EP1149143B1 - Produit pour le nettoyage de surfaces dures - Google Patents

Produit pour le nettoyage de surfaces dures Download PDF

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Publication number
EP1149143B1
EP1149143B1 EP99907471A EP99907471A EP1149143B1 EP 1149143 B1 EP1149143 B1 EP 1149143B1 EP 99907471 A EP99907471 A EP 99907471A EP 99907471 A EP99907471 A EP 99907471A EP 1149143 B1 EP1149143 B1 EP 1149143B1
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EP
European Patent Office
Prior art keywords
cleaning
molecule
composition
ethylene oxide
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99907471A
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German (de)
English (en)
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EP1149143A1 (fr
Inventor
Karl-Heinz Rogmann
Birgit Skodell
Heiko Faubel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecolab GmbH and Co OHG
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Ecolab GmbH and Co OHG
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Publication of EP1149143A1 publication Critical patent/EP1149143A1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the present invention relates to an aqueous agent for cleaning hard Surfaces that are a combination of soluble in the alkaline medium Contains polymer compounds and nonionic surfactants, as well as the use these agents for machine cleaning of floors.
  • the surfaces are already after very dirty in no time.
  • the cleaning is usually done in two steps, namely the Cleaning as such and subsequent preservation of the surface of the covering. Products that contain both cleaning and care products do not show any sufficient cleaning performance so that dirt builds up continuously.
  • solubility of film-forming substances is only limited, so that they will not come off completely and not or only during the next cleaning can be removed incompletely, so that it builds a strong Care film can come. This in turn affects the surefootedness and that visual appearance of the floor and does special cleaning at certain intervals required.
  • the present invention was therefore based on the object, the conventional cleaning agents to improve and thereby cleaning agents for hard surfaces, especially for the commercial sector, to develop a good cleaning performance show and at the same time preserve the surface so that the Cleaning in one operation and preferably with automatic cleaning machines can be carried out.
  • the agents according to the invention are preferably diluted with water used, the application concentration usually between 0.5 and 5 wt .-%, preferably between 2 and 5 wt .-%, based on the application solution.
  • the Can be used manually or in conventional cleaning machines, for example by applying the cleaning solution and then mechanical scrubbing with scrubber driers or other scrubbing machines.
  • the loosened dirt is well dispersed in the detergent fleet, so that it does not re-enter deposits the pores of the soil material before the liquor is suctioned off. After this Scrubbing-suction process does not rinse the floor, the remaining moisture dries up.
  • a wafer-thin care film forms on the surface Prevents or reduces the adherence of dirt. This care film will completely dissolved again during the next cleaning process and forms again from the remaining residual moisture.
  • the cleaning agent according to the invention is also particularly characterized by that the surfactant combination has a wide range of oily and pigmented. Dirt removed.
  • the cleaning performance ranges from that of special cleaning active anionic detergents, but has the advantage that at no excessive amounts of foam are generated when using them impair the continuous operation of the cleaning machines.
  • Suitable polymers according to the invention are generally all polymer compounds which are soluble in water in the alkaline range, provided that they are not metal-crosslinked.
  • the film-forming temperature is preferably between 0 and 80 ° C. These are preferably (meth) acrylic acid (ester) copolymers. Solubility is usually achieved through carboxylic acid groups.
  • Polymers used with preference contain a (meth) acrylate copolymer of 1 to 30 parts by weight, based on the copolymer, carboxylic acid-containing monomers, 30 to 70 parts by weight, based on the copolymer, of monomers which form homopolymers with glass transition temperatures below 20 ° C., preferably C 1 -C 6 -alkyl esters of acrylic acid and / or the C 4 -C 8 -alkyl esters of methacrylic acid, and 30 to 70 parts by weight, based on the copolymer, of comonomers which form homopolymers with glass transition temperatures above room temperature, preferably C 1 -C 3 -alkyl esters the (meth) acrylic acid or styrene.
  • a (meth) acrylate copolymer of 1 to 30 parts by weight, based on the copolymer, carboxylic acid-containing monomers, 30 to 70 parts by weight, based on the copolymer, of monomers which form homo
  • Comonomers containing carboxylic acid groups are, in particular, ethylenic unsaturated carboxylic acids are suitable, with acrylic acid and methacrylic acid being preferred are.
  • Suitable comonomers with glass transition temperatures below 20 ° C. that is to say glass transition temperatures below room temperature (in each case based on the homopolymers of the monomers), are suitable C 1 -C 3 -alkyl esters of (meth) acrylic acid, such as, for example, methyl methacrylate or ethyl methacrylate.
  • a particularly preferred comonomer whose homopolymer has a glass transition temperature above room temperature is styrene.
  • Copolymers used with preference are those of acrylic acid and / or (Meth) acrylic acid with styrene, acrylic acid esters and / or methacrylic acid esters.
  • the copolymers of (meth) acrylic acid are particularly preferred (Meth) acrylic acid esters and / or styrene, e.g. for example copolymers Acrylic acid methyl ester, acrylic acid ethyl ester, methacrylic acid and styrene.
  • the monomers are present in the copolymers in proportions such that the Film formation temperature of the finished copolymer dispersion is between 0 and 80 ° C.
  • the Setting the proportions of comonomers around this film-forming temperature received, is familiar to the expert. Obtain the specified film formation temperatures softener-free systems, i.e. on copolymers without further additives.
  • Polymers are preferably used which are only in the alkaline range are water soluble while they are insoluble in the acidic range. Such products are commercially available and are offered in emulsified form.
  • the polymers of component A are present in an amount of 5 up to 45% by weight, preferably 5 to 30% by weight and in particular 8 to 20% by weight, based on the finished agent and calculated as a pure polymer.
  • the surfactants contained as component B are commercially available products that are in a Amount from 2 to 90 wt .-%, preferably from 5 to 65 wt .-%, and in particular from 5 to 35 wt .-% based on the finished agent are included.
  • the pH of the agents according to the invention is preferably between 8 and 10 .mu.m to ensure the solubility of the polymer compounds of component A.
  • Alkalizing agents can be used both volatile and solid alkalis, such as NaOH and KOH, alkali carbonates, ammonia, water glass and / or amines, such as Alkylamines and alkanolamines, preferably ammonia or alkanolamines be used. With the amount of the alkalizing agent it should be taken into account that when using commercially available polymer emulsions as component A, these already may contain small amounts of alkalizing agents.
  • the agents according to the invention can contain anionic surfactants and other nonionic surfactants other than component B as cosurfactants, Alkalizing agent, alkaline complexing agent, miscible with water organic solvents, cleaning-active salts, solubilizing agents and others Contain usual additives.
  • Suitable anionic co-surfactants in particular C 8 -C 22 alkanesulfonates, C 8 -C 22 alkylbenzenesulfonates, C 8 -C 22 alkyl sulfates, C 8 -C 22 -Fettklarestersulfonate, C 8 -C 22 fatty alcohol ether sulfates, fatty acid soaps or mixtures thereof can be used become.
  • Anionic cosurfactants can be added in an amount of up to 3% by weight, preferably from 0.5 to 1% by weight, based on the finished composition.
  • nonionic cosurfactants are the adducts of 13 to 40 moles of ethylene oxide with C 8 -C 22 alcohols or from 1 to 40 moles of ethylene oxide with C 8 -C 22 alkylphenols and the alkyl polyglycosides.
  • the nonionic cosurfactants can be used in an amount of up to 8% by weight, in particular up to 6% by weight and particularly preferably up to 2% by weight. based on the finished product.
  • the cleaning agents according to the invention can be used as so-called normal products Concentrates and pastes are present, it being known to the person skilled in the art that the transitions are fluent between these products.
  • Normal products are usually liquid and represent solutions of their ingredients.
  • the so-called concentrates are Solutions or emulsions of the ingredients and have a liquid to viscous Consistency.
  • surfactants can usually be used in an amount of up to 35% by weight, in concentrates up to 65% by weight and in pastes in an amount up to 90 % By weight may be included.
  • the third possible embodiment is the pastes that can be dosed using suitable devices.
  • the pastes contain the active ones Ingredients in an amount up to 95 wt .-%. On additives and solvents preferably not used in pastes.
  • the agents according to the invention can be used as further optional components Contain complexing agents that are capable of being affected by an extreme Compensate for water hardness when using the agents.
  • Complexing agents that are capable of being affected by an extreme Compensate for water hardness when using the agents.
  • NTA-Na and / or sodium gluconate are preferred used.
  • the complexing agents can be used in an amount of up to 8% by weight, preferably 0.5 to 5 wt .-%, based on the finished agent, are used. If the agent contains phosphates, the amount of complexing agents can be lower.
  • water-miscible organic solvents can be used be included, with fat-dissolving solvents being preferred.
  • suitable solvents are mono- and dialcohols, ether alcohols and polyethers.
  • Typical representatives can be isopropanol, butyl glycol, ethylene glycol monophenyl ether, Dimethyldiglykol and Methylpyrrolidon be called.
  • Preferably lower ones Ether alcohols, for example mono- or diethylene monoalkyl ethers with 1 to 4 Carbon atoms used in the alkyl group.
  • the solvent content is not more than 30% by weight, preferably not more than 20% by weight and in particular between 0.5 and 10% by weight, based on the finished agent.
  • alkaline salts such as B. polyphosphates and pyrophosphates, in particular Sodium tripolyphosphate or tetrapotassium pyrophosphate.
  • B. polyphosphates and pyrophosphates in particular Sodium tripolyphosphate or tetrapotassium pyrophosphate.
  • These salts will be preferably in an amount of 2 to 8% by weight, but at most 15% by weight, based on the finished agent used.
  • solubilizers such.
  • the brokers can in agents according to the invention in amounts of up to 10% by weight, in particular 1 to 6% by weight, each based on the finished agent. Also have fatty acid soaps solvent properties. If the detergent contains soap, the The amount of solubilizers usually has to be very small.
  • the agents according to the invention can also contain inorganic agents as further optional components Neutral salts, colors and fragrances, thickeners and corrosion inhibitors as well as possibly Disinfectant may be included.
  • the amount of additives is preferably not more than 5% by weight, preferably not more than 2% by weight and in particular of 0.05 to 1 wt .-%, based on the finished agent.
  • detergents for Auxiliaries customary for commercial purposes can also be included, provided that they do not affect the effect of the invention.
  • the agent contains 5 to 30% by weight of a polymer of component A, 2 to 45% by weight of surfactants Component B, up to 6% by weight of further nonionic surfactants, up to 2% by weight anionic surfactants, up to 30% by weight alkalizing agent, up to 5% by weight alkaline reacting complexing agents, up to 30% by weight water-miscible organic Solvents and up to 8% by weight of other additives, such as solubilizers, thickeners, Dyes and fragrances.
  • Another object of the present invention relates to the use of Above described means for cleaning hard surfaces, in particular of floors with a rough surface, preferably for machine cleaning of Floors.
  • Tables 1 and 2 show the compositions of six of the invention Recipes and six comparison formulations reproduced.
  • the quantities of the individual components are percentages by weight and relate to the finished product and anhydrous raw materials.
  • the cleaning effect of the wiping care products was checked with the help of a Gardner washability and abrasion tester as determined in the quality standards of the industrial association Putz- und Vietnamesestoff e.V. is described (soap-oil-fat-waxes, 108, pages 526-528 (1982)).
  • This method uses a white PVC film with a test soiling made of soot and fat and under standardized conditions with a the sponge soaked in the cleaning agent is wiped mechanically.
  • the Cleaning performance is determined by photoelectric determination of the reflectance measured.
  • the care effect is shown, among other things, by the fact that a film from previous treatments with the same agent facilitates the detachment of subsequently applied soiling.
  • the test method specified above was therefore modified in such a way that the film was wiped with the wiping agent to be tested and then dried before the same stain was applied. After applying the soiling, the test was then carried out like the cleaning performance:
  • the wiping agents 1 to 6 Excellent cleaning performance over both non-pretreated and also have compared to pretreated film.
  • the pretreated film is used the dirt is removed even better than from the original film.
  • the for By comparison, means R1-R3 / P1-P3 used show good ones Cleaning services either only on untreated film (6) or only on pretreated film.
  • the agents not according to the invention are in their care effect quite comparable to the agents according to the invention, but perform differently than these, after multiple application to a film addition, the natural look and the Impair the sure-footedness of the treated surfaces.
  • the sliding friction was measured. It was made with a neutral lubricant (standardized filter paper) measured.
  • the sliding friction value of 0.650 represents the original covering. The lower the sliding friction value, the slippery the surface.
  • the second value given in the table indicates the foam breakdown, where values above 70/70 ml show problems with too much foam, what in practice causes the scrubber drier early due to the foam pad turns off and the capacity of the device can not be fully used.
  • the dispersibility was measured using a standardized test dirt Shake method determined.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (10)

  1. Produit aqueux pour le nettoyage de surfaces dures ayant une valeur de pH au-dessus de 7 qui contient:
    A) de 5 à 45 % en poids d'au moins un composé polymère qui n'est pas mouillé par des ions métalliques, soluble en milieu alcalin, ayant une température de formation de film comprise entre 0 et 80°C,
    B) de 2 à 90 % en poids d'une combinaison d'agents tensioactifs à base d'alcools gras en C6-C18 linéaires alkoxylés avec 1 à 10 groupes oxyde d'éthylène et de 1 à 5 groupes oxyde de propylène, les groupes OH libres pouvant être bloqués par un groupe alkyle en C1 à C4, et au moins un autre agent tensioactif choisi dans le groupe qui consiste en des alcools en C8-C18 à chaíre ramifiée alkoxyles avec de 1 à 8 éléments d'oxyde d'éthylène dans la molécule, les groupes OH libres pouvant être bloqués par un groupe alkyle en C1-C4, des éthoxylates d'alcool gras en C8-C18 avec de 1 à 12 éléments d'oxyde d'éthylène dans la molécule et des éthers mixtes hydroxylés ayant la formule I suivante : R1O[CH2CH(CH3)O]x(CH2CHR2O)y[CH2CH(OH)]zR3 dans laquelle
    R1 signifie un reste hydrocarboné aliphatique, linéaire ayant en moyenne de 4 à 18 atomes de carbone dans la molécule, y compris leurs mélanges.
    R2 signifie un atome d'hydrogène ou un groupe alkyle ayant de 1 à 6 atomes de carbone, et
    R3 signifie un reste hydrocarboné aliphatique linéaire ayant en moyenne de 2 à 14 atomes de carbone y compris leur mélange,
    x représente O ou 1 à 5,
    y représente 1 à 30, et
    z représente 1 à 3.
  2. Produit selon la revendication 1,
    caractérisé en ce que
    les composants A et B sont présents dans le rapport de 1:1 à 10:1, de préférence de 5:1 à 1:1.
  3. Produit selon la revendication 1 ou la revendication 2,
    caractérisé en ce que
    comme composé polymère soluble en milieu alcalin, il contient des copolymérisats à base d'acide(méth)acrylique avec des esters d'acide(méth)acrylique et/ou du styrène, de préférence des copolymérisats à base d'ester méthylique d'acide acrylique, d'ester d'éthyle d'acide acrylique, d'acide méthacrylique et de styrène.
  4. Produit selon l'une quelconque des revendications 1 à 3,
    caractérisé en ce que
    la valeur du pH est ajustée avec un agent d'alcalinisation choisi dans le groupe consistant en NaOH, KOH, l'ammoniac, les silicates solubles, les carbonates de métal alcalin, et/ou des amines, de préférence à des valeurs comprises entre 8 et 10.
  5. Produit selon l'une quelconque des revendications 1 à 4,
    caractérisé en ce que
    des co-agents tensioactifs anioniques et non ioniques, des agents d'alcalinisation, des agents complexants à réaction alcaline, des solvants organiques miscibles à l'eau, des sels actifs pour le nettoyage, des agents de solubilisation, ainsi que d'autres additifs usuels, sont contenus.
  6. Produit selon l'une quelconque des revendications 1 à 5,
    caractérisé en ce qu'
    il contient des co-agents anioniques choisis dans le groupe des (alkane enC8-C22) sulfonates, des (alkyl en C8 à C22) benzène sulfonates, des (alkyl en C8-C22) sulfates, des sulfonates d'ester d'acide gras en C8 à C22, des sulfates d'éther d'alcool gras en C8 à C22, des savons d'acide gras et leurs mélanges.
  7. Produit selon l'une quelconque des revendications 1 à 6,
    caractérisé en ce qu'
    il contient des co-agents tensioactifs non ionique choisis dans le groupe des adduits de 13 à 40 mol d'oxyde d'éthylène sur des alcools en C8-C22, des adduits de 1 à 40 mol d'oxyde d'éthylène sur des (alkyl en C8-C22) phénols, des alkylpolyglycosides et leurs mélanges.
  8. Utilisation du produit de nettoyage selon l'une quelconque des revendications 1 à 7, après dilution en vue du nettoyage de surfaces dures, en particulier de planchers ayant des surfaces rugueuses.
  9. Utilisation selon la revendication 8 en vue du nettoyage de planchers à la machine.
  10. Procédé de nettoyage à la machine de surfaces dures, selon lequel les surfaces sont traitées d'une manière connue en soi avec des machines de nettoyage en utilisant une solution de nettoyage aqueuse,
    caractérisé en ce que
    la solution de nettoyage est produite en utilisant un produit aqueux de nettoyage ayant une valeur de pH supérieure à 7 qui contient les constituants suivants :
    A) de 5 à 45 % en poids d'au moins un composé polymère qui n'est pas mouillé par des ions métalliques, soluble en milieu alcalin, ayant une température de formation de film comprise entre O et 80°C.
    B) de 2 à 90 % en poids d'une combinaison d'agents tensioactifs à base d'alcools gras en C8-C18 linéaires alkoxylés avec 1 à 10 groupes oxyde d'éthylène et de 1 à 5 groupes oxyde de propylène, les groupes OH libres pouvant être bloqués par un groupe alkyle en C1 à C4, et au moins un autre agent tensloactif choisi dans le groupe qui consiste en des alcools en C8-C18 à chaíne ramifiée alkoxylés ayant de 1 à 8 éléments d'oxyde d'éthylène dans la molécule, les groupes OH libres pouvant être bloqués par un groupe alkyle en C1-C4, des éthoxylates d'alcool gras en C8-C18 ayant de 1 à 12 éléments d'oxyde d'éthylène dans la molécule et des éthers mixtes hydroxylés ayant la formule I suivante : R1O[CH2CH(CH3)O]x(CH2CHR2O)y[CH2CH(OH)]zR3 dans laquelle
    R1 signifie un reste hydrocarboné aliphatique, linéaire ayant en moyenne de 4 à 18 atomes de carbone dans la molécule, y compris leurs mélanges,
    R2 signifie un alome d'hydrogène ou un groupe alkyle ayant de 1 à 6 atomes de carbone, et
    R3 signifie un reste hydrocarboné aliphatique linéaire ayant en moyenne de 2 à 14 atomes de carbone y compris leur mélange,
    x représente O ou 1 à 5,
    y représente 1 à 30, et
    z représente 1 à 3.
EP99907471A 1999-02-02 1999-02-02 Produit pour le nettoyage de surfaces dures Expired - Lifetime EP1149143B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP1999/000643 WO2000046327A1 (fr) 1999-02-02 1999-02-02 Produit pour le nettoyage de surfaces dures

Publications (2)

Publication Number Publication Date
EP1149143A1 EP1149143A1 (fr) 2001-10-31
EP1149143B1 true EP1149143B1 (fr) 2002-09-04

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Country Link
EP (1) EP1149143B1 (fr)
DE (1) DE59902606D1 (fr)
DK (1) DK1149143T3 (fr)
WO (1) WO2000046327A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106635436A (zh) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 一种新型运动地板清洁剂

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2002220660A1 (en) * 2000-11-02 2002-05-15 Brunt, Thomas Alexander Composition for cleaning hard surfaces
DE50200978D1 (de) * 2001-02-01 2004-10-21 Cognis Deutschland Gmbh Spül- und Reinigungsmittel
DE10153768A1 (de) * 2001-11-02 2003-05-15 Cognis Deutschland Gmbh Hydroxymischether mit Polymeren
DE10229421A1 (de) * 2002-06-29 2004-01-29 Ecolab Gmbh & Co. Ohg Bodenreinigungs- und/oder Pflegemittel
US7279455B2 (en) * 2003-11-06 2007-10-09 Ecolab, Inc. Rinse aid composition and method of rising a substrate
DE102004053015A1 (de) 2004-11-03 2006-05-04 Lanxess Deutschland Gmbh Rußreiniger
CN101479373B (zh) * 2006-07-14 2011-06-08 埃科莱布有限公司 碱性地板清洁组合物和清洁地板的方法
US7521412B2 (en) 2007-05-25 2009-04-21 Ecolab Inc. Dimensionally stable solid rinse aid
US8383570B2 (en) 2007-05-25 2013-02-26 Ecolab Usa Inc. Enhanced melting point rinse aid solid compositions with synergistic preservative
US20110108068A1 (en) 2007-05-25 2011-05-12 Ecolab Usa Inc. Enhanced melting point rinse aid solids
AU2010247013B2 (en) 2009-05-12 2015-02-26 Ecolab Usa Inc. Fast drying and fast draining rinse aid
US8567161B2 (en) 2009-05-28 2013-10-29 Ecolab Usa Inc. Wetting agents for aseptic filling
US9011610B2 (en) 2012-06-22 2015-04-21 Ecolab Usa Inc. Solid fast draining/drying rinse aid for high total dissolved solid water conditions
US9567551B2 (en) 2012-06-22 2017-02-14 Ecolab Usa Inc. Solid rinse aid composition and method of making same
DE202013001148U1 (de) * 2013-02-06 2014-05-07 Wetrok Ag Reinigungsmittel
WO2015120560A1 (fr) * 2014-02-11 2015-08-20 Wetrok Ag Produit pour décaper des surfaces
US10550354B2 (en) 2015-05-19 2020-02-04 Ecolab Usa Inc. Efficient surfactant system on plastic and all types of ware
CN109153947B (zh) 2016-05-23 2021-03-16 埃科莱布美国股份有限公司 通过使用高分子量油包水乳液聚合物的减少雾化的碱性和中性清洁、消毒和杀菌组合物
JP6791987B2 (ja) 2016-05-23 2020-11-25 エコラボ ユーエスエー インコーポレイティド 高分子量油中水型乳化ポリマーを用いた、ミスティングが低減した酸性洗浄、除菌および消毒組成物の削減
CA3054827C (fr) 2017-03-01 2023-02-14 Ecolab Usa Inc. Assainisseurs et desinfectants a risques d'inhalation reduits par l'intermediaire de polymeres de poids moleculaire eleve
CA3107070A1 (fr) 2018-07-25 2020-01-30 Ecolab Usa Inc. Formulation d'adjuvant de rincage pour le nettoyage de pieces automobiles
WO2021011451A1 (fr) 2019-07-12 2021-01-21 Ecolab Usa Inc. Agent de nettoyage alcalin à buée réduite par l'utilisation de polymères en émulsion solubles dans les alcalis

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1528592A (en) * 1974-12-10 1978-10-11 Procter & Gamble Floor care and cleaning composition
ATE68519T1 (de) * 1986-07-24 1991-11-15 Henkel Kgaa Schaumarme und/oder schaumdaempfende tensidgemische und ihre verwendung.
CA2004310C (fr) * 1989-05-05 1995-02-21 John Jerome Burke Agent nettoyant de surface dure contenant des polymeres de polyacrylate servant de renforcateur detersif
JP3007916B2 (ja) * 1991-06-03 2000-02-14 ライオン株式会社 金属表面洗浄用水性液状アルカリ洗浄剤組成物
DE4335046A1 (de) * 1993-10-14 1995-04-20 Henkel Kgaa Wäßriges Fußbodenreinigungsmittel
JPH07118689A (ja) * 1993-10-20 1995-05-09 Lion Corp 硬表面洗浄剤組成物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106635436A (zh) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 一种新型运动地板清洁剂

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EP1149143A1 (fr) 2001-10-31
DE59902606D1 (de) 2002-10-10
DK1149143T3 (da) 2003-01-06
WO2000046327A1 (fr) 2000-08-10

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