WO2000068355A1 - Verfahren zur kalten herstellung von perlglänzenden tensidzubereitungen - Google Patents
Verfahren zur kalten herstellung von perlglänzenden tensidzubereitungen Download PDFInfo
- Publication number
- WO2000068355A1 WO2000068355A1 PCT/EP2000/003853 EP0003853W WO0068355A1 WO 2000068355 A1 WO2000068355 A1 WO 2000068355A1 EP 0003853 W EP0003853 W EP 0003853W WO 0068355 A1 WO0068355 A1 WO 0068355A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbon atoms
- fatty
- acid
- esters
- alkyl
- Prior art date
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- 239000004094 surface-active agent Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 title abstract 2
- -1 polyol ester Chemical class 0.000 claims abstract description 59
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- 235000014113 dietary fatty acids Nutrition 0.000 claims description 39
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- 150000002337 glycosamines Chemical class 0.000 description 2
- 150000002338 glycosides Chemical group 0.000 description 2
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
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- XMMODWGMKHUZQW-UHFFFAOYSA-N 2-hydroxy-16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCC(O)C(O)=O XMMODWGMKHUZQW-UHFFFAOYSA-N 0.000 description 1
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- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
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- QNAYBMKLOCPYGJ-UHFFFAOYSA-N Alanine Chemical class CC([NH3+])C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-N 0.000 description 1
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- 239000004593 Epoxy Substances 0.000 description 1
- 101001061807 Homo sapiens Rab-like protein 6 Proteins 0.000 description 1
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 1
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- OTGQIQQTPXJQRG-UHFFFAOYSA-N N-(octadecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCO OTGQIQQTPXJQRG-UHFFFAOYSA-N 0.000 description 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
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- 102100029618 Rab-like protein 6 Human genes 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- AQKOHYMKBUOXEB-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-(16-methylheptadecanoyloxy)oxolan-2-yl]-2-(16-methylheptadecanoyloxy)ethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCC(C)C)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCC(C)C AQKOHYMKBUOXEB-RYNSOKOISA-N 0.000 description 1
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- 239000013543 active substance Substances 0.000 description 1
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- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- IAJILQKETJEXLJ-QTBDOELSSA-N aldehydo-D-glucuronic acid Chemical class O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-QTBDOELSSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 239000013011 aqueous formulation Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000000035 biogenic effect Effects 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- SAQPWCPHSKYPCK-UHFFFAOYSA-N carbonic acid;propane-1,2,3-triol Chemical compound OC(O)=O.OCC(O)CO SAQPWCPHSKYPCK-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 1
- 229940048848 lauryl glucoside Drugs 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- KHLCTMQBMINUNT-UHFFFAOYSA-N octadecane-1,12-diol Chemical compound CCCCCCC(O)CCCCCCCCCCCO KHLCTMQBMINUNT-UHFFFAOYSA-N 0.000 description 1
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000008389 polyethoxylated castor oil Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229940068965 polysorbates Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- PVNIQBQSYATKKL-UHFFFAOYSA-N tripalmitin Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC PVNIQBQSYATKKL-UHFFFAOYSA-N 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0089—Pearlescent compositions; Opacifying agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
Definitions
- the invention is in the field of pearlescent preparations, especially cosmetics, and relates to a method for producing these agents by cold means.
- the prior art knows a large number of formulations which give surface-active agents the desired pearlescence.
- pearlescent concentrates in the form of flowable aqueous dispersions which contain 15 to 40% by weight of pearlescent components, 5 to 55% by weight of emulsifiers and 0.1 to Contain 5 or 15 to 40 wt .-% polyols.
- the pearlescent waxes are acylated polyalkylene glycols, monoalkanolamides, linear, saturated fatty acids or ketosulfones.
- the two European patents EP 0181773 B1 and EP 0285389 B1 propose shampoo compositions which contain surfactants, non-volatile silicones and pearlescent waxes.
- the subject of European patent application EP 0205922 A2 (Henkel) are flowable pearlescent concentrates which contain 5 to 15% by weight of acylated polyglycols, 1 to 6% by weight of fatty acid monoethanolamides and 1 to 5% by weight of nonionic emulsifiers.
- nonionic, flowable pearlescent dispersions can also be obtained by preparing mixtures of 5 to 30% by weight of acylated polyglycols and 0.1 to 20% by weight of selected nonionic surfactants.
- European patent application EP 0581193 A2 Hoechst
- preservative-free pearlescent dispersions which contain acylated polyglycol ethers, betaines, anionic surfactants and glycerol.
- polyglycerol esters as crystallization aids for the production of pearlescent concentrates is proposed in European patent application EP 0684302 A1 (Th. Goldschmidt).
- pearlescent waxes have melting points above 80 ° C. and can therefore not be incorporated cold into aqueous formulations.
- the skilled person is therefore forced to work according to a hot process, i.e. melt the waxes and allow them to slowly crystallize out in the formulation, the fine particle size of the crystals and thus the brilliance of the pearlescence being a function of the cooling rate. It is therefore immediately clear that such methods are time and energy consuming, so that there is a desire for a cheaper alternative.
- pearlescent concentrates which are more or less concentrated surfactant preparations which the pearlescent waxes already have in finely divided, i.e.
- pearlescent concentrates can be processed cold, but the actual problem is not solved by this, but only shifted to the level of the manufacturer of these intermediates, since the concentrates are of course only accessible by a hot process.
- the object of the present invention was therefore to provide a process which enables the cold incorporation of pearlescent waxes into surfactant preparations - be it intermediate products, such as e.g. Pearlescent concentrates or final formulations, e.g. Shampoos - allowed. At the same time, neither the brilliance of the pearlescence nor the stability of the formulations should be adversely affected by the cold process.
- the invention relates to a process for the cold production of pearlescent surfactant preparations, in which aqueous surfactant solutions are introduced and mixtures of pearlescent waxes and polyol esters are stirred in at temperatures in the range from 10 to 45, preferably 15 to 25 ° C.
- aqueous surfactant solutions are introduced and mixtures of pearlescent waxes and polyol esters are stirred in at temperatures in the range from 10 to 45, preferably 15 to 25 ° C.
- polyol esters lowers the melting point of pearlescent waxes to such an extent that their cold (10 to 25 ° C.) incorporation into surfactant formulations is possible without any problems.
- the preparations are intermediate products (e.g. pearlescent concentrates) or final formulations for the consumer (e.g.
- compositions have a brilliant pearlescence, are stable in storage and also allow the incorporation of ingredients that are difficult to formulate, e.g. Silicone oils.
- the invention includes the knowledge that not only pearlescent agents can be produced in this way, but - depending on the wax type and the emulsifier - also those which have an intense whitening.
- the surfactant preparations can be either intermediates, as pearl giancy concentrates or final formulations for the consumer, such as Trade hair shampoos or dishwashing detergents.
- the preparations may contain anionic, nonionic, cationic and / or amphoteric or amphoteric surface-active substances, the proportion of which in the compositions, depending on whether it is a concentrate or a dilution, is in the range from 1 to 35, preferably 5 to 15 or 15 to 40, preferably 25 to 35% by weight.
- anionic surfactants are soaps, alkylbenzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, fatty acid ether sulfates, hydroxymic ether sulfate sulfate, hydroxymischogether sulfate sulfate Mono- and dialkylsulfosuccinates, mono- and dialkylsulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid ethionates, fatty acid sarcosinates, fatty acid
- nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid, fatty acid amide, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers and mixed formals, of hydroxy mixed ethers, optionally partially oxidized alk (en) yl oligoglycosides or glucuronic acid derivatives, fatty acid N-alkyl glucamides, protein hydrolyzates (particularly herbal Wheat-based products), polyol fatty acid esters, sugar esters, sorbitan esters, Polysorbates and amine oxides. If the nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
- cationic surfactants are quaternary ammonium compounds, such as, for example, dimethyldistearylammonium chloride, and esterquats, in particular quaternized fatty acid trialkanolamine ester salts.
- amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
- the surfactants mentioned are exclusively known compounds. With regard to the structure and manufacture of these substances, reference is made to relevant reviews, for example, J.Falbe (ed.), “Surfactants in Consumer Products”, Springer Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), “Catalysts, Tenside und Mineralöladditive ", Thieme Verlag, Stuttgart, 1978, pp. 123-217.
- the surfactant preparations can contain other customary auxiliaries and additives, such as oil bodies, superfatting agents, consistency enhancers, thickening agents, polymers, silicone compounds, fats, waxes, stabilizers, biogenic agents, deodorants, antiperspirants, antidandruff agents, film formers, swelling agents, UV light protection factors, antioxidants , Hydrotropes, preservatives, insect repellents, self-tanners, solubilizers, perfume oils, dyes and the like.
- auxiliaries and additives such as oil bodies, superfatting agents, consistency enhancers, thickening agents, polymers, silicone compounds, fats, waxes, stabilizers, biogenic agents, deodorants, antiperspirants, antidandruff agents, film formers, swelling agents, UV light protection factors, antioxidants , Hydrotropes, preservatives, insect repellents, self-tanners, solubilizers, perfume oils, dyes and the like.
- pearlescent waxes are: alkylene glycol esters, fatty acid alkanolamides, partial glycerides, esters of polyvalent, optionally hydroxy-substituted carboxylic acids, fatty alcohols, fatty acids, fatty ketones, fatty aldehydes, fatty ethers, fatty carbonates, ring-opening products of olefin epoxides and mixtures thereof.
- alkylene glycol esters which form component (a1) are usually mono- and / or diesters of alkylene glycols which follow the formula (III)
- R 5 CO is a linear or branched, saturated or unsaturated acyl radical having 6 to 22 carbon atoms
- R 6 is hydrogen or R 5 CO
- A is a linear or branched alkylene radical having 2 to 4 carbon atoms and n is a number of 1 to 5.
- Typical examples are mono- and / or diesters of ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, tri- ethylene glycol or tetraethylene glycol with fatty acids with 6 to 22, preferably 12 to 18 carbon atoms as there are: caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, linoleic acid, petroselenic acid, petroselenic acid , Linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures.
- the use of ethylene glycol mono- and / or distearate is particularly preferred.
- Fatty acid alkanolamides which are suitable as pearlescent waxes of group (a2) follow the formula (IV),
- R 7 CO represents a linear or branched, saturated or unsaturated acyl radical having 6 to 22 carbon atoms
- R 8 represents hydrogen or an optionally hydroxy-substituted alkyl radical having 1 to 4 carbon atoms
- B represents a linear or branched alkylene group having 1 to 4 carbon atoms.
- Typical examples are condensation products of ethanolamine, methylethanolamine, diethanolamine, propanolamine, methylpropanolamine and dipropanolamine and their mixtures with caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, oleic acid, isostroic acid, isostroic acid Linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures.
- the use of stearic acid ethanolamide is particularly preferred.
- Partial glycerides which have pearlescent properties and form component (a3), are monoesters and / or diesters of glycerol with linear, saturated fatty acids, namely, for example, caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, behenic acid and their technical grade Mixtures. They follow the formula (V),
- R 9 CO for a linear, saturated acyl radical having 6 to 22 carbon atoms
- R 10 and R 11 independently of one another for hydrogen or R 9 CO, x, y and z in total for 0 or for numbers from 1 to 30 and
- X for is an alkali or alkaline earth metal with the proviso that at least one of the two radicals R 10 and R 11 is hydrogen.
- Typical examples are lauric acid monoglyceride, lauric acid diglyceride, coconut fatty acid monoglyceride, coconut fatty acid triglyceride, palmitic acid monoglyceride, palmitic acid triglyceride, stearic acid monoglyceride, stearic acid diglyceride, tallow fatty acid monoglyceride, Tallow fatty acid diglyceride, behenic acid monoglyceride, behenic acid diglyceride and their technical mixtures, which may still contain minor amounts of triglyceride from the manufacturing process.
- Pearlescent waxes which form component (a4) are further esters of polyvalent, optionally polyfunctional, preferably hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms.
- Metal salts, in particular alkali metal salts, of monoesters of dicarboxylic acids or of mono- and / or diesters of tricarboxylic acids are also suitable.
- esters of polyfunctional carboxylic acids, preferably hydroxycarboxylic acids with partial esters of polyols, and the metal salts of the corresponding half-esters can also be used as component (a4).
- esters examples include malonic acid, malic acid, fumaric acid, adipic acid, sebacic acid, azelaic acid, dodecanedioic acid, phthalic acid, isophthalic acid and in particular succinic acid and malic acid, citric acid and in particular tartaric acid and mixtures thereof.
- the fatty alcohols contain 6 to 22, preferably 12 to 18 and in particular 16 to 18 carbon atoms in the alkyl chain.
- Typical examples are capronic alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palomoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linoleolyl alcohol, linoleolyl alcohol, linoleol alcohol alcohol, linoleol alcohol alcohol, linoleol alcohol alcohol, linoleol alcohol alcohol and brassidyl alcohol and their technical mixtures.
- the esters can be present as full or partial esters, preferably mono- and especially diesters of carboxylic or hydroxycarboxylic acids.
- Typical examples are succinic acid mono- and dilauryl esters, succinic acid mono- and dicetearly esters, succinic acid mono- and distearyl esters, tartaric acid mono- and dilauryl esters, tartaric acid mono- and dicocoalkyl esters, tartaric acid mono- and dicetearyl esters, citro- nenoic acid di- and -trilaurylester, citric acid mono-, -di and -trikokosalkylester as well as citric acid mono-, -di- and -tricetearylester and their metal salts, preferably alkali salts.
- a further group of pearlescent waxes (a5) can be fatty alcohols and / or fatty acids which follow the formula (VI)
- R 12 represents a linear, optionally hydroxy-substituted alkyl radical and / or acyl radical having 16 to 48, preferably 18 to 36, carbon atoms.
- suitable alcohols are cetearyl alcohol, hydroxystearyl alcohol, behenyl alcohol and oxidation products of long-chain paraffins;
- acids are stearic acid, hydroxystearic acid and especially behenic acid, the latter preferably in a purity above 90% by weight.
- Fat ketones which are suitable as component (a6) preferably follow the formula (VII),
- R 13 and R 14 independently of one another represent alkyl and / or alkenyl radicals having 1 to 22 carbon atoms, with the proviso that they have a total of at least 24 and preferably 32 to 48 carbon atoms.
- the ketones can be prepared by methods known in the art, for example by pyrolysis of the corresponding fatty acid magnesium salts.
- the ketones can be symmetrical or asymmetrical, but the two radicals R 13 and R 14 preferably differ only by one carbon atom and are derived from fatty acids having 16 to 22 carbon atoms. Stearon is characterized by particularly advantageous pearlescent properties.
- Fatty aldehydes (a7) suitable as pearlescent waxes preferably correspond to the formula (VIII)
- R 15 CO represents a linear or branched acyl radical having 24 to 48, preferably 28 to 32, carbon atoms.
- pearlescent waxes (a8) are fatty ethers of the formula (IX)
- R 16 and R 17 independently of one another represent alkyl and / or alkenyl radicals having 1 to 22 carbon atoms, with the proviso that they have a total of at least 24 and preferably 32 to 48 carbon atoms.
- Fat ethers of the type mentioned are usually prepared by acidic condensation of the corresponding fatty alcohols. Fat ethers with particularly advantageous pearlescent properties are obtained by condensation of fatty alcohols having 16 to 22 carbon atoms, such as, for example, cetyl alcohol, cetearyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, behenyl alcohol and / or erucyl alcohol.
- Fatty carbonates preferably of the formula (X), are also suitable as component (a9),
- R 18 and R 19 independently of one another represent alkyl and / or alkenyl radicals having 1 to 22 carbon atoms, with the proviso that in total they have at least 24 and preferably 32 to 48 carbon atoms. have lenstoffatome.
- the substances are obtained by transesterifying, for example, dimethyl or diethyl carbonate with the corresponding fatty alcohols in a manner known per se. Accordingly, the fatty carbonates can be constructed symmetrically or asymmetrically. However, carbonates are preferably used in which R 18 and R 19 are the same and stand for alkyl radicals having 16 to 22 carbon atoms.
- Transesterification products of dimethyl or diethyl carbonate with cetyl alcohol, cetearyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, behenyl alcohol and / or erucyl alcohol in the form of their mono- and diesters or their technical mixtures are particularly preferred.
- the epoxy ring opening products which finally form group (a10) are known substances which are usually prepared by acid-catalyzed reaction of terminal or internal olefin epoxides with aliphatic alcohols.
- the reaction products preferably follow the formula (XI)
- R 20 and R 21 represent hydrogen or an alkyl radical having 10 to 20 carbon atoms, with the proviso that the sum of the carbon atoms of R 20 and R 21 is in the range from 10 to 20 and R 22 represents an alkyl and / or alkenyl radical having 12 to 22 carbon atoms and / or the radical of a polyol having 2 to 15 carbon atoms and 2 to 10 hydroxyl groups.
- Typical examples are ring opening products of ⁇ -dodecene epoxide, ⁇ -hexadecene epoxide, ⁇ -octadecenepoxide, ⁇ -eicose epoxide, ⁇ -docose epoxide, i-dodecene epoxide, i-hexadecene epoxide, i-octadecenepoxide, i-eicose epoxide and / or i-docohol alcohol epoxide with lauryl alcohol , coconut fatty alcohol, myristyl alcohol, cetyl alcohol, cetearyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, behenyl alcohol and / or erucyl alcohol.
- Ring opening products of hexa- and / or octadecene epoxides with fatty alcohols having 16 to 18 carbon atoms are preferably used.
- polyols are used for the ring opening, the following substances are involved: glycerin; Alkylene glycols, such as, for example, ethylene glycol, ethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons; technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10, such as technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight; Methyl compounds, such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol; Lower alkyl glucosides,
- pearlescent concentrates are produced in the sense of the method according to the invention, so If the proportion of pearlescent waxes in the preparations is usually in the range from 5 to 45, preferably 10 to 45 and in particular 25 to 35% by weight, if the formulations are final, the pearlescent content is of course substantially lower and is typically 0.5 to 3% preferably 1 to 2% by weight.
- Polyol esters which are used in the sense of the invention to lower the melting point of the pearlescent waxes can be selected from the following groups of compounds:
- Partial esters of polyglycerin (average degree of self-condensation 2 to 8), polyethylene glycol (molecular weight 400 to 5000), trimethylolpropane, pentaerythritol, sugar alcohols (e.g. sorbitol), alkyl glucosides (e.g. methyl glucoside, butyl giucoside, lauryl glucoside) and polyglucosides saturated (e.g. cellulose) / or unsaturated, linear or branched fatty acids with 12 to 22 carbon atoms and / or hydroxycarboxylic acids with 3 to 18 carbon atoms and their adducts with 1 to 30 moles of ethylene oxide;
- Suitable partial glycerides are hydroxystearic acid monoglyceride, stearic acid diglyceride hydroxy, isostearic acid, Isostearinklarediglycerid, oleic acid monoglyceride, oleic acid diglyceride, Ricinolklaremoglycerid, Ricinolklarediglycerid, Linolklaremonoglycerid, linoleic acid diglyceride, LinolenTalkremonoglycerid, Linolenchurediglycerid, Erucaklaklamonoglycerid, erucic acid diglyceride, rid Weinchuremonoglycerid, Weinklarediglycerid, Citronenklamonoglycerid, Citronendiglyce-, Malic acid monoglyceride, malic acid diglyceride and their technical mixtures, which may still contain minor amounts of triglyceride from the manufacturing process. Addition products of 1 to 30, preferably 5 to
- polyglycerol esters are polyglyceryl-2 dipolyhydroxystearates (Dehymuls® PGPH), polyglycerol-3-diisostearates (Lameform® TGI), polyglyceryl-4 isostearates (Isolan® Gl 34), polyglyceryl-3 oleates, diisostearoyl polyglyearylate-3 (Isolan® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care® 450), Polyglyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether (Chimexane® NL) , Polyglyceryl-3 Distearate (Cremophor® GS 32) and Polyglyceryl Polyricinoleate (Admul® WOL 1403) Polyglyceryl Dimerate Is
- polystyrene resin examples include the mono-, di- and triesters of trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like which are optionally reacted with 1 to 30 mol of ethylene oxide.
- the proportion of the polyol esters in the preparations is usually in the range from 0.5 to 15, preferably 1 to 10 and in particular 5 to 8% by weight; if the end formulations are the polyol ester - Holds of course much lower and is typically 0.1 to 1 and preferably about 0.5 wt .-%.
- the content of the polyol esters, based on the amount of pearlescent wax is usually in the range from 1 to 15 and preferably 5 to 10% by weight.
- the surfactant preparations can in principle contain all types of surfactants; their selection depends solely on the desired application profile for end use.
- the trend preparations are pearlescent concentrates, that is to say intermediate products.
- the selection of the surfactant component is more critical, since the application requirements primarily consist of permanently stabilizing the highest possible amounts of pearlescent wax and keeping the viscosity of the agents so low that they can still be pumped and metered without problems.
- nonionic surfactants from at least one of the following groups are suitable: > Addition products of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear fatty alcohols with 8 to 22 carbon atoms, with fatty acids with 12 to 22 carbon atoms, with alkylphenols with 8 to 15 carbon atoms in the alkyl group and Alkylamines with 8 to 22 carbon atoms in the alkyl radical;
- adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols or with castor oil are known, commercially available products. These are mixtures of homologs whose average degree of alkoxylation is the ratio of the amounts of ethylene oxide and / or propylene oxide and substrate, with which the addition reaction is carried out.
- Ci2 / i8 fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE 2024051 PS as refatting agents for cosmetic preparations.
- C ⁇ / 18 alkyl mono- and oligoglycosides, their preparation and their use are known from the prior art.
- glycoside residue both monoglycosides in which a cyclic sugar residue is glycosidically bonded to the fatty alcohol and oligomeric glycosides with a degree of oligomerization of up to about 8 are suitable.
- the degree of oligomerization is a statistical mean value which is based on a homolog distribution customary for such technical products.
- Zwitterionic surfactants can also be used as emulsifiers.
- Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule.
- Particularly suitable zwitterionic surfactants are the so-called betaines, such as the N-alkyl-N, N-dimethylammonium glycinate, for example coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example coconut acylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylm -hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
- betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for
- fatty acid amide derivative known under the CTFA name of Cocamidopropyl Betaine is particularly preferred.
- Suitable emulsifiers are ampholytic surfactants.
- Ampholytic surfactants are before understood surface-active compounds which, in addition to a C ⁇ / i ⁇ alkyl or acyl group, contain at least one free amino group and at least one -COOH or -S ⁇ 3H group in the molecule and are capable of forming internal salts.
- ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each with about 8 to 18 carbon atoms in the alkyl group.
- Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and Ci2 / i8-acylsarcosine.
- cationic surfactants are also suitable as emulsifiers, those of the ester quat type, preferably methyl-quaternized difatty acid triethanolamine ester salts, being particularly preferred.
- polyols may be advantageous to use to lower the viscosity.
- Polyols that come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups.
- the polyols can also contain further functional groups, in particular amino groups, or be modified with nitrogen. Typical examples are
- Alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons;
- Methyl compounds such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
- Dialcohol amines such as diethanolamine or 2-amino-1, 3-propanediol.
- the amount of polyols used is - based on the surfactant preparations - typically in the range from 0.1 to 15 and preferably 0.5 to 5% by weight. If higher amounts of polyol, preferably glycerol or ethylene glycol, are used, the concentrates are simultaneously stabilized against microbial attack.
- the surfactant preparations are usually prepared by introducing an aqueous surfactant or emulsifier solution, if appropriate together with other auxiliaries and additives, at 10 to 25 ° C., and introducing, homogenizing and crystallizing the mixture of pearlescent wax and polyol ester at this temperature . It is also possible to provide a concentrated aqueous (anion) surfactant paste, to stir the mixture of pearlescent wax and polyol ester in the cold and then to dilute the mixture to the desired concentration with further water or to mix in the presence of polymeric hydrophilic thickeners such as hydroxypropyl - perform cellulosic, xanthan gum or polymers of the carbomer type. Finally, the mixture of pearlescent wax and polyol ester can already be dissolved or dispersed in a subset of the aqueous surfactant solution and can thus be mixed with the main amount of the preparation.
- the melting point-lowering effect by the addition of polyol esters to commercially available pearlescent waxes is shown in Table 1.
- the pure waxes and mixtures of 90% by weight wax and 10% by weight polyol ester were compared.
- Shampoos of the following composition were then produced: 12 g coconut fatty alcohol + 2EO sulfate sodium salt, 1.5 g dimethylpolysiloxane, 3 g coconut alkyl glucoside and 1.5 g of an ester quat (water ad 100% by weight).
- the preparations were (a) heated to 90 ° C. and mixed with 1 g of pearlescent waxes V1 to V4 each and cooled to ambient temperature within 1 h, or (b) at 20 ° C. mixed with 1 g of mixtures 1 to 4 .
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Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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US10/009,289 US6727217B1 (en) | 1999-05-07 | 2000-04-28 | Cold production method for pearly lustre surfactant preparations |
DE50010521T DE50010521D1 (de) | 1999-05-07 | 2000-04-28 | Verfahren zur kalten herstellung von perlglänzenden tensidzubereitungen |
JP2000616323A JP2004506592A (ja) | 1999-05-07 | 2000-04-28 | 真珠光沢剤界面活性剤組成物の製法 |
EP00929458A EP1177274B8 (de) | 1999-05-07 | 2000-04-28 | Verfahren zur kalten herstellung von perlglänzenden tensidzubereitungen |
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DE19921187.6 | 1999-05-07 | ||
DE19921187A DE19921187C2 (de) | 1999-05-07 | 1999-05-07 | Verfahren zur kalten Herstellung von perlglänzenden Tensidzubereitungen |
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EP (1) | EP1177274B8 (de) |
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Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19937298A1 (de) * | 1999-08-06 | 2001-02-22 | Cognis Deutschland Gmbh | Wäßrige Perlglanzkonzentrate |
DE10025671B4 (de) * | 2000-05-24 | 2006-07-27 | Cognis Ip Management Gmbh | Emulgatoren |
DE10162026A1 (de) * | 2001-12-18 | 2003-07-03 | Cognis Deutschland Gmbh | Hochkonzentriert fließfähige Perlglanzkonzentrate |
US7923425B2 (en) * | 2006-08-21 | 2011-04-12 | Henkel Ag & Co. Kgaa | Low-foaming, acidic low-temperature cleaner and process for cleaning surfaces |
JP2008150308A (ja) * | 2006-12-15 | 2008-07-03 | Mitsui Fine Chemicals Inc | 毛髪改質剤、毛髪改質剤成分を含有する毛髪化粧料、及び毛髪の改質方法 |
US8529788B2 (en) * | 2007-03-12 | 2013-09-10 | Kao Corporation | Pearlescent composition |
BR112012004297A2 (pt) | 2009-08-27 | 2017-05-30 | Otc Gmbh | concentrado perolado e método para a fabricação do mesmo. |
DE102009040454A1 (de) | 2009-08-27 | 2011-03-24 | Otc Verwaltungs Gmbh | Herstellung von Perlglanzdispersionen |
EP2723343A2 (de) | 2011-06-23 | 2014-04-30 | The Procter and Gamble Company | Verfahren zur herstellung von kristallen zur verwendung für eine körperpflegezusammensetzung |
BR112014029758A2 (pt) | 2012-05-30 | 2017-06-27 | Clariant Finance Bvi Ltd | composição contendo n-metil-n-acilglucamina |
WO2013178671A2 (de) | 2012-05-30 | 2013-12-05 | Clariant International Ltd. | Verwendung von n-methyl-n-acylglucaminen als solubilisatoren |
DE102012021647A1 (de) | 2012-11-03 | 2014-05-08 | Clariant International Ltd. | Wässrige Adjuvant-Zusammensetzungen |
US20160136072A1 (en) * | 2013-06-28 | 2016-05-19 | Clariant International Ltd. | Use of special N-methyl-N-acylglucamines in skin-cleaning agents and hand dishwashing agents |
US9833395B2 (en) * | 2013-10-25 | 2017-12-05 | Galaxy Surfactants Ltd. | Sustainable cold-dispersible pearlescent concentrate |
DE102014005771A1 (de) | 2014-04-23 | 2015-10-29 | Clariant International Ltd. | Verwendung von wässrigen driftreduzierenden Zusammensetzungen |
DE102015213478A1 (de) | 2015-07-17 | 2017-01-19 | Henkel Ag & Co. Kgaa | Stabilisierungsgemisch |
DE102015219608B4 (de) | 2015-10-09 | 2018-05-03 | Clariant International Ltd | Universelle Pigmentdispersionen auf Basis von N-Alkylglukaminen |
DE102015219651A1 (de) | 2015-10-09 | 2017-04-13 | Clariant International Ltd. | Zusammensetzungen enthaltend Zuckeramin und Fettsäure |
DE102016207877A1 (de) | 2016-05-09 | 2017-11-09 | Clariant International Ltd | Stabilisatoren für Silikatfarben |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3617306A1 (de) * | 1985-05-23 | 1986-11-27 | Lion Corp | Verfahren zur herstellung einer hochkonzentrierten perliermitteldispersion |
DE4103551A1 (de) * | 1991-02-06 | 1992-08-13 | Henkel Kgaa | Fliessfaehiges perlglanzkonzentrat |
EP0684302A1 (de) * | 1994-05-28 | 1995-11-29 | Th. Goldschmidt AG | Wässrige, fliessfähige Perlglanzkonzentrate |
WO1997047719A1 (de) * | 1996-06-07 | 1997-12-18 | Henkel Kommanditgesellschaft Auf Aktien | Wässrige perlglanzkonzentrate |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1165574B (de) | 1960-08-08 | 1964-03-19 | Dehydag Gmbh | Verfahren zur Herstellung von als Emulgiermittel fuer Salbengrundlagen dienenden Mischestern |
DE2024051C3 (de) | 1970-05-16 | 1986-05-07 | Henkel KGaA, 4000 Düsseldorf | Verwendung der Veresterungsprodukte von Glycerin-Äthylenoxid-Addukten mit Fettsäuren als Rückfettungsmittel in kosmetischen Zubereitungen |
CA1261276A (en) | 1984-11-09 | 1989-09-26 | Mark B. Grote | Shampoo compositions |
DE3519080A1 (de) | 1985-05-28 | 1986-12-04 | Henkel Kgaa | Fliessfaehiges perlglanzkonzentrat |
JPH0699275B2 (ja) * | 1985-11-05 | 1994-12-07 | 株式会社コーセー | 非水クレンジング料 |
ATE80792T1 (de) | 1987-04-01 | 1992-10-15 | Procter & Gamble | Shampoo-praeparate. |
DE3843572A1 (de) * | 1988-12-23 | 1990-06-28 | Henkel Kgaa | Fliessfaehiges perlglanzkonzentrat |
US5711899A (en) | 1988-12-23 | 1998-01-27 | Henkel Kommanditgesellschaft Auf Aktien | Free flowing pearlescent concentrate |
EP0569843B1 (de) | 1992-05-13 | 1995-11-15 | Hoechst Aktiengesellschaft | Nichtionische, fliessfähige Perlglanzdispersionen |
DE4224715A1 (de) | 1992-07-27 | 1994-02-03 | Hoechst Ag | Fließfähige konservierungsmittelfreie Perlglanzdispersionen |
JPH0782140A (ja) * | 1993-09-14 | 1995-03-28 | Kao Corp | 真珠光沢液体洗浄剤組成物 |
DE4420516C2 (de) * | 1994-06-13 | 1998-10-22 | Henkel Kgaa | Polyglycerinpolyhydroxystearate |
US5612655A (en) * | 1995-07-06 | 1997-03-18 | Allen Telecom Group, Inc. | Filter assembly comprising a plastic resonator support and resonator tuning assembly |
DE19527120A1 (de) * | 1995-07-25 | 1997-01-30 | Henkel Kgaa | Fließfähiges Perlglanzkonzentrat |
DE19619645A1 (de) * | 1996-05-15 | 1997-11-20 | Henkel Kgaa | Haarbehandlungsmittel |
DE19622968C2 (de) * | 1996-06-07 | 2000-08-17 | Cognis Deutschland Gmbh | Wäßrige Perlglanzkonzentrate |
DE19641280C2 (de) * | 1996-10-07 | 1999-09-16 | Henkel Kgaa | Verwendung von Monoglycerid(ether)sulfaten als Perlglanzwachse |
DE19646869C1 (de) * | 1996-11-13 | 1997-12-04 | Henkel Kgaa | Kosmetische Zubereitungen |
DE19646867C1 (de) * | 1996-11-13 | 1997-12-04 | Henkel Kgaa | Kosmetische Zubereitungen |
DE19650473C1 (de) * | 1996-12-05 | 1998-04-02 | Henkel Kgaa | Kosmetische Zubereitungen |
JPH10182343A (ja) * | 1996-12-25 | 1998-07-07 | Kao Corp | パール光沢組成物およびその製造法 |
GB9711685D0 (en) * | 1997-06-05 | 1997-08-06 | Procter & Gamble | Cosmetic compositions |
-
1999
- 1999-05-07 DE DE19921187A patent/DE19921187C2/de not_active Expired - Fee Related
-
2000
- 2000-04-28 US US10/009,289 patent/US6727217B1/en not_active Expired - Fee Related
- 2000-04-28 EP EP00929458A patent/EP1177274B8/de not_active Expired - Lifetime
- 2000-04-28 WO PCT/EP2000/003853 patent/WO2000068355A1/de active IP Right Grant
- 2000-04-28 DE DE50010521T patent/DE50010521D1/de not_active Expired - Fee Related
- 2000-04-28 ES ES00929458T patent/ES2245310T3/es not_active Expired - Lifetime
- 2000-04-28 JP JP2000616323A patent/JP2004506592A/ja active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3617306A1 (de) * | 1985-05-23 | 1986-11-27 | Lion Corp | Verfahren zur herstellung einer hochkonzentrierten perliermitteldispersion |
DE4103551A1 (de) * | 1991-02-06 | 1992-08-13 | Henkel Kgaa | Fliessfaehiges perlglanzkonzentrat |
WO1992013512A1 (de) * | 1991-02-06 | 1992-08-20 | Henkel Kommanditgesellschaft Auf Aktien | Fliessfähiges perlglanzkonzentrat |
EP0684302A1 (de) * | 1994-05-28 | 1995-11-29 | Th. Goldschmidt AG | Wässrige, fliessfähige Perlglanzkonzentrate |
WO1997047719A1 (de) * | 1996-06-07 | 1997-12-18 | Henkel Kommanditgesellschaft Auf Aktien | Wässrige perlglanzkonzentrate |
Also Published As
Publication number | Publication date |
---|---|
EP1177274A1 (de) | 2002-02-06 |
EP1177274B1 (de) | 2005-06-08 |
DE19921187A1 (de) | 2000-11-16 |
ES2245310T3 (es) | 2006-01-01 |
EP1177274B8 (de) | 2005-08-03 |
DE19921187C2 (de) | 2001-06-28 |
JP2004506592A (ja) | 2004-03-04 |
US6727217B1 (en) | 2004-04-27 |
DE50010521D1 (de) | 2005-07-14 |
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