WO2003004546A1 - Modifizierte nachkondensierte polyester - Google Patents
Modifizierte nachkondensierte polyester Download PDFInfo
- Publication number
- WO2003004546A1 WO2003004546A1 PCT/CH2002/000177 CH0200177W WO03004546A1 WO 2003004546 A1 WO2003004546 A1 WO 2003004546A1 CH 0200177 W CH0200177 W CH 0200177W WO 03004546 A1 WO03004546 A1 WO 03004546A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polyester
- hbp
- condensation
- mixture
- groups
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/005—Dendritic macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Definitions
- the invention relates to a process for the production of a modified polyester with improved rheological and mechanical properties according to claim 1, to a product produced by the process according to the invention with improved mechanical properties according to claim 18 and to an additive package which can be used for the production of such a modified polyester Claim 20.
- polyester It is known to process polyester together with reactive additives to improve the rheological and mechanical properties. If this processing takes place in the melt, for example in an extruder, the polyester is also subjected to various degradation reactions which limit the achievement of a high molecular weight or even counteract it at the same time as the build-up reaction with the reactive additive.
- an inhomogeneous mixture of highly crosslinked particles or gels can be formed in an otherwise low molecular weight matrix.
- the object of the invention is therefore to provide a method in which a large number of polyester chains are linked to form macromolecules with a high degree of branching and a very high molecular weight, but without producing a significant amount of crosslinking.
- HBP hyperbranched polymer
- both the degree of branching and the degree of crosslinking of the macromolecules can be influenced in a targeted manner.
- more branching of the individual separate molecules and at the same time less crosslinking of the molecules can achieve high melt strength with low brittleness (high breaking strength) of the solidified melt (end product).
- a polyester in particular a thermoplastic polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate or polycarbonate is used. Both virgin material and recycled material, in particular in the form of recycled PET bottle chips, can be used.
- the polyester material can be present as a homopolymer or as a copolymer, the molecular weight of the polyester, measured as intrinsic viscosity IV, being between 0.2 and 1.0, typically between 0.6 and 0.85 dl / g.
- Recycled material comprises material that is produced as consumer recyclate as well as industrial recyclate from products such as bottles, foils or fibers and is either processed directly or sorted, washed and shredded beforehand.
- hyperbranched polymer HBP
- hyperbranched dendritic macromolecules hyperbranched dendritic macromolecules
- three-dimensional, highly branched molecules with a structural branching structure are generally referred to. These include the highly symmetrical dendrimers, as well as similar structures with a higher degree of asymmetry.
- Hyperbranched dendritic macromolecules consist of a core with one or more reactive sites or functional groups and a number of branching layers consisting of one or more branched chain extenders with at least three reactive sites or functional groups, and optionally one or more spacer layers and / or a layer terminating chain Molecules or functional groups, wherein at least one reactive site or functional group can react with a reactive site of the polymer into which the HBP is to be incorporated and can lead to a connection.
- Preferred functional groups for the reaction with polyester are, for example, hydroxyl, epoxy, anhydride or carboxyl groups.
- the HBP can be added alone or as part of an additive package. Additives from the group of impact modifiers, nucleating agents, catalysts, dyes and pigments, stabilizers, compatibilizers, molecular weight-increasing or elasticity-increasing additives, reinforcing fibers or fillers are also used to produce the additive package.
- a carrier material can be used, in which all additives can be incorporated.
- the additive package can be present both as a homogeneous powder or granulate and as a simple additive mixture.
- the mixing and melting of the polyester with the HBP can be carried out in an extruder, kneader or other suitable apparatus, such as, for example, a melt polymerization reactor as used in the production of polyester.
- a melt polymerization reactor as used in the production of polyester.
- Both single-screw and twin-screw extruders as well as multi-screw extruders such as a ring extruder or planetary extruder are suitable as extruders.
- the polyester and the HBP can be introduced into the mixing apparatus both simultaneously and in succession.
- the HBP can be added as a solid to the polyester in the solid as well as in the molten state. It is also possible to melt the polyester and the HBP in separate machines and only then mix them.
- the HBP can react with the polyester during melting and mixing.
- the process should be carried out in such a way, in particular by controlling the residence time and the temperature, that not all free reactive end groups react with the polyester.
- To process the polyester it is advisable to remove water from the polyester and possibly also the HBP. This takes place according to known drying processes either in a separate dryer or in an extruder, as long as the materials are still in the solid state or also by degassing the melt.
- Further process steps can follow the melting process, such as melt degassing, melt filtration, mixing in and homogenizing further additives or building up pressure to shape and convey the material.
- the molten material is returned to the solid form by cooling in contact with a suitable cooling medium, such as air, water or a cooled surface.
- a suitable cooling medium such as air, water or a cooled surface.
- the material is preferably first pressed through a shaping nozzle or into a mold.
- a common method is granulation, for example by strand granulation or head granulation. However, films or other shaped pieces can also be used, if appropriate after comminution.
- Solid-phase post-condensation and crystallization During the solid-phase post-condensation step, some or all of the still free reactive end groups of the HBP react with the polyester. At the same time, the molecules of the polyester react with each other. Both lead to an increase in the molecular weight, depending on the amount of HBP and completeness of the reaction, a branched or crosslinked modified polyester is formed. In many cases, crosslinking is not desirable (brittleness), and the HBP concentration and process conditions are chosen so that a branched, modified polyester is formed.
- the solid phase post-condensation can be carried out either continuously or as a batch process under vacuum or in a gas stream, such as, for example, air, nitrogen, water vapor or carbon dioxide.
- a step of crystallization Before the step of solid phase post-condensation, a step of crystallization usually has to be carried out. This crystallization step can take place as part of the cooling or granulation process or also within the post-condensation reactor. However, the crystallization step can also be carried out in a separate process step. consequences. Reactors with mechanical stirrers in which the product is heated or apparatuses in which the product is heated and agitated by a gas stream, such as, for example, in a fluidized bed, fluidized bed or fluidized bed apparatus, are typically used. Crystallization can take place in one or more steps.
- the solid phase post-condensation can be followed by a further step for cooling or further processing. Cooling can take place as part of the post-condensation process or in a separate process step.
- a polyester granulate (Eastman, 9921 W) was ground and dried in vacuo at 105 ° C. for 12 hours.
- the material was extruded in a rotating twin-screw extruder (Prism TSE 16) at 220 ° C in the feed area, 265 ° C melting and conveying area and 240 ° C at the die and then pelletized.
- the solution viscosity (IV) in phenol / dichlorobenzene and the elongation viscosity at 270 ° C. using a capillary rheometer with a pull-off device were measured and the tensile stress at the respective degrees of stretching was determined therefrom.
- the tensile stress is calculated according to: F * (Vf -Vo) / Ad / Vo
- Ad nozzle area
- Example 3 2 kg of the extruded polyester granulate from Example 1 was then crystallized for 20 minutes at 175 ° C. in air in a fluid bed reactor. 0.5kg of this was post-condensed in a nitrogen stream at 210 ° C. for 7 hours and then rapidly cooled. Again succeeded . a determination of the tensile stress at given degrees of stretch and the IV.
- Example 3 2 kg of the extruded polyester granulate from Example 1 was then crystallized for 20 minutes at 175 ° C. in air in a fluid bed reactor. 0.5kg of this was post-condensed in a nitrogen stream at 210 ° C. for 7 hours and then rapidly cooled. Again succeeded . a determination of the tensile stress at given degrees of stretch and the IV.
- Example 3 2 kg of the extruded polyester granulate from Example 1 was then crystallized for 20 minutes at 175 ° C. in air in a fluid bed reactor. 0.5kg of this was post-condensed in a nitrogen stream at
- HBP Perstorp, Bolteron H20, a two-layer dendritic polymer with theoretically 16 primary hydroxyl groups and a molecular weight of 1747 g / mol
- Extruded product from Example 3 was processed and measured analogously to the conditions from Example 2, but the post-condensation was carried out at 210 ° C. for 5 hours.
- Example 3 was repeated with 0.1% of the HBP.
- Extruded product from Example 5 was processed and measured analogously to the conditions from Example 2, but the post-condensation was carried out at 210 ° C. for 4 hours.
- Example 3 was repeated, however, with 0.04% of an HBP (Perstorp, Bolteron H40, a four-layer dendritic polymer with theoretically 64 primary hydroxyl groups and a molecular weight of 73.16 g / mol).
- HBP Perstorp, Bolteron H40, a four-layer dendritic polymer with theoretically 64 primary hydroxyl groups and a molecular weight of 73.16 g / mol
- Extruded product from Example 7 was processed and measured analogously to the conditions from Example 2, but the post-condensation was carried out at 210 ° C. for 6 hours.
- Example 7 was repeated, however, with 0.1% of the HBP.
- Example 10 is repeated, however, with 0.1% of the HBP.
- Extruded product from Example 9 was processed and measured analogously to the conditions from Example 2, but the post-condensation was carried out at 210 ° C. for 5 hours.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02704541A EP1401911B1 (de) | 2001-07-03 | 2002-03-26 | Modifizierte nachkondensierte polyester |
MXPA03011762A MXPA03011762A (es) | 2001-07-03 | 2002-03-26 | Poliester modificado postcondensado. |
DE50205208T DE50205208D1 (de) | 2001-07-03 | 2002-03-26 | Modifizierte nachkondensierte polyester |
AT02704541T ATE312129T1 (de) | 2001-07-03 | 2002-03-26 | Modifizierte nachkondensierte polyester |
PL02367629A PL367629A1 (en) | 2001-07-03 | 2002-03-26 | Modified postcondensed polyester |
US10/748,203 US20040192857A1 (en) | 2001-07-03 | 2003-12-31 | Modified post-condensed polyesters |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10132928A DE10132928A1 (de) | 2001-07-03 | 2001-07-03 | Modifizierte nachkondensierte Polyester |
DE10132928.8 | 2001-07-03 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/748,203 Continuation US20040192857A1 (en) | 2001-07-03 | 2003-12-31 | Modified post-condensed polyesters |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003004546A1 true WO2003004546A1 (de) | 2003-01-16 |
Family
ID=7690921
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CH2002/000177 WO2003004546A1 (de) | 2001-07-03 | 2002-03-26 | Modifizierte nachkondensierte polyester |
Country Status (9)
Country | Link |
---|---|
US (1) | US20040192857A1 (es) |
EP (1) | EP1401911B1 (es) |
CN (1) | CN1522269A (es) |
AT (1) | ATE312129T1 (es) |
DE (2) | DE10132928A1 (es) |
ES (1) | ES2253513T3 (es) |
MX (1) | MXPA03011762A (es) |
PL (1) | PL367629A1 (es) |
WO (1) | WO2003004546A1 (es) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1424360A1 (de) * | 2002-11-26 | 2004-06-02 | Bayer Aktiengesellschaft | Hochfliessfähige Polymerzusammensetzungen mit verzweigten Fliesshilfsmitteln |
WO2004111126A1 (en) * | 2003-06-11 | 2004-12-23 | Bp Corporation North America Inc. | Crystallizable thermoplastic resins and dendrimers with improved fabrication characteristics |
WO2005075563A1 (de) * | 2004-02-04 | 2005-08-18 | Basf Aktiengesellschaft | FLIEßFÄHIGE POLYESTERFORMMASSEN |
WO2005075565A1 (de) * | 2004-02-04 | 2005-08-18 | Basf Aktiengesellschaft | Fliessfähige polyesterformmassen |
WO2006008130A1 (de) * | 2004-07-21 | 2006-01-26 | Basf Aktiengesellschaft | Kontinuierliches verfahren zur herstellung von polyalkylenarylaten mit hyperverzweigten polyestern und/oder polycarbonaten |
WO2011014751A1 (en) | 2009-07-30 | 2011-02-03 | E. I. Du Pont De Nemours And Company | Overmolded heat resistant polyamide composite structures and processes for their preparation |
WO2011014754A1 (en) | 2009-07-30 | 2011-02-03 | E. I. Du Pont De Nemours And Company | Heat resistant polyamide composite structures and processes for their preparation |
WO2011014770A2 (en) | 2009-07-30 | 2011-02-03 | E. I. Du Pont De Nemours And Company | Heat resistant semi-aromatic polyamide composite structures and processes for their preparation |
WO2011155947A1 (en) | 2010-06-11 | 2011-12-15 | E. I. Du Pont De Nemours And Company | Creep-resistant composite structures and processes for their preparation |
WO2011159377A1 (en) | 2010-06-14 | 2011-12-22 | E. I. Du Pont De Nemours And Company | Long-term outdoor exposure resistant polyester composite structures and processes for their preparation |
WO2011159382A1 (en) | 2010-06-14 | 2011-12-22 | E. I. Du Pont De Nemours And Company | Long-term outdoor exposure resistant overmolded polyester composite structures and processes for their preparation |
WO2012021435A1 (en) | 2010-08-10 | 2012-02-16 | E. I. Du Pont De Nemours And Company | Polyamide composite structures and processes for their preparation |
US8334046B2 (en) | 2009-05-12 | 2012-12-18 | E I Du Pont De Nemours And Company | Overmolded polyamide composite structures and processes for their preparation |
US8362122B2 (en) | 2005-02-01 | 2013-01-29 | Basf Se | Flowable polyesters with carbodiimide stabilizers |
WO2013045965A1 (en) | 2011-09-28 | 2013-04-04 | Italmatch Chemicals S.P.A. | Halogen-free flame retardant polyesters composition |
US9597861B2 (en) | 2010-10-29 | 2017-03-21 | E I Du Pont De Nemours And Company | Composite structures having improved heat aging and interlayer bond strength |
EP2513190A4 (en) * | 2009-12-17 | 2017-08-23 | E. I. du Pont de Nemours and Company | Polyester compositions with good melt rheological properties |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1367080A1 (en) * | 2002-05-29 | 2003-12-03 | Hycail B.V. | Hyperbranched poly(hydroxycarboxylic acid) polymers |
US8489442B1 (en) | 2004-02-02 | 2013-07-16 | Avaya Inc. | Interface for meeting facilitation and coordination, method and apparatus |
MY139705A (en) * | 2004-07-19 | 2009-10-30 | Basf Ag | Mixtures of hyperbranched polyesters with polycarbonates as additive for polyester molding compositions |
DE102004059243A1 (de) * | 2004-08-10 | 2006-02-23 | Basf Ag | Thermoplastische Formmassen mit verbesserten Fließ- und Entformungseigenschaften |
DE102004038976A1 (de) | 2004-08-10 | 2006-02-23 | Basf Ag | Fließfähige Polyesterformmassen mit ASA/ABS und SAN |
DE102004038979A1 (de) | 2004-08-10 | 2006-02-23 | Basf Ag | Schlagzähmodifizierte Polyester mit hyperverzweigten Polyestern |
DE102004049342A1 (de) | 2004-10-08 | 2006-04-13 | Basf Ag | Fließfähige Thermoplaste mit halogenfreiem Flammschutz |
DE102004050025A1 (de) | 2004-10-13 | 2006-04-20 | Basf Ag | Fließfähige Thermoplaste mit Halogenflammschutz |
DE102004051241A1 (de) * | 2004-10-20 | 2006-05-04 | Basf Ag | Fließfähige Polyamide mit hyperverzweigten Polyestern/Polycarbonaten |
DE102005002044A1 (de) | 2005-01-14 | 2006-07-20 | Basf Ag | Fließfähige Polyester mit Hydrolyseschutz |
US7471647B2 (en) * | 2005-04-29 | 2008-12-30 | Alcatel Lucent | Bridged network spanning tree abnormality detection |
DE102005027549A1 (de) | 2005-06-14 | 2006-12-21 | Basf Ag | Mehrkomponentenformkörper mit Polyesterschichten |
US20090286927A1 (en) * | 2005-06-27 | 2009-11-19 | Niels Dan Anders Sodergard | Hyperbranched Polymers |
DE102005032585A1 (de) * | 2005-07-11 | 2007-01-25 | Basf Ag | Verfahren zur Herstellung von Leder |
DE102005034999A1 (de) * | 2005-07-22 | 2007-01-25 | Basf Ag | Fließfähige Polyester mit Polyesterelastomeren |
DE102005034980A1 (de) * | 2005-07-22 | 2007-01-25 | Basf Ag | Fasern und Flüssigkeitsbehälter aus PET |
US7984378B1 (en) | 2006-02-07 | 2011-07-19 | Avaya Inc. | Management of meetings by grouping |
US8600794B2 (en) * | 2006-05-10 | 2013-12-03 | Avaya Inc. | Meeting notification and merging agents |
US7778858B1 (en) | 2006-07-17 | 2010-08-17 | Avaya Inc. | Linking unable to respond messages to entries in electronic calendar |
US10445703B1 (en) | 2006-10-30 | 2019-10-15 | Avaya Inc. | Early enough reminders |
US8037143B1 (en) | 2006-10-30 | 2011-10-11 | Avaya Inc. | Automatic display of email distribution lists |
US7827240B1 (en) | 2007-01-02 | 2010-11-02 | Avaya Inc. | Calendar item hierarchy for automatic specialization |
JP2011502843A (ja) | 2007-11-20 | 2011-01-27 | ビーエーエスエフ ソシエタス・ヨーロピア | Gid/witのための熱可塑性成形材料の使用 |
CN104479309B (zh) * | 2015-01-17 | 2017-10-27 | 上海青品新材料科技有限公司 | 改性聚酯组合物以及由其制得的材料 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5480944A (en) * | 1993-08-23 | 1996-01-02 | Alliedsignal Inc. | Interpenetrating blends of linear polymers and compatible fractal polymers |
WO1997045474A1 (en) * | 1996-05-28 | 1997-12-04 | Perstorp Ab | A thermoplastic compound |
EP0819716A2 (en) * | 1996-07-18 | 1998-01-21 | SINCO ENGINEERING S.p.A. | Improved process for the production of polyester resins |
US5998565A (en) * | 1995-11-28 | 1999-12-07 | Dsm N.V. | Composition comprising a plastic and an additive |
US6099778A (en) * | 1996-10-28 | 2000-08-08 | Eastman Chemical Company | Process for producing pet articles with low acetaldehyde |
DE19905877A1 (de) * | 1999-02-12 | 2000-08-17 | Daimler Chrysler Ag | Hochfestes Polymerharz |
WO2001074946A1 (en) * | 2000-03-30 | 2001-10-11 | General Electric Company | Use of dendrimers as a processing aid and surface modifier for thermoplastic resins |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3405098A (en) * | 1965-10-29 | 1968-10-08 | Du Pont | Process for preparing high viscosity linear condensation polyesters from partially polymerized glycol terephthalates |
DE2559290B2 (de) * | 1975-12-31 | 1979-08-02 | Davy International Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen Herstellung von hochmolekularem PoIyäthylenterephthalat |
US4238593B1 (en) * | 1979-06-12 | 1994-03-22 | Goodyear Tire & Rubber | Method for production of a high molecular weight polyester prepared from a prepolymer polyester having an optional carboxyl content |
US4408022A (en) * | 1981-12-15 | 1983-10-04 | Celanese Corporation | Blend of polyalkylene terephthalate and wholly aromatic polyester and process for producing the same |
US5362843A (en) * | 1993-09-22 | 1994-11-08 | Hoechst Celanese Corporation | Process for preparing highly branched macromolecule polymers |
US6414084B1 (en) * | 2000-04-13 | 2002-07-02 | General Electric Company | High flow polyphenylene ether formulations with dendritic polymers |
US20020068796A1 (en) * | 2000-08-03 | 2002-06-06 | Frank Uwe Ernst | Pneumatic tire having a rubber component containing a dendrimer |
US6319576B1 (en) * | 2000-11-20 | 2001-11-20 | The Coca-Cola Company | Method to increase the crystallization rate of polyesters |
DK1387862T3 (en) * | 2001-05-17 | 2015-01-19 | Basf Se | Polymer WITH IMPROVED permanence AND OVERFLADEAFFINITET |
US20040260035A1 (en) * | 2003-06-11 | 2004-12-23 | Issam Dairanieh | Crystallizable thermoplastic resins and dendrimers with improved fabrication characteristics |
-
2001
- 2001-07-03 DE DE10132928A patent/DE10132928A1/de not_active Withdrawn
-
2002
- 2002-03-26 MX MXPA03011762A patent/MXPA03011762A/es unknown
- 2002-03-26 PL PL02367629A patent/PL367629A1/xx not_active Application Discontinuation
- 2002-03-26 ES ES02704541T patent/ES2253513T3/es not_active Expired - Lifetime
- 2002-03-26 WO PCT/CH2002/000177 patent/WO2003004546A1/de not_active Application Discontinuation
- 2002-03-26 CN CNA028134621A patent/CN1522269A/zh active Pending
- 2002-03-26 DE DE50205208T patent/DE50205208D1/de not_active Expired - Lifetime
- 2002-03-26 AT AT02704541T patent/ATE312129T1/de not_active IP Right Cessation
- 2002-03-26 EP EP02704541A patent/EP1401911B1/de not_active Expired - Lifetime
-
2003
- 2003-12-31 US US10/748,203 patent/US20040192857A1/en not_active Abandoned
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5480944A (en) * | 1993-08-23 | 1996-01-02 | Alliedsignal Inc. | Interpenetrating blends of linear polymers and compatible fractal polymers |
US5998565A (en) * | 1995-11-28 | 1999-12-07 | Dsm N.V. | Composition comprising a plastic and an additive |
WO1997045474A1 (en) * | 1996-05-28 | 1997-12-04 | Perstorp Ab | A thermoplastic compound |
EP0819716A2 (en) * | 1996-07-18 | 1998-01-21 | SINCO ENGINEERING S.p.A. | Improved process for the production of polyester resins |
US6099778A (en) * | 1996-10-28 | 2000-08-08 | Eastman Chemical Company | Process for producing pet articles with low acetaldehyde |
DE19905877A1 (de) * | 1999-02-12 | 2000-08-17 | Daimler Chrysler Ag | Hochfestes Polymerharz |
WO2001074946A1 (en) * | 2000-03-30 | 2001-10-11 | General Electric Company | Use of dendrimers as a processing aid and surface modifier for thermoplastic resins |
Non-Patent Citations (3)
Title |
---|
CARR P L ET AL: "Dielectric and mechanical characterization of aryl ester dendrimer/PET blends", POLYMER, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 37, no. 12, 1996, pages 2395 - 2401, XP004069150, ISSN: 0032-3861 * |
JANG J. & AL.: "Crystallization behavior of poly(ethyleneterephthalate) blended with hyperbranched polymers: the effect of terminal groups and composition of hyperbranched polymers", MACROMOLECULES, vol. 33, no. 5, 2000, pages 1864 - 1870, XP001079109 * |
MULKERN T J ET AL: "Processing and characterization of reactive polystyrene/hyperbranched polyester blends", POLYMER, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 41, no. 9, April 2000 (2000-04-01), pages 3193 - 3203, XP004184965, ISSN: 0032-3861 * |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1424360A1 (de) * | 2002-11-26 | 2004-06-02 | Bayer Aktiengesellschaft | Hochfliessfähige Polymerzusammensetzungen mit verzweigten Fliesshilfsmitteln |
WO2004111126A1 (en) * | 2003-06-11 | 2004-12-23 | Bp Corporation North America Inc. | Crystallizable thermoplastic resins and dendrimers with improved fabrication characteristics |
WO2005075563A1 (de) * | 2004-02-04 | 2005-08-18 | Basf Aktiengesellschaft | FLIEßFÄHIGE POLYESTERFORMMASSEN |
WO2005075565A1 (de) * | 2004-02-04 | 2005-08-18 | Basf Aktiengesellschaft | Fliessfähige polyesterformmassen |
CN100455626C (zh) * | 2004-02-04 | 2009-01-28 | 巴斯福股份公司 | 可流动的聚酯模塑组合物 |
KR101188577B1 (ko) | 2004-07-21 | 2012-10-05 | 바스프 에스이 | 초분지형 폴리에스테르 및/또는 폴리카르보네이트를함유하는 폴리알킬렌 아릴레이트의 연속 제조 방법 |
WO2006008130A1 (de) * | 2004-07-21 | 2006-01-26 | Basf Aktiengesellschaft | Kontinuierliches verfahren zur herstellung von polyalkylenarylaten mit hyperverzweigten polyestern und/oder polycarbonaten |
US8362122B2 (en) | 2005-02-01 | 2013-01-29 | Basf Se | Flowable polyesters with carbodiimide stabilizers |
US8334046B2 (en) | 2009-05-12 | 2012-12-18 | E I Du Pont De Nemours And Company | Overmolded polyamide composite structures and processes for their preparation |
WO2011014770A2 (en) | 2009-07-30 | 2011-02-03 | E. I. Du Pont De Nemours And Company | Heat resistant semi-aromatic polyamide composite structures and processes for their preparation |
WO2011014754A1 (en) | 2009-07-30 | 2011-02-03 | E. I. Du Pont De Nemours And Company | Heat resistant polyamide composite structures and processes for their preparation |
WO2011014751A1 (en) | 2009-07-30 | 2011-02-03 | E. I. Du Pont De Nemours And Company | Overmolded heat resistant polyamide composite structures and processes for their preparation |
EP2513190A4 (en) * | 2009-12-17 | 2017-08-23 | E. I. du Pont de Nemours and Company | Polyester compositions with good melt rheological properties |
WO2011155947A1 (en) | 2010-06-11 | 2011-12-15 | E. I. Du Pont De Nemours And Company | Creep-resistant composite structures and processes for their preparation |
WO2011159377A1 (en) | 2010-06-14 | 2011-12-22 | E. I. Du Pont De Nemours And Company | Long-term outdoor exposure resistant polyester composite structures and processes for their preparation |
WO2011159382A1 (en) | 2010-06-14 | 2011-12-22 | E. I. Du Pont De Nemours And Company | Long-term outdoor exposure resistant overmolded polyester composite structures and processes for their preparation |
WO2012021435A1 (en) | 2010-08-10 | 2012-02-16 | E. I. Du Pont De Nemours And Company | Polyamide composite structures and processes for their preparation |
EP3287268A1 (en) | 2010-08-10 | 2018-02-28 | E. I. du Pont de Nemours and Company | Polyamide composite structures and processes for their preparation |
US9597861B2 (en) | 2010-10-29 | 2017-03-21 | E I Du Pont De Nemours And Company | Composite structures having improved heat aging and interlayer bond strength |
WO2013045965A1 (en) | 2011-09-28 | 2013-04-04 | Italmatch Chemicals S.P.A. | Halogen-free flame retardant polyesters composition |
Also Published As
Publication number | Publication date |
---|---|
EP1401911B1 (de) | 2005-12-07 |
MXPA03011762A (es) | 2004-07-01 |
ES2253513T3 (es) | 2006-06-01 |
PL367629A1 (en) | 2005-03-07 |
DE10132928A1 (de) | 2003-01-16 |
CN1522269A (zh) | 2004-08-18 |
US20040192857A1 (en) | 2004-09-30 |
EP1401911A1 (de) | 2004-03-31 |
DE50205208D1 (de) | 2006-01-12 |
ATE312129T1 (de) | 2005-12-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1401911B1 (de) | Modifizierte nachkondensierte polyester | |
DE102006012587B4 (de) | Verfahren und Vorrichtung zur Kristallisation von Polyestermaterial | |
EP1188783B1 (de) | Verfahren zur Herstellung von Polyestern mit reduziertem Gehalt an freiem Acetaldehyd | |
DE10136911A1 (de) | Modifizierte nachkondensierte Polyester | |
DE19811280C2 (de) | Verfahren und Vorrichtung zur Rückgewinnung von linearem Polyester | |
EP1673211B1 (de) | Verfahren zur herstellung eines formkörpers aus einem polykondensat | |
EP1742981B1 (de) | Verfahren zur herstellung von hochkondensiertem polyestergranulat | |
DE4032510A1 (de) | Verfahren zur kontinuierlichen herstellung von polyesterharz mit hohem molekulargewicht | |
DE4239260B4 (de) | Verfahren zur Herstellung von feinteilige Additive enthaltendem Polyester-Masterbatch | |
DE1929149A1 (de) | Verfahren zur Endgruppenmodifizierung von Polyestern | |
DE19503053A1 (de) | Verfahren zur direkten Herstellung von Polyester-Verpackungen | |
DE2913215A1 (de) | Modifiziertes polyaethylenterephthalat, seine herstellung und verwendung | |
DE102006023354A1 (de) | Verfahren und Vorrichtung zur Wiederverwertung von Polyestermaterial | |
DE69233252T2 (de) | Verfahren zur produktion von polyester mit hohem molekulargewicht | |
DE4429524C2 (de) | Verfahren zur Herstellung von linearen omega-Hydroxycarbonsäureeinheiten enthaltenden Copolyestern | |
WO2019162265A1 (de) | Vorrichtung und verfahren zum einmischen von recyclingmaterial in eine polyesterschmelze | |
DE60311437T2 (de) | Verfahren zur herstellung von modifiziertem thermoplastischem polyester | |
EP0553617B1 (de) | Verfahren zur Herstellung füllstoffhaltiger thermoplastischer Formmassen | |
WO2021185757A1 (de) | Verfahren zur herstellung eines zur verwendung in einem extrusionsblasverfahren geeigneten pet-ausgangsmaterials und im extrusionsblasverfahren hergestellter hohlkörper | |
DE10259694A1 (de) | Herstellung eines Polyester-Performs mit reduziertem Acetaldehydgehalt | |
AT525907B1 (de) | Verfahren zur Bearbeitung von Polykondensaten | |
AT508252B1 (de) | Verfahren und vorrichtung zur herstellung von teilkristallinem polymermaterial | |
EP3418321A1 (en) | Process for the preparation of a granulated plasticiser formulation containing a long-chain branched alcohol and polypropylene, formulation thus obtained and process for plasticising poly(lactic acid) using this formulation | |
KR20230068030A (ko) | 재생 폴리에스테르 수지를 이용한 고강도 장섬유 제조방법 | |
DE1645360A1 (de) | Verfahren zur Polymerisation von ss-Lactonen |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2002704541 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2003/011762 Country of ref document: MX |
|
WWE | Wipo information: entry into national phase |
Ref document number: 10748203 Country of ref document: US |
|
WWE | Wipo information: entry into national phase |
Ref document number: 20028134621 Country of ref document: CN |
|
WWP | Wipo information: published in national office |
Ref document number: 2002704541 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
ENP | Entry into the national phase |
Ref document number: 20040240 Country of ref document: UZ Kind code of ref document: A |
|
WWG | Wipo information: grant in national office |
Ref document number: 2002704541 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: JP |
|
WWW | Wipo information: withdrawn in national office |
Country of ref document: JP |