WO2003044339A1 - Dispositif filtrant les gaz d'echappement - Google Patents

Dispositif filtrant les gaz d'echappement Download PDF

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Publication number
WO2003044339A1
WO2003044339A1 PCT/CN2002/000836 CN0200836W WO03044339A1 WO 2003044339 A1 WO2003044339 A1 WO 2003044339A1 CN 0200836 W CN0200836 W CN 0200836W WO 03044339 A1 WO03044339 A1 WO 03044339A1
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WIPO (PCT)
Prior art keywords
cover body
filter cover
filter
end surface
exhaust gas
Prior art date
Application number
PCT/CN2002/000836
Other languages
English (en)
French (fr)
Inventor
Shusheng Li
Original Assignee
Shusheng Li
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Shusheng Li filed Critical Shusheng Li
Priority to AU2002349746A priority Critical patent/AU2002349746A1/en
Publication of WO2003044339A1 publication Critical patent/WO2003044339A1/zh

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N1/00Silencing apparatus characterised by method of silencing
    • F01N1/08Silencing apparatus characterised by method of silencing by reducing exhaust energy by throttling or whirling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/0217Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters the filtering elements having the form of hollow cylindrical bodies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/021Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
    • F01N3/033Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
    • F01N3/035Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/02Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
    • F01N3/037Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of inertial or centrifugal separators, e.g. of cyclone type, optionally combined or associated with agglomerators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2882Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2882Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices
    • F01N3/2885Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices with exhaust silencers in a single housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2370/00Selection of materials for exhaust purification
    • F01N2370/40Activated carbon or charcoal

Definitions

  • Catalytic filter device for processing exhaust gas of internal combustion engine
  • the present invention generally relates to a device for processing exhaust gas from an internal combustion engine, and more particularly to a catalytic filter device for processing exhaust gas discharged from an internal combustion engine. Background technique
  • the present invention proposes a catalytic filter device for treating exhaust gas from an internal combustion engine. Summary of the invention
  • One of the objectives of the present invention is to provide a catalytic filter device used in the process of treating the exhaust gas of an internal combustion engine, comprising: an outer casing having a first end surface and a second end surface opposite to each other; an air inlet port located at the first end of the outer casing; One end surface; an air outlet on the second end surface of the outer casing; a first filter cover body placed in the outer casing, one end of which is connected to the second end surface and the other end closed; a second filter cover body disposed in the first filter One end of the cover body is connected to the second end surface, and the other end is closed.
  • the inner cavity is in communication with the air outlet on the second end surface.
  • both the first filter cover body and the second filter cover body are screen grids.
  • the first filter cover body and the second filter cover body are filled with a particulate catalyst, and the exhaust gas can be filtered from the first filter cover body.
  • the outside of the cover body flows into the inside of the second filter cover body.
  • the inner wall of the outer casing of the catalytic filter device includes a heat insulation layer.
  • the catalyst is aluminum beads or ceramic flakes or a mixture of the two.
  • platinum, palladium, or cobalt, or a mixture thereof, and mixtures of aluminum beads or ceramic flakes with platinum, palladium, and cobalt can also be applied. In the present invention.
  • FIG. 1 is a schematic diagram of an embodiment of a catalytic filtering device according to the present invention
  • FIG. 2 is a cross-sectional view of the catalytic filter device shown in FIG. 1; a detailed description of a preferred embodiment of the present invention
  • the catalytic filter device 100 includes: an outer casing 1000 having a first end surface 10 and a second end surface 20.
  • the first end surface 10 has an air inlet 11 through which exhaust gas from the internal combustion engine enters the catalytic filter device 100.
  • One end of the catalytic filter device 106 disposed in the outer casing 1000 is fixed on the second end surface 20, and the other end is a closed end 1061.
  • the closed end 1061 is spaced apart from the air inlet 11 by a certain distance, preferably the distance is as small as possible, so that the exhaust gas can enter the catalytic filter device 106 as soon as possible after entering the catalytic filter device.
  • the catalytic filter device 106 includes a first filter cover body 1064, and a second filter cover body 1065 is fixed in the first filter cover body 1064.
  • the first filter cover body 1064 and the second filter cover body 1065 are made of aluminum and ferromagnetic materials, respectively, and can be formed into various shapes including a cylindrical shape, and are preferably formed into a cylindrical shape.
  • the inner cavity of the second filter housing is in communication with the air outlet 21 on the second end surface 20.
  • the first filter cover body 1064 and the second filter cover body 1065 share the same closed end 1061.
  • a catalyst 1062 is filled between the first filter case and the second filter case.
  • the catalyst is aluminum beads or ceramic flakes or a mixture of both.
  • a thermal insulation layer 108 is provided in the outer casing 1000 to ensure that the catalytic reaction in the catalytic filtering device of the present invention can be performed at a higher temperature. This can be achieved by filling the outer casing 1000 with a heat insulating material such as clay and asbestos or a mixture thereof.
  • the inner wall of the outer housing 1000 and the second end surface 10 between the first end face 20 may be A1 2 0 3 layer 109. Such that the initial portion of the tail catalytic reaction at the A1 2 0 3 layer effect.
  • the exhaust gas flows through the first filter cover body 1064, performs the catalytic reaction under the action of the catalyst 1062, passes through the second filter cover body 1065, enters the inside of the second filter cover body, and is then discharged from the air outlet 21.
  • the first and second filter hoods eliminate any solid particles present in the exhaust. '

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Processes For Solid Components From Exhaust (AREA)
  • Exhaust Silencers (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Description

处理内燃机尾气的催化过滤装置 技术领域
本发明一般涉及处理内燃机尾气的装置, 特别是用于处理从内燃机排出的 尾气的催化过滤装置。 背景技术
内燃机已被广泛用于各种不同的交通工具。从内燃机排出的尾气含有 CO, C02, HC和 NOx, 这些气体是导致大气污染和地球温室效应的主要因素之一。
现有技术中, 处理尾气的方法主要集中于以下两种方式。 其一为贵金属催 化转化。 这种方法需要使用贵金属如 Pt、 Pd含量较高的催化剂, 从而导致较高 的成本。 此外, 即使是最不易被氧化的贵金属 Pt, 在尾气中含有的 NOx和氧 存在的情况下, 也会被慢慢氧化, 从而使催化剂失去活性。 另一处理尾气的方 法为采用过滤装置进行过滤。 现有的过滤装置通常艮难处理有机可溶性杂质。 此外, 现有的过滤装置很难阻止尾气在约 500Ό的温度下产生硫酸盐和在更低 的温度下吸附 HC。 因此, 需要为过滤装置设置再生处理装置。
本发明为解决现有技术的缺陷, 提出了一种用于处理内燃机尾气的催化过 滤装置。 本发明概述
本发明的目的之一是提供一种在处理内燃机尾气的过程中使用的催化过 滤装置, 包括: 外壳体, 具有相对而设的第一端面和第二端面;进气口, 位于外 壳体的第一端面上; 出气口, 位于外壳体的第二端面上;第一过滤罩体, 置于外 壳体内, 其一端与第二端面连接, 另一端封闭;第二过滤罩体, 置于第一过滤罩 体内, 其一端与第二端面连接, 另一端封闭, 其内腔与第二端面上的出气口连 通。 在本发明中, 第一过滤罩体和第二过滤罩体都为滤网栅结^, 第一过滤罩 体和第二过滤罩体之间填充有颗粒催化剂 , 尾气可从所述第一过滤罩体的外部 流入到所述第二过滤罩体的内部。
在本发明的一优选实施方案中, 催化过滤装置的外壳体内壁包括一保温 层。 在另一实施方案中, 催化剂为铝珠或陶瓷片或两者的混合物, 当然铂、钯、 或钴、 或其混合物, 以及铝珠或陶瓷片与铂、 钯、 钴的混合物也可应用于本发 明中。
本发明的催化过滤装置结构筒单, 催化剂原料成本低, 但可以达到很好的 处理内燃机尾气的效果。 附图筒要说明 - 图 1是根据本发明的催化过滤装置一实施例的示意图;
图 2是图 1所示的催化过滤装置的剖视图; 本发明优选实施例的详细说明
下面结合附图对本发明进行详细说明。
图 1和图 2显示了本发明一实施例的用于处理来自内燃机的尾气的催化过 滤装置 100。 该催化过滤装置 100包括: 外壳体 1000, 具有第一端面 10和第二 端面 20。第一端面 10具有进气口 11 ,来自内燃机的尾气通过该进气口 11进入 催化过滤装置 100。 设置在外壳体 1000内的催化过滤装置 106, 一端固定在 第二端面 20上, 另一端为封闭端 1061。 封闭端 1061与进气口 11间隔一定的 距离, 优选该距离尽可能地小, 使得尾气进入催化过滤装置后能够尽快进入催 化过滤装置 106。
催化过滤装置 106包括第一过滤罩体 1064, 在第一过滤罩体 1064内固定 有第二过滤罩体 1065。第一过滤罩体 1064和第二过滤罩体 1065分别由铝和铁 磁材料制成, 可以形成为包括圆柱体形状在内的多种形状, 并优选形成为圆柱 体形状。 第二过滤罩体的内腔与第二端面 20上的出气口 21连通。 第一过滤罩 体 1064和第二过滤罩体 1065共用相同的封闭端 1061。在第一过滤罩体与第二 过滤罩体之间填充有催化剂 1062。 催化剂为铝珠或陶瓷片或两者的混合物。
另外, 在本发明的优选实施例中, 在外壳体 1000中设置有保温层 108, 以 保证本发明催化过滤装置内的催化反应能够在较高的温度下进行。 这可以通过 在外壳体 1000内充填绝热材料如粘土和石棉或其混合物来实现。
外壳体 1000在第一端面 10和第二端面 20之间的内壁可以是 A1203层 109。 使得部分尾气在该 A1203层的作用下进行初步催化反应。
因此, 尾气流经第一过滤罩体 1064, 在催化剂 1062的作用下进行催化反 应后经第二过滤罩体 1065, 进入笫二过滤罩体的内部, 然后从出气口 21排出。 这样尾气中具有较高分子量的一些物质可以被进一步分解。 第一和第二过滤罩 体可以消除在尾气中存在的任何固体颗粒。 '
本领域的技术人员应当理解, 上述实施例和说明只是对本发明的举例说 明。 在本发明的精神和实质范围内的各种修改和变形都应属于本发明的范围。

Claims

权 利 要 求 书
1. 一种处理内燃机尾气的催化过滤装置, 包括:
外壳体, 包括相对而设的第一端面和第二端面;
进气口, 位于所述外壳体的所述第一端面上;
出气口, 位于所述外壳体的所述第二端面上;
第一过滤罩体, 置于所述外壳体内, 其一端与所述第二端面连接, 另一端 封闭;
第二过滤罩体, 置于所述第一过滤罩体内, 其一端与所述第二端面连接, 另一端封闭, 其内腔与所述第二端面上的出气口连通;
其中, 所述的第一过滤罩体和第二过滤罩体都为金属滤网栅结构, 第一过 滤罩体和第二过滤罩体之间填充有催化剂, 废气可从所述第一过滤罩体的外部 流入到所述第二过滤罩体的内腔。
2. 根据权利要求 1的催化过滤装置, 其中所述外壳体包括一保温层。
3. 根据权利要求 2的催化过滤装置,其中所述外壳体内壁包括一三氧化铝 层。
4. 根据权利要求 2的催化过滤装置,其中所述第二过滤罩体与第一过滤罩 体共有一封闭端。
5.根据权利要求 3的催化过滤装置, 其中所述第二过滤罩体与第一过滤罩 体共有一封闭端。
6. 根据权利要求 1所述的催化过滤装置,其中所述颗粒催化剂为铝珠或陶 瓷片或两者的混合物。
7. 根据权利要求 2的催化过滤装置,其中所述颗粒催化剂为铝珠或陶瓷片 或两者的混合物。
8. 根据权利要求 3的催化过滤装置,其中所述颗粒催化剂为铝珠或陶瓷片 或两者的混合物。
9. 根据权利要求 4的催化过滤装置,其中所述颗粒催化剂为铝珠或陶瓷片 或两者的混合物。
10.根据权利要求 5的催化过滤装置, 其中所述颗粒催化剂为铝珠或陶瓷 片或两者的混合物。
PCT/CN2002/000836 2001-11-22 2002-11-22 Dispositif filtrant les gaz d'echappement WO2003044339A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002349746A AU2002349746A1 (en) 2001-11-22 2002-11-22 An exhaust gas filter device

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN01129977.0 2001-11-22
CNB011299770A CN1171007C (zh) 2001-11-22 2001-11-22 内燃机高功率输出、尾气低温排放净化系统

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WO2003044339A1 true WO2003044339A1 (fr) 2003-05-30

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PCT/CN2002/000837 WO2003044341A1 (fr) 2001-11-22 2002-11-22 Procede pour ameliorer le rendement d'un moteur par traitement des gaz d'echappement et dispositif d'application du procede
PCT/CN2002/000838 WO2003044340A1 (fr) 2001-11-22 2002-11-22 Dispositif de tourbillonnement et systeme de traitement des gaz d'echappement d'un moteur a combustion interne
PCT/CN2002/000834 WO2003044337A1 (fr) 2001-11-22 2002-11-22 Dispositif d'absorption utilise pour le traitement des gaz d'echappement d'un moteur
PCT/CN2002/000836 WO2003044339A1 (fr) 2001-11-22 2002-11-22 Dispositif filtrant les gaz d'echappement
PCT/CN2002/000835 WO2003044336A1 (fr) 2001-11-22 2002-11-22 Dispositif de refroidissement et d'insonorisation pour le traitement des gaz d'echappement d'un moteur a combustion interne

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PCT/CN2002/000837 WO2003044341A1 (fr) 2001-11-22 2002-11-22 Procede pour ameliorer le rendement d'un moteur par traitement des gaz d'echappement et dispositif d'application du procede
PCT/CN2002/000838 WO2003044340A1 (fr) 2001-11-22 2002-11-22 Dispositif de tourbillonnement et systeme de traitement des gaz d'echappement d'un moteur a combustion interne
PCT/CN2002/000834 WO2003044337A1 (fr) 2001-11-22 2002-11-22 Dispositif d'absorption utilise pour le traitement des gaz d'echappement d'un moteur

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PCT/CN2002/000835 WO2003044336A1 (fr) 2001-11-22 2002-11-22 Dispositif de refroidissement et d'insonorisation pour le traitement des gaz d'echappement d'un moteur a combustion interne

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US6725654B2 (en) 2004-04-27
WO2003044336A1 (fr) 2003-05-30
CN1171007C (zh) 2004-10-13
CN1360139A (zh) 2002-07-24
WO2003044340A1 (fr) 2003-05-30
AU2002349744A1 (en) 2003-06-10
WO2003044341A1 (fr) 2003-05-30
WO2003044337A1 (fr) 2003-05-30
AU2002349747A1 (en) 2003-06-10

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