WO2000066648A1 - Kristallisierende polyetherpolyole, ein verfahren zu deren herstellung sowie deren verwendung - Google Patents

Kristallisierende polyetherpolyole, ein verfahren zu deren herstellung sowie deren verwendung Download PDF

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Publication number
WO2000066648A1
WO2000066648A1 PCT/EP2000/003495 EP0003495W WO0066648A1 WO 2000066648 A1 WO2000066648 A1 WO 2000066648A1 EP 0003495 W EP0003495 W EP 0003495W WO 0066648 A1 WO0066648 A1 WO 0066648A1
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WO
WIPO (PCT)
Prior art keywords
crystallizing
propylene oxide
polyol
molecular weight
polyethene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2000/003495
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German (de)
English (en)
French (fr)
Inventor
Walter Schäfer
Jörg Hofmann
Pramod Gupta
Pieter Ooms
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Priority to AT00922645T priority Critical patent/ATE274015T1/de
Priority to KR1020017013782A priority patent/KR100558233B1/ko
Priority to BRPI0010066-8A priority patent/BR0010066B1/pt
Priority to CA002371540A priority patent/CA2371540C/en
Priority to DE50007496T priority patent/DE50007496D1/de
Priority to EP00922645A priority patent/EP1177237B1/de
Priority to MXPA01010932A priority patent/MXPA01010932A/es
Priority to AU42963/00A priority patent/AU4296300A/en
Priority to US10/030,489 priority patent/US6569981B1/en
Priority to HK02107962.7A priority patent/HK1046418B/zh
Priority to PL00351610A priority patent/PL351610A1/xx
Priority to JP2000615675A priority patent/JP4896296B2/ja
Publication of WO2000066648A1 publication Critical patent/WO2000066648A1/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2250/00—Compositions for preparing crystalline polymers

Definitions

  • the invention relates to crystallizing polyether polyols, a process for their preparation and their use for the production of polyurethane materials, in particular polyurethane foams, elastomers and coatings.
  • Crystallizing poly (oxypropylene) polyols are known and are distinguished in polyurethane (PUR) applications by an improvement in mechanical
  • the object was therefore to provide crystallizing polyethene polyols based on propylene oxide with reduced viscosity in order to achieve the above-described
  • the object of the invention was achieved by providing new, crystallizing polyethene polyols.
  • the invention therefore relates to crystallizing polyethene polyols which can be prepared by reacting initially propylene oxide with polyhydroxy compounds in the presence of an alkoxy compound containing zinc and / or aluminum atoms to give a crystallizing polyethene polyol having an average molecular weight M n of 500 to 5000 and subsequent further reaction of the crystallizing polyether polyol thus obtained with 10 to 90 wt .-%, based on the Amount of the crystallizing polyol, an epoxide in the presence of a catalyst which does not stereospecifically polymerize propylene oxide, to give a crystallizing polyethene polyol with an average molecular weight M n of 1000 to 20,000.
  • Another object of the present invention is a process for the preparation of crystallizing Polyethe ⁇ olyolen, which is characterized in that first propylene oxide with polyhydroxy compounds in the presence of an alkoxy compound containing zinc and / or aluminum atoms to a crystallizing polyether polyol having an average molecular weight M n of 500 to
  • the reaction of the crystallizing polyethene polyol obtained as an intermediate with the epoxide can be carried out catalytically in any manner, for example by acidic, basic or coordinative catalysis, preferably by alkali metal hydroxide or double metal cyanide (DMC) catalysis.
  • acidic, basic or coordinative catalysis preferably by alkali metal hydroxide or double metal cyanide (DMC) catalysis.
  • DMC double metal cyanide
  • the crystallizing polyethene polyol obtained as an intermediate can be further processed with the epoxy in the manner described without removing the catalyst used in its production.
  • Suitable polyhydroxy compounds according to the invention are all polyhydroxy compounds known for the reaction with epoxides, in particular polyhydroxy compounds having 2 to 6 hydroxyl groups per molecule and a molecular weight of 90 to 2000. preferably 200 to 1500. In particular, they are used
  • Polypropylene glycols Polyethylene glycols, dihydroxypolyethylene oxide polypropylene oxide block copolymers and randomly structured EO / PO copolymers. Such compounds are described, for example, in Kirk-Othmer (3) 754 to 789.
  • polyhydroxy compounds on ethylene glycol, ethylene glycol, dipropylene glycol, propylene glycol, 1,4-butanediol, 1,6-hexanediol,
  • Glycerol trimethylolpropane, pentaerythritol, sorbitol or sucrose started polypropylene glycols with an average molecular weight M n of 200 to 2,000 or mixed polymers of propylene oxide and ethylene oxide started on ethylene glycol, propylene glycol, 1,4-butanediol, glycerol or trimethylolpropane, which have an average molecular weight M n of 200 own up to 2,000, and mixtures of the polyhydroxy compounds mentioned with each other.
  • catalysts which are capable of stereospecifically polymerizing propylene oxide. These are the known aluminum and / or zinc atoms
  • Alkoxy compounds which may also contain aluminum and / or zinc alkyl groups, such as those e.g. in Encycl. of polym. Be. and Engineering 6, 284-307.
  • ⁇ -Oxoalkoxides containing aluminum and zinc atoms as described in US 3432445.
  • bimetallic aluminum and zinc atoms containing ⁇ -oxoalkoxides are used as catalysts (so-called Teyssie catalysts) which correspond to the following general formula:
  • R represents a C2-C12 alkyl radical
  • alkyl radicals examples include: the ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, hexyl, decyl, undecyl and dodecyl radicals, preferably the propyl, isopropyl, butyl and isobutyl residue.
  • alkoxy compounds containing aluminum and / or zinc atoms described above are generally treated and modified with the star polyol (as described in DE 19 748 359).
  • alkali metal hydroxides such as potassium and / or cesium hydroxide
  • alkaline earth metal hydroxides such as strontium and / or barium hydroxide and double metal cyanide (DMC) catalysts are preferably used (see e.g. Kirk-Othmer (3), 18, pages 616 to 645).
  • Double metal cyanide (DMC) catalysts which are suitable for the polyaddition of the epoxides to the crystallizing polyethene polyols obtained as intermediates are generally known (see, for example, US Pat. Nos. 3,440,109, 3,829,505, 3,941,849 and 5,158,922).
  • the use of these DMC catalysts for the production of Polyethe ⁇ olyolen causes in particular a reduction in the proportion of monofunctional polyethers with terminal double bonds, so-called monools, compared to the conventional production of Polyethe ⁇ olyolen using alkali catalysts, such as alkali metal hydroxides.
  • DMC catalysts are usually obtained by reacting an aqueous solution of a metal salt with the aqueous solution of a metal cyanide salt in the presence of a low molecular weight organic complex ligand, for example an ether.
  • aqueous solutions of zinc chloride (in excess) and potassium hexacyanocobaltate are mixed and then - Ethane (Glyme) added to the suspension formed. After filtration and washing the Catalyst with aqueous glyme solution becomes an active catalyst of the general formula
  • Improved DMC catalysts e.g. in EP-A 700 949, EP-A 743 093, EP-A 761 708, WO 97/40086, WO 98/16310, DE-A 197 45 120, DE-A 197 57 574 and DE-A 198 102 269 are also extremely high
  • Preferred epoxides for addition to the intermediate are propylene oxide,
  • Alkoxy compounds are reacted with the starting polyol with substitution of the alkoxy group or also the alkyl group with the starting polyol group at about 20 to 200 ° C.
  • the catalysts are reacted in such a way that one equivalent of starch polyol is reacted with an amount of catalyst which in total contains 10 "3 to 1 mol of aluminum and / or zinc, preferably 10 " 2 to 0.6 mol.
  • modified Al / Zn atoms-containing alkoxy compounds is preferred.
  • the alcohols formed during the substitution reaction and possibly also alkanes are removed, for example, by heating under vacuum.
  • starter polyol ie with the above polyhydroxy compounds. modified and preferably used "Teyssie catalysts" of the specified
  • the formula is then then at 50 to 150 ° C, preferably 80 to 160 ° C under a total pressure of 0.5 to 20 bar, preferably 1 to 5 bar, propylene oxide and in such an amount in grams (g) that the Sum of the amount of starting polyol in g and the amount of propylene oxide in g divided by moles of starting polyol is 600 to 3000, preferably 800 to 2500 g per mole.
  • Alkaline earth metal hydroxide is added as the base, 0.1 to 2 g, preferably 0.2 to 1 g, of base being used per 100 g of polyethene polyol obtained. Water or volatile organic compounds, which are obtained during the addition, are optionally removed with heating in vacuo.
  • the intermediate can be freed from the catalyst prior to the further addition of epoxides, e.g. by reacting with acids and separating the resulting metal salts.
  • epoxides e.g. by reacting with acids and separating the resulting metal salts.
  • a method is preferred in which the catalyst is separated from the end product.
  • the addition of the epoxide to the crystallizing polyethene polyols obtained as intermediates can be carried out at normal pressure or at total pressures of 0.5 to 20 bar, preferably 1 to 5 bar (absolute), and at a temperature of 80 to 200 ° C., preferably 90 to 150 ° C, are carried out, the amount of epoxy being such that a hydroxypropyl ether having an average molecular weight M n of 1000 to
  • 20,000 preferably 1500 to 10,000, arises, determined via GPC (polystyrene as standard) or via the content of hydroxyl end groups.
  • the reaction of the epoxides with the crystalline polyether polyol obtained as an intermediate can also be carried out according to another preferred embodiment with catalysis by means of a double metal instead of with alkali catalysis.
  • cyanide catalyst there is preferably no interim separation of the catalyst containing the aluminum and / or zinc atoms.
  • the double metal cyanide catalyst concentration is selected so that the polyaddition of the epoxides can be controlled well under the given reaction conditions.
  • the catalyst concentration is generally in the range from 0.0005 to 1% by weight, preferably in the range from 0.001 to 0.1% by weight, based on the amount of the polyether polyol to be prepared.
  • the polyaddition in the presence of double metal cyanide catalysts can be carried out at total pressures from 0.5 to 20 bar, preferably 1 to 5 bar, and at temperatures from 50 to 200 ° C., preferably 70 to 160 ° C.
  • One possible way of reacting the partially crystalline polyethene polyol with propylene oxide is, for example, to gradually feed the mixture of the catalyst, the partially crystalline polyethene polyol and the propylene oxide, which may also contain solvents, into a reactor in such a way that after the exothermic reaction has started, a fast heat dissipation e.g. is guaranteed over large reactor areas. To complete the reaction, the mixture can still be circulated.
  • the polyethene polyol produced according to the invention is treated with aqueous acid to remove or reduce the metal content, a pH of ⁇ 6 being set.
  • aqueous acid to remove or reduce the metal content
  • the resulting metal salts are extracted by extraction with water or by precipitation, possibly with the addition of suitable solvents, e.g. B. toluene, removed from the Polyethe ⁇ olyol.
  • suitable solvents e.g. B. toluene
  • Possible acids include hydrochloric acid, phosphoric acid, sulfuric acid, benzoic acid, citric acid and / or lactic acid.
  • Other less preferred forms of working up are, for example, treatment with ion exchangers or with adsorbents.
  • the polyaddition reaction of the epoxides to the polyether polyol obtained in the meantime can be carried out in bulk or in an inert, organic solvent, such as toluene and / or tetrahydrofuran.
  • the amount of solvent is usually 10 to 30% by weight, based on the amount of the product to be prepared
  • the crystallizing polyethene polyols produced by the process according to the invention are outstandingly suitable for the production of polyurethane materials, such as PUR elastomers, PUR foams and PUR coatings.
  • 40 parts of a 0.35 molar solution of di- ⁇ -oxo [bis (l-methylethyloxy) aluminum] zinc are added to 440 parts of a hydroxypolyether based on propylene oxide having an OH number of 380 mg KOH / g and started with trimethylolpropane Heated at 130 ° C for 3 hours.
  • the reaction mixture is cooled to 95 ° C. and vacuum (0.3 mbar) is applied for one hour.
  • 100 parts of toluene are added and the toluene is then distilled off again at 0.3 mbar until a temperature of 130 ° C. is reached.
  • a double metal cyanide catalyst (prepared in accordance with EP 743 093) is added and 1160 parts of propylene oxide are then added dropwise at 110 ° C.
  • the product is taken up in methylene chloride and 10% sulfuric acid is added until the crude product has a pH ⁇ 5 and then washed with water.
  • the product is washed with an aqueous bicarbonate solution and water. The organic phase is separated off and the solvent is removed.
  • 40 parts of a 0.35 molar solution of di- ⁇ -oxo [bis (l-methylethyloxy) aluminum] zinc are added to 440 parts of a hydroxypolyether based on propylene oxide having an OH number of 380 mg KOH / g and started with trimethylolpropane Heated at 130 ° C for 3 hours.
  • the reaction mixture is cooled to 95 ° C. and a vacuum (0.3 mbar) is applied for one hour.
  • 100 parts of toluene are added and the toluene is then distilled off again at 0.3 mbar until a temperature of 130 ° C. is reached.
  • Double metal cyanide catalyst is added and then 850 parts of propylene oxide are added dropwise at 110 ° C.
  • the product is taken up in toluene and 10% sulfuric acid is added until the crude product has a pH ⁇ 5 and then washed with water.
  • the product is mixed with an aqueous bicarbonate solution and
  • Washed water Washed water. The organic phase is separated off and the solvent is removed.
  • the product is washed with an aqueous bicarbonate solution and water.
  • the organic phase is separated off and the solvent is removed.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyethers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Paints Or Removers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Steroid Compounds (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Polyesters Or Polycarbonates (AREA)
PCT/EP2000/003495 1999-04-28 2000-04-18 Kristallisierende polyetherpolyole, ein verfahren zu deren herstellung sowie deren verwendung Ceased WO2000066648A1 (de)

Priority Applications (12)

Application Number Priority Date Filing Date Title
AT00922645T ATE274015T1 (de) 1999-04-28 2000-04-18 Kristallisierende polyetherpolyole, ein verfahren zu deren herstellung sowie deren verwendung
KR1020017013782A KR100558233B1 (ko) 1999-04-28 2000-04-18 결정성 폴리에테르 폴리올, 그의 제조 방법 및 그의 용도
BRPI0010066-8A BR0010066B1 (pt) 1999-04-28 2000-04-18 polieterpolióis cristalizadores, processo para a sua preparação bem como seu emprego.
CA002371540A CA2371540C (en) 1999-04-28 2000-04-18 Crystallising polyether polyols, a method for producing them and use of the same
DE50007496T DE50007496D1 (de) 1999-04-28 2000-04-18 Kristallisierende polyetherpolyole, ein verfahren zu deren herstellung sowie deren verwendung
EP00922645A EP1177237B1 (de) 1999-04-28 2000-04-18 Kristallisierende polyetherpolyole, ein verfahren zu deren herstellung sowie deren verwendung
MXPA01010932A MXPA01010932A (es) 1999-04-28 2000-04-18 Polioleteres cristalizantes, procedimiento para su preparacion y su uso.
AU42963/00A AU4296300A (en) 1999-04-28 2000-04-18 Crystallising polyether polyols, a method for producing them and use of the same
US10/030,489 US6569981B1 (en) 1999-04-28 2000-04-18 Crystallizing polyether polyols, a method for producing them and use of the same
HK02107962.7A HK1046418B (zh) 1999-04-28 2000-04-18 結晶聚醚多元醇及其製備方法和應用
PL00351610A PL351610A1 (en) 1999-04-28 2000-04-18 Crystallising polyether polyols, a method for producing them and use of the same
JP2000615675A JP4896296B2 (ja) 1999-04-28 2000-04-18 結晶化ポリエーテルポリオール

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19919267.7 1999-04-28
DE19919267A DE19919267A1 (de) 1999-04-28 1999-04-28 Kristallisierende Polyetherpolyole, ein Verfahren zu deren Herstellung sowie deren Verwendung

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WO2000066648A1 true WO2000066648A1 (de) 2000-11-09

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PCT/EP2000/003495 Ceased WO2000066648A1 (de) 1999-04-28 2000-04-18 Kristallisierende polyetherpolyole, ein verfahren zu deren herstellung sowie deren verwendung

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US (1) US6569981B1 (https=)
EP (1) EP1177237B1 (https=)
JP (1) JP4896296B2 (https=)
KR (1) KR100558233B1 (https=)
CN (1) CN1117789C (https=)
AT (1) ATE274015T1 (https=)
AU (1) AU4296300A (https=)
BR (1) BR0010066B1 (https=)
CA (1) CA2371540C (https=)
CZ (1) CZ20013850A3 (https=)
DE (2) DE19919267A1 (https=)
ES (1) ES2226820T3 (https=)
HK (1) HK1046418B (https=)
HU (1) HUP0200943A2 (https=)
ID (1) ID30442A (https=)
MX (1) MXPA01010932A (https=)
PL (1) PL351610A1 (https=)
RU (1) RU2001132153A (https=)
TW (1) TW527376B (https=)
WO (1) WO2000066648A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE532811T1 (de) 2006-08-31 2011-11-15 Asahi Glass Co Ltd Verfahren zur reinigung einer polyetherverbindung
SG191340A1 (en) * 2010-12-27 2013-08-30 Dow Global Technologies Llc Alkylene oxide polymerization using a double metal cyanide catalyst complex and a magnesium, group 3-group 15 metal or lanthanide series metal compound

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB893274A (en) * 1957-04-08 1962-04-04 Gen Tire & Rubber Co Polymerization of olefin oxides
DE1720337A1 (de) * 1967-12-27 1971-06-09 Basf Ag Verfahren zur Herstellung von hochmolekularen Polyaethern aus Epoxyden
US4962281A (en) * 1985-12-13 1990-10-09 The Dow Chemical Company Synthesis of stereoregular poly(propylene oxide)
EP0862947A1 (de) * 1997-03-06 1998-09-09 Basf Aktiengesellschaft Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren und Verfahren zur Herstellung von Polyetheralkoholen

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4812080B1 (https=) * 1969-10-20 1973-04-18
JPS495237B1 (https=) * 1970-01-07 1974-02-06
JPS495637B1 (https=) * 1970-03-19 1974-02-08
JPS4917440B1 (https=) * 1970-09-08 1974-04-30
DE19748359A1 (de) * 1997-11-03 1999-05-06 Bayer Ag Verfahren zur Herstellung teilkristalliner Polyetherpolyole

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB893274A (en) * 1957-04-08 1962-04-04 Gen Tire & Rubber Co Polymerization of olefin oxides
DE1720337A1 (de) * 1967-12-27 1971-06-09 Basf Ag Verfahren zur Herstellung von hochmolekularen Polyaethern aus Epoxyden
US4962281A (en) * 1985-12-13 1990-10-09 The Dow Chemical Company Synthesis of stereoregular poly(propylene oxide)
EP0862947A1 (de) * 1997-03-06 1998-09-09 Basf Aktiengesellschaft Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren und Verfahren zur Herstellung von Polyetheralkoholen

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US6569981B1 (en) 2003-05-27
EP1177237B1 (de) 2004-08-18
CN1117789C (zh) 2003-08-13
ID30442A (id) 2001-12-06
DE50007496D1 (de) 2004-09-23
CZ20013850A3 (cs) 2002-02-13
DE19919267A1 (de) 2000-11-02
BR0010066A (pt) 2002-01-15
RU2001132153A (ru) 2003-09-10
JP4896296B2 (ja) 2012-03-14
CN1349548A (zh) 2002-05-15
PL351610A1 (en) 2003-05-05
ATE274015T1 (de) 2004-09-15
EP1177237A1 (de) 2002-02-06
CA2371540A1 (en) 2000-11-09
KR100558233B1 (ko) 2006-03-10
HUP0200943A2 (en) 2002-07-29
MXPA01010932A (es) 2002-06-21
BR0010066B1 (pt) 2010-06-15
KR20020003872A (ko) 2002-01-15
HK1046418B (zh) 2004-05-07
HK1046418A1 (en) 2003-01-10
JP2002543255A (ja) 2002-12-17
ES2226820T3 (es) 2005-04-01
TW527376B (en) 2003-04-11
AU4296300A (en) 2000-11-17
CA2371540C (en) 2008-07-08

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