WO2002078044A2 - Method of processing a surface of a workpiece - Google Patents
Method of processing a surface of a workpiece Download PDFInfo
- Publication number
- WO2002078044A2 WO2002078044A2 PCT/JP2002/002751 JP0202751W WO02078044A2 WO 2002078044 A2 WO2002078044 A2 WO 2002078044A2 JP 0202751 W JP0202751 W JP 0202751W WO 02078044 A2 WO02078044 A2 WO 02078044A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- workpiece
- plasma
- ions
- negative ions
- processing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32082—Radio frequency generated discharge
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/30—Electron-beam or ion-beam tubes for localised treatment of objects
- H01J37/317—Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32009—Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
- H01J37/32357—Generation remote from the workpiece, e.g. down-stream
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
- H01J37/32—Gas-filled discharge tubes
- H01J37/32431—Constructional details of the reactor
- H01J37/32697—Electrostatic control
- H01J37/32706—Polarising the substrate
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/46—Generating plasma using applied electromagnetic fields, e.g. high frequency or microwave energy
Definitions
- the positive ions and the negative ions have substantially the same mass. Therefore, the positive ions and the negative ions can alternately be extracted from a plasma comprising a mixture of positive ions and negative ions and accelerated in an AC or DC pulsed electric field having a frequency of 1 MHz or lower, preferably 600 kHz or lower. At this time, accumulated charges are reduced on the surface of the workpiece, for thereby suppressing etching profile irregularities or charge build-up damage. Therefore, the workpiece can be processed in a fine pattern having a higher aspect ratio.
- a etching rate can be enhanced by chemical sputtering effect.
- the ions that have passed through the grid electrode 5 are emitted as an energetic beam into the process chamber 6.
- the ion beam travels directly in the process chamber 6 and is applied to the workpiece X placed on the workpiece holder 20, for thereby etching the surface of the workpiece X, cleaning the surface of the workpiece X, modifying (e.g., nitriding or oxidizing) the surface of the workpiece X, or depositing a film on the workpiece X.
- the ion beam generated through the grid electrode 4 may be neutralized to generate a neutral particle beam.
- an orifice electrode made of an electrically conductive material may be used as a neutralization device or neutralizing the ion beam, as shown in FIG. 3. In FIG.
- the neutral particle beam travels directly in the process chamber 6 and is applied to the workpiece X placed on the workpiece holder 20, for thereby etching the surface of the workpiece X, cleaning the surface of the workpiece X, modifying (e.g., nitriding or oxidizing) the surface of the workpiece X, or depositing a filmon the workpiece X.
- FIG. 4 is a timing chart showing timing chart showing operating states of the processing apparatus shown in FIG.1.
- Va represents the potential of the coil 10
- Te the electron temperature in the plasma generating chamber 2
- ne the electron density in the plasma generating chamber 2
- ni the negative ion density in the plasma generating chamber 2
- Vbl, Vb2 and Vb3 the potentials of the grid electrode 4.
- the timing chart is schematically shown in FIG. 4, and the shown frequencies are different from the actual frequencies, for example.
- the high-frequency voltage applied by the high-frequency power supply 101 is interrupted for 100 microseconds.
- the period of time (100 microseconds) for which the high-frequency voltage is interrupted is sufficiently longer than a period of time in which the electrons in the plasma are attached to the residual process gas to generate negative ions, and sufficiently shorter than a period of time in which the electron density in the plasma is lowered to extinguish the plasma.
- the period of time (10 microseconds) for which the high-frequency voltage is applied is long enough to recover the energy of the electrons in the plasma which has been lowered during the interruption of the high-frequency voltage.
- FIG. 5 is a schematic view showing a whole arrangement of a processing apparatus according to a second embodiment of the present invention, with electric components in block form.
- like parts and components are denoted by the same reference numerals and characters as those of the first embodiment and will not be described below.
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Electromagnetism (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Drying Of Semiconductors (AREA)
- ing And Chemical Polishing (AREA)
- Welding Or Cutting Using Electron Beams (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/471,743 US6909087B2 (en) | 2001-03-26 | 2002-03-22 | Method of processing a surface of a workpiece |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001088888A JP2002289584A (ja) | 2001-03-26 | 2001-03-26 | 表面処理方法 |
| JP2001-88888 | 2001-03-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2002078044A2 true WO2002078044A2 (en) | 2002-10-03 |
| WO2002078044A3 WO2002078044A3 (en) | 2003-03-06 |
Family
ID=18943908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2002/002751 Ceased WO2002078044A2 (en) | 2001-03-26 | 2002-03-22 | Method of processing a surface of a workpiece |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US6909087B2 (enExample) |
| JP (1) | JP2002289584A (enExample) |
| TW (1) | TW541572B (enExample) |
| WO (1) | WO2002078044A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10014192B2 (en) | 2011-07-20 | 2018-07-03 | Lam Research Corporation | Apparatus for atomic layering etching |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7387738B2 (en) | 2003-04-28 | 2008-06-17 | Air Products And Chemicals, Inc. | Removal of surface oxides by electron attachment for wafer bumping applications |
| US7897029B2 (en) * | 2008-03-04 | 2011-03-01 | Air Products And Chemicals, Inc. | Removal of surface oxides by electron attachment |
| US8361340B2 (en) * | 2003-04-28 | 2013-01-29 | Air Products And Chemicals, Inc. | Removal of surface oxides by electron attachment |
| JP2011199297A (ja) * | 2004-07-07 | 2011-10-06 | Showa Denko Kk | プラズマ処理方法およびプラズマエッチング方法 |
| JP2006049817A (ja) * | 2004-07-07 | 2006-02-16 | Showa Denko Kk | プラズマ処理方法およびプラズマエッチング方法 |
| US20060236931A1 (en) * | 2005-04-25 | 2006-10-26 | Varian Semiconductor Equipment Associates, Inc. | Tilted Plasma Doping |
| KR100698614B1 (ko) * | 2005-07-29 | 2007-03-22 | 삼성전자주식회사 | 플라즈마 가속장치 및 그것을 구비하는 플라즈마 처리시스템 |
| KR100653073B1 (ko) * | 2005-09-28 | 2006-12-01 | 삼성전자주식회사 | 기판처리장치와 기판처리방법 |
| GB2437820B (en) | 2006-04-27 | 2011-06-22 | Matsushita Electric Industrial Co Ltd | Fast atom bombardment source, fast atom beam emission method, and surface modification apparatus |
| US7772544B2 (en) * | 2007-10-09 | 2010-08-10 | Tokyo Electron Limited | Neutral beam source and method for plasma heating |
| EP2160081A1 (en) * | 2008-08-27 | 2010-03-03 | Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. | Non-thermal plasma for wound treatment and associated apparatus and method |
| US8338220B2 (en) * | 2009-02-06 | 2012-12-25 | Applied Materials, Inc. | Negatively charged passivation layer in a photovoltaic cell |
| JP2010228066A (ja) * | 2009-03-27 | 2010-10-14 | Kyushu Univ | ナノドットの作製方法 |
| US20110139748A1 (en) * | 2009-12-15 | 2011-06-16 | University Of Houston | Atomic layer etching with pulsed plasmas |
| KR101335237B1 (ko) * | 2010-11-05 | 2013-11-29 | 가부시키가이샤 알박 | 라디칼 클리닝 장치 및 방법 |
| JP6210658B2 (ja) * | 2012-06-01 | 2017-10-11 | 新日鐵住金株式会社 | 金属のガス切断方法及び金属のガス切断装置 |
| US9892931B2 (en) * | 2013-10-14 | 2018-02-13 | Taiwan Semiconductor Manufacturing Company Ltd. | Semiconductor manufacturing apparatus and method thereof |
| WO2018173227A1 (ja) * | 2017-03-23 | 2018-09-27 | Sppテクノロジーズ株式会社 | 中性粒子ビーム処理装置 |
| JP7412074B2 (ja) * | 2018-07-18 | 2024-01-12 | 住友重機械工業株式会社 | 負イオン照射装置、及び負イオン照射装置の制御方法 |
| CN118571739A (zh) * | 2019-03-14 | 2024-08-30 | 朗姆研究公司 | 用于高深宽比蚀刻的等离子体蚀刻工具 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4158589A (en) * | 1977-12-30 | 1979-06-19 | International Business Machines Corporation | Negative ion extractor for a plasma etching apparatus |
| US4250009A (en) * | 1979-05-18 | 1981-02-10 | International Business Machines Corporation | Energetic particle beam deposition system |
| US4837591A (en) * | 1988-05-02 | 1989-06-06 | Xerox Corporation | Highlight color imaging by depositing positive and negative ions on a substrate |
| JP2572270B2 (ja) * | 1988-09-30 | 1997-01-16 | 新敏術事業団 | 超高純度成膜装置 |
| JPH05326452A (ja) * | 1991-06-10 | 1993-12-10 | Kawasaki Steel Corp | プラズマ処理装置及び方法 |
| JP2845163B2 (ja) * | 1994-10-27 | 1999-01-13 | 日本電気株式会社 | プラズマ処理方法及びその装置 |
| WO1997016946A2 (en) * | 1995-10-31 | 1997-05-09 | Arakhne Technology Inc | Uniform plasma generation, filter, and neutralization apparatus and method |
| JP2842344B2 (ja) * | 1995-11-14 | 1999-01-06 | 日本電気株式会社 | 中性粒子ビーム処理装置 |
| JPH1079372A (ja) * | 1996-09-03 | 1998-03-24 | Matsushita Electric Ind Co Ltd | プラズマ処理方法及びプラズマ処理装置 |
| JPH1083899A (ja) * | 1996-09-09 | 1998-03-31 | Ebara Corp | 中性粒子線源 |
| DE19929278A1 (de) * | 1998-06-26 | 2000-02-17 | Nissin Electric Co Ltd | Verfahren zum Implantieren negativer Wasserstoffionen und Implantierungseinrichtung |
| JP2000100790A (ja) * | 1998-09-22 | 2000-04-07 | Canon Inc | プラズマ処理装置及びそれを用いた処理方法 |
| JP3948857B2 (ja) * | 1999-07-14 | 2007-07-25 | 株式会社荏原製作所 | ビーム源 |
| JP3912993B2 (ja) * | 2001-03-26 | 2007-05-09 | 株式会社荏原製作所 | 中性粒子ビーム処理装置 |
| JP4073174B2 (ja) * | 2001-03-26 | 2008-04-09 | 株式会社荏原製作所 | 中性粒子ビーム処理装置 |
| JP2002289585A (ja) * | 2001-03-26 | 2002-10-04 | Ebara Corp | 中性粒子ビーム処理装置 |
-
2001
- 2001-03-26 JP JP2001088888A patent/JP2002289584A/ja active Pending
-
2002
- 2002-03-22 WO PCT/JP2002/002751 patent/WO2002078044A2/en not_active Ceased
- 2002-03-22 US US10/471,743 patent/US6909087B2/en not_active Expired - Fee Related
- 2002-03-25 TW TW091105701A patent/TW541572B/zh not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10014192B2 (en) | 2011-07-20 | 2018-07-03 | Lam Research Corporation | Apparatus for atomic layering etching |
Also Published As
| Publication number | Publication date |
|---|---|
| US20040094400A1 (en) | 2004-05-20 |
| JP2002289584A (ja) | 2002-10-04 |
| WO2002078044A3 (en) | 2003-03-06 |
| US6909087B2 (en) | 2005-06-21 |
| TW541572B (en) | 2003-07-11 |
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