WO2000041891A1 - Stratifie pouvant etre imprime - Google Patents

Stratifie pouvant etre imprime Download PDF

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Publication number
WO2000041891A1
WO2000041891A1 PCT/GB2000/000085 GB0000085W WO0041891A1 WO 2000041891 A1 WO2000041891 A1 WO 2000041891A1 GB 0000085 W GB0000085 W GB 0000085W WO 0041891 A1 WO0041891 A1 WO 0041891A1
Authority
WO
WIPO (PCT)
Prior art keywords
recording layer
layer
printable laminate
viscoeiastic
tne
Prior art date
Application number
PCT/GB2000/000085
Other languages
English (en)
Inventor
Colin J. Cook
Hazel A. Warden
Original Assignee
Hunt Graphics Europe Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunt Graphics Europe Ltd. filed Critical Hunt Graphics Europe Ltd.
Priority to EP00900282A priority Critical patent/EP1144196A1/fr
Priority to AU19945/00A priority patent/AU1994500A/en
Priority to JP2000593482A priority patent/JP2003534144A/ja
Priority to KR1020017008901A priority patent/KR20010112242A/ko
Publication of WO2000041891A1 publication Critical patent/WO2000041891A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B41M5/5281—Polyurethanes or polyureas

Definitions

  • a target substrate can be one of any number of materials including fabrics , ceramic materials , posterboard, rigid PVC, or mounting board such as, foam board or expanded PVC board which are widely used in the graphic art industry.
  • the typical recording medium for receiving and transferring an image formed by an ink- jet printer has a carrier and at least two of the following layers : a release layer, a protective barrier layer, image transfer layer, and an adhesive layer.
  • the International Application PCT/GB98/00481 filed February i ⁇ , 1998 for "TRANSFER FILM" describes a carrier having a transfer film which has only one layer. This single layer is a mixture of heat-activatable adhesive particles and a binder that also is ink-absorbing, thereby defining a porous matrix.
  • a transfer film can be adhered to the target substrate without removing the carrier, whereby the carrier remains affixed to the layer holding the printed image, thereby providing physical protection for the image.
  • Patent Application 09/107,302 filed June 20, 1998 for "PRINTABLE LAMINATE” (the disclosure of which is incorporated herein by reference), describes a printable laminate material for transferring an image produced by an ink jet printer to a target substrate.
  • the printable laminate has a carrier film on one side of which is disposed an image recording layer comprising an ink absorber and a heat activatable adhesive.
  • the ink absorber is a modified cellulose material, though a cellulose gum or a single cationically charged water- soluble polymer may alsc be used.
  • the heat activatable adhesive is a polyurethan .
  • the polyurethane of the image recording layer is in the form of small strand- like structures which are distributed throughout the i k absorber thereby forming an homogenous mixture with the ink absorber of the recording layer.
  • U.S. Patent: 5,501,902 describes a multi-layer printable transfer material which can be sealed at 177 G C using a smoothing iron. However, this temperature is far too high for use with mounting boards commonly found in the graphic arts industry. Furthermore, the ⁇ 902 Patent describes the use of a powdered polymer with a particle size of up tc 2 ⁇ m. The large particle size tends to produce a printed image having a grainy appearance with a consequent loss of clarity, contrast and brilliance of the printed image.
  • International Patent Application WO 98/02314 describes a printable transfer material that releases from a temporary carrier, wherein the transferred image is waterproof .
  • This material uses a porous matrix of large particles of a typical size of 20 ⁇ m.
  • the transfer material is subjected tc a high temperature (typically 190 "O to form a film of polymer which encapsulates the ink inside the film.
  • the inventions disclosed in International Application PCT/GB98/00481 and U.S. Patent Application 09/107,302 have been further investigated, particularly regarding the ability of the printable laminate to resist the separation or delamination of the carrier film from the image recording layer. It was found that cutting or cropping of the printable laminate to obtain a proper size image for display or to obtain a mounted image having an irregular outline as found in some commercial advertising displays often causes the protective carrier layer :o separate from the recording layer .
  • the present invention may provide a printable laminate material with improved resistance to delamination cf the carrier film from the image recording layer through the use of new heat activated adhesives, new ink absorbers, and combinations thereof in the recording layer.
  • the printable laminate material may have improved resistance tc delamination of the carrier film provided by a layer of polymeric material having desirable viscoeiastic properties in the structure cf the printable laminate.
  • a printable laminate comprising a carrier film which is substantially transparent, and an image recording layer which is disposed en the carrier film.
  • the image recording layer comprises a heat activated adhesive and an ink absorber.
  • the heat activatable adhesive is one or more adhesive materials such as poiyurethanes , vinyl ester copolymers, acrylics, and icnomers formed from various salts of oiefir.s and unsat rated acid copolymers.
  • the adhesives are most preferable those which are available in the form of aqueous dispersions .
  • the ink absorber is one cr more ink absorber materials such as blends of cationic polymers, blends of cationic polymers and cellulose either, and polyvinyl alcohol.
  • the new adhesives and combinations of adhesives and ink absorbers produce an ink recording layer with a higher yield point, making the laminate less susceptible to delamination.
  • a patentable laminate comprising a carrier film which is substantially transparent, a layer of viscoeiastic material disposed on the carrier film, and an image recording layer disposed on the layer of viscoeiastic material.
  • the viscoeiastic material is one or more thermoplastic polymers such as polyurethanes , acrylics, vinyls, butadiene-styrene copolymers, i s opren - s tyrene copolymers, polychloroprenes , and olefinic polymers having physical properties which contribute to the "damping" of shearing forces imposed by a blade cutting the laminate.
  • the image recording layer includes an ink absorber which may be one or more blends of cationic polymers, blends of cationic polymers and cellulose ether, and polyvinyi alcohol, along with a heat activatable adhesive which may include one or more materials such as polyurethanes, vinyl ester copolymers, acrylic ester copolymers, and ionomers as previously described in reference to the heat activatable adhesives such as polyurethanes, phenoxy resins, acrylics, vinyls, butadiene-styrene copolymers, i soprene - styrene copolymers, polychloroprenes, and olefinic polymers, which may be the same or different than the viscoeiastic materials as described herein above.
  • a heat activatable adhesive which may include one or more materials such as polyurethanes, vinyl ester copolymers, acrylic ester copolymers, and ionomers as previously described in reference to the heat activatable adhesive
  • Figure 1 shows a cross-sectional representation of an embodiment of the printable laminate of the invention which includes a carrier film, and image recording layer.
  • a second embodiment cf the printable laminate of the invention which includes a carrier film, a layer of viscoeiastic material and image recording layer.
  • Figure 3 shows a partial cross-sectional representation of a printable laminate of the invention in the process of being laminated to a target substrate.
  • FIG 1 shows a printable laminate 10 made according to the first embodiment of the present invention.
  • the printable laminate comprises a substantially transparent carrier film 12 having a first surface and a second surface, and an image recording layer 14 having an inner surface and an outer surface, the inner surface of the image recording layer being directly supported in full and intimate contact on one of the surfaces of the carrier film 12.
  • the exposed outer surface cf the image recording layer is intended for receiving an ink image which typically is applied by means of an ink-jet printer (not shown) .
  • the pattern of ink deposits 16 formed by the ink-jet printer diffuse through the thickness of the recording layer 14 without substantial de ⁇ radation.
  • a printable laminate 20 made according to the second embodiment of the present invention is shown.
  • the printable laminate 20 comprises a carrier film 12 having a first surface and a second surface, a layer of viscoeiastic material 25 likewise having a first surface and a second surface, the viscoeiastic material being directly supported on one of its surfaces in full and intimate contact on one cf surface cf the carrier film, and an image recording layer 14 having an inner surface and an outer surface, the inner surface being directly supported in full and intimate contact with the other surface of the layer of viscoeiastic material.
  • the exposed outer surface of the image recording layer is intended for receiving an image applied by an ink- jet printer (not shown) , wherein the image takes the form cf a pattern of ink deposits 16 as described above in reference to Figure 1.
  • the image recording layer is heated by contact of the printable laminate with the heated laminating roller
  • the recording layer of this embodiment cf the invention comprising a carrier film and an image recording layer comprises a heat activated adhesive and an mk-absorper .
  • the heat activated adhesive fcr use m this em odiment of tne invention is one or more adhesives selected from the group consisting cf polyurethanes, vinyl ester copolymers, acrylic ester copolymers, and cnomeric copolymers.
  • Examples cf vinyl ester copolymers suitaoie for use m tne invention include materials wnich are commercially available under tne names CRODALAM 29-188 from Croda Adhesives, Newark Nottmghamsnire , UK, VINNAPAS available in tne grades EP1 , ⁇ P400, ⁇ N424, and EF424, and EF41, and VINNOL CE752, all available from Wacker-Chemie , Kunststoff, Germany.
  • the acrylic ester copoivmerized with a cationic- substituted acrylic monomer is available under the name GLASCOL grades DP6-2779, and DP6-2724, from Ciba Specialty Chemicals.
  • the copolymer of cationic- substituted acrylic ester and acrylamide is exemplified by the materials commercially available under the name SEDIPUR grades CL 750, and CF 604, from BASF.
  • the polyoxazolines are exemplified by poly (2-ethyl-2- oxazoline) from Sigma Aldrich Company Limited of
  • the heat activatable adhesive and ink absorber together comprise 90 - 100% cf the total weight of the image recording layer.
  • the heat activated adhesive and ink absorber comprise from about 92 to 99% and most preferable, from 97 - 99% of the total weight of the recording layer.
  • the heat activatable adhesive comprises about 33 - 77% pph (parts per hundred weight; and most preferably, about 40 - 65 pph of the total weight of the image recording layer, with at least 75% of the remaining weight of the recording layer constituted by a different, ink absorbing, preferable thermoplastic, cationic polymer material.
  • the viscoeiastic material is a thermoplastic polymer witn viscoeiastic physical properties wmch exmpits good adhesion tc tne carrier film and also to the ink aosorbing layer. Desirable properties of the viscoeiastic material include a T iglass transition temperature; of less than room temperature and typically Between -55"C and *10°C. A modulus (storage modulus, or G') of between 5 x 10 and 2 x 10 dyne /cm is desirable. A viscosity (loss modulus) of between 2.2 x 10 and 4 x 10 Poise is preferable.
  • acrylics useful in this embodiment of the invention include those acrylic polymers commercially available under the name DUROTAK from National Starch and Chemical Company, Slough, Berkshire, UK; ACRONAL grades from BASF.
  • the vinyls suitable for use in the adhesive layer of this invention include: VINNAPAS EP1, available from Wacker Chemie of Kunststoff, Germany.
  • Butadiene-styrene copolymers suitable for use in the invention are exemplified by REVINEX 80R10 from Doverstrand Ltd., Harlow, Essex, United Kingdom.
  • Isoprene- styrene copolymers are exemplified by the materials available from Shell Chemicals UK Limited, Chester, UK, under the name KRATON D and KRATON G.
  • Polychioroprene is commercially available from 3ayer A.G., Dormagen, Germany, under the names DISP ⁇ RCOLL C and BAYPREN .
  • Suitable olefinic polymers include poiyisobutyiene commercially available from BASF, under the name OPPANOL.
  • Other olefinic polymers include polybutadiene and poiyisoprene .
  • the layer of viscoeiastic material may contain minor amounts of various materials to improve the performance of the printable laminate. These materials include plasticizers to further improve the desired viscoeiastic and extensible properties of the material.
  • light absorbers may be added tc the viscoeiastic materials tc aid in the filtering cf various segments of the light spectrum which are transmitted through the carrier layer and eventually reach the image in the image recording layer.
  • ultra-violet light absorber materials can be added to the adhesive layer to remove that part cf the UV spectrum that would tend to degrade the image held in the ink absorbing layer through the actinating effect of sunlight and artificial light.
  • Suitable plasticizers such as phthalate esters, are commercially available from Alcohols Ltd., Bishop's Stortford, Hertfordshire, UK; phosphate esters are available from Ciba, Manchester, UK; and chlorinated paraffin is available from IC Chlor- Chemicals , ncorn, Cheshire, UK.
  • Suitable light absorbers are known widely and include such materials sold under the trademark TINUVIN, from Ciba Chemicals, Manchester, UK.
  • thermoplastic polymers for use m this embodiment in the invention may be particularly tacky when used at room temperature. Therefore it is envisioned that the carrier film may be treated with a release-coating material on the surface fcr the film opposite the adhesive layer so that the film can be easiiv unwound from a soocl or roll and unwound as needed for use m printing or mounting of tne printable laminate.
  • Sucn release coatings are commonly Known ⁇ r. tne adhesives industry and include such materials as ESCOAT P ' polyvinyi octadecyl caroamate > , commercially available from Emerald Chemicals Ltd, Windsor, Berkshire, UK.
  • the image recording layer cf tnis empodiment of the invention comprises a heat activatable adnesive and an ink absorper
  • the heat activataple adhesive is one or more materials selected from the group consisting of polyuretnanes , vinyl ester copolymers, acrylic ester copolymers, and ionomeric copolymers, (all as previously ctescriPed m reference to the neat activatable adnesive found m tne image recording layer cf the first empodiment cf tne invention) , polyuretnanes, acrylics, vinyls, putadiene- styrene copolymers, isoprene- styrene copolymers, polychloroprenes, and olefinic polymers (all as previously described m reference to tne viscoeiastic material as described above in reference to tne present embodiment of the invention) and phenoxy resins.
  • the ink absorbers for use m the present empodiment are selected from tne group consisting of blends of cationic polymers, blends of cationic polymers and cellulose ether, ana pc-yvinyl alconol, all as previously ⁇ escrioed m reference to the ⁇ n ⁇ aosorper of tne first embodiment cf tne present invention) .
  • the phenoxy resin suitable for use as a heat activatable adnesive m the recording layer cf the invention s exemplified by the resin commercially available under the name PKHW-35, from Phenoxy Associates, ROCK: Hill, South Carolina.
  • the image recording layer it may be necessary tc use an amphoteric surfactant m comomation witn the pnenoxy resin to act as a cr.arge reverser
  • the pnenoxy resin us suppiie ⁇ _n tne form cr an anionic dispersion m water and anionic dispersions are not normally ccmpatioie with cationic polymers ' such as ink aPsorpers wnicn may be used m tne image recording layer, Therefore, the practitioner will appreciate tne need fcr re ⁇ ucmg tne negative cnarge of tne pnenoxy resin tnrougn the use of an ampnote ⁇ c surfactant.
  • the ampnoteric surfactant acts as a "bri ⁇ ge” oetween tne anionic phenoxy resin and the cationic polymers m tne image recording layer. It will be appreciated tnat tne utility of ampnoteric surfactants extends oeyond the use m systems using phenoxy resins. In fact, any anionic adhesive used in connection with this invention may have its compatibility witn cationic ink apsorPers improved tnougn tne use of ampnoteric surfactants.
  • An example of a suitable ampnoteric surfactant s CRODATERIC CYNA, from Cro ⁇ a Surfactants Ltd., Snaitn, Humbersi ⁇ e, UK.
  • the viscoeiastic material may be deposited directly onto the carrier film m the form of an aqueous dispersion, a solution formed with an organic solvent, or -_n tne form of a hot melt.
  • the viscoeiastic material layer comprises 60 - 80% by weight of tne viscoeiastic material layer and tne image recording layer ccmpined.
  • tne viscoeiastic material comprises 62.5 - 80.0% and most preferaoly, 70. C - 75.0% of tne comDined amount of tne viscoeiastic material layer and tne image recording layer.
  • tne UV lignt aosoroer if present, comprises about 2.0 - 5.0% py weignt cf tne tota-_ weignt cf tne viscoeiastic material laver
  • the viscoeiastic material layer s typically within tne range cf 20 - 50 urn thick, w th 25 - 40 ⁇ m oemg preferable, and 30 - 35 urn being most preferable
  • the recording layer m this embodiment cf the invention is applied to the carrier film m the form of an emulsion, preferable a water-based emulsion, and allowed to dry.
  • the structure of tne dried film is that cf adhesive particles distributed throughout an essentially continuous layer of tne water-soluble ink abscroer .
  • the size of the adhesive particles is typically m the range of 0.08 - 3.0 ⁇ m, with a O . lum particle size being preferred.
  • the adhesive particles have a strand- like conformation.
  • the heat activatable adhesive comprises 50 - 60 ph and most preferably, 57.8 - 59.8 pph cf the total weight cf the image recording layer, while the ink absorber comprises 34 - 50 pph, preferably 39 - 49 pph, or most preferaply, 39.2 - 41.2 ppn cf the total weight cf the image recording layer.
  • the balance of the image recording layer comprises optionally comprises surfactant and/cr a thickener.
  • the image recording layer may be deposited directly on to the layer of viscoeiastic material and subjected tc conditions for promoting drying.
  • a test print was made with the laminate by printing an image on the laminate with a CHROMA 24 ink jet printer, commonly available from Encad Inc., San Diego, CA, USA.
  • Two samples of the printed laminate cf this example were prepared in this manner.
  • a first sample was laminated to a piece cf foam board of 3mm thickness and a second sample was laminated tc a piece of expanded PVC Board cf 3mm thickness using a roller iaminator set tc 100°C at a pressure of 80 psi with a feed rate speed of 2 feet per minute .
  • Subsequent tc laminating, the printable laminate and mounting board were permitted to cool to room temperature. Adhesion of the laminate to the target board of each sample was tested using a sample pull test.
  • a printable laminate was prepared by applying a coating cf an ink absorber layer 25g dry weight! per square meter of the laminate.
  • the ink absorber layer was prepared from:
  • Example 3 ⁇ is quite similar to Example 3A except that the ink absorber cf Example 3A (a blend of cationic polymers) is further blended with a relatively small amount of cellulose ether.
  • the preferred dry weight coat of the image layer according to Example 3B is between 28 and 30 grams per square meter, preferably on the DEEP CRYSTAL or CRYSTAL MATT carrier film previously described. This gives luster and matt products respectively. A simple gloss effect can be obtained by coating polyester film of 50 microns tnickness.
  • the dry weight percent cf the polyurethane can be in the range of 40 50 : range of tne cationic polymer blend can be 45 - 50%; and the range of the cellulose ether can be about 3 - 10%.
  • the effective dry weight range can be between about 25 - 35 , preferably 28 - 30, grams per square meter.
  • a corona discharge treated polyester film was used as the carrier fiim to which was applied a mixture cf the ink absorbing layer material in an amount cf ⁇ 5g per square meter ⁇ ry weignt
  • the formula cf the image recording layer material as follows :
  • Examples 1 - 4 support a preference that at least one of the absorber materials have thermoplastic adhesive properties (e.g., the vinyl pyrrolidone - vinyl ester copolymers LUVISKOL VA64, PVP/VA S-630 and Coilacoi VL; Klucel ⁇ ; and poiyoxazoiine .
  • thermoplastic adhesive properties e.g., the vinyl pyrrolidone - vinyl ester copolymers LUVISKOL VA64, PVP/VA S-630 and Coilacoi VL; Klucel ⁇ ; and poiyoxazoiine .
  • a mixture of ingredients for forming an ink absorbing layer was deposited en to a corona discharge treated polyester fiim.
  • the dry weight cf the ink absorbing layer was about 35g per square meter.
  • the ink absorbing layer was dried at a temperature below about 58 °C.
  • the formula of the ink absorbing mixture was prepared from the following components :

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Laminated Bodies (AREA)
  • Ink Jet (AREA)

Abstract

L'invention concerne un film stratifié pouvant être imprimé. Ce film présente une résistance améliorée à la séparation des couches du stratifié. Selon un mode de réalisation, la présente invention traite de l'utilisation de nouveaux matériaux absorbant l'encre, et de nouveaux matériaux adhésifs dans une couche d'enregistrement d'encre sur un film de support. Selon un autre mode de réalisation, l'invention a pour objet une couche adhésive placée entre la couche d'enregistrement à chaud et le substrat de film de support. L'invention traite aussi d'un procédé permettant de sélectionner l'association de matériaux adhésifs et de matériaux absorbant l'encre dans la couche d'enregistrement d'encre pour améliorer la résistance de ces matériaux à la séparation des couches.
PCT/GB2000/000085 1999-01-15 2000-01-13 Stratifie pouvant etre imprime WO2000041891A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP00900282A EP1144196A1 (fr) 1999-01-15 2000-01-13 Stratifie pouvant etre imprime
AU19945/00A AU1994500A (en) 1999-01-15 2000-01-13 Printable laminate
JP2000593482A JP2003534144A (ja) 1999-01-15 2000-01-13 印刷可能な積層体
KR1020017008901A KR20010112242A (ko) 1999-01-15 2000-01-13 인쇄가능한 적층판

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US23203099A 1999-01-15 1999-01-15
US09/232,030 1999-01-15

Publications (1)

Publication Number Publication Date
WO2000041891A1 true WO2000041891A1 (fr) 2000-07-20

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PCT/GB2000/000085 WO2000041891A1 (fr) 1999-01-15 2000-01-13 Stratifie pouvant etre imprime

Country Status (7)

Country Link
EP (1) EP1144196A1 (fr)
JP (1) JP2003534144A (fr)
KR (1) KR20010112242A (fr)
CN (1) CN1139497C (fr)
AU (1) AU1994500A (fr)
TW (1) TW524758B (fr)
WO (1) WO2000041891A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001025856A1 (fr) * 1999-10-01 2001-04-12 Foto-Wear, Inc. Materiau de transfert d'image comportant une couche de reception d'image et procede de transfert thermique mettant en application ce materiau

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6881458B2 (en) * 2002-06-03 2005-04-19 3M Innovative Properties Company Ink jet receptive coating
KR100404335B1 (en) * 2002-09-11 2003-11-05 Shinwoo Hi Tech Co Ltd Real picture printer board with plotter and process for production thereof
KR100518789B1 (ko) * 2002-12-04 2005-10-05 삼성전자주식회사 잉크젯 프린터용 기록 매체 및 그 제조 방법
KR101158219B1 (ko) * 2010-11-10 2012-06-20 삼성전기주식회사 쿠션지 및 이를 이용한 방열 인쇄회로기판의 제조 방법
JP2014205246A (ja) * 2013-04-10 2014-10-30 セイコーエプソン株式会社 記録物製造用用紙および記録物
CN108909230B (zh) * 2018-07-06 2020-04-10 福州艾瑞数码影像有限公司 弱溶剂型墨水的喷墨打印介质及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225652A (en) * 1979-04-09 1980-09-30 Minnesota Mining And Manufacturing Company Transparent sheet material
EP0487350A1 (fr) * 1990-11-21 1992-05-27 Xerox Corporation Feuilles réceptrices revêtues
EP0782931A1 (fr) * 1995-12-07 1997-07-09 E.I. Du Pont De Nemours And Company Feuille receptrice pour enregistrement par jet d'encre
EP0858913A1 (fr) * 1997-02-17 1998-08-19 Hunt Europe Limited Film de transfert

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225652A (en) * 1979-04-09 1980-09-30 Minnesota Mining And Manufacturing Company Transparent sheet material
EP0487350A1 (fr) * 1990-11-21 1992-05-27 Xerox Corporation Feuilles réceptrices revêtues
EP0782931A1 (fr) * 1995-12-07 1997-07-09 E.I. Du Pont De Nemours And Company Feuille receptrice pour enregistrement par jet d'encre
EP0858913A1 (fr) * 1997-02-17 1998-08-19 Hunt Europe Limited Film de transfert

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001025856A1 (fr) * 1999-10-01 2001-04-12 Foto-Wear, Inc. Materiau de transfert d'image comportant une couche de reception d'image et procede de transfert thermique mettant en application ce materiau
US6869910B2 (en) 1999-10-01 2005-03-22 Foto-Wear, Inc. Image transfer material with image receiving layer and heat transfer process using the same

Also Published As

Publication number Publication date
KR20010112242A (ko) 2001-12-20
CN1139497C (zh) 2004-02-25
JP2003534144A (ja) 2003-11-18
TW524758B (en) 2003-03-21
AU1994500A (en) 2000-08-01
EP1144196A1 (fr) 2001-10-17
CN1340005A (zh) 2002-03-13

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