WO2002100538A3 - Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/si02 katalysatoren - Google Patents

Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/si02 katalysatoren Download PDF

Info

Publication number
WO2002100538A3
WO2002100538A3 PCT/EP2002/006348 EP0206348W WO02100538A3 WO 2002100538 A3 WO2002100538 A3 WO 2002100538A3 EP 0206348 W EP0206348 W EP 0206348W WO 02100538 A3 WO02100538 A3 WO 02100538A3
Authority
WO
WIPO (PCT)
Prior art keywords
production
side chains
cycloaliphatic compounds
hydrogenation
catalysts
Prior art date
Application number
PCT/EP2002/006348
Other languages
English (en)
French (fr)
Other versions
WO2002100538A8 (de
WO2002100538A2 (de
Inventor
Arnd Boettcher
Jan-Dirk Arndt
Original Assignee
Basf Ag
Arnd Boettcher
Vanoppen Dominic
Jan-Dirk Arndt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Arnd Boettcher, Vanoppen Dominic, Jan-Dirk Arndt filed Critical Basf Ag
Priority to JP2003503350A priority Critical patent/JP2004529200A/ja
Priority to EP02758224A priority patent/EP1404444A2/de
Priority to KR20037016145A priority patent/KR20040030664A/ko
Priority to US10/480,239 priority patent/US20040176549A1/en
Priority to AU2002325235A priority patent/AU2002325235A1/en
Publication of WO2002100538A2 publication Critical patent/WO2002100538A2/de
Publication of WO2002100538A3 publication Critical patent/WO2002100538A3/de
Publication of WO2002100538A8 publication Critical patent/WO2002100538A8/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/28—Ethers with hydroxy compounds containing oxirane rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/28—Ethers with hydroxy compounds containing oxirane rings
    • C07D303/30—Ethers of oxirane-containing polyhydroxy compounds in which all hydroxyl radicals are etherified with oxirane-containing hydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1405—Polycondensates modified by chemical after-treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)

Abstract

Verfahren zur Herstellung von cycloaliphatischen Verbindungen (I), die Seitenketten mit Epoxidgruppen aufweisen durch heterogen-katalische Hydrierung einer Vebindung (II), die wenigstens eine carbocyclische, aromatische Gruppe und wenigstens eine Seitenkette mit wenigstens einer Epoxid-Gruppe aufweist, an einem Ruthenium-Katalisator, das dadurch gekennzeichnet ist, dass der Ruthenium-Katalysator erhältlich ist durch: i) ein oder mehrfaches Behandeln eines Trägermaterials auf Basis von amorphem Siliziumdioxid mit einer halogenfreien wässrigen Lösung einer niedermolekularen Rutheniumverbindung und anschliessendes Trocknen des behandelten Trägermaterials bei einer Temperatur unterhalb 200 °C; ii) Reduktion des in (i) erhaltenen Feststoffs mit Wasserstof bei einer Temperatur im Bereich von 100 bis 350 °C, wobei man Schritt (ii) unmittelbar im Anschluss an Schritt (i) durchführt.
PCT/EP2002/006348 2001-06-11 2002-06-10 Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/si02 katalysatoren WO2002100538A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2003503350A JP2004529200A (ja) 2001-06-11 2002-06-10 エポキシ基を有する側鎖を有する脂環式化合物（ｉ）の製造方法
EP02758224A EP1404444A2 (de) 2001-06-11 2002-06-10 Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/sio2 katalysatoren
KR20037016145A KR20040030664A (ko) 2001-06-11 2002-06-10 Ｒｕ/ＳｉＯ2 촉매상 수소화에 의한 에폭시기 함유 측쇄를갖는 지환족 화합물의 제조 방법
US10/480,239 US20040176549A1 (en) 2001-06-11 2002-06-10 Method for the production of cycloaliphatic compounds (1) having side chains with epoxy groups
AU2002325235A AU2002325235A1 (en) 2001-06-11 2002-06-10 Method for the production of cycloaliphatic compounds having side chains with epoxy groups by hydrogenation on ru/s102 catalysts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10128204A DE10128204A1 (de) 2001-06-11 2001-06-11 Verfahren zur Herstellung von cycloaliphatischen Verbindungen I, die Seitenketten mit Epoxidgruppen aufweisen
DE10128204.4 2001-06-11

Publications (3)

Publication Number Publication Date
WO2002100538A2 WO2002100538A2 (de) 2002-12-19
WO2002100538A3 true WO2002100538A3 (de) 2003-03-27
WO2002100538A8 WO2002100538A8 (de) 2003-11-20

Family

ID=7687862

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/006348 WO2002100538A2 (de) 2001-06-11 2002-06-10 Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/si02 katalysatoren

Country Status (8)

Country Link
US (1) US20040176549A1 (de)
EP (1) EP1404444A2 (de)
JP (1) JP2004529200A (de)
KR (1) KR20040030664A (de)
CN (1) CN1239488C (de)
AU (1) AU2002325235A1 (de)
DE (1) DE10128204A1 (de)
WO (1) WO2002100538A2 (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1699557A1 (de) * 2003-12-22 2006-09-13 Basf Aktiengesellschaft Ruthenium-heterogenkatalysator, verfahren zur hydrierung einer carbocyclischen aromatischen gruppe und kernhydrierte bisglycidylether der bisphenole a und f
DE10361157A1 (de) * 2003-12-22 2005-07-21 Basf Ag Ruthenium-Heterogenkatalysator und Verfahren zur Herstellung eines Bisglycidylethers der Formel I
DE102005027567A1 (de) 2005-06-14 2006-12-21 Basf Ag Verfahren zum Passivieren von metallischen Oberflächen mit Säuregruppen aufweisenden Polymeren
DE102005029200A1 (de) 2005-06-22 2006-12-28 Basf Ag Katalysator und Verfahren zur Hydrierung von hydrierbare Gruppen enthaltenden organischen Verbindungen
EP1896174A1 (de) * 2005-06-22 2008-03-12 Basf Se Ruthenium-heterogenkatalysator und verfahren zur hydrierung einer carbocyclischen aromatischen gruppe, insbesondere zur herstellung von kernhydrierten bisglycidylethern der bisphenole a und f
US7947859B2 (en) * 2005-08-26 2011-05-24 Asahi Kasei Chemicals Corporation Process for production of cycloolefin
DE102005062354A1 (de) * 2005-12-23 2007-06-28 Basf Ag Verfahren zur Umsetzung eines aromatischen Kohlenwasserstoffs in Gegenwart von Wasserstoff
WO2010079035A2 (de) 2008-12-17 2010-07-15 Basf Se Kontinuierliches verfahren zur herstellung von substituierten cyclohexylmethanolen
EP2512658A2 (de) 2009-12-15 2012-10-24 Basf Se Katalysator und verfahren zur hydrierung von aromaten
US10150102B2 (en) * 2014-03-12 2018-12-11 Dow Global Technologies Llc Catalyst regeneration process
WO2015138128A1 (en) 2014-03-12 2015-09-17 Dow Global Technologies Llc Epoxy resin compositions
CN114570361B (zh) * 2022-03-30 2023-01-06 福州大学 一种用于氨分解制氢Ru基催化剂及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3336241A (en) * 1963-11-12 1967-08-15 Shell Oil Co Process for preparing epoxy compounds and resulting products
US5334790A (en) * 1992-02-26 1994-08-02 Catalytica Process and catalyst for partially hydrogenating aromatics to produce cycloolefins
US6130344A (en) * 1997-11-27 2000-10-10 Mitsubishi Chemical Corporation Process for producing compound having epoxy group

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3629632A1 (de) * 1986-08-30 1988-03-03 Basf Ag Verfahren zur herstellung von 2,2-di-(p-glycidoxi-cyclohexyl)-propan
JP2814711B2 (ja) * 1990-07-13 1998-10-27 三菱化学株式会社 シクロオレフィンの製造法
DE4414089A1 (de) * 1994-04-22 1995-10-26 Basf Ag Verfahren zur selektiven Hydrierung von aromatischen Gruppen in Gegenwart von Epoxygruppen

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3336241A (en) * 1963-11-12 1967-08-15 Shell Oil Co Process for preparing epoxy compounds and resulting products
US5334790A (en) * 1992-02-26 1994-08-02 Catalytica Process and catalyst for partially hydrogenating aromatics to produce cycloolefins
US6130344A (en) * 1997-11-27 2000-10-10 Mitsubishi Chemical Corporation Process for producing compound having epoxy group

Also Published As

Publication number Publication date
AU2002325235A1 (en) 2002-12-23
US20040176549A1 (en) 2004-09-09
JP2004529200A (ja) 2004-09-24
EP1404444A2 (de) 2004-04-07
DE10128204A1 (de) 2002-12-12
CN1535175A (zh) 2004-10-06
AU2002325235A8 (en) 2005-10-13
KR20040030664A (ko) 2004-04-09
WO2002100538A8 (de) 2003-11-20
WO2002100538A2 (de) 2002-12-19
CN1239488C (zh) 2006-02-01

Similar Documents

Publication Publication Date Title
WO2002100538A8 (de) Verfahren zur herstellung von cycloaliphatischen verbindungen, die seitenketten mit epoxidgruppen aufweisen, durch hydrierung an ru/si02 katalysatoren
WO2002100537A3 (de) Ruthenium-katalysatoren auf einem träger auf si02-basis für die katalytische hydrierung von sacchariden
WO2002100539A3 (de) Verfahren zur herstellung von sorbit durch hydrierung geeigneter mono- und disaccharide an einem ru/si02-katalysator
ATE260907T1 (de) Verfahren zur herstellung von olefinischen epoxiden
WO2001096418A3 (de) Auf calciniertes hydrotalcit geträgerter katalysatorfeststoff zur olefinpolymerisation
ATE455741T1 (de) Verfahren zur herstellung von sek.-butylbenzol
MXPA03011983A (es) Metodo de antioxidacion y agua que funcionada como antioxidante.
ES2122745T3 (es) Procedimiento para la regeneracion de un catalizador.
CA2120364A1 (en) Method of removing volatile organic compounds from water
DE69902114D1 (de) Verfahren zur Herstellung von olefinischen Epoxiden
CA2202906A1 (en) Process and installation for the treatment of effluents by oxidation and denitrification in the presence of a heterogeneous catalyst
HUP0004411A2 (hu) Eljárás szerves vegyületek szelektív oxidálására és molekulaszita-katalizátorok előállítására
PT787747E (pt) Processo para a preparacao de componentes cataliticos solidos e de um catalisador para a polimerizacao de olefinas
EP0273368A3 (de) Verfahren zur Herstellung von hitzehärtbaren Harzen
ATE348795T1 (de) Verfahren zur herstellung von oximen
BR9809715B1 (pt) catalisador para produÇço de acetato vinÍlico por reaÇço de etileno, oxigÊnio e Ácido acÉtico e processo para produÇço do mesmo.
WO2000068278A3 (en) Process to prepare hydrogenated polymers with improved colour
TW376380B (en) Coproduction of 6-aminocapronitrile and hexamethylenediamine
BR9908395B1 (pt) processo de tratamento da mistura da reação proveniente da oxidação direta do ciclo-hexano a ácido adìpico.
ATE253979T1 (de) Silberkatalysator, verfahren zu seiner herstellung und verfahren zur herstellung von ethylenoxid
CA2202905A1 (en) Process and installation for the treatment of effluents by oxidation in the presence of a heterogeneous catalyst
NZ508464A (en) Method for treatment of aqueous streams comprising biosolids using an anionic inorganic colloid and an organic polymer
EP1223152A3 (de) Verfahren zur Zersetzung von hydrophilen Polymeren
DE69018069T2 (de) Katalysatorsystem für die Herstellung von trans-1,4-Polybutadien.
EP1535932A4 (de) Verfahren zur herstellung von buten-oligomer

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
CFP Corrected version of a pamphlet front page
CR1 Correction of entry in section i

Free format text: IN PCT GAZETTE 51/2002 UNDER (71) DELETE "VANOPPEN, DOMINIC ¢BE/BE!; DAHLIALAAN 12, B-2950 KAPELLEN (BE)."; UNDER (72, 75) ADD "VANOPPEN, DOMINIC ¢BE/BE!; DAHLIALAAN 12, B-2950 KAPELLEN (BE)."

Free format text: IN PCT GAZETTE 51/2002 UNDER (71) DELETE "VANOPPEN, DOMINIC ¢BE/BE!; DAHLIALAAN 12, B-2950 KAPELLEN (BE)."; UNDER (72, 75) ADD "VANOPPEN, DOMINIC ¢BE/BE!; DAHLIALAAN 12, B-2950 KAPELLEN (BE)."

WWE Wipo information: entry into national phase

Ref document number: 10480239

Country of ref document: US

Ref document number: 2003503350

Country of ref document: JP

Ref document number: 2002758224

Country of ref document: EP

Ref document number: 1020037016145

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 028132777

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2002758224

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWR Wipo information: refused in national office

Ref document number: 2002758224

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 2002758224

Country of ref document: EP