WO2014121406A1 - Produit de nettoyage - Google Patents

Produit de nettoyage Download PDF

Info

Publication number
WO2014121406A1
WO2014121406A1 PCT/CH2014/000011 CH2014000011W WO2014121406A1 WO 2014121406 A1 WO2014121406 A1 WO 2014121406A1 CH 2014000011 W CH2014000011 W CH 2014000011W WO 2014121406 A1 WO2014121406 A1 WO 2014121406A1
Authority
WO
WIPO (PCT)
Prior art keywords
cleaning agent
agent according
weight
parts
component
Prior art date
Application number
PCT/CH2014/000011
Other languages
German (de)
English (en)
Inventor
Remo WILD
Mirko LAAGER
Silvana CECCHETTO
Original Assignee
Wetrok Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wetrok Ag filed Critical Wetrok Ag
Priority to PL14702440T priority Critical patent/PL2954036T3/pl
Priority to MYPI2015702550A priority patent/MY182079A/en
Priority to SG11201506177RA priority patent/SG11201506177RA/en
Priority to EP14702440.0A priority patent/EP2954036B1/fr
Priority to JP2015556355A priority patent/JP2016507620A/ja
Publication of WO2014121406A1 publication Critical patent/WO2014121406A1/fr
Priority to ZA2015/05008A priority patent/ZA201505008B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/164—Organic compounds containing a carbon-carbon triple bond
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines

Definitions

  • the invention relates to a cleaning agent according to the preamble of patent claim 1.
  • the invention has for its object to provide a cleaning agent which shows an improved cleaning effect and achieves optimum results in its use for cleaning water-resistant, especially non-textile surfaces. Another object is to provide a cleaning agent which is optimally suited for use in scrubber driers.
  • the invention solves the problem with a cleaning agent having the features according to claim 1.
  • the mode of action of the inventive cleaning agent is based less on the principle of Schmutzemuigi für irritant by surfactants, but consists of the combination of two cleaning technologies.
  • the wetting agent used lowers the surface tension of the detergent diluted with water in less than 1 second to below 30mN / m (measured at room temperature), which in combination with the mechanical power of cleaning offers the possibility of dirt particles in the water to suspend the cleaning liquor.
  • an anti redeposition agent By combining with an anti redeposition agent, the dirt particles are held in suspension, which counteracts a Redeposition.
  • the emulsifier allows the poorly water-soluble wetting agent a fast, homogeneous distribution in the cleaning liquor and surprisingly gives her a greatly improved emulsifying effect.
  • the so-suspended, slightly negatively charged, dirt particles are electrostatically suspended due to the negative charges of the neutralized polyaspartic acid.
  • this is not used here for binding the existing Ca 2+ ions, but for electrosteric repulsion of the negatively charged dirt particles by the likewise negatively charged, long-chain molecules.
  • Defoamer can be dispensed with.
  • the negatively charged organic macromolecule is advantageously a polymeric anti-redeposition agent and may be selected from the following classes of substances: aminopolycarboxylates, organic phosphonates, polycarboxylates or copolymers thereof.
  • the at least one negatively charged organic macromolecule may be a polyaspartic acid or water-soluble salts thereof.
  • the negatively charged organic macromolecule may also be a polyacrylate, e.g. an acrylic homopolymer, preferably having a molecular weight of 4 ⁇ 00 to 6 ⁇ 00.
  • the nonionic surfactant may be an acetyldiol, preferably an alkoxylated acetyldiol; the anionic surfactant may be an anionic perfluoroalkyl polymer or an alkyl sulfosuccinate; the cationic surfactant may be a cationic perfluoroalkyl copolymer and the amphoteric surfactant may be an alkylamidopropyl betaine.
  • the wetting agent may also comprise one or more ethoxylated acetyl diols.
  • the nonionic emulsifier may be selected from the group of fatty alcohol alkoxylates; the anionic emulsifier can be selected from the group of alkyl sulfates or Alkyl ether sulfates may be selected; the cationic emulsifier may be selected from the group of quaternary ammonium compounds and the amphoteric emulsifier may be selected from the group of betaines and sultaines.
  • the emulsifier may also comprise one or more, preferably branched, ethoxylated fatty alcohols.
  • the polyaspartic acid (or its salts thereof) preferably has an average molecular weight between 1000-10 ⁇ 00 g / mol, preferably between 2000-3000 g / mol.
  • a particle size distribution D50 of 0.07 mm or even 0.01 mm gives particularly good results.
  • the detergent is preferably used in granular or tableted form, which simplifies storage.
  • the tablets have expediently a volume of at least 1 cm 3 , preferably at least 5 cm 3 .
  • the volume is expediently at most 100 cm 3 , preferably at most 12 cm 3 .
  • the maximum diameter of the tablets is expediently 10 cm, preferably 7 cm.
  • the minimum diameter of the tablets is expediently 1 cm, preferably 3 cm. These dimensions allow for optimal dosing and dissolution in water.
  • the detergent according to the invention is expediently dissolved in water shortly before use.
  • 500-10000 parts by weight of water can be used to dissolve it.
  • 600 to 1900 parts by weight of water, preferably 900 to 1300 parts by weight of water can be used for its dissolution.
  • the cleaning agent additionally contains a water-swelling substance, for example polyvinylpyrrolidone.
  • a water-swelling substance for example polyvinylpyrrolidone.
  • This dissolves in granular or tablet form detergent present faster in water.
  • the tablet-shaped detergent should expediently dissolve in water in less than 10 minutes, preferably less than 2 minutes.
  • the surface tension of the aqueous solution of the cleaning agent at room temperature can be lowered within a maximum of one second, preferably within not more than 0.6 seconds, to a value of less than 40 mN / m, preferably less than 30 mN / m.
  • the cleaning agent contains the following additional component:
  • the effervescent mixture is preferably a mixture of citric acid, bicarbonate and / or sodium carbonate.
  • the detergent may be a effervescent mixture of a carbonate and an organic acid, e.g. Citric acid, or a citrate are added. The excess of citrate serves to complex the calcium ions.
  • the branched, ethoxylated fatty alcohol is an iso C8-C18 nonionic surfactant which is preferably etherified with 2-20 ethylene oxide units.
  • the branched, ethoxylated fatty alcohol may be an iso C10-C14 nonionic surfactant which is preferably etherified with 5-10 ethylene oxide units.
  • the iso C8-C18 nonionic surfactant may be iso-C13 (10EO) or iso-C11 (7EO).
  • proportions of components a), b) and c) of the cleaning agent according to the invention may be in the following relationship to each other:
  • Component b 0.05-50 parts by weight
  • Component c 0.01-50 parts by weight.
  • Component a) 1-10 parts by weight
  • Component b) 0.5-5 parts by weight
  • Component c 0.1-5.0 parts by weight.
  • components a), b) and c) may be in the following relationship to each other:
  • Component c) 1-2 parts by weight.
  • Component d) 0.3-150 parts by weight j. preferably 3.0-15.0 parts by weight.
  • the inventive detergent is particularly suitable for use in scrubber-driers. It is particularly suitable for wet wiping and for manual or industrial foaming.
  • the cleaning agent may additionally contain a complexing agent.
  • the formulations represent the composition of a dosing unit (e.g., 1 tablet or 1 sachet or 1 powder ration, etc.) which is to be dissolved in 8-10 liters of water to obtain a suitable cleaning solution:
  • a dosing unit e.g., 1 tablet or 1 sachet or 1 powder ration, etc.
  • anionic fluorosurfactant C4-C6 straight-chain fluorinated hydrocarbon
  • Na-lauryl ether sulfate 2EO as emulsifier for the wetting agent
  • anionic fluorosurfactant C4-C6 straight-chain fluorinated hydrocarbon
  • fatty alcohol iso-C 12-14 8EO (as emulsifier for the wetting agent)
  • anionic fluoroetting agent C4-C6 straight-chain fluorinated hydrocarbon
  • Na-lauryl ether sulfate 2EO as emulsifier for the wetting agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un produit de nettoyage qui contient les composants suivants : a) au moins une macromolécule organique chargée négativement; b) au moins un agent mouillant non ionique, anionique, cationique ou amphotère; et c) au moins un agent émulsifiant non ionique, anionique, cationique ou amphotère pour le ou les agents mouillants. L'agent mouillant non ionique est un acétyldiol ou un polydiméthylsiloxane; l'agent mouillant anionique est un polymère d'alkyle perfluoré anionique ou un sulfosuccinate d'alkyle. L'agent mouillant cationique est un copolymère d'alkyle perfluoré cationique. L'agent mouillant amphotère est une alkylamidopropylbétaïne.
PCT/CH2014/000011 2013-02-06 2014-01-29 Produit de nettoyage WO2014121406A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
PL14702440T PL2954036T3 (pl) 2013-02-06 2014-01-29 Środek czyszczący
MYPI2015702550A MY182079A (en) 2013-02-06 2014-01-29 Cleaning composition
SG11201506177RA SG11201506177RA (en) 2013-02-06 2014-01-29 Cleaning agent
EP14702440.0A EP2954036B1 (fr) 2013-02-06 2014-01-29 Composition nettoyante
JP2015556355A JP2016507620A (ja) 2013-02-06 2014-01-29 洗浄剤
ZA2015/05008A ZA201505008B (en) 2013-02-06 2015-07-13 Cleaning agent

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE202013001148.3 2013-02-06
DE202013001148.3U DE202013001148U1 (de) 2013-02-06 2013-02-06 Reinigungsmittel

Publications (1)

Publication Number Publication Date
WO2014121406A1 true WO2014121406A1 (fr) 2014-08-14

Family

ID=50033295

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CH2014/000011 WO2014121406A1 (fr) 2013-02-06 2014-01-29 Produit de nettoyage

Country Status (8)

Country Link
EP (1) EP2954036B1 (fr)
JP (2) JP2016507620A (fr)
DE (1) DE202013001148U1 (fr)
MY (1) MY182079A (fr)
PL (1) PL2954036T3 (fr)
SG (1) SG11201506177RA (fr)
WO (1) WO2014121406A1 (fr)
ZA (1) ZA201505008B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10676621B2 (en) 2016-03-04 2020-06-09 S. C. Johnson & Son, Inc. Multi-purpose floor finish composition
US11603510B2 (en) 2019-03-06 2023-03-14 Ecolab Usa Inc. Concentrated solid hard surface cleaner

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* Cited by examiner, † Cited by third party
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US5500153A (en) * 1994-07-05 1996-03-19 The Procter & Gamble Company Handwash laundry detergent composition having improved mildness and cleaning performance
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* Cited by examiner, † Cited by third party
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WO2000046327A1 (fr) * 1999-02-02 2000-08-10 Henkel-Ecolab Gmbh & Co. Ohg Produit pour le nettoyage de surfaces dures
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US20050250668A1 (en) * 2004-05-05 2005-11-10 Serobian Ashot K Rheologically stabilized silicone dispersions
US20050255172A1 (en) * 2004-05-14 2005-11-17 Navid Omidbakhsh Hydrogen peroxide-based skin disinfectant
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10676621B2 (en) 2016-03-04 2020-06-09 S. C. Johnson & Son, Inc. Multi-purpose floor finish composition
US11214697B2 (en) 2016-03-04 2022-01-04 S. C. Johnson & Son, Inc. Multi-purpose floor finish composition
US11603510B2 (en) 2019-03-06 2023-03-14 Ecolab Usa Inc. Concentrated solid hard surface cleaner

Also Published As

Publication number Publication date
JP2018184606A (ja) 2018-11-22
EP2954036A1 (fr) 2015-12-16
EP2954036B1 (fr) 2019-03-06
JP2016507620A (ja) 2016-03-10
MY182079A (en) 2021-01-18
PL2954036T3 (pl) 2019-08-30
SG11201506177RA (en) 2015-09-29
DE202013001148U1 (de) 2014-05-07
ZA201505008B (en) 2017-07-26

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