570 air Substances 0.000 claims 1
- 239000006227 byproduct Substances 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 238000010891 electric arc Methods 0.000 claims 1
- 238000010248 power generation Methods 0.000 claims 1
- -1 syngas Substances 0.000 claims 1
- 230000002378 acidificating Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Abstract
L'invention concerne un procédé destiné à la conversion de gaz naturel en hydrocarbures liquides, consistant à chauffer le gaz à une plage de température sélectionnée pendant un laps de temps suffisant et/ou à produire la combustion du gaz à une température suffisante et dans des conditions adaptées, pendant un temps de réaction suffisant pour convertir une partie du flux gazeux en hydrocarbures réactifs, principalement en éthylène ou en acétylène. Le gaz contenant l'acétylène peut être séparé de façon que l'acétylène soit converti en éthylène. L'éthylène peut être mis en réaction en présence d'un catalyseur acide pour produire un liquide constitué principalement de pétrole ou d'essence. Une partie du gaz naturel entrant ou de l'hydrogène produit dans le procédé peut être utilisée pour chauffer le reste du gaz naturel à la plage de température sélectionnée. Les constituants du gaz réactif sont utilisés dans une étape de liquéfaction catalytique et/ou pour un autre traitement chimique.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04817184A EP1667949A4 (fr) | 2003-09-23 | 2004-05-14 | Procede de conversion de gaz naturel en hydrocarbures liquides |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US50520403P | 2003-09-23 | 2003-09-23 | |
US60/505,204 | 2003-09-23 | ||
US10/844,852 US7183451B2 (en) | 2003-09-23 | 2004-05-13 | Process for the conversion of natural gas to hydrocarbon liquids |
US10/844,852 | 2004-05-13 |
Publications (3)
Publication Number | Publication Date |
---|---|
WO2005035689A2 WO2005035689A2 (fr) | 2005-04-21 |
WO2005035689A3 WO2005035689A3 (fr) | 2005-12-29 |
WO2005035689B1 true WO2005035689B1 (fr) | 2006-02-16 |
Family
ID=34316755
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2004/015292 WO2005035689A2 (fr) | 2003-09-23 | 2004-05-14 | Procede de conversion de gaz naturel en hydrocarbures liquides |
Country Status (3)
Country | Link |
---|---|
US (8) | US7183451B2 (fr) |
EP (1) | EP1667949A4 (fr) |
WO (1) | WO2005035689A2 (fr) |
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US5414170A (en) | 1993-05-12 | 1995-05-09 | Stone & Webster Engineering Corporation | Mixed phase front end C2 acetylene hydrogenation |
DE59600215D1 (de) | 1995-03-10 | 1998-07-02 | Basf Ag | Weiterverwendung des Verdünnungsgases aus der Gasphasen-Partialoxidation einer organischen Verbindung |
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CN1519053A (zh) | 1998-09-03 | 2004-08-11 | 催化剂组合物 | |
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WO2003015916A1 (fr) | 2000-09-29 | 2003-02-27 | China Petroleum And Chemical Corporation | Catalyseur d'hydrocraquage selectif des hydrocarbures insatures, son procede de fabrication et ses applications |
-
2004
- 2004-05-13 US US10/844,852 patent/US7183451B2/en not_active Expired - Lifetime
- 2004-05-14 WO PCT/US2004/015292 patent/WO2005035689A2/fr active Application Filing
- 2004-05-14 EP EP04817184A patent/EP1667949A4/fr not_active Withdrawn
-
2007
- 2007-01-31 US US11/669,451 patent/US7667085B2/en not_active Expired - Lifetime
-
2010
- 2010-01-08 US US12/684,385 patent/US7915464B2/en not_active Expired - Fee Related
- 2010-01-08 US US12/684,395 patent/US7915465B2/en not_active Expired - Fee Related
- 2010-01-08 US US12/684,213 patent/US7915461B2/en not_active Expired - Fee Related
- 2010-01-08 US US12/684,221 patent/US7915462B2/en not_active Expired - Fee Related
- 2010-01-08 US US12/684,373 patent/US7915463B2/en not_active Expired - Fee Related
- 2010-01-08 US US12/684,401 patent/US7915466B2/en not_active Expired - Fee Related
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