HUP0004411A2 - Eljárás szerves vegyületek szelektív oxidálására és molekulaszita-katalizátorok előállítására - Google Patents

Eljárás szerves vegyületek szelektív oxidálására és molekulaszita-katalizátorok előállítására

Info

Publication number
HUP0004411A2
HUP0004411A2 HU0004411A HUP0004411A HUP0004411A2 HU P0004411 A2 HUP0004411 A2 HU P0004411A2 HU 0004411 A HU0004411 A HU 0004411A HU P0004411 A HUP0004411 A HU P0004411A HU P0004411 A2 HUP0004411 A2 HU P0004411A2
Authority
HU
Hungary
Prior art keywords
catalysts
molecular sieve
organic compounds
selective oxidation
moleculesieve
Prior art date
Application number
HU0004411A
Other languages
English (en)
Inventor
Keith R. Olewine
Prahlad R. Singh
Gerald P. Tercho
Jack N. Wentz
Original Assignee
Du Pont Pharmaceuticals Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont Pharmaceuticals Company filed Critical Du Pont Pharmaceuticals Company
Publication of HUP0004411A2 publication Critical patent/HUP0004411A2/hu
Publication of HUP0004411A3 publication Critical patent/HUP0004411A3/hu

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N5/00—Radiation therapy
    • A61N5/10—X-ray therapy; Gamma-ray therapy; Particle-irradiation therapy
    • A61N5/1001—X-ray therapy; Gamma-ray therapy; Particle-irradiation therapy using radiation sources introduced into or applied onto the body; brachytherapy
    • A61N5/1027—Interstitial radiation therapy
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K51/00—Preparations containing radioactive substances for use in therapy or testing in vivo
    • A61K51/12—Preparations containing radioactive substances for use in therapy or testing in vivo characterised by a special physical form, e.g. emulsion, microcapsules, liposomes, characterized by a special physical form, e.g. emulsions, dispersions, microcapsules
    • A61K51/1282—Devices used in vivo and carrying the radioactive therapeutic or diagnostic agent, therapeutic or in vivo diagnostic kits, stents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N5/00—Radiation therapy
    • A61N5/10—X-ray therapy; Gamma-ray therapy; Particle-irradiation therapy
    • A61N5/1001—X-ray therapy; Gamma-ray therapy; Particle-irradiation therapy using radiation sources introduced into or applied onto the body; brachytherapy
    • A61N2005/1019—Sources therefor
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61N—ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY
    • A61N5/00—Radiation therapy
    • A61N5/10—X-ray therapy; Gamma-ray therapy; Particle-irradiation therapy
    • A61N5/1001—X-ray therapy; Gamma-ray therapy; Particle-irradiation therapy using radiation sources introduced into or applied onto the body; brachytherapy
    • A61N2005/1019—Sources therefor
    • A61N2005/1024—Seeds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Optics & Photonics (AREA)
  • Public Health (AREA)
  • Physics & Mathematics (AREA)
  • Veterinary Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Epidemiology (AREA)
  • Medicinal Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Pathology (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Radiology & Medical Imaging (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Medicinal Preparation (AREA)
  • Materials For Medical Uses (AREA)
  • Radiation-Therapy Devices (AREA)
  • Prostheses (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)

Abstract

A találmány szerves vegyületek szelektív oxidálására alkalmaseljárásra, valamint molekulaszita-katalizátorok előállítására szolgálóeljárásra vonatkozik. A találmány tárgyát képező eljárás szerintoxidálható szerves vegyületet egy reakciózónában hidrogén-peroxiddalérintkeztetnek olyan, katalitikusan hatásos mennyiségű oldhatatlankatalizátor jelenlétében, amely szilícium-dioxidból és legalább egyhidrogén-peroxid-aktiváló fém oxidjából áll, szililezőszerrel vankezelve, és ennek a kezelésnek az eredményeként a kezelt katalizátoraktivitása legalább kétszerese a kezeletlen katalizátorénak. Atalálmány szerint úgy állítanak elő molekulaszita-katalizátorokat,hogy szilícium-oxidot és titán-oxidot tartalmazó katalizátorokatszintetizálnak, és a katalizátorokat dietoxi-szilán és etil-titanátkopolimerével érintkeztetve molekulaszita-katalizátorokat képeznek. Ó
HU0004411A 1997-11-14 1998-11-12 Process for the selective oxidation of organic compounds and for the preparing of the moleculesieve catalysts HUP0004411A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6599397P 1997-11-14 1997-11-14
PCT/US1998/024180 WO1999025666A2 (en) 1997-11-14 1998-11-12 Process for the selective oxidation of organic compounds

Publications (2)

Publication Number Publication Date
HUP0004411A2 true HUP0004411A2 (hu) 2001-04-28
HUP0004411A3 HUP0004411A3 (en) 2001-06-28

Family

ID=22066559

Family Applications (1)

Application Number Title Priority Date Filing Date
HU0004411A HUP0004411A3 (en) 1997-11-14 1998-11-12 Process for the selective oxidation of organic compounds and for the preparing of the moleculesieve catalysts

Country Status (17)

Country Link
US (1) US6391279B1 (hu)
EP (1) EP1056683A2 (hu)
JP (1) JP2001523651A (hu)
KR (1) KR20010032082A (hu)
CN (1) CN1278808A (hu)
AR (1) AR014027A1 (hu)
AU (1) AU2197099A (hu)
BR (1) BR9815311A (hu)
EE (1) EE200000234A (hu)
HR (1) HRP980595A2 (hu)
HU (1) HUP0004411A3 (hu)
IL (1) IL136124A0 (hu)
NO (1) NO20002406D0 (hu)
PL (1) PL340827A1 (hu)
SK (1) SK6752000A3 (hu)
WO (1) WO1999025666A2 (hu)
ZA (1) ZA9810409B (hu)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6547816B1 (en) * 1999-07-12 2003-04-15 Civatech Corporation Formable integral source material for medical devices
DE19959525A1 (de) * 1999-12-09 2001-06-13 Bayer Ag Katalysatoren auf Basis Edelmetall- und Titan-haltiger, organisch-anorganisch Hybridmaterialien zur selektiven Oxidation von Kohlenwasserstoffen
EP1121980B1 (en) * 2000-01-31 2007-04-11 SOLVAY (Société Anonyme) Process of oxidation with a catalyst comprising a composition of antimony trifluoride and silica
US6746661B2 (en) * 2000-11-16 2004-06-08 Microspherix Llc Brachytherapy seed
US7776310B2 (en) 2000-11-16 2010-08-17 Microspherix Llc Flexible and/or elastic brachytherapy seed or strand
WO2005095370A1 (en) * 2004-03-31 2005-10-13 Council Of Scientific & Industrial Research An improved catalytic process for the preparation of epoxides from alkenes
US8187159B2 (en) 2005-07-22 2012-05-29 Biocompatibles, UK Therapeutic member including a rail used in brachytherapy and other radiation therapy
US7736293B2 (en) 2005-07-22 2010-06-15 Biocompatibles Uk Limited Implants for use in brachytherapy and other radiation therapy that resist migration and rotation
JP5176426B2 (ja) * 2007-03-16 2013-04-03 住友化学株式会社 シクロアルカノール及び／又はシクロアルカノンの製造方法
KR100987379B1 (ko) * 2008-01-07 2010-10-12 이도형 해양 오염 방지용 오일 방제선
KR200452158Y1 (ko) * 2008-04-18 2011-02-10 조병호 해상 오염 크리닝 장치
US8663210B2 (en) 2009-05-13 2014-03-04 Novian Health, Inc. Methods and apparatus for performing interstitial laser therapy and interstitial brachytherapy
AU2010200556B2 (en) * 2010-02-15 2012-02-02 Oncobeta International Gmbh Brachytherapy method of treating skin tumours using a tailor-made radioactive source
JP2012006887A (ja) * 2010-06-28 2012-01-12 Sumitomo Chemical Co Ltd プロピレンオキサイドの製造方法
CN102766031A (zh) * 2011-05-05 2012-11-07 岳阳昌德化工实业有限公司 一种环己烷氧化的方法
CN102757304B (zh) * 2011-04-29 2014-12-17 岳阳昌德化工实业有限公司 一种环己烷氧化的方法
CN102757306B (zh) * 2011-04-29 2015-01-28 岳阳昌德化工实业有限公司 一种环己酮的制备方法
CN102757305B (zh) * 2011-04-29 2014-12-17 岳阳昌德化工实业有限公司 一种环己烷氧化的方法
CN102757303B (zh) * 2011-04-29 2014-12-17 岳阳昌德化工实业有限公司 一种环己烷氧化的方法
CN102766026B (zh) * 2011-05-05 2014-12-17 岳阳昌德化工实业有限公司 一种环己烷氧化制环己醇的方法
CN105712954A (zh) * 2014-12-05 2016-06-29 中国科学院大连化学物理研究所 一种1-辛烯环氧化制备1,2-环氧辛烷的方法
CN107552031B (zh) * 2016-07-01 2020-12-11 东联化学股份有限公司 含钛氧化硅材料的制备方法及应用
CN107262147B (zh) * 2017-06-14 2019-09-27 昆明理工大学 一种耐硫性催化燃烧催化剂及制备方法
WO2024011452A1 (zh) * 2022-07-13 2024-01-18 深圳先进技术研究院 一种薄膜的制备方法及其应用

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3351049A (en) 1965-04-12 1967-11-07 Hazleton Nuclear Science Corp Therapeutic metal seed containing within a radioactive isotope disposed on a carrier and method of manufacture
US3640093A (en) * 1969-03-10 1972-02-08 Owens Illinois Inc Process of converting metalorganic compounds and high purity products obtained therefrom
US3923843A (en) * 1972-03-13 1975-12-02 Shell Oil Co Epoxidation process with improved heterogeneous catalyst
IT1127311B (it) * 1979-12-21 1986-05-21 Anic Spa Materiale sintetico,cristallino,poroso costituito da ossidi di silicio e titanio,metodo per la sua preparazione e suoi usi
US4323055A (en) * 1980-04-08 1982-04-06 Minnesota Mining And Manufacturing Company Radioactive iodine seed
US4510924A (en) 1980-07-10 1985-04-16 Yale-New Haven Hospital, Inc. Brachytherapy devices and methods employing americium-241
IT1150699B (it) * 1982-03-19 1986-12-17 Anic Spa Procedimento per la ossidrilazione di idrocarburi aromatici
US4697575A (en) 1984-11-21 1987-10-06 Henry Ford Hospital Delivery system for interstitial radiation therapy including substantially non-deflecting elongated member
US4702228A (en) 1985-01-24 1987-10-27 Theragenics Corporation X-ray-emitting interstitial implants
ES2033693T3 (es) * 1986-01-28 1993-04-01 Eniricerche S.P.A. Un procedimiento para la exposidacion de compuestos olefinicos.
US4994013A (en) * 1988-07-28 1991-02-19 Best Industries, Inc. Pellet for a radioactive seed
US5084002A (en) 1988-08-04 1992-01-28 Omnitron International, Inc. Ultra-thin high dose iridium source for remote afterloader
GB8904177D0 (en) 1989-02-23 1989-04-05 Amersham Int Plc Low energy radiation source and devices
US5405309A (en) 1993-04-28 1995-04-11 Theragenics Corporation X-ray emitting interstitial implants
DE4419195A1 (de) 1993-07-12 1995-01-19 Degussa Strukturierter Katalysator, bestehend aus mikroporösen Oxiden von Silicium, Aluminium und Titan
JP3658790B2 (ja) * 1995-03-30 2005-06-08 住友化学株式会社 触媒及びオキシラン化合物の製造方法
US5713828A (en) * 1995-11-27 1998-02-03 International Brachytherapy S.A Hollow-tube brachytherapy device
DE19545042A1 (de) * 1995-12-02 1997-06-05 Studiengesellschaft Kohle Mbh Amorphe mikroporöse Mischoxidkatalysatoren mit kontrollierter Oberflächenpolarität für die selektive heterogene Katalyse Adsorption und Stofftrennung
US5759945A (en) * 1997-03-26 1998-06-02 Arco Chemical Technology, L.P. Preparation of titanium-containing catalysts using titanosiloxane polymers
DE69924973T2 (de) * 1998-02-12 2006-03-09 Robert Burlington Robertson Eingekapselte brachytherapie quellen mit niedriger energie
US5997463A (en) * 1998-03-26 1999-12-07 North American Scientific Laser welded brachytherapy source and method of making the same
US6007475A (en) * 1998-08-12 1999-12-28 Cns Technology, Inc. Radioactive therapeutic seeds
US6200258B1 (en) * 1999-08-10 2001-03-13 Syntheon, Llc Radioactive therapeutic seed having selective marker configuration

Also Published As

Publication number Publication date
EP1056683A2 (en) 2000-12-06
AU2197099A (en) 1999-06-07
NO20002406L (no) 2000-05-09
AR014027A1 (es) 2001-01-31
NO20002406D0 (no) 2000-05-09
SK6752000A3 (en) 2000-10-09
JP2001523651A (ja) 2001-11-27
EE200000234A (et) 2001-06-15
ZA9810409B (en) 2000-05-15
KR20010032082A (ko) 2001-04-16
WO1999025666A3 (en) 1999-09-10
HRP980595A2 (en) 2000-02-29
WO1999025666A2 (en) 1999-05-27
IL136124A0 (en) 2001-05-20
US6391279B1 (en) 2002-05-21
HUP0004411A3 (en) 2001-06-28
BR9815311A (pt) 2001-08-07
PL340827A1 (en) 2001-02-26
CN1278808A (zh) 2001-01-03

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