WO2002095122A1 - Hydrophob modifizierte polyethylenimine und polyvinylamine zur antiknitterausrüstung von cellulosehaltigen textilien - Google Patents
Hydrophob modifizierte polyethylenimine und polyvinylamine zur antiknitterausrüstung von cellulosehaltigen textilien Download PDFInfo
- Publication number
- WO2002095122A1 WO2002095122A1 PCT/EP2002/005424 EP0205424W WO02095122A1 WO 2002095122 A1 WO2002095122 A1 WO 2002095122A1 EP 0205424 W EP0205424 W EP 0205424W WO 02095122 A1 WO02095122 A1 WO 02095122A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- hydrophobically modified
- polyvinylamines
- textiles
- acid
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/61—Polyamines polyimines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
Definitions
- the invention relates to methods for anti-creasing of cellulose-containing textiles, the use of hydrophobically modified polyethylemmines and polyvinylamines as anti-creasing additives and textile treatment agents, solid and liquid detergent formulations and laundry detergents which contain the hydrophobically modified polyethylemmines and polyvinylamines.
- Textiles containing cellulose are easy to care for, for example, by treatment with condensation products made from urea, glyoxal and formaldehyde.
- the equipment takes place during the manufacture of the textile materials.
- Other additives such as plasticizing compounds are often used in the finishing.
- the textiles finished in this way have the advantage over the untreated cellulose textiles after the washing process that they have fewer creases and folds, are easier to iron and are softer and smoother.
- WO 92/01773 discloses the use of microemulsified aminosiloxanes in fabric softeners to reduce the formation of creases and wrinkles during the washing process (anti-crease equipment). At the same time, ironing should be made easier by using the aminosiloxanes.
- a method for pretreating textile materials is known from WO 98/4772, a mixture of a polycarboxylic acid and a cationic plasticizer being applied to the textile materials. Anti-crease is achieved. From EP-A 0 300 525, fabric softeners based on crosslinkable amino-functionalized silicones are known which bring about a crease protection or an easy ironing effect for the textiles treated with them.
- Formulations are known from WO 99/55953 which cause an anti-creasing effect in the treated textiles.
- the formulations consist of lubricants, polymers that ensure the dimensional and dimensional stability of the textiles, lithium salts and optionally other ingredients such as plasticizers, ionic and nonionic surfactants, odor-binding substances and bactericides.
- the formulation is preferably applied to the textile material by spraying.
- EP-A 0 978 556 describes a mixture of a plasticizer and a crosslinking component with cationic properties as a means of providing textiles with anti-crease and wrinkle protection, and a process for the anti-wrinkle finishing of textiles.
- WO 00/24853 describes a fabric softener formulation which has an anti-crease effect on the treated textiles.
- Modified silicones such as aminopolydimethylsiloxane-polyalkylene oxide copolymers or sulfated or sulfonated vegetable oils such as sulfated castor oil are preferably used as agents reducing the tendency of the textiles to crease.
- the object of the invention is to provide a further process for the anti-wrinkle treatment of cellulose-containing textiles as well as further finishing agents for the anti-wrinkle treatment of such textiles.
- the object is achieved by a process for the anti-creasing of cellulose-containing textiles by treating the textiles with a finishing agent and drying the treated textiles, characterized in that the finishing agent contains one or more hydrophobically modified polyethyleneimines and / or polyvinylamines in dissolved or dispersed form.
- the object is also achieved by finishing agents for anti-crease finishing of cellulose-containing textiles which contain the hydrophobically modified polyethylemmines and / or the hydrophobically modified polyvinylamines.
- finishing agents for anti-crease finishing of cellulose-containing textiles which contain the hydrophobically modified polyethylemmines and / or the hydrophobically modified polyvinylamines.
- polyethylemmines which are used according to the invention in hydrophobically modified form as anti-crease additives are understood to be the homopolymers of ethyleneimine (aziridine) or its higher homologues and the graft polymers of polyamidoamines or polyvinylamines with ethyleneimine or its higher homologues.
- the polyethylemmines can be uncrosslinked or crosslinked, quaternized and / or modified by reaction with alkylene oxides, dialkyl or alkylene carbonates or Cp to C 4 carboxylic acids.
- Polyethylenimine homopolymers which can be present in uncrosslinked or crosslinked form can be used as the polyethylenemines which are modified hydrophobically.
- the polyethyleneimine homopolymers can by known methods, such as. B. in Römpps Chemie Lexikon, 8th ed. 1992, pp. 3532-3533, or in Ullmanns Enzyklopadie der Technische Chemie, 4th ed. 1974, vol. 8, pp. 212-213 and the literature described there become. They have a molecular weight in the range of approximately 200 to 1,000,000 g / mol. Higher molecular weight polymers are obtained by crosslinking with polyfunctional compounds.
- Suitable polyfunctional, crosslinking compounds are, for example, diisocyanates such as hexamethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane, 4,4'-diisocyanate and diphenylmethane diisocyanate, dihaloalkanes such as 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane and 1,6-dichlorohexane , Diepoxides such as oligo- and polyethylene glycol bispoxides, epihalohydrins such as epichlorohydrin, bischlorohydrin ethers of alkylene glycols and polyalkylene glycols with 2 to 100 ethylene oxide and / or propylene oxide units, alkylene carbonates such as ethylene carbonate and propylene carbonate and bischloroformates such as 2,2-dimethylpropylene bischloroformate.
- Polyethyleneimines in the sense of the present invention are also those polymers containing ethyleneimine units which can be obtained by grafting polyamidoamines with ethyleneimine. These can be networked with the crosslinkers mentioned under A.
- Grafted polyamidoamines are known for example from US-A-4 144 123 or DE-B-24 34 816.
- the polyamidoamines can be obtained, for example, by condensation of
- dibasic carboxylic acids such as oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid, itaconic acid, adipic acid, tartaric acid, citric acid, propanetricarboxylic acid, butanetetracarboxylic acid, glutaric acid, suberic acid, sebacic acid, terephthalic acid and their esters, acid chlorides or anhydrides in the mixture with acid chlorides or anhydrides 50 mol% of monobasic amino acids, monobasic hydroxycarboxylic acids and / or monobasic carboxylic acids can be present,
- dibasic carboxylic acids such as oxalic acid, malonic acid, succinic acid, maleic acid, fumaric acid, itaconic acid, adipic acid, tartaric acid, citric acid, propanetricarboxylic acid, butanetetracarboxylic acid, glutaric acid, suberic acid, sebacic acid, terephthalic acid and their est
- Polyalkylene polyamines are understood to mean compounds which contain at least 3 basic nitrogen atoms in the molecule, for example diethylenetriamine, dipropylenetriamine, triethylenetetramine, tripropylenetetramine, tetraethylenepentamine, pentaethylenehexamine, N- (2-aminoethyl) -l, 3-propanediamine and N, N'-bis ( 3-aminopropyl) ethylenediamine.
- Suitable diamines are, for example, 1,2-diaminoethane, 1,3-diaminopropane, 1,4-
- the compounds (i) and (ii) are condensed as described, for example, in EP-B 0 703 972.
- the graft polymers generally contain 10 to 90% by weight of polyamidoamines as the graft base and 90 to 10% by weight of ethyleneimine as the graft base.
- polyethylemmines are also those polymers containing ethyleneimine units which can be obtained by grafting polyvinylamines with ethyleneimine.
- Polyvinylamines are by complete or partial saponification of polymers of open-chain N-vinylcarboxamides of the general formula (I)
- R 1 , R 2 H or Ci to C 6 alkyl
- the degree of saponification is generally 5 to 100%.
- the graft polymers can be crosslinked with the crosslinking agents mentioned under A.
- the graft polymers generally contain 10 to 90% by weight of polyvinylamines as the graft base and 90 to 10% by weight of ethylene imine as the graft base.
- Polyethyleneimines within the meaning of the present invention also include the polymers corresponding to the compounds listed under A to C of higher homologues of ethyleneimine, such as propyleneimine (2-methylaziridine), 1- or 2-butyleneimine (2-ethylaziridine or 2,3-dimethylaziridine ), Roger that.
- the polymers of ethyleneimine are preferred.
- the polyethylemmines mentioned under A to D can be modified by reaction with alkylene oxides such as ethylene oxide, propylene oxide or butylene oxide, dialkyl carbonates such as dimethyl carbonate and diethyl carbonate, alkylene carbonates such as ethylene carbonate or propylene carbonate, or CrC 4 carboxylic acids.
- alkylene oxides such as ethylene oxide, propylene oxide or butylene oxide
- dialkyl carbonates such as dimethyl carbonate and diethyl carbonate
- alkylene carbonates such as ethylene carbonate or propylene carbonate
- CrC 4 carboxylic acids CrC 4 carboxylic acids
- the polyethylemmines or polyvinylamines mentioned under A to D can also be present in quaternized form.
- Suitable quaternizing agents are alkylating agents such as dimethyl sulfate, diethyl sulfate, methyl chloride, methyl iodide, ethyl chloride or benzyl chloride.
- the quaternization can take place before or after the hydrophobization (see below).
- polyvinylamines which are used according to the invention in hydrophobically modified form as anti-crease additives are understood to be the homo- or copolymers of N-vinylcarboxamides which are at least partially saponified.
- the polyvinylamines can be uncrosslinked or crosslinked, quaternized and / or modified by reaction with alkylene oxides, dialkyl or alkylene carbonates or Ci to C 4 carboxylic acids.
- N-vinylcarboxamides of the formula (I) above are used.
- N-vinylformamide is preferred.
- polyvinylamines are also the copolymers
- the polymers have a K value of 5 to 300 (determined according to H. Fikentscher, Cellulose Chemie, Volume 13, pages 58-64 and 71-74 (1932) in 5% strength by weight aqueous sodium chloride solution at 25 ° C. and one Polymer concentration of 0.5 wt .-%).
- Suitable N-vinylcarboxamides are the compounds mentioned under E. N-vinylformamide is preferred.
- the polymers mentioned under E and F are at least partially saponified, that is to say 5 to 100%, preferably 20 to 100%, particularly preferably 40 to 100%) of the amide groups originally present in the polymers have been converted into amino groups by saponification.
- the saponification can take place both in the alkaline and in the acidic medium.
- polymers and copolymers containing vinylamine units used according to the invention are prepared by methods such as those described, for example, in US Pat. B. are known from US-A-4 421 602, EP-A-0 216 387 and EP-A-0 251 182.
- the polyvinylamines mentioned under E and F can also be crosslinked.
- the crosslinkers mentioned under A are suitable as crosslinkers.
- the polyvinylamines mentioned under E and F can be modified by reaction with alkylene oxides such as ethylene oxide, propylene oxide or butylene oxide, dialkyl carbonates such as dimethyl carbonate and diethyl carbonate, alkylene carbonates such as ethylene carbonate or propylene carbonate or C 1 -C 4 carboxylic acids. The modification can take place before or after the hydrophobization (see below).
- the polyvinylamines mentioned under E and F can also be present in quaternized form.
- Suitable quaternizing agents are alkylating agents such as dimethyl sulfate, diethyl sulfate, methyl chloride, methyl iodide, ethyl chloride or benzyl chloride.
- the quaternization can take place before or after the hydrophobization (see below).
- the polyethylemmines A to D and polyvinylamines E and F used according to the invention are hydrophobically modified.
- Hydrophobically modified in the sense of the present invention means that in the polymers listed under A to F, the hydrogen atoms of the primary and secondary amino groups are partly by linear or branched alkyl, alkenyl, hydroxyalkyl or alkylcarboxy radicals having 10 to 22 carbon atoms, preferably 14 up to 18 carbon atoms in the alkyl radical, which can carry further substituents such as carboxyl groups, are replaced.
- Long-chain linear or branched carboxylic acids with 10 to 22 carbon atoms, preferably 14 to 18 carbon atoms in the alkyl or alkylene radical such as capric acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, margaric acid, stearic acid, nonadecanoic acid, arachic acid, Behenic acid, palmitoleic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid and mixtures thereof, preferably stearic acid, palmitic acid and oleic acid, or the acid chlorides, esters or anhydrides of the carboxylic acids mentioned, Linear or branched alkyl halides with 10 to 22 carbon atoms, preferably 14 to 18 carbon atoms in the alkyl radical, such as tetradecyl chloride, hexadecyl chloride, oc
- Alkyl epoxides with 10 to 22 carbon atoms, preferably 14 to 18 carbon atoms, such as hexadecenyl oxide and octadecenyl oxide and mixtures thereof,
- Alkyl ketene dimers with 10 to 22 carbon atoms, preferably 14 to 18 carbon atoms in the alkyl radical, such as lauryl ketene, palmityl ketene, stearyl ketene and oleyl ketene dimers and mixtures thereof,
- Cyclic dicarboxylic acid anhydrides in particular alkyl-substituted succinic anhydrides having 10 to 22 carbon atoms, preferably 14 to 18 carbon atoms in the alkyl radical, such as dodecenylsuccinic anhydride, tetradecylsuccinic anhydride, hexadecenylsuccinic anhydride and mixtures thereof,
- Alkyl isocyanates having 10 to 22 carbon atoms, preferably 14 to 18 carbon atoms in the alkyl radical, such as tetradecyl isocyanate, hexadecyl isocyanate, octadecyl isocyanate and mixtures thereof, or
- the degree of hydrophobization is 0.1 to 20% by weight, preferably 0.3 to 10% by weight, particularly preferably 0.5 to 7% by weight, of the abovementioned hydrophobicizing reagents, based on the weight of the finished product.
- the invention also relates to the use of the hydrophobically modified polyethylemmines and polyvinylamines in finishing agents for anti-creasing of cellulose-containing textiles.
- Finishing agents are any liquid formulations which contain the hydrophobically modified polyethylemmines or polyvinylamines for application to the textile material in dissolved or dispersed form.
- the finishing agents according to the invention can be present, for example, as finishing agents in the narrower sense in the manufacture of the textiles or in the form of an aqueous washing liquor or as liquid textile treatment agents.
- Suitable solvents are, for example, water, alcohols such as Methanol, ethanol and propanol, THF or their mixtures.
- textiles for example, it is possible to treat the textiles with the finishing agent in connection with textile production. Textiles that have not yet been treated or have been insufficiently treated with finishing agents can be treated, for example, in the home area before or after washing, for example when ironing, with a textile treatment agent which contains the hydrophobically modified polyethylemmines or polyvinylamines. However, it is also possible to treat the textiles with hydrophobically modified polyethyleneimines or polyvinylamines in the main wash cycle or after the main wash cycle in the care or fabric softener cycle of the washing machine.
- the present invention also relates to the use of the hydrophobically modified polyethylemmines and polyvinylamines in the manufacture of the textiles, in the treatment of the textiles before and after washing, in the main wash cycle, in the fabric rinse cycle and in ironing. Different formulations are required for this.
- a textile treatment agent can be used as finishing agent which, in addition to hydrophobically modified polyethyleneimines or polyvinylamines, contains a surface-active agent in dissolved or dispersed form.
- the cellulose-containing textiles are sprayed, for example, with the hydrophobically modified polyethyleneimines or polyvinylamines, the amount applied generally being 0.01 to 10% by weight, preferably 0.1 to 7, particularly preferably 0.3 to 4% by weight on the weight of the dry textile goods.
- the finishing agent can, however, also be applied to the textile goods by immersing the textiles in a bath which is generally 0.1 to 10% by weight, preferably 0.3 to 5% by weight, based on the weight of the dry textile goods contains, dissolved or dispersed, hydrophobically modified polyethyleneimines or polyvinylamines.
- the textile is either only briefly immersed in the bath or can also remain there for a period of, for example, 1 to 30 minutes.
- the cellulose-containing textiles, which have been treated with the finishing agent either by spraying or by immersion, are optionally pressed off and dried.
- the drying can be done in air or in a dryer or by hot ironing the treated textile.
- By drying the finishing agent is fixed on the textile. The most favorable conditions for this can easily be determined with the help of experiments.
- the temperature during drying, including ironing is generally 40 to 150 ° C, preferably 60 to 110 ° C.
- the iron ironing program is particularly suitable for ironing.
- the textiles which have been treated with the hydrophobically modified polyethyleneimines or polyvinylamines in dissolved or dispersed form by the process described above have excellent wrinkle and wrinkle protection which persists over several washes. Ironing the textiles is often no longer necessary.
- the textiles treated in this way also have fiber and color protection.
- the invention also relates to a textile treatment composition containing
- d) 0 to 60% by weight of further ingredients such as further wetting agents, plasticizers, lubricants, water-soluble, film-forming and adhesive polymers, fragrances and dyes, stabilizers, fiber and color protection additives, viscosity modifiers, soil release additives, corrosion protection additives, bactericides, Preservatives and spray aids, and
- Preferred silicones b) are silicones containing amino groups, which are preferably in microemulsified form, alkoxylated, in particular ethoxylated silicones, polyalkylene oxide polysiloxanes, polyalkylene oxide aminopolydimethylsiloxanes, silicones with quaternary ammonium groups (silicone quats) and silicone surfactants.
- Suitable plasticizers or lubricants are, for example, oxidized polyethylenes or waxes and oils containing paraffin.
- Suitable water-soluble, film-forming and adhesive polymers are, for example, (co) polymers based on acrylamide, N-vinylpyrrolidone, vinylformamide, N-vinylimidazole, vinylamine, N, N'-dialkylaminoalkyl (meth) acrylates, N, N'-dialkylaminoalkyl (meth) acrylamides, (meth) acrylic acid, (meth) acrylic acid alkyl esters and / or vinyl sulfonate.
- the basic monomers mentioned above can also be used in quaternized form.
- the formulation can additionally contain a spraying aid.
- a spraying aid such as ethanol, isopropanol, ethylene glycol or propylene glycol
- alcohols such as ethanol, isopropanol, ethylene glycol or propylene glycol
- Other common additives are fragrances and dyes, stabilizers, fiber and color protection additives, viscosity modifiers, soil release additives, corrosion protection additives, bactericides and preservatives in the amounts customary for this.
- the textile treatment agent can also generally be applied by spraying when the textile is ironed after washing. This not only makes ironing considerably easier, the textiles are also equipped with long-lasting crease and wrinkle protection.
- hydrophobically modified polyethylenemines and polyvinylamines can also be used when washing the textiles in the main washing cycle of the washing machine.
- the invention also relates to a solid detergent formulation containing
- a solid detergent formulation according to the invention is usually in powder or granule form or in extrudate or tablet form.
- the invention further relates to a liquid detergent formulation
- Solvents solubilizers, hydrotropes, thickeners and / or alkanolamines,
- Suitable silicones b) are the silicones mentioned above.
- Suitable anionic surfactants c) are in particular:
- (Fatty) alcohol sulfates alcohols having 8 to 22 of (fat), preferably from 10 to 18 carbon atoms, for example C 9 - to C ⁇ -alcohol sulfates, C 12 - to C 14 - alcohol sulfates, C 12 - C ⁇ 8 - alcohol sulfates, lauryl sulfate, cetyl sulfate , Myristyl sulfate, palmityl sulfate, stearyl sulfate and tallow fatty alcohol sulfate; - Sulphated alkoxylated C 8 - to C 2 alcohols (alkyl ether sulfates).
- Compounds of this type are prepared, for example, by first alkoxylating a C 8 to C 22 , preferably a C 10 to C 18 alcohol, for example a fatty alcohol, and then sulfating the alkoxylation product.
- Ethylene oxide is preferably used for the alkoxylation;
- LAS alkyl benzosulfonates
- LAS linear C - to C 3 - alkyl benzene sulfonates and alkyl toluenesulfonates;
- Alkanesulfonates such as C 8 to C 2 , preferably C 10 to C 18 alkanesulfonates; Soaps such as the Na and K salts of C 8 to C 24 carboxylic acids.
- the anionic surfactants mentioned are preferably added to the detergent in the form of salts.
- Suitable cations in these salts are alkali metal ions such as sodium, potassium and lithium and ammonium ions such as hydroxyethylammonium, di (hydroxyethyl) ammonium and tri (hydroxyethyl) ammonium.
- Suitable nonionic surfactants c) are in particular:
- alkoxylated C 8 to C 22 alcohols such as fatty alcohol alkoxylates or oxo alcohol alkoxylates. These can be alkoxylated with ethylene oxide, propylene oxide and or butylene oxide. All alkoxylated alcohols which contain at least two molecules of one of the above-mentioned alkylene oxides added can be used as surfactants.
- block polymers of ethylene oxide, propylene oxide and / or butylene oxide come into consideration or addition products which contain the alkylene oxides mentioned in a statistical distribution.
- the nonionic surfactants generally contain 2 to 50, preferably 3 to 20, moles of at least one alkylene oxide per mole of alcohol. These preferably contain as alkylene oxide Ethylene oxide.
- the alcohols preferably have 10 to 18 carbon atoms.
- the alkoxylates have a broad or narrow alkylene oxide homolog distribution;
- Alkylphenol alkoxylates such as alkylphenol ethoxylates with C 6 to C 14 alkyl chains and 5 to 30 alkylene oxide units;
- Alkyl polyglucosides having 8 to 22, preferably 10 to 18 carbon atoms in the alkyl chain and generally 1 to 20, preferably 1.1 to 5, glucoside units; N-alkyl glucamides, fatty acid amide alkoxylates, fatty acid alkanolamide alkoxylates and block copolymers of ethylene oxide, propylene oxide and / or butylene oxide.
- Suitable inorganic builders d) are in particular:
- zeolites crystalline or amorphous aluminosilicates with ion-exchanging properties such as, in particular, zeolites.
- Suitable zeolites are in particular zeolites A, X, B, P, MAP and HS in their Na form or in forms in which Na is partly against others
- Cations such as Li, K, Ca, Mg, or ammonium are exchanged; crystalline silicates such as, in particular, disilicates or layered silicates, for example ⁇ -Na 2 Si 2 O 5 or ⁇ -Na Si O 5.
- the silicates can be used in the form of their alkali metal, alkaline earth metal or ammonium salts, preferably as Na, Li and Mg silicates ; amorphous silicates such as sodium metasilicate or amorphous disilicate;
- Carbonates and hydrogen carbonates can be used in the form of their alkali metal, alkaline earth metal or ammonium salts.
- Na, Li and Mg carbonates or bicarbonates are preferred, in particular sodium carbonate and / or sodium bicarbonate; - polyphosphates such as Pentasodium.
- Suitable organic cobuilders e) are in particular low molecular weight, oligomeric or polymeric carboxylic acids.
- Suitable low molecular weight carboxylic acids are, for example, citric acid, hydrophobically modified citric acid such as. B. agaric acid, malic acid, tartaric acid, gluconic acid, glutaric acid, succinic acid, imidodisuccinic, oxydisuccinic acid, propane tricarboxylic acid, butane tetracarboxylic acid, Cyclopentantetra- carboxylic acid, alkyl and alkenyl succinic acids and aminopolycarboxylic acids such as nitrilotriacetic acid, .beta.-alaninediacetic acid, ethylenediaminetetraacetic acid, Serine diacetic acid, isoserine diacetic acid, N- (2-hydroxyethyl) iminodiacetic acid, ethylenediamine disuccinic acid and methyl and ethylglycinediacetic acid; Suitable oligomeric or polymeric carboxylic acids are,
- Vinyl alkyl ether with -CC 8 alkyl groups vinyl acetate, vinyl propionate, (meth) acrylic ester of CpC 8 - alcohols and styrene.
- the homopolymers of acrylic acid and copolymers of acrylic acid with maleic acid are preferably used.
- Polyaspartic acids are also suitable as organic cobuilders.
- the oligomeric and polymeric carboxylic acids are used in acid form or as the sodium salt.
- Suitable bleaches are, for example, adducts of hydrogen peroxide with inorganic salts such as e.g. Sodium perborate monohydrate, sodium perborate tetrahydrate or sodium carbonate perhydrate or percarboxylic acids such as e.g. Phthalimidopercaproic.
- inorganic salts such as e.g. Sodium perborate monohydrate, sodium perborate tetrahydrate or sodium carbonate perhydrate or percarboxylic acids such as e.g. Phthalimidopercaproic.
- Suitable bleach activators are, for example, N, N, N ', N'-tetraacetylethylene diamine (TAED), sodium p-nonanoyloxybenzenesulfonate or N-methylmorpholinium acetonitrile-methyl sulfate.
- TAED N, N, N ', N'-tetraacetylethylene diamine
- sodium p-nonanoyloxybenzenesulfonate sodium p-nonanoyloxybenzenesulfonate or N-methylmorpholinium acetonitrile-methyl sulfate.
- Enzymes preferably used in detergents are proteases, lipases, amylases, cellulases, oxidases or peroxidases.
- Suitable color transfer inhibitors are, for example, homopolymers and copolymers of 1-vinylpyrrolidone, 1-vinylimidazole or 4-vinylpyridine-N-oxide. Homo- and copolymers of 4-vinylpyridine reacted with chloroacetic acid are also suitable as color transfer inhibitors.
- the concentration of the hydrophobically modified polyethylemmines or polyvinylamines in the wash liquor is, for example, 10 to 5000 ppm and is preferably in that
- the textiles treated with the hydrophobically modified polyethyleneimines or polyvinylamines in the main washing cycle of the washing machine not only crease significantly less than untreated textiles. They are also easier to iron, softer and smoother, more dimensionally and dimensionally stable and, after being washed several times, look less "used” due to their fiber and color protection, ie they have less lint and knots and less color damage or fading.
- the hydrophobically modified polyethyleneimines or polyvinylamines can be used in the so-called soft or conditioner rinse after the main wash cycle.
- concentration of the hydrophobically modified polyethyleneimines or polyvinylamines in the wash liquor is, for example, 10 to 5000 ppm and is preferably in the range from 50 to 1000 ppm.
- Ingredients typical for a fabric softener or conditioner may possibly be present in the wash liquor.
- the textiles treated in this way also have a very good crease protection after drying on a line or preferably in a tumble dryer, which is associated with the positive effects on ironing already described above.
- the anti-crease can be significantly increased by briefly ironing the textiles after drying.
- Treatment in a soft or conditioner cycle also has a positive effect on the shape stability of the textiles. Furthermore, the formation of knots and lint is inhibited and color damage is suppressed.
- the invention also relates to a laundry detergent containing
- Suitable silicones b) are the silicones mentioned above.
- Preferred cationic surfactants c) are selected from the group of the quaternary diesterammonium salts, the quaternary tetraalkylammonium salts, the quaternary diamidoammonium salts, the amidoamine esters and imidazolium salts. These are preferably contained in the laundry detergent in an amount of 3 to 30% by weight.
- Examples are quaternary diester ammonium salts which have two C ⁇ to C 22 alk (en) yl carbonyloxy (mono- to pentamethylene) residues and two Ci to C 3 alkyl or hydroxyalkyl residues on the quaternary N atom and as a counter ion for example, wear chloride, bromide, methyl sulfate or sulfate.
- Quaternary diesterammonium further include in particular those corresponding to the trimethylene group carries a C ⁇ - to C 22 -alk (en) ylcarbonyloxytrimethylen radical, on the central carbon atom form a C ⁇ - to C 22 -alk (en) ylcarbonyloxy radical, and have three C to C 3 alkyl or hydroxyalkyl radicals on the quaternary N atom and, for example, carry chloride, bromide, methyl sulfate or sulfate as counterion.
- Quaternary tetraalkylammonium salts are in particular those which have two C 1 -C 6 -alkyl radicals and two C 8 - to C 24 -alk (en) yl radicals on the quaternary N atom and, for example, chloride, bromide, methyl sulfate or sulfate as counterions wear.
- Quaternary diamidoammonium salts are in particular those which have two C 8 - to C 24 -alk (en) ylcarbonylaminoethylene radicals, a substituent selected from hydrogen, methyl, ethyl and polyoxyethylene with up to 5 oxyethylene units and as the fourth radical a methyl group on the quaternary N. -Atom and have as counterion, for example, chloride, bromide, methyl sulfate or sulfate.
- Amidoamino esters are, in particular, tertiary amines which, as substituents on the N atom, have a C ⁇ to C 22 alk (en) ylcarbonylamino (mono- to trimethylene) radical, a C ⁇ to C22 alk (en) ylcarbonyloxy (mono- to trimethylene) ) Residue and a methyl group.
- Imidazolinium salts are in particular those in which the 2-position of the heterocycle, a C 14 - to C 18 -alk (en) yl radical, the neutral N-atom form a C 14 - to C ⁇ -A ⁇ e ⁇ ylcarbony ⁇ oxy or amino) carry the ethylene radical and hydrogen, methyl or ethyl on the N atom carrying the positive charge; counterions here are, for example, chloride, bromide, methyl sulfate or sulfate.
- reaction solution 100 g of the above reaction solution were reacted at 90 ° C with 26.0 g of butylene oxide. After cooling to 50 ° C., 1.7 g of a 50% strength by weight aqueous solution of potassium hydroxide and 300 g of xylene were added, the water was removed and the reaction mixture was reacted with 34.8 g of ethylene oxide.
- Fabric made of cotton (BW) of the size given in Table 1 with a weight per unit area of 160 g / m 2 was sprayed on both sides with the finishing agents according to Examples 1-6, so that the application amount was 2%, based on the respective weight of the dry textile goods. and then hot ironed in a slightly damp state.
- tissue samples treated in this way were washed for comparison with untreated tissue samples of the same size and in the presence of ballast tissue with a liquid detergent at 40 ° C. in an automatic household washing machine (load between 1.5 and 3.0 kg) and then dried in a tumble dryer.
- a standard washing or standard cleaning program was used (40 ° C colored wash program or cupboard dry program).
- the flat tissue samples were visually graded in accordance with the AATCC test method 124, where grade 1 means that the fabric is very creased and has many folds, while grade 5 is given for crease-free and wrinkle-free fabric.
- grade 1 means that the fabric is very creased and has many folds
- grade 5 is given for crease-free and wrinkle-free fabric.
- the tissue samples pretreated with equipment A, B and C received grades from 2 to 3.5. In contrast, the untreated tissue samples were given grade 1.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyamides (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002446906A CA2446906A1 (en) | 2001-05-18 | 2002-05-16 | Hydrophobically modified polyethylenimines and polyvinylamines for wrinkle-resistant finishing of textiles containing cellulose |
MXPA03010172A MXPA03010172A (es) | 2001-05-18 | 2002-05-16 | Polietileniminas y polivinilaminas hidrofobicamente modificadas para textiles celulosicos a prueba de arrugas. |
US10/477,208 US7141077B2 (en) | 2001-05-18 | 2002-05-16 | Hydrophobically modified polyethylenimines and polyvinylamines for wrinkle-resistant finishing of textiles containing cellulose |
EP02750941A EP1395697B1 (de) | 2001-05-18 | 2002-05-16 | Hydrophob modifizierte polyethylenimine und polyvinylamine zur antiknitterausrüstung von cellulosehaltigen textilien |
DE50210981T DE50210981D1 (de) | 2001-05-18 | 2002-05-16 | Hydrophob modifizierte polyethylenimine und polyvinylamine zur antiknitterausrüstung von cellulosehaltigen textilien |
JP2002591578A JP2004531656A (ja) | 2001-05-18 | 2002-05-16 | セルロースを含有するテキスタイルの防しわ処理のための疎水性に変性されたポリエチレンイミンおよびポリビニルアミン |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10124387A DE10124387A1 (de) | 2001-05-18 | 2001-05-18 | Hydrophob modifizierte Polyethylenimine und Polyvinylamine zur Antiknitterausrüstung von cellulosehaltigen Textilien |
DE10124387.1 | 2001-05-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002095122A1 true WO2002095122A1 (de) | 2002-11-28 |
Family
ID=7685364
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2002/005424 WO2002095122A1 (de) | 2001-05-18 | 2002-05-16 | Hydrophob modifizierte polyethylenimine und polyvinylamine zur antiknitterausrüstung von cellulosehaltigen textilien |
Country Status (9)
Country | Link |
---|---|
US (1) | US7141077B2 (de) |
EP (1) | EP1395697B1 (de) |
JP (1) | JP2004531656A (de) |
AT (1) | ATE374275T1 (de) |
CA (1) | CA2446906A1 (de) |
DE (2) | DE10124387A1 (de) |
ES (1) | ES2291487T3 (de) |
MX (1) | MXPA03010172A (de) |
WO (1) | WO2002095122A1 (de) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005033402A1 (de) * | 2003-09-30 | 2005-04-14 | Basf Aktiengesellschaft | Verfahren zur vorbehandlung von zellulosehaltigem textil |
WO2008055857A3 (en) * | 2006-11-10 | 2009-02-19 | Basf Se | Biocidal coatings |
EP2225309A1 (de) * | 2007-12-20 | 2010-09-08 | Basf Se | Pfropfpolymere mit oligoalkyleniminseitenketten, verfahren zu ihrer herstellung und ihre verwendung |
EP2366456A1 (de) | 2010-03-19 | 2011-09-21 | Omya Development AG | Schwimmschaumflotation zum Trennen von Silicaten und Alkalin-Erdmetallcarbonaten unter Verwendung eines Kollektors mit mindestens einem wasserabweisend modifizierten Polyalkylenimin |
WO2012027369A2 (en) | 2010-08-23 | 2012-03-01 | Diversapack Of California, Llc | System and method for straightening or shaping hair |
US8778321B2 (en) | 2007-10-01 | 2014-07-15 | Nanotex Llc | Modification of cellulosic substrates to control body odor |
WO2020053001A1 (en) | 2018-09-11 | 2020-03-19 | Basf Se | A fabric care composition comprising hydrophobically modified polyalkyleneimine as dye fixative polymer |
EP3821904A1 (de) * | 2014-01-03 | 2021-05-19 | Zensun (Shanghai) Science & Technology, Co., Ltd. | Formel zur herstellung von neuregulin |
WO2021094127A1 (en) | 2019-11-14 | 2021-05-20 | Basf Se | A fabric care composition comprising hydrophobically modified polyalkyleneimine and a biocide |
WO2021115912A1 (en) | 2019-12-09 | 2021-06-17 | Basf Se | Formulations comprising a hydrophobically modified polyethyleneimine and one or more enzymes |
WO2021209278A1 (en) | 2020-04-14 | 2021-10-21 | Basf Se | Method of imparting chlorine resistance effect to colored fabric |
Families Citing this family (52)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE440129T1 (de) * | 2004-02-17 | 2009-09-15 | Optimer Inc | Zusammensetzungen als gewebeweichmacher |
WO2007095670A1 (en) * | 2006-02-20 | 2007-08-30 | Commonwealth Scientific And Industrial Research Organisation | Method and composition for priming wood and natural fibres |
FR2907678B1 (fr) * | 2006-10-25 | 2012-10-26 | Oreal | Composition de coloration des fibres keratiniques comprenant un copolymere bloc polysiloxane/polyuree |
ES2376369T3 (es) * | 2006-12-22 | 2012-03-13 | Basf Se | Polialquilenaminas modificadas de manera hidrófuga en calidad de inhibidores de transferencia de colorante. |
US20080164439A1 (en) * | 2007-01-10 | 2008-07-10 | Xinggao Fang | Textiles treated with hyperbranched polyethyleneimine derivatives for odor control properties |
US20080163437A1 (en) * | 2007-01-10 | 2008-07-10 | Xinggao Fang | Cellulosic textiles treated with hyperbranched polyethyleneimine derivatives |
FR2918989B1 (fr) * | 2007-07-18 | 2010-08-27 | Snf Sas | Polymeres cationiques d'acrylamide post ramifies solubles dans l'eau et leurs realisations |
US20090169502A1 (en) * | 2008-01-02 | 2009-07-02 | L'oreal | Compositions and methods for treating keratinous substrates using polyamides |
DK2250245T3 (da) * | 2008-02-29 | 2011-12-12 | Buck Chemie Gmbh | Klæbemiddel til påføring på en sanitær genstand |
FR2928373B1 (fr) * | 2008-03-05 | 2010-12-31 | Centre Nat Rech Scient | Polymere derive de la polyethylenimine lineaire pour le transfert de gene. |
WO2009118714A2 (en) | 2008-03-28 | 2009-10-01 | Ecolab Inc. | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
US20090246258A1 (en) * | 2008-03-28 | 2009-10-01 | Piyush Shukla | Antimicrobial and odor adsorbing textile |
US8871807B2 (en) | 2008-03-28 | 2014-10-28 | Ecolab Usa Inc. | Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids |
US8809392B2 (en) | 2008-03-28 | 2014-08-19 | Ecolab Usa Inc. | Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents |
US20100050346A1 (en) * | 2008-08-28 | 2010-03-04 | Corona Iii Alessandro | Compositions and methods for providing a benefit |
EP2857489A3 (de) * | 2008-08-28 | 2015-04-29 | The Procter and Gamble Company | Verfahren zur Herstellung einer Textilpflegezusammensetzung |
CA3045126A1 (en) * | 2009-05-05 | 2010-11-11 | Arbutus Biopharma Corporation | Methods of delivering oligonucleotides to immune cells |
EP2464693B1 (de) * | 2009-08-13 | 2015-01-28 | Huntsman Advanced Materials (Switzerland) GmbH | Nachreinigender wirkstoff |
PE20130494A1 (es) * | 2010-02-18 | 2013-04-24 | Huntsman Adv Mat Switzerland | Mezcla de tintes reactivos de fibras |
BR112012021444A2 (pt) * | 2010-02-24 | 2016-05-31 | Relypsa Inc | polímero de amina reticulado, composição farmacêutica, método de redução do colesterol ldl sérico em um indivíduo, métodos para tratar doença, de remoção de sais biliares de um indivíduo, e para melhorar o controle glicêmico em um indivíduo, e, processo para preparar o polímero de aminas. |
JP5882991B2 (ja) | 2010-05-14 | 2016-03-09 | ザ サン プロダクツ コーポレーション | ポリマー含有洗浄組成物ならびにその生成法および使用法 |
US20120183489A1 (en) * | 2011-01-14 | 2012-07-19 | Ricky Ah-Man Woo | Compositions comprising metallated malodor control polymers |
US9248209B2 (en) * | 2011-01-14 | 2016-02-02 | The Procter & Gamble Company | Compositions comprising hydrophobically modified malodor control polymers |
US20130108959A1 (en) * | 2011-10-27 | 2013-05-02 | Stephan Bauer | Use of a composition comprising vinyl monomer-comprising polymer, solvent and at least one halogen-free biocide |
US20130136712A1 (en) * | 2011-11-29 | 2013-05-30 | Ricky Ah-Man Woo | Malodor Control Compositions Comprising Malodor Control Polymers And Acid Catalysts And Methods Thereof |
US9321664B2 (en) | 2011-12-20 | 2016-04-26 | Ecolab Usa Inc. | Stable percarboxylic acid compositions and uses thereof |
MX360142B (es) | 2012-03-30 | 2018-10-24 | Ecolab Usa Inc | Usos de acido peracetico/peroxido de hidrogeno y agentes reductores de peroxido para el tratamiento de fluidos de perforacion, fluidos de fracturacion y aguas de flujo de retorno y aguas de desecho. |
US8846593B2 (en) * | 2012-04-25 | 2014-09-30 | Basf Se | Dishwashing composition comprising a covalently modified alkyleneimine polymer |
US20140256811A1 (en) | 2013-03-05 | 2014-09-11 | Ecolab Usa Inc. | Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids |
US8822719B1 (en) | 2013-03-05 | 2014-09-02 | Ecolab Usa Inc. | Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring |
US10165774B2 (en) | 2013-03-05 | 2019-01-01 | Ecolab Usa Inc. | Defoamer useful in a peracid composition with anionic surfactants |
DE102014206828A1 (de) * | 2014-04-09 | 2015-10-15 | Henkel Ag & Co. Kgaa | Bügelerleichterung von Textilien |
DE102014222924A1 (de) * | 2014-11-11 | 2016-05-12 | Henkel Ag & Co. Kgaa | Bügelerleichterung von Textilien |
KR101738954B1 (ko) * | 2015-11-05 | 2017-05-23 | 한국과학기술원 | 하이드록시 에틸그룹으로 부분 치환하여 개질된 폴리에틸렌이민 및 이의 제조 방법 |
DE102016207835A1 (de) | 2016-05-06 | 2017-11-09 | Henkel Ag & Co. Kgaa | Knitterneigungsvermeidung bei Textilien |
WO2018042060A1 (de) | 2016-09-05 | 2018-03-08 | Drei Lilien Pvg Gmbh & Co. Kg | Offenporige membran mit innerem raumdurchspannendem polymerem strukturnetzwerk zur elektrophoretischen stoffselektiven separation sowie verfahren zu deren herstellung und anwendung |
US10752868B2 (en) | 2016-11-09 | 2020-08-25 | Henkel IP & Holding GmbH | Unit dose detergent composition |
CN110352232A (zh) | 2017-02-13 | 2019-10-18 | 荷兰联合利华有限公司 | 洗衣组合物添加剂 |
BR112019016823B1 (pt) | 2017-02-13 | 2024-01-02 | Unilever Ip Holdings B.V. | Composição auxiliar para a lavagem de tecidos, método de lavagem de tecidos e uso da composição auxiliar para a lavagem de tecidos |
US20200171214A1 (en) | 2017-07-07 | 2020-06-04 | Drei Lilien Pvg Gmbh & Co. Kg | Bioresorbable surface coating for delaying degradation |
JP7449857B2 (ja) * | 2017-12-07 | 2024-03-14 | エコラボ ユーエスエー インコーポレイティド | 分枝状ポリアミンを使用してリップスティックを除去するための組成物および方法 |
CN112513220B (zh) * | 2018-07-25 | 2023-10-10 | 狮王特殊化学株式会社 | 拒水剂、拒水性纤维产品的制造方法以及拒水性纤维产品 |
US11518963B2 (en) | 2018-10-18 | 2022-12-06 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US11299591B2 (en) | 2018-10-18 | 2022-04-12 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US11732218B2 (en) | 2018-10-18 | 2023-08-22 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US11466122B2 (en) | 2018-10-18 | 2022-10-11 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
DE102019219242A1 (de) | 2019-12-10 | 2021-06-10 | Henkel Ag & Co. Kgaa | Knitterneigungsvermeidung bei Textilien |
KR20220155257A (ko) * | 2020-04-01 | 2022-11-22 | 라이온 가부시키가이샤 | 섬유 제품 처리제 조성물 및 섬유 제품의 처리 방법 |
CN112391072B (zh) * | 2020-11-12 | 2021-10-26 | 陕西科技大学 | 一种疏水长链改性l-组氨酸缓蚀剂及其制备方法和应用 |
CN112717715B (zh) * | 2020-12-14 | 2024-04-05 | 太原科技大学 | 一种具有纳米亲水通道聚乙烯基胺膜及其制备应用 |
CN113373688B (zh) * | 2021-06-08 | 2022-05-13 | 雅蒂诗(广州)时装有限公司 | 防皱修身的连衣裙的制备方法及其制成的连衣裙 |
WO2024068700A1 (en) | 2022-09-29 | 2024-04-04 | Basf Se | Improving adhesion of fibre materials in rubber composites |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4937000A (de) * | 1972-08-18 | 1974-04-05 | ||
US4011613A (en) * | 1975-11-18 | 1977-03-15 | The United States Of America As Represented By The Secretary Of Agriculture | Durable-press properties in cotton containing fabrics via polymeric N-methylol reagents |
US4520143A (en) * | 1978-05-09 | 1985-05-28 | Commonwealth Scientific And Industrial Research Organization | Compositions for the treatment of textile materials |
US5879749A (en) * | 1997-09-16 | 1999-03-09 | National Starch And Chemical Investment Holding Corporation | Crosslinkable fabric care compositions |
EP0978556A1 (de) * | 1998-08-03 | 2000-02-09 | The Procter & Gamble Company | Zusammensetzung zum Knitterfestmachen |
DE10008930A1 (de) * | 2000-02-25 | 2001-08-30 | Basf Ag | Antiknitterausrüstung von cellulosehaltigen Textilien und Wäschenachbehandlungsmittel |
DE10060373A1 (de) * | 2000-12-05 | 2002-06-06 | Basf Ag | Reaktiv modifizierte, teilchenförmige Polymerisate zur Behandlung der Oberflächen textiler und nicht-textiler Materialien |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4800026A (en) | 1987-06-22 | 1989-01-24 | The Procter & Gamble Company | Curable amine functional silicone for fabric wrinkle reduction |
AU8199791A (en) | 1990-07-23 | 1992-02-18 | Procter & Gamble Company, The | Liquid fabric softeners containing microemulsified amino silanes |
AU2811097A (en) * | 1996-05-03 | 1997-11-26 | Procter & Gamble Company, The | Cotton soil release polymers |
GB9615613D0 (en) | 1996-07-25 | 1996-09-04 | Unilever Plc | Fabric treatment composition |
WO1999055953A1 (en) | 1998-04-27 | 1999-11-04 | The Procter & Gamble Company | Fabric wrinkle control composition and method |
US6376456B1 (en) | 1998-10-27 | 2002-04-23 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Wrinkle reduction laundry product compositions |
-
2001
- 2001-05-18 DE DE10124387A patent/DE10124387A1/de not_active Withdrawn
-
2002
- 2002-05-16 WO PCT/EP2002/005424 patent/WO2002095122A1/de active IP Right Grant
- 2002-05-16 ES ES02750941T patent/ES2291487T3/es not_active Expired - Lifetime
- 2002-05-16 MX MXPA03010172A patent/MXPA03010172A/es not_active Application Discontinuation
- 2002-05-16 EP EP02750941A patent/EP1395697B1/de not_active Expired - Lifetime
- 2002-05-16 CA CA002446906A patent/CA2446906A1/en not_active Abandoned
- 2002-05-16 JP JP2002591578A patent/JP2004531656A/ja not_active Withdrawn
- 2002-05-16 DE DE50210981T patent/DE50210981D1/de not_active Expired - Lifetime
- 2002-05-16 US US10/477,208 patent/US7141077B2/en not_active Expired - Fee Related
- 2002-05-16 AT AT02750941T patent/ATE374275T1/de not_active IP Right Cessation
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4937000A (de) * | 1972-08-18 | 1974-04-05 | ||
US4011613A (en) * | 1975-11-18 | 1977-03-15 | The United States Of America As Represented By The Secretary Of Agriculture | Durable-press properties in cotton containing fabrics via polymeric N-methylol reagents |
US4520143A (en) * | 1978-05-09 | 1985-05-28 | Commonwealth Scientific And Industrial Research Organization | Compositions for the treatment of textile materials |
US5879749A (en) * | 1997-09-16 | 1999-03-09 | National Starch And Chemical Investment Holding Corporation | Crosslinkable fabric care compositions |
EP0978556A1 (de) * | 1998-08-03 | 2000-02-09 | The Procter & Gamble Company | Zusammensetzung zum Knitterfestmachen |
DE10008930A1 (de) * | 2000-02-25 | 2001-08-30 | Basf Ag | Antiknitterausrüstung von cellulosehaltigen Textilien und Wäschenachbehandlungsmittel |
DE10060373A1 (de) * | 2000-12-05 | 2002-06-06 | Basf Ag | Reaktiv modifizierte, teilchenförmige Polymerisate zur Behandlung der Oberflächen textiler und nicht-textiler Materialien |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Section Ch Week 197443, Derwent World Patents Index; Class A87, AN 1974-74932V, XP002215760 * |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005033402A1 (de) * | 2003-09-30 | 2005-04-14 | Basf Aktiengesellschaft | Verfahren zur vorbehandlung von zellulosehaltigem textil |
WO2008055857A3 (en) * | 2006-11-10 | 2009-02-19 | Basf Se | Biocidal coatings |
US8778321B2 (en) | 2007-10-01 | 2014-07-15 | Nanotex Llc | Modification of cellulosic substrates to control body odor |
EP2225309A1 (de) * | 2007-12-20 | 2010-09-08 | Basf Se | Pfropfpolymere mit oligoalkyleniminseitenketten, verfahren zu ihrer herstellung und ihre verwendung |
US8662311B2 (en) | 2010-03-19 | 2014-03-04 | Omya International Ag | Froth flotation process for the separation of silicates and alkaline earth metal carbonates using a collector comprising at least one hydrophobically modified polyalkyleneimine |
WO2011113866A1 (en) | 2010-03-19 | 2011-09-22 | Omya Development Ag | Froth flotation process for the separation of silicates and alkaline earth metal carbonates using a collector comprising at least one hydrophobically modified polyalkyleneimine |
EP2366456A1 (de) | 2010-03-19 | 2011-09-21 | Omya Development AG | Schwimmschaumflotation zum Trennen von Silicaten und Alkalin-Erdmetallcarbonaten unter Verwendung eines Kollektors mit mindestens einem wasserabweisend modifizierten Polyalkylenimin |
WO2012027369A2 (en) | 2010-08-23 | 2012-03-01 | Diversapack Of California, Llc | System and method for straightening or shaping hair |
EP3821904A1 (de) * | 2014-01-03 | 2021-05-19 | Zensun (Shanghai) Science & Technology, Co., Ltd. | Formel zur herstellung von neuregulin |
WO2020053001A1 (en) | 2018-09-11 | 2020-03-19 | Basf Se | A fabric care composition comprising hydrophobically modified polyalkyleneimine as dye fixative polymer |
US12024691B2 (en) | 2018-09-11 | 2024-07-02 | Basf Se | Fabric care composition comprising hydrophobically modified polyalkyleneimine as dye fixative polymer |
WO2021094127A1 (en) | 2019-11-14 | 2021-05-20 | Basf Se | A fabric care composition comprising hydrophobically modified polyalkyleneimine and a biocide |
WO2021115912A1 (en) | 2019-12-09 | 2021-06-17 | Basf Se | Formulations comprising a hydrophobically modified polyethyleneimine and one or more enzymes |
WO2021209278A1 (en) | 2020-04-14 | 2021-10-21 | Basf Se | Method of imparting chlorine resistance effect to colored fabric |
Also Published As
Publication number | Publication date |
---|---|
EP1395697B1 (de) | 2007-09-26 |
ATE374275T1 (de) | 2007-10-15 |
MXPA03010172A (es) | 2004-03-16 |
DE10124387A1 (de) | 2002-11-28 |
CA2446906A1 (en) | 2002-11-28 |
DE50210981D1 (de) | 2007-11-08 |
EP1395697A1 (de) | 2004-03-10 |
US7141077B2 (en) | 2006-11-28 |
US20040139559A1 (en) | 2004-07-22 |
JP2004531656A (ja) | 2004-10-14 |
ES2291487T3 (es) | 2008-03-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1395697B1 (de) | Hydrophob modifizierte polyethylenimine und polyvinylamine zur antiknitterausrüstung von cellulosehaltigen textilien | |
EP2126020B1 (de) | Hydrophob modifizierte polyalkylenimine als farbübertragungsinhibitoren | |
DE60221571T2 (de) | Azetidiniummodifizierte polymere und zusammensetzung zur behandlung von textilen flächengebilden | |
DE69924124T2 (de) | Wäschepflegezusammensetzung | |
EP1339910B1 (de) | Hochverzweigte polymere zur antiknitterausrüstung von cellulosehaltigen textilien | |
DE69713280T2 (de) | Dispergierbares polyolefin enthaltende wäschepflegemittelzusammensetzungen und deren anwendung | |
WO2006079626A1 (de) | Verwendung von polymeren auf basis modifizierter polyamine als zusatz zu waschmitteln | |
DE69805978T2 (de) | Textilienbehandlungsmittel | |
EP1343934A2 (de) | Reaktiv modifizierte, teilchenförmige polymerisate zur behandlung der oberflächen textiler und nicht-textiler materialien | |
EP0874802A1 (de) | Fettsäurederivate und ihre verwendung als tenside in wasch- und reinigungsmitteln | |
DE10118478A1 (de) | Polysiloxanhaltige Polymere zur Antiknitterausrüstung von cellulosehaltigen Textilien | |
DE60021903T2 (de) | Verwendung von zusammensetzungen zur textilpflege | |
DE10215522A1 (de) | Kationisch modifizierte anionische Polyurethandispersionen | |
DE10056163A1 (de) | Hydrophil modifizierte Polyisocyanate und Polyurethane zur Antiknitterausrüstung von cellulosehaltigen Textilien | |
DE60319857T2 (de) | Gewebebehandlungsmittel | |
DE10008930A1 (de) | Antiknitterausrüstung von cellulosehaltigen Textilien und Wäschenachbehandlungsmittel | |
EP3850069A1 (de) | Textilpflegezusammensetzung mit hydrophob modifiziertem polyalkyleneimin als farbstofffixierendes polymer | |
DE69101456T2 (de) | Flüssige Textilweichmacherzusammensetzung. | |
EP0038295A1 (de) | Komponentengemische aus Epoxyd-Polyalkylenpolyaminoamid-Umsetzungsprodukten und aus Polymerisaten auf Acrylbasis und/oder Styrol, deren Herstellung und Verwendung als Papierleimungs- und Textilbehandlungsmittel | |
WO2002103106A1 (de) | Verfahren zur schmutzablösungsfördernden behandlung von oberflächen textiler und nicht-textiler materialien | |
DE102015219849A1 (de) | Waschmittel enthaltend Isoparaffine | |
DE60105763T3 (de) | Zusammensetzung zur textilpflege | |
WO2021209278A1 (en) | Method of imparting chlorine resistance effect to colored fabric | |
DE10066215B4 (de) | Verwendung von polyquarternären Polysiloxanen als waschbeständige hydrophile Weichmacher von Textilien |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/2003/010172 Country of ref document: MX |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2446906 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2002591578 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 10477208 Country of ref document: US |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2002750941 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 2002750941 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWG | Wipo information: grant in national office |
Ref document number: 2002750941 Country of ref document: EP |