WO2004011552A1 - 金型離型性を有する硬化性組成物 - Google Patents
金型離型性を有する硬化性組成物 Download PDFInfo
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- WO2004011552A1 WO2004011552A1 PCT/JP2003/009126 JP0309126W WO2004011552A1 WO 2004011552 A1 WO2004011552 A1 WO 2004011552A1 JP 0309126 W JP0309126 W JP 0309126W WO 2004011552 A1 WO2004011552 A1 WO 2004011552A1
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- 239000000203 mixture Substances 0.000 title claims abstract description 77
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 93
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- 229910052751 metal Inorganic materials 0.000 claims abstract description 29
- 239000002184 metal Substances 0.000 claims abstract description 29
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- 238000006459 hydrosilylation reaction Methods 0.000 claims abstract description 27
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims abstract description 11
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 8
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000008116 calcium stearate Substances 0.000 claims abstract description 5
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 5
- 235000019359 magnesium stearate Nutrition 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 122
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- 239000000178 monomer Substances 0.000 claims description 57
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- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 25
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 25
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 10
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- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 9
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- UZIAQVMNAXPCJQ-UHFFFAOYSA-N triethoxysilylmethyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)COC(=O)C(C)=C UZIAQVMNAXPCJQ-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical group CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- FRZSCIVUSFMNBX-UHFFFAOYSA-L zinc;12-hydroxyoctadecanoate Chemical compound [Zn+2].CCCCCCC(O)CCCCCCCCCCC([O-])=O.CCCCCCC(O)CCCCCCCCCCC([O-])=O FRZSCIVUSFMNBX-UHFFFAOYSA-L 0.000 description 1
- IFNXAMCERSVZCV-UHFFFAOYSA-L zinc;2-ethylhexanoate Chemical compound [Zn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O IFNXAMCERSVZCV-UHFFFAOYSA-L 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
Definitions
- Curable composition having mold release properties
- the present invention relates to a curable composition. More specifically, the present invention relates to a curable molding composition having mold releasability, comprising an alkenyl group-containing vinyl polymer, a hydrosilyl group-containing compound, and a hydrosilylation catalyst as essential components.
- a curable molding composition having mold releasability, comprising an alkenyl group-containing vinyl polymer, a hydrosilyl group-containing compound, and a hydrosilylation catalyst as essential components.
- thermoplastic resin or a thermosetting resin For molded products mainly composed of vinyl polymers or (meth) acrylic polymers, high-molecular-weight polymers are mixed with various additives in a heated state using a roll, mill, etc., and formed. Has been obtained.
- thermoplastic resin or a thermosetting resin it is necessary to mold in a heat-melted state, and there are problems such as the inability to use heat-sensitive additives.
- a curable composition containing a group-containing compound and curable by a hydrosilylation reaction is disclosed.
- the cured product obtained from such a curable composition may not have sufficient mold releasability, and the cured product may be damaged at the time of demolding after forming a molded article or the like, So-called rubber tears occurred, and in some cases, rubber could not come off from the mold. Disclosure of the invention
- An object of the present invention is to provide a cured product having generally good mechanical properties, oil resistance, heat resistance, weather resistance, etc., containing a vinyl polymer, and having a curability for molding which can be cured by a hydrosilylation reaction. It is an object of the present invention to provide a curable composition for molding having excellent mold release properties.
- the present inventors have intensively studied to solve the above-mentioned problems, and when applying to a curing system (addition-type curing system) capable of curing an alkenyl group-containing vinyl polymer by a hydrosilylation reaction, It has been found that a composition excellent in mold releasability can be obtained by adding ⁇ , and the present invention has been accomplished.
- the vinyl monomer constituting the main chain of the Bier polymer (I) of the present invention is not particularly limited, and various types can be used.
- (meta) key Crylic acid (meth) methyl acrylate, (meth) ethyl acrylate, (n-propyl) (meth) acrylate, isopropyl (meth) acrylate, _n_butyl acrylate, (meth) acrylic acid Isobutyl, tert-butyl (meth) acrylate, n-pentyl (meth) acrylate, n-hexyl (meth) acrylate, cyclohexyl (meth) acrylate, n- (meth) acrylate Heptyl, 1-octyl (meth) acrylate, 2-ethylethyl (meth) acrylate, nonyl (meth) acrylate, decyl (meth) acrylate, dodecyl (met
- (Meth) Acrylic acid monomers such as styrene monomers such as styrene, vinyl toluene, permethylstyrene, chlorostyrene, styrenesulfonic acid and salts thereof; fluorine such as perfluoroethylene, perfluoropropylene, and vinylidene fluoride Containing vinyl monomer; Biertrimethoxysilane, vinyl Silicon-containing vinyl monomers such as triethoxysilane; maleic anhydride, maleic acid, monoalkyl and dialkyl esters of maleic acid; fumaric acid, monoalkyl and dialkyl esters of fumaric acid; maleimide, methylmaleimide, ethyl Maleimide monomers such as maleimide, propylmaleimide, butylmaleimide, hexylmaleimide, octylmaleimide, dodecylmaleimide, stearylmaleimide, phenolmaleimide, and
- mainly polymerize the above monomer mainly polymerizing usually means to polymerize using 50% by weight or more of all monomer components. These may be used alone or a plurality of them may be copolymerized. Among them, styrene-based monomers and (meth) acrylic-acid-based monomers are preferred in view of the physical properties of the product. More preferred are acrylate ester monomers and methacrylate monomers, particularly preferred are acrylate monomers, and still more preferred is butyl acrylate.
- these preferred monomers may be copolymerized with other monomers, or may be copolymerized by block copolymer, in which case the preferred monomers are contained at a weight ratio of 40%.
- (meth) acrylic acid means acrylic acid and Z or methacrylic acid.
- the (meth) acrylic polymer in the present invention generally refers to a polymer obtained by using 30% by weight or more of (meth) acrylic acid ester of all monomer components.
- the ratio between the weight average molecular weight and the number average molecular weight measured by chromatography is not particularly limited, but is preferably less than 1.8, preferably 1.7 or less, and more preferably 1.6 or less. It is more preferably at most 1.5, particularly preferably at most 1.4, most preferably at most 1.3.
- a chromate form is used as a mobile phase, the measurement is performed with a polystyrene gel column, and the number average molecular weight and the like can be determined in terms of polystyrene.
- the number average molecular weight of the Bier polymer of the present invention is not particularly limited, but is preferably in the range of 500 to 1, 000, 0000, more preferably 100 to 100, 000. preferable. If the molecular weight is too low, the intrinsic properties of the biel-based polymer are hardly exhibited, and if it is too high, handling becomes difficult.
- the vinyl polymer (I) of the present invention can be obtained by various polymerization methods, and the method is not particularly limited, but a radical polymerization method is preferable from the viewpoint of versatility of the monomer and easy control.
- a radical polymerization method is preferable from the viewpoint of versatility of the monomer and easy control.
- controlled radical polymerization is preferred, living radical polymerization is more preferred, and atom transfer radical polymerization is particularly preferred.
- the alkenyl group can be introduced by directly introducing the alkenyl group in the polymerization reaction system, by synthesizing a vinyl polymer having a specific functional group, and then adding the specific functional group to the alkenyl group in one or several steps. And a method of converting into a group.
- Methods for synthesizing vinyl polymers having functional groups by radical polymerization can be classified into “general radical polymerization” and “controlled radical polymerization”.
- the “general radical polymerization method” refers to a vinyl monomer having a specific functional group using a polymerization initiator such as an azo compound or a peroxide (hereinafter referred to as “functional monomer”) and another vinyl. This is a method of simply copolymerizing with a system monomer.
- the “dical polymerization method” is a method capable of introducing a specific functional group at a controlled position such as a terminal.
- the “general radical polymerization method” is a simple method and can be used in the present invention, but a specific functional group is only stochastically introduced into the polymer due to copolymerization. Therefore, in order to obtain a polymer with a high degree of functionalization, it is necessary to use a large amount of a functional monomer. There are points. Also, since it is a free radical polymerization, there is a problem that only a polymer having a wide molecular weight distribution ⁇ high viscosity can be obtained.
- the “controlled radical polymerization method” can be classified into a “chain transfer agent method” and a “living radical polymerization method”.
- the “controlled radical polymerization method” is characterized in that polymerization is carried out using a chain transfer agent having a specific functional group, and a vinyl polymer having a functional group at a terminal can be obtained.
- the “living radical polymerization method” is characterized by using a special polymerization system so that the growing terminal of the polymer grows without causing side reactions such as termination reaction. As a result, a polymer having a molecular weight almost as designed can be obtained by the “riving radical polymerization method”.
- the “chain transfer agent method” can be used in the present invention because it can introduce a functional group into a polymer terminal relatively quantitatively as compared with the “general radical polymerization method”.
- a considerably large amount of a chain transfer agent having a specific functional group is required with respect to the initiator, and there is an economical problem including a treatment such as recovery of the chain transfer agent.
- the radical polymerization using a chain transfer agent is not particularly limited, but examples of a method for obtaining a pinyl-based polymer having a terminal structure suitable for the present invention include the following two methods.
- radical polymerization is difficult to control because the polymerization rate is high and a termination reaction is likely to occur due to force coupling between radicals.
- the “living radical polymerization method” is unlikely to cause a side reaction such as a termination reaction while having a narrow molecular weight distribution (MwZM n is about 1 ::! To about 1.5). A polymer is obtained, and the molecular weight can be freely controlled by the charging ratio of the monomer and the initiator.
- the "living radical polymerization method” can obtain a polymer having a narrow molecular weight distribution and a low viscosity, and can introduce a monomer having a specific functional group into almost any position of the polymer. It is more preferable as a method for producing the vinyl polymer having the specific functional group.
- living polymerization refers to polymerization in which the terminal is always active and the molecular chain grows, but in general, it is one in which the terminal is inactivated and one in which the terminal is activated. Pseudo-living polymerization that grows in a state of equilibrium is also included. The definition in the present invention is also the latter.
- the "atom transfer radical polymerization method” in which an organic halide or a sulfonyl halide compound is used as an initiator and a vinyl monomer is polymerized using a transition metal complex as a catalyst is the above-mentioned "living radical polymerization method".
- a Bier polymer having a specific functional group has a halogen or the like at the terminal, which is relatively advantageous for the functional group conversion reaction, and has a high degree of freedom in designing initiators and catalysts. Is more preferable as the production method.
- This atom transfer radical polymerization method includes, for example, Matyjasz ewski et al., Journal of American 'Chemical Soc. Et al. (J. Am. Chem. Soc.) 1995, 117, 5614, Macromolecule (Macromo lecules) 1995, 28, 7901, Science (1996), 272, 866, WO96 / 30421, WO97Z18247, WO98 / 01480, WO 98 40415, or Sawamoto et al., Macromolecules (Macromo 1 ecu 1 es), 1995, Vol. 28, p. 721, JP-A-9-208616, JP-A-8-41117 Publications.
- the atom transfer radical polymerization of the present invention includes so-called reverse atom transfer radical polymerization.
- Reverse atom transfer radical polymerization is a highly oxidized state when a normal atom transfer radical polymerization catalyst generates radicals, for example, using Cu (I) as a catalyst.
- This is a method in which a common radical initiator such as a peroxide is allowed to act on Cu (I) when used, and as a result, an equilibrium state similar to that of atom transfer radical polymerization is created (Macromo lecules 1999 , 32, 2872).
- any of these living radical polymerization methods is not particularly limited, but an atom transfer radical polymerization method is preferable.
- a radical scavenger such as a nitroxide compound
- Such compounds include, but are not limited to, 2, 2, 6, 6-substituted 1-1-piperidinyloxy radicals and 2,2,5,5-substituted-11-pyrrolidinyloxy radicals, Nitroxy free radicals from cyclic hydroxyamines are preferred.
- an alkyl group having 4 or less carbon atoms such as a methyl group and an ethyl group is suitable.
- nitroxy-free radical compounds include, but are not limited to, 2,2,6,6-tetramethyl-1-piperidinyloxy radical (TEMPO), 2,2,6,6-tetraethyl-1-pipe Lydinyloxy radical, 2,2,6,6-tetramethyl-4-oxo-1-piperidinyloxy radical, 2,2,5,5-tetramethyl-1-pyrolidinyloxy radical, 1, 1 , 3,3-tetramethyl-2-isoindolinyloxy radical, N, N-di-t-butylamyloxy radical, and the like.
- a stable free radical such as galpinoxyl (g alv i noxy 1) free radical may be used.
- the radical capping agent is used in combination with a radical generator. It is considered that the reaction product of the radical capping agent and the radical generator serves as a polymerization initiator, and the polymerization of the addition-polymerizable monomer proceeds.
- the combination ratio of both is not particularly limited, but the radical initiator 0.1 mol to 10 mol per 1 mol of the radical capping agent. Is appropriate.
- the radical generator various compounds can be used, but a peroxide capable of generating a radical under the polymerization temperature condition is preferable.
- the peroxide include, but are not limited to, dialkyl peroxides such as benzoyl peroxide, lauroyl peroxide and the like, dialkyl peroxides such as dicumyl peroxide, di-t-butyl peroxide, and diisopropoxide.
- dialkyl peroxides such as benzoyl peroxide, lauroyl peroxide and the like
- dialkyl peroxides such as dicumyl peroxide, di-t-butyl peroxide, and diisopropoxide.
- Propyl peroxydicarbonate Propyl peroxydicarbonate
- peroxycarbonates such as bis (4-tert-butylcyclohexyl) peroxydicarbonate, and alkyl esters such as t-butylperoxyctoate and t-butylperoxybenzoate.
- Benzolpoxide is particularly preferred.
- a radical generator such as a radical-generating azo compound such as azobisisobutyronitrile may be used in place of peroxide.
- an alkoxyamine compound as shown in the figure below was used. It may be used as an initiator.
- an alkoxyamine compound is used as an initiator, if it has a functional group such as a hydroxyl group as shown in the above figure, a polymer having a functional group at the terminal is used. Is obtained. When this is used in the method of the present invention, a polymer having a functional group at a terminal can be obtained.
- Polymerization conditions such as a monomer, a solvent, and a polymerization temperature used in the polymerization using a radical scavenger such as a nitroxide compound are not limited, and may be the same as those used for atom transfer radical polymerization described below.
- an organic halide particularly an organic halide having a highly reactive carbon-halogen bond (for example, a carbonyl compound having a halogen at the 0; position or a compound having an halogen at the benzyl position)
- a sulfonyl halide compound or the like is used as an initiator.
- C 6 H 5 is a phenyl group
- X is chlorine, bromine, or iodine.
- R 3 is a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, an aryl group, or an aralkyl group, and X is chlorine, bromine, or iodine.
- An organic halide or a sulfonyl halide compound used as an initiator to A vinyl polymer having a terminal structure represented by the general formula (1) can be obtained by performing atom transfer radical polymerization of the polymer.
- R 1 and R 2 represent a group bonded to the ethylenically unsaturated group of the vinyl monomer.
- X represents chlorine, bromine, or iodine.
- an organic octogenide or a sulfonyl halide compound having a specific functional group which does not start polymerization together with a functional group which starts polymerization can also be used.
- a vinyl polymer having a specific functional group at one main chain terminal and a terminal structure represented by the general formula (1) at the other main chain terminal is obtained.
- Examples of such a specific functional group include an alkenyl group, a crosslinkable silyl group, a hydroxyl group, an epoxy group, an amino group, an amide group and the like.
- the organic halide having an alkenyl group is not limited.
- R 5 is hydrogen or a methyl group
- R 6 and R 7 are hydrogen, or a monovalent alkyl group having 1 to 20 carbon atoms, aryl group, or aralkyl, or mutually linked at the other end.
- R 8 is — C ( ⁇ ) O— (ester group), one C ( ⁇ )-(keto group), or o—, m—, p-phenylene group
- R 9 is a direct bond, Or a divalent organic group having 1 to 20 carbon atoms, which may contain one or more ether bonds, where X is chlorine, bromine, or iodine
- R 6 and R 7 include hydrogen, methyl, ethyl, n-propyl, isopropyl, butyl, pentyl, and hexyl.
- R 6 and R 7 may be linked at the other end to form a cyclic skeleton.
- X is chlorine, bromine, or iodine
- n is an integer of 0 to 20
- X is chlorine, bromine, or iodine
- n is an integer of 1 to 20
- m is an integer of 0 to 20.
- n - CH CH 2
- n - CH CH 2
- n - CH CH 2
- n - CH CH 2
- X is chlorine, bromine, or iodine
- n is an integer of 0 to 20
- o m
- X is chlorine, bromine, or iodine
- n is an integer of 1 to 20
- m is an integer of 0 to 20
- X is chlorine, bromine, or iodine
- n is an integer of 0 to 20.
- X is chlorine, bromine, or iodine
- n is an integer of 1 to 20
- m is an integer of 0 to 20
- the organic halide having an alkenyl group further includes a compound represented by the general formula (3).
- H 2 C C (R 5 ) — R 9 — C (R 6 ) (X)-R 10 — R 7 (3)
- R 10 is a direct bond, one C (O) O— (ester group), one C (O) one (keto group ) Or o-, m-, p-phenylene group)
- R 8 is a direct bond or a divalent organic group having 1 to 20 carbon atoms (which may contain one or more ether bonds). If the bond is a direct bond, a halogen bond is present. It is a halogenated arylated compound with a vinyl group bonded to carbon. in this case Since the carbon-halogen bond is activated by the adjacent vinyl group, R 1 Q does not necessarily have to have a C ( ⁇ ) ⁇ group or a phenylene group, and may be a direct bond. When R 9 is not a direct bond, R 1G is preferably a C ( ⁇ ) ⁇ group, a C (0) group, or a phenylene group for activating a carbon-halogen bond.
- X is chlorine, bromine, or iodine
- R is an alkyl group, aryl group, or aralkyl group having 1 to 20 carbon atoms.
- X is chlorine, bromine, or iodine
- n is an integer of 0 to 20.
- the organic halide having a crosslinkable silyl group is not particularly limited, and examples thereof include those having a structure represented by the general formula (4).
- R 11 R 12 is an alkyl group having 1 to 20 carbon atoms, an aryl group, an aralkyl group, or ( R ′) 3 S i O— (R ′ is a monovalent hydrocarbon group having 1 to 20 carbon atoms, and the three R ′s may be the same or different.)
- a triorganosiloxy group and when two or more R 11 or R 12 are present, they may be the same or different Y represents a hydroxyl group or a hydrolyzable group, and Y represents 2 When there are more than one, they may be the same or different: a represents 0, 1, 2, or 3, and b represents 0, 1, or 2.
- m represents 0 to It is an integer of 19. However, it satisfies that a + mb ⁇ 1)
- X is chlorine, bromine, iodine, and n is an integer of 0 to 20.
- X is chlorine, bromine, iodine
- n is an integer of 1 to 20
- m is an integer of 0 to 20.
- X is chlorine, bromine, or iodine.
- Examples of the organic octogenide having a crosslinkable silyl group further include those having a structure represented by the general formula (5).
- X is chlorine, bromine, or iodine
- R is an alkyl group, aryl group, or aralkyl group having 1 to 20 carbon atoms.
- the organic halide having a hydroxyl group or the sulfonyl halide is not particularly limited, and examples thereof include the following.
- X is chlorine, bromine, or iodine
- R is a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, an aryl group, an aralkyl group, and n is an integer of 1 to 20.
- X is chlorine, bromine, or iodine
- R is a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, an aryl group, an aralkyl group
- n is an integer of 1 to 20.
- the organic halide having an epoxy group or the sulfonyl halide compound is not particularly limited, and examples thereof include the following.
- X is chlorine, bromine, or iodine
- R is a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, an aryl group, an aralkyl group
- n is an integer of 1 to 20.
- Equation f £ is the arizo 3 ⁇ 4 of charcoal 1-20, or ara
- N is 0 ⁇ 20 fiber
- X is ⁇ bromine or iodine
- X is chlorine, bromine or iodine
- X is chlorine bromine or iodine, etc.
- the transition metal complex used as the polymerization catalyst is not particularly limited, but is preferably a metal complex having a central metal of Group 7, 8, 9, 10 or 11 of the periodic table. More preferred are complexes of zero-valent copper, monovalent copper, divalent ruthenium, divalent iron and divalent nickel. Among them, a copper complex is preferable. Specific examples of monovalent copper compounds include cuprous chloride, cuprous bromide, cuprous iodide, cuprous cyanide, cuprous oxide, cuprous perchlorate, etc. is there.
- a copper compound 2,2′-biviridyl or a derivative thereof, 1,10-phenanthroline or a derivative thereof, or tetramethylethylenediamine, pentamethylethylenediamine or hexamethyltris (2 —Aminoethyl)
- a polyamine such as amine is added as a ligand.
- a tristriphenylphosphine complex of divalent ruthenium chloride (RuCl 2 (P Ph 3 ) 3 ) is also suitable as a catalyst.
- ruthenium compound is used as a catalyst, aluminum alkoxides are added as an activator.
- divalent bis triphenyl phosphine complex of iron F e C 1 2 (PPh 3) 2)
- 2 -valent nickel bis triphenyl phosphine complex N i C 1 2 (PPh 3) 2)
- divalent piston-butyl phosphine complexes of nickel N i B r 2 (PBu 3) 2
- the polymerization reaction can be carried out without solvent, but can also be carried out in various solvents.
- the type of the solvent is not particularly limited.
- hydrocarbon solvents such as benzene and toluene
- ether solvents such as getyl ether, tetrahydrofuran, diphenyl ether, anisol, and dimethoxybenzene
- methylene chloride, and chloroform Halogenated hydrocarbon solvents such as mouth form and chlorobenzene
- ketone solvents such as acetone, methyl ethyl ketone and methyl isobutyl ketone
- methanol, ethanol, propano Alcohol solvents such as toluene, isopropanol, n-butyl alcohol and tert-butyl alcohol
- nitrile solvents such as acetonitrile, propionitrile and benzonitrile
- ester solvents such as ethyl acetate and butyl acetate;
- the polymerization can be carried out in the range of 0 to 200, preferably in the range of room temperature to 150.
- the alkenyl group in the present invention is not limited, but is preferably one represented by the general formula (7).
- R 13 represents hydrogen or an organic group having 1 to 20 carbon atoms.
- R 13 is hydrogen or an organic group having 1 to 20 carbon atoms.
- the organic group having 1 to 20 carbon atoms is not particularly limited, but is preferably an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aralkyl group having 7 to 20 carbon atoms. And the like.
- R 13 is more preferably hydrogen or a methyl group.
- the alkenyl group of the polymer (I) is not activated by a carboxy group, an alkenyl group, or an aromatic ring conjugated to the carbon-carbon double bond.
- the form of bonding between the alkenyl group and the main chain of the polymer is not particularly limited, but is preferably bonded via a carbon-carbon bond, an ester bond, an ether bond, a carbonate bond, an amide bond, a urethane bond, or the like.
- At least one alkenyl group has a molecular chain since the molecular weight between cross-linking points that greatly affects rubber elasticity can be increased. Is preferably at the end of More preferably, all the alkenyl groups have at the molecular chain terminal.
- a method for producing a vinyl polymer having at least one alkenyl group at the molecular terminal, in particular, a (meth) acrylic polymer is disclosed in Japanese Patent Publication No. 3-14068, Japanese Patent Publication No. No. 4, JP-A-6-219192, and the like.
- these methods are free radical polymerization methods using the above “chain transfer agent method”
- the resulting polymer has a relatively high proportion of alkenyl groups at the molecular chain ends, while Mw / M n
- the value of the molecular weight distribution represented by is generally as large as 2 or more, and there is a problem that the viscosity increases.
- a vinyl polymer is synthesized by radical polymerization, preferably living radical polymerization, for example, a polymerizable alkenyl group and a polymerizable alkenyl group in one molecule as shown in the following general formula (9) are used.
- R 14 represents hydrogen or a methyl group
- R 15 represents —C (O) ⁇ —, or o—, m—, p-phenylene group
- R 16 represents a direct bond or carbon number.
- R 17 represents hydrogen or an organic group having 1 to 20 carbon atoms.
- R 17 is hydrogen or an organic group having 1 to 20 carbon atoms.
- the organic group having 1 to 20 carbon atoms is not particularly limited, but is preferably an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aralkyl group having 7 to 20 carbon atoms. And the like.
- R 17 is more preferably a hydrogen or a methyl group.
- the timing of reacting a compound having both a polymerizable alkenyl group and a low polymerizable alkenyl group in one molecule is not limited.However, particularly in the case of living radical polymerization, when a rubber-like property is expected, polymerization is performed. End of reaction or end of reaction of specified monomer Later, it is preferred to react as a second monomer.
- A-c Various organic compounds having an alkenyl group such as an organic tin such as, for example, aryltributyltin and aryltrioctyltin may be used as the biel polymer having at least one highly reactive carbon-18 halogen bond.
- an organic tin such as, for example, aryltributyltin and aryltrioctyltin
- (A-d) A method wherein a vinyl polymer having at least one highly reactive carbon-halogen bond is reacted with a stabilized carbanion having an alkenyl group as shown in the general formula (10) to replace halogen.
- R 17 is the same as above.
- R 18 and R 19 are both electron-withdrawing groups for stabilizing carbanion C—, or one is the above-mentioned electron-withdrawing group and the other is hydrogen or a group having 1 to 10 carbon atoms.
- R 2Q represents a direct bond or a divalent organic group having 1 to 10 carbon atoms, and may contain one or more ether bonds, and M + represents an alkali metal ion. , Or quaternary ammonium ion.
- the electron withdrawing groups for R 18 and R 19 include — C ⁇ 2 R (ester group), —C (O) R (keto group), —CON (R 2 ) (amide group), — COSR (thioester group) one CN (nitrile group), - N_ ⁇ 2 is (nitro group), etc., - C0 2 R, one C (O) R and - CN are particularly preferred.
- the substituent R is an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms or an aralkyl group having 7 to 20 carbon atoms, preferably an alkyl group or a phenyl group having 1 to 10 carbon atoms. It is.
- (Ae) Pinyl system having at least one highly reactive carbon-halogen bond An enolate anion is prepared by reacting a polymer with a simple metal such as zinc or an organometallic compound, followed by an alkenyl group-containing compound having a leaving group such as a halogen acetyl group, and an alkenyl group.
- a biel polymer having at least one highly reactive carbon-halogen bond for example, an alkenyl or carboxylate anion having an alkenyl group represented by the general formula (11) or (12) Reacting to replace halogen.
- R 21 is a divalent organic group having 1 to 20 carbon atoms and may contain one or more ether bonds.
- H 2 C C (R 17 ) — R 22 -C (O) 0-M + (12)
- R 22 is a direct bond or a divalent organic group having 1 to 20 carbon atoms and may contain one or more ether bonds.
- a living radical polymerization method is preferable as a method for synthesizing a vinyl polymer, and an atom transfer radical A polymerization method is more preferred.
- a highly reactive carbon-halogen bond is used.
- a chain transfer polymerization method using an octalogenide as a chain transfer agent or an atom transfer radical polymerization method using an organic octamate or a sulfonyl halide compound as an initiator is used.
- atom transfer radical polymerization is more preferred.
- the methods (A-a) to (A-f) the methods (A-b) and (A-f) are preferable because the control is easier. The method of introducing (A-b) and (A-f) is described in detail below.
- the method (Ab) is characterized in that a vinyl polymer obtained by living radical polymerization of a vinyl monomer is reacted with a compound having at least two alkenyl groups having low polymerizability (hereinafter referred to as a gen compound). And
- At least two alkenyl groups of the diene compound may be the same or different from each other.
- a terminal alkenyl group [CH 2 C (R) -R '; R is hydrogen or an organic group having 1 to 20 carbon atoms, R' is an organic group having 1 to 20 carbon atoms, May be bonded to each other to have a cyclic structure.
- an internal alkenyl group [R'-C (R) C (R) -R '; R is hydrogen or an organic group having 1 to 20 carbon atoms, R and R are organic groups having 1 to 20 carbon atoms; One R or two R's may be the same or different.
- R is hydrogen or an organic group having 1 to 20 carbon atoms.
- the organic group having 1 to 20 carbon atoms include an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, and 7 to 20 carbon atoms.
- R is particularly preferably hydrogen or a methyl group.
- At least two alkenyl groups of the alkenyl groups of the gen compound may be conjugated.
- the diene compound include, for example, isoprene, piperylene, butadiene, myrcene, 1,5-hexadiene, 1,7-octadiene, 1,9-decadiene, and 4-vinyl-1-cyclohexene. Among them, 1,5-hexadiene, 1,7-octadiene and 1,9-decadiene are preferred.
- a living radical polymerization of a pinyl-based monomer is performed, and the obtained polymer is isolated from the polymerization system. Then, the isolated polymer is subjected to a radical reaction with a gen compound to have an alkenyl group at a target terminal.
- a method of adding a gen compound to the polymerization reaction system at the end of the polymerization reaction or after completion of the reaction of a predetermined vinyl monomer is more preferable because it is simple.
- the gen compound may be in an equivalent amount or a small excess amount with respect to the polymerization growth terminal, but when the reactivity of the two alkenyl groups is equal or there is little difference, Since both of the two alkenyl groups react with each other and the polymerization terminals are coupled to each other, the amount of the gen compound added is preferably an excess amount relative to the polymer growth terminal, preferably 1.5 times or more, more preferably Is 3 times or more, particularly preferably 5 times or more.
- the (A-f) method is characterized by reacting a vinyl polymer having at least one highly reactive carbon-halogen bond with an alkenyl group-containing oxyanion or a carboxylate anion to replace halogen.
- the oxyanion or carboxylate anion having an alkenyl group is not particularly limited, and examples thereof include those represented by the general formula (11) or (12).
- H 2 C C (R 17 ) — R 21 — 0- M + (1 1)
- R 21 is a divalent organic group having 1 to 20 carbon atoms and may contain one or more ether bonds.
- H 2 C C (R 17 ) -R 22 -C ( ⁇ ) 0-M + (12)
- R 22 is a direct bond or a divalent organic group having 1 to 20 carbon atoms and may contain one or more ether bonds.
- oxyanion or propyloxydione include, for example, ammonia; alkylamines such as trimethylamine, triethylamine and triptylamine; polyamines such as tetramethylethylenediamine and pentamethylethylenetriamine; pyridine and picoline. Pyridine compounds such as
- the amount of the basic compound used may be an equivalent amount or a small excess amount relative to the precursor, and is preferably from 1 to L.2 equivalent.
- Examples of the solvent used when the precursor compound and the basic compound are reacted include, for example,
- alkenyl alcohols such as aryl alcohol
- salts of aryloxy alcohols such as ethylene daricol monoaryl ether
- phenolic hydroxyl-containing alkenyl group salts such as aryl phenol and aryloxy phenol
- 10-pentadecylenic acid
- Alkenyl group-containing carboxylate salts such as monopentenoic acid and bieracetic acid; and the like.
- M + is a counter cation, and the types of M + include alkali metal ions, specifically, lithium ion, sodium ion, potassium ion, and quaternary ammonium ion.
- alkali metal ions specifically, lithium ion, sodium ion, potassium ion, and quaternary ammonium ion.
- the quaternary ammonium ion include tetramethylammonium ion, tetraethylammonium ion, tetrabenzylammonium ion, trimethyldodecylammonium ion, tetrabutylammonium ion, and dimethylpyridinium ion.
- the amount of oxyanion or carboxylate anion used may be an excess with respect to the halogen, preferably 1 to 5 equivalents, more preferably 1 to 2 equivalents, and still more preferably 1.0 to 1.2 equivalents. is there.
- the solvent for carrying out this reaction is not particularly limited, but a solvent having a relatively high polarity is preferable, and examples thereof include getyl ether, tetrahydrofuran, and diphenyle.
- Ether solvents such as ter, anisol and dimethoxybenzene; halogenated hydrocarbon solvents such as methylene chloride and chloroform; ketone solvents such as acetone, methyl ethyl ketone and methyl isobutyl ketone; methanol, ethanol, and propane Alcohol solvents such as phenol, isopropanol, n-butyl alcohol, and tert-butyl alcohol; nitrile solvents such as acetonitrile, propionitrile, and benzonitrile; ester solvents such as ethyl acetate and butyl acetate; ethylene carbonate, Carbonate-based solvents such as propylene glycol; amide-based solvents such as dimethylformamide and dimethylace
- reaction temperature is not limited, it is generally 0 to 150 ° C, more preferably room temperature to 100 ° C.
- amines, ammonium salts, crown ethers and the like may be added to the reaction system as a reaction accelerator.
- the oxyanion or the carboxylate anion may be prepared by reacting with a base in a reaction system using an alcohol or a carboxylic acid as a precursor instead of the oxyanion or the carboxylate anion.
- a vinyl polymer having at least one alkenyl group has at least a hydroxyl group.
- (A-h) A method of reacting an alkenyl group-containing isocyanate compound such as aryl isocyanate.
- (A-k) A method in which a diisocyanate compound is reacted with a vinyl polymer having a hydroxyl group, and a compound having both an alkenyl group and a hydroxyl group in the remaining isocyanate group is reacted.
- the compound having both an alkenyl group and a hydroxyl group is not particularly limited, and includes, for example, alkenyl alcohols such as 10-pentadecenol, 5-hexenol, and aryl alcohol.
- the diisocyanate compound is not particularly limited, and any conventionally known compounds can be used.
- An isocyanate compound such as an acid salt; These can be used alone or in combination of two or more. Also, a block isocyanate may be used.
- diisocyanate having no aromatic ring such as hexamethylene diisocyanate, hydrogenated diphenylmethane diisocyanate, etc. It is preferable to use a net compound.
- Examples of the method for producing the biel polymer having at least one hydroxyl group used in the methods (B) and (A-g) to (A-j) include the following methods, but are not limited to these methods. Not something.
- H 2 C C (R 14 ) -R 15 -R 16 -OH (15)
- (B-d) A method in which a vinyl monomer is radially polymerized using hydrogen peroxide or a hydroxyl group-containing initiator as described in, for example, JP-A-6-239912 and JP-A-8-283310.
- the electron withdrawing groups for R 18 and R 19 include — C ⁇ 2 R (ester group), —C (O) R (keto group), —CON (R 2 ) (amide group), — COSR (thioester group) , - CN (nitrile group), one N0 2 is (nitro group), etc., - C0 2 R, - C (O) R and single CN are particularly preferred.
- the substituent R is an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms or an aralkyl group having 7 to 20 carbon atoms, preferably an alkyl group or a phenyl group having 1 to 10 carbon atoms. It is.
- reaction conditions As for M + , reaction conditions, solvents and the like, all those described in the description of (A-f) can be preferably used.
- the compound represented by the above general formula (19) is not particularly limited. However, because it is easy to obtain, compounds such as 10-indesenol, 8-octenol, 5-hexenol, and aryl alcohol Alkenyl alcohols are preferred.
- a living radical is used as a method for synthesizing a vinyl polymer.
- a polymerization method is preferred, and an atom transfer radical polymerization method is more preferred.
- the highly reactive carbon--18 halogen bond is used.
- the atom transfer radical polymerization method is more preferable.
- the methods (Bb) and (Bi) are preferred because they are easier to control.
- the hydrosilyl group-containing compound as the component (B) is not particularly limited as long as it is a compound having a silyl group having a lip at the mouth which can be cured by crosslinking with a vinyl polymer having at least one alkenyl group as the component (A).
- R 23 and R 24 represent an alkyl group having 1 to 6 carbon atoms or a phenyl group
- R 25 represents an alkyl group or an aralkyl group having 1 to 10 carbon atoms.
- A is 0 ⁇ a ⁇ l 0 0
- B is an integer satisfying 2 ⁇ b ⁇ 100
- c is an integer satisfying 0 ⁇ c ⁇ l 00.
- R 26 and R 27 represent an alkyl group having 1 to 6 carbon atoms or a phenyl group
- R 28 represents an alkyl group or an aralkyl group having 1 to 10 carbon atoms.
- D is 0 d ⁇ 8, and e is 2 ⁇ e ⁇ 10, f is an integer of 0 ⁇ f ⁇ 8, and satisfies 3 ⁇ d + e + f10.
- siloxanes from the viewpoint of compatibility with the (meth) acrylic polymer, chain siloxanes represented by the following general formulas (25) and (26) having a phenyl group;
- R 29 represents hydrogen or a methyl group.
- I is an integer satisfying 2 ⁇ i ⁇ 10
- j is an integer satisfying 0 j ⁇ 8, and 3 ⁇ i + j ⁇ 10.
- C 6 H 5 is And represents a radical.
- the compound having at least one hydrosilyl group as the component (B) further includes a compound represented by the general formula (22)
- a compound obtained by subjecting the hydrosilyl group-containing compound represented by any one of (2) to (28) to an addition reaction so that a part of the hydrosilyl group remains even after the reaction can also be used.
- Various compounds can be used as the compound having two or more alkenyl groups in the molecule.
- hydrocarbons such as 1,4-pentadiene, 1,5-hexadiene, 1,6-dibutadiene, 1,7-octadiene, 1,8-nonadiene, and 1,9-decadiene
- ether compounds such as ⁇ ⁇ ⁇ ⁇ , ⁇ , diarylbisphenol A, 3,3 ′ diarylbisphenol A, diaryl phthalate, diaryl isophthalate, triallyl trimellitate, tetraaryl pyromellitate And the like and ester compounds such as diethylene daryldiaryl carbonate and the like.
- the above-mentioned alkenyl group-containing compound is slowly and dropwise added to the excess amount of the hydrosilyl group-containing compound shown in the above general formulas (22) to (28) in the presence of a hydrosilylation catalyst.
- the following compounds are preferred in view of the availability of raw materials, the ease of removing excess siloxane used, and the compatibility with the vinyl polymer (I).
- hydrosilylation catalyst which is the component (C) of the present invention
- any catalyst can be used.
- platinum one vinylsiloxane complex ⁇ for example, P t n (V iMe 2 S i OS iMe 2 V i) n , P t C (Me V i S i O) 4] m ⁇
- platinum primary phosphine complex ⁇ for example, P t (PP h 3) 4, P t (PBu 3) 4 ⁇
- Platinum monophosphite complex for example, Pt [P ( ⁇ P) 3 ] 4 , PtCP (OBu) 3 ] 4 (where Me is a methyl group, Bu is a butyl group, Vi is a vinyl group, Ph Represents a phenyl group, n and m represent integers)
- examples of the catalyst other than platinum compounds RhC l (PPh 3) 3 , RhC 1 3, Rh / Al 2 ⁇ 3, RuC.l 3, I rC l 3, FeC l 3, A 1 C 1 3 , P d C 1 2 • 2H 2 0, N i C 1 2, T i C 1 4, and the like.
- These catalysts may be used alone or in combination of two or more.
- chloroplatinic acid, platinum-olefin complex, platinum-vinylsiloxane complex, Pt (acac) 2 and the like are preferable.
- the amount of catalyst is preferably used in the range of 10- 1 ⁇ 10- 8 mo 1 against alkenyl group lmo 1 in component (A). And it is preferably employed in the range of 10- 2 to 1 0 one 6 mo 1.
- the hydrosilylation catalyst is generally expensive and corrosive.
- Metallic stones are generally a combination of long-chain fatty acids and metal ions.
- a non-polar or low-polarity part based on fatty acids and a polar part based on the bonding part with metal are combined in one molecule. If you have it you can use it.
- the long-chain fatty acids include saturated fatty acids having 1 to 18 carbon atoms, unsaturated fatty acids having 3 to 18 carbon atoms, and aliphatic dicarboxylic acids.
- a saturated fatty acid having 1 to 18 carbon atoms is preferable from the viewpoint of availability, and a saturated fatty acid having 6 to 18 carbon atoms is particularly preferable from the viewpoint of releasing effect.
- metal ion examples include zinc, cobalt, aluminum, strontium and the like in addition to the alkali metal and the alkaline earth metal. More specific examples of metal stones include lithium stearate, lithium 12-hydroxystearate, lithium laurate, lithium oleate, lithium 2-ethylhexanoate, sodium stearate, and 12-hydroxy.
- metal stearate salts are preferable from the viewpoint of availability and safety, and particularly from the viewpoint of economy, calcium stearate, magnesium stearate, and stearin are preferred.
- One or more selected from the group consisting of zinc oxides are most preferred.
- the amount of the metal stone added is not particularly limited, but is usually used in a range of 0.05 to 5 parts by weight based on 100 parts by weight of the component (A), and 0.05 to 4 parts by weight. It is preferable to use parts by weight. If the amount is too large, the physical properties of the cured product will be reduced. If the amount is too small, the intended mold release property will not be obtained.
- Examples of the reinforcing silica that is the component (E) of the composition of the present invention include fumed silica and precipitated silica. Among them, those having a particle size of 50 m or less and a specific surface area of 80 m 2 Zg or more are preferable from the viewpoint of reinforcing effect.
- Surface-treated silica for example, surface-treated with organosilane, organosilazane, diorganocyclopolysiloxane, or the like, is more preferable because it easily exhibits fluidity suitable for molding.
- a more specific example of the reinforcing silica-based material includes Nipsi 1 manufactured by Nippon Silica Co., Ltd., which is one of non-limiting silicas.
- the amount of the reinforcing silica to be added is not particularly limited, but is 0.1 to 100 parts by weight, preferably 0.5 to 80 parts by weight, particularly 1 to 50 parts by weight with respect to the component (A). It is preferable to use the department. If the amount is less than 0.1 part by weight, the effect of improving the reinforcing properties may not be sufficient, and if it exceeds 100 parts by weight, the workability of the curable composition may be reduced. . Further, the reinforcing silica of the present invention may be used alone or in combination of two or more.
- the curable composition of the present invention includes various additives for adjusting the physical properties, for example, a flame retardant, an anti-aging material, a filler, a plasticizer, a curable modifier, a physical property modifier, an adhesion promoter, Storage stability improvers, solvents, radical inhibitors, metal deactivators, ozone deterioration inhibitors, phosphorus peroxide decomposers, lubricants, pigments, foaming agents, photocurable resins, etc. And may be appropriately blended. These various additives may be used alone or in combination of two or more.
- a vinyl polymer is inherently a polymer having excellent durability, an antioxidant is not always necessary.
- conventionally known antioxidants, ultraviolet absorbers, light stabilizers and the like can be appropriately used. it can.
- various fillers may be used as necessary in addition to the reinforcing silica as the component (E).
- the filler include, but are not particularly limited to, wood flour, pulp, cotton chips, asbestos, glass fiber, carbon fiber, my strength, walnut shell powder, rice hull powder, graphite, diatomaceous earth, clay, silica (fumed silica) , Precipitated silica, crystalline silica, fused silica, dolomite, carboxylic anhydride, hydrous carboxylic acid, etc.), reinforcing fillers such as carbon black; heavy calcium carbonate, colloidal calcium carbonate, magnesium carbonate, diatomaceous earth, Calcined clay, clay, talc, titanium oxide, bentonite, organic bentonite, ferric oxide, bengar, aluminum fine powder, flint powder, zinc oxide, activated zinc, zinc dust, zinc carbonate, glass balloon, etc. Fillers such as; asbestos, glass fiber and glass filament, carbon fiber,
- precipitated silica fumed silica, crystalline silica, fused silica, dolomite, carbon black, calcium carbonate, titanium oxide, and talc are preferred.
- a high-strength cured product mainly fumed silica, precipitated silica, caustic anhydride, hydrous gay acid, carbon black, surface-treated fine calcium carbonate, crystalline silica, and fused silica
- a filler selected from silica, calcined clay, clay and activated zinc white can be added.
- silica whose surface is previously subjected to hydrophobic treatment with an organic silicon compound such as organosilane, organosilazane, or diorganopolysiloxane is more preferable.
- a filler selected from titanium oxide, calcium carbonate, talc, ferric oxide, zinc oxide, and shirasu balloon can be added.
- the specific surface area of calcium carbonate is small, the effect of improving the breaking strength, breaking elongation, adhesion and weather resistance of the cured product may not be sufficient.
- the greater the specific surface area the greater the effect of improving the strength at break, elongation at break, adhesion and weather resistance of the cured product.
- the calcium carbonate has been subjected to a surface treatment using a surface treatment agent.
- a surface treatment agent organic substances such as fatty acids, fatty acid stones, and fatty acid esters and various surfactants, and various power coupling agents such as a silane coupling agent and a titanate coupling agent are used.
- cabronic acid examples include, but are not limited to, cabronic acid, caprylic acid, pelargonic acid, capric acid, pendecanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, and oleic acid.
- salts of the fatty acids such as sodium and potassium, and alkyl esters of the fatty acids.
- the surfactant include polyoxyethylene alkyl ether sulfates and long-chain alcohol sulfates, and sulfate-type anionic surfactants such as sodium salts and potassium salts thereof, and alkylbenzene sulfonic acid, Alkyl naphthylene sulfonic acid, paraffin sulfonic acid, ⁇ -olefin sulfonic acid, alkyl sulfosuccinic acid, etc. Sulfonic acid-type anionic surfactants such as lime salts and potassium salts are exemplified.
- the amount of the surface treatment agent to be treated is preferably 0.1 to 20% by weight, more preferably 1 to 5% by weight, based on calcium carbonate. If the treatment amount is less than 0.1% by weight, the effect of improving workability, adhesion and weather resistance may not be sufficient, and if it exceeds 20% by weight, the storage stability of the curable composition may be insufficient. May drop.
- colloidal calcium carbonate is used when the effect of improving the thixotropy of the compound, the breaking strength of the cured product, the breaking elongation, and the adhesiveness and weather resistance is particularly expected. Is preferred.
- heavy calcium carbonate is sometimes added for the purpose of lowering the viscosity, increasing the amount of the formulation, reducing costs, etc.When using this heavy calcium carbonate, use the following as necessary. can do.
- Heavy calcium carbonate is obtained by mechanically grinding and processing natural chalk (chalk), marble, and limestone.
- the pulverization method includes a dry method and a wet method, but a wet pulverized product is often not preferable because the storage stability of the curable composition of the present invention is often deteriorated.
- Heavy calcium carbonate becomes a product having various average particle sizes by classification. Is not particularly limited, the strength at break, elongation at break, when to expect the effect of improving adhesiveness and weather-resistant adhesion, the value of specific surface area include: 1. 5 m 2 Roh g to 50 m 2 / g Preferably, Above 50m is a further preferred 2 / g or less, 2.
- the value of the specific surface area is an air permeation method (a method of determining the specific surface area from the permeability of air to a powder-packed layer) performed according to JISK 5101 as a measuring method. )).
- the measuring device it is preferable to use a specific surface area measuring device SS-100 manufactured by Shimadzu Corporation.
- fillers may be used alone or in combination of two or more depending on the purpose and need. Is not particularly limited, for example, to suppress the value of the specific surface area as required combine 1. 5 m 2 Z g or more heavy calcium and colloidal calcium carbonate, the increase in the viscosity distribution compound moderately, Improvements in the breaking strength, elongation at break, adhesion and weather resistance of the cured product can be greatly expected.
- the filler When the filler is used, the filler is preferably used in an amount of 5 to 100 parts by weight, more preferably 100 to 500 parts by weight, based on 100 parts by weight of the Bier polymer. It is more preferably used in the range of 40 parts by weight, particularly preferably in the range of 40 to 300 parts by weight. If the amount is less than 5 parts by weight, the effect of improving the breaking strength, elongation at break, adhesion and weather resistance of the cured product may not be sufficient. The workability of the composition may be reduced.
- the filler may be used alone or in combination of two or more.
- fine hollow particles may be used in combination with these reinforcing fillers.
- Such minute hollow particles are not particularly limited, but have a diameter of lmm or less, preferably 500 mm, as described in “The Latest Technology of Functional Filaments” (CM C).
- CM C The Latest Technology of Functional Filaments
- a hollow body made of an inorganic or organic material of 200 m or less is used.
- a true specific gravity of 1. O g / cm 3 is preferable to use a less is fine hollow bodies, even zero. It is preferred to use a 5 g / cm 3 or less is small hollow bodies.
- Examples of the inorganic balloon include a silicate balloon and a non-silicate balloon.
- Silica balloons include shirasu balloon, perlite, glass balloon, and silica.
- Balloons, fly ash balloons, and the like, and non-silicic acid balloons include alumina balloons, zirconia balloons, carpone balloons, and the like.
- Specific examples of these inorganic balloons include Winlite manufactured by Dichi Kasei as a Shirasu balloon, Sankilite manufactured by Sanki Kogyo, Caloon manufactured by Nippon Sheet Glass, Cellstar Z-28 manufactured by Sumitomo Suriname, EMERSON & CUM as a glass balloon.
- Examples of the organic balun include a balun of a thermosetting resin and a balun of a thermoplastic resin.
- thermosetting balloon include a phenol balloon, an epoxy balun, and a urea balloon.
- examples include Saran balloons, polystyrene balloons, polymethacrylate balloons, polyvinyl alcohol balloons, and styrene-acrylic balloons.
- a balloon of a crosslinked thermoplastic resin can be used. The balloon mentioned here may be a balloon after foaming, or a balloon containing a foaming agent may be foamed after blending.
- organic balloons include UCAR and PHENOL ICMIC OBALLOONS manufactured by Union Power Co., Ltd. as phenolic balloons, ECCOSPHER ES manufactured by EMERSON & CUMING as epoxy balloons, and ECCOS PHE manufactured by EMERSON & CUM ING as urea balloons.
- the above balloons may be used alone or as a mixture of two or more.
- the surface of these balloons is improved with fatty acids, fatty acid esters, rosin, rosin lignin, silane coupling agents, titanium coupling agents, aluminum coupling agents, polypropylene glycol, etc. to improve the dispersibility and the workability of the compound. What has been processed can be used.
- These baluns are used to reduce the weight and cost without impairing the flexibility and elongation / strength of the physical properties when the composition is cured.
- the content of the balloon is not particularly limited, it can be preferably used in the range of 0.1 to 50 parts, more preferably 0.1 to 30 parts, per 100 parts by weight of the vinyl polymer.
- the amount is less than 0.1 part, the effect of weight reduction is small, and when the amount is more than 50 parts, a decrease in tensile strength among mechanical properties when the composition is cured may be observed.
- the specific gravity of the balloon is 0.1 or more, it is preferably 3 to 50 parts, more preferably 5 to 30 parts.
- the plasticizer that can be blended is not particularly limited.
- dibutyl phthalate, diheptyl phthalate, di (2-ethylhexyl) phthalate, butyl benzyl phthalate, and the like may be used for the purpose of adjusting physical properties and controlling properties.
- Furic acid esters Dioctyl adipate, Dioctyl sebacate, Dibutyl sebacate, Succinic Non-aromatic dibasic acid esters such as isodecyl acid; aliphatic esters such as butyl oleate and acetyl methyl ricinoleate; diethylene diol dibenzoate, triethylene glycol dibenzoate, pentaerythritol ester and the like Polyalkylene glycol esters; Phosphoric esters such as tricresyl phosphate and tributyl phosphate; Trimellitic esters; Polystyrenes such as polystyrene and poly- ⁇ -methylstyrene; polybutadiene, polybutene, polyisobutylene, butadiene Acrylonitrile, polychloroprene; Chlorinated paraffins; Hydrocarbon oils such as alkyl diphenyl, partially hydrogenated phenyl,
- Xyplasticizers Polyesters obtained from dibasic acids such as sebacic acid, adipic acid, azelaic acid, and phthalic acid and dihydric alcohols such as ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, and dipropylene glycol
- Plasticizers Pinyl polymers obtained by polymerizing pinyl monomers such as acrylic plasticizers by various methods, and the like.
- a polymer plasticizer which is a polymer having a number average molecular weight of 500 to 1500, is added to obtain a viscosity of the curable composition and a cured product obtained by curing the composition.
- the mechanical properties such as tensile strength and elongation of the polymer can be adjusted, and the initial physical properties are maintained for a long time compared to the case where a low molecular weight plasticizer that is a plasticizer that does not contain polymer components is used. It is possible to improve the drying property (also referred to as coating property) when an alkyd paint is applied to the cured product.
- the polymer plasticizer may or may not have a functional group.
- the number average molecular weight of the high molecular weight plasticizer is described as 500 to 150 000, Preferably it is 800-10000, more preferably 1000-8000. If the molecular weight is too low, the plasticizer flows out over time due to heat or rainfall, and the initial physical properties cannot be maintained for a long time, and the alkyd coating property may not be improved. On the other hand, if the molecular weight is too high, the viscosity increases, and the workability deteriorates.
- polymeric plasticizers those that are compatible with the vinyl polymer are preferred.
- vinyl polymers are preferred in view of compatibility, weather resistance, and heat resistance.
- a (meth) acrylic polymer is preferable, and an acrylic polymer is more preferable.
- Examples of the method for synthesizing this acrylic polymer include those obtained by conventional solution polymerization, and solventless acrylic polymers.
- the latter acrylic plasticizer was prepared by a high-temperature continuous polymerization method (USP4414370, JP-A-59-6207, JP-B 5-58005, JP-A-1-313522, USP 5010166) without using a solvent or a chain transfer agent. Therefore, it is more preferable for the purpose of the present invention.
- Examples thereof include, but are not limited to, Toagosei Co., Ltd., UP series, etc. (see Industrial Materials, October 1999).
- a living radical polymerization method can also be mentioned as another synthesis method. This method is preferable because the molecular weight distribution of the polymer is narrow and the viscosity can be reduced. Further, atom transfer radical polymerization is more preferable, but not limited thereto.
- the molecular weight distribution of the polymeric plasticizer is not particularly limited, but is preferably narrow, and is preferably less than 1.8. 1.7 or less is more preferred, 1.6 or less is still more preferred, 1.5 or less is still more preferred, 1.4 or less is particularly preferred, and 1.3 or less is most preferred.
- the plasticizers including the above-mentioned polymer plasticizers may be used alone or in combination of two or more, but are not necessarily required. If necessary, a high-molecular plasticizer may be used, and a low-molecular plasticizer may be further used in a range that does not adversely affect the physical properties. These plasticizers can be added at the time of polymer production.
- the amount of the plasticizer to be used is not limited, but it is 5 to 150 parts by weight, preferably 10 to 120 parts by weight, more preferably 100 to 100 parts by weight of the vinyl polymer. Is from 20 to 100 parts by weight. If the amount is less than 5 parts by weight, the effect as a plasticizer will not be exhibited, and if it exceeds 150 parts by weight, the mechanical strength of the cured product will be insufficient.
- a reactive diluent described below may be used in addition to the above-described plasticizer.
- the reactive diluent include organic compounds having at least one alkenyl group or alkynyl group capable of undergoing a hydrosilylation reaction in the molecule. This compound reduces the viscosity of the composition before curing, and at the time of the curing reaction, binds to the Si-H group of the hydrosilyl group-containing compound (II) by the hydrosilylation reaction, and is eventually incorporated into the network structure. .
- the present invention there is no particular limitation as long as it is an organic compound having at least one alkenyl group or alkynyl group capable of undergoing a hydrosilylation reaction in the molecule.
- a compound having a polar group such as an ester group is preferable from the viewpoint of good solubility.
- the lower the molecular weight the easier the compatibility becomes, so that it is preferable.
- the molecular weight is sufficiently compatible, it may be higher to some extent.
- the reactive diluent compound does not have a carbon-carbon unsaturated bond having low activity for hydrosilylation. I like it.
- the compound When a low-boiling compound that can be volatilized during curing and curing is used as the reactive diluent compound, the compound may change its shape before and after curing, or may adversely affect the environment due to volatiles. Accordingly, an organic compound having a boiling point at room temperature of 100 or more is particularly preferable.
- Specific examples of the reactive diluent compound include 1-octene, 4-vinylcyclohexene, acrylyl acetate, 1,1-diacetoxy 2-propene, methyl pentadecenoate, 8-acetoxy 1,6-tactagene, and the like. However, it is not limited to this.
- the amount of the reactive diluent compound to be added is within a range that does not hinder the formation of a three-dimensional crosslinked structure by the hydrosilylation reaction between the vinyl polymer (I) and the hydrosilyl group-containing compound (II).
- the reactive diluent compound is 0.1 to 100 parts by weight per 100 parts by weight of the vinyl polymer (I). It is preferable to use 0.5 to 70 parts by weight, particularly 1 to 50 parts by weight.
- Solvents that can be blended include, for example, aromatic hydrocarbon solvents such as toluene and xylene, ester solvents such as ethyl acetate, butyl acetate, amyl acetate, and cellosolve acetate, methyl ethyl ketone, methyl isobutyl ketone, and diisobutyl. Examples thereof include ketone solvents such as ketones. These solvents may be used during the production of the polymer.
- Examples of the curing regulator that can be blended include compounds containing an aliphatic unsaturated bond.
- the curing regulator that can be blended include compounds containing an aliphatic unsaturated bond.
- R a and R b are the same or different and represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, or an aryl group having 6 to 10 carbon atoms. Is also good. )
- Examples of acetylenic alcohols with a good balance between storage stability and curability include 2-phenyl-3-butyne-12-yl, 1-ethynyl-1-cyclohexanol, and 35-dimethyl-1-hexynyl. 3-ol, 3-methyl-1-1-hexin-1-ol, 3-ethyl-1--1-pentin-3-ol, 2-methyl-3-butyn-1-ol, 3-methyl-1-pentin-3- Oars and the like.
- Compounds other than acetylene alcohols containing an aliphatic unsaturated bond that improves storage stability at high temperatures include:
- R e R d R e are the same or different and are a hydrogen atom or a hydrocarbon group having 16 carbon atoms, and the total number of carbon atoms of R c R d R e is 26.
- Rc and R d , or R d and R e are a hydrocarbon group, they may be linked to each other.
- R f , R g , and R h are the same or different and are a hydrocarbon group having 1 to 10 carbon atoms. However, R g and R h may be mutually connected.
- Ri may be the same or different, at least one of which is a hydrocarbon group having 1 to 10 carbon atoms having an acetylenic unsaturated bond.
- N is an integer of 1 to 10 Represents.
- R j may be the same or different and each represents a hydrogen atom, a halogen, or a monovalent hydrocarbon group having 1 to 10 carbon atoms.
- X represents a halo such as chlorine, bromine or the like.
- Olefinic compounds of olefinic alcohols such as vinyl acetate, aliphatic carboxylic acid esters of olefinic alcohols such as vinyl acetate, tetravinylsiloxane cyclics, nitriles containing aliphatic unsaturated bonds such as 2-pentenenitrile, and alkyl acetylenedicarboxylates. —, Maleic acid ester, diorganofumarate and the like.
- the amount of the curability modifier used can be almost arbitrarily selected as long as it is uniformly dispersed in the components (A) and (B). It is preferable to use in the range of 1 to 1000 molar equivalents.
- the curability adjusting agent may be used alone or in combination of two or more.
- the curable composition of the present invention When the curable composition of the present invention is used alone as a molded rubber, it is not necessary to particularly add an adhesive, but if it is necessary to perform two-color molding with a different kind of substrate, a vinyl-based resin is used. It does not significantly inhibit the cross-linking reaction between the union (I) and the hydrosilyl group-containing compound (II), does not significantly affect the physical properties of the obtained cured product, and does not affect the mold release property of the present invention. It is possible to add an adhesion-imparting agent to an extent that is not present.
- the adhesiveness-imparting agent that can be blended is not particularly limited as long as it imparts adhesiveness to the curable composition, but is preferably a crosslinkable silyl group-containing compound, and more preferably a silane coupling agent.
- Specific examples thereof include alkylalkoxysilanes such as methyltrimethoxysilane, dimethyldimethoxysilane, trimethylmethoxysilane and n-propyltrimethoxysilane; and alkylalkoxysilanes such as dimethyldiisopropoxysilane and methyltriisopropoxyoxysilane.
- Isopropenoxysilane silanes containing a vinyl-type unsaturated group such as vinyltrimethoxysilane, vinyldimethylmethoxysilane, vinyltriethoxysilane, methacryloyloxypropylmethyldimethoxysilane, and acryloxypropylmethyltriethoxysilane.
- Silicone varnishes polysiloxanes and the like. Among them, cross-linking with organic groups having atoms other than carbon and hydrogen such as epoxy group, (meth) acrylic group, isocyanate group, isocyanurate group, olebamate group, amino group, mercapto group, carboxyl group, etc.
- a silane coupling agent having a hydrophilic silyl group is also preferable.
- alkoxysilanes having an isocyanate group include isopropyl isopropyl trimethoxy silane, isopropyl propyl triethoxy silane, and ⁇ -isopropyl propyl methyl ethoxy methoxy.
- Silanes, isocyanate group-containing silanes such as isopropyl cyanomethyldimethoxysilane; and alkoxysilanes having an isocyanurate group include isocyanurate silanes such as tris (trimethoxysilyl) isocyanurate; amino groups
- alkoxysilanes having the following are ⁇ -aminopropyltrimethoxysilane, r-aminopropyltriethoxysilane, r-aminopropylmethyldimethoxysilane, r-aminopropylmethyljetoxysilane, ⁇ - () 3-amino Tyl) —aminopropyl trimethoxysilane, ⁇ — (monoaminoethyl) ⁇ -aminopropylmethyldimethoxysilane, N— () 3-aminoethyl) ⁇ -aminopropyltriethoxysilane, N— (/
- silylated amino polymers can also be used as the silane coupling agent.
- unsaturated aminosilane complexes phenylamino long-chain alkylsilanes, aminosilylated silicones, silylated polyesters, and the like, which are derivatives of the above, can also be used as the silane coupling agent.
- alkoxysilanes having an epoxy group or a (meth) acryl group in the molecule are more preferable from the viewpoint of curability and adhesiveness.
- alkoxysilane having an epoxy group include adalicidoxypropylmethyldimethoxysilane, adalicidoxypropyltrimethoxysilane, aglycidoxypropyltriethoxysilane, ⁇ - (3,4-epoxycyclohexyl) ethyltrimethoxysilane,) 3- (3,4-epoxycyclohexyl) ethyltriethoxysilane, aglycidoxypropylmethyldiisoproponoxysilane, etc.
- alkoxysilanes having a (meth) acrylic group examples include: methacryloxypropyltrimethoxysilane, methacryloxypropyltriethoxysilane, acryloxypropyltrimethoxysilane, and acryloxypropyltriethoxysilane.
- a crosslinkable silyl group condensation catalyst can be used together with the above-mentioned adhesiveness-imparting agent.
- the crosslinkable silyl group condensation catalyst include dibutyltin dilaurate, dibutyltin diacetylacetonate, and dibutyltin dimethoxide.
- examples thereof include organic tin compounds such as tin and tin octylate; organic aluminum compounds such as aluminum acetyl acetonate; and organic titanium compounds such as tetraisopropoxy titanium and tetrabutoxy titan.
- silane coupling agent examples include an epoxy resin, a phenol resin, sulfur, an alkyl titanate, and an aromatic polyisocyanate.
- the adhesiveness-imparting agent is incorporated in an amount of 0.01 to 20 parts by weight based on 100 parts by weight of the vinyl polymer (I). If the amount is less than 0.01 part by weight, the effect of improving the adhesion is small, and if it exceeds 20 parts by weight, the physical properties of the cured product are adversely affected. Preferably it is 0.1 to 10 parts by weight, more preferably 0.5 to 5 parts by weight.
- the above-mentioned adhesiveness-imparting agent may be used alone or in combination of two or more.
- the vinyl polymer (I) and the hydrosilyl group-containing compound (II) can be mixed in any ratio, but from the viewpoint of curability, the molar ratio of the alkenyl group to the hydrosilyl group is in the range of 5 to 0.2. And more preferably 2.5 to 0.4.
- the molar ratio is 5 or more, only a low-strength cured product with insufficient adhesion is obtained, and when it is less than 0.2, a large amount of active hydrosilyl groups remains in the cured product after curing. As a result, cracks andware are generated, and a uniform and strong cured product cannot be obtained.
- the curable composition is cured by the addition reaction of the Si—H group to the alkenyl group using the noble metal catalyst, the curing speed is extremely high, which is convenient for line production.
- the temperature for thermosetting is preferably in the range of 100 ° C to 180 ° C. At a temperature lower than 100 ° C, the curing reaction hardly proceeds because the composition has excellent storage stability. The hydrosilylation reaction proceeds, and a cured product can be obtained in a short time.
- the curable composition according to the present invention has excellent storage stability even at a relatively high temperature, so that the composition can be handled with a lower viscosity, and is suitable for liquid injection molding at a high temperature.
- the curable composition when allowed to flow, it is preferably performed at a temperature of 30 ° C. or more and less than 100 ° C., but is preferably flowed at a temperature of 40 ° C. or more and less than 80 ° C. Is more preferable.
- the curable composition can be caused to flow at a temperature of 30 ° C. or more and less than 100 ° C., and a curing reaction can be carried out while flowing at 30 ° C. or more. That is, the curable composition of the present invention can be used as a resin for injection molding (RIM, LIM, etc.).
- the molding method when the curable composition of the present invention is used as a molded article is not particularly limited, and various generally used molding methods can be used. For example, casting molding, compression molding, transfer molding, injection molding, extrusion molding, rotary molding, hollow molding, thermoforming and the like can be mentioned. In particular, injection molding is preferred from the viewpoint that automation and continuity are possible and productivity is excellent.
- the curable composition of the present invention includes, but is not limited to, electric and electronic component materials such as solar cell back-side encapsulants, electric insulating materials such as insulating coatings for electric wires and cables, coating materials, foams, and electric and electronic materials. Potting materials, films, gaskets, casting materials, artificial marble, various molding materials, and various applications such as netted glass and sealing materials for waterproofing and waterproofing of laminated glass end faces (cut sections). is there.
- the molded article exhibiting rubber elasticity obtained from the curable composition of the present invention can be widely used mainly for gaskets and packings.
- gaskets and packings For example, in the automotive field, It can be used as a sealing material for maintaining airtightness, an anti-vibration material for glass, an anti-vibration material for body parts, especially for wind seal gaskets and gaskets for door glass.
- a chassis part it can be used for anti-vibration and sound-proof engines and suspension rubbers, especially engine mount rubber.
- engine parts it can be used for hoses for cooling, fuel supply, exhaust control, etc., and seal materials for engine oil. It can also be used for exhaust gas cleaning equipment parts and brake parts.
- Oil gas meter packing Oil supply pipe, diaphragm valve, air supply pipe, etc.
- Carr Edge turntable seat, belts, pulleys first class, and the like.
- structural gaskets zipper gaskets
- air film structure roofing materials waterproofing materials, fixed sealing materials, vibration proofing materials, soundproofing materials, setting blocks, sliding materials, etc.
- sports field it can be used for sports floors such as all-weather pavement and gymnasium floors, sports shoes for shoe soles and midsole, and ball poles for golf poles.
- anti-vibration rubber it can be used as anti-vibration rubber for automobiles, anti-vibration rubber for railway vehicles, anti-vibration rubber for aircraft, fenders, etc.
- rubber expansion joints, bearings, water barriers, waterproof sheets, rubber dams, elastic pavements, vibration-isolating pats, protective bodies, etc. as structural materials, rubber formwork, rubber packing, rubber as auxiliary construction materials Skirt, sponge Mats, mortar hoses, mortar strainers, etc., rubber sheets, air hoses, etc. as construction auxiliary materials, rubber buoys, wave absorbers, etc. as safety measures products, oil fences, silt fences, antifouling materials, marine hoses, dressing as environmental protection products Can be used for hoses, oil skimmers, etc. In addition, it can be used for rubber plate, mat, foam board, etc.
- number average molecular weight and “molecular weight distribution (ratio of weight average molecular weight to number average molecular weight)” were calculated by a standard polystyrene conversion method using gel permeation chromatography (GPC). However, a GPC column packed with a crosslinked polystyrene gel (shodeX GPC K-804; manufactured by Showa Dye) was used, and a form of GPC solvent was used.
- GPC gel permeation chromatography
- the mold releasability was evaluated based on the following four steps regarding the ease of removal of the cured product from the mold.
- the cured product can be removed from the mold without resistance
- the solid copper in the polymer mixture was filtered with a bag filter (manufactured by HA YWARD, nominal filter cloth pore diameter l ⁇ m).
- the filtrate contains 50 parts SH (manufactured by Kyowa Chemical Co., Ltd .: 2 parts by weight per 100 parts by weight of copolymer).
- Toluene 100 parts by weight per 100 parts by weight of copolymer
- Kyowaward 500 SH (2 parts by weight per 100 parts by weight of copolymer)
- Kyoward 700 SL Kyowa Chemical (2 parts by weight based on 100 parts by weight of polymer)
- a hindered phenolic antioxidant Irganox O1 O; 0.05 parts by Ciba Chemicals
- Irganox O1 O 0.05 parts by Ciba Chemicals
- the number average molecular weight of the copolymer [P 1] was 18,000, and the molecular weight distribution was 1.1.
- the average number of alkenyl groups introduced per molecule of the copolymer was determined by 1 H NMR analysis to be 1.9.
- Example 3 The releasability was evaluated in the same manner as in Example 1 except that 1 part of calcium stearate (trade name: SC-100, manufactured by Sakai Chemical) was used as the metal stone. The results are shown in Table 1. (Example 3)
- the releasability was evaluated in the same manner as in Example 1 except that 1 part of zinc stearate (trade name: SZ-100, manufactured by Sakai Chemical) was used as the metal stone. The results are shown in Table 1.
- Example 1 Same as Example 1 except that 1 part of zinc stearate (trade name: SZ-100, manufactured by Sakai Chemical) was used as the metal stone, and the mold release was evaluated after the mold was cooled to room temperature after press vulcanization. And the releasability was evaluated. The results are shown in Table 1.
- SZ-100 trade name: SZ-100, manufactured by Sakai Chemical
- Zinc stearate (trade name: SZ-100, manufactured by Sakai Chemical) as metal stone Except for using 5 parts, the releasability was evaluated in the same manner as in Example 1. The results are shown in Table 1
- the releasability was evaluated in the same manner as in Example 1 except that 0.5 part of zinc stearate (trade name: SZ-P, manufactured by Sakai Chemical) was used as the metal stone. The results are shown in Table 1.
- the present invention provides a molding curable composition having excellent mold release properties by using an alkenyl group-containing Bier polymer, a hydrosilyl group-containing compound, a hydrosilylation catalyst, and a metal stone as essential components.
- This Bier polymer is preferably produced by living radical polymerization, more preferably by atom transfer radical polymerization, whereby precise control of molecular weight and functionalization ratio enables appropriate physical property control. .
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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US10/518,497 US20050228128A1 (en) | 2002-07-30 | 2003-07-17 | Mold-releasable curable composition |
EP03741471A EP1526155A4 (en) | 2002-07-30 | 2003-07-17 | RELEASABLE CURABLE COMPOSITION |
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JP2002221373A JP2004059783A (ja) | 2002-07-30 | 2002-07-30 | 金型離型性を有する硬化性組成物 |
JP2002-221373 | 2002-07-30 |
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US (1) | US20050228128A1 (ja) |
EP (1) | EP1526155A4 (ja) |
JP (1) | JP2004059783A (ja) |
CN (1) | CN1671794A (ja) |
WO (1) | WO2004011552A1 (ja) |
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EP1760112B1 (en) * | 2004-05-28 | 2009-09-02 | Kaneka Corporation | Curable composition and cured product thereof |
DE102005055649B4 (de) * | 2004-11-24 | 2018-01-11 | Osaka Soda Co., Ltd. | Zusammensetzung für Gummi und Vulkanisationsprodukt |
JP5236941B2 (ja) * | 2005-02-25 | 2013-07-17 | 株式会社カネカ | 硬化性組成物およびその硬化物 |
JP4860953B2 (ja) * | 2005-07-08 | 2012-01-25 | 富士通株式会社 | シリカ系被膜形成用材料、シリカ系被膜及びその製造方法、多層配線及びその製造方法、並びに、半導体装置及びその製造方法 |
DE102005045167B4 (de) * | 2005-09-21 | 2012-07-05 | Carl Freudenberg Kg | Verwendung eines vernetzten Kautschukcompounds als Material für eine Brennstoffzelle |
TWI520973B (zh) | 2010-09-01 | 2016-02-11 | Kaneka Corp | 電氣、電子元件材料用組合物及其硬化物 |
CN103237827A (zh) | 2010-12-02 | 2013-08-07 | 株式会社钟化 | 光学材料用活性能量射线固化性组合物、固化物及其制造方法 |
CN103827218B (zh) | 2011-12-08 | 2016-03-16 | 迈图高新材料日本合同公司 | 氢硅烷化固化型硅橡胶组合物 |
DE102012101710A1 (de) * | 2012-03-01 | 2013-09-05 | Solarworld Innovations Gmbh | Verfahren zur Einkapselung einer Solarzelle in einer Polymermatrix |
TWI829640B (zh) | 2017-07-10 | 2024-01-21 | 美商陶氏有機矽公司 | 可固化聚矽氧組合物及光學半導體裝置 |
CN112795167B (zh) * | 2019-11-13 | 2023-04-07 | 台光电子材料股份有限公司 | 树脂组合物及其制品 |
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EP0604104A2 (en) * | 1992-12-14 | 1994-06-29 | Shin-Etsu Chemical Co., Ltd. | Hydrosilylative compositions and hydrosilylation reaction processes |
EP0985710A1 (en) * | 1998-09-02 | 2000-03-15 | Dow Corning Toray Silicone Company, Ltd. | Curable silicone composition |
JP2001342350A (ja) * | 2000-03-27 | 2001-12-14 | Kanegafuchi Chem Ind Co Ltd | 硬化性組成物 |
Family Cites Families (13)
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JPH04222871A (ja) * | 1990-12-25 | 1992-08-12 | Toray Dow Corning Silicone Co Ltd | 硬化性オルガノポリシロキサン組成物 |
US5371150A (en) * | 1992-07-08 | 1994-12-06 | Shin-Etsu Chemical Co., Ltd. | Fluorocarbon rubber composition |
US5468550A (en) * | 1994-06-06 | 1995-11-21 | Bridgestone/Firestone, Inc. | EPDM roofing membrane with improved burn resistivity |
EP0709403A1 (en) * | 1994-10-28 | 1996-05-01 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Curable composition for injection molding |
US5763548A (en) * | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
JP3806475B2 (ja) * | 1996-02-08 | 2006-08-09 | 株式会社カネカ | 末端に官能基を有する(メタ)アクリル系重合体の 製造方法 |
US5733480A (en) * | 1996-09-24 | 1998-03-31 | Quantum Chemical Corporation | Semiconductive extrudable polyolefin compositions and articles |
JP4063384B2 (ja) * | 1998-03-02 | 2008-03-19 | ダウ・コ−ニング・コ−ポレ−ション | ハイドロカーボンオキシシリル官能性ポリマーの製造方法 |
US6753372B1 (en) * | 1997-07-25 | 2004-06-22 | E. I. Du Pont De Nemours And Company | Flame retardant polyolefin compositions |
EP1002847B8 (en) * | 1997-08-06 | 2015-06-03 | Kaneka Corporation | Self-adhesive composition |
WO2000020498A1 (fr) * | 1998-10-08 | 2000-04-13 | Kaneka Corporation | Compositions durcissables |
KR100682809B1 (ko) * | 1999-03-16 | 2007-02-15 | 미쓰이 가가쿠 가부시키가이샤 | 가교성 고무 조성물 및 그 용도 |
DE60134851D1 (de) * | 2000-05-24 | 2008-08-28 | Kaneka Corp | Härtbare zusammensetzungen und kompatibilitätsmittel |
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2002
- 2002-07-30 JP JP2002221373A patent/JP2004059783A/ja active Pending
-
2003
- 2003-07-17 WO PCT/JP2003/009126 patent/WO2004011552A1/ja active Application Filing
- 2003-07-17 US US10/518,497 patent/US20050228128A1/en not_active Abandoned
- 2003-07-17 EP EP03741471A patent/EP1526155A4/en not_active Withdrawn
- 2003-07-17 CN CN03817431.6A patent/CN1671794A/zh active Pending
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EP0604104A2 (en) * | 1992-12-14 | 1994-06-29 | Shin-Etsu Chemical Co., Ltd. | Hydrosilylative compositions and hydrosilylation reaction processes |
EP0985710A1 (en) * | 1998-09-02 | 2000-03-15 | Dow Corning Toray Silicone Company, Ltd. | Curable silicone composition |
JP2001342350A (ja) * | 2000-03-27 | 2001-12-14 | Kanegafuchi Chem Ind Co Ltd | 硬化性組成物 |
Non-Patent Citations (1)
Title |
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See also references of EP1526155A4 * |
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EP1526155A1 (en) | 2005-04-27 |
EP1526155A4 (en) | 2005-10-19 |
US20050228128A1 (en) | 2005-10-13 |
JP2004059783A (ja) | 2004-02-26 |
CN1671794A (zh) | 2005-09-21 |
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