WO2002078044A2 - Method of processing a surface of a workpiece - Google Patents

Method of processing a surface of a workpiece Download PDF

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Publication number
WO2002078044A2
WO2002078044A2 PCT/JP2002/002751 JP0202751W WO02078044A2 WO 2002078044 A2 WO2002078044 A2 WO 2002078044A2 JP 0202751 W JP0202751 W JP 0202751W WO 02078044 A2 WO02078044 A2 WO 02078044A2
Authority
WO
WIPO (PCT)
Prior art keywords
workpiece
plasma
ions
negative ions
processing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2002/002751
Other languages
English (en)
French (fr)
Other versions
WO2002078044A3 (en
Inventor
Katsunori Ichiki
Kazuo Yamauchi
Hirokuni Hiyama
Seiji Samukawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ebara Corp
Original Assignee
Ebara Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ebara Corp filed Critical Ebara Corp
Priority to US10/471,743 priority Critical patent/US6909087B2/en
Publication of WO2002078044A2 publication Critical patent/WO2002078044A2/en
Publication of WO2002078044A3 publication Critical patent/WO2002078044A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32082Radio frequency generated discharge
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/30Electron-beam or ion-beam tubes for localised treatment of objects
    • H01J37/317Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32357Generation remote from the workpiece, e.g. down-stream
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32697Electrostatic control
    • H01J37/32706Polarising the substrate
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/46Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy

Definitions

  • the positive ions and the negative ions have substantially the same mass. Therefore, the positive ions and the negative ions can alternately be extracted from a plasma comprising a mixture of positive ions and negative ions and accelerated in an AC or DC pulsed electric field having a frequency of 1 MHz or lower, preferably 600 kHz or lower. At this time, accumulated charges are reduced on the surface of the workpiece, for thereby suppressing etching profile irregularities or charge build-up damage. Therefore, the workpiece can be processed in a fine pattern having a higher aspect ratio.
  • a etching rate can be enhanced by chemical sputtering effect.
  • the ions that have passed through the grid electrode 5 are emitted as an energetic beam into the process chamber 6.
  • the ion beam travels directly in the process chamber 6 and is applied to the workpiece X placed on the workpiece holder 20, for thereby etching the surface of the workpiece X, cleaning the surface of the workpiece X, modifying (e.g., nitriding or oxidizing) the surface of the workpiece X, or depositing a film on the workpiece X.
  • the ion beam generated through the grid electrode 4 may be neutralized to generate a neutral particle beam.
  • an orifice electrode made of an electrically conductive material may be used as a neutralization device or neutralizing the ion beam, as shown in FIG. 3. In FIG.
  • the neutral particle beam travels directly in the process chamber 6 and is applied to the workpiece X placed on the workpiece holder 20, for thereby etching the surface of the workpiece X, cleaning the surface of the workpiece X, modifying (e.g., nitriding or oxidizing) the surface of the workpiece X, or depositing a filmon the workpiece X.
  • FIG. 4 is a timing chart showing timing chart showing operating states of the processing apparatus shown in FIG.1.
  • Va represents the potential of the coil 10
  • Te the electron temperature in the plasma generating chamber 2
  • ne the electron density in the plasma generating chamber 2
  • ni the negative ion density in the plasma generating chamber 2
  • Vbl, Vb2 and Vb3 the potentials of the grid electrode 4.
  • the timing chart is schematically shown in FIG. 4, and the shown frequencies are different from the actual frequencies, for example.
  • the high-frequency voltage applied by the high-frequency power supply 101 is interrupted for 100 microseconds.
  • the period of time (100 microseconds) for which the high-frequency voltage is interrupted is sufficiently longer than a period of time in which the electrons in the plasma are attached to the residual process gas to generate negative ions, and sufficiently shorter than a period of time in which the electron density in the plasma is lowered to extinguish the plasma.
  • the period of time (10 microseconds) for which the high-frequency voltage is applied is long enough to recover the energy of the electrons in the plasma which has been lowered during the interruption of the high-frequency voltage.
  • FIG. 5 is a schematic view showing a whole arrangement of a processing apparatus according to a second embodiment of the present invention, with electric components in block form.
  • like parts and components are denoted by the same reference numerals and characters as those of the first embodiment and will not be described below.

Landscapes

  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Electromagnetism (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Drying Of Semiconductors (AREA)
  • ing And Chemical Polishing (AREA)
  • Welding Or Cutting Using Electron Beams (AREA)
PCT/JP2002/002751 2001-03-26 2002-03-22 Method of processing a surface of a workpiece Ceased WO2002078044A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US10/471,743 US6909087B2 (en) 2001-03-26 2002-03-22 Method of processing a surface of a workpiece

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001088888A JP2002289584A (ja) 2001-03-26 2001-03-26 表面処理方法
JP2001-88888 2001-03-26

Publications (2)

Publication Number Publication Date
WO2002078044A2 true WO2002078044A2 (en) 2002-10-03
WO2002078044A3 WO2002078044A3 (en) 2003-03-06

Family

ID=18943908

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/002751 Ceased WO2002078044A2 (en) 2001-03-26 2002-03-22 Method of processing a surface of a workpiece

Country Status (4)

Country Link
US (1) US6909087B2 (enExample)
JP (1) JP2002289584A (enExample)
TW (1) TW541572B (enExample)
WO (1) WO2002078044A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10014192B2 (en) 2011-07-20 2018-07-03 Lam Research Corporation Apparatus for atomic layering etching

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US7387738B2 (en) 2003-04-28 2008-06-17 Air Products And Chemicals, Inc. Removal of surface oxides by electron attachment for wafer bumping applications
US7897029B2 (en) * 2008-03-04 2011-03-01 Air Products And Chemicals, Inc. Removal of surface oxides by electron attachment
US8361340B2 (en) * 2003-04-28 2013-01-29 Air Products And Chemicals, Inc. Removal of surface oxides by electron attachment
JP2011199297A (ja) * 2004-07-07 2011-10-06 Showa Denko Kk プラズマ処理方法およびプラズマエッチング方法
JP2006049817A (ja) * 2004-07-07 2006-02-16 Showa Denko Kk プラズマ処理方法およびプラズマエッチング方法
US20060236931A1 (en) * 2005-04-25 2006-10-26 Varian Semiconductor Equipment Associates, Inc. Tilted Plasma Doping
KR100698614B1 (ko) * 2005-07-29 2007-03-22 삼성전자주식회사 플라즈마 가속장치 및 그것을 구비하는 플라즈마 처리시스템
KR100653073B1 (ko) * 2005-09-28 2006-12-01 삼성전자주식회사 기판처리장치와 기판처리방법
GB2437820B (en) 2006-04-27 2011-06-22 Matsushita Electric Industrial Co Ltd Fast atom bombardment source, fast atom beam emission method, and surface modification apparatus
US7772544B2 (en) * 2007-10-09 2010-08-10 Tokyo Electron Limited Neutral beam source and method for plasma heating
EP2160081A1 (en) * 2008-08-27 2010-03-03 Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. Non-thermal plasma for wound treatment and associated apparatus and method
US8338220B2 (en) * 2009-02-06 2012-12-25 Applied Materials, Inc. Negatively charged passivation layer in a photovoltaic cell
JP2010228066A (ja) * 2009-03-27 2010-10-14 Kyushu Univ ナノドットの作製方法
US20110139748A1 (en) * 2009-12-15 2011-06-16 University Of Houston Atomic layer etching with pulsed plasmas
KR101335237B1 (ko) * 2010-11-05 2013-11-29 가부시키가이샤 알박 라디칼 클리닝 장치 및 방법
JP6210658B2 (ja) * 2012-06-01 2017-10-11 新日鐵住金株式会社 金属のガス切断方法及び金属のガス切断装置
US9892931B2 (en) * 2013-10-14 2018-02-13 Taiwan Semiconductor Manufacturing Company Ltd. Semiconductor manufacturing apparatus and method thereof
WO2018173227A1 (ja) * 2017-03-23 2018-09-27 Sppテクノロジーズ株式会社 中性粒子ビーム処理装置
JP7412074B2 (ja) * 2018-07-18 2024-01-12 住友重機械工業株式会社 負イオン照射装置、及び負イオン照射装置の制御方法
CN118571739A (zh) * 2019-03-14 2024-08-30 朗姆研究公司 用于高深宽比蚀刻的等离子体蚀刻工具

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US4158589A (en) * 1977-12-30 1979-06-19 International Business Machines Corporation Negative ion extractor for a plasma etching apparatus
US4250009A (en) * 1979-05-18 1981-02-10 International Business Machines Corporation Energetic particle beam deposition system
US4837591A (en) * 1988-05-02 1989-06-06 Xerox Corporation Highlight color imaging by depositing positive and negative ions on a substrate
JP2572270B2 (ja) * 1988-09-30 1997-01-16 新敏術事業団 超高純度成膜装置
JPH05326452A (ja) * 1991-06-10 1993-12-10 Kawasaki Steel Corp プラズマ処理装置及び方法
JP2845163B2 (ja) * 1994-10-27 1999-01-13 日本電気株式会社 プラズマ処理方法及びその装置
WO1997016946A2 (en) * 1995-10-31 1997-05-09 Arakhne Technology Inc Uniform plasma generation, filter, and neutralization apparatus and method
JP2842344B2 (ja) * 1995-11-14 1999-01-06 日本電気株式会社 中性粒子ビーム処理装置
JPH1079372A (ja) * 1996-09-03 1998-03-24 Matsushita Electric Ind Co Ltd プラズマ処理方法及びプラズマ処理装置
JPH1083899A (ja) * 1996-09-09 1998-03-31 Ebara Corp 中性粒子線源
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JP3912993B2 (ja) * 2001-03-26 2007-05-09 株式会社荏原製作所 中性粒子ビーム処理装置
JP4073174B2 (ja) * 2001-03-26 2008-04-09 株式会社荏原製作所 中性粒子ビーム処理装置
JP2002289585A (ja) * 2001-03-26 2002-10-04 Ebara Corp 中性粒子ビーム処理装置

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10014192B2 (en) 2011-07-20 2018-07-03 Lam Research Corporation Apparatus for atomic layering etching

Also Published As

Publication number Publication date
US20040094400A1 (en) 2004-05-20
JP2002289584A (ja) 2002-10-04
WO2002078044A3 (en) 2003-03-06
US6909087B2 (en) 2005-06-21
TW541572B (en) 2003-07-11

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