EP0633924B1 - Utilisation de detergents pour surfaces dures, notamment en verre - Google Patents
Utilisation de detergents pour surfaces dures, notamment en verre Download PDFInfo
- Publication number
- EP0633924B1 EP0633924B1 EP93908848A EP93908848A EP0633924B1 EP 0633924 B1 EP0633924 B1 EP 0633924B1 EP 93908848 A EP93908848 A EP 93908848A EP 93908848 A EP93908848 A EP 93908848A EP 0633924 B1 EP0633924 B1 EP 0633924B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- cleaning composition
- mixtures
- water
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011521 glass Substances 0.000 title claims description 5
- 239000003599 detergent Substances 0.000 title abstract description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 40
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 23
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 19
- 239000003960 organic solvent Substances 0.000 claims abstract description 17
- 239000003513 alkali Substances 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 32
- 238000004140 cleaning Methods 0.000 claims description 26
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000003945 anionic surfactant Substances 0.000 claims description 14
- 239000002736 nonionic surfactant Substances 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- -1 ether alcohols Chemical class 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 10
- 150000001735 carboxylic acids Chemical class 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 8
- 150000001298 alcohols Chemical class 0.000 claims description 8
- 239000012141 concentrate Substances 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 4
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 239000002250 absorbent Substances 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 1
- 238000007865 diluting Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 30
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 17
- 125000000129 anionic group Chemical group 0.000 abstract description 4
- 238000011086 high cleaning Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract 1
- 239000012459 cleaning agent Substances 0.000 description 18
- 230000000694 effects Effects 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- GQCZPFJGIXHZMB-UHFFFAOYSA-N 1-tert-Butoxy-2-propanol Chemical compound CC(O)COC(C)(C)C GQCZPFJGIXHZMB-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 125000003563 glycoside group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Definitions
- ethanol isopropanol and n-propanol are used as alcohols, of which in turn ethanol is particularly preferred.
- Sufficiently water-soluble compounds with up to 10 carbon atoms in the molecule are suitable as ether alcohols.
- ether alcohols are ethylene glycol monobutyl ether, propylene glycol monobutyl ether, Diethylene glycol monobutyl ether, propylene glycol mono-tertiary butyl ether and propylene glycol monoethyl ether.
- Ethylene glycol monobutyl ether and propylene glycol monobutyl ether are particularly preferred in the context of the invention.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Claims (11)
- Utilisation d'un produit aqueux pour le nettoyage des surfaces dures, dans laquelle ce produit contient un tensio-actif anionique, un solvant organique miscible avec l'eau, choisi dans le groupe des alcools, des éther-alcools et de leurs mélanges, un alcali choisi dans le groupe de l'ammoniac, des alcanolamines ayant jusqu'à 9 atomes de carbone et de leurs mélanges, ainsi qu'un acide carboxylique ayant jusqu'à 6 atomes de carbone ou un mélange de ces acides carboxyliques et avec un rapport des équivalents, dans ce produit, de l'amine et/ou de l'ammoniac à l'acide carboxylique compris entre 1:0,9 et 1:0,1.
- Utilisation selon la revendication 1, dans laquelle le produit de nettoyage contient, en outre, un tensio-actif non ionique.
- Utilisation selon l'une des revendications 1 à 2, dans laquelle, dans le produit de nettoyage, l'acide carboxylique est choisi dans le groupe constitué de l'acide acétique, de l'acide citrique, de l'acide lactique ou de leurs mélanges.
- Utilisation selon l'une des revendications 1 ou 2, dans laquelle le produit de nettoyage contient de l'ammoniaque et une éthanolamine choisie dans le groupe de la mono-, de la di- et de la triéthanolamine, ainsi que de leurs mélanges et contient, de préférence, de la monoéthanolamine.
- Utilisation selon l'une des revendications 1 ou 2, dans laquelle le produit de nettoyage contient comme solvant organique miscible avec l'eau, un mélange d'un alcool inférieur ayant 2 ou 3 atomes de carbone et d'éther glycolique choisi dans le groupe constitué de l'éther monobutylique de l'éthylèneglycol, de l'éther monobutylique du propylèneglycol et leurs mélanges.
- Utilisation selon l'une des revendications 1 ou 2, dans laquelle, dans le produit de nettoyage, l'agent tensio-actif anionique est choisi dans le groupe constitué des alcanesulfonates, des alkyléthersulfates, des alkylsulfates et de leurs mélanges.
- Utilisation selon la revendication 2, dans laquelle, dans le produit de nettoyage, l'agent tensio-actif non ionique est choisi dans le groupe constitué des éthoxylates d'alcools à longue chaîne, des alkylpolyglycosides et de leurs mélanges.
- Utilisation selon la revendication 7, dans laquelle, dans le produit de nettoyage, on utilise une combinaison de tensio-actifs constituée d'un alkyle sulfate gras et d'alkylpolyglycoside.
- Utilisation selon la revendication 1, dans laquelle le produit de nettoyage contient les substances actives ci-après:0,05 à 0,3% en poids de tensio-actifs anioniques,0 à 0,15% en poids de tensio-actifs non ioniques,0,5 à 15% en poids de solvants organiques miscibles avec l'eau,0,1 à 3% en poids d'ammoniac et/ou d'alcanolamines0,05 à 3% en poids d'acide carboxylique0 à 2% en poids d'autres adjuvants usuelsjusqu'à 100% en poids d'eau.
- Utilisation selon la revendication 1, dans laquelle le produit de nettoyage est préparé par dilution d'un concentré contenant les substances actives suivantes:0,3 à 3% en poids de tensio-actifs anioniques,0 à 1% en poids de tensio-actifs non ioniques,10 à 50% en poids de solvants organiques miscibles avec l'eau,1 à 10% en poids d'ammoniac et/ou d'alcanolamines1 à 10% en poids d'acide carboxylique0 à 10% en poids d'autres adjuvants usuelsjusqu'à 100% en poids d'eau, avec un minimum de 10%.
- Utilisation selon l'une des revendications 1 à 10, pour le nettoyage de surfaces dures et, en particulier de verre, le produit de nettoyage étant appliqué en quantité de 1,5 à 5 g/m2 sur la surface à traiter, de préférence par pulvérisation, et lesdites surfaces étant essuyées ensuite avec un objet mou et absorbant.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4210364 | 1992-03-30 | ||
| DE4210364A DE4210364B4 (de) | 1992-03-30 | 1992-03-30 | Reinigungsmittel für harte Oberflächen, insbesondere Glas |
| PCT/EP1993/000689 WO1993020176A1 (fr) | 1992-03-30 | 1993-03-22 | Detergent pour surfaces dures, notamment en verre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0633924A1 EP0633924A1 (fr) | 1995-01-18 |
| EP0633924B1 true EP0633924B1 (fr) | 1996-06-19 |
Family
ID=6455409
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP93908848A Expired - Lifetime EP0633924B1 (fr) | 1992-03-30 | 1993-03-22 | Utilisation de detergents pour surfaces dures, notamment en verre |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0633924B1 (fr) |
| JP (1) | JPH07505182A (fr) |
| AT (1) | ATE139561T1 (fr) |
| CA (1) | CA2133468A1 (fr) |
| DE (2) | DE4210364B4 (fr) |
| DK (1) | DK0633924T3 (fr) |
| ES (1) | ES2088671T3 (fr) |
| GR (1) | GR3020378T3 (fr) |
| WO (1) | WO1993020176A1 (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5531933A (en) * | 1993-12-30 | 1996-07-02 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing specific polycarboxylate detergent builders |
| AU675833B2 (en) * | 1994-03-23 | 1997-02-20 | Amway Corporation | Concentrated all-purpose light duty liquid cleaning composition and method of use |
| US5534198A (en) * | 1994-08-02 | 1996-07-09 | The Procter & Gamble Company | Glass cleaner compositions having good filming/streaking characteristics and substantive modifier to provide long lasting hydrophilicity |
| EP0842251B1 (fr) | 1996-02-14 | 2005-10-26 | Stepan Company | Produit de nettoyage pour surfaces dures, contenant un hydrotrope et laissant peu de residus |
| GB9911818D0 (en) † | 1999-05-21 | 1999-07-21 | Reckitt & Colman Inc | Improvements in or relating to organic compositions |
| DE10258831A1 (de) * | 2002-12-17 | 2004-07-08 | Henkel Kgaa | Reinigungsmittel für harte Oberflächen |
| DE102010007321B4 (de) * | 2010-02-08 | 2017-11-09 | Chemische Werke Kluthe Gmbh | Wässrige Reinigungslösung, insbesondere zur Entfernung von Lackanhaftungen, sowie Konzentratzusammensetzung zur Bereitstellung einer wässrigen Reinigungslösung |
| CN105283530A (zh) * | 2013-05-24 | 2016-01-27 | 宝洁公司 | 浓缩型表面活性剂组合物 |
| US11937602B2 (en) | 2017-09-26 | 2024-03-26 | Ecolab Usa Inc. | Solid acid/anionic antimicrobial and virucidal compositions and uses thereof |
| AU2020408331B2 (en) | 2019-12-16 | 2023-12-14 | Ecolab Usa Inc. | Anionic surfactant impact on virucidal efficacy |
| WO2022241180A1 (fr) | 2021-05-14 | 2022-11-17 | Ecolab Usa Inc. | Retraitement d'instrument par neutralisation |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3839234A (en) * | 1973-01-26 | 1974-10-01 | C Roscoe | Multi-purpose cleaning concentrate |
| DE3642564A1 (de) * | 1985-12-12 | 1987-07-09 | Lion Corp | Fluessiges wasch- und reinigungsmittel |
| DE3713998A1 (de) * | 1987-04-27 | 1988-11-10 | Henkel Kgaa | Reinigungsmittel fuer harte oberflaechen |
| US4943392A (en) * | 1988-06-03 | 1990-07-24 | The Procter & Gamble Company | Containing butoxy-propanol with low secondary isomer content |
| AU4702289A (en) * | 1989-01-19 | 1990-07-26 | Sterling Drug Inc. | Hard surface cleaning composition |
| DE3910974A1 (de) * | 1989-04-05 | 1990-10-11 | Henkel Kgaa | Fluessigwaschmittel |
| GB8909157D0 (en) * | 1989-04-21 | 1989-06-07 | Procter & Gamble | Hard-surface cleaning compositions |
| DE3943070A1 (de) * | 1989-12-27 | 1991-07-04 | Henkel Kgaa | Fluessiges reinigungsmittel fuer harte oberflaechen |
-
1992
- 1992-03-30 DE DE4210364A patent/DE4210364B4/de not_active Expired - Fee Related
-
1993
- 1993-03-22 ES ES93908848T patent/ES2088671T3/es not_active Expired - Lifetime
- 1993-03-22 DE DE59303027T patent/DE59303027D1/de not_active Expired - Lifetime
- 1993-03-22 DK DK93908848.0T patent/DK0633924T3/da active
- 1993-03-22 JP JP5517037A patent/JPH07505182A/ja active Pending
- 1993-03-22 AT AT93908848T patent/ATE139561T1/de not_active IP Right Cessation
- 1993-03-22 WO PCT/EP1993/000689 patent/WO1993020176A1/fr not_active Ceased
- 1993-03-22 CA CA002133468A patent/CA2133468A1/fr not_active Abandoned
- 1993-03-22 EP EP93908848A patent/EP0633924B1/fr not_active Expired - Lifetime
-
1996
- 1996-06-27 GR GR960401749T patent/GR3020378T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GR3020378T3 (en) | 1996-09-30 |
| WO1993020176A1 (fr) | 1993-10-14 |
| JPH07505182A (ja) | 1995-06-08 |
| CA2133468A1 (fr) | 1993-10-14 |
| ATE139561T1 (de) | 1996-07-15 |
| DK0633924T3 (da) | 1996-10-21 |
| EP0633924A1 (fr) | 1995-01-18 |
| ES2088671T3 (es) | 1996-08-16 |
| DE59303027D1 (de) | 1996-07-25 |
| DE4210364A1 (de) | 1993-10-07 |
| DE4210364B4 (de) | 2006-05-18 |
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