WO2000066802A1 - Eisen-nickel-legierung - Google Patents

Eisen-nickel-legierung Download PDF

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Publication number
WO2000066802A1
WO2000066802A1 PCT/EP2000/000840 EP0000840W WO0066802A1 WO 2000066802 A1 WO2000066802 A1 WO 2000066802A1 EP 0000840 W EP0000840 W EP 0000840W WO 0066802 A1 WO0066802 A1 WO 0066802A1
Authority
WO
WIPO (PCT)
Prior art keywords
max
iron
nickel alloy
temperature range
mass
Prior art date
Application number
PCT/EP2000/000840
Other languages
German (de)
English (en)
French (fr)
Inventor
Bodo Gehrmann
Original Assignee
Krupp Vdm Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Krupp Vdm Gmbh filed Critical Krupp Vdm Gmbh
Priority to DE50000570T priority Critical patent/DE50000570D1/de
Priority to EP00905008A priority patent/EP1173628B1/de
Priority to JP2000615423A priority patent/JP2002543291A/ja
Publication of WO2000066802A1 publication Critical patent/WO2000066802A1/de
Priority to HK02106790A priority patent/HK1045718A1/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
    • C22C38/105—Ferrous alloys, e.g. steel alloys containing cobalt containing Co and Ni

Definitions

  • the invention relates to a low-expansion iron-nickel alloy.
  • iron-based alloys with 36% nickel have a low coefficient of expansion in the temperature range of 20 and 100 ° C. For this reason, these alloys have been used for several decades where constant lengths are required even when the temperature changes, such as precision instruments, watches, bimetals. With the development of color television sets and computer monitors in the direction of higher resolution, color fidelity and contrast strength even under unfavorable lighting conditions, and in particular with regard to the development of ever flatter and larger screens, iron-nickel materials are increasingly being used for shadow masks.
  • an iron-based alloy with at least 34% nickel with a lower coefficient of thermal expansion in the temperature range from 20 to 100 ° C of below 1.0 x 10 "6 / K could be developed by the Manganese content was kept below 0.1% and the iron / nickel ratio Fe / Ni was chosen between 1.75 and 1.83.
  • Typical values of the coefficient of thermal expansion in the temperature range from 20 to 100 ° C. are approximately between 0.6 and 0 , 9 x 10 "6 / K.
  • DE-A 22 17 280 relates to a pinhole in color picture tubes, the material of which is an iron-nickel alloy with a specific thermal expansion in the temperature range of 20-80 ° of 0-2, preferably from 0.6 to 1.2 x 10 " 6 / C of the following composition (in% by weight) is: 30 - 45% Ni, 0 - 2.5% Mn, 0 - 2% Si, 0 - 2% C, 0 - 8% Co, 0 - 11% Cr, 0 - 3% W, balance iron preferred alloy should have the following composition (in% by weight): 30-31% Ni, 4-8, preferably 5-7% Co, balance iron.
  • An iron-nickel alloy is known from JP-A 6-336655, which has a Ni content of between 35 and 36% by weight of Co contents of between 0 and 0.7% by weight.
  • iron-based alloys with approximately 32% nickel and 5% cobalt have an even lower coefficient of thermal expansion in the temperature range from 20 to 100 ° C. Therefore, these alloys are used for the highest requirements regarding thermal length stability. However, due to the high alloy costs due to the high cobalt content, these alloys are not widely used in industry.
  • an alloy which achieves a coefficient of thermal expansion in the temperature range from 20 to 100 ° C. even below 1.0 x 10'6 / K.
  • the alloy costs must be significantly lower than that of the iron-based alloy with about 32% nickel and 5% cobalt.
  • the object of the invention is to provide a low-expansion iron-nickel alloy which, when using inexpensive alloy elements, nevertheless achieves optimal thermal expansion coefficients in the temperature range from 20-100 ° C. and which should be usable for different applications.
  • the alloy particularly when processing the alloy into shadow masks for color television sets, must have good hot and cold formability.
  • the alloy according to the invention contains max. 0.009% carbon, max. 0.1% manganese, max. 0.1% silicon and max. 0.1% aluminum and the usual manufacturing-related additions in only a very small amount with residual iron.
  • the alloy according to the invention is characterized by excellent processability and requires no additional process steps in the production of shadow masks. It also shows the long-term stability of its thermal properties that meets the needs.
  • the alloy according to the invention achieves very low coefficients of thermal expansion in the temperature range from 20 to 100 ° C. from below 0.6 x 10 " ⁇ / K.
  • a higher manganese content of at least 0.2% is essential for good hot formability.
  • the alloy according to the invention is both very good hot and cold formable even at very low manganese contents of less than 0.05%.
  • This goal is also achieved by using a low-expansion iron-nickel alloy that (in mass%) for setting a thermal expansion coefficient ⁇ 0.6 x 10 "6 / K in the temperature range from 20 to 100 ° C in addition to a maximum of 0.009 % C, max.0.1% Mn, max.0.1% Si and max.0.1% AI, 0.5 to 2.0% Co and 35.0 to 36.0% Ni, balance iron and contains manufacturing-related admixtures, both for
  • AK AK (20-100 ° C): Average coefficient of thermal expansion for the temperature range 20 to 100 ° C.
  • the average thermal expansion coefficient in the temperature range from 20 to 100 ° C. of the alloy E according to the invention is, at 0.44 ⁇ 10 6 / K, significantly lower than the coefficients of the alloy examples ST1, ST2, ST3 and ST4 belonging to the prior art.
  • the specified alloying elements chromium, titanium, copper, sulfur, phosphorus, magnesium, zirconium and boron are considered to be additives due to the manufacturing process.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrodes For Cathode-Ray Tubes (AREA)
  • Paper (AREA)
PCT/EP2000/000840 1999-05-03 2000-02-02 Eisen-nickel-legierung WO2000066802A1 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE50000570T DE50000570D1 (de) 1999-05-03 2000-02-02 Eisen-nickel-legierung
EP00905008A EP1173628B1 (de) 1999-05-03 2000-02-02 Eisen-nickel-legierung
JP2000615423A JP2002543291A (ja) 1999-05-03 2000-02-02 鉄−ニッケル合金
HK02106790A HK1045718A1 (en) 1999-05-03 2002-09-17 Iron-nickel alloy

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19920144.7 1999-05-03
DE19920144A DE19920144C1 (de) 1999-05-03 1999-05-03 Eisen-Nickel-Legierung

Publications (1)

Publication Number Publication Date
WO2000066802A1 true WO2000066802A1 (de) 2000-11-09

Family

ID=7906709

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2000/000840 WO2000066802A1 (de) 1999-05-03 2000-02-02 Eisen-nickel-legierung

Country Status (8)

Country Link
EP (1) EP1173628B1 (ko)
JP (1) JP2002543291A (ko)
KR (1) KR100636082B1 (ko)
CN (1) CN1110576C (ko)
DE (2) DE19920144C1 (ko)
HK (1) HK1045718A1 (ko)
TW (1) TW524861B (ko)
WO (1) WO2000066802A1 (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1200130C (zh) * 2001-07-05 2005-05-04 杰富意钢铁株式会社 低热膨胀合金薄板以及使用该薄板的荫罩
WO2009135469A1 (de) * 2008-05-08 2009-11-12 Thyssenkrupp Vdm Gmbh Eisen-nickel-legierung
CN104404339A (zh) * 2014-11-04 2015-03-11 无锡贺邦金属制品有限公司 一种铁镍基合金冲压件
CN104404340A (zh) * 2014-11-04 2015-03-11 无锡贺邦金属制品有限公司 铁镍合金冲压件
KR102018989B1 (ko) * 2018-07-18 2019-09-05 정애자 유골분 용융가열 패널
CN113195763B (zh) * 2019-03-26 2022-02-18 日本铸造株式会社 低温稳定性优异的低热膨胀合金及其制造方法
CN111763891B (zh) * 2020-07-23 2022-03-29 江苏省沙钢钢铁研究院有限公司 一种铁镍铜合金及其真空熔炼工艺
CN114107834B (zh) * 2021-11-05 2022-06-28 河钢股份有限公司 一种高强铁镍钼合金丝材及其低成本制备方法
CN114889245B (zh) * 2022-04-16 2024-05-28 上海殷菲合金材料有限公司 一种复合金属片及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0567989A1 (en) * 1992-04-27 1993-11-03 Hitachi Metals, Ltd. Shadow mask sheet, method of producing the same and cathode ray tube provided therewith
JPH06336655A (ja) * 1993-05-31 1994-12-06 Nkk Corp 黒化処理性に優れたシャドウマスク用Ｆｅ−Ｎｉ系合金薄板およびＦｅ−Ｎｉ−Ｃｏ系合金薄板
EP0713923A1 (fr) * 1994-11-23 1996-05-29 Imphy S.A. Alliage fer-nickel à faible coefficient de dilatation
US5811918A (en) * 1994-01-17 1998-09-22 U.S. Philips Corporation Shadow mask of the nickel-iron type having specific composition

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2217280A1 (de) * 1972-04-11 1973-10-31 Metallgesellschaft Ag Lochblende in farbbildroehren
DE4402684C2 (de) * 1993-05-27 2001-06-21 Krupp Vdm Gmbh Verwendung einer ausdehnungsarmen Eisen-Nickel-Legierung

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0567989A1 (en) * 1992-04-27 1993-11-03 Hitachi Metals, Ltd. Shadow mask sheet, method of producing the same and cathode ray tube provided therewith
JPH06336655A (ja) * 1993-05-31 1994-12-06 Nkk Corp 黒化処理性に優れたシャドウマスク用Ｆｅ−Ｎｉ系合金薄板およびＦｅ−Ｎｉ−Ｃｏ系合金薄板
US5811918A (en) * 1994-01-17 1998-09-22 U.S. Philips Corporation Shadow mask of the nickel-iron type having specific composition
EP0713923A1 (fr) * 1994-11-23 1996-05-29 Imphy S.A. Alliage fer-nickel à faible coefficient de dilatation

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 120, no. 12, 21 March 1994, Columbus, Ohio, US; abstract no. 140352, LEE, J. H. ET AL: "Effects of manganese, chromium and cobalt on the thermal expansion behaviors of iron-nickel Invar alloys" XP002137903 *
PATENT ABSTRACTS OF JAPAN vol. 1995, no. 03 28 April 1995 (1995-04-28) *
TAEHAN KUMSOK HAKHOECHI (1993), 31(7), 867-872 *

Also Published As

Publication number Publication date
EP1173628A1 (de) 2002-01-23
EP1173628B1 (de) 2002-09-25
CN1110576C (zh) 2003-06-04
DE19920144C1 (de) 2000-08-03
CN1348508A (zh) 2002-05-08
KR100636082B1 (ko) 2006-10-18
DE50000570D1 (de) 2002-10-31
TW524861B (en) 2003-03-21
JP2002543291A (ja) 2002-12-17
KR20020016622A (ko) 2002-03-04
HK1045718A1 (en) 2002-12-06

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