WO2002026925A1 - Haftendes sanitärreinigungs- und beduftungsmittel - Google Patents
Haftendes sanitärreinigungs- und beduftungsmittel Download PDFInfo
- Publication number
- WO2002026925A1 WO2002026925A1 PCT/EP2001/008972 EP0108972W WO0226925A1 WO 2002026925 A1 WO2002026925 A1 WO 2002026925A1 EP 0108972 W EP0108972 W EP 0108972W WO 0226925 A1 WO0226925 A1 WO 0226925A1
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- WO
- WIPO (PCT)
- Prior art keywords
- weight
- agent
- sanitary
- aliphatic
- group
- Prior art date
Links
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/05—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating specially adapted to be released by contact with a liquid, e.g. for toilets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
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- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/2041—Dihydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Definitions
- the invention relates to an adhesive sanitary agent for cleaning and / or disinfecting and / or for fragrance delivery for sanitary objects such as toilet bowls.
- sanitary agents are viscous, generally pasty gels, which are applied from an appropriate container directly to the surface of the sanitary object and adhere there and can only be rinsed off after a large number of rinsing processes.
- Adhesive sanitary agents of this type are known from WO 99/66017. In addition to surfactants, water and fragrances, they also include adhesion promoters and are viscous, solid or pasty agents. It is also known from WO99 / 66017 that rigid gels can additionally comprise glycols and glycol derivatives.
- the known adhesive sanitary agents can be applied in a simple and hygienic manner with a suitable device, adhere to the upper surface of the sanitary article, retain their shape and are not washed down as a whole even under the influence of water, but are only completely dissolved after a large number of rinses.
- the present invention has for its object to provide an adhesive sanitary agent that maintains a handsome and smooth surface regardless of the flushing frequency of the toilet and in which the formation of poorly soluble residues due to drying is avoided.
- an adhesive sanitary agent consisting of surfactants, an adhesion promoter and water
- a smooth surface of the applied agent which is independent of the rinsing frequency can be achieved and the formation of a white encrusted surface of poorly soluble residues can be avoided if the agent additionally either at least a compound selected from the group consisting of glycerol, 1,3-dihydroxypropane, 1,3- or 1,4-dihydroxybutane, 1,3-dihydroxyisobutane, pentaerythritol or between 1 and 20% by weight, preferably between 5 and 15% by weight and particularly preferably comprises between 7 and 13% by weight of an aliphatic di-, oligo- or polyhydroxy compound or its ether.
- the addition of the humectant according to the invention also avoids the drying out of the surface observed in the known agents with the formation of poorly soluble residues.
- the use of the compounds according to the invention for the adhesive sanitary agents also has a positive effect on the life of the agent, because these compounds improve the dissolving behavior of the sanitary agent and thus reduce the amount of perfume to be used.
- the agent according to the invention achieves rinsing numbers of 100 to 150 rinses compared to rinsing numbers of up to 300 rinses in the known adhesive sanitary products. Rinsing numbers from 100 to 150 are desirable, since the agent is then to be renewed once a week for a 3 to 4 person household and, in addition, with a resolution of 1/100 to 1/150 of the agent per washing process, the individual active ingredients of the agent (including perfume) in the desired concentration. If - as with the known agents - rinsing times of up to 300 rinses are obtained, the concentration of the perfume must be increased in order to obtain the same scent impression per rinse.
- the humectants according to the invention also serve as solubilizers and accelerate the dissolution process of the agent and thus a constant release of the individual components of the sanitary agent in a concentrated form with each rinsing process.
- the rinsing behavior of the agent is significantly improved when using the humectants according to the invention compared to the use of sodium sulfate, which is used, for example, in WO 99/66017.
- the moisturizing agents according to the invention also have a positive influence on the consistency of the agent.
- Any aliphatic compound which has at least two hydroxyl groups can be used as the aliphatic di-, oligo- or polyhydroxy compound or its ether.
- aliphatic dihydroxy compounds include glycol, 1, 2- or 1, 3 dihydroxypropane, 1, 2-, 1, 3-, 2,3- or 1, 4-dihydroxybutane, the isomers of dihydroxyisobutane, the dihydroxypentanes etc.
- Trihydroxy compounds such as, for example, glycerol or longer-chain trihydroxy compounds, such as, for example, trihydroxyhexane, trihydroxyheptene, etc., can also be used as humectants.
- Pentaerythritol for example, can be used as the tetrahydoxy compound. Pentahydroxy, hexahydroxy, etc. can be considered as further oligohydroxy compounds. Sugar, polysaccharides such as starch, cellulose or polymers can also be used as oligo- or polyhydroxy compounds.
- ethers of di-, oligo- or polyhydroxy compounds as humectants, such as, for example, diethylene glycol, oligoethylene glycols such as triethylene glycol, but also polyhydroxyethers such as, for example, polymethylene or polyethylene glycol.
- the humectant according to the invention can have an even number, for example in the glycol, but also an odd number of carbon atoms, for example in the glycerol.
- Unbranched molecules such as glycol, but also branched molecules such as pentaerythritol, can also be used as humectants.
- the agent according to the invention has between 1 and 20% by weight, preferably between 5 and 15% by weight and particularly preferably between 7 and 13% by weight, of the aliphatic di-, oligo- or polyhydroxy compounds or their ether on. It is particularly preferred to use glycerol as the humectant.
- the adhesion promoter causes the agent to adhere to the surface. In general, it forms network-like structures that give the agent the required dimensional stability even under the strong force of rinsing water.
- the molecules of the coupling agent are longer or long chain, essentially elongated molecules which are at least partially hydrophilic and thus comprise at least one hydrophilic residue or a hydrophilic group which interacts with water.
- the adhesion promoters should preferably be unbranched molecules in order to enable the desired network formation.
- the coupling agent can either be overall hydrophilic or also partially hydrophilic, partially hydrophobic.
- Organic molecules with a hydrophilic and a hydrophobic end can be used as adhesion promoters.
- polyalkoxy groups preferably polyethoxy, polypropoxy or polybutoxy or also mixed polyalkoxy groups such as poly (ethoxypropoxy) groups can be used as hydrophilic groups.
- Anionic groups for example sulfonates, carbonates or sulfates, can also be used as the hydrophilic end.
- Stearates especially sodium or potassium stearate, are also suitable as adhesion promoters.
- adhesion promoter molecules also have a hydrophobic end, straight-chain alkyl radicals are particularly suitable for the hydrophobic radical, with even-numbered alkyl radicals being particularly preferred because of the better biodegradability.
- the molecules should be unbranched.
- alkyl groups are selected as the hydrophobic radicals, alkyl radicals having at least twelve carbon atoms are preferred. Particularly good results have been achieved with an alkyl chain length between 16 and 30 carbon atoms, in particular 16, 18, 20 and 22 carbon atoms.
- the adhesion promoters can also include alkylbenzene residues as hydrophobic residues, for example dodecylbenzene or similar residues, as is the case with the adhesion promoter sodium dodecylbenzenesulfonate.
- Preferred adhesion promoters are polyalkoxyalkanes, preferably a mixture of alkyl (C20-C20) ethoxylate with 35 EO or alkyl (C22) ethoxyate with 35 EO and alkyl (C16-C18) ethoxylate with 30 EO, but also alkyl sulfonates such as sodium dodecylbenzenesulfonate or alkyl carbonates or alkyl sulfates.
- the adhesion promoter becomes more lipophilic, which, for example, increases the solubility of perfume and thus the intensity of the fragrance.
- the concentration of the adhesion promoter to be used depends on its hydrophilicity and its ability to form networks. They can be, for example, 10 and 40% by weight, preferably between 15 and 35% by weight and particularly preferably between 20 and 30% by weight, which is particularly preferred when using polyalkoxyalkanes.
- water should be present in the formulation at least 20% by weight, preferably between 35 and 65% by weight, in particular between 40 and 60% by weight.
- the water content depends, among other things, on the hydrophilicity of the adhesion promoter used.
- the sanitary agent can comprise other customary constituents, for example perfume oil, disinfectants, preservatives, such as, for example, isothiazolone derivatives or foam stabilizers, such as coconut fatty acid amidopropyl betaine or coconut fatty acid amidopropyl dimethyl amine oxide, coconut fatty acid mono / diethanolate or lime ethersulfate or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether glycerol or alkyl polyether g
- olefin sulfonates ether sulfates and / or surfactants, in particular acid methyl taurides
- surfactants in particular acid methyl taurides
- salts such as sodium sulfate
- the salt content can be up to 10% by weight, preferably up to 5% by weight.
- the agent according to the invention can be applied and renewed in a hygienic manner without touching possibly contaminated devices connected to the toilet bowl.
- a major advantage of the agent according to the invention is that it can be portioned according to the wishes of the consumer. If the consumer desires more intensive scenting or if the toilet is used frequently, the dosage can be increased accordingly.
- the agent according to the invention can also be applied in a simple manner at the same time to different places on the sanitary object, for example in order to achieve a uniform cleaning action both on the right and on the left side of a toilet bowl.
- the agent according to the invention can also be applied in different compositions to a sanitary article at different locations. This makes it possible, for example, for two ingredients which are incompatible with one another, for example halogen-releasing agents and oxidation-sensitive perfuming substances, to be used for a common cleaning and / or scenting of the toilet by local separation.
- the adhesion achieved on the sanitary object is so good even when it is attached to a vertical surface that the agent does not become detached even under the additional action of flushing water flows.
- the sanitary agents according to the invention can only be rinsed off after a large number of rinsing processes.
- the number of flushing operations is of course dependent on the composition of the respective sanitary agent, the amount applied and the geometry of the sanitary agent applied.
- Fragrance and / or fragrance substances can also be added to the agent in order to improve the air in the room, and it is also contemplated that only fragrance and fragrance media be introduced into a toilet bowl in this way.
- the sanitary agent can also be used for other sanitary items such as urinals, urinals, but also for hand basins or the like.
- the agent according to the invention is preferably an ointment-like pasty and / or cream-like gel.
- the gels are essentially dimensionally stable so that they do not "run down” or "drip".
- These pasty gels preferably comprise about 1% by weight to 25% by weight, in particular 5 to 15% by weight, fragrances, 1% by weight to 20% by weight, in particular 5 to 10% by weight, anionic surfactants, 20% by weight .% to 40% by weight of adhesion promoter, between 1 and 20% by weight, preferably between 5 and 15% by weight, aliphatic di-, oligo- or polyhydroxy compounds or their ethers or the compound (s) from the group glycerol, 1, 3-dihydroxypropane, 1, 3- or 1, 4-dihydroxybutane, 1, 3-dihydroxyisobutane, pentaerythritol, 0% by weight to 1% by weight thickener and 0% by weight to 5% by weight, preferably between 0 and 1% by weight .%, Preservatives and about 35 to 65% by weight of water.
- ⁇ -olefin sulfonates, methyl taurides and ether sulfates are used in particular as anionic surfactants.
- alkyl (C12-C14) -plyethylene glycol (2EO) ether sulfate-triisopropanol-ammonium salt has proven itself as an anionic surfactant which also acts as a foamer.
- This anionic surfactant is preferred since, in contrast to olefin sulfonate or tauride, it does not leak even in higher concentrations.
- Alkyl (C16-C18) ethoxylate (30 EO) and alkyl (C22) ethoxylate (35 EO) are preferably used as adhesion promoters and nonionic surfactants.
- the agent further preferably comprises 0 to 3% by weight of amine oxides, such as, for example, coconut fatty acid amidopropyldimethylamine oxide (35%), which is available from Rewo / Goldschmidt as a foam stabilizer under the name Rewominox B204 and 0 to 2% by weight thickener, such as a polysaccharide, in particular a xanthan gum, which is available, for example, from Rhodia under the name Rhodopol T.
- isothiazonone derivatives can be used as preservatives.
- the gels can preferably be introduced into the toilet bowl through tubes, comparable to toothpaste tubes, syringes or cartridges, and remain there for a large number of successive flushing processes.
- the viscosities of these pasty gels to be determined on a Haake viscometer, plate-cone system, PK 5 1 ° sensor, shear rate of 25 s "1 and 20 ° C should be at least 15,000 mPas, usually at least 50,000 mPas, preferably at least 90,000 mPas and especially preferably at least 110,000 mPas.
- the viscosity at 20 ° C is approximately 120,000 mPas (Haake viscometer, plate-cone system, sensor PK 5 1 °, shear rate 25 s "1 ).
- Imbentin V100 from the company Dr. was used as alkyl (C22) ethoxylate (35EO) W. Kolb AG used as the alkyl (C16-C18) ethoxylate (30EO) the Imbentin 168S / 300 der Dr. W. Kolb GmbH AG, as alkyl (C12-C14) -polyethylene glycol- (2EO) - ether sulfate-triisopropanolammonium salt the marlinate 242/90 T from CONDEA GmbH, as isothiazolone derivatives the Parmetol K 40 from Schülke & Mayr and Citrix Extra F548373 from Quest International as a perfume.
- the agent according to the invention had a smooth and transparent surface of the gel until complete dissolution, even at a low rinsing frequency of four rinses per day.
- the dissolution process was largely independent of the rinsing frequency.
- the comparative agent had the following components:
- the viscosity is approximately 110,000 mPas at 20 ° C (Haake viscometer, plate-cone system, PK 1 ° sensor, shear rate 25 s "1 ).
- Hostapon T was 50% from Clariant as methyl tauride, Rewominox B 204 from Rewo / Goldschmidt as coconut fatty acid amidopropyldimethylamine oxide (35%), Rhodopol T from Rhodia as xanthan gum and Citrix II 98 as a perfume -1103 from Quest International.
- the foam numbers of the known agent were determined to be 60/60/50 ml under the above conditions.
- the surface of the known agent became gritty, uneven and furrowed at low rinsing frequencies, that is, at four rinses / day. After a long period of inactivity without rinsing, the surface of the applied adhesive sanitary agent hardened, it turned white and a poorly soluble residue was formed.
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- Detergent Compositions (AREA)
- Devices That Are Associated With Refrigeration Equipment (AREA)
- Endoscopes (AREA)
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Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01965164A EP1325103B1 (de) | 2000-09-29 | 2001-08-02 | Haftendes sanitärreinigungs- und beduftungsmittel |
DE50109091T DE50109091D1 (de) | 2000-09-29 | 2001-08-02 | Haftendes sanitärreinigungs- und beduftungsmittel |
AU2001285865A AU2001285865A1 (en) | 2000-09-29 | 2001-08-02 | Adhesive sanitary cleaning and deodorising product |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10048887A DE10048887A1 (de) | 2000-09-29 | 2000-09-29 | Haftendes Sanitärreinigungs- und Beduftungsmittel |
DE10048887.0 | 2000-09-29 |
Publications (1)
Publication Number | Publication Date |
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WO2002026925A1 true WO2002026925A1 (de) | 2002-04-04 |
Family
ID=7658505
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2001/008972 WO2002026925A1 (de) | 2000-09-29 | 2001-08-02 | Haftendes sanitärreinigungs- und beduftungsmittel |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1325103B1 (de) |
AT (1) | ATE318885T1 (de) |
AU (1) | AU2001285865A1 (de) |
DE (2) | DE10048887A1 (de) |
WO (1) | WO2002026925A1 (de) |
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Also Published As
Publication number | Publication date |
---|---|
AU2001285865A1 (en) | 2002-04-08 |
EP1325103B1 (de) | 2006-03-01 |
DE10048887A1 (de) | 2002-04-18 |
ATE318885T1 (de) | 2006-03-15 |
EP1325103A1 (de) | 2003-07-09 |
DE50109091D1 (de) | 2006-04-27 |
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