WO2003076712A1 - Procede pour traiter un tissu teint a l'indigo, et tissu teint a l'indigo traite selon le procede - Google Patents

Procede pour traiter un tissu teint a l'indigo, et tissu teint a l'indigo traite selon le procede Download PDF

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Publication number
WO2003076712A1
WO2003076712A1 PCT/JP2002/005551 JP0205551W WO03076712A1 WO 2003076712 A1 WO2003076712 A1 WO 2003076712A1 JP 0205551 W JP0205551 W JP 0205551W WO 03076712 A1 WO03076712 A1 WO 03076712A1
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WO
WIPO (PCT)
Prior art keywords
indigo
vintage
color
fabric
nitrogen
Prior art date
Application number
PCT/JP2002/005551
Other languages
English (en)
Japanese (ja)
Inventor
Tatsuhiko Nakano
Original Assignee
Kotosen Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kotosen Co., Ltd. filed Critical Kotosen Co., Ltd.
Priority to EP02733317A priority Critical patent/EP1486607A4/fr
Priority to AU2002306249A priority patent/AU2002306249A1/en
Priority to US10/507,072 priority patent/US20050223507A1/en
Publication of WO2003076712A1 publication Critical patent/WO2003076712A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
    • D06M11/65—Salts of oxyacids of nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67391—Salts or oxidising-compounds mixtures
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/10—After-treatment with compounds containing metal
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/13—Fugitive dyeing or stripping dyes
    • D06P5/132—Fugitive dyeing or stripping dyes with oxidants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/15—Locally discharging the dyes
    • D06P5/153—Locally discharging the dyes with oxidants

Definitions

  • the present invention relates to a method of processing a dyed fabric and a dyed dyed fabric processed by the method.
  • the present invention relates to a method for processing indigo dyed fabric and a dyed fabric processed by the method.
  • indigo dyed products dyed with indigo dyes exhibit relatively clear hues immediately after dyeing.For a long period of time, for example, during storage or use for ten to several decades
  • those with relatively high dyeing density gradually change to deep blue and calm hue
  • those with relatively low dyeing density gradually change to yellowish deep calm hue.
  • vintage colors are preferred in denim, and the demand for denim having vintage colors is rapidly increasing. If denim is actually stored for a long period of time in order to obtain denim having such a vintage color, the supply amount is insufficient, and a method of applying the vintage color to the denim in a relatively short time is desired.
  • the entire fabric or the whole fabric is formed at the stage when the fabric is formed using a warp yarn dyed only with indigo dye. Attempts have also been made to overdie the entire product with the yellow dye at the stage of commercialization. However, since the weft yarn is also dyed at the same time with such a technique, the resulting hue has a sense of incongruity that clearly indicates that a yellow dye has been used, and it is difficult to sufficiently reproduce the original vintage color. could not.
  • Japanese Patent Application Laid-Open No. 11-200261 discloses a method of processing cotton products such as jeans in which nitric acid is allowed to act on a cotton product such as jeans or a fabric thereof and then neutralized with a basic substance.
  • nitric acid is allowed to act on a cotton product such as jeans or a fabric thereof and then neutralized with a basic substance.
  • Even if the denim could be given a vintage color, it easily disappeared by post-processing such as washing.
  • the dyeing concentration of the Indigo dye tends to decrease significantly, and it has been difficult to set the dyeing concentration of the Indigo dye at a relatively high level. Disclosure of the invention
  • the present invention has been made in view of the above circumstances, and has a vintage color equivalent to the indigo dyed fabric actually stored or used for a long period of time, and is hardly lost even by washing processing!
  • An object of the present invention is to provide a method for processing an Indigo dyed fabric that can be applied in a relatively short period of time, and an Indigo dyed fabric to which such a vintage color has been applied.
  • the present invention relates to a method for processing an indigo dyed fabric, which comprises applying a nitrogen-based oxidizing agent to an indigo dyed fabric and subjecting the dough to heat treatment, and to an indigo dyed fabric processed by the method.
  • a nitrogen-based oxidizing agent is first applied to the indigo dyed fabric (nitrogen-based oxidizing agent application step).
  • the indigo dyed fabric used in the method of the present invention is a fabric at least partially dyed with a synthetic or natural indigo dye.
  • the portion dyed with the Indigo dye has a vintage color equivalent to that of the Indigo dyed fabric actually stored or used for a long period of time, and is hardly lost even by washing. Vintage color.
  • fabric is not limited to a planar form such as a woven fabric, a knitted fabric, or a non-woven fabric, but may be in the form of a product thereof (for example, jeans, etc.), as well as by twisting S-weave and a plurality of Ht. It is used in a concept that also encompasses the form of a thread or the like.
  • the fiber that can constitute the fabric is not particularly limited as long as it can be dyed with an indigo dye.
  • cellulosic natural fibers cotton, hemp, etc.
  • cellulosic regenerated fibers rayon, cuvula, etc.
  • cellulosic half Synthetic boats such as acetate
  • blends of these with synthetic fibers may be used.
  • so-called denim in which cotton yarn dyed with the indigo dye is woven as warp yarn and undyed cotton yarn (raw yarn) is woven as weft yarn, and a relatively large number of warp yarns appear on the front side surface, It is preferable from the viewpoint of giving a more excellent vintage color.
  • the dum may be one which has been subjected to a conventionally known processing described later, for example, a baking treatment, a blanching treatment, a twist preventing treatment, a P-squaring treatment, a washing treatment, or the like.
  • the untreated fabric immediately after weaving may be used, but from the viewpoint of applying the vintage color uniformly and efficiently, the one that has been subjected to shampooing, blanching, twist prevention, and shrinkproofing is used. Is preferred.
  • the washing treatment is usually performed after the treatment of the present invention.
  • a known processing may be performed after the processing of the present invention is performed.
  • the nitrogen-based oxidizing agent used in the present invention is an oxidizing agent capable of oxidizing an indigo dye and capable of generating nitrogen oxide in a subsequent nitrogen oxide generating step.
  • a nitrogen-based oxidizing agent examples include nitrate, nitric acid, ammonium nitrate, nitrite, nitrite, and ammonium nitrite.
  • the indigo dyed fabric that is actually stored or used for a long period of time is used. It is considered that it is possible to give a vintage color that is the same vintage color and hardly disappears by washing.
  • the nitrogen oxides generated by using a specific oxidizing agent (nitrogen-based oxidizing agent) and performing the processing in the subsequent steps are:
  • nitrogen-based oxidizing agent nitrogen-based oxidizing agent
  • the fabric can be given an excellent vintage color.
  • the vintage color can be easily removed by post-processing such as washing and processing even if a vintage color can be imparted.
  • nitrates include heavy metal nitrates, such as zinc nitrate, lead nitrate, iron nitrate, copper nitrate, and manganese nitrate; alkali metal nitrates, such as sodium nitrate and nitric acid rim. And nitrites of alkaline earth metals such as magnesium nitrate, calcium nitrate, barium nitrate and the like.
  • nitrites include nitrites of heavy metals, such as zinc nitrite; nitrites of metal, such as sodium nitrite, and lithium nitrite, etc .; and nitrites of earth metal, such as alkali , Magnesium nitrite, calcium nitrite and the like.
  • nitrate or nitrite When nitrate or nitrite is used, a compound containing a metal constituting a salt remains in the fabric to which a vintage color is imparted by the method of the present invention.
  • zinc nitrate when used as a nitrogen-based oxidizing agent, zinc oxide remains in the dough.
  • nitrogen-based oxidizing agents from the viewpoint of achieving a better vintage color and availability, it is preferable to use heavy metal nitrate, nitric acid, ammonium nitrate, alkali metal nitrite, and more preferably heavy metal nitrate. Use ammonium nitrate, especially zinc nitrate.
  • the nitrogen-based oxidizing agent When applying the nitrogen-based oxidizing agent to the dough, it is sufficient that the nitrogen-based oxidizing agent can be uniformly present on the dough, preferably between the yarns or fibers constituting the dough.
  • the dough may be impregnated with the aqueous solution by applying the solution to the dough, or the fabric may be impregnated with the aqueous solution by dipping the dough in the above aqueous solution and squeezing, or 3 nitrogen-based oxidation.
  • the agent may be sprayed on the fabric, but from the viewpoint of giving a better vintage color, it is preferable to employ the above-mentioned method (1) or (2).
  • the method of the above (1) is applied to the front side of the denm. Apply the above aqueous solution only to the surface It is preferable to apply. Also, by employing the method (1), a slight decrease in the dough strength can be avoided.
  • the concentration of the nitrogen-based oxidizing agent in the aqueous solution is not particularly limited as long as it can impart a vintage color to the dough, but is usually 15 g / L to 200 g / L.
  • Nitrogen oxides may be used in combination of two or more of the compounds exemplified above, as long as an excellent vintage color is achieved, and in that case, the total of their concentrations may be within the above range.
  • the temperature of the aqueous solution is not particularly limited, and may be room temperature or may be heated to promote the dissolution of the nitrogen-based oxidizing agent in water. It is preferred that
  • additives such as a penetrating agent and a thickener may be added to the nitrogen-based oxidizing agent aqueous solution.
  • the penetrant is an additive for promoting the impregnation of the aqueous solution of the nitrogen-based oxidizing agent into the dough in the case of adopting the method (1).
  • an anionic or nonionic surfactant can be used. .
  • a viscosity agent is an additive for facilitating the application of a nitrogen-based oxidizing agent aqueous solution by a doctor-type coating machine or the like in the case of adopting the above method ⁇ .
  • Thickeners and methyl starch thickeners can be used.
  • the coating amount of the aqueous solution is not particularly limited as long as capable of imparting vintage color fabric, in case of using a denim about 450 g / m 2, typically, 50 g / m 2 or more on, preferably 100 to it is a 180g / m 2. If the coating amount is too small, the applied vintage color is too light, and it is difficult to realize the effect of the present invention. If the coating amount is too large, the dyeing concentration of the indigo dye tends to decrease.
  • the drawing rate is not particularly limited as long as capable of imparting vintage color fabric, in case of using a denim about 450 g / m 2, typically 50% or more, rather preferably at 50-80% is there.
  • the squeezing rate is the ratio of the “weight of the aqueous solution impregnated into the dough immediately after squeezing” to the “weight of the dried dough before the treatment”. If the aperture ratio is too small, the applied vintage color is too light, and it is difficult to realize the effects of the present invention. Aperture rate If it is too large, the dyeing concentration with the indigo dye tends to decrease. Also, the strength of the dough tends to decrease.
  • the dough may be subjected to the next step (nitrogen oxide generation step) or may be dried. Drying may be achieved to such an extent that good transportability of the dough to the next process can be ensured.
  • It may be carried out by holding at 120 ° C for 1 to 10 minutes or by leaving it at room temperature.
  • the dough to which the nitrogen-based oxidizing agent has been applied is subjected to a process for generating nitrogen oxides (nitrogen oxide generation step).
  • the process of nitrogen oxides occurs, if NOx (eg from the nitrogen-based oxidizing agent is applied to the dough, N 2 0, N 2 0 3, N0 2, N 2 0 4, N 2 0 5, N0 3, N 2 0 6, preferably N0 2, N 2 0, a process capable of generating a particular N0 2, etc.), for example, heat treatment.
  • NOx eg from the nitrogen-based oxidizing agent
  • known heating means can be used as long as the below-mentioned treatment temperature and treatment time can be secured, and examples thereof include a roller type baking machine and a pin tenter type heat setter.
  • the treatment temperature and the treatment time are not particularly limited as long as nitrogen oxides are generated from the nitrogen-based oxidizing agent, but usually, the treatment is preferably carried out at 100 to 220 ° C for 0.5 to 2 minutes.
  • N0 2 is generated based on.
  • N 20 occurs based on
  • the processing method of the present invention denim having a relatively high dyeing concentration with an indigo dye is used, and a vintage color with a bluish black is achieved.
  • the vintage color achieved by the present invention can be arbitrarily changed from bluish to yellowish by changing the processing conditions (nitrogen-based oxidizing agent concentration, temperature and time of heat treatment, etc.). It is adjustable. In other words, the higher the nitrogen-based oxidant concentration, the closer the vintage color becomes to yellowish. The higher the heating temperature, the closer the vintage color becomes to yellowish. The longer the heating time, the closer the vintage color becomes to yellowish.
  • Known processing which may be applied to the dough, especially denim before or after the above-mentioned processing method (application step and nitrogen oxide generation step) of the present invention includes, for example, scalding, blanching, twist prevention Treatment, shrink-proof treatment, washing treatment, and the like.
  • scalding blanching
  • twist prevention Treatment shrink-proof treatment
  • washing treatment and the like.
  • the hair-burning process is a process for baking and smoothing the fluff on the surface of the dough to smooth the dough and to improve the appearance of the dough.
  • a hot plate type an electrothermal type or a gas flame type. Burn it.
  • the blanching process is a process for softening the dough. Specifically, a hot water solution of various softeners is absorbed by the dough and dried.
  • the twist prevention process is a process in which the fabric is twisted prior to washing so that the fabric is not further twisted in washing. This is because the twilled fabric immediately after weaving has the property of being twisted when washed. For example, using a known skew processing device or skew correction device.
  • Shrink-prevention treatment is a process that reduces the shrinkage due to washing by shrinking the fabric to some extent before washing. This is because the twill fabric immediately after weaving has the property of shrinking when washed.
  • a known shrink-proofing machine may be used.
  • the washing treatment is a known treatment for processing cloth, particularly denim cloth, to a desired color and texture, and includes, for example, hot water washing, enzyme washing, and stone wash. Such processing is usually done shortly before or mainly after commercialization, and mainly after commercialization. An over-die or bleach-out may be performed immediately before or immediately after the washing process.
  • Denim (AIJ23599; manufactured by Kurashiki Boseki Co., Ltd., fabric weight: 460 g / m 2 ) was subjected to shaving treatment, blanching treatment, twist preventing treatment, and shrinkproof treatment. After that, a doctor-type coating machine was applied to the denim front surface with an aqueous solution of zinc nitrate hexahydrate at a concentration of 100 g / L and methylcellulose-based adhesive at a concentration of 6 g / L at a coating amount of 160 g per square meter. After coating and drying, heat treatment was performed at 180 ° C for 2 minutes using a baking machine.
  • Denim (AIJ23599; Kurashiki Boseki Co., Ltd., dough weight: 460 g / ra 2 ) is hair-burned and treated with a continuous padder to obtain a zinc nitrate hexahydrate concentration of 150 g / L and a non-ion penetrant concentration of 3 g / L. After impregnating and drying the aqueous solution at a squeezing ratio of 60%, it was subjected to a heat treatment at 180 ° C. for 2 minutes using a baking machine.
  • the aqueous solution for application was changed to an aqueous solution of ammonium nitrate with a concentration of 130 g / L, and
  • Denim was processed in the same manner as in Example 1 except that the heat treatment was performed at 210 ° C. for 2 minutes.
  • Example 4
  • Denim was processed in the same manner as in Example 1 except that the aqueous solution for application was changed to a nitric acid aqueous solution having a concentration of 20 g / L, and heat treatment was performed at 170 ° C for 2 minutes.
  • the denim was processed in the same manner as in Example 1, except that the aqueous solution for application was changed to an aqueous solution of sodium nitrite having a concentration of 150 g / L, and the heat treatment was performed at 210 ° C. for 2 minutes. Comparative Example 1
  • the aqueous solution for application was changed to an aqueous solution of potassium permanganate with a concentration of 10 g / L, heat treatment was performed at 140 ° C for 2 minutes, denim that was heat-treated was washed with sodium acid sodium sulfite, and brush application was performed. Other than that, denim was processed in the same manner as in Example 1.
  • indigo dyed fabric (particularly denim) can be imparted with a vintage color equivalent to that of indigo dyed fabric (particularly deem) actually stored or used for a long period of time in a relatively short period of time.
  • the vintage color can be arbitrarily adjusted from bluish to yellowish by changing the processing conditions (nitrogen-based oxidizer concentration, temperature and time of heat treatment, etc.).
  • the binge color imparted by the method of the present invention is difficult to be eliminated by washing.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Abstract

La présente invention concerne un procédé permettant de traiter un tissu teint à l'indigo, ce procédé permettant de conférer en un temps relativement court une couleur vieillie qui est égale à celle des tissus teints à l'indigo ayant été réellement stockés ou utilisés pendant longtemps, et qui sont moins susceptible de décharger à la lessive. L'invention concerne également un tissu teint à l'indigo et auquel on a conféré une couleur vieillie. Ce procédé se caractérise en ce qu'on applique au tissu teint à l'indigo un oxydant azoté, puis qu'on le chauffe.
PCT/JP2002/005551 2002-03-12 2002-06-05 Procede pour traiter un tissu teint a l'indigo, et tissu teint a l'indigo traite selon le procede WO2003076712A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP02733317A EP1486607A4 (fr) 2002-03-12 2002-06-05 Procede pour traiter un tissu teint a l'indigo, et tissu teint a l'indigo traite selon le procede
AU2002306249A AU2002306249A1 (en) 2002-03-12 2002-06-05 Method of processing indigo-dyed fabric and indigo-dyed fabric processed by the method
US10/507,072 US20050223507A1 (en) 2002-03-12 2002-06-05 Method of processing indigo-dyed fabric and indigo-dyed fabric processed by the method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2002-67131 2002-03-12
JP2002067131A JP3822121B2 (ja) 2002-03-12 2002-03-12 インジゴ染色生地の加工方法および該方法によって加工されたインジゴ染色生地

Publications (1)

Publication Number Publication Date
WO2003076712A1 true WO2003076712A1 (fr) 2003-09-18

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ID=27800274

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/005551 WO2003076712A1 (fr) 2002-03-12 2002-06-05 Procede pour traiter un tissu teint a l'indigo, et tissu teint a l'indigo traite selon le procede

Country Status (5)

Country Link
US (1) US20050223507A1 (fr)
EP (1) EP1486607A4 (fr)
JP (1) JP3822121B2 (fr)
AU (1) AU2002306249A1 (fr)
WO (1) WO2003076712A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4773727B2 (ja) * 2005-01-21 2011-09-14 保土谷化学工業株式会社 染色および消臭機能の付与された布帛
WO2017097953A1 (fr) 2015-12-10 2017-06-15 Acticell Gmbh Traitement de matière textile
US10900166B2 (en) 2015-12-10 2021-01-26 Acticell Gmbh Treatment of textile material
CN107326692A (zh) * 2017-05-25 2017-11-07 无锡金双面料科技有限公司 一种防水透气型印花色织布的加工工艺
CN112888819A (zh) * 2019-05-08 2021-06-01 尚科纺织企业工业及贸易公司 改变纺织品、织物和服装的颜色的方法

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JPS5135784A (fr) * 1974-09-19 1976-03-26 Mitsubishi Gas Chemical Co
JPS5455679A (en) * 1977-10-12 1979-05-02 Daito Yakuhin Kougiyou Kk Production of cellulosic fiber product
JPH04300374A (ja) * 1991-03-26 1992-10-23 Manac Inc インジゴ被染物のカラー加工用処理剤及びカラー加工方法
JPH11200261A (ja) * 1998-01-19 1999-07-27 Kouritsu:Kk ジーンズ等綿製品の加工方法

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Publication number Priority date Publication date Assignee Title
GB998404A (en) * 1961-12-06 1965-07-14 Johnson & Johnson Treatment of cellulosic materials
CH1866172A4 (fr) * 1972-12-21 1975-10-15
US5350423A (en) * 1992-09-23 1994-09-27 Burlington Industries Inc. Fabric finishing procedure

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
JPS5135784A (fr) * 1974-09-19 1976-03-26 Mitsubishi Gas Chemical Co
JPS5455679A (en) * 1977-10-12 1979-05-02 Daito Yakuhin Kougiyou Kk Production of cellulosic fiber product
JPH04300374A (ja) * 1991-03-26 1992-10-23 Manac Inc インジゴ被染物のカラー加工用処理剤及びカラー加工方法
JPH11200261A (ja) * 1998-01-19 1999-07-27 Kouritsu:Kk ジーンズ等綿製品の加工方法

Non-Patent Citations (1)

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Title
See also references of EP1486607A4 *

Also Published As

Publication number Publication date
US20050223507A1 (en) 2005-10-13
EP1486607A1 (fr) 2004-12-15
AU2002306249A1 (en) 2003-09-22
JP2003268683A (ja) 2003-09-25
JP3822121B2 (ja) 2006-09-13
EP1486607A4 (fr) 2006-08-23

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