WO2005012216A1 - Silber, vanadium und ein promotormetall enthaltendes multimetalloxid und dessen verwendung - Google Patents
Silber, vanadium und ein promotormetall enthaltendes multimetalloxid und dessen verwendung Download PDFInfo
- Publication number
- WO2005012216A1 WO2005012216A1 PCT/EP2004/008296 EP2004008296W WO2005012216A1 WO 2005012216 A1 WO2005012216 A1 WO 2005012216A1 EP 2004008296 W EP2004008296 W EP 2004008296W WO 2005012216 A1 WO2005012216 A1 WO 2005012216A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- catalyst
- multimetal oxide
- weight
- catalytically active
- precatalyst
- Prior art date
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 18
- 239000002184 metal Substances 0.000 title claims abstract description 18
- 229910044991 metal oxide Inorganic materials 0.000 title abstract 3
- 229910052720 vanadium Inorganic materials 0.000 title description 9
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title description 9
- 239000004332 silver Substances 0.000 title description 5
- 229910052709 silver Inorganic materials 0.000 title description 4
- 239000003054 catalyst Substances 0.000 claims abstract description 128
- 239000012041 precatalyst Substances 0.000 claims abstract description 36
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 35
- 230000003647 oxidation Effects 0.000 claims abstract description 33
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 26
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 9
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 9
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 6
- 239000001301 oxygen Substances 0.000 claims abstract description 6
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 5
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 5
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 4
- 229910052797 bismuth Inorganic materials 0.000 claims abstract 2
- 229910052703 rhodium Inorganic materials 0.000 claims abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-dimethylbenzene Natural products CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 39
- 239000007789 gas Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 23
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 20
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 20
- 229940078552 o-xylene Drugs 0.000 claims description 19
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 18
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 16
- RAVDHKVWJUPFPT-UHFFFAOYSA-N silver;oxido(dioxo)vanadium Chemical compound [Ag+].[O-][V](=O)=O RAVDHKVWJUPFPT-UHFFFAOYSA-N 0.000 claims description 16
- 150000001299 aldehydes Chemical class 0.000 claims description 14
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims description 14
- 150000001735 carboxylic acids Chemical class 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 11
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 9
- 229910001882 dioxygen Inorganic materials 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 7
- 238000010586 diagram Methods 0.000 claims description 7
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 7
- 229910052792 caesium Inorganic materials 0.000 claims description 6
- -1 cesium compound Chemical class 0.000 claims description 6
- 238000011065 in-situ storage Methods 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 229910000906 Bronze Inorganic materials 0.000 claims description 4
- 239000010974 bronze Substances 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims description 4
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 2
- 230000003247 decreasing effect Effects 0.000 claims description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 35
- 239000000725 suspension Substances 0.000 description 26
- 238000000576 coating method Methods 0.000 description 21
- 239000011248 coating agent Substances 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 150000001875 compounds Chemical class 0.000 description 13
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- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 10
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- 239000011230 binding agent Substances 0.000 description 10
- 238000001035 drying Methods 0.000 description 10
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- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 229940100890 silver compound Drugs 0.000 description 7
- 150000003379 silver compounds Chemical class 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 238000007669 thermal treatment Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
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- 239000012876 carrier material Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000005711 Benzoic acid Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 235000010233 benzoic acid Nutrition 0.000 description 5
- 239000000543 intermediate Substances 0.000 description 5
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 5
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- 150000003839 salts Chemical class 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 4
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 4
- FLJPGEWQYJVDPF-UHFFFAOYSA-L caesium sulfate Chemical compound [Cs+].[Cs+].[O-]S([O-])(=O)=O FLJPGEWQYJVDPF-UHFFFAOYSA-L 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical class [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000012495 reaction gas Substances 0.000 description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 101710134784 Agnoprotein Proteins 0.000 description 3
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
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- OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 description 3
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- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 2
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- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
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- 235000019792 magnesium silicate Nutrition 0.000 description 2
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
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- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
- C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/682—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium, tantalum or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
- C01G31/006—Compounds containing, besides vanadium, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
- C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/10—Silver compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0221—Coating of particles
- B01J37/0223—Coating of particles by rotation
Definitions
- the invention relates to a multimetal oxide containing silver, vanadium and a promoter metal, its use for the production of precatalysts and catalysts for the gas phase partial oxidation of aromatic hydrocarbons, the (pre) catalysts thus obtained and a process for the production of aldehydes, carboxylic acids and / or carboxylic anhydrides using the catalysts.
- aldehydes, carboxylic acids and / or carboxylic acid anhydrides is industrially produced by the catalytic gas phase oxidation of aromatic hydrocarbons such as benzene, o-, m- or p-xylene, naphthalene, toluene or durol (1, 2,4,5-tetramethylbenzene)
- Fixed bed reactors preferably tube bundle reactors.
- benzaldehyde, benzoic acid, maleic anhydride, phthalic anhydride, isophthalic acid, terephthalic acid or pyromellitic acid anhydride are obtained.
- a mixture of a gas containing molecular oxygen, for example air, and the starting material to be oxidized is generally passed through a plurality of tubes arranged in a reactor, in which there is a bed of at least one catalyst.
- WO 00/27753 and WO 01/85337 describe multimetal oxides containing silver and vanadium oxide and their use for the partial oxidation of aromatic hydrocarbons.
- the object of the invention is to improve the yields achieved with these catalysts without impairing the selectivities.
- a has a value from 0.3 to 1.9
- Q represents an element selected from P, As, Sb and / or Bi, b has a value from 0 to 0.3,
- M represents a metal selected from Nb, Ce, W, Mn, Ta, Pd, Pt, Ru and / or Rh,
- c has a value from 0.001 to 0.5, with the proviso that (a-c)> 0.1,
- d is a number which is determined by the valency and frequency of the elements in formula I other than oxygen
- e has a value from 0 to 20.
- the invention also relates to a precatalyst which can be converted into a catalyst for the gas phase partial oxidation of aromatic hydrocarbons and which consists of an inert non-porous support and at least one layer applied thereon which comprises a multimetal oxide defined above.
- the invention also relates to a catalyst for the gas phase partial oxidation of aromatic hydrocarbons, which consists of an inert non-porous support and at least one layer applied thereon, which comprises as a catalytically active composition a silver-vanadium oxide bronze which comprises at least one from the group Nb, Ce , W, Mn, Ta, Pd, Pt, Ru and / or Rh contains selected metal M, and wherein the Ag: V atomic ratio is 0.15 to 0.95 and the M: V atomic ratio is 0.0005 to 0.25 , preferably 0.001 to 0.15.
- a catalyst for the gas phase partial oxidation of aromatic hydrocarbons which consists of an inert non-porous support and at least one layer applied thereon, which comprises as a catalytically active composition a silver-vanadium oxide bronze which comprises at least one from the group Nb, Ce , W, Mn, Ta, Pd, Pt, Ru and / or Rh contains selected metal M, and wherein the Ag: V atomic
- the invention also relates to a process for the preparation of aldehydes, carboxylic acids and / or carboxylic anhydrides, in which a gaseous stream comprising an aromatic hydrocarbon and a gas containing molecular oxygen is brought into contact at elevated temperature with a catalyst defined above.
- the multimetal oxide according to the invention is preferably in a crystal structure, the powder X-ray diagram of which is due to diffraction reflections at the interplanar spacings d 15.23 ⁇ 0.6, 12.16 ⁇ 0.4, 10.68 ⁇ 0.3, 3.41 ⁇ 0.04, 3 , 09 ⁇ 0.04, 3.02 ⁇ 0.04, 2.36 ⁇ 0.04 and 1.80 ⁇ 0.04 A.
- the X-ray diffraction reflections are given in the form of the network plane distances d [A] which are independent of the wavelength of the X-radiation used, and which can be calculated from the measured diffraction angle using Bragg's equation.
- the variable a preferably has a value of 0.5 to 1.0, and particularly preferably 0.6 to 0.9, the value of the variable b is preferably 0 to 0.1, and the value of the variable c is preferably 0.005 to 0.2, in particular 0.01 to 0.1.
- the number d is determined from the valency and frequency of the elements other than oxygen in the multimetal oxide of the formula I.
- the number e which is a measure of the water content, is preferably 0 to 5.
- the specific surface area according to BET is in generally more than 1 m 2 / g, preferably 3 to 250 m 2 / g, in particular 10 to 250 m 2 / g and particularly preferably 20 to 80 m 2 / g.
- Preferred metals M are Nb, Ce, W, Mn and Ta, in particular Ce and Mn, of which Ce is most preferred.
- a suspension of vanadium pentoxide (V 2 O 5 ) is generally heated with the solution of a silver compound and a solution of a compound of metal component M and, if appropriate, the solution of a compound of Q.
- polar organic solvents such as polyols, polyethers or amines, e.g. B. pyridine, preferably water is used as solvent.
- Silver nitrate is preferably used as the silver salt, the use of other soluble silver salts, e.g. B. silver acetate, silver perchlorate or silver fluoride is also possible.
- the element or elements Q from the group P, As, Sb and / or Bi can be used in elemental form or as oxides or hydroxides. However, they are preferably used in the form of their soluble compounds, especially their organic or inorganic water-soluble compounds. Particularly preferred among these are the inorganic water-soluble compounds, especially the alkali and ammonium salts and in particular the partially neutralized or free acids of these elements, such as phosphoric acid, hydrochloric acid, antimony hydrochloric acid, the ammonium hydrogen phosphates, arsenates, antimonates and bismuthates and the alkali hydrogen phosphates, arsenates. -antimonates and bismuthates.
- phosphorus is very particularly preferably used on its own, in particular in the form of phosphoric acid, phosphorous acid, hypophosphorous acid, ammonium phosphate or phosphoric acid ester and especially as ammonium dihydrogen phosphate.
- salts of the metal component M those are generally chosen which are soluble in the solvent used. If water is used as a solvent in the production of the multimetal oxides according to the invention, the perchlorates or carboxylates, in particular the acetates, of the metal component M can be used, for example.
- the nitrates of the metal component M in question are preferably used, in particular citrate or manganese nitrate.
- the reaction of the V 2 O 5 with the silver compound, the compound of the metal component M and optionally Q can generally be carried out at room temperature or at elevated temperature.
- the reaction is carried out at temperatures from 20 to 375 ° C., preferably at 20 to 100 ° C. and particularly preferably at 60 to 100 ° C.
- the temperature of the reaction is above the temperature of the boiling point of the solvent used, the reaction is expediently carried out in a pressure vessel under the autogenous pressure of the reaction system.
- the reaction conditions are preferably selected so that the reaction can be carried out at atmospheric pressure.
- the duration of this reaction can be 10 minutes to 3 days, depending on the type of starting materials converted and the temperature conditions used. An extension of the reaction time of the reaction, for example to 5 days and more, is possible.
- the reaction of the V 2 O 5 with the silver compound, the compound of the metal component M to the multimetal oxide according to the invention is carried out over a period of 6 to 24 hours.
- the orange-red color of the V 2 ⁇ 5 suspension changes and the new compound forms in the form of a dark brown suspension.
- the amounts of V 2 O 5 , silver compound and the compound of the metal component M resulting from a and c of formula I are reacted with one another to produce it.
- the silver compound is generally reacted with the vanadium pentoxide in a ratio which corresponds to an Ag: V atomic ratio of 0.15 to 0.95, preferably 0.25 to 0.5, corresponding to a value for a in formula I. from 0.3 to 1.9 or 0.5 to 1.0.
- the silver compound is particularly preferably added with respect to the vanadium pentoxide in an amount which corresponds to an atomic ratio Ag: V of 0.3 to 0.45, corresponding to a value for a in formula I of 0.6 to 0.9.
- the compound of the metal component M is generally used in an amount of 0.0005 to 0.25, preferably 0.001 to 0.1, based on V 2 O 5 .
- the multimetal oxide according to the invention thus formed can be isolated from the reaction mixture and stored until further use. Isolation of the multimedia talloxides can e.g. B. by filtering the suspension and drying the solid obtained, the drying both in conventional dryers, but also, for. B. can be carried out in freeze dryers.
- the drying of the multimetal oxide suspension obtained is particularly advantageously carried out by spray drying. It may be advantageous to wash the multimetal oxide obtained in the reaction salt-free before it dries.
- Spray drying is generally carried out under atmospheric pressure or reduced pressure. Depending on the pressure used and the solvent used, the inlet temperature of the drying gas is determined - air is generally used as such, but other drying gases such as nitrogen or argon can of course also be used.
- the inlet temperature of the drying gas into the spray dryer is advantageously chosen so that the outlet temperature of the drying gas cooled by evaporation of the solvent does not exceed 200 ° C. for a longer period.
- the outlet temperature of the drying gas is set to 50 to 150 ° C., preferably 100 to 140 ° C. If storage of the multimetal oxide is not intended, the multimetal oxide suspension obtained can also be used without further isolation and drying of the multimetal oxide, for example for the production of the precatalysts according to the invention by coating.
- the multimetal oxides according to the invention are used as a precursor compound for the preparation of the catalytically active composition of catalysts such as are used for the gas phase oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic acid anhydrides with a gas containing molecular oxygen.
- the multimetal oxides according to the invention are preferably used for the production of so-called coated catalysts, they can also be used as a precursor for the production of conventional supported catalysts or of unsupported catalysts, that is to say catalysts which do not contain any support material.
- the catalysts according to the invention for the partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic acid anhydrides from the multimetal oxides according to the invention are expediently carried out via the stage of a so-called "precatalyst" which can be stored and traded as such and from which the active catalyst is either by thermal treatment can be produced or generated in situ in the oxidation reactor under the conditions of the oxidation reaction.
- the precatalyst is therefore a precursor of the catalyst which consists of an inert non-porous support material and at least one layer applied in the form of a shell, this layer preferably 30 to 100% by weight, in particular 50 to 100% by weight .
- the layer consists entirely of a multimetal oxide according to formula I.
- the catalytically active layer contains other components besides the multimetal oxide according to formula I, this can be done e.g. B. inert materials such as silicon carbide or steatite, but also other known catalysts for the oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic acid anhydrides based on vanadium oxide / anatase.
- the precatalyst preferably contains 5 to 25% by weight, based on the total weight of the precatalyst, of multimetal oxide.
- carrier materials of the prior art such as are advantageously used in the production of shell catalysts for the oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic acid anhydrides, can be used as an inert, non-porous support material for the precatalysts and coated catalysts according to the invention, for example quartz (SiO 2 ), porcelain, magnesium oxide, tin dioxide, silicon carbide, rutile, alumina (Al 2 O 3 ), aluminum silicate, steatite (magnesium silicate), zirconium silicate, cerium silicate or mixtures of these carrier materials.
- quartz SiO 2
- porcelain porcelain
- magnesium oxide tin dioxide
- silicon carbide silicon carbide
- rutile rutile
- aluminum silicate steatite (magnesium silicate), zirconium silicate, cerium silicate or mixtures of these carrier materials.
- non-porous is to be understood in the sense of "except for technically ineffective amounts of pores non-porous", since technically inevitably a small number of pores can be present in the carrier material, which ideally should not contain any pores.
- Steatite and silicon carbide are particularly worth mentioning as advantageous carrier materials.
- the shape of the support material is generally not critical for the precatalysts and coated catalysts according to the invention.
- catalyst supports in the form of spheres, rings, tablets, spirals, tubes, extrudates or grit can be used.
- the dimensions of these catalyst supports correspond to those of the catalyst supports commonly used for the production of shell catalysts for the gas phase partial oxidation of aromatic hydrocarbons.
- the abovementioned support materials in powder form can also be mixed into the catalytically active composition of the coated catalysts according to the invention.
- the suspension obtained in the reaction of the vanadium pentoxide with a silver compound, a compound of the metal component M and optionally Q according to the processes of DE-A 16 92938 and DE-A 1769998 can be applied in a heated coating drum at elevated temperature to the inert carrier material existing catalyst supports are sprayed until the desired amount of multimetal oxide, based on the total weight of the precatalyst, is reached.
- fluidized bed coaters as described in DE-A 12 80 756, can be used for the shell-shaped application of the multimetal oxide according to the invention to the catalyst support.
- a slurry of the powder of the multimetal oxide according to the invention obtained after isolation and drying can be used in these coating processes.
- organic binders preferably copolymers, dissolved or advantageously added in the form of an aqueous dispersion, generally using binder contents of 10 to 20% by weight, based on the solids content of the suspension or slurry of the multimetal oxide according to the invention.
- Suitable binders are e.g. B.
- coating temperatures of 20 to 500 ° C. are generally used, it being possible for the coating in the coating apparatus to be carried out under atmospheric pressure or under reduced pressure.
- the coating is generally carried out at 0 ° C. to 200 ° C., preferably at 20 to 150 ° C., in particular at room temperature to 100 ° C.
- higher coating temperatures e.g. B. temperatures of 200 to 500 ° C to apply.
- part of the binder can remain in the layer applied to the catalyst support.
- the binder escapes from the applied layer by thermal decomposition and / or combustion.
- the conversion of the precatalyst into an invented The coated catalyst according to the invention can also be carried out by thermal treatment at temperatures above 500 ° C., for example at temperatures up to 650 ° C., preferably the thermal treatment is carried out at temperatures above 200 to 500 ° C., in particular at 300 to 450 ° C.
- the multimetal oxides according to the invention decompose with the formation of catalytically active silver vanadium oxide bronzes.
- Silver-vanadium oxide bronzes are understood to mean silver-vanadium oxide compounds with an atomic Ag: V ratio of less than 1. They are generally semiconducting or metallically conductive, oxidic solids, which preferably crystallize in layer or tunnel structures, the vanadium in the [V 2 O 5 ] host lattice being partially reduced to V (IV).
- some of the multimetal oxides applied to the catalyst support can already be converted to catalytically active silver-vanadium oxide bronzes and / or silver-vanadium oxide compounds which are not elucidated crystallographically with regard to their structure and which can be converted into the silver-vanadium oxide bronzes mentioned. be decomposed.
- This decomposition takes place practically completely at coating temperatures of 300 to 500 ° C., so that with a coating at 300 to 500 ° C. the coated catalyst according to the invention can be obtained without passing through the precursor of the precatalyst.
- the shell catalysts according to the invention are preferably produced from the precatalysts according to the invention or are produced in situ from these precatalysts in the reactor for the oxidation of the aromatic hydrocarbons.
- the multimetal oxides contained in the precatalyst decompose to silver vanadium oxide bronzes.
- This conversion of the multimetal oxides according to the invention contained in the precatalyst to silver-vanadium oxide bronzes takes place in particular in situ in the reactor for the gas phase partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic acid anhydrides, for example in the reactor for producing phthalic anhydride from o-xylene and / or naphthalene , at the temperatures generally used of 300 to 450 ° C., if instead of the coated catalyst according to the invention a precatalyst according to the invention is used in this reaction.
- Another possibility for producing a coated catalyst according to the invention consists in the thermal treatment of the multimetal oxide powder according to the invention at temperatures of above 200 to 650 ° C. and the coating of the inert non-porous catalyst support, optionally with the addition of a binder, with the silver vanadium oxide obtained in this way -Bronze.
- the coated catalysts according to the invention are particularly preferably from the precatalysts according to the invention in one stage or, if appropriate, after a thermal treatment in the course of or after the coating of the catalyst support, in several stages, in particular in one stage, in each case in situ in the oxidation reactor under the conditions of the oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic anhydrides.
- the catalytically active shell of the shell catalyst produced according to the invention generally contains 30 to 100% by weight, preferably 50 to 100% by weight, based on the total weight of the catalytically active shell, of the silver-vanadium oxide bronzes thus produced, the silver and the vanadium in the catalytically active shell is generally present in an Ag: V atomic ratio of 0.15 to 0.95, preferably 0.25 to 0.5 and particularly preferably 0.3 to 0.45.
- the catalytically active layer of the coated catalysts according to the invention particularly preferably consists entirely of the silver vanadium oxide bronzes produced according to the invention. If the catalytically active layer or layers contains other components besides the silver-vanadium oxide bronzes produced according to the invention, this can be done e.g. B.
- Inert materials of the prior art such as silicon carbide or steatite, but also or non-inventive catalyst compounds for the oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic acid anhydrides such.
- the layer thickness of the catalyst shell containing the catalytically active constituents is generally 10 to 250 mm. This also applies if the catalyst bowl consists of several layers applied in succession.
- the BET surface area of the coated catalysts according to the invention is generally 2 to 100 m 2 / g, preferably 2 to 40 m 2 / g and particularly preferably 3 to 20 m 2 / g.
- the coated catalysts according to the invention are used for the partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic acid anhydrides, in particular for the gas phase partial oxidation of o-xylene and / or naphthalene to phthalic anhydride or of toluene to benzoic acid and / or benzaldehyde, with a gas containing molecular oxygen ,
- the catalysts according to the invention can be used alone or in combination with other, differently active catalysts, for example catalysts of the prior art based on vanadium oxide / anatase, the different catalysts generally in separate catalyst beds which are in one or more fixed catalyst beds can be arranged in the reactor.
- the coated catalysts or precatalysts according to the invention are filled into the reaction tubes of a tubular reactor for this purpose. B. by means of a molten salt, thermostated to the reaction temperature. If a precatalyst according to the invention is used instead of the coated catalyst according to the invention, this results under the temperature conditions of the partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and / or carboxylic acid anhydrides, in particular in the partial oxidation of o-xylene and / or naphthalene to phthalic anhydride or in the partial oxidation of toluene to benzoic acid and benzaldehyde, a coated catalyst according to the invention.
- the reaction gas is at temperatures of 100 to 650 ° C and preferably 250 to 480 ° C and at an overpressure of generally 0.1 to 2.5 bar, preferably from 0.3 to 1.5 bar with a space velocity of generally 750 to 5000 h " .
- the reaction gas supplied to the catalyst is generally produced by mixing a gas containing molecular oxygen, which in addition to oxygen may also contain suitable reaction moderators and / or diluents, such as water vapor, carbon dioxide and / or nitrogen, with the aromatic hydrocarbon to be oxidized, where the molecular oxygen-containing gas generally 1 to 100 vol .-%, preferably 2 to 50 vol .-% and particularly preferably 10 to 30 vol .-% oxygen, 0 to 30 vol .-%, preferably 0 to 20 vol .-% % Water vapor and 0 to 50 vol .-%, preferably 0 to 1 vol .-% carbon dioxide, the rest nitrogen.
- a gas containing molecular oxygen which in addition to oxygen may also contain suitable reaction moderators and / or diluents, such as water vapor, carbon dioxide and / or nitrogen
- the molecular oxygen-containing gas generally 1 to 100 vol .-%, preferably 2 to 50 vol .-% and particularly preferably 10 to 30
- the molecular oxygen-containing gas is generally charged with 30 to 300 g per Nm 3 , preferably with 70 to 150 g per Nm 3, of the aromatic hydrocarbon to be oxidized. Air is particularly advantageously used as the molecular oxygen-containing gas
- the gas phase partial oxidation is advantageously carried out in such a way that two or more zones, preferably two zones, of the catalyst bed in the reaction tube are thermostatted to different reaction temperatures, for example reactors with separate salt baths, as described in DE-A 2201 528 or DE-A 28 30 765 are described, can be used.
- the reaction is carried out in two reaction zones, as described in DE-A 40 13 051, the reaction zone located towards the gas inlet of the reaction gas, which generally comprises 30 to 80% by volume of the total catalyst volume, is reduced to 1 to 20 ° C, preferably by 1 to 10 ° C and in particular by 2 to 8 ° C higher reaction temperature than the reaction zone towards the gas outlet thermostatted.
- Such a procedure is referred to as two- or multi-zone structuring of the reactor.
- the gas phase oxidation can also be carried out without division into temperature zones at a uniform reaction temperature.
- the aromatic hydrocarbon is first of all carried out on a bed of the invention Shell catalyst converted into a reaction mixture with partial conversion.
- the reaction mixture obtained or a fraction thereof can then be brought into contact with at least one further catalyst whose catalytically active composition contains vanadium pentoxide and anatase.
- the gaseous stream is preferably passed in succession over a bed of an upstream catalyst and a bed of a downstream catalyst, the bed of the upstream catalyst containing a catalyst according to the invention and the bed of the downstream catalyst containing at least one catalyst whose catalytically active mass Contains vanadium pentoxide and anatase.
- the catalytically active mass of the downstream catalyst contains 1 to 40% by weight of vanadium oxide, calculated as VO 5 , 60 to 99% by weight of titanium dioxide, calculated as TiO 2 , up to 1% by weight of a cesium compound as Cs, up to 1% by weight of a phosphorus compound, calculated as P, and up to 10% by weight of antimony oxide, calculated as Sb 2 O 3 .
- the bed of the downstream catalyst advantageously comprises at least two layers of catalysts whose catalytically active mass has a different Cs content, the Cs content decreasing in the direction of flow of the gaseous stream.
- the partially reacted reaction mixture contains e.g. B. phthalic anhydride and other oxidation products such as o-tolylaldehyde, o-tolylcarboxylic acid and phthalide, and unreacted o-xylene. It can then be processed further by either
- o-xylene from the phthalic anhydride and the other oxidation products, which are intermediates in the reaction path from o-xylene to phthalic anhydride, is separated off and recycled and the stream of phthalic anhydride and intermediates of one or more further catalyst beds with, for. B. is supplied to a vanadium oxide / anatase-based coated catalyst, where the intermediates are selectively oxidized to phthalic anhydride; or by
- Benzaldehyde is used, for example, as a flavoring.
- the powder obtained had a BET specific surface area of 61 m 2 / g.
- a powder X-ray diagram of the powder obtained was recorded using a D 5000 diffractometer from Siemens using Cu-K ⁇ radiation (40 kV, 30 mA). The diffractometer was equipped with an automatic primary and secondary aperture system as well as a secondary monochromator and scintillation detector.
- the powder obtained had a BET specific surface area of 58 m 2 / g.
- a powder X-ray diagram was recorded of the powder obtained.
- the following network plane distances d [ ⁇ ] with the associated relative intensities [%] were obtained from the powder X-ray diagram: 15.09 (6.8), 11, 98 (5.7), 10.61 (9.4), 4, 36 (16.8), 3.84 (14.7), 3.40 (81, 7), 3.09 (61, 1), 3.01 (100), 2.58 (26.4), 2.47 (27.9), 2.41 (21.6), 2.36 (37.8), 2.04 (32.2), 1.93 (28.9), 1.80 (42 , 2), 1, 55 (43.4).
- the powders thus produced were applied to magnesium silicate balls as follows: 300 g of steatite balls with a diameter of 3.5 to 4 mm were in a coating drum at 20 ° C. for 20 min with 40 g of Coated powder and 4.4 g of oxalic acid with the addition of 35.3 g of a mixture containing 60% by weight of water and 40% by weight of glycerol and then dried.
- the powders were applied to magnesium silicate rings as follows: 350 g steatite rings with an outer diameter of 7 mm, a length of 3 mm and a wall thickness of 1.5 mm were used in one Coating drum at 20 ° C. for 20 min with 84.4 g of the powder and 9.4 g of oxalic acid with the addition of 66.7 g of a mixture containing 60% by weight of water and 40% by weight of glycerol and then dried.
- the weight of the catalytically active composition thus applied determined on a sample of the precatalyst obtained, was 18% by weight, based on the total weight of the finished catalyst, after heat treatment at 450 ° C. for one hour.
- the catalytically active composition applied in this way consisted on average of 0.16% by weight of phosphorus (calculated as P), 7.5% by weight of vanadium (calculated as V 2 O 5 ), 3.2% by weight Antimony (calculated as Sb 2 O 3 ), 0.40% by weight cesium (calculated as Cs) and 88.74% by weight titanium dioxide.
- the coated catalyst thus obtained was heated to 160 ° C. in a coating drum and together with 14 g of an organic binder consisting of a copolymer of acrylic acid / maleic acid (weight ratio 75:25) with a suspension of 502 g of anatase with a BET surface area of 21 m 2 / g, 35.8 g vanadyl oxalate, 2.87 g cesium sprayed sulfate, 720 g water and 198 g formamide.
- the catalytically active composition applied in this way consisted on average of 4.0% by weight of vanadium (calculated as V 2 O 5 ), 0.4% by weight of cesium (calculated as Cs) and 88.8% by weight titanium dioxide.
- the weight of the layers applied was 9.3% by weight of the total weight of the finished catalyst.
- the catalytically active composition applied in this way i.e. the catalyst shell, consisted on average of 0.15% by weight of phosphorus (calculated as P), 7.5% by weight of vanadium (calculated as V 2 O 5 ), 3, 2% by weight of antimony (calculated as Sb 2 O 3 ), 0.1% by weight of cesium (calculated as Cs) and 89.05% by weight of titanium dioxide.
- the catalysts A.1, A.2 and A.3 (coated steatite balls) were filled into an 80 cm long iron tube with a clear width of 16 mm up to a bed length of 66 cm.
- the iron pipe was surrounded by an electric heating jacket for temperature control.
- 360 Nl of air with a load of 98.5% by weight o-xylene of 60 g of o-xylene / Nm 3 of air were passed through the tube from top to bottom every hour.
- the results obtained are summarized in the table below.
- CO x selectivity corresponds to the proportion of o-xylene converted to combustion products (CO, CO 2 ); the residual selectivity to 100% corresponds to the proportion of the o-xylene converted to the valuable product phthalic anhydride and the intermediates o-tolylaldehyde, o-tolylic acid and phthalide and by-products such as maleic anhydride, citraconic anhydride and benzoic acid
- a BET surface area of the active composition of 6.7 m 2 / g and a vanadium oxidation state of 4.63 were determined on an expansion sample of the catalyst A.1.
- the following network plane distances d [A] with the associated relative intensities l re ⁇ [%] were obtained from the powder X-ray diagram: 4.85 (9.8), 3.50 (14.8), 3.25 (39.9) , 2.93 (100), 2.78 (36.2), 2.55 (35.3), 2.43 (18.6), 1.97 (15.2), 1.95 (28, 1), 1, 86 (16.5), 1, 83 (37.5), 1, 52 (23.5).
- Example B.2 was repeated, but in each case 0.80 m of the catalyst A.5, 1.40 m of the catalyst A.4 and then 0.80 m of the precatalyst A.1 were filled. An average PSA yield of 117.2% by weight was achieved.
- Example B.3 was repeated, but in each case 0.90 m of catalyst A.5, 1.60 m of catalyst A.4 and then 0.50 m of precatalyst A.1 were introduced. An average PSA yield of 116.7% by weight was achieved. The conversion was more than 99.94%, the residual phthalide content at the reactor outlet was less than 0.35% by weight.
- This example shows that when using the catalysts according to the invention, high PSA yields can also be achieved with a bed length of the silver vanadium oxide catalyst which is significantly shorter than in example B.1.
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Abstract
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Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
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US10/566,019 US7462727B2 (en) | 2003-07-25 | 2004-07-23 | Multimetal oxide containing silver, vanadium and a promoter metal and use thereof |
EP04763465.4A EP1654211B1 (de) | 2003-07-25 | 2004-07-23 | Silber, vanadium und ein promotormetall enthaltendes multimetalloxid und dessen verwendung |
JP2006521492A JP4330626B2 (ja) | 2003-07-25 | 2004-07-23 | 銀、バナジウムおよび推進剤金属を含有する多金属酸化物およびその使用 |
BRPI0412840-0A BRPI0412840A (pt) | 2003-07-25 | 2004-07-23 | óxido multimetálico, uso do mesmo, pré-catalisador, catalisador, e, processo para a preparação de aldeìdos, ácidos carboxìlicos e/ou anidridos carboxìlicos |
MXPA06000687A MXPA06000687A (es) | 2003-07-25 | 2004-07-23 | Oxido de multimetal que comprende plata, vanadio y un metal promotor y su uso. |
CN2004800215313A CN1829678B (zh) | 2003-07-25 | 2004-07-23 | 含有银、钒和助催化剂金属的多金属氧化物及其用途 |
IL173063A IL173063A0 (en) | 2003-07-25 | 2006-01-10 | Multi-metal oxide comprising silver, vanadium and a promoter metal and use thereof |
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DE10334132A DE10334132A1 (de) | 2003-07-25 | 2003-07-25 | Silber, Vanadium und ein Promotormetall enthaltendes Multimetalloxid und dessen Verwendung |
DE10334132.3 | 2003-07-25 |
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PCT/EP2004/008296 WO2005012216A1 (de) | 2003-07-25 | 2004-07-23 | Silber, vanadium und ein promotormetall enthaltendes multimetalloxid und dessen verwendung |
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US (1) | US7462727B2 (de) |
EP (1) | EP1654211B1 (de) |
JP (1) | JP4330626B2 (de) |
KR (1) | KR20060066068A (de) |
CN (1) | CN1829678B (de) |
BR (1) | BRPI0412840A (de) |
DE (1) | DE10334132A1 (de) |
IL (1) | IL173063A0 (de) |
IN (1) | IN2006CH00292A (de) |
MX (1) | MXPA06000687A (de) |
RU (1) | RU2006105703A (de) |
TW (1) | TW200514750A (de) |
WO (1) | WO2005012216A1 (de) |
ZA (1) | ZA200601637B (de) |
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WO2005092496A1 (de) * | 2004-03-26 | 2005-10-06 | Basf Aktiengesellschaft | Katalysator mit einer silber-vanadiumoxidphase und einer promotorphase |
WO2009095216A3 (de) * | 2008-02-01 | 2010-04-29 | Josef Breimair | Katalysator für die katalytische gasphasenoxidation von aromatischen kohlenwasserstoffen zu aldehyden, carbonsäuren und/oder carbonsäureanhydriden, insbesondere zu phthalsäureanhydrid |
FR2939328A3 (fr) * | 2008-12-09 | 2010-06-11 | Renault Sas | Materiau catalytique de combustion de matiere carbonee |
US8106220B2 (en) | 2006-05-19 | 2012-01-31 | Basf Se | Preparation of phthalic anhydride by gas phase oxidation of O-xylene in a main reactor and postreactor |
US8153825B2 (en) | 2006-05-19 | 2012-04-10 | Basf Se | Preparation of phthalic anhydride by gas phase oxidation of o-xylene |
CN108722397A (zh) * | 2018-06-05 | 2018-11-02 | 青岛科技大学 | 一种高尔夫球状Ag/TiO2复合多孔微球及其制备方法 |
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DE10334132A1 (de) | 2003-07-25 | 2005-04-07 | Basf Ag | Silber, Vanadium und ein Promotormetall enthaltendes Multimetalloxid und dessen Verwendung |
DE102004028930A1 (de) * | 2004-06-15 | 2006-01-05 | Basf Ag | Silber, Vanadium und ein Element der Phosphorgruppe enthaltendes Multimetalloxid und dessen Verwendung |
KR100714606B1 (ko) * | 2005-02-25 | 2007-05-07 | 주식회사 엘지화학 | 불포화 알데히드 및/또는 불포화 산의 제조방법 |
DE102005061382A1 (de) * | 2005-12-21 | 2007-06-28 | Basf Ag | Umwandlung eines Präkatalysators in eine katalytisch aktive Silber-Vanadiumoxid-Bronze |
BRPI0910954A2 (pt) * | 2008-04-07 | 2016-01-05 | Basf Se | método para iniciar um reator de oxidação em fase gasosa |
US8187705B2 (en) * | 2010-07-15 | 2012-05-29 | Silberline Manufacturing Company, Inc. | Manganese vanadium tantalum oxide and pigments having a black metallic effect coated with the same |
WO2016100967A1 (en) * | 2014-12-19 | 2016-06-23 | Dimien Llc | Vanadium oxide compositions and systems and methods for creating them |
CN107519886A (zh) * | 2015-07-31 | 2017-12-29 | 烟台智本知识产权运营管理有限公司 | 一种甲苯选择性氧化催化剂及其制备方法 |
CN106552622B (zh) * | 2015-09-28 | 2019-12-17 | 中国石化扬子石油化工有限公司 | 一种V-Ag-Si-O催化剂、其制备方法及其应用 |
CN109046412B (zh) * | 2018-08-23 | 2021-05-25 | 常州新日催化剂股份有限公司 | 一种正丁烷氧化制顺酐催化剂及其制备方法 |
US11541374B2 (en) * | 2018-09-05 | 2023-01-03 | Sabic Global Technologies B.V. | Vanadium oxide supported catalyst for alkane dehydrogenation |
CN112221496B (zh) * | 2020-10-13 | 2022-11-04 | 天津大学 | 多元金属氧化物基柴油机氧化催化器用催化剂及制备方法 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005092496A1 (de) * | 2004-03-26 | 2005-10-06 | Basf Aktiengesellschaft | Katalysator mit einer silber-vanadiumoxidphase und einer promotorphase |
US7338918B2 (en) | 2004-03-26 | 2008-03-04 | Basf Aktiengesellschaft | Catalyst having a silver-vanadium oxide phase and a promoter phase |
US8106220B2 (en) | 2006-05-19 | 2012-01-31 | Basf Se | Preparation of phthalic anhydride by gas phase oxidation of O-xylene in a main reactor and postreactor |
US8153825B2 (en) | 2006-05-19 | 2012-04-10 | Basf Se | Preparation of phthalic anhydride by gas phase oxidation of o-xylene |
WO2009095216A3 (de) * | 2008-02-01 | 2010-04-29 | Josef Breimair | Katalysator für die katalytische gasphasenoxidation von aromatischen kohlenwasserstoffen zu aldehyden, carbonsäuren und/oder carbonsäureanhydriden, insbesondere zu phthalsäureanhydrid |
FR2939328A3 (fr) * | 2008-12-09 | 2010-06-11 | Renault Sas | Materiau catalytique de combustion de matiere carbonee |
CN108722397A (zh) * | 2018-06-05 | 2018-11-02 | 青岛科技大学 | 一种高尔夫球状Ag/TiO2复合多孔微球及其制备方法 |
CN108722397B (zh) * | 2018-06-05 | 2021-11-26 | 青岛科技大学 | 一种高尔夫球状Ag/TiO2复合多孔微球及其制备方法 |
Also Published As
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DE10334132A1 (de) | 2005-04-07 |
CN1829678A (zh) | 2006-09-06 |
EP1654211B1 (de) | 2013-05-15 |
ZA200601637B (en) | 2007-04-25 |
IL173063A0 (en) | 2006-06-11 |
EP1654211A1 (de) | 2006-05-10 |
US20060247446A1 (en) | 2006-11-02 |
IN2006CH00292A (de) | 2007-07-06 |
TW200514750A (en) | 2005-05-01 |
BRPI0412840A (pt) | 2006-09-26 |
US7462727B2 (en) | 2008-12-09 |
MXPA06000687A (es) | 2006-04-19 |
JP2007533577A (ja) | 2007-11-22 |
RU2006105703A (ru) | 2006-08-27 |
CN1829678B (zh) | 2010-12-15 |
KR20060066068A (ko) | 2006-06-15 |
JP4330626B2 (ja) | 2009-09-16 |
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