WO2001032756A1 - Coated hollow polyester molding, method of reclaiming the same, and solution for surface coating - Google Patents
Coated hollow polyester molding, method of reclaiming the same, and solution for surface coating Download PDFInfo
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- WO2001032756A1 WO2001032756A1 PCT/JP2000/007587 JP0007587W WO0132756A1 WO 2001032756 A1 WO2001032756 A1 WO 2001032756A1 JP 0007587 W JP0007587 W JP 0007587W WO 0132756 A1 WO0132756 A1 WO 0132756A1
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- Prior art keywords
- polyester
- hollow molded
- molded article
- coat layer
- weight
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J11/00—Recovery or working-up of waste materials
- C08J11/04—Recovery or working-up of waste materials of polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/044—Forming conductive coatings; Forming coatings having anti-static properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
- Y10T428/1393—Multilayer [continuous layer]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
Definitions
- the present invention relates to a coated polyester hollow molded article, a method for regenerating the same, and a solution for surface coating. More specifically, the present invention relates to a coated polyester hollow molded article having a coating which can be easily removed without adversely affecting the polyester hollow molded article itself, a method for regenerating the same, and a surface coating solution for forming the coating.
- PEN Polyethylene naphthalene dicarboxylate
- PET polyethylene terephthalate
- washing is performed using an aqueous sodium hydroxide solution (1 to 6%) at 50 to 100%.
- the PAN-based hollow molded article has a high surface hardness, it is easily damaged by the surface, and it is necessary to suppress the occurrence of surface damage for recovery and reuse.
- Japanese Patent Application Laid-Open No. H10-110107 discloses terephthalic acid and alkali metal sulphate.
- a method for producing a hot water-soluble polyester by subjecting an aromatic dicarboxylic acid containing a phonate group or a lower alkyl ester thereof to an esterification reaction or a transesterification reaction with an ethylene glycol, followed by melt polycondensation, and further by solid phase polymerization to produce a hot water-soluble polyester.
- the publication discloses that the hot water-soluble polyester produced can be used as a material for forming a pattern by dissolving a required portion with hot water after forming a woven fabric.
- Japanese Patent Application Laid-Open No. Hei 8-17664 discloses that a polyester containing an ion-dissociable group-containing dicarboxylic acid component and Z or an ion-dissociable group-containing glycol component in the molecular main chain of polyester is 51 mol% or more based on the total acid components.
- a water-soluble polyester having a polymerization temperature of 180 or more and less than 240 and having an intrinsic viscosity of 0.25 or more as measured at 35 in orthophenol phenol is disclosed. This publication discloses that this water-soluble polyester is useful for producing a low-charge easily adhesive polyester film useful for packaging materials, magnetic cards, magnetic tapes, magnetic disks, printing materials and the like.
- Another object of the present invention is to provide a surface coating solution used for producing the coated polyester hollow molded article of the present invention.
- Still another object of the present invention is to provide a recycling method for recycling and recycling the coated polyester hollow molded article of the present invention.
- the above-mentioned object and advantages of the present invention are, secondly, at least one kind of diamine selected from the group consisting of naphthodienedicarboxylic acid units and terephthalic acid units.
- Acid unit 7 to 20 mol% of the total dicarboxylic acid unit is used as the dicarboxylic acid component, and 65 to 95 mol% of the ethylene glycol unit and the total diol unit and 35 to 5 mol% of the diethylene glycol unit and the total diol unit.
- a solution for surface coating of a polyester hollow molded article comprising 1 to 40% by weight of a polyester having a diol unit of 5 to 5% by mole, and a surfactant of 0.1 to 0.1% by weight and a liquid medium. Is done.
- a recovered coated polyester hollow molded article of the present invention is prepared, a polyester coat layer is removed from the hollow molded article, and a polyester coat layer is formed.
- the present invention is achieved by a method for regenerating a coated polyester hollow molded article, characterized in that a polyester coat layer is newly provided on the surface of the hollow molded article from which is removed.
- the coated polyester hollow molded article of the present invention will be described.
- the hollow polyester molded article (A) constituting the coated polyester hollow molded article is preferably an aromatic polyester, more preferably an ethylene-2,6-naphthalenedicarboxylate unit and an ethylene terephthalate unit.
- the repeat unit chosen comprises an aromatic polyester which makes up at least 85 mol% of the total repeat units.
- the aromatic polyesters can be used alone or as a blend of two or more.
- polyethylene terephthalate and polyethylene-1,6-naphthalenedicarboxylate are particularly preferred.
- the intrinsic viscosity of the aromatic polyester is preferably from 0.5 to 1.0, more preferably from 0.55 to 0.8, particularly preferably from 0.55 to 0.75. If the intrinsic viscosity is less than 0.5, the blowability is poor, and it is difficult to obtain a molded body having a uniform thickness. If the intrinsic viscosity is more than 1.0, the stretching stress is high, which may cause haze, which is preferable. Absent.
- the polyester hollow molded body main body made of the polyester can be produced by molding by applying a known ordinary molding method. Examples of applicable molding methods include a biaxial stretching blow method (a cold parison method and a hot parison method), an injection blow method, and a direct blow method. In addition, a molding method in which the polyester is formed into a sheet-like molded product and then processed into a hollow molded product may be applied.
- the polyester hollow molded product may be a bottle.
- the polyester coat layer (B) on the outer surface of the polyester hollow molded article preferably has a weight reduction rate of 3% by weight or less when treated with water at 25 for 2 hours and 75% or less. It is removed when treated with an alkaline aqueous solution of pH 1.6 for 9 minutes.
- the polyester hollow molded article is distributed and used on the market as a container, and may come into contact with water during this time. Also, the coat layer is substantially retained. If the rate of decrease is larger than this range, the coat layer substantially peels off or peels off, causing problems in appearance. This weight loss rate is more preferably 2% by weight or less.
- the coating is easily removed under alkaline conditions in the washing step from the polyester hollow molded article that has been distributed and used as a container. can do.
- the coating can be removed with an aqueous alkaline solution under such conditions, the coating is often, for example, 60-; LOOt: preferably hot water at 70-95, such as pH5. It can likewise be removed with 5 to 8.5, preferably 6 to 8, hot water.
- a preferred polyester coat layer (B) having such properties has at least one dicarboxylic acid unit selected from the group consisting of a naphthylene dicarboxylic acid unit and a terephthalic acid unit in a proportion of 92.999 to the total dicarboxylic acid unit. 60 mol%, isofluoric acid unit 0.01 to 20 mol% based on the total dicarboxylic acid unit and isofluoric acid unit having a sulfonic acid metal salt group based on the total dicarboxylic acid unit?
- Polyester containing up to 20 mol% of dicarboxylic acid component, and 65 to 95 mol% of ethylene glycol unit to all diol units and 35 to 5 mol% of diethylene glycol unit to all diol units.
- Consists of Examples of the naphthalenedicarboxylic acid unit include 2,6-naphthalenedicarboxylic acid and 2,7-naphthalenedicarboxylic acid, and 2,6-naphthalenedicarboxylic acid is preferred.
- Naphthalenedicarboxylic acid units and terephthalic acid units may be derived from ester derivatives.
- the ester derivative include methyl ester, ethyl ester, propyl ester, and butyl ester, with methyl ester being preferred.
- At least one unit selected from naphthalenedicarboxylic acid units and terephthalic acid units is 60 to 92.99 mol% per total dicarboxylic acid component. If it is less than 60 mol%, the water resistance of the polyester will decrease, and if it exceeds 92.99 mol%, the solubility in hot water will decrease. Further, from the viewpoint of hot water solubility, the naphthalenedicarboxylic acid unit is preferably 50 mol% or less of all dicarboxylic acid components.
- the naphthene dicarboxylic acid unit is preferably from 0 to 50 mol%, more preferably from 0 to 30 mol%, particularly preferably from 0 to 30 mol%, based on all dicarboxylic acid components. ⁇ 10 mol%.
- isophthalic acid unit examples include esters such as methyl, ethyl, propyl, and butyl as isophthalic acid and derivatives thereof.
- the isophthalic acid unit is from 0.01 to 20 mol%, preferably from 0.01 to 15 mol%, particularly preferably from 5 to 10 mol%, based on all dicarboxylic acid components. If it is less than 0.01 mol%, the crystallinity of the polyester is too high. If it exceeds 20 mol%, the polymerization reactivity and the crystallinity will be greatly reduced.
- Examples of the isophthalic acid unit having a sulfonic acid metal base include 5-lithium sulfoisophthalic acid, 5-sodium sulfoisophthalic acid, and 5-potassium sulfoisophthalic acid, with 5-sodium sulfoisophthalic acid being preferred. .
- the derivative is, for example, an ester, and examples thereof include methyl ester, ethyl ester, propyl ester, and butyl ester, with methyl ester being preferred.
- the isofluric acid unit having a sulfonic acid metal base is present in an amount of 7 to 20 mol%, preferably 8 to 15 mol%, particularly preferably 9 to 13 mol%, based on the total dicarboxylic acid component. is there. If it is less than 7 mol%, the hot water-soluble resin is sufficient, and if it exceeds 20 mol%, the reactivity during polymerization is poor, and the melt viscosity becomes too high, resulting in poor productivity.
- Ethylene glycol units are 65-95 mole% per total diol component.
- the diethylene glycol units are from 5 to 35 mol%, preferably from 10 to 35 mol%, particularly preferably from 10 to 25 mol%, based on the total diol component. If it is less than 5 mol%, the solubility in hot water decreases, and if it exceeds 35 mol%, deterioration by heat is large.
- the diethylene dalicol unit may be derived from the diethylene dalicol component added at the time of polymerization, or may be produced by a polymerization reaction.
- polyester of the polyester coat layer (B) isophthalic acid units having a sulfonic acid metal salt group account for 8 to 15 mol% of all dicarboxylic acid units, and ethylene glycol units correspond to all diol units. Polyesters that are 75 to 95 mol%, on the other hand, are preferred.
- Such polyesters preferably have an intrinsic viscosity of 0.2 to 0.5, more preferably 0.25 to 0.45. If the intrinsic viscosity is less than 0.2, it is difficult to form a chip at the time of polymerization, and the strength is unfavorably low. If it exceeds 0.5, productivity during polymerization is poor and hot water solubility is poor, which is not preferable.
- the glass transition temperature of such polyesters is preferably in the range of 55 to 90.
- polyesters of the polyester coat layer (B) in particular, the following properties (1), (2) and (3);
- the water solubility of 95 is 10% by weight or more
- the polyester having the above can eliminate the concern of contamination of the contents of the hollow molded article, and can maintain good transparency and a substantially scratch-free surface even when the hollow molded article is collected and reused.
- the functionality of the polyester coat layer (B) can be increased.
- Such a polyester can be produced by the following method.
- Terephthalic acid or its ester-forming derivative preferably, dimethyl ester
- isophthalic acid or its ester-forming derivative preferably, dimethyl ester
- isophthalic acid having a sulfonic acid metal base or its ester-forming derivative
- isophthalic acid having a sulfonic acid metal base or its ester-forming derivative
- dimethyl ester 2,6-naphthalenedicarboxylic acid or an ester-forming derivative thereof (preferably, dimethyl ester) and ethylene glycol (optionally, diethylene glycol is added)
- ethylene glycol optionally, diethylene glycol is added
- cobalt manganese, calcium, magnesium, Z or a titanium compound as a catalyst.
- an alkali metal As the alkali metal, lithium, sodium and potassium are preferable, and sodium is particularly preferable.
- the amount of addition is preferably 100 to 400 mmol, more preferably 100 to 250 mmol, based on 100 mol of all dicarboxylic acid components.
- a polycondensation reaction is carried out under heating and vacuum in the presence of a germanium, antimony and / or titanium catalyst and a phosphorus compound.
- inorganic phosphoric acid such as orthophosphoric acid, hypophosphorous acid, and phosphorous acid
- organic phosphoric acid such as trimethyl phosphate
- the polymer is used in the form of chips or pellets, or in the form of blocks, and ground.
- the coat layer can be formed by applying the polyester for surface coating as a liquid coating liquid to at least the outer surface of the polyester hollow molded article main body and drying.
- the solution for surface coating of the present invention contains 1 to 40% by weight of the polyester for surface coating in the coating solution. If it is less than 1% by weight, it is difficult to form a film, and if it exceeds 40% by weight, it becomes highly viscous and difficult to handle.
- a solution comprising 1 to 40% by weight of a ester, 0.1 to 10% by weight of a surfactant and a liquid medium.
- an ionic or nonionic surfactant can be used.
- Preferred are polyethylene glycol and polyoxyethylene sorbine alkylate. It is also preferable to use these surfactants in combination. That is, in a preferred embodiment of the present invention, the surfactant is polyethylene glycol and polyoxyethylene sorbitan alkylate, and the weight ratio of both is preferably 1 from the viewpoint of film forming property and aqueous property at the time of coating. 0: 1 to 1: 5, more preferably 10: 1 to 1: 2.
- the surfactant is contained in an amount of 0.1 to 10% by weight, preferably 0.1 to 5% by weight.
- a surfactant within this range, the wettability when applying the coating liquid for forming the coating layer is improved, and the formed coating layer is removed with hot water or an alkaline aqueous solution. Becomes easier. If it exceeds 10% by weight, solubility in water at normal temperature increases.
- polyethylene glycol those having a low viscosity in a liquid state are preferable, and those having a molecular weight of from 200 to 1,000 are particularly preferable.
- polyoxyethylene sorbitan alkylate polyoxyethylene sorbitan acetate, polyoxyethylene sorbitan stearate, and polyoxyethylene sorbitan palmitate are preferred, and particularly, polyoxyethylene sorbitan alcoholate is preferred.
- the surface coating solution is preferably made into an aqueous solution or dispersion by dissolving or dispersing the above-mentioned components in water.
- dissolving or dispersing it is preferable to use hot water, preferably 60 to 100 hot water, from the viewpoint of hygiene and safety of handling.
- the polyester for surface coating is converted into hot water, preferably hot water at 60 to 100 hours, preferably within 20 hours, more preferably within 10 hours, particularly preferably within 3 hours. Dissolve with. This is from the viewpoint of suppressing hydrolysis.
- the concentration at this time is preferably 1 to 40% by weight, more preferably 5 to 20% by weight. % By weight. Further, the concentration is appropriately adjusted within this range depending on the coating method and the coating film thickness. If it is less than 1% by weight, the coating film thickness is thin and non-uniform, which is not preferable. If the content exceeds 40% by weight, the amount of the undissolved insoluble in hot water increases, and the viscosity of the solution increases.
- a polyester for surface coating is dissolved in an organic solvent such as ethanol, methanol, isopropyl alcohol, black form, acetone, methyl ethyl ketone, and ethyl acetate at a high concentration, and then mixed with water. This makes it possible to use a dispersing method.
- the surfactant only needs to be contained in the surface coating solution, and may be added at any stage.
- the surface coating solution of the present invention preferably has a haze value of 30% or less at 25, a pH of more than 5 and less than 7, and a viscosity of 0.5 Pas or less,
- the electric conductivity is 100 to 4, 000 i SZ cm.
- the surface coating solution of the present invention can contain at least one agent selected from the group consisting of an ultraviolet absorber and a colorant.
- the surface coating solution of the present invention is also novel for the surface coating of a polyester hollow molded article.
- a surface coating solution comprising 1 to 40% by weight of the above specific polyester of the present invention, 0.1 to 10% by weight of a surfactant and a liquid medium.
- Use of polyester hollow moldings for coating is also provided.
- the coating layer formed by using the surface coating solution of the present invention has an effect of preventing the occurrence of scratches on the outer surface of the hollow molded article, filling small scratches and preventing the appearance from being impaired. Further, it has an ultraviolet absorbing ability and has an effect of suppressing deterioration of polyethylene naphthalenedicarboxylate of the polyester hollow molded article due to ultraviolet rays during use, collection and storage.
- the polyester hollow molded article of the present invention having this coat layer has a body with a haze of preferably 5% or less, more preferably 2% or less at a thickness of 300 / zm. If the haze exceeds 5%, the transparency is low and the polyester hollow molded body When used as a bottle to be filled, the appearance of value as a product is impaired, which is not preferable.
- the thickness of the coat layer is preferably 0.1 to 10 / zm, more preferably 0.1 to 5, more preferably 0.2 to 2; m. If it is less than 0.1 / xm, the effect of suppressing light deterioration due to coating on the surface of the hollow molded article is low, which is not preferable. Absent.
- the coating layer can contain 5 to 50 parts by weight of a surfactant based on 100 parts by weight of the polyester derived from the surfactant contained in the coating solution.
- this coat layer is renewed by removing and regenerating each time the polyester hollow molded article is used repeatedly.
- the recovered coated polyester hollow molded article of the present invention is prepared, the polyester coat layer is removed from the hollow molded article, and the polyester coat layer is removed.
- the present invention provides a method for regenerating a coated polyester hollow molded article, which comprises providing a new polyester coat layer on the surface of the hollow molded article.
- the step of removing the coat layer is preferably a step including washing with heated water or an aqueous solution of water, and washing with water thereafter.
- the temperature of the water or the alkaline aqueous solution used for removing the coat layer in the washing with the heated water or the alkaline aqueous solution is preferably from 60 to 100 :, more preferably from 65 to 95. If it is lower than this, sufficient cleaning cannot be performed, the coat layer cannot be sufficiently removed, and further, a bactericidal effect cannot be expected, which is not preferable. If it is higher than this, thermal deformation of the polyester hollow molded article is caused, which is not preferable. If an aqueous solution is used, sodium hydroxide is preferably used at a concentration of 1 to 6%.
- Washing with water followed by washing with warm water or aqueous solution is preferred. Preferably at 95 use the following water. This washing may be sufficient to sufficiently wash away the alkaline aqueous solution.
- the polyester hollow molded article is regenerated by forming a coat layer on the polyester hollow molded article from which the coat layer has been removed and updating the coat layer.
- the method for forming the coat layer may be the same as the method for forming the coat layer used when manufacturing the polyester hollow molded article.
- the above-mentioned surface coating solution of the present invention is preferably used.
- the renewal of the coat layer is preferably performed every time the polyester hollow molded article is used repeatedly. That is, the polyester hollow molded article is preferably regenerated by the above-mentioned regenerating method every time it is reused.
- the polyester hollow molded article can be used repeatedly by renewing the coat layer by this regenerating method.
- the body has a haze of 5% or less at a thickness of 300 at the time of repeated use 20 times, more preferably 5% or less. It can be less than 2%.
- the polyester hollow molded body is exposed to the ultraviolet rays of sunlight, and the amount is 7,500 mJZcm 2 to 90,000 m in the ultraviolet ray in the wavelength range of 310 nm to 400 nm in one repeated use. J Zcm 2 is estimated.
- the solution for surface coating was applied to a PEN film, and the wetting property at this time was evaluated. Furthermore, the coating layer was formed by air drying after coating, and the surface condition of the coating layer was evaluated.
- the solution for surface coating is dried in an evaporator to measure the intrinsic viscosity as a solid. And the initial intrinsic viscosity.
- the surface coating liquid of Reference Example 1 was kept at 100 at 2 hours, and then dried in an evaporator to obtain a solid, and the intrinsic viscosity was measured to obtain the final intrinsic viscosity.
- the stability of the surface coating solution was calculated using the following equation.
- a 4 cm x 4 cm test piece was cut from the bottle body (about 300 im thick). When there was a surface coat layer, the entire surface coat layer was cut out.
- test piece was irradiated with ultraviolet light for 4 hours using a xenon tester (Shimadzu Xenon Tester XW-150).
- the amount of exposure of the test piece to ultraviolet light was measured with a MIN-10RUTA UV intensity meter UM-10 (light receiving unit UM-250, 360).
- the test piece was set on a turbidity meter (manufactured by Nippon Denshoku Kogyo Co., Ltd., Color and color dir e fer en c e me ter, MODEL 1001 DP), and the haze was measured.
- Example 1 (Production of polyester for surface coating and solution for surface coating) Dimethyl terephthalate (hereinafter abbreviated as DMT) 100 parts by weight, dimethyl 5-sodium sulfoisophthalate (hereinafter sometimes abbreviated as K 2) 19 parts by weight, dimethyl isophthalate (hereinafter sometimes abbreviated as K 2) Hereinafter, it may be abbreviated as DMI.
- DMT dimethyl terephthalate
- K 2 dimethyl 5-sodium sulfoisophthalate
- K 2 dimethyl isophthalate
- DMI dimethyl isophthalate
- ethylene glycol hereinafter may be abbreviated as EG 72 parts by weight
- EG ethylene glycol
- the remaining methanol was distilled out of the system and subjected to transesterification while heating to 250.At the stage when methanol was almost completely distilled, antimony trioxide was added as a polymerization catalyst. Then, trimethyl phosphate was added as a stabilizer to terminate the ester exchange reaction.
- the reaction product is then subjected to a polycondensation reaction under a high temperature and high vacuum to obtain a polymer having an intrinsic viscosity of 0.40 (in a mixed solvent of 2 parts by weight of tetracloane and 3 parts by weight of phenol, 25).
- a polymer having an intrinsic viscosity of 0.40 in a mixed solvent of 2 parts by weight of tetracloane and 3 parts by weight of phenol, 25).
- polyester A for surface coating was obtained.
- This polyester A for surface coating is dissolved in hot water at 95 so as to have a concentration of 10% by weight as a solution for surface coating, and further, a molecular weight of 20% by weight is used as a solution for surface coating.
- 0 polyethylene glycol and 0.5% by weight of polyoxyethylene sorbitol were added to form a surface coating solution under the conditions shown in Table 1.
- the surface coating solution was evaluated. The results are shown in Tables 1 and 2.
- the coat layer formed using the surface coating solution did not dissolve in the warm water at 35 and did not peel off.
- Example 2 In the same manner as in Example 1, a polyester for surface coating was obtained with the composition shown in Table 1, and was used as a solution for surface coating under the conditions shown in Tables 1 and 2. The surface coating solution was evaluated. The results are shown in Tables 1 and 2.
- Polyester of a polyester hollow molded article was produced by the method of Reference Example 1 below.
- the reaction product was subjected to a polycondensation reaction under high temperature and high vacuum to obtain a prevolimer having an intrinsic viscosity of 0.50 (in a mixed solvent of 2 parts by weight of tetrachloroethane and 3 parts by weight of phenol, 25). .
- a prevolimer having an intrinsic viscosity of 0.50 in a mixed solvent of 2 parts by weight of tetrachloroethane and 3 parts by weight of phenol, 25).
- this prepolymer into a strand type chip
- it is further subjected to solid-state polymerization under heating vacuum to obtain an intrinsic viscosity (a mixed solvent of 2 parts by weight of phenol and 3 parts by weight of phenol, 35).
- an intrinsic viscosity a mixed solvent of 2 parts by weight of phenol and 3 parts by weight of phenol, 35.
- a thermoplastic polyester was obtained as a solid-phase polymerized polymer.
- the reaction product was subjected to a polycondensation reaction under a high temperature and high vacuum to obtain a prepolymer having an intrinsic viscosity (a mixed solvent of 2 parts by weight of tetracloane and 3 parts by weight of phenol, 25) of 0.50.
- a prepolymer having an intrinsic viscosity a mixed solvent of 2 parts by weight of tetracloane and 3 parts by weight of phenol, 25
- an intrinsic viscosity a mixed solvent of 2 parts by weight of phenol and 3 parts by weight of phenol, with 35.
- the reaction product was subjected to a polycondensation reaction under high temperature and high vacuum to obtain a prepolymer having an intrinsic viscosity (a mixed solvent of 2 parts by weight of tetrachloroethane and 3 parts by weight of phenol, at 25 ° C.) of 0.57.
- a prepolymer having an intrinsic viscosity (a mixed solvent of 2 parts by weight of tetrachloroethane and 3 parts by weight of phenol, at 25 ° C.) of 0.57.
- this prepolymer is further subjected to solid phase polymerization under heating vacuum to obtain an intrinsic viscosity (in a mixed solvent of 2 parts by weight of tetrachloroethane and 3 parts by weight of phenol, 25) of 0.83.
- a thermoplastic polyester as a solid-phase polymer was obtained.
- 2, 6-Dimethyl naphthalenedicarboxylate 88 parts by weight, 9.6 parts by weight of dimethyl terephthalate and 70 parts by weight of ethylene glycol by-produced using cobalt acetate and manganese acid as transesterification catalysts
- Methanol was distilled out of the system and transesterification was carried out while heating to 250.At the stage when methanol was almost completely distilled off, antimony trioxide was added as a polymerization catalyst, and trimethyl phosphate was subsequently used as a stabilizer. Was added to terminate the transesterification reaction.
- the reaction product is subjected to a polycondensation reaction under high temperature and high vacuum to obtain a prepolymer having an intrinsic viscosity of 0.44 (in a mixed solvent of 2 parts by weight of tetrachlorobenzene and 3 parts by weight of phenol, 25).
- a prepolymer having an intrinsic viscosity of 0.44 in a mixed solvent of 2 parts by weight of tetrachlorobenzene and 3 parts by weight of phenol, 25).
- the intrinsic viscosity a mixed solvent of 2 parts by weight of phenol with trichloride and 3 parts by weight of phenol, with 35
- Polyesters B and C for surface coating were produced by the methods of Examples 13 and 14 below.
- the resulting reaction product was subjected to a polycondensation reaction under high temperature and high vacuum to obtain a polymer having an intrinsic viscosity of 0.35 (in a mixed solvent of 2 parts by weight of tetracloane and 3 parts by weight of phenol, at 25). Using this polymer as a strand type chip, polyester B for surface coating was obtained.
- the resulting reaction product was subjected to a polycondensation reaction under high temperature and high vacuum to obtain a polymer having an intrinsic viscosity of 0.30 (mixed solvent of 2 parts by weight of tetrachloroethane and 3 parts by weight of phenol, 25). Using this polymer as a strand type chip, polyester C for surface coating was obtained.
- a preform of a hollow molded body was injection-molded, and then the preform was heated and oriented blown to form a pottle.
- the preform was molded using an M100 DM molding machine manufactured by Meiki Seisakusho (cylinder setting: 290, screw rotation speed: 160 rpm, molding cycle: 30 sec), and the average body thickness of the preform was 4.2 mm. The weight was about 55.
- the bottle was molded with LB01 manufactured by K RUPP CORPOPLAST, and the bottle had an inner volume of about 1.5 L (liter), an average body thickness of about 300 wm, and a haze of 0.7%.
- Coating solutions 1 to 8 were prepared with the compositions shown in Table 3. One of coating liquids 1 to 8 was applied to the outer surface of the above bottle and air-dried to form a surface coat layer having a thickness of about 1 m, thereby producing a bottle having a surface coat layer. The test piece was cut out from the bottle.
- the test piece was irradiated with ultraviolet rays by the above method, and further washed by the above method to remove the surface coating layer. In this state, the operation of forming a surface coat layer again, irradiating with ultraviolet rays, and washing was repeated a total of 20 times in the same manner as in the preparation of the initial surface coat layer.
- the surface coat layer of the bottle provided with the original surface coat layer and the surface coat layer of the test piece could not be removed with water (pH 6.5) of 25 (35 or less). Was completely removed in the washing.
- Examples 25 to 28 A bottle was prepared in the same manner as in Example 1 using the polyesters of Reference Examples 2 to 5 as the polyester of the bottle, and a bottle having a surface coat layer was prepared and similarly evaluated. The results are shown in Tables 3 and 4.
- a preform was injection molded using the polymer, and then the preform was heated and then oriented blown to form a bottle.
- the preform was molded using a Miki ODM molding machine manufactured by Meiki Seisakusho (cylinder setting: 290, screw rotation speed: 160 rpm, molding cycle: 30 sec), and the average body thickness of the preform was 4.2 mm.
- the weight was about 55 g.
- the bottle was molded from KRUPP CORPOPLA ST's LB O1, and the bottle had an internal volume of about 1.5 L (liter), an average body thickness of about 300 m, and a haze of 0.7%. No coat layer was formed.
- the operation of irradiating the test piece with ultraviolet rays by the above method and further washing it by the above method was repeated 20 times. The haze at 20 repetitions was measured. Table 4 shows the results.
- This polymer was formed into a strand-shaped pellet (a column with a height of 3.5 mm, a short diameter of the bottom surface of 2.5 mm and a long diameter of 3.5 mm).
- thermoplastic polyester was obtained under the conditions shown in Table 5 and evaluated.
- Rats indicate 2,6-naphthalene 'flavor' xylate.
- thermoplastic polyester Using 1 Omg of thermoplastic polyester as a sample, the measurement was performed by DSC at a heating rate of 5 ° C. Zmin.
- thermoplastic polyester Pellets of thermoplastic polyester (3.5 mm high, cylindrical with a minor axis of 2.5 mm at the bottom and a major axis of 3.5 mm) are dissolved in excess water and dissolved in a thermoplastic polyester solution. And The obtained solution was passed through a sieve having an opening of 100 m to remove solids.
- the amount of the thermoplastic polyester in the solution after removing the solid content is defined as (the amount of the thermoplastic polyester used)-(the amount of the thermoplastic polyester removed as a solid content), and the concentration of the thermoplastic polyester in the solution.
- thermoplastic polyester dissolved to a concentration of 10% in water at 95 1 (1% of a thermoplastic polyester dissolved to a concentration of 10% in water at 95 at 95 ° C) (Intrinsic viscosity after holding for a time).
- thermoplastic polyester The intrinsic viscosity of the thermoplastic polyester was measured on a sample dried by removing water with a vacuum dryer.
- Example 29 The polymer prepared in Example 29 was dissolved in water at 95 so that the concentration of the polymer prepared in Example 29 was 10% by weight, and the solution was filtered through a sieve having openings of 150 mm, 77 Aim and 45 / xm in order. Thus, a liquid composition was produced. Table 6 shows the evaluation results of the liquid composition. Using this liquid composition, a coat layer was formed by spray coating on a 38 Oml capacity bottle made of Teijin's polyethylene naphthalate resin (brand name: TN 8065). This coat layer did not dissolve in water at 30 and did not peel off, but the coat layer was removed by washing with warm water at 75 C for 15 minutes.
- TN 8065 Teijin's polyethylene naphthalate resin
- Example 44 In the same manner as in Example 43, a thermoplastic polyester having a composition shown in Table 6 was obtained to produce a liquid composition. Table 6 shows the evaluation results of the liquid composition.
- thermoplastic polyester having a composition shown in Table 6 was obtained to produce a liquid composition.
- Table 6 shows the evaluation results of the liquid composition.
- a coat layer was formed by spray coating on a 380 ml bottle of polyethylene naphthalate resin (brand name: TN8605) manufactured by Teijin Limited. This coat layer did not dissolve in water at 30 and did not peel off, but the coat layer was removed by washing with warm water at 75:15 minutes.
- polyethylene naphthalate resin brand name: TN8605
- DC indicates 2,6-naphthalene / methylcarboxy'xylate.
- thermoplastic polyester A certain amount of thermoplastic polyester is dissolved in 95 hot water. This liquid was sequentially filtered through sieves having openings of 150 m, 77 m, and 45 m to prepare a liquid composition. The concentration of the thermoplastic polyester in the liquid composition was calculated from the remaining solid content after evaporating the liquid to dryness.
- tinuvin 234 (manufactured by Ciba Specialty Chemicals) is dissolved in acetone or black-mouthed form, mixed with the above-mentioned polyester-containing solution with stirring, and the temperature is gradually raised to 95. The liquid composition was adjusted after removal.
- the liquid composition was put into a sampler, and measured with Co1 or r and colol or differ enc e me ter MODEL; 1001 DP manufactured by Nippon Denshoku Industries Co., Ltd.
- the liquid polyester was put into a sampler, and measured with a pH meter F-14 (25 ° C) manufactured by H ⁇ RIBA.
- the liquid composition was placed in a sampler, and measured with a single-cylindrical rotational viscometer Bis Metron VS-A1 (at 25) manufactured by Shibaura System Co., Ltd.
- the liquid composition was put into a sampler and measured with an electric conductivity meter CM-21P (at 25) manufactured by Toa Denpa Kogyo Co., Ltd.
- Tinuvin 234 (manufactured by Ciba Specialty Chemicals) was dissolved in acetone to a concentration of 0.5% by weight to form a solution, and an equal amount of the liquid composition of Example 43 was stirred and mixed. To 95, remove the acetone, The product was adjusted.
- a coat layer was formed by a spray coating method on a 380 m1 volume bottle composed of a polyethylene naphthalate resin (brand name: TN8065) manufactured by Teijin Limited.
- the coat layer did not dissolve in water at 30 and did not peel off, but at 75 the coat layer was removed by a 15 minute warm water wash.
- liquid composition was sprayed on a polyethylene naphthalate resin (brand name: TN8065) chip manufactured by Teijin Limited to form an ultraviolet absorber-containing layer on the surface.
- a polyethylene naphthalate resin brand name: TN8065
- Teijin Limited Teijin Limited to form an ultraviolet absorber-containing layer on the surface.
- a 380 ml bottle of this tip was uniformly formed containing a UV absorber.
- Tinuvin 234 (manufactured by Ciba Specialty Chemicals) was dissolved in chloroform at a concentration of 5% by weight to form a solution, and an equal amount of the liquid composition of Example 43 was stirred and mixed. Then, the temperature was raised to 95 to remove the black form, thereby preparing a liquid composition.
- Teijin's polyethylene naphthalate resin (brand name: TN8065) was supplied from the top feed of a twin-screw open 2 vent, vacuum 2 vent extruder and melted.
- the liquid composition was added to the molten portion of the resin using a metering injection machine. Open vents were placed before and after the dosing machine to remove water as a solvent. Next, the residual solvent and the polyester decomposition gas were removed by two vacuum vents, and the resin was discharged in the form of a strand to form chips.
- the chip was molded to form a pot containing 380 ml of UV absorber uniformly.
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020017008361A KR20010082773A (ko) | 1999-11-02 | 2000-10-27 | 피복 폴리에스테르 중공성형체, 이의 재생방법 및 표면코팅용 용액 |
US09/869,609 US6627280B1 (en) | 1999-11-02 | 2000-10-27 | Coated hollow polyester molding, method of reclaiming the same, and solution for surface coating |
EP00970170A EP1153963A4 (en) | 1999-11-02 | 2000-10-27 | COATED HOLLOW POLYESTER MOLDING, METHOD FOR RECOVERING THE SAME, AND SOLUTION FOR SURFACE TREATMENT |
NO20013295A NO20013295L (no) | 1999-11-02 | 2001-07-02 | Belagt polyester hulstopt produkt, fremgangsmate ved regenerering og overflatebelegningslosning derfor |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31217599A JP3809040B2 (ja) | 1999-11-02 | 1999-11-02 | ポリエステル製中空成形体、その再生方法および製造方法 |
JP11/312175 | 1999-11-02 | ||
JP11/312174 | 1999-11-02 | ||
JP31217499A JP3909178B2 (ja) | 1999-11-02 | 1999-11-02 | 表面コート液およびその製造方法 |
Publications (1)
Publication Number | Publication Date |
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WO2001032756A1 true WO2001032756A1 (en) | 2001-05-10 |
Family
ID=26567050
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Application Number | Title | Priority Date | Filing Date |
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PCT/JP2000/007587 WO2001032756A1 (en) | 1999-11-02 | 2000-10-27 | Coated hollow polyester molding, method of reclaiming the same, and solution for surface coating |
Country Status (6)
Country | Link |
---|---|
US (1) | US6627280B1 (ja) |
EP (1) | EP1153963A4 (ja) |
KR (1) | KR20010082773A (ja) |
NO (1) | NO20013295L (ja) |
TW (1) | TWI256958B (ja) |
WO (1) | WO2001032756A1 (ja) |
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CN101048275A (zh) * | 2004-08-31 | 2007-10-03 | 因维斯塔技术有限公司 | 具有低雾度的聚酯-聚酰胺共混物 |
US20110256311A1 (en) * | 2010-04-15 | 2011-10-20 | The Coca Cola Company | Method of coating a container using a semi-permanent coating composition capable of blocking ultraviolet light |
CN111378102B (zh) * | 2020-04-22 | 2022-06-10 | 江门市制漆厂有限公司 | 一种耐水解的水性聚酯树脂及其制备方法和应用 |
Citations (6)
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JPS5131879B1 (ja) * | 1966-02-28 | 1976-09-09 | ||
JPH06134950A (ja) * | 1992-10-23 | 1994-05-17 | Toray Ind Inc | 易接着性ポリエステルフィルム |
JPH06263902A (ja) * | 1993-03-11 | 1994-09-20 | Toray Ind Inc | 易接着性ポリエステルフィルム |
US5391429A (en) * | 1992-01-07 | 1995-02-21 | Diafoil Hoechst Company, Limited | Polyester film |
JPH08225672A (ja) * | 1994-12-09 | 1996-09-03 | Teijin Ltd | ポリエチレンナフタレート成形体の蛍光防止方法 |
JPH1148429A (ja) * | 1997-07-31 | 1999-02-23 | Toyobo Co Ltd | ポリエステル樹脂多層成形体 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5131879A (en) | 1974-09-12 | 1976-03-18 | Takara Mfg Co Ltd | Suraidosuitsuchi no kirikaehoshiki |
US4482586A (en) * | 1982-09-07 | 1984-11-13 | The Goodyear Tire & Rubber Company | Multi-layer polyisophthalate and polyterephthalate articles and process therefor |
US4643925A (en) * | 1982-09-07 | 1987-02-17 | The Goodyear Tire & Rubber Company | Multi-layer polyisophthalate and polyterephthalate articles and process therefor |
US4604257A (en) * | 1982-09-07 | 1986-08-05 | The Goodyear Tire & Rubber Company | Multi-layer polyisophthalate and polyterephthalate articles and process therefor |
JPS61243833A (ja) * | 1985-04-19 | 1986-10-30 | Nippon Synthetic Chem Ind Co Ltd:The | ガス遮断性のすぐれたポリエステル成形物の製造法 |
JPH04366164A (ja) * | 1991-06-13 | 1992-12-18 | Toyobo Co Ltd | 水系分散体 |
JP3537152B2 (ja) | 1993-02-17 | 2004-06-14 | 日本合成化学工業株式会社 | コーティング用組成物 |
JPH08176284A (ja) | 1994-12-22 | 1996-07-09 | Teijin Ltd | 水溶性ポリエステル及びその製造法 |
US5769126A (en) * | 1996-09-12 | 1998-06-23 | Samsung Electronics Co., Ltd. | Discharge valve assembly in a reciprocating compressor |
DE19921885A1 (de) * | 1999-05-12 | 2000-11-16 | Bayer Ag | Dispersionsmittel und daraus hergestellte Beschichtung |
-
2000
- 2000-10-27 US US09/869,609 patent/US6627280B1/en not_active Expired - Fee Related
- 2000-10-27 WO PCT/JP2000/007587 patent/WO2001032756A1/ja not_active Application Discontinuation
- 2000-10-27 EP EP00970170A patent/EP1153963A4/en not_active Withdrawn
- 2000-10-27 KR KR1020017008361A patent/KR20010082773A/ko not_active Application Discontinuation
- 2000-10-31 TW TW89122912A patent/TWI256958B/zh not_active IP Right Cessation
-
2001
- 2001-07-02 NO NO20013295A patent/NO20013295L/no not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5131879B1 (ja) * | 1966-02-28 | 1976-09-09 | ||
US5391429A (en) * | 1992-01-07 | 1995-02-21 | Diafoil Hoechst Company, Limited | Polyester film |
JPH06134950A (ja) * | 1992-10-23 | 1994-05-17 | Toray Ind Inc | 易接着性ポリエステルフィルム |
JPH06263902A (ja) * | 1993-03-11 | 1994-09-20 | Toray Ind Inc | 易接着性ポリエステルフィルム |
JPH08225672A (ja) * | 1994-12-09 | 1996-09-03 | Teijin Ltd | ポリエチレンナフタレート成形体の蛍光防止方法 |
JPH1148429A (ja) * | 1997-07-31 | 1999-02-23 | Toyobo Co Ltd | ポリエステル樹脂多層成形体 |
Non-Patent Citations (1)
Title |
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See also references of EP1153963A4 * |
Also Published As
Publication number | Publication date |
---|---|
EP1153963A4 (en) | 2002-11-06 |
TWI256958B (en) | 2006-06-21 |
EP1153963A1 (en) | 2001-11-14 |
KR20010082773A (ko) | 2001-08-30 |
NO20013295D0 (no) | 2001-07-02 |
US6627280B1 (en) | 2003-09-30 |
NO20013295L (no) | 2001-08-30 |
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