WO2000046327A1 - Produit pour le nettoyage de surfaces dures - Google Patents

Produit pour le nettoyage de surfaces dures Download PDF

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Publication number
WO2000046327A1
WO2000046327A1 PCT/EP1999/000643 EP9900643W WO0046327A1 WO 2000046327 A1 WO2000046327 A1 WO 2000046327A1 EP 9900643 W EP9900643 W EP 9900643W WO 0046327 A1 WO0046327 A1 WO 0046327A1
Authority
WO
WIPO (PCT)
Prior art keywords
molecule
cleaning
ethylene oxide
group
linear
Prior art date
Application number
PCT/EP1999/000643
Other languages
German (de)
English (en)
Inventor
Karl-Heinz Rogmann
Birgit Skodell
Heiko Faubel
Original Assignee
Henkel-Ecolab Gmbh & Co. Ohg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel-Ecolab Gmbh & Co. Ohg filed Critical Henkel-Ecolab Gmbh & Co. Ohg
Priority to PCT/EP1999/000643 priority Critical patent/WO2000046327A1/fr
Priority to DE59902606T priority patent/DE59902606D1/de
Priority to DK99907471T priority patent/DK1149143T3/da
Priority to US09/890,660 priority patent/US6530383B1/en
Priority to EP99907471A priority patent/EP1149143B1/fr
Publication of WO2000046327A1 publication Critical patent/WO2000046327A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the present invention relates to an aqueous agent for cleaning hard surfaces, which contains a combination of polymer compounds soluble in alkaline medium and nonionic surfactants, and to the use of these agents for the mechanical cleaning of floors.
  • the hard surfaces include, for example, natural stone coverings, tiles such as porcelain stoneware, but also elastic coverings such as linoleum and PVC.
  • the hard surfaces When cleaning hard surfaces in the commercial sector, it must also be taken into account that the surfaces have different structures and, at the same time, soiling of the most varied types has to be removed, possibly with simultaneous disinfection, depending on the application. For this reason, a large number of funds have been developed for this area.
  • the selection of the agents is essentially determined by whether the agents perform the cleaning task on the most varied of materials in the shortest possible time, regardless of the type of contamination. For economic reasons, machines are used for this in commercial cleaning.
  • Floor cleaning generally uses scrubber driers (automatic cleaning machines) or scrubbing machines (single-disc or counter-rotating multi-disc machines or brush rolling machines). In the latter case, the cleaning agents are suctioned off in a second operation using a water suction device.
  • solubility of film-forming substances is only limited, so that they do not dissolve completely and cannot be removed again or only incompletely during the next cleaning, so that a strong care film can build up. This in turn affects the sure-footedness and the visual appearance of the floor and requires special cleaning at certain intervals.
  • the present invention was therefore based on the object of improving the conventional cleaning agents and thereby developing cleaning agents for hard surfaces, in particular for the commercial sector, which show good cleaning performance and at the same time preserve the surface, so that cleaning in one operation and preferably can be carried out with automatic cleaning machines.
  • the present invention relates to an aqueous agent for cleaning hard surfaces with a pH above 7, which contains A) 5 to 45% by weight of at least one polymer compound which is soluble in the alkaline medium and not crosslinked via metal ions and has a film-forming temperature between 0 and 80 ° C., and
  • R 1 is a linear, aliphatic hydrocarbon radical with an average of 4 to 18 carbon atoms in the molecule including their mixtures
  • R 2 is a hydrogen atom or an alkyl group with 1 to 6 carbon atoms
  • R 3 represents a linear, aliphatic hydrocarbon radical with an average of 2 to 14 carbon atoms in the molecule, including their mixtures, y represents 1 to 30 and z represents 1 to 3
  • components A and B are present in a ratio of 1 1 to 10 1, preferably 5 1 to 1 1
  • the agents according to the invention are preferably used in dilution with water, the application concentration usually being between 0.5 and 5% by weight, preferably between 2 and 5% by weight, based on the application solution.
  • the application can be carried out manually or in conventional cleaning machines, for example by applying the cleaning solution and then mechanical scrubbing with scrubber driers or other scrubbing machines.
  • the loosened dirt is well dispersed in the cleaner liquor so that it does not redeposit into the pores of the floor material before the liquor is suctioned off.
  • the floor is not rinsed, the remaining moisture dries.
  • a wafer-thin care film forms on the surface, which prevents or reduces dirt from adhering. This care film is completely dissolved again during the next cleaning process and forms again from the remaining moisture
  • the cleaning agent according to the invention is also characterized in particular by the fact that the surfactant combination removes a broad spectrum of oily and pigment-containing soiling.
  • the cleaning performance is close to that of anionic cleaning agents which are particularly active in cleaning, but has the advantage that no excessive amounts of foam are formed when they are used impair the continuous operation of the cleaning machines.
  • the cleaning agent according to the invention When the cleaning agent according to the invention is used for cleaning surfaces, there is no build-up of the care film, since this is completely dissolved again when cleaned again.
  • the low film thickness and the nature of the film also ensure that the tiles are sure-footed.
  • Suitable polymers according to the invention are generally all polymer compounds which are soluble in water in the alkaline range, provided that they are not metal-crosslinked.
  • the film-forming temperature is preferably between 0 and 80 ° C. These are preferably (meth) acrylic acid (ester) copolymers. Solubility is generally achieved by carboxylic acid groups.
  • Preferred polymers contain a (meth) acrylate copolymer of 1 to 30 parts by weight, based on the copolymer, carboxylic acid-containing monomers, 30 to 70 parts by weight, based on the copolymer, monomers, the homopolymers with gas transition temperatures form below 20 ° C, preferably d-Ce alkyl esters of acrylic acid and / or the C -C 8 alkyl esters of methacrylic acid, and 30 to 70 parts by weight, based on the copolymer, of comonomers which form homopolymers with glass transition temperatures above room temperature, preferably C. ⁇ Cs-A ⁇ ylester of (meth) acrylic acid or styrene.
  • Particularly suitable comonomers containing carboxylic acid groups are ethylenically unsaturated carboxylic acids, acrylic acid and methacrylic acid being preferred.
  • comonomers with glass transition temperatures below 20 ° C that is glass transition temperatures below room temperature (based in each case on the homopolymers of the monomers)
  • -C-C 3 -alkyl esters of (meth) acrylic acid are suitable, such as methyl methacrylate or ethyl methacrylate.
  • a particularly preferred comonomer whose homopolymer has a glass transition temperature above room temperature is styrene.
  • Copolymers used with preference are those of acrylic acid and / or (meth) acrylic acid with styrene, acrylic acid esters and / or methacrylic acid esters.
  • the copolymers of (meth) acrylic acid with (meth) acrylic acid esters and / or styrene e.g. for example copolymers of methyl acrylate, ethyl acrylate, methacrylic acid and styrene.
  • the monomers are present in the copolymers in such proportions that the film-forming temperature of the finished copolymer dispersion is between 0 and 80.degree.
  • the person skilled in the art is familiar with setting the quantitative ratios of comonomers in order to maintain this film-forming temperature.
  • the film formation temperatures mentioned relate to plasticizer-free systems, i.e. on copolymers without further additives.
  • Polymers are preferably used which are water-soluble only in the alkaline range, while they are insoluble in the acidic range. Such products are commercially available and are offered in emulsified form.
  • the polymers of component A are present in an amount of 5 to 45% by weight, preferably 5 to 30% by weight and in particular 8 to 20% by weight, based on the finished composition and calculated as a pure polymer , contain.
  • the surfactants contained as component B are commercially available products which are present in an amount of 2 to 90% by weight, preferably 5 to 65% by weight, and in particular 5 to 35% by weight, based on the finished composition.
  • the pH of the agents according to the invention is preferably between 8 and 10 in order to ensure the solubility of the polymer compounds of component A.
  • Alkalizing agents which can be used are both volatile and solid alkalis, such as NaOH and KOH, alkali carbonates, ammonia, waterglass and / or amines, such as alkylamines and alkanolamines, ammonia or alkanolamines preferably being used. When considering the amount of the alkalizing agent, it should be taken into account that when using commercially available polymer emulsions as component A, these may already contain small amounts of alkalizing agents.
  • the agents according to the invention can contain anionic surfactants and other nonionic surfactants other than component B as cosurfactants, alkalizing agents, alkaline reacting complexing agents, water-miscible organic solvents, cleaning-active salts, solubilizing agents and other customary additives as further ingredients.
  • Anionic cosurfactants can be added in an amount of up to 3% by weight, preferably from 0.5 to 1% by weight, based on the finished composition.
  • nonionic cosurfactants which can be mentioned are the adducts of 13 to 40 mol of ethylene oxide with C 8 -C 22 alcohols or from 1 to 40 mol of ethylene oxide with C 8 -C 22 alkylphenols and the alkylpolyglycosides.
  • the nonionic cosurfactants can be used in an amount of up to 8% by weight, in particular up to 6% by weight and particularly preferably up to 2% by weight, based on the finished composition.
  • the cleaning agents according to the invention can be present as so-called normal products, as concentrates and as pastes, it being known to the person skilled in the art that the transitions between these products are fluid.
  • Normal products are usually liquid and represent solutions of their ingredients.
  • the so-called concentrates are solutions or emulsions of the ingredients and have a liquid to viscous consistency.
  • surfactants can usually be used in an amount of up to 35% by weight, in concentrates up to 65% by weight and in pastes in an amount up to 90% by weight.
  • the third possible embodiment is the pastes, which can be dosed using suitable devices.
  • the pastes contain the active ingredients in an amount of up to 95% by weight. Pastes preferably do not contain additives and solvents.
  • the agents according to the invention can contain complexing agents which are able to compensate for impairments caused by extreme water hardness when the agents are used.
  • Pentasodium triphosphate, trisodium citrate, sodium gluconate, tetrasodium methylenediamine tetraacetate (EDTA-Na), products based on polyaspartic acid and trisodium nitversia acetate (NTA-Na) are particularly suitable.
  • NTA-Na and / or sodium gluconate are preferably used.
  • the complexing agents can be used in an amount of up to 8% by weight, preferably 0.5 to 5% by weight, based on the finished agent. If the agent contains phosphates, the amount of complexing agents can be lower.
  • water-miscible organic solvents may be present, with liposoluble solvents being preferred.
  • suitable solvents are mono- and dialcohols, ether alcohols and polyethers.
  • Typical representatives can be mentioned isopropanol, butyl glycol, ethylene glycol monophenyl ether, dimethyl diglycol and methyl pyrrolidone.
  • Lower ether alcohols for example mono- or diethylene monoalkyl ethers having 1 to 4 carbon atoms in the alkyl group, are preferably used.
  • the solvent content is not more than 30% by weight, preferably not more than 20% by weight and in particular between 0.5 and 10% by weight, based on the finished composition.
  • the performance of the agents according to the invention can be increased by adding further alkaline salts, such as. B. polyphosphates and pyrophosphates, especially sodium tripolyphosphate or tetrapotassium pyrophosphate.
  • alkaline salts such as. B. polyphosphates and pyrophosphates, especially sodium tripolyphosphate or tetrapotassium pyrophosphate.
  • these salts are preferably used in an amount of 2 to 8% by weight, but at most 15% by weight, based on the finished agent.
  • solubilizers such as. B. cumene sulfonate, octyl sulfate, toluenesulfonate, xyloisulfonate or urea.
  • solubilizers can be contained in the agent according to the invention in amounts of up to 10% by weight, in particular 1 to 6% by weight, in each case based on the finished agent.
  • Fatty acid soaps also have solubilizing properties. If the cleaning agent contains soap, the amount of solubilizer can usually be very small.
  • the agents according to the invention may also contain inorganic neutral salts, colorants and fragrances, thickeners and corrosion inhibitors and, if appropriate, disinfectants as further optional constituents.
  • the amount of the additives is preferably not more than 5% by weight, preferably not more than 2% by weight and in particular from 0.05 to 1% by weight, based on the finished composition. Further auxiliaries customary in cleaning agents for commercial purposes can also be included, provided they do not impair the effect according to the invention.
  • the composition contains 5 to 30% by weight of a polymer of component A, 2 to 45% by weight of surfactants of component B, up to 6% by weight of further nonionic surfactants, up to 2% by weight % anionic surfactants, up to 30% by weight of alkalizing agent, up to 5% by weight of alkaline complexing agents, up to 30% by weight of water-miscible organic solvents and up to 8% by weight of further additives, such as Solubilizers, thickeners, dyes and fragrances.
  • further additives such as Solubilizers, thickeners, dyes and fragrances.
  • the present invention further relates to the use of the agents described above for cleaning hard surfaces, in particular floors with a rough surface, preferably for machine cleaning floors.
  • Yet another object of the present invention relates to a method for the mechanical cleaning of hard surfaces, in which the surfaces are processed in a manner known per se using cleaning machines using an aqueous cleaning agent with a pH value above 7, characterized in that the cleaning agent contains : A) 5 to 45% by weight of at least one polymer compound which is soluble in the alkaline medium and is not crosslinked via metal ions and has a film-forming temperature between 0 and 80 ° C., and
  • R 1 is a linear, aliphatic hydrocarbon radical with an average of 4 to 18 carbon atoms in the molecule including their mixtures
  • R 2 is a hydrogen atom or an alkyl group with 1 to 6 carbon atoms
  • R 3 is a linear, aliphatic hydrocarbon radical with an average of 2 to 14 carbon atoms in the molecule including their mixtures, x is 0 or 1 to 5, y is 1 to 30 and z is 1 to 3.
  • Tables 1 and 2 show the compositions of six formulations according to the invention and six comparison formulations.
  • the quantities of the individual components are percentages by weight and relate to the finished product and anhydrous raw materials.
  • Polymer 1 Syntran® 1503, polyacrylate dispersion from Interpolymer Corp. Massachusetts Polymer 2 Ubatol® U 3920, polyacrylate dipersion from Cray Valley, Tönisvorst Polymer 3 Primat® 644 polymer dispersion from Rohm and Haas, Philadelphia Polymer 4 copolymer from 58% by weight methyl methacrylate, 30% by weight ethyl acrylate, 10% by weight % Acrylic acid, 2% by weight styrene
  • the degrees of alkoxylation given represent average ranges or values. Testing the cleaning effect
  • the cleaning effect of the wiping care products was determined with the aid of a Gardner washability and abrasion test device, as described in the quality standards of the Industrial Association of Cleaning and Care Products (Seife- ⁇ le-Fette-Wwachs, 108, pages 526-528 (1982) ).
  • a white PVC film is coated with soot and grease and is wiped under a machine with a sponge soaked in the cleaning agent under standardized conditions.
  • the cleaning performance is measured by photoelectric determination of the reflectance.
  • the care effect is shown, among other things, by the fact that a film from previous treatments with the same agent facilitates the detachment of subsequently applied soiling.
  • test method specified above was therefore modified in such a way that the film was wiped with the wiping agent to be tested before the application of the same soiling and then dried. After applying the soiling, the test was then carried out like the cleaning performance:
  • the wiping agents 1 to 6 according to the invention have an excellent cleaning performance both with respect to non-pretreated and to pretreated film. Soiling is removed even more effectively from pretreated film than from the original film.
  • the agents R1-R3 / P1-P3 used for comparison show good cleaning performance either only on untreated film (6) or only on pretreated film.
  • the agents according to the invention are in their care effect quite comparable to the agents according to the invention, but unlike these, after multiple use leads to a film addition which adversely affects the natural appearance and the sure-footedness of the treated surfaces.
  • test fields After drying, the fields were exposed to natural inspection. The arrangement of the test fields was changed daily. The test fields were evaluated by means of a test with a test field that was not used.
  • test duration was 5 days with daily sampling and subsequent cleaning with 5% product solution.
  • the evaluation was based on the following key.
  • the sliding friction was measured. It was measured with a neutral lubricant (standardized filter paper).
  • the sliding friction values listed in Table 3 represent an average of 10 measurements.
  • the sliding friction value of 0.650 represents the original covering. The lower the sliding friction value, the more slippery the surface.
  • the dispersibility was determined using a standardized test dirt using the shaking method.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un produit aqueux utilisé pour le nettoyage de surfaces dures, présentant un pH supérieur à 7, qui contient: A) 5 à 45 % en poids d'au moins un composé polymère non réticulé par des ions métal, soluble dans un milieu alcalin, présentant une température de formation de film comprise entre 0 et 80 °C; et B) 2 à 90 % en poids d'une combinaison de tensioactifs constituée d'un alcool gras C8-C18 alcoxylé linéaire comportant 1 à 10 groupes oxyde d'éthylène et 1 à 5 groupes oxyde de propylène par molécule, le groupe OH libre pouvant être fermé par un groupe alkyle C1-C4, et d'au moins un autre tensioactif du groupe constitué d'alcools C8-C18 alcoxylés à chaîne ramifiée, comprenant 1 à 8 unités oxyde d'éthylène, les groupes OH libres pouvant être fermés par un groupe alkyle C1-C4, d'éthoxylats d'alcools gras C8-C18 comportant 1 à 12 unités oxyde d'éthylène dans la molécule, et d'éthers mixtes hydroxy correspondant à la formule (I) R1O[CH2CH(CH3)O]x(CH2CHR2O)y[CH2CH(OH)zR3, dans laquelle R1 représente un reste hydrocarbure linéaire aliphatique comprenant en moyenne 4 à 18 atomes de carbone dans la molécule, y compris leur mélange, R2 représente un atome d'hydrogène ou un groupe alkyle possédant 1 à 6 atomes de carbone, R3 représente un reste hydrocarbure linéaire aliphatique possédant en moyenne 2 à 14 atomes de carbone dans la molécule y compris leurs mélanges, x peut valoir de 0 ou 1 à 5, y peut valoir de 1 à 30 et z peut valoir de 1 à 3.
PCT/EP1999/000643 1997-11-22 1999-02-02 Produit pour le nettoyage de surfaces dures WO2000046327A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
PCT/EP1999/000643 WO2000046327A1 (fr) 1999-02-02 1999-02-02 Produit pour le nettoyage de surfaces dures
DE59902606T DE59902606D1 (de) 1999-02-02 1999-02-02 Mittel zum reinigen von harten oberflächen
DK99907471T DK1149143T3 (da) 1999-02-02 1999-02-02 Middel til rengøring af hårde overflader
US09/890,660 US6530383B1 (en) 1997-11-22 1999-02-02 Agent for cleaning hard surfaces
EP99907471A EP1149143B1 (fr) 1999-02-02 1999-02-02 Produit pour le nettoyage de surfaces dures

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP1999/000643 WO2000046327A1 (fr) 1999-02-02 1999-02-02 Produit pour le nettoyage de surfaces dures

Publications (1)

Publication Number Publication Date
WO2000046327A1 true WO2000046327A1 (fr) 2000-08-10

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Application Number Title Priority Date Filing Date
PCT/EP1999/000643 WO2000046327A1 (fr) 1997-11-22 1999-02-02 Produit pour le nettoyage de surfaces dures

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Country Link
EP (1) EP1149143B1 (fr)
DE (1) DE59902606D1 (fr)
DK (1) DK1149143T3 (fr)
WO (1) WO2000046327A1 (fr)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002036725A1 (fr) * 2000-11-02 2002-05-10 Unilever N.V. Composition pour le nettoyage de surfaces dures
US6831052B2 (en) * 2001-02-01 2004-12-14 Cognis Deutschland Gmbh Cleaning compositions containing hydroxy mixed ethers, methods of preparing the same, and uses therefor
US7022662B2 (en) * 2001-11-02 2006-04-04 Cognis Deutschland Gmbh & Co. Kg Compositions containing hydroxy mixed ethers and polymers
US7279455B2 (en) * 2003-11-06 2007-10-09 Ecolab, Inc. Rinse aid composition and method of rising a substrate
WO2008008063A1 (fr) * 2006-07-14 2008-01-17 Ecolab Inc. Composition alcaline de nettoyage pour sols et procédé de nettoyage d'un sol
US7521412B2 (en) 2007-05-25 2009-04-21 Ecolab Inc. Dimensionally stable solid rinse aid
US7776158B2 (en) * 2002-06-29 2010-08-17 Ecolab Usa Inc. Floor cleaning and care compositions
US8324147B2 (en) 2009-05-12 2012-12-04 Ecolab Usa Inc. Fast drying and fast draining solid rinse aid consisting essentially of a quaternary non-ionic surfactant mixture
US8367600B2 (en) 2007-05-25 2013-02-05 Ecolab Usa Inc. Dimensionally stable solid rinse aid
US8383570B2 (en) 2007-05-25 2013-02-26 Ecolab Usa Inc. Enhanced melting point rinse aid solid compositions with synergistic preservative
US8567161B2 (en) 2009-05-28 2013-10-29 Ecolab Usa Inc. Wetting agents for aseptic filling
WO2014121406A1 (fr) * 2013-02-06 2014-08-14 Wetrok Ag Produit de nettoyage
US9011610B2 (en) 2012-06-22 2015-04-21 Ecolab Usa Inc. Solid fast draining/drying rinse aid for high total dissolved solid water conditions
WO2015120560A1 (fr) * 2014-02-11 2015-08-20 Wetrok Ag Produit pour décaper des surfaces
US9567551B2 (en) 2012-06-22 2017-02-14 Ecolab Usa Inc. Solid rinse aid composition and method of making same
US9982220B2 (en) 2015-05-19 2018-05-29 Ecolab Usa Inc. Efficient surfactant system on plastic and all types of ware
US10370626B2 (en) 2016-05-23 2019-08-06 Ecolab Usa Inc. Reduced misting acidic cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers
US10392587B2 (en) 2016-05-23 2019-08-27 Ecolab Usa Inc. Reduced misting alkaline and neutral cleaning, sanitizing, and disinfecting compositions via the use of high molecular weight water-in-oil emulsion polymers
US11155769B2 (en) 2018-07-25 2021-10-26 Ecolab Usa Inc. Rinse aid formulation for cleaning automotive parts
US11540512B2 (en) 2017-03-01 2023-01-03 Ecolab Usa Inc. Reduced inhalation hazard sanitizers and disinfectants via high molecular weight polymers
US11834633B2 (en) 2019-07-12 2023-12-05 Ecolab Usa Inc. Reduced mist alkaline cleaner via the use of alkali soluble emulsion polymers

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DE102004053015A1 (de) 2004-11-03 2006-05-04 Lanxess Deutschland Gmbh Rußreiniger
CN106635436A (zh) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 一种新型运动地板清洁剂

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EP0254208A2 (fr) * 1986-07-24 1988-01-27 Henkel Kommanditgesellschaft auf Aktien Mélanges d'agents tensio-actifs peu moussants et/ou anti-mousse et leur utilisation
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WO1995010589A1 (fr) * 1993-10-14 1995-04-20 Henkel Kommanditgesellschaft Auf Aktien Agent de nettoyage aqueux pour sols
JPH07118689A (ja) * 1993-10-20 1995-05-09 Lion Corp 硬表面洗浄剤組成物

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Publication number Priority date Publication date Assignee Title
FR2294231A1 (fr) * 1974-12-10 1976-07-09 Procter & Gamble Europ Composition d'entretien et de nettoyage des sols
EP0254208A2 (fr) * 1986-07-24 1988-01-27 Henkel Kommanditgesellschaft auf Aktien Mélanges d'agents tensio-actifs peu moussants et/ou anti-mousse et leur utilisation
US5126068A (en) * 1989-05-05 1992-06-30 Burke John J Hard surface cleaning composition containing polyacrylate copolymers as performance boosters
JPH04359096A (ja) * 1991-06-03 1992-12-11 Lion Corp 金属表面洗浄用水性液状アルカリ洗浄剤組成物
WO1995010589A1 (fr) * 1993-10-14 1995-04-20 Henkel Kommanditgesellschaft Auf Aktien Agent de nettoyage aqueux pour sols
JPH07118689A (ja) * 1993-10-20 1995-05-09 Lion Corp 硬表面洗浄剤組成物

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Cited By (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002036725A1 (fr) * 2000-11-02 2002-05-10 Unilever N.V. Composition pour le nettoyage de surfaces dures
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US7022662B2 (en) * 2001-11-02 2006-04-04 Cognis Deutschland Gmbh & Co. Kg Compositions containing hydroxy mixed ethers and polymers
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EP1149143B1 (fr) 2002-09-04
DK1149143T3 (da) 2003-01-06
DE59902606D1 (de) 2002-10-10
EP1149143A1 (fr) 2001-10-31

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