WO2003070783A1 - Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers - Google Patents

Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers Download PDF

Info

Publication number
WO2003070783A1
WO2003070783A1 PCT/US2003/004098 US0304098W WO03070783A1 WO 2003070783 A1 WO2003070783 A1 WO 2003070783A1 US 0304098 W US0304098 W US 0304098W WO 03070783 A1 WO03070783 A1 WO 03070783A1
Authority
WO
WIPO (PCT)
Prior art keywords
group
film
monomer
forming composition
composite coating
Prior art date
Application number
PCT/US2003/004098
Other languages
English (en)
French (fr)
Inventor
Roxalana L. Martin
Edward R. Coleridge
Mark A. Tucker
Mary E. Grolemund
Original Assignee
Ppg Industries Ohio, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/076,984 external-priority patent/US6686432B2/en
Application filed by Ppg Industries Ohio, Inc. filed Critical Ppg Industries Ohio, Inc.
Priority to CA 2476433 priority Critical patent/CA2476433C/en
Priority to KR1020047012561A priority patent/KR100586127B1/ko
Priority to DE2003615133 priority patent/DE60315133T2/de
Priority to BR0307662A priority patent/BR0307662A/pt
Priority to AU2003219738A priority patent/AU2003219738B2/en
Priority to JP2003569690A priority patent/JP2005517776A/ja
Priority to EP20030716009 priority patent/EP1474453B1/en
Publication of WO2003070783A1 publication Critical patent/WO2003070783A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00—Coating compositions based on unspecified macromolecular compounds
    • C09D201/02—Coating compositions based on unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers

Definitions

  • Such copolymers may not be made using Lewis acids and/or transition metals as catalysts, and are preferably substantially free of Lewis acids and/or transition metals, in order to overcome any drawbacks associated with the use of Lewis acids and/or transition metals in coating compositions.
  • suitable aromatic diisocyanates are 4,4'-diphenylmethane diisocyanate, and toluene diisocyanate.
  • suitable aliphatic diisocyanates are straight chain aliphatic diisocyanates, such as 1 ,6- hexamethylene diisocyanate.
  • cycloaliphatic diisocyanates can be employed. Examples include isophorone diisocyanate and 4,4'-methylene- bis-(cyclohexyl isocyanate).
  • suitable higher polyisocyanates are 1,2,4-benzene triisocyanate and polymethylene polyphenyl isocyanate.
  • the polyurethanes can be prepared with unreacted carboxylic acid groups which, upon neutralization with bases such as amines, allows for dispersion into aqueous medium.
  • Stress is described as force per unit area. Although the precise mechanism by which the MICROFLUIDIZER ® emulsifier stresses the pre-emulsification mixture to particulate is not thoroughly understood, it is theorized that stress is exerted in more than one manner. It is believed that one manner in which stress is exerted is by shear; that is, the force is such that one layer or plane moves parallel to an adjacent, parallel plane. Stress can also be exerted from all sides as a bulk, compression stress. In this instance, stress could be exerted without any shear. A further manner of producing intense stress is by cavitation. Cavitation occurs when the pressure within a liquid is reduced enough to cause vaporization.
  • the polydispersity index of the copolymer is usually less than 4, in many cases less than 3.5, typically less than 3.0, and, in some cases, less than 2.5.
  • polydispersity index is determined from the following equation: (weight average molecular weight (Mw) / number average molecular weight (Mn)).
  • Mw weight average molecular weight
  • Mn number average molecular weight
  • Mn and Mw are determined from gel permeation chromatography using polystyrene standards.
  • R 6 , R 7 , and R 9 are independently selected from the group consisting of H, CF 3 , straight or branched alkyl of 1 to 20 carbon atoms, aryl, unsaturated straight or branched alkenyl or alkynyl of 2 to 10 carbon atoms, unsaturated straight or branched alkenyl of 2 to 6 carbon atoms substituted with a halogen, C 3 -C ⁇ cycloalkyl, heterocyclyl and phenyl;
  • R 8 is selected from the group consisting of H, Ci to C ⁇ alkyl, and COOR 15 , wherein R 15 is selected from the group consisting of H, an alkali metal, a Ci to C ⁇ alkyl group, glycidyl, and aryl.
  • Dynol® 604 ethoxylated acetylenic diol available from Air Products and Chemicals, Inc.
  • Cymel® 327 Highly methylated, high imino content melamine formaldehyde resin in isobutanol available from available from Cytec Industries, Inc.
PCT/US2003/004098 2002-02-15 2003-02-12 Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers WO2003070783A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA 2476433 CA2476433C (en) 2002-02-15 2003-02-12 Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers
KR1020047012561A KR100586127B1 (ko) 2002-02-15 2003-02-12 아이소뷰틸렌 유형 단량체의 교대 공중합체를 함유하는수성 필름-형성 조성물
DE2003615133 DE60315133T2 (de) 2002-02-15 2003-02-12 Wässrige, filmbildende zusammensetzungen enthaltend alternierende copolymere des isobutylens
BR0307662A BR0307662A (pt) 2002-02-15 2003-02-12 Composição formadora de filme e composição para revestimento compósita de vários componentes
AU2003219738A AU2003219738B2 (en) 2002-02-15 2003-02-12 Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers
JP2003569690A JP2005517776A (ja) 2002-02-15 2003-02-12 イソブチレン型モノマーの交互コポリマーを含有する水系フィルム形成組成物
EP20030716009 EP1474453B1 (en) 2002-02-15 2003-02-12 Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US10/076,984 US6686432B2 (en) 2002-02-15 2002-02-15 Alternating copolymers of isobutylene type monomers
US10/076,984 2002-02-15
US10/357,797 US6787597B1 (en) 2002-02-15 2003-02-04 Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers
US10/357,797 2003-02-04

Publications (1)

Publication Number Publication Date
WO2003070783A1 true WO2003070783A1 (en) 2003-08-28

Family

ID=27759909

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/004098 WO2003070783A1 (en) 2002-02-15 2003-02-12 Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers

Country Status (10)

Country Link
US (1) US7101930B2 (US07101930-20060905-C00001.png)
EP (1) EP1474453B1 (US07101930-20060905-C00001.png)
JP (2) JP2005517776A (US07101930-20060905-C00001.png)
CN (1) CN1308358C (US07101930-20060905-C00001.png)
AU (1) AU2003219738B2 (US07101930-20060905-C00001.png)
BR (1) BR0307662A (US07101930-20060905-C00001.png)
CA (1) CA2476433C (US07101930-20060905-C00001.png)
DE (1) DE60315133T2 (US07101930-20060905-C00001.png)
ES (1) ES2290444T3 (US07101930-20060905-C00001.png)
WO (1) WO2003070783A1 (US07101930-20060905-C00001.png)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005016979A1 (en) * 2003-08-06 2005-02-24 Ppg Industries Ohio, Inc. Etherified carbamate functional copolymers of isobutylene type monomers, and their use in curable compositions
WO2005054305A2 (en) * 2003-11-26 2005-06-16 Ppg Industries Ohio, Inc. Method of making copolymers containing olefinic type monomers
WO2007057365A2 (de) * 2005-11-18 2007-05-24 Basf Se Verfahren zur herstellung einer wässrigen polymerisatdispersion
WO2011002831A1 (en) 2009-06-30 2011-01-06 Lubrizol Advanced Materials, Inc. Composite polymer emulsion
WO2021016613A1 (en) * 2019-07-25 2021-01-28 Ppg Industries Ohio, Inc. Acrylic polymers, aqueous polymeric dispersions prepared therefrom, and curable film-forming compositions prepared therefrom

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6686432B2 (en) * 2002-02-15 2004-02-03 Ppg Industries Ohio, Inc. Alternating copolymers of isobutylene type monomers
TW200508286A (en) * 2003-03-25 2005-03-01 Nippon Paint Co Ltd Method of producing oil-in-water type emulsoid containing internally crosslinked fine resin particle, oil-in-water type emulsoid containing internally crosslinked fine resin particle, cation electrodeposition coating composition and substance coated
US20070014819A1 (en) * 2005-07-13 2007-01-18 Weckteck Biotechnology Company Limited Method of emulsifying phytosterol by natural saponin,emulsion prepared thereby and water dispersible phytosterol powder product
US20080163793A1 (en) * 2006-10-13 2008-07-10 Taminco Method of inhibiting nitrosamine formation in waterborne coating
US20090023862A1 (en) * 2007-07-17 2009-01-22 Ppg Industries Ohio, Inc. Solventborne thermosetting compositions containing copolymers of isobutylene type monomers
US20100160561A1 (en) * 2008-12-24 2010-06-24 Ppg Industries Ohio, Inc. Copolymers of alpha-olefin type monomers and curable film-forming compositions containing them
KR20140084267A (ko) * 2011-10-25 2014-07-04 유니-픽셀 디스플레이스, 인코포레이티드 디스플레이 장치를 위한 가요적인 내스크랫치성 필름
JP6166526B2 (ja) * 2011-12-09 2017-07-19 株式会社日本触媒 硬化性樹脂組成物及びその用途
JP6103107B2 (ja) * 2015-04-21 2017-03-29 ダイキン工業株式会社 水性分散体、塗膜及び塗装物品
EP3181595A1 (en) * 2015-12-17 2017-06-21 Lanxess Inc. Treatment of epoxidized unsaturated isoolefin copolymers
US9932486B1 (en) * 2016-10-05 2018-04-03 Eastman Chemical Company Coalescent and non-ionic surfactant blend
MX2021012092A (es) * 2019-04-04 2022-03-17 Arkema France Copolimeros acrilicos opticos hidrofobicos de calor elevado.
US20220177622A1 (en) * 2019-04-04 2022-06-09 Trinseo Europe Gmbh Impact resistant hydrophobic high heat optical acrylic copolymers
US11891466B2 (en) 2022-03-04 2024-02-06 Trinseo Europe Gmbh Heat resistant PMMA copolymers having high temperature and high humidity environmental stability for electronic component applications

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0594071A1 (en) * 1992-10-23 1994-04-27 Basf Corporation Partially-defunctionalized aminoplast curing for polymer compositions
WO1994010212A1 (en) * 1992-10-30 1994-05-11 Ppg Industries, Inc. Aqueous aminoplast-curable film-forming compositions providing films having resistance to acid etching
US5552487A (en) * 1994-05-09 1996-09-03 Basf Corporation Method for powder coatings
WO1997030131A1 (en) * 1996-02-16 1997-08-21 Ppg Industries, Inc. Coating compositions with flow modifiers and the flow modifiers and multilayered coatings
EP0982337A2 (en) * 1998-08-28 2000-03-01 Basf Corporation Compound and coating compositions for adhesion to olefinic substrates
WO2000026308A1 (en) * 1998-10-30 2000-05-11 E.I. Du Pont De Nemours And Company Aqueous coating compositions
WO2000075791A2 (en) * 1999-06-03 2000-12-14 Ppg Industries Ohio, Inc. Block copolymers prepared by controlled radical polymerization and their use as flow modifiers

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2411599A (en) * 1940-11-09 1946-11-26 Standard Oil Dev Co Polymerization process
US2378629A (en) * 1941-09-10 1945-06-19 Du Pont Copolymers of maleic anhydride
US2531196A (en) * 1942-10-20 1950-11-21 Du Pont Vinyl polymers and process for producing the same
US3919180A (en) * 1968-07-03 1975-11-11 Bridgestone Tire Co Ltd Method of producing alternating copolymers of donor monomer and acceptor monomer from not less than three monomers
JPS4936822B1 (US07101930-20060905-C00001.png) * 1970-03-04 1974-10-03
US3984299A (en) * 1970-06-19 1976-10-05 Ppg Industries, Inc. Process for electrodepositing cationic compositions
US3947338A (en) * 1971-10-28 1976-03-30 Ppg Industries, Inc. Method of electrodepositing self-crosslinking cationic compositions
JPS515645B2 (US07101930-20060905-C00001.png) * 1971-12-02 1976-02-21
JPS49103983A (US07101930-20060905-C00001.png) * 1973-02-02 1974-10-02
US4147688A (en) * 1975-03-19 1979-04-03 Ppg Industries, Inc. Method of preparing dispersions of gelled polymeric microparticles and products produced thereby
JPS5222090A (en) * 1975-08-11 1977-02-19 Exxon Research Engineering Co Additive for labricating oil comprising functional random copolymers
US4147679A (en) * 1976-06-02 1979-04-03 Ppg Industries, Inc. Water-reduced urethane coating compositions
JPS5325666A (en) * 1976-08-23 1978-03-09 Kasei Co C I Self swelling waterstopping material production method
NZ186925A (en) * 1977-04-25 1979-12-11 Ici Ltd Top-coating based on a basecoat and top-coat compositions not requiring an intermediate baking operation
GB2073609B (en) * 1980-04-14 1984-05-02 Ici Ltd Coating process
JPS5883633A (ja) * 1981-11-13 1983-05-19 Unitika Ltd 生理活性物質固定化用担体
JPH0248024B2 (ja) * 1982-10-04 1990-10-23 Kuraray Co Kyusuiseifuirumu
JPS60245680A (ja) * 1984-05-18 1985-12-05 Kuraray Co Ltd 高度耐水性接着剤
US4681811A (en) * 1985-08-19 1987-07-21 Ppg Industries, Inc. Color plus clear coatings employing polyepoxides and polyacid curing agents in the clear coat
JPS6253365A (ja) * 1985-09-03 1987-03-09 Idemitsu Petrochem Co Ltd 共重合体組成物
US4732790A (en) * 1986-08-21 1988-03-22 Ppg Industries, Inc. Color plus clear application of thermosetting high solids coating composition of hydroxy-functional epoxies and anhydrides
US5214101A (en) * 1986-09-29 1993-05-25 Ppg Industries, Inc. Powder coating composition comprising a co-reactable particulate mixture of carboxylic acid group-containing polymers and beta-hydroxyalkylamide curing agent
US4937288A (en) * 1986-09-29 1990-06-26 Ppg Industries, Inc. Powder coating composition
DE3874836T2 (de) * 1987-07-31 1993-04-29 Nippon Oils & Fats Co Ltd Waermehaertende pulvrige beschichtungszusammensetzung.
US5229458A (en) * 1987-08-19 1993-07-20 Ppg Industries, Inc. Powder coating of particulate thermoset resin and olefin-maleic anhydride copolymer
US4798746A (en) * 1987-08-24 1989-01-17 Ppg Industries, Inc. Basecoat/clearcoat method of coating utilizing an anhydride additive in the thermoplastic polymer-containing basecoat for improved repairability
US4889890A (en) * 1987-12-30 1989-12-26 Ppg Industries, Inc. Powder coating curing system containing a beta-hydroxyalkylamide
JPH01304145A (ja) * 1988-06-02 1989-12-07 Asahi Chem Ind Co Ltd 水走り防止性遮水材
EP0365098B1 (en) * 1988-10-21 1993-12-08 Akzo Nobel N.V. Waterborne coatings and binder systems for use therein
US5084541A (en) * 1988-12-19 1992-01-28 American Cyanamid Company Triazine crosslinking agents and curable compositions
US4997900A (en) * 1988-12-27 1991-03-05 Cargill, Incorporated Powder coating comprising acetone oxime blocked diisocyanate and polyester
US5071904A (en) * 1989-05-30 1991-12-10 Ppg Industries, Inc. Waterborne coating compositions for automotive applications
US5098955A (en) * 1989-09-18 1992-03-24 Ppg Industries, Inc. Powder coating composition low Tg and high Tg polymers with acid groups
US5202382A (en) * 1989-09-18 1993-04-13 Ppg Industries, Inc. Thermosetting powder coating composition containing a mixture of low Tg and high Tg polymers with acid functional groups
JPH03131648A (ja) * 1989-10-16 1991-06-05 Kuraray Co Ltd 樹脂組成物、接着剤組成物およびガラス基材
JP3131985B2 (ja) * 1990-08-30 2001-02-05 ダイキン工業株式会社 含フッ素共重合体および該重合体を含む塗料用組成物
US5508337A (en) * 1992-02-11 1996-04-16 Bayer Aktiengesellschaft Powder coating compositions, a process for their preparation, and their use for the coating of heat resistant substrates
US5356973A (en) * 1992-08-31 1994-10-18 Ppg Industries, Inc. Aqueous based coating compositions having improved metallic pigment orientation
TW242644B (US07101930-20060905-C00001.png) * 1992-10-30 1995-03-11 Ppg Industries Inc
US5407707A (en) * 1993-11-01 1995-04-18 Ppg Industries, Inc. Powder coating composition based on epoxy containing polymers and polyacid curing agents
US5554692A (en) * 1994-01-06 1996-09-10 Ferro Corporation Blocked isocyanate crosslinkers based on pentaerythritol for use in thermosetting coatings
DE4406157A1 (de) * 1994-02-25 1995-08-31 Bayer Ag Pulverlack und seine Verwendung
EP0755420B1 (en) * 1994-04-13 1999-10-20 PPG Industries Ohio, Inc. Thermosetting powder coating compositions
US5976701A (en) * 1994-04-29 1999-11-02 Ppg Industries Ohio, Inc. Flexible aminoplast-curable film-forming compositions and composite coating
JPH08100096A (ja) * 1994-09-30 1996-04-16 Asahi Glass Co Ltd 室温硬化性組成物
US5807937A (en) * 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
US5777061A (en) * 1996-02-14 1998-07-07 Bayer Corporation Blocked polyisocyanate crosslinkers for providing improved flow properties to coating compositions
US6114489A (en) * 1997-03-27 2000-09-05 Herberts Gmbh Reactive hyperbranched polymers for powder coatings
ES2241262T3 (es) * 1998-02-18 2005-10-16 Ppg Industries Ohio, Inc. Composicion de recubrimiento compuesta de multicomponentes y sustrato recubierto.
US6306965B1 (en) * 1998-08-31 2001-10-23 Ppg Industries Ohio, Inc. Thermosetting compositions containing carbamate-functional polylmers prepared using atom transfer radical polymerization
US6319987B1 (en) * 1998-08-31 2001-11-20 Ppg Industries Ohio, Inc. Thermosetting compositions containing hydroxyl-functional polymers prepared using atom transfer radical polymerization
US6111001A (en) * 1998-11-24 2000-08-29 Ppg Industries Ohio, Inc. Compositions containing rheology modifiers with functional group-containing polymers
US6197883B1 (en) * 1999-06-03 2001-03-06 Ppg Industries Ohio, Inc. Thermosetting coating compositions containing flow modifiers prepared by controlled radical polymerization
US6875832B2 (en) 2001-04-24 2005-04-05 Ppg Industries Ohio, Inc. Synthesis of vinyl polymers by controlled radical polymerization
US6784248B2 (en) 2002-02-15 2004-08-31 Ppg Industries Ohio, Inc. Thermosetting compositions containing alternating copolymers of isobutylene type monomers

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0594071A1 (en) * 1992-10-23 1994-04-27 Basf Corporation Partially-defunctionalized aminoplast curing for polymer compositions
WO1994010212A1 (en) * 1992-10-30 1994-05-11 Ppg Industries, Inc. Aqueous aminoplast-curable film-forming compositions providing films having resistance to acid etching
US5552487A (en) * 1994-05-09 1996-09-03 Basf Corporation Method for powder coatings
WO1997030131A1 (en) * 1996-02-16 1997-08-21 Ppg Industries, Inc. Coating compositions with flow modifiers and the flow modifiers and multilayered coatings
EP0982337A2 (en) * 1998-08-28 2000-03-01 Basf Corporation Compound and coating compositions for adhesion to olefinic substrates
WO2000026308A1 (en) * 1998-10-30 2000-05-11 E.I. Du Pont De Nemours And Company Aqueous coating compositions
WO2000075791A2 (en) * 1999-06-03 2000-12-14 Ppg Industries Ohio, Inc. Block copolymers prepared by controlled radical polymerization and their use as flow modifiers

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005016979A1 (en) * 2003-08-06 2005-02-24 Ppg Industries Ohio, Inc. Etherified carbamate functional copolymers of isobutylene type monomers, and their use in curable compositions
WO2005054305A2 (en) * 2003-11-26 2005-06-16 Ppg Industries Ohio, Inc. Method of making copolymers containing olefinic type monomers
WO2005054305A3 (en) * 2003-11-26 2005-07-14 Ppg Ind Ohio Inc Method of making copolymers containing olefinic type monomers
KR100788075B1 (ko) * 2003-11-26 2007-12-21 피피지 인더스트리즈 오하이오 인코포레이티드 올레핀형 단량체를 함유하는 공중합체의 제조방법
US7323529B2 (en) 2003-11-26 2008-01-29 Pp6 Industries Ohio, Inc. Method of making copolymers containing olefinic type monomers
WO2007057365A2 (de) * 2005-11-18 2007-05-24 Basf Se Verfahren zur herstellung einer wässrigen polymerisatdispersion
WO2007057365A3 (de) * 2005-11-18 2007-11-01 Basf Ag Verfahren zur herstellung einer wässrigen polymerisatdispersion
WO2011002831A1 (en) 2009-06-30 2011-01-06 Lubrizol Advanced Materials, Inc. Composite polymer emulsion
WO2021016613A1 (en) * 2019-07-25 2021-01-28 Ppg Industries Ohio, Inc. Acrylic polymers, aqueous polymeric dispersions prepared therefrom, and curable film-forming compositions prepared therefrom
US11261265B2 (en) 2019-07-25 2022-03-01 Ppg Industries Ohio, Inc. Acrylic polymers, aqueous polymeric dispersions prepared therefrom, and curable film-forming compositions prepared therefrom

Also Published As

Publication number Publication date
JP2005517776A (ja) 2005-06-16
US7101930B2 (en) 2006-09-05
CN1308358C (zh) 2007-04-04
ES2290444T3 (es) 2008-02-16
AU2003219738B2 (en) 2005-07-14
DE60315133D1 (de) 2007-09-06
EP1474453A1 (en) 2004-11-10
BR0307662A (pt) 2005-01-04
AU2003219738A1 (en) 2003-09-09
CN1642996A (zh) 2005-07-20
CA2476433A1 (en) 2003-08-28
US20040249077A1 (en) 2004-12-09
EP1474453B1 (en) 2007-07-25
DE60315133T2 (de) 2008-04-10
JP2007297638A (ja) 2007-11-15
CA2476433C (en) 2010-06-22

Similar Documents

Publication Publication Date Title
US6787597B1 (en) Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers
EP1474453B1 (en) Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers
US6803413B2 (en) Waterborne thermosetting compositions containing alternating copolymers of isobutylene type monomers
US7722958B2 (en) Organic solvent-free film-forming compositions, multi-layer composite coatings, and related methods
AU8570098A (en) Graft copolymer emulsions and two-package waterborne urethane coatings
JP2007308714A (ja) イソブチレンのコポリマーを含有する水系組成物
JP2007533839A (ja) 実質的に有機溶媒を含まないフィルム形成組成物、多層複合塗装および関連した方法
EP1453864A1 (en) Method for obtaining coating compositions having reduced voc
US20040062871A1 (en) Method of providing cured coating films free of popping defects
US20060211813A1 (en) Phosphonic acid-modified microgel dispersion
US7163984B2 (en) Waterborne coating compositions containing monomeric difunctional compounds
WO2005016979A1 (en) Etherified carbamate functional copolymers of isobutylene type monomers, and their use in curable compositions

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 2003219738

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2003716009

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2003569690

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 1020047012561

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 2476433

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 20038057867

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2003716009

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 2003219738

Country of ref document: AU

WWG Wipo information: grant in national office

Ref document number: 2003716009

Country of ref document: EP