WO2003002678A1 - Composition de polissage pour sol - Google Patents

Composition de polissage pour sol Download PDF

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Publication number
WO2003002678A1
WO2003002678A1 PCT/US2002/019853 US0219853W WO03002678A1 WO 2003002678 A1 WO2003002678 A1 WO 2003002678A1 US 0219853 W US0219853 W US 0219853W WO 03002678 A1 WO03002678 A1 WO 03002678A1
Authority
WO
WIPO (PCT)
Prior art keywords
meth
floor polish
acrylate
polish composition
compounds
Prior art date
Application number
PCT/US2002/019853
Other languages
English (en)
Inventor
Shoji Ouchi
Tamio Nakamura
Original Assignee
Johnsondiversey, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnsondiversey, Inc. filed Critical Johnsondiversey, Inc.
Priority to EP02744549A priority Critical patent/EP1406981A1/fr
Priority to US10/480,861 priority patent/US20040198880A1/en
Publication of WO2003002678A1 publication Critical patent/WO2003002678A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09G—POLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00—Polishing compositions
    • C09G1/04—Aqueous dispersions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09G—POLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00—Polishing compositions
    • C09G1/06—Other polishing compositions
    • C09G1/14—Other polishing compositions based on non-waxy substances
    • C09G1/16—Other polishing compositions based on non-waxy substances on natural or synthetic resins

Definitions

  • the present invention relates to a floor polish composition suitable for wooden floorings, artificial floorings made of synthetic resins, and concrete, marble and other stone floors.
  • Floor polish compositions are used with a view to achieve a beautiful appearance of floor materials such as wooden floorings, artificial floorings made of synthetic resins, and concrete, marble and other stone floors; and to protect the floor surface.
  • floor polish compositions can be oil- based compositions using solvents, aqueous compositions or compositions in emulsion.
  • Japanese Patent Publication Nos . S47-14019 and S47-15597 disclose floor polish compositions for wooden floorings, artificial floorings made of synthetic resins, and concrete, marble and other stone floors which use polyvalent metal compounds.
  • the polyvalent metal compounds including zinc, cobalt, cadmium, nickel, chromium, zirconium, tin, tungsten, aluminium and other heavy metals form complexes with ammonia or amines.
  • Japanese Patent Publication No. S60 -48542 proposes a method for dispersing zinc oxide in a polymer emulsion instead of using metal complexes .
  • the floor polish compositions are obtained through a process comprising the step of dispersing zinc oxide, for instance through stirred mixing, in an emulsion comprising an acrylic . copolymer, resulting in stable compositions that do not emit amine odors during drying.
  • These polyvalent metal compounds are added to increase the durability, water resistance and removability of the floor polish composition, but, owing to the growing environmental awareness, it would be desirable to avoid the use of polyvalent metal compounds (heavy metals, etc) .
  • Japanese Patent Application Laid-open No. H8- 92529 discloses a floor polish composition using calcium as a metal crosslinking agent; however, this merely replaces the metal crosslinking agent by calcium, which [by itself] does not impart sufficient durability and wear resistance to the film compared with the usual zinc crosslinking agents; the aforementioned invention partially compensates this drawback by carrying out a crosslinking reaction between an aqueous urethane resin and a calcium compound.
  • Aqueous coating compositions have also been proposed which do not use any metal crosslinking agent at all.
  • durability is improved by including 0.1-100 parts by mass of an amine compound for 100 parts by mass (solids) of an aqueous dispersion of a copolymer having a glass transition temperature of 80°C or less.
  • the polish according to this method involves drawbacks in that, when it is used for recoating, the amines migrate into the base coat thereby resulting in an insufficient gloss, while the increased viscosity makes the coating operation more difficult.
  • Preferred viscosities for floor polish compositions are usually not larger than 15 mPa . s .
  • the inventors carried out a diligent research which resulted in the present invention, whose object is to provide a floor polish composition having superior water resistance, durability and coating property among other properties, in particular without comprising polyvalent metal compounds (heavy metals, etc); and which allows to obtain sufficient film hardness and gloss shortly after being applied and dried, exhibiting as well an excellent environmental compatibility.
  • floor polish compositions having superior water resistance, durability and coating property among other properties, in particular without comprising polyvalent metal compounds (heavy metals, etc) ; and which allows to obtain sufficient film hardness and gloss shortly after being applied and dried, exhibiting as well an excellent environmental compatibility, could be obtained by means of a polymer of ethylenic unsaturated compounds having a specific glass transition temperature and a specific acid value.
  • the first aspect of the present invention consists in a floor polish composition containing an aqueous dispersion of a polymer of ethylenic unsaturated compounds having a glass transition temperature ranging from 60 to 130°C and an acid value ranging from 130 to 180, and which does not use metal crosslinking agents.
  • the second aspect of the present invention consists in a floor polish composition wherein the polymer of ethylenic unsaturated compounds is obtained from at least two kinds of monomers, one of which is acrylic acid, and contains methyl methacrylate and / or styrene as monomers.
  • the third aspect of the present invention consists in a floor polish composition containing 0.1-100 parts by mass of an amine compound for 100 parts by mass (solids) of the polymer of ethylenic unsaturated compounds; and the fourth aspect consists in a floor polish composition comprising no amine compounds
  • the polymer of ethylenic unsaturated compounds in aqueous dispersion used in the present invention has a glass transition temperature range varying form 60 to 130°C and an acid value range varying from 130 to 180.
  • Tg glass transition temperature
  • 1/Tg l/Tgl + 2/Tg2 + W3/Tg3 ...
  • WI, W2, W3... represent the weight fractions of the monomers 1, 2, 3 in the polymer
  • Tgl, Tg2 , Tg3 represent the glass transition temperatures (absolute temperatures) of the homopolymers (pure polymers) of the same monomers 1,2,3...
  • the preferred acid value range for the above polymer of ethylenic unsaturated compounds used in the present invention is set to a range from 130 to 180.
  • the acid value represents the mg of potassium hydroxide (KOH) necessary to neutralize the carboxylic acids present in lg of polymer.
  • KOH potassium hydroxide
  • the theoretical acid values of the ⁇ , ⁇ -unsaturated carboxylic acids used for manufacturing the polymer of ethylenic unsaturated compounds are, for instance, 779 for acrylic acid and 652 for methacrylic acid.
  • the theoretical acid value of a polymer containing 10% by mass of methacrylic acid would be 65, calculated through the fraction of ⁇ , ⁇ -unsaturated carboxylic acids in the polymer and rounded to the nearest integer.
  • ethylenic unsaturated monomers that can be used are: (a) ⁇ , ⁇ -unsaturated carboxylic acids, (b) (meth) acylates, (c) methacrylates, and (d) monomers copomerizable with , ⁇ -unsaturated carboxylic acids or (meth) acrylates and methacrylates. More specifically, preferred (a) ⁇ , ⁇ -unsaturated carboxylic acid compounds include for instance (meth) acrylic acid, fumaric acid, itaconic acid, aleic acid, methacrylic acid, crotonic acid, etc., and methacrylic acid is particularly preferably used. These ⁇ , ⁇ -unsaturated carboxylic acid monomers can be used singly or in combination of 2 or more .
  • Preferred (b) acrylates include for instance alkyl (meth) acrylates such as methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, i-propyl (meth) acrylate, n-butyl (meth) acrylate, i-butyl
  • Preferred (c) methacrylates include for instance methyl methacrylate and ethyl methacrylate, cycloalkyl methacrylates, phenyl methacrylates, benzyl methacrylates, glycidyl methacrylates, etc.; herein methyl methacrylate is preferably used.
  • These methacrylate monomers can be used singly or in combination of 2 or more.
  • Preferred (d) monomers copomerizable with ⁇ , ⁇ -unsaturated carboxylic acids or (meth) acrylates and methacrylates include for instance aromatic vinyl monomers such as styrene, ⁇ -methyl styrene, 4 -methyl styrene, 2 -methyl styrene, 3 -methyl styrene, 4-methoxy styrene, 2-hydroxy styrene, 4 -ethyl styrene, 4- ethoxy styrene, 3, 4-dimethyl styrene, 2-chlorostyrene, 3- chloorstyrene, 4 -chloro-3 -methyl styrene, 4-t-butyl styrene, 2,4-dichloro styrene, 2,6 dichlorostyrene, 1-vinyl naphthalene, divinyl benzene, etc.; (me
  • (meth) acrylate ethylene glycol (meth) acrylate monophthalate, ethylene glycol (meth) acrylate hydroxyethyl phthalate, etc.; epoxy compounds such as allyl glycidyl ether, glycidyl (meth) acrylate, methyl glycidyl (meth) acrylate, etc.; polyfunctional monomers such as divinyl benzene, ethylene glycol di (meth) acrylate, diethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, tetraethylene glycol di (meth) acrylate, propylene glycol di (meth) acrylate, dipropylene glycol di (meth) acrylate, tripropylene glycol di (meth) acrylate, tetrapropylene glycol di (meth) acrylate, butanediol di (meth) acrylate, hexanediol di (me
  • polymers of ehtylenically unsaturated compounds are preferably obtained from at least two types of monomers, one of which is acrylic acid, and contain methyl methacrylate and / or styrene monomers.
  • polymers of ehtylenically unsaturated compounds consisting of at least two types of monomers comprising methacrylic acid and methyl methacrylate polymers of ehtylenically unsaturated compounds consisting of at least two types of monomers comprising methacrylic acid and styrene
  • polymers of ehtylenically unsaturated compounds consisting of at least three types of monomers comprising methacrylic acid, methyl methacrylate and styrene are preferred.
  • the above polymers of ehtylenically unsaturated compounds are obtained for instance as an aqueous dispersion with a concentration of 8 to 50 % solids by weight, and are added to the floor polish composition of the present invention in proportions ranging from 6 to 35% solids by weight.
  • the floor polish composition of the present invention is constituted by other conventional components such as plasticizers, coalescents, levelling agents, slip modifiers, wetting agents, etc.
  • Usable plasticizers include: phthalates such as dimethyl phthalate, diethyl phthalate, dibutyl phthalate, di-2 -ethyl hexyl phthalate, diisononyl phthalate, diisodecyl phthalate, butyl benzyl phthalate, etc.; citrates such as acetyl tributyl citrate, etc.; phosphates such as tributyl phosphate, tri-2- ethyl hexyl phosphate, triphenyl phosphate, tricresyl phosphate, tributoxyethyl phosphate, etc.; dibasic esters of fatty acids such as dibutyl adipate, di-2-ethyl hexyl adipate, di-n-alkyl adipates 610 , di-2-ethyl hexyl adipate, di-2-ethyl hexyl se
  • alcohols such as ethanol , isopropyl alcohol, etc.
  • polyvalent alcohols such as ehtylene glycol, etc.
  • glycol ethers such as dithylene glycol monomethyl ether, diethylene glycol monoethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, ethylene glycol mono-2 -methyl hexyl ether, diethylene glycol mono-2- ethyl hexyl ether, etc.
  • glycol ethers such as dithylene glycol monomethyl ether, diethylene glycol monoethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, ethylene glycol mono-2 -methyl hexyl ether, diethylene glycol mono-2- ethyl hexyl ether, etc.
  • alkali-soluble resins etc may be used, such as styrene / acrylic copolymers, styrene / ⁇ -methyl styrene / acrylic copolymers, styrene / methacrylic copolymers, diisobutylene / maleic anhydride copolymers, rosin-modified maleic acid [resins], shellac, etc.
  • vegetal waxes such as candelilla wax, carnauba wax, rice wax, haze wax, jojoba oil, etc.
  • animal waxes such as bee wax, lanoline, cachalot, etc.
  • mineral waxes such as montan wax, ozokerite, ceresin, etc.
  • petroleum waxes such as paraffin wax, microcrystalline wax, petrolatum, etc.
  • hydrocarbon waxes such as Fischer-Tropsch waxes, etc.
  • synthetic waxes such as polyethylene (oxide) waxes, polypropylene (oxide) waxes, etc.
  • anionic surfactants such as fluorinated surfactants, silicone- based surfactants, high alcohol sodium alkylsulfate, sodium alkyl benzene sulfonate, sodium succinic acid dialkyl ester sulfonate, sodium alkyl diphenyl ether disulfonate, sodium polyoxyethylene alkyl sulfate, sodium polyoxyethylene alkyl phenyl ether sulfate, sodium alkane sulfonates, etc.; fatty acid esters such as polyoxyehtylene alkyl ethers, polyoxyethylene polyoxypropylene alkyl ethers, polyoxyethylene polyoxypropylene copolymers, sucrose fatty acid esters, sorbitan fatty acid esters, polyethylene glycol fatty acid esters, polyglicerine fatty acid esters, etc.; fatty acid alkanolamides such as coconut oil fatty acid alkanolamide, lauri
  • alkyl betaine ampholytic surfactants such as lauryl betaine, etc.
  • amido betaine ampholytic surfactants such as lauroyl amidopropyl betaine, etc.
  • imidazoline ampholytic surfactants such as 2-alkyl-N-carboxyethyl imidazolium betaine, etc .
  • alkylsulfobetaine ampholytic surfactants such as coco amido dimethyl hydroxypropyl sulfobetaine, etc.
  • other ampholytic surfactants such as N-alkyl- ⁇ -aminopropionates, N-alkyl- ⁇ - iminodipropionates, and ⁇ -alanine ampholytic surfactants, etc.
  • pH adjusting agents such as ammonia, preservatives, defoamers, anti-fungal agents, fragrances, dyestuffs, urethane resins, colloidal silica, optical brighteners, ultraviolet absorbing agents, etc.
  • the floor polish composition of the present invention does not contain polyvalent metal compounds (heavy- metals, etc.) forming metal crosslinking agents such as, for instance: zinc oxide, calcium oxide, calcium hydroxide, aluminium hydroxide, ammine zinc carbonate, calcium ethylenediamine carbonate -ammonia, ammine zinc acetate, ammine zinc acrylate, ammine zinc malate, ammine calcium alanate, etc.
  • polyvalent metal compounds herein.
  • metal crosslinking agents such as, for instance: zinc oxide, calcium oxide, calcium hydroxide, aluminium hydroxide, ammine zinc carbonate, calcium ethylenediamine carbonate -ammonia, ammine zinc acetate, ammine zinc acrylate, ammine zinc malate, ammine calcium alanate, etc.
  • polyvalent metals refer to bivalent or higher valence metals, such as beryllium, magnesium, calcium, strontium, iron, cobalt, nickel, zinc, manganese, copper, cadmium, lead, bismuth, barium, antimony, zirconium, etc.
  • polyvalent metal compounds refer to compounds containing these polyvalent metals.
  • floor polish compositions contained these polyvalent metal compounds, whereby after applying the floor polish, the metal and the acid components (methacrylic acid or acrylic acid, etc.) in the polymer (polymer of ehtylenically unsaturated compounds) reacted during the drying process through a metal crosslinking mechanism, thereby bringing about an improvement in durability, water resistance and removability; however, owing to the growing environmental awareness, it would be desirable to avoid the use of polyvalent metal compounds, etc. (heavy metals, etc) .
  • the floor polish composition of the present invention may coprise amine compounds such as ⁇ -aminoalcohol, ⁇ -aminoalcohol, diethanolamine, triethanolamine, 2-amino- isohexyl alcohol, N,N-diethyl ethanolamine, N,N-dimethyl ethanolamine, aminoethyl ethanolamine, N-methyl-N,N- diethanolamine, N, N-butyl ethanolamine, N-methyl ethanolamine, 3-amino-l-propanol , etc; the content of amine compound for 100 parts by mass (solids) of the polymer of ethylenic unsaturated compounds may be 0.1 parts by weigh or less, but preferably no amine compound is present.
  • amine compounds such as ⁇ -aminoalcohol, ⁇ -aminoalcohol, diethanolamine, triethanolamine, 2-amino- isohexyl alcohol, N,N-diethyl ethanolamine, N,N-dimethyl ethanolamine
  • Proportions in the formulation greater than the above often result in an unpleasant odor of the composition itself, depending on subjective appreciations. Also, when the proportions of these amine compounds in the formulation are higher than several parts by mass for 100 parts by mass (solids) of the polymer of ethylenic unsaturated compounds, when the floor polish composition is used for recoating, several drawbacks become apparent, as the amines migrate into the base coat thereby resulting in an insufficient gloss while the increased viscosity makes the coating operation more difficult.
  • the non-volatile content of the above optional components is preferably adjusted to from about 12% by mass to about 40% by mass .
  • a preferred method for the manufacture of the floor polish composition of the present invention may involve the steps of adding plasticizers, coalescents, alkali-soluble resins and fluorinated surfactants to water, then adding the polymer of ethylenic unsaturated compounds, and then mixing with synthetic waxes, etc. Also, as required by the process, appropriate optional components such as pH adjusting agents like ammonia, preservatives, defoamers, anti-fungal agents, fragrances, dyestuffs, urethane resins, colloidal silica, optical brighteners, ultraviolet absorbing agents, etc. can also be added.
  • pH adjusting agents like ammonia, preservatives, defoamers, anti-fungal agents, fragrances, dyestuffs, urethane resins, colloidal silica, optical brighteners, ultraviolet absorbing agents, etc.
  • nBA is n-butyl acrylate
  • 2EHA is 2- ethyl hexyl acrylate
  • MAA is methacrylic acid
  • MMA is methyl methacrylate
  • ST is styrene
  • Tg is the glass transition temperature, respectively.
  • the viscosity of the tested floor polish compositions was measured using a single cylinder viscometer (units mPa • s) as set out in JIS K 3920 (Test methods for floor polishes) .
  • the tested compositions were applied three times onto vinyl composition tiles (nyuu machiko V No. 33 from Toli Co.), after drying at 38°C for 24 hours, 0.1 mL of water was added dropwise onto them, as set out in JIS K 3920 (Test methods for floor polishes) . 1 hour later the bleaching of the composition vinyl tiles was evaluated visually. [Evaluation criteria]
  • fluorinated surfactant S-100 (fluorinated surfactant from
  • defoamer SE-21 (defoamer from WSC Co., content 17%)
  • wax emulsion hai tekku E-4B (polyethylene wax emulsion from Toho Chemicals, content 40%)
  • plasticizer tributoxyethyl phosphate (plasticizer from
  • crosslinking agent aqueous solution of ammonium zinc carbonate complex (zinc content 12%)
  • the above examples 1 to 7 show that the floor polish composition of the present invention exhibits good properties as regards appearance, pH, viscosity, gloss, black heel mark resistance, tackiness, water resistance, environmental safety, composition odor and overall rating.
  • Comparative example 1 is an example where the Tg temperature is below the lower limit of the range according to the present invention, exhibiting a high tackiness and poor usability.
  • Comparative example 2 is an example where the acid value is below the lower limit of the range according to the present invention, exhibiting a deficient black heel mark (BHM) resistance and poor usability.
  • Comparative example 3 is an example where the acid value exceeds the upper limit of the range according to the present invention, exhibiting a deficient water resistance and poor usability.
  • Comparative example 4 wherein the composition contains conventional polymers with metal crosslinking agents, has environmental safety problems.
  • the floor polish composition of the present invention can be used as a floor polish composition suitable for wooden floorings, artificial floorings made of synthetic resins, and concrete, marble and other stone floors.
  • the present invention provides a floor polish composition having superior water resistance, durability; coating property among other properties, in particular without comprising polyvalent metal compounds (heavy metals, etc); and which allows to obtain sufficient film hardness and gloss shortly after being applied and dried, exhibiting as well an excellent environmental compatibility.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

La présente invention porte sur une composition de polissage pour planchers en bois, pour planchers artificiels fabriqués dans des résines synthétiques et pour autres types de sols en béton, marbre ou pierre. Cette composition a une meilleure résistance à l'eau, une plus grande durabilité et de meilleures propriétés de revêtement entre autres, mais ne comprend pas toutefois de composés métalliques polyvalents (métaux lourds, etc). Cette composition permet d'obtenir une dureté de film suffisante qui brille rapidement après application et séchage, et présente également une meilleure compatibilité avec l'environnement. Cette composition de polissage pour sol comprend une dispersion aqueuse d'un polymère constitué de composés insaturés éthyléniques ayant une température de transition du verre comprise entre 60 et 130 °C et une valeur acide comprise entre 130 et 180 mg, mais n'inclue pas d'agents de réticulation métalliques.
PCT/US2002/019853 2001-06-29 2002-06-25 Composition de polissage pour sol WO2003002678A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP02744549A EP1406981A1 (fr) 2001-06-29 2002-06-25 Composition de polissage pour sol
US10/480,861 US20040198880A1 (en) 2001-06-29 2002-06-25 Floor polish composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001/198240 2001-06-29
JP2001198240A JP4808337B2 (ja) 2001-06-29 2001-06-29 フロアーポリッシュ用組成物

Publications (1)

Publication Number Publication Date
WO2003002678A1 true WO2003002678A1 (fr) 2003-01-09

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EP (1) EP1406981A1 (fr)
JP (1) JP4808337B2 (fr)
AR (1) AR034714A1 (fr)
WO (1) WO2003002678A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4563750B2 (ja) * 2004-08-30 2010-10-13 ユシロ化学工業株式会社 水性フロアーポリッシュ組成物
JP6126838B2 (ja) * 2012-12-26 2017-05-10 ヘンケルジャパン株式会社 フロアーポリッシュ用組成物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989010380A1 (fr) * 1988-04-18 1989-11-02 S.C. Johnson & Son, Inc. Compositions a base d'un polyurethane dispersible dans l'eau et d'un polymere acrylique
JPH0860102A (ja) * 1994-08-23 1996-03-05 Johnson Kk フロアーポリッシュ用組成物
US5977228A (en) * 1997-06-26 1999-11-02 S. C. Johnson Commercial Markets, Inc. Plasticized aqueous coating compositions
EP1046688A1 (fr) * 1999-04-22 2000-10-25 JSR Corporation Composition de revêtement aqueuse contenant la résine acrylique et l'alcanolamine

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3030906B2 (ja) * 1991-04-01 2000-04-10 ジェイエスアール株式会社 水性被覆組成物
JP4644905B2 (ja) * 1999-04-22 2011-03-09 Ｊｓｒ株式会社 水性被覆組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989010380A1 (fr) * 1988-04-18 1989-11-02 S.C. Johnson & Son, Inc. Compositions a base d'un polyurethane dispersible dans l'eau et d'un polymere acrylique
JPH0860102A (ja) * 1994-08-23 1996-03-05 Johnson Kk フロアーポリッシュ用組成物
US5977228A (en) * 1997-06-26 1999-11-02 S. C. Johnson Commercial Markets, Inc. Plasticized aqueous coating compositions
EP1046688A1 (fr) * 1999-04-22 2000-10-25 JSR Corporation Composition de revêtement aqueuse contenant la résine acrylique et l'alcanolamine

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 199619, Derwent World Patents Index; Class A13, AN 1996-185107, XP002214505 *

Also Published As

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EP1406981A1 (fr) 2004-04-14
AR034714A1 (es) 2004-03-17
JP2003013010A (ja) 2003-01-15
JP4808337B2 (ja) 2011-11-02

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