經濟部智慧財產局員工消費合作社印製 524758 A7 B7 五、發明說明（） 本發明係關於將經列印的成像轉換到目標基材上，特 別是廣告板、發泡板或硬的P V C。 在廣泛的技術中，對於數位式截取成像，業已經發展 出適合於電子計算可讀取的形式，可用電腦來編輯該成 像，列印該經編輯的成像到紀錄媒質上，而且，然後從 該紀錄媒質上將成像轉換到目標基材上。該目標基材可 以是包括紡織品、陶瓷材料、廣告板、硬PVC或如發泡 板或膨化P V C板之泊定板的數種材料之任何一種，彼等 材料傺已廣泛使用於繪圖技藝工業中。 用來接受和轉換由噴墨印表機所形成的成像之典型的 紀錄媒質，偽具有載體和下列釋出層、保護性障層、成 像轉換層和黏著層等層中之至少兩層。1 9 9 8年二月1 6曰 所提出的國際申請案P C T / G B 9 8 / 0 0 4 8 1 "轉換膜"，其記述 一種具有僅具一層之轉換膜之載體。該單一層偽一種可 熱活化黏著性粒子和黏合劑之混合物，其也是吸收油墨 的，因此界定了多孔性基體。當於商業繪圖應用中使用 時，此類轉換膜#可以在沒有移除載體下，而黏著於目 標基材上，因而該載體停留固著於抓取該成像之層上， 因而對該成像提供了物理性保護。 1998年六月30日所提出的美國專利申請案USP 09/ 1 0 7 , 3 0 2 可列印積層”，（其掲示併於本文以供參考）， 其偽記述一種適用於將由噴墨印表機所製得的成像轉換 到目標基材上之可列印積層材料。該可列印積層傺具有 一種載體膜於配置在包括吸油墨劑和可熱活化黏劑之成 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------裝-----^----訂— (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 524758 A7 _B7 _ 五、發明說明（2 ) 像紀錄層之一側。該吸油墨劑傺一種經改良的纖維材料 ，然而亦可使用纖維槍或單陽離子電荷水溶性聚合物。 熱可黏著劑俗為聚胺基甲酸酯。在該3 0 2專利申請案中 ，成像記錄層中之聚胺基甲酸酯偽以似小束狀結構之形 式分布於整個吸油墨劑中，因而形成一種具紀錄層的吸 油墨劑之均勻的混合物。 美國專利申請案ϋ S P 5，5 0 1，9 0 2，其偽描述一種可以 在1 7 7 °C下，利用平滑鐵而包封之多層可列印轉換材料。 然而，此溫度對在繪圖技藝工業中一般所使用之泊定板 而言，通常係太高。此外，該902專利，偽描述使用一 種具有粒子大小至高為2 Q # m之聚合物粉末。較大的粒 子尺寸，偽趨向於製造具多粒子外觀的列印成像，因而 損失了列印成像之透明性、對比和亮。 國際專利申請WO 98/G2314傺描述一種從暫時性載體 中釋出之可列印轉換材料，其中經換轉換的成像像防水 的。此材料偽使用一種典型尺寸為2 G微米之大粒子的多 孔性基體。將該轉換材料置於高溫（典型為1 9 0 °C )下， 而使形成將油墨包封於其膜内之聚合物膜。 國際申請案P C T / G B 9 8 / 0 0 4 8 1和美國專利申請案U S P 09/107,3 0 2之發明掲示中，其業已完成進一步之調査 ，恃別是關於可列印積層阻止載體膜從成像紀錄層分離 或分隔之能力。業已發現：將該可列印積層予以切或 割而得到如某些商業廣告展示中研發現之適合展示之 恰當尺寸，或獲得具有不規則外形之泊定成像，傺時 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 0 裝-----：----訂------ 524758 A7 B7 五、發明說明（ 中 序 程 割 切 在 於 由 〇 傷 層其 體， 載隔 護分 保之 以膜 中體 層載 錄， 紀下 該境 從璟 致此 導在 常 該 ， 〇 層 的積 起印 弓 歹 所可 力該 縮過 壓通 和並 力越 張橫 ，拉 力下 剪# 的 ， 加力 施之 所構 片建 刀所 割片 切 刀 ， 由 轉著 像.黏 成之 該間 服層 克體 來載 夠和 足 層 係錄 ，記 力像 之成 用該 作 ， 所點 中伏 料降 材性 割附 切黏 於之 且層 而換 鍵 膜 體 Κ Jls 之 隔 分 所 層 錄 紀 像 成 從 該 了 失 損 則 敗 失 於 由 可 像致 隔導 分能 之可 層中 體隔 載分 ，該 且在 更 ， 〇 質 用品 作之 護像 保成 的 印 供列 提低 所降 層的 體大 載大 和能 化 mx ί 觀 外 像 成 他 其 是 者 或 像 成 了 礙 阻 匕匕 會 可 而 因 應 c 效化 ,劣 之 上 著從 黏 的 化良 活改 熱經 的有 新具 用種 使一 過供 透提 ，而 中 ， 層 合 錄組 紀其 在及 以劑 可附 偽吸 明的 發新 本 、 劑 性 〇 抗 料阻 材之 層膜 積體 印載 列離 可分 的之 性提 抗所 阻料 之材 膜合 體聚 載由 離的 分良 層改 錄經 紀有 像具 成 所 有 具 中 構 結 之 層 積 印 列 可 在 係 其 〇 ，質 料性 材性 層彈 積滯 印黏 列的 可要 的想 ------------·裝—j----訂---------^91. (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 ，之 層上 積層 印體 列載 可於 種置 一 配 供及 提以m， 其膜 ， 體 %載 ds 觀的 一 明 第透 之為 明上 發質 本實 照括 依包 其 吸 ， 墨料 油材 及性 劑著 著黏 黏個 化多 活個 熱 一 括為 包傺 層 ， 錄劑 紀著 像黏 成化 該活 〇 熱 層可 錄該 紀 。 像劑 成收 烴黏 烯 。 從物 及聚 、共 酸酸 烯和 丙飽 、未 物及 聚以 共物 酯聚 烯離 乙之 、成 酯形 酸所 甲類 基鹽 胺的 聚同 如·不 例之 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 524758 A7 B7 五、發明說明（ 經濟部智慧財產局員工消費合作社印製 油子乙生層 ，滯合生？共含物，酸面乙烯烯相成參的 該離聚偽積 層黏聚産 Θ 烯包合醇甲前丁 丙乙以在以個 。陽及，該 積之性力 乙偽摻乙胺如、氯苯可該用多 佳有、合得 印上塑剪、苯，之烯聚及物聚 — 傺。述或 、 | Ψ] 最混者組使 列層熱的旨希層物乙之以烯、丙其料描個 為摻一之而 可體種與tiH錄合聚劑、乙物 ，材所一 者如任劑， 種載多賦Μπ 紀聚及著物、聚 ·物性面是 甲異 、 得例之附層 一該或所〜 像性以黏聚物共纟聚彈前即 安 、 梭 獲，維吸錄 供於種面 ㉗成陽，化共酸烯離滯與意 而劑纖和紀 提置一刀^該個物活類烯乙±fc、之黏以 ， 式附和劑墨 係，傺之1&M 。多合可酯丙苯稀物的可同 形吸物著油 其膜料層 希物或摻熱酸、㈣乙合述像相 液墨合黏之 ，體材積1¾合個之如烯酯丙，本聚描其劑 散油聚及點 點載性該勿 聚一醚個丙酸氯烴所，墨 分個子，伏 觀的彈削έί·"- 烴是素多、甲異物烯面劑油 性多離劑降 二明滯切}烯烯以維或物胺 /聚及前墨吸 溶或陽著的 第透黏由ng乙及可纖個聚聚勿離烯中油之 水個有黏高。之為該對P1丁烯條和一共該Η之丙文吸例 以一混的較離明上。有am、丙其物括類照*物氯本之體 以傜摻新有分發質層具 U 物氯，合包酯參婦合聚於中具 可劑、該具於本實料如用烯聚劑聚以烯的乙聚、同層一 偽附物。種易照括材諸作乙、墨性可乙到苯烴物不錄第 劑吸合醇一不依包性，尼、物油陽著、提"，烯聚或紀的 著墨聚烯成較 其彈物阻物聚吸、沿酯所烯及共同像照 (請先閱讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 524758 A7 _B7_ 五、發明說明（5 ) 如陽性聚合物之摻合物、陽性聚合物和纖維素醚之摻合 物般之吸油墨劑材料。 因此，本發明像包括數種成份和如具有相對於每一其 餘者之相關的一種或更多種的成份，以及擁有於如下所 詳細描述之特徵、性質和相關元素之物件。 圖式之詳細説明 第1圖所示為代表本發明之可列印積層之具體例之橫 斷面圖，其包含載體薄膜和成像紀錄層。 第2圖所示為代表本發明之可列印積層之第.二具體例 之橫斷面圖，其包含載體薄膜、黏滯彈性材料層和成像 紀錄層。 第3圖所示為代表本發明之在將積層到目標基材上程 序中之可列印積層之具體例之部份橫斷面圖。 太發明夕詳細説明 在如下之圖式和說明中，將參照以相同之序號來定義 類似之圖形、結構及其特徵。 第1圖傺顯示依照本發明之第一具體例所製得的可列 印積層1 〇。該可列印積層1 G傺包括具有第一表面和第二 -----------------^----訂— (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 表於紀由表 1 外撐像藉印層 和支成的墨錄 面全該型噴紀 表完。典由過 内像觸該該透 有面接受。穿 具表之接像而 及内與以成散 以之地用墨擴 ， 層切算油偽 12錄密打的 ， 膜紀且傺塗16 體像上 ，施樣 載成面面所圖 之該表表^)積 明。個外貞澱 透層一的墨 上錄之露{油 質紀12曝機的 實像膜經表成 之成薄之印形 面之體層墨所 表面載錄噴機 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作社印製 524758 A7 _B7_ 五、發明說明（6 ) 之厚度，但沒有實質上降解。 在第2圖中，偽為依照本發明之第二個具體例所製作 的可列印積層2 Q。該可列印積層傺2 0，傺包括具有第一 表面和第二表面之實質上透明之載體薄膜1 2，具有類似 於第一表面和第二表面之黏滯彈性材料層2 5。該黏滯彈 性材料偽直接支撐於載體薄膜1 2之一個表面上且密切地 與之接層觸，以及内表面和外表面之成像紀錄層1 4，該 成像紀錄層之内表面係完全直接支撐且密切地接觸於黏 滯彈性材料之一個表面上。該成像紀錄層之經曝露的外 表面，#打算用以接受該典型的藉由噴墨印表機（未顯 示）所施塗的油墨成像，其中該由噴墨印表機所形成的 油墨澱積圖樣1 6 ,則參照如第1圖之描述。 在第3圖中，傺顯示：依照本發明之第一個具體例而 製作的可列印積層1 〇，傺在程序中積層到固接板3 0上。 此處所顯示的固接板，實質上傺為從在支撐紙層3 4的至 少一側上之經膨化的聚苯乙烯層3 2所形成之剛硬的、平 面的結構。該紙提供了黏著於可列印積層1 〇之便利的表 面。該在第3圖中可列印積層之成像紀錄層1 4，傺在積 層前經噴墨印表機列印成像，正如同在成像紀錄層中之 油墨澱積圖樣1 6之證明一般。 該成像紀錄層像經由與具有經加熱的積層棍3 6之可列 印積層而加熱到使在成像紀錄層之黏著劑活化的溫度。 可以預見的，可以使用其他的加熱該積層的成像紀錄層 之方法，包含使用該棍之外部加熱元件。當黏著劑傺經 -8 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁)Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 524758 A7 B7 V. Description of the invention () The invention relates to the conversion of the printed image onto the target substrate, especially the advertising board, foam board or rigid P V C. In a wide range of technologies, for digital capture imaging, a form suitable for electronic computing has been developed, which can be edited by a computer, the edited image can be printed on a recording medium, and then from that The image is transferred to the target substrate on a recording medium. The target substrate may be any one of several materials including textiles, ceramic materials, advertising boards, rigid PVC, or podium boards such as foamed boards or expanded PVC boards, which have been widely used in the graphic arts industry . A typical recording medium used to receive and convert the images formed by inkjet printers has a carrier and at least two of the following release layers, protective barrier layers, imaging conversion layers, and adhesive layers. The international application PCT / G B 9 8/0 0 4 8 1 " conversion membrane " filed on February 16, 1998 was described as a carrier having a conversion membrane with only one layer. This single layer is a pseudo-mixture of heat-activatable adhesive particles and a binder, which is also ink-absorbing, thus defining a porous matrix. When used in commercial drawing applications, this type of conversion film can be adhered to the target substrate without removing the carrier, so the carrier stays fixed on the layer that captures the imaging, thus providing the imaging Physical protection. U.S. Patent Application No. 09 / 107,302, filed on June 30, 1998, "printable laminates", (which is shown and incorporated herein by reference), falsely states that a The image produced by the machine is converted to a printable build-up material on the target substrate. The printable build-up has a carrier film configured at a cost including an ink absorbent and a heat-activatable adhesive. Standard (CNS) A4 specification (210 X 297 mm) ------------ install ----- ^ ---- order— (Please read the precautions on the back before filling this page ) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 524758 A7 _B7 _ V. Description of the invention (2) One side of the recording layer. The ink absorber is an improved fiber material, but fiber guns or monocations can also be used. Charge-soluble water-soluble polymer. Thermoadhesive is conventionally polyurethane. In this 302 patent application, the polyurethane in the imaging recording layer is pseudo-distributed in a small bundle-like structure. In the entire ink absorbing agent, thus forming a record layer of ink absorbing agent uniformly mixed US patent application 专利 SP 5,50 1,920, which falsely describes a multilayer printable conversion material that can be encapsulated with smooth iron at 17.7 ° C. However, this temperature The podium plate generally used in the graphic arts industry is usually too high. In addition, the 902 patent falsely describes the use of a polymer powder having a particle size of up to 2 Q # m. Larger particle sizes, pseudo It tends to produce print images with a multi-particle appearance, thus losing the transparency, contrast and brightness of print images. International patent application WO 98 / G2314 傺 describes a printable conversion material released from a temporary carrier, The converted image is waterproof. This material uses a porous substrate with a large particle with a typical size of 2 G microns. The conversion material is placed at a high temperature (typically 190 ° C) to form Polymer film encapsulating ink in its film. International invention PCT / GB 9 8/0 0 4 1 1 and US patent application USP 09/107, 3 0 2 have been shown in the invention, they have completed further Survey, let's not about listable The ability of the laminate to prevent the carrier film from being separated or separated from the imaging record layer. It has been found that the printable laminate is cut or cut to obtain the appropriate size as found in some commercial advertising displays, or to have an irregular shape For fixed imaging, the paper size is applicable to Chinese National Standard (CNS) A4 specification (210 X 297 mm). (Please read the precautions on the back before filling this page) 0 Pack -----: --- -Order ------ 524758 A7 B7 V. Description of the invention (The middle sequence cut is based on the body of the injury layer, and the protection and reinsurance are recorded in the body layer of the membrane. The guide should always be, the accumulation of the printed bow on the 0th layer can be reduced by the pressure and the force is more and more stretched, and the force is cut by #. Rotate the image. The layered body of the suit is loaded to record the foot layer. The memory of the image is used as the work. The material in the spot is cut and adhered to the layer and changed keys. Membrane KK Jls partition office recording video The damage is lost in the middle layer of the layer which can be separated by the image, and the printout of the protective image of the quality product is used to reduce the large load of the lowered layer. Can transform mx ί The appearance of him becomes his own person or the hindering dagger will be able to respond to the c effect. On the other hand, there is a new kind of tool that can be used to change the heat from the sticky goodness to the heat. For through-drawing, and the middle-layer recording group will be able to attach a false copy of the new version of the film, the drug properties. Anti-resistance material of the laminated film printed on the separation of the separable sexual resistance The material and material assembly of the material that is blocked is rewritable from the separated layers. The broker has a layered print of all the structures in the middle. The material can be printed in layers. Want to think ------------ · install—j ---- order --------- ^ 91. (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs. The body ’s full-load ds view is the clearest evidence of the quality of the hair, including its absorption, inks, oils, and sex agents sticking together, and more heat is included as the envelope layer, recording agent The epigraph is like a glue that melts the activity. The thermal layer can record the epigraph. The imaging agent yields hydrocarbon olefins. Polyesters, polyacids, polyacrylic acid and propylene, polyethers, polyethers, polyenes, polyethylenyl, ethyl esters, and ester-forming acids are all polymerized in the same manner. Examples of this paper are applicable to China. National Standard (CNS) A4 specification (210 X 297 mm) 524758 A7 B7 V. Description of the invention (Printed oil acetonitrile layer from the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs, stagnant congenital? Total inclusions, acidic vinylene phase The ionization pseudo-layers of the cohesive layer produce Θ ene-containing alcohol methyl butyl propylene ethyl. The positive and negative effects of this product are pseudo-doped with ethylamine such as chlorobenzene. Plastic scissor, benzene, olefin polymerization and material polymerization-傺. 或 or, | Ψ] The most mixed group is to make the layer heat, and the layer material is acetylene and acrylic. The species and the tiH recording and polymerization agent, the second material, and the material are the same as any agent. The species contains multiple ππ polymerizations and works. The physical and physical properties are different. Adhesive polymer co-condensation before the bomb is immediately installed, shuttled, maintenance and recording for the seed surface ㉗ Chengyang, chemical co-acid stagnation and intentional agent and fiber extract One knife ^ This kind of active vinyl ± fc, the adhesive agent, the formula of the ink system, 傺 of 1 & M. Polycocoate propylene benzene thinner can be shaped absorbent oil film material layer or blended The combination of hot acid and ethyl acetate is similar to that of liquid ink, and the volume is 1¾, such as allyl acrylate. This polymer describes its oil dispersion and point loading. The ink is divided into two parts, and the view of the bombardment of Fuguan.-"Hydrocarbons are prime, methyl foreign substances, surface oils, multi-ionic agents, diamine, and stagnate. The first transparent adhesive is composed of ng B and water that can be polymerized. The water in the oil is highly viscous. The pair of P1 butene strips and the proverbial absorption of a total of 以 are more mixed. Above, there are am, propyl, and other types of photos, such as chlorine, and the body is mixed with a new distribution layer with U chlorine, and the ester-containing ginseng women are gathered in the Chinese medicine, which is based on the actual materials such as Ethylene polymerization using olefin polymerization agent, same layer of a pseudo-adhesion. A kind of easy-to-use materials such as B, ink properties can be ethyl to benzene hydrocarbons do not record the first agent, alcohol, non-inclusive, Oil-on-line, mention ", polyene or period of ink polyene Compared with its bullet-blocking poly-absorption, along with esters and common images (please read the precautions on the back before filling this page) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 524758 A7 _B7_ V. Description of the invention (5) An ink absorbing material such as a blend of a positive polymer, a blend of a positive polymer and a cellulose ether. Therefore, the present invention like to include several components and if Each remaining is related to one or more ingredients, and objects possessing features, properties, and related elements described in detail below. DETAILED DESCRIPTION OF THE DRAWINGS Figure 1 shows a printable representation of the present invention. A cross-sectional view of a specific example of a laminate, which includes a carrier film and an imaging recording layer. Fig. 2 is a cross-sectional view showing a second specific example of a printable laminate of the present invention, which includes a carrier film, a layer of viscoelastic material, and an imaging recording layer. Fig. 3 is a partial cross-sectional view showing a specific example of a printable laminate in the process of laminating onto a target substrate of the present invention. Detailed description of the invention In the following drawings and descriptions, similar figures, structures and features will be defined with the same reference numbers. Fig. 1 (i) shows a printable laminate 10 made according to a first specific example of the present invention. The printable build-up 1 G 傺 includes a first surface and a second ----------------- ^ ---- order — (Please read the precautions on the back before filling (This page) The printing of the printed sheet of Yu Ji's sheet by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is complete. The code should be accepted by the internal image. Wear the image of the watch and expand it with ink inside and inside. The layer is cut into 12 layers of oil and fake, and the film is painted on the 16 body image. The sample is loaded into the surface as shown in the figure. The table ^) accumulated. The externally recorded dew on the outer layer of the transparent layer {The real image film of the oil quality Ji 12 exposure machine is formed into a thin printed surface, and the surface of the inkjet printer is loaded on the surface. The paper dimensions are applicable to Chinese national standards ( CNS) A4 specification (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 524758 A7 _B7_ V. The thickness of the invention description (6), but it has not been substantially degraded. In Fig. 2, a printable build-up layer 2Q fabricated in accordance with a second specific example of the present invention is assumed. The printable buildup layer 傺 20, 傺 includes a substantially transparent carrier film 12 having a first surface and a second surface, and a viscoelastic material layer 25 similar to the first surface and the second surface. The viscoelastic material is directly supported on one surface of the carrier film 12 and closely contacts it, and the imaging record layer 14 on the inner surface and the outer surface. The inner surface of the imaging record layer is completely directly supported. It is in close contact with one surface of the viscoelastic material. The exposed outer surface of the imaging record layer is intended to receive the image of the typical ink applied by an inkjet printer (not shown), wherein the ink deposit formed by the inkjet printer For plot 16, refer to the description in Figure 1. In Fig. 3, "傺" shows: a printable build-up layer 10 made according to the first specific example of the present invention, and "傺" is laminated on the fixed board 30 in the procedure. The fixing plate shown here is substantially a rigid, flat structure formed from an expanded polystyrene layer 32 on at least one side of the supporting paper layer 34. The paper provides a convenient surface that adheres to the printable laminate 10. The image recording layer 14 which can be printed in FIG. 3 can be printed and imaged by an inkjet printer before being laminated, just like the proof of the ink deposition pattern 16 in the image recording layer. The image recording layer image is heated to a temperature at which the adhesive on the image recording layer is activated through a printable layer having a heated layering stick 36. It is foreseeable that other methods of heating the laminated imaging record layer can be used, including using an external heating element of the stick. When the adhesive is passed -8-This paper size applies to Chinese National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page)
524758 A7 _B7_ 五、發明說明（7 ) 活化時，該固接板3 G和可列印積層傺使與積層接觸，而 且該自積層棍36而來的熱和源自受箍縮棍38之壓力，傺 確定足夠使可列印積層黏著於固接板上。 將瞭解到，在本發明中並沒有打算使成像紀錄層之熔 融轉移或成像紀錄層從載體膜中釋出。而是，在可列印 積層完成黏著於目標表面之後，企圖使該載體保留在成 像紀錄層位置上。 該在本發明中之載體膜，較宜是透明或實質上透明之 具有聚合組成物之膜。此類適合本發明載,體明之聚合膜 材料，傺包含聚酯物、聚氯乙烯、聚氟乙烯或聚丙烯膜 。此外，多層載體膜亦可以使用於本發明中，待別是當 圖形上需要織物時。適合於本發明使用之多層載體膜之 一，偽為D E E P晶形物，傺3 Q微米之積層，聚丙烯織膜， 和5 0微米聚酯膜，可自A s s i - D 〇 m a η，比利時購得。M A T T 晶形物僳為可自相同供貨商而購得的似多層載體膜。 該所選取膜的表面可視情況地經化學品及/或不同的 程序來處理，而改善該材料對膜之黏著性。其處理方法 中之一，俗為電翬放電處理。在本發明中所使用載體膜 -----------------^----訂--------- (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 差 有 具 為 宜 較 間 之 米 微 ο 5 2 到 6 3 於 界 像 圍 範 度 厚 之 有 具 和 膜 曲豆 dfln 括 包 偽 層 錄 紀 之 〇 中 度例 厚體 之具 米之 微明 5 發 為本 多在 不 明酸 發甲 本基 在胺 。聚 層自 錄傺 紀其 像 ， 成劑 之著 物黏 墨化 油活 吸熱 和之 劑用 著使 黏所 化中 活例 熱體 括具， 包此 類 酯 子 離 和 物 聚 共 類 酯 条 烯 丙 / 物 聚 共 類 酯 条 烯 乙 / 酯 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 經濟部智慧財產局員工消費合作社印製 524758 A7 _B7_ 五、發明說明（8 ) 共聚物組成群類所選取之一種或多種黏著劑。在本發明 此具體例中所使用之吸油墨物，其偽自陽性聚合物之摻 混物、陽性聚合物和纖維醚之摻混物和聚乙烯醇類組成 群類之所選取之一種或多種材料。 在本發明中所使用之聚胺基甲酸酯，其典型的市售可 得的材料為可自巴斯夫，齊朵，齊歇爾，英國所購得的 DS 3507、DS 3459、200A級之 LUPHEN-D,可自巴克斯登 ，杜威伊齊，沃斯特歇爾，英國所購得的WITC0B0ND級 之2 3 3 - 2 2，2 4 2 - 6 7，2 8 0 - 4 2和7 5 5，以可自然恩卡瑞辛， 挪威齊，齊歇爾，英國所購得的N E 0 R E Z R - 5 6 3。 在本發明中所使用之乙烯条酯類之實例，其市售可得 的材料包括可自柯達黏著劑公司，紐沃克納特馬歇爾， 英國所購得商品名為C R 0 D A L A Μ 2 9 - 1 8 8，可自巴華克爾 化學公司，慕尼黑，德國所購得的Ε Ρ 1，Ε Ρ 4 0 0，Ε Ν 2 4 和 E F 4 1 級，和 C Ε 7 5 2。 在本發明中所使用之合適的乙烯条酯類共聚物之賁例 ，包括可自西巴特殊化學品公司，巴拉佛得，西約克歇 爾，英國所購之GALSCOL级，以及可自BASF所購得的 ACRONAL 290D〇 在本發明中所使用之合適的離子共聚物之實例，其傜 為金屬、鋁或從烯烴和未飽和酸之共聚物所形成的銨鹽 。該最典型的烯烴係為C 2 - C 10之烯烴。未飽和酸偽與 烯烴共聚合，以形成酸性共聚物，該未飽和酸包括丙烯 条、甲基丙烯条、丁烯条、戊烯条及其他工業上已知的 - 1 0 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) · ϋ ϋ ϋ ϋ n ·ϋ I 一 口、· I I I I ϋ ·1 I · 經濟部智慧財產局員工消費合作社印製 524758 A7 B7 五、發明說明（） 多種合適的酸。適合的材料與共聚物組合而形成包含金 屬以及其他如鈉、鉀、鋅、銨和醯銨之鹽類。 在本發明中所使用作為吸收劑之陽性聚合物，其通常 是含有三價氮或四價氮。於官能基中，該三價氮可以存 在部份的線性或環狀結構，例如一级、二级或三級胺或 脾基酸化合物、聚胺、醯胺、吡咯啶酬、胺氧化物和芳 香族氮環（雜環）。該四级胺，則典型的俗由三級胺與烷 基或烷基芳基鹵化物反應所形成的。原則上，任何一種 含有三級氮或環狀氮之聚合物，均可，轉化成四級氮化合 物。特定的陽性聚合物，係可選自於乙烯吡咯啶酮均聚 物、乙烯吡咯啶酮-乙烯条酯類共聚物、丙烯酸条酯類、 乙烯吡咯啶酮共聚物、丙烯酸条酯類-經陽離子取代丙 烯酸單體共聚物、聚BS唑和經陽離子取代丙烯酸酯類-丙烯醯胺共聚物。在本發明此具體例中所使用之乙烯基 吡咯酮均聚物，其典型實例為傺可自BASF市售購得之 L U V i S 0 K L K 3 0和K 6 ϋ级，自國際特殊産品，蓋勤弗，思 絡，英國所購得之Ρ V Ρ Κ - 6 0，及自西巴特殊化學品公司 ，所購之G A L S C 0 L級D Ρ 6 - 7 1 3 2。在本發明中所使用之乙 烯基吡咯酮-乙烯条酯類共聚物，其典型實例為像可自 B A S F市售購得之L ϋ V I S 0 K L V A 6 4、自國際特殊産品所購 得之 PVP/VA S-630,及自 BASF所購之 COLLACRAL VL。該 丙烯酸酯類與經陽離子取代的丙烯酸單體共聚合，其偽 可自西巴特殊化學品公司所購得之GALSCOL级DP 6 - 2 7 9 9 和D P 6 - 2 7 2 4。該經陽離子取代的丙烯酸與丙烯酸醯胺之 -1 1 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -------------裝—^—訂---------線· (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 524758 A7 _B7_ 10 五、發明說明（） 共聚合，其典型材料為係可自B A S F所購之S E D I Ρ ϋ R級 C L 7 5 0和C F 6 0 4。該聚鸣唑之典型實例為聚（2 -乙基-2 -唑），傜可自格林漢，杜塞特，英國之西格馬有限公司 購得。 僅管如上所定義的各種不同吸收材料，該熱塑性油墨 趿收劑則偽較為合宜的。例如，經纖維材料所改質的他 種吸收材料，以及更宜的是經熱塑性纖維材料改質。合 適的油墨吸收劑，傺包含羥丙基纖維和纖維膠。特別喜 好的熱塑性經改質的纖維素之一，傺為可市售得自赫克 利士，威靈頓，德拉瓦之克魯塞爾E經改質纖維粉末。 其他合適的不具熱塑性之材料，偽包含布蘭諾斯纖維膠 (羧甲基纖維鈉）。此等通常可以記述為纖維醚。前面所 提到的G A L A S C 0 L D P 6，亦是一種合適的但為非熱塑性之 材料。 在本發明此具體例中所使用之聚乙烯条醇，其典型實 例為偽可自如下而市售購得：自哈羅化學公司，哈羅， 艾斯克斯，英國所購得之M0W10L 8-88、ALC0TEX 55-022H 和ALCOTEX SG，及自沃克化學公司所購之P0LVI0LM05/ 140。 ； 熱可活化黏著劑和油墨吸收劑總共佔成像紀錄層總重 量之9 0〜1 0 G %。較宜，包括熱可活化黏著劑和油墨吸 收劑為紀錄層之總重量之9 2到9 9 %而更宜是包括熱可活 化黏著劑和油墨吸收劑為紀錄層之總重量之9 7到9 9 %。 該熱可活化黏著劑包括約3 3 - 7 7 % pph (每百份重量之份 -1 2 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------裝-----^----訂--------- (請先閱讀背面之注意事項再填寫本頁) 524758 A7 B7 五、發明說明（ 11 數 之 量 重 總 層 錄 紀 像 成 約 是 宜 最 而 佔 及 劑 收 吸 墨 油 的 同 不 由 偽 成 組 所 料 材 物 合 75聚 少性 至子 之離 量陽 重 、 餘性 剩塑 之熱 層為 錄宜 紀較 吸 墨 油 該 為視 宜 ， 較層 ，錄 ph紀 P 像 6 6 成 ~ 的 2 餘 約其 之 Ο 量ph 重 P S 總50 層 ~ 錄30 紀之 像量 成重 佔總 共之 總層 劑錄 收紀 層膜 錄體 紀載 像於 成成 該形 善該 改 〇 以性 ， 用 劑應 厚和 增理 和處 劑之 性中 活作 面製 異層 有積 含印 地列 況可 情在 約 有 〇 具度 m厚 其之 ，米 層微 錄26 紀有 像具 成為 之宜 上較 圍 範 度 厚 之 米 微 而使 式並 形 ， 之液 液化 化乳 乳之 以主 傺為 其水 ，以 層 種 錄一 紀是 之宜 中較 體 ， 具上 此膜 0 隱 發載 本於 在塗 施 之其 層或 錄刀 紀刮 像以 成含 〇 包 燥 ， 乾行 下進 度來 溫段 之手 薄的 箸適 黏合 成何 形任 膜以 該可 於偽 低 ， 在用 其應 可傺分 及，續 料構連 材結個 漠1整 塗的之 塗燥子 滴乾粒 、經性 料該著 材 D 黏 錄層的 紀的, 像適收 成合吸 該成墨 布形油 分而之 來料基 置材水 裝塗於 布噴溶 分的可 他能為 於 界 偽 小 大 之 子 粒ο 性於 著等 黏約 該有 〇 具 層 ， 布圍 範 之 米 微 著 黏 該 LT 夕 此 ο 宜 合 為 較 小 大 之 米 徼 -------------裝-----^----訂---------線 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 滯 黏 的 展 擴 可 將 括 包 過 透 0係 形 ， 外中 之例 狀體 束具 成他 有其 具明 # 發 子本 粒在 性 展 擴 俘 J 可 提" 而該 中中 構文 結本 層在 積 。 印層 列積 可之 在膜 入體 併載 料除 材消 合以 聚抗 性阻 彈的 經 良 而因 時中 抗例 阻體 壞具 破此 和明 力發 到本 受在 在 〇 料質 材性 著之 謂列 意排 偽新 ， 重 語他 術其 門或 專長 之伸 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 524758 經濟部智慧財產局員工消費合作社印製 A7 _B7_ v 12 五、發明說明（） 此包括了載體膜、置於載體膜上之黏滯彈性材料、以及 置於該黏滯彈性材料上之成像紀錄層。 在本發明此具體例中所使用之載體膜，偽如同前面所 述者一般。 該黏滯彈性材料傺為具有熱塑物理性質之熱塑聚合物 ，該熱塑物理性質傺為對載體膜亦對油墨吸收層均展現 良好的黏箸性。該黏滯彈性材料所想要的性質，傺包含 小於室溫而且典型為界於-5 5 °C和+ 1 0 °C間之T g (玻璃轉 化温度）。所想要的模數（儲存模數或G 1為界於5 X 1 0 5 和2 X 1 0 6達因/平方公分之間。所想要的黏滯性（低模 數）為界於2 . 2 X 1 0 5和4 X 1 0 6泊之間較為合宜。如同 本發明中黏滯彈性材料物理性質之一般描述，該材料抗 阻當受力或在切割或切削可列印積層時受力之破壞時， 該材料傺可擴展的。 熟習此項技藝者當暸解到：本發明之黏滯彈性材料層 傜可以與如美國專利申請案Q 9 / G 7 / 3 G 2所記載之可列印 積層，以及其他可列印積層而組合使用的，特別是那些 將載體膜保持在積層中者。 黏滯彈性材料傺可以包括自聚胺基甲酸酯、丙烯酸条 、乙烯条、丁二烯-苯乙烯共聚物、異丙烯-苯乙烯共聚 物、聚氯乙烯和烯烴聚合物所組成之群類中選出之一種 或多種聚合物。在乙烯条之類別中，乙烯-乙烯基醋酸 酯共聚物傺特別適合於本發明中使用。 在本發明此具體例中，丙烯条之特別有用的例子為那 -14- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------------^----訂--------I. (請先閱讀背面之注意事項再填寫本頁) 524758 A7 _B7_ 13 五、發明說明（） 些商品名為D U R 0 T A K可從國家澱粉及化學公司，斯洛， 博克歇爾，英國而市售購得的丙烯聚合物；來自BASF之 A C R 0 N A L級的丙烯聚合物。 適合使用於本發明之黏著層中之乙烯条，其包含可得 自德國慕尼黑之華克公司之V I N N A P A S E P 1。 適合使用於本發明之丁二烯-苯乙烯共聚物，其典型 實例為可得自英國哈羅艾斯克斯之杜弗斯特安德公司之 REVINEX 8 0 R 1 0 〇 適合使用於本發明之異丙烯-苯乙烯共聚物，其典型 材料為可得自殼化學英國有限公司，策斯特，英國之 RRATON D和 HKRATON G 〇 聚氯乙烯係可從貝爾A . G .公司，朵爾門尼，德國市售 而得的，其商品名為D I S P E R C 0 L L C及B A Υ Ρ β E N。 適合的烯烴聚合物，其偽包括從BASF公司商品名為 0 P A N 0 L市售而得之聚異丁烯。其他烯烴聚合物包括聚丁 二烯和聚異丙烯。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 訂---------線. 改材添之。以吸 以該以塊像，在 ，良可段成上生 料改，譜之層發 材以外光層著而 同劑此的錄黏力 不塑。同紀到效 的增質不像料用 量含性助成材作 微包展輔達劑之 有料擴以到收光 含材可 ，至吸造 以等和料甚線人 。I 可此性材 ，外和份 1 偽 C 彈性膜紫光部 _ 層能滯彈體加陽譜 料性黏滯載添太光 材之的黏透以過UV 性層要到穿可透之 彈積想劑傺傺算像 滯印所收譜，打成 黏列到吸光的該之 該可達光該別除層 善料加，特去收 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 524758 A7 B7 14 五、發明說明（） 合適的增塑劑如對酞酸酯物，傺可從酒精公司、碧瑟 之斯脫弗公司，赫恃弗德歇爾公司，英國而購得。磷酸 酯物#可從西巴，曼徹斯特，英國而售得的。以及氯化 鏈烷烴傺可從I C I氯化學公司，如孔，策歇爾，英國而 售得的。適合的光吸收劑係為眾所週知的，並包含此類 可從西巴，曼徹斯恃，英國以商標名T I N U V I N販售而得 的材料。 在本發明此類具體例中所使用之某些熱塑性聚合物， 當在室溫下使用時偽可以是特別黏的。因此，可以預見 的，其載體膜傺可以用在表面上之分離塗層材料，來處 理相對於黏著層之膜，以使得該膜可以輕易的線軸或棍 上解開，並且如所需要使用於可列印積層之列印或固接 般之解開。諸如此類之分離塗層，通常傺在黏著工業中 所知的，而且包含此等如E S C 0 A T P (聚乙烯十八烷基胺 甲酸酯）之材料，其偽可從伊孟爾德化學有限公司，威 德舍爾，伯克歇爾，英國而市售得到的。 在本發明此具體例中之成像紀錄層，偽包括可熱活化 黏著劑及油墨吸收劑。該可熱活化黏著劑傺選自於如下 所組成群類之一種或多種材料：聚胺基甲酸酯、乙烯基 酯共聚物、丙烯基酯共聚物、及離子共聚物（全部傺與 先前在本發明第一具體例成像紀錄層中熱活化黏著劑所 描述者相同）、聚胺基甲酸酯、丙烯条、乙烯条、丁二 烯-苯乙烯共聚物、異丙烯-苯乙烯共聚物、聚氯乙烯、 及烯烴聚合物（全部傺與先前在本發明具體例中之黏滯 -1 6 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ----------------^----訂--------- (請先閱讀背面之注意事項再填寫本頁) 524758 經濟部智慧財產局員工消費合作社印製 Α7 Β7 五、發明說明（1 ) 彈性材料所描述者相同）、以及酚氧樹脂。本發明中所 使用之油墨吸收劑傺選自於如下所組成群類：陽性聚合 物之摻混物、陽性聚合物和纖維素醚之摻混物以及聚乙 烯基醇（全部係與先前在本發明第一具體例中之油墨吸 收劑所描逑者相同）。 在本發明成像紀錄層中作為可熱活化黏著劑使用之酚 氧樹脂，其典型實例為以商標名P K H W - 3 5酚氧協會，洛 克希爾，南柯羅納斯市售而得的。當酚氧使用於成像紀 錄層中時，其可能必需與兩性界面活性劑組合使用，以 作為電荷貯庫。正常情形，該酚氧樹脂偽以溶於水之陰 離子性分散液形式來供應，並且陰離子性分散液並不對 應於該陽性聚合物，（例如油墨吸收劑偽可以於成像紀 錄層中使用）。因此，熟習此項技藝者，當透過使用兩 性界面活性劑而認知到酚氧樹脂所需要減少的負電荷價 數。該兩性界面活性劑係作為在成像紀錄層中之酚氧樹 脂和陽性聚合物間之”橋樑"。當認知到，兩性界面活性 劑之功用，偽在使用酚氧樹脂之體条中之下。事實上， 在本發明接合中所使用之任何一種陰離子性黏著劑，係 可能具有其對應之使用兩性界面活性劑而改質的陽性油 墨吸收劑。合適的兩性界面活性之一，傺為柯逹界面活 性劑股份有限公司，斯耐斯，漢伯斯德，英國之 CRODATERIC CΥΝΑ〇 黏滯彈性材料傺可以水溶性分散液、與有機溶劑形成 水溶液，或熱熔融形式而直接澱積於載體膜上。通常， -1 7 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝-----^----訂---------族 «丨 經濟部智慧財產局員工消費合作社印製 524758 A7 _B7_ 16 五、發明說明（） 該黏滯彈性材料包括佔黏滯彈性材料層和成像紀錄層總 重量之6 0〜8 G重量％。較宜，該黏滯彈性材料包括佔黏 滯彈性材料層和成像紀錄層總重量之6 2 . 5〜8 0 . 0重量％ ，而最宜是佔黏滯彈性材料層和成像紀錄層總重量之 7 0 · 0 〜7 5 · 0 〇 在黏滯彈性材料層中，該黏滯彈性材料傜可以包括至 高為該層總重量之1QG重量％。如果存在的話，增塑劑可 以包括至高為該黏滯彈性材料層總重量之1 〇 〇重量％。同 樣的，如果存在的話，ϋ V光吸收劑可以包括該黏滯彈性 材料層總重量之約2 . G〜5 · 0重量％。 該黏滯彈性材料層之厚度，典型上偽界於2 Q〜5 0微米 之間，較宜是具有2 5〜4 0微米，並且最宜是3 0〜3 5微米。 在本發明此具體例中之紀錄層，偽以乳化液之形式而 施加於載體膜上，較宜是以水為主之乳化液，並使之乾 燥。該經乾燥的膜結構，係為可溶於水基之油墨吸收劑 的黏箸性粒子之整個連續分布層。該黏著性粒子之大小 偽界於Q.Q8〜30.G微米之範圍，具有約等於0.1微米之 大小較為合宜。此外該黏著性粒子係具有成束狀之外形。 該油墨吸收層偽可以含有分散性黏著劑之水溶液形式 而澱積於黏著性層之上，並且該層像在低於形成黏著性 分散液之溫度下乾燥成最小之厚度。 該可熱活化黏著劑及油墨吸收劑一起佔成像紀錄層總 重量之9 3〜9 8 %。較宜，可熱活化黏著劑及油墨吸收劑 一起佔94〜98%，而且最宜是佔成像紀錄層總重量之佔 - 1 8 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁〕 · ϋ ϋ ϋ ϋ I I n 一 口、I ϋ ϋ I I I ϋ I · 524758 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（17 ) 9 7〜9 8 %。當油墨吸收劑包括佔成像紀錄層總重量之3 4 〜5 G p p h，較宜是油墨吸收劑包括佔成像紀錄層總重量 之3 9〜4 9 p p h ,而且最宜是佔成像紀錄層總重量之3 9 . 2〜 4 1 . 2pph時，則該可熱活化黏著劑包括佔成像紀錄層總 重量之4 8〜6 4 p p h，較宜是可熱活化黏著劑包括佔成像 紀錄層總重量之50〜6Gpph，而且最宜是佔成像紀錄層 總重量之5 7 . 8〜5 9 . 8 p p h。該成像紀錄層之其餘部份， 傺包括視情況地包括界面活性劑及/或增稠劑。 該成像紀錄層偽可以直澱積於黏滯彈性材料層之上， 並使之乾燥。然而，較佳的結果是經由在分離片上之油 墨紀錄材料，促使該材料將該成像紀錄層乾燥而得到的 。當乾燥時，該成像紀錄層傺直接置於黏滯彈性材料層 之上。該分離片偽可以在將成像紀錄層置放於黏滯彈性 材料層之前或緊接在其後而移除。 本發明業已作一般性之描述，除非有特別的說明之外 ，以下之實施例係包含用以舉例説明以使易於瞭解本發 明，以及並不打算用來限制本發明之申請專利範圍之目 的。 太發明奮旃例 依照賁施例1 - 6而製備具有載體膜和油墨吸收層之可 列印積層之樣品群組。實施例1 - 4傺使用在每一配方中 含至少一種熱塑性之油墨吸收劑，而實施例5 - 6則使用 在無顯箸熱塑性之油墨吸收劑。 奮施例1 -1 9- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ------------裝-----^----訂---------線_ (請先閱讀背面之注意事項再填寫本頁) 524758 A7 B7 18 五、發明說明（） 製備載體膜以供油墨吸收層塗覆。所使用的載體膜偽 斯威登公司製，懷特斯亥，英國，商標名為E T I C 0 U R T之 市售可得的方向性聚丙烯膜。該膜之厚度為約5 7微米。 依如下所示之成分及量來製備成像紀錄層之混合物。 成分 說明 重量 乾重 GASCOL LS20 (聚丙烯酸酯） 5 0 · 7重量％ 4 9 · 6重量％ 去離子水 （稀釋劑） 2 4 · 4重量％ •… LUISKOL VA64 (乙烯基吡咯啶酮 24.4重量％ 49.7重量％ 乙烯基酯共聚物） LUMITEN AFK (界面活性劑） 0.5重量％ 0.7重量％ 該混合物偽施加於載體膜上並且於約5 G °C下乾燥。使 用足夠量之混合物，以使得包括油墨吸收層之材料之量 ，在乾燥後偽為約25克每平方公尺。 利用C H R Ο Μ A 2 4噴墨印表機將成像列印於積層上以測 試積層列印，通常該印表機可購自印卡德公司，聖地牙 哥，加州，美國。以此方式制備此實施例中之兩個列印 積層試樣。第一値試樣，傺積層到3厘米厚之發泡板上 ，而第二個試樣則利用積層棍壓機，在設定之1 G (TC、 經濟部智慧財產局員工消費合作社印製 8 0 p s i之壓力下，以2呎每分鐘之飼入速率，積層到經 擴展的3厘米厚之P V C板上。緊接於積層之後，使該可 列印積層和固接板冷卻到室溫下。黏著該積層到每一個 試樣之目標測試板上，該每一個試樣偽經利用樣品拉伸 試樣而測試。在測試中，施加拉力到積層上，直到發生 可列印積層從固接板上分離為止。假若，積層帶走固接 -2 0 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 524758 A7 B7 , 19 五、發明說明（） 板上部份或全部的表面紙，則該黏著品質可視為良好〇 假若從固接板上剝離之積層，未帶走一部份的表面紙， 則該黏著品質可視為是差的。在非紙塗層板之情況時， 假若，積層偽很困難的從板或經消除含成像層之載體上 分離，則該黏著品質可視為良好。經發現：此實施例中 之可列印積層均對固接板提供良好的黏著性。 奮旃例2 利用與實施例1相同之載體膜，經由施加2 5克（乾重） 每平方公尺之油墨吸收層之積層塗層來製備可列印積層 。依如下所示來製備油墨吸收層。 成分 説明 重量 乾重 AQUASEAL 1127 (聚丙烯酸酯） 70·3重量％ 48.4重量％ LUISKOL VA64 (乙烯基吡咯啶 14.1重量％ 48. 6重量％ 酮乙烯基酯共聚物） 去離子水 （稀釋劑） 1 4 · 1重量％ , · · 氨，比重0.88 (中和劑） 〇.5重量％ .·· 溴酸 酸化劑、沈澱劑 0 . 7重量％ 2 . 4重量％ L ϋ Μ I T E N A F Κ (界面活性劑） 0·3重量％ 0.6重量％ 利用與實施例1相同之方法，將成像紀錄層予以乾燥 並印列成像。實施例2之第一個可列印積層試樣，偽積 層到3厘米厚之發泡板上，而第二値試樣則利用積層棍 壓機，在設定之1 〇 Q °C、8 Q p s i之壓力下，以2呎每分鐘 之飼入速率，積層到經擴展的3厘米厚之P V C板上。經 發現：此兩者對經擴展的PVC板和發泡板均具良好的黏 -2 1 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝-----：----訂---------線 經濟部智慧財產局員工消費合作社印製 524758 A7 _B7_ 2 0 五、發明說明（） 著性。524758 A7 _B7_ 5. Description of the invention (7) When activated, the fixed plate 3 G and the printable laminate are brought into contact with the laminate, and the heat from the laminate stick 36 and the pressure from the pinch 38傺 Make sure that the printable laminate is adhered to the fixed board. It will be understood that there is no intention in the present invention to cause a fusion transfer of the imaging recording layer or release of the imaging recording layer from the carrier film. Instead, after the printable layer has finished adhering to the target surface, it is attempted to keep the carrier at the imaging record layer position. The carrier film in the present invention is preferably a transparent or substantially transparent film having a polymer composition. Such polymeric film materials suitable for the present invention include polyester, polyvinyl chloride, polyvinyl fluoride, or polypropylene films. In addition, a multi-layer carrier film can also be used in the present invention, except when a fabric is required for graphics. One of the multilayer carrier films suitable for use in the present invention, a pseudo-DEEP crystal, a laminated layer of 3 Q micron, a polypropylene woven film, and a 50 micron polyester film, are available from Assi-Doma, Belgium. Got. The M A T T crystalline form is a multi-layer-like carrier film available from the same supplier. The surface of the selected film can be optionally treated with chemicals and / or different procedures to improve the adhesion of the material to the film. One of the treatment methods is the electric discharge treatment. Carrier film used in the present invention ----------- Order --------- (Please read the precautions on the back before filling (This page) The consumer cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs prints the difference between the micrometer and the micrometer. 5 2 to 6 3 In the world, the range is thick, and the film Qudou dfln includes the pseudo-layer record. 〇 Moderate cases of thick body with twilight 5 meters thick and unidentified acid methylbenzyl in amine. The self-recording image of the polymer layer is recorded, and the work of the agent is to stick the ink to the oil to absorb heat, and the agent is used to make the glue in the living case. Allyl / polyester esters Ethylene / ester This paper size applies the Chinese National Standard (CNS) A4 (210 X 297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 524758 A7 _B7_ V. Description of the invention ( 8) One or more adhesives selected for the copolymer group. The ink-receiving material used in this embodiment of the present invention is one or more selected from a mixture of a pseudo-positive polymer, a blend of a positive polymer and a fiber ether, and a polyvinyl alcohol group. material. Polyurethanes used in the present invention are typically commercially available materials such as DS 3507, DS 3459, and 200A grades of LUPHEN, which are commercially available from BASF, Ziduo, Zicher, and the United Kingdom. -D, WITC0B0ND grade 2 3 3-2 2, 2 4 2-6 7, 2 8 0-4 2 and 7 5 available from Bucksden, Dewey Qi, Worcester, UK 5. NE 0 REZR-5 6 3, which can be purchased from Encarisin, Qi, Norway, Qischer, UK. Examples of vinyl strip esters used in the present invention. Commercially available materials include those commercially available from Kodak Adhesives Corporation, Newark Nat Marshall, UK under the trade name CR 0 DALA Μ 2 9-1 88, EP 1, EP 4 0 0, EN 2 4 and EF 4 1 grades, and C E 7 5 2 available from Barvakel Chemical Company, Munich, Germany. Examples of suitable ethylene stripe ester copolymers used in the present invention include GALSCOL grades available from SIBA Specialty Chemicals, Balaford, West Yorkshire, UK, and BASF Examples of commercially available ACRONAL 290D0 are examples of suitable ionic copolymers used in the present invention, in which hydrazone is a metal, aluminum, or an ammonium salt formed from a copolymer of an olefin and an unsaturated acid. The most typical olefins are C 2 -C 10 olefins. Unsaturated acids are pseudo-copolymerized with olefins to form acidic copolymers. The unsaturated acids include propylene, methacrylic, butene, pentene, and others known in the industry.-1 0-Applicable to this paper size China National Standard (CNS) A4 Specification (210 X 297 mm) (Please read the precautions on the back before filling out this page) · ϋ ϋ ϋ ϋ n · ϋ I bite, · IIII ϋ · 1 I · Ministry of Economic Affairs Intellectual Property Printed by the Bureau's Consumer Cooperatives 524758 A7 B7 V. Invention Description () A variety of suitable acids. Suitable materials are combined with the copolymer to form metals and other salts such as sodium, potassium, zinc, ammonium, and ammonium ammonium. The positive polymer used as an absorbent in the present invention usually contains trivalent nitrogen or tetravalent nitrogen. In the functional group, the trivalent nitrogen may have a partial linear or cyclic structure, such as a primary, secondary, or tertiary amine or splenic acid compound, polyamine, amidine, pyrrolidine, amine oxide, and Aromatic nitrogen ring (heterocyclic). The quaternary amine is typically formed by the reaction of a tertiary amine with an alkyl or alkylaryl halide. In principle, any polymer containing tertiary nitrogen or cyclic nitrogen can be converted into a quaternary nitride. The specific positive polymer may be selected from the group consisting of vinylpyrrolidone homopolymer, vinylpyrrolidone-vinyl ester copolymers, acrylic acid esters, vinylpyrrolidone copolymer, acrylic acid esters-cationized Substituted acrylic monomer copolymers, polyBSazoles and cation-substituted acrylic esters-acrylamides copolymers. The typical examples of the vinylpyrrolidone homopolymer used in this specific example of the present invention are LUV i S 0 KLK 30 and K 6 ϋ grades commercially available from BASF, from international special products, covers Qin Fu, Siluo, UK purchased PV PK-60, and GALSC 0 L-level D PF 6-7 1 3 2 purchased from Xiba Specialty Chemicals. Typical examples of the vinylpyrrolidone-vinyl ester copolymers used in the present invention are like LϋVIS 0 KLVA 6 commercially available from BASF 4. PVP / VA S-630, and COLLACRAL VL purchased from BASF. The acrylates are copolymerized with cation-substituted acrylic monomers, and are pseudo-GALCOL grade DP 6-2 7 9 9 and D P 6-2 7 2 4 available from SIBA Special Chemicals. The cation-substituted acrylic acid and ammonium acrylate -1 1-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------- packing— ^ —Order --------- Line · (Please read the precautions on the back before filling out this page) Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Consumer Cooperatives 524758 A7 _B7_ 10 V. Description of Invention () Co-aggregation, its Typical materials are SEDI P ϋ R grade CL 7 50 and CF 6 0 4 available from BASF. A typical example of the polyimidazole is poly (2-ethyl-2-azole), which is commercially available from Greenham, Dusselt, Sigma Co., Ltd., England. Regardless of the different absorbing materials as defined above, the thermoplastic ink scavenger is more suitable. For example, other absorbent materials modified by fiber materials, and more preferably modified by thermoplastic fiber materials. A suitable ink absorbent, 傺 contains hydroxypropyl fibers and viscose. One of the particularly preferred thermoplastic modified celluloses is the Krussel E modified fiber powder commercially available from Hercules, Wellington, Drava. Other suitable non-thermoplastic materials include pseudo-Branos viscose (carboxymethylcellulose sodium). These can usually be described as fiber ether. The aforementioned G A L A S C 0 L D P 6 is also a suitable but non-thermoplastic material. A typical example of the polyvinyl alcohol used in this specific example of the present invention is a pseudo-commercially available commercially: M0W10L 8- available from Harlow Chemical Company, Harlow, Aix, UK 88. ALC0TEX 55-022H and ALCOTEX SG, and P0LVI0LM05 / 140 purchased from Walker Chemical Company. ; The heat-activatable adhesive and ink absorber account for a total of 90 to 10 G% of the total weight of the imaging record layer. Preferably, it includes 92 to 99% of the total weight of the recording layer including the heat-activatable adhesive and the ink absorbent, and more preferably includes 97 to 97% of the total weight of the recording layer including the heat-activatable adhesive and the ink absorbent. 9 9%. The heat-activatable adhesive includes about 3 3-7 7% pph (parts per 100 parts by weight-1 2-this paper size applies to China National Standard (CNS) A4 specifications (210 X 297 mm) ----- ------- Install ----- ^ ---- Order --------- (Please read the precautions on the back before filling this page) 524758 A7 B7 V. Description of the invention (11 The total weight of the total layer recording is the most suitable and the most suitable is to absorb the ink and absorb the ink. The material of the group of materials can be combined with the amount of 75. The weight of the material is positive, the heat of the residual plasticity. The layer is more suitable for the ink-absorbing oil than the ink absorber. For the upper layer, the ph-phase P image is 60% to 60% of the more than 0. The amount of ph is PS and the total is 50 layers. The 30-day image is the total weight. The overall layer recording and recording layer film recordings are recorded in the form of the film, the shape should be good, and the nature should be improved. The application agent should be thick and the conditioner and the nature of the agent should work as a surface. It can be said that the thickness is about 0 ° m and the thickness of the micro-level recording of the 26th century is better than the thickness of the micrometer. The main ingredient of the milk is the water, and it is appropriate to record it in layers. With this film 0, it is hidden in the coating or the scraped image of the knife. Dry, dry, and dry in the warm section of the hand, thin thin film suitable for the formation of any shape of the film, so that it can be false low, in which it should be able to be divided, and the continuous structure of the continuous structure of the coating Dry particles, dry materials, and long-lasting materials of the adhesive layer of the recording layer, like a suitable product and absorb the ink-forming cloth-shaped oil. The base material is water-coated and sprayed on the cloth. In order to be a pseudo-small big seed in the world, there should be 0 layers in the nature, and the rice of the cloth encircling fan should stick to the LT, so it should be combined into a small rice. -------- ----- Equipment ----- ^ ---- Order --------- line (Please read the precautions on the back before filling this page) Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs The sticky expansion and expansion can include the 0-transparent shape, and the external body can be bundled into other parts of its body. # 发 子 本 粒 在 性 展 Extended capture J 可 提 & q uot; The Chinese and Chinese texts are structured in this layer. The printed layer can be placed in the membrane and loaded with materials to eliminate the material to aggregate the resistance and resistance of the bomb. He Mingli sent a message to the public that the material quality of the material is arguably anti-counterfeiting. The language of the paper is different from other methods or expertise. The paper size is applicable to China National Standard (CNS) A4 (210 X 297). (%) 524758 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _B7_ v 12 V. Description of the invention () This includes the carrier film, the viscoelastic material placed on the carrier film, and the viscoelastic material placed on the viscoelastic material. Image recording layer. The carrier film used in this embodiment of the present invention is substantially the same as that described above. The viscoelastic material is a thermoplastic polymer with thermoplastic physical properties. The thermoplastic physical property is that it exhibits good adhesion to both the carrier film and the ink absorbing layer. The desired properties of this viscoelastic material include Tg (glass transition temperature) less than room temperature and typically between -5 ° C and + 10 ° C. The desired modulus (storage modulus or G 1 is bounded between 5 X 1 0 5 and 2 X 1 0 6 dyne / cm 2. The desired viscosity (low modulus) is bounded by 2. 2 X 1 0 5 and 4 X 1 0 6 are more suitable. As the general description of the physical properties of the viscoelastic material in the present invention, the material resists resistance when under stress or when cutting or cutting printable laminates The material is extensible when damaged by force. Those skilled in the art will understand that the viscoelastic material layer of the present invention can be used as described in US Patent Application Q 9 / G 7/3 G 2 Printable laminates, and other printable laminates are used in combination, especially those that retain the carrier film in the laminate. Viscoelastic materials may include self-urethane, acrylic strips, vinyl strips, butadiene One or more polymers selected from the group consisting of diene-styrene copolymers, isopropylene-styrene copolymers, polyvinyl chloride and olefin polymers. In the category of ethylene bars, ethylene-vinyl acetate Copolymer VII is particularly suitable for use in the present invention. In this specific example of the present invention, A particularly useful example of olefin strips is that -14- This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ------------------ ^ ---- Order -------- I. (Please read the notes on the back before filling out this page) 524758 A7 _B7_ 13 V. Description of the invention () These products are sold under the names of DUR 0 TAK and national starch and Chemical company, Sillow, Boxer, UK, commercially available propylene polymer; ACR 0 NAL grade propylene polymer from BASF. Ethylene strips suitable for use in the adhesive layer of the present invention, which contain available VINNAPASEP 1. from Walker, Munich, Germany. Suitable butadiene-styrene copolymers for use in the present invention, a typical example of which is REVINEX 8 available from Duversteander, Harvard Essex, UK 0 R 1 0 〇 Iso-propylene-styrene copolymers suitable for use in the present invention, the typical materials of which are available from Shell Chemical UK Ltd., Zester, RRATON D and HKRATON G 〇 Polyvinyl chloride are available from Bell A.G. company, Dolmeni, Germany, commercially available under the trade name DISPER C 0 LLC and BA Ρ β β EN. Suitable olefin polymers include pseudo-isobutene commercially available from BASF under the trade name 0 PAN 0 L. Other olefin polymers include polybutadiene and polyisopropylene. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page) Order --------- line. In order to absorb the image of the block, in the good, it can be converted into a raw material, the spectrum of the layer of hair is coated with a light layer, and the viscosity of the same agent is not plastic. The quality improvement in the same period is not like the use of the content of the auxiliary material as a micro-encapsulated auxiliary agent, the material can be expanded to the finished material, to the suction and so on. I This material, outer part 1 Pseudo-C elastic film Violet part _ Layer energy retarder plus positive spectrum material Viscosity load Titanium material for penetration through UV-resistant layer to penetrate through the elastic The imaginary agent is calculated as a stagnant spectrum, and it should be added to the absorbable light that should be added to the light absorption layer. It should be added to the good material, and the wisdom of the Ministry of Economic Affairs and the Intellectual Property Bureau staff consumer cooperatives to print the wisdom of the Ministry of Economic Affairs. Printed by the Consumer Affairs Cooperative of the Property Bureau 524758 A7 B7 14 V. Description of the invention () Suitable plasticizers such as terephthalates, can be obtained from alcohol companies, Bethesto's Steve Company, and Huxford Descher Company. , Purchased in the UK. Phosphate # is commercially available from Siba, Manchester, UK. As well as chlorinated paraffin hydrazones are commercially available from I C I Chlorine Chemicals, such as Kong, Zecher, United Kingdom. Suitable light absorbers are well known and include such materials which are commercially available under the trade name T I N U V I N from Siba, Manchester, UK. Certain thermoplastic polymers used in such specific examples of the invention may be particularly sticky when used at room temperature. Therefore, it is foreseen that the carrier film can be used as a separation coating material on the surface to treat the film relative to the adhesive layer, so that the film can be easily unwound on a spool or stick, and used as required It can print the printing of multi-layers or unfasten it like fixing. Such separation coatings are generally known in the adhesive industry and contain such materials as ESC 0 ATP (polyethylene octadecyl carbamate), which can be obtained from Immund Chemical Co., Ltd. , Weidsher, Berkshire, UK and commercially available. The imaging recording layer in this embodiment of the present invention includes a heat-activatable adhesive and an ink absorber. The heat-activatable adhesive is selected from one or more materials of the following group: polyurethane, vinyl ester copolymer, propylene ester copolymer, and ionic copolymer (all The first specific example of the present invention has the same description as the thermally activated adhesive in the imaging recording layer), polyurethane, propylene strip, ethylene strip, butadiene-styrene copolymer, isopropylene-styrene copolymer, Polyvinyl chloride, and olefin polymers (all of which have the same viscosity as in the specific examples of the present invention-16-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ----- ----------- ^ ---- Order --------- (Please read the notes on the back before filling out this page) 524758 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Α7 Β7 5. Description of the invention (1) The elastic material is the same as described), and phenolic resin. The ink absorbent used in the present invention is selected from the group consisting of a blend of a positive polymer, a blend of a positive polymer and a cellulose ether, and polyvinyl alcohol (all of which are the same as those previously described in this document). The ink absorbent described in the first specific example of the invention is the same). Typical examples of phenolic resins used as heat-activatable adhesives in the imaging recording layer of the present invention are commercially available under the trade name P K H W-35 Phenoxy Association, Rock Hill, South Coronas. When phenolic oxygen is used in the imaging recording layer, it may be necessary to use it in combination with an amphoteric surfactant as a charge reservoir. Normally, the phenolic resin is supplied in the form of an anionic dispersion that is soluble in water, and the anionic dispersion is not compatible with the positive polymer (for example, an ink absorber can be used in the imaging recording layer). Therefore, those skilled in the art, when using amphoteric surfactants, will realize that the negative charge of phenolic resins needs to be reduced. The amphoteric surfactant acts as a "bridge" between the phenolic resin and the positive polymer in the imaging record layer. When it was recognized that the function of the amphoteric surfactant was in the body of the phenolic resin, In fact, any of the anionic adhesives used in the bonding of the present invention may have a corresponding positive ink absorbent modified using an amphoteric surfactant. One of the suitable amphoteric interface activities is 傺 Ke逹 CRODATERIC CΥΝΑ〇 Viscoelastic Material of Surfactant Co., Ltd., Snearth, Humberstead, UK 傺 Can be directly deposited on the carrier film in water-soluble dispersions, aqueous solutions with organic solvents, or hot-melt forms Normally, -1 7-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Loading ----- ^ --- -Order --------- Family «丨 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 524758 A7 _B7_ 16 V. Description of the invention () The viscoelastic material includes a layer of viscoelastic material and an imaging record layer 60 ~ 8 G% by weight of the total weight. More preferably, the viscoelastic material includes 6 2 .5 ~ 8 0. 0% by weight of the total weight of the viscoelastic material layer and the imaging recording layer, and the most preferably The total weight of the viscoelastic material layer and the imaging recording layer is 7 0 · 0 ~ 7 5 · 0 〇 In the viscoelastic material layer, the viscoelastic material 傜 may include up to 1QG wt% of the total weight of the layer. If If present, the plasticizer may include up to 100% by weight of the total weight of the viscoelastic material layer. Similarly, if present, the ϋV light absorber may include about 2% of the total weight of the viscoelastic material layer G ~ 5 · 0% by weight. The thickness of the viscoelastic material layer is typically between 2 Q ~ 50 micrometers, more preferably 25 ~ 40 micrometers, and most preferably 30 ~ 35 μm. The recording layer in this specific example of the present invention is applied to the carrier film in the form of an emulsion, and it is more preferable to dry the water-based emulsion. The dried film structure Is a continuous distribution layer of viscous particles that are soluble in water-based ink absorbents The size of the adhesive particles is in the range of Q.Q8 ~ 30.G microns, and it is more suitable to have a size equal to about 0.1 microns. In addition, the adhesive particles have a bundle-like outer shape. The ink absorbing layer may contain The dispersible adhesive is deposited on the adhesive layer in the form of an aqueous solution, and the layer is dried to a minimum thickness at a temperature lower than the temperature at which the adhesive dispersion is formed. The heat-activatable adhesive and the ink absorber together occupy 9 3 ~ 98% of the total weight of the imaging recording layer. More preferably, the heat-activatable adhesive and ink absorber together account for 94 ~ 98%, and most preferably the total weight of the imaging recording layer-1 8-This paper Standards are applicable to China National Standard (CNS) A4 specifications (210 X 297 mm) (Please read the precautions on the back before filling out this page) · ϋ ϋ ϋ ϋ II n sip, I ϋ ϋ III ϋ I · 524758 Ministry of Economic Affairs wisdom A7 B7 printed by the Consumer Cooperatives of the Property Bureau V. Invention Description (17) 9 7 ~ 98%. When the ink absorbent comprises 3 4 to 5 G pph of the total weight of the imaging record layer, it is more preferable that the ink absorbent includes 3 9 to 4 9 pph of the total weight of the imaging record layer, and most preferably the total weight of the imaging record layer In the case of 39. 2 to 4 1.2 pph, the heat-activatable adhesive includes 4 8 to 6 4 pph, preferably the heat-activatable adhesive includes the total weight of the imaging record layer. 50 ~ 6 Gpph, and most preferably 57.8 to 59.8 pph of the total weight of the imaging record layer. The remainder of the imaging record layer includes, optionally, a surfactant and / or a thickener. The imaging recording layer can be deposited directly on the viscoelastic material layer and allowed to dry. However, a better result is obtained by using an ink recording material on the separation sheet to urge the material to dry the imaging recording layer. When dry, the imaging recording layer 傺 is placed directly on top of the viscoelastic material layer. The separator can be removed before or immediately after the imaging recording layer is placed on the viscoelastic material layer. The present invention has been described generally. Unless otherwise specified, the following examples are included for the purpose of illustration to make the invention easier to understand, and are not intended to limit the scope of patenting of the present invention. Exemplary inventions A sample group of printable laminates having a carrier film and an ink absorbing layer was prepared according to Examples 1 to 6. Examples 1 to 4 used ink absorbents containing at least one thermoplastic in each formulation, while Examples 5 to 6 used ink absorbents without significant thermoplastics. Fen Shi Example 1 -1 9- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ------------ Installation ----- ^ ---- Order --------- Line_ (Please read the precautions on the back before filling out this page) 524758 A7 B7 18 V. Description of the invention () Prepare a carrier film for coating the ink absorbing layer. The carrier film used was a commercially available directional polypropylene film manufactured by Swaden, Whiteswater, UK, under the trade name E T I C 0 U R T. The thickness of the film is about 57 microns. A mixture of imaging recording layers was prepared with the ingredients and amounts shown below. Ingredient Description Weight Dry Weight GASCOL LS20 (Polyacrylate) 5 0 · 7 wt% 4 9 · 6 wt% Deionized Water (Diluent) 2 4 · 4 wt% •… LUISKOL VA64 (Vinylpyrrolidone 24.4 wt% 49.7% by weight of vinyl ester copolymer) LUMITEN AFK (surfactant) 0.5% by weight 0.7% by weight The mixture was pseudo-applied to a carrier film and dried at about 5 G ° C. A sufficient amount of the mixture is used so that the amount of the material including the ink absorbing layer is approximately 25 grams per square meter after drying. A CH R OM A 2 4 inkjet printer was used to print the images on the buildup to test the buildup printing, which is typically available from Inca Card Corporation, San Diego, California, USA. In this way, two print laminate samples in this example were prepared. The first sample was stacked on a foam board of 3 cm thickness, while the second sample was printed on a set 1 G (TC, Employee Consumption Cooperative of Intellectual Property Bureau of the Ministry of Economic Affairs 8 using a laminated stick press). Laminate onto an expanded 3-cm-thick PVC board at a feed rate of 2 feet per minute at a pressure of 0 psi. Immediately after the laminate, allow the printable laminate and the anchor plate to cool to room temperature Adhere the laminate to the target test board of each sample. Each sample is tested by using the sample to stretch the sample. In the test, a tensile force is applied to the laminate until the printable laminate is firmly attached. Until the board is separated. If the laminate is taken away and fixed-2 0-This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) 524758 A7 B7, 19 V. Description of the invention () Board part Or all the surface paper, the adhesion quality can be regarded as good. If the laminate peeled from the fixed board, a part of the surface paper is not taken away, the adhesion quality can be regarded as poor. On non-paper coated boards In the case, if it is difficult to laminate the board or warp Except for the separation on the carrier containing the imaging layer, the adhesion quality can be regarded as good. It was found that the printable laminates in this embodiment all provide good adhesion to the fixed board. Example 2 uses the same as in Example 1. The carrier film was prepared by applying a laminated coating of 25 grams (dry weight) of the ink absorbing layer per square meter to prepare a printable laminate. The ink absorbing layer was prepared as follows. Ingredients Description Dry AQUASEAL 1127 ( Polyacrylate) 70 · 3% by weight 48.4% by weight LUISKOL VA64 (Vinyl pyrrolidine 14.1% by weight 48.6% by weight Ketone vinyl ester copolymer) Deionized water (diluent) 1 4 · 1% by weight, · · · Ammonia, specific gravity 0.88 (neutralizing agent) 0.5% by weight ... Bromate acidifying agent, precipitant 0.7% by weight 2.4% by weight L ϋ Μ ITENAF κ (surfactant) 0.3% by weight 0.6 % By weight Using the same method as in Example 1, the imaging record layer is dried and printed for imaging. The first printable laminated sample of Example 2 was pseudo-laminated onto a 3 cm thick foam board, and Laminated bar presses Laminated on an expanded 3 cm thick PVC board at a feed rate of 2 feet per minute at a set pressure of 10 ° C and 8 Q psi. It was found that these two pairs of expanded PVC Both the board and the foamed board have good adhesion-2 1-This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) Packing --- -: ---- Order --------- Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 524758 A7 _B7_ 2 0 V. Description of the invention ().
奮施例3 A 利用經電翬放電處理之聚酯膜，澱積3 5克（乾重）每平 方公尺之成像紀錄層材料於載體膜上，以製備可列印積 層。該油墨吸收層#於低於5 8 °C之温度下乾燥。油墨吸 收層之配方係如下所示： 成分 説明 重量 乾重 WICTBOND (聚丙烯酸酯） 59·2重量％ 55· 3重量％ 232-22 LUISKOL VA64 (乙烯基吡咯啶 16.6重量％ 38. 8重量％ 酮乙烯基酯共聚物） 去離子水 （稀釋劑） 1 6 · 6重量％ ... GLASCOL DP6-(陽性聚合物） 6.7重量％ 4.9重量％ 7 13 2 LUMITEN IRA (界面活性劑） 0.9重量％ 1.0重量％ 在油墨吸收層乾燥之後，利用如實施例1之G S油墨組 C Μ Ο Μ A 2 4噴墨印表機列印。將該列印成像予以乾燥， 並且將第一列印成像試樣積層到3厘米厚之發泡板上， 而第二列印成像試樣則利用積層輾壓機，在設定之1 D 0 °C 、8 G p s i之壓力下，以2呎每分鐘之飼入速率，積層到 經擴展的3厘米厚之P V C板上。經發現：在剝離測試上， 此積層到經擴展的P V C板和發泡板兩者均具良好的黏著性。 -2 2 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) ^^1 * n -i-Bi n i·— ·ϋ 一 口、I ϋ Β-ϋ —ϋ 1 ϋ· ·1_— tm/ I · 經濟部智慧財產局員工消費合作社印製 經濟部智慧財產局員工消費合作社印製 524758 A7 _B7_ 2 1 五、發明說明（）Example 3A Using a polyester film treated with an electric discharge, 35 g (dry weight) of an imaging recording layer material per square meter was deposited on a carrier film to prepare a printable layer. The ink absorbing layer # is dried at a temperature below 58 ° C. The formula of the ink absorbing layer is as follows: Ingredient Description Weight Dry Weight WICTBOND (Polyacrylate) 59.2% by weight 55.3% by weight 232-22 LUISKOL VA64 (Vinylpyrrolidine 16.6% by weight 38.8% by weight Ketone Vinyl ester copolymer) Deionized water (diluent) 1 6 · 6 wt% ... GLASCOL DP6- (positive polymer) 6.7% 4.9% by weight 7 13 2 LUMITEN IRA (surfactant) 0.9% by weight 1.0 % By weight After the ink absorbing layer is dried, printing is performed using a GS ink set C ΜΜΜ A 2 4 inkjet printer as in Example 1. The print image is dried, and the first print image sample is laminated on a 3 cm thick foam plate, and the second print image sample is laminated using a laminating machine at a setting of 1 D 0 ° At a pressure of C, 8 G psi, at a feed rate of 2 feet per minute, it was laminated onto an expanded 3 cm thick PVC board. It was found that on the peel test, this laminate had good adhesion to both the expanded PVC board and the expanded board. -2 2-This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) (Please read the precautions on the back before filling this page) ^^ 1 * n -i-Bi ni · — · ϋ Yikou, I ϋ Β-ϋ —ϋ 1 ϋ · · 1_— tm / I · Printed by the Employees 'Cooperatives of the Intellectual Property Bureau of the Ministry of Economy Printed by the Employees' Cooperatives of the Intellectual Property Bureau of the Ministry of Economy 524758 A7 _B7_ 2
奮施例3B 成分 説明 重量 乾重 WICTBOND (聚丙烯酸酯） 43.48重量％ 45.66重量％ 232-22 LUISKOL VA64 (乙烯基吡咯啶 18.60重量％ 48.83重量％ 酮乙烯基酯共聚物） KLUCEL E (改質的纖維素〉1 . 8 2重量％ 4 · 7 7重量％ 去離子水 （稀釋劑） 34·98重量％ LUMITEN IRA (界面活性劑） 0 · 5 6重量％ 0 · 7 4重量°/〇 除了實施例3Α之油墨吸收劑（陽性聚合物之摻混物）僳 進一步與相當量之纖維素醚摻混外，實施例3Β偽相當類 於實施例3 Α。依照實施例3 Β，較佳的成像層塗層之乾重 傺界於2 8和3 Q克每平方公尺之間，較宜是在如前述之 DEEP CRYSTAL或CRYSTAL MATT載體膜上。此個別的産生 了光澤和霧面産物。簡易的光澤效果，可由塗覆約5 0微 米厚之聚酯膜而得到。在此具體例中，聚胺基甲酸酯之 乾重百分比傺可以在4 Q〜5 0 %之範圍内，所摻混的陽性聚 合物偽可以在45〜50%之範圍内，而纖維素醚係可以在 3〜1 0 %之範圍内。有效的抖重範圍係可以界於約在2 5〜 3 5，較宜在2 8〜3 0克每平方公尺之間。 奮施例4 利用經電翬放電處理之聚酯膜來作為載體膜，並施加 3 5克乾重每平方公尺之油墨吸收層材料於其上。該成像 紀錄層材料之配方如下所示： -23- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -----------裝—^—訂--------- (請先閱讀背面之注意事項再填寫本頁) 524758 經濟部智慧財產局員工消費合作社印製 A7 B7 2 2 五、發明說明（） 成分 說明 重量乾重 CROD AL AM (乙烯基酯共 59.6重量％ 5 7.2重量％ -29-188 聚物） L U I S K 0 L V A 6 4 (乙烯基吡咯啶 15.8重量％ 36·1重量％ 酮乙烯基酯共聚物） 去離子水 （稀釋劑） 15 _ 8重量％ ... GLASCOL DP6-(陽性聚合物） 7. 9重量％ 5.7重量％ 7 13 2 LUMITEN AFK (界面活性劑） 〇·9重量％ 1·卩重量％ 該油墨吸收層材料偽在低於5 8 °C之溫度下乾燥。然後 ，利用如先前所描述之方法，將可列印積層予以列印並 積層到3厘米厚之發泡板和3厘米厚之經擴展的PVC板 上。剝離測試顯示：此積層到經擴展的P V C板和發泡板 兩者的黏著性均非常高。 實施例1-4支持了較宜存在至少一種之具有熱塑性黏 著性質（例如，L U I S K 0 L V A 6 4乙烯基吡咯啶酬乙烯基酯 共聚物，PVP/VA S-630及 Collacol VL， Klucel E及聚 枵唑）之吸收劑材料。 奮_例5 如在以上之實施例中，可列印積層傺經由將成像紀錄 層形成於經電翬放電處理之聚酯膜上而製得的。該成像 紀錄層之乾重為3 5克每平方公尺，並且傺於低於5 8 °C之 溫度下乾燥。成像紀錄層材料之配方偽如下所示： -2 4 一 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁> • 裝-----^—訂---------線· 五 經濟部智慧財產局員工消費合作社印製 524758 A7 B7 2 3 發明說明（） 成分 説明 重量 乾重 ACRONAL 290D (乙烯基酯共 30.3重量％ 76.9重量％ 聚物） LUISKOL K90 (乙烯基吡咯啶 4 · 2重量％ 2 1 · 3糞量％ 酮乙烯基酯共聚物） 去離子水 （稀釋劑） 6 4 · 8重量％ L U Μ I T E N IRA (界面活性劑） 0.7重量％ 1.8重量％ 如在先前之實施例一般，將可列印積層列印成具有成 像者，並乾燥之，而且第一試樣積層到3厘米厚之發泡 板上，以及將第二試樣積層到3厘米厚之經擴展的PVC 板上。剝離測試顯示：此積層到經擴展的PVC板和發泡 板兩者的黏著性均非常高。 奮施例6 將用以形成油墨吸收層之成分混合物，澱積在經電翬 放電處理之聚酯膜上。該油墨及收層之乾重為3 5克每平 方公尺。在施加該材料之後，該油墨吸收層傺在低於58°C 之溫度下乾燥。油墨吸收混合物之配方傜如下所示： 成 分 説 明 重量 乾重 WI CT B0 N D 7 5 5 (聚 胺 基 甲 酸 3 1 . 9重 量 % 5 7 • 9重 量 % 酯 ) MO WI 0 L 8 -88 (聚 乙 烯 基 醇） 1 3 · 4重 量 % 4 0 • 6重 量 % 去離 子 水 (稀 釋 劑 ) 5 3 . 8重 量 % · · LUMI T E N AFK (界 面 活 性 劑） 0 · 9重 量 % 1 • 5重 量 % -25- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） -----------裝-----^----訂---------線 (請先閱讀背面之注意事項再填寫本頁) 524758 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（ 2 4 如在先前之賁施例一般，將可列印積層以噴墨印表機 列印。積層之第一試樣傺阽到3厘米厚之發泡板上，而 第二試樣傺阽到3厘米厚之經擴展的P V C板上。剝離測 試證明：此積層到經擴展的P V C板和發泡板兩者的黏著 性均非常高。 其他具有依照本發明黏滯彈性材料層之可列印積層之 試樣，傜如實施例7、8及9所示。 窨旆例7 製備包括載體膜、黏滯彈性聚合物層及成像紀錄層之 可列印積層，詳如下逑：具有厚度為2 3微米之聚酯膜， 以丙烯酸条共聚物塗覆之，而形成黏滯彈性材料層。該 丙烯酸条聚合物，傺可從英國之國家澱粉及化學股份有 限公司市售而得的，其標記為1 8 13 - 1 8 4 6。該黏滯彈性材 料之施用量為30克乾重每平方公尺。 該成像紀錄層傺由如下所示之組成物所形成的： 說明 (改質的纖維素） (乙烯基樹脂） (稀釋劑） (界面活性劑） (界面活性劑） 成分 K L U C E L E WBV 110 去離子水 LUMITEN AFK P LURO N I C P E 6 1 0 0 氨，比重0 · 8 8 (中和劑） 重量 乾重 7. 6重量％ 38. 9重量％ 22. 8重量％ 57.1重量％ 6 8 . 1 重量 ％ ... 0 . 7重量％ 0 . 4重量％ 0 . 4重量％ 2 . 1重量％ 1 . 9重量％ 首先，分離性襯裡（如可從里克山分離劑公司，阿培 -26- 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁> 裝 訂---------· 524758 經濟部智慧財產局員工消費合作社印製 Α7 Β7 心 2 5 五、發明說明（） 得諾，荷蘭所購得之P 〇 L Y - S L I K 1 1 0 - 8 0 )，偽以2 4 - 2 8克 每平方公尺之塗層乾重而直接澱積於該成像紀錄層上。 然後，將該油墨紀錄層積層到可延展的聚合物層上，並 且移除分離性襯裡。之後，利用G S油墨組C H R Ο Μ A 2 4噴 墨印表機列印油墨吸收層。將成像予以乾燥之後，並且 利用積層輥壓機，在設定之l〇〇°C、8Qpsi之壓力下，以 2呎每分鐘之飼入速率，將可列印積層接著到發泡板之 目標基材上。經發現：在油墨吸收層之表面和發泡板之 .間得到可接受之黏著性位準。 奮旃例8 在此實施例中，5 0微米厚之聚酯膜俗經作為可延展的 聚合物之聚胺基甲酸酯（W I C T B 0 Ο 2 3 2 - 2 2 )之分散液所 塗覆，其量等於2 G克乾重每平方公尺。 該成像紀錄層偽由如下所示之配方而製備的： 成分 說明 重量 乾重 LUVISK0L (乙烯基吡咯啶 15.0重量％ 97·4重量％ 酮） 去離子水 （稀釋劑） 8 4 · 2重量％ ... LUMITEN IRA (界面活性劑） 0.8重量％ 2·6重量％ 該成像紀錄層偽形成於塗層乾重為1 4 - 1 8克每平方公 尺之分離性襯裡上，然後，轉移到預先形成於載體膜上 之黏滯彈性材料層上。如以上實施例1 7所描述者一般， 將成像列印於紀錄層之外表面上，然後以先前所描述之 方法，將試樣積層到發泡板上。在剝離試驗上，經發現 -21 - 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） (請先閱讀背面之注意事項再填寫本頁) 裝----l· — 訂---------線0. 524758 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（ 2 6 :在成像之表面和板之間得到可 得注意的是，當相同的油墨紀錄 量的黏滯彈性底劑之聚酯膜上時 得到可忽略的黏著性位準。其説 已知的其他材料相比較，本發明 層化具有較大的阻抗。 窨施例9 在此實施例中，該載體膜偽經 施例 7 之 N a t i ο n a 1 1 8 0 - 1 8 4 6 )以 尺範圍之量所塗覆，並乾燥。 該成像紀錄層傺利用酚氧樹脂 製備的： 成分 説明 P K H W - 3 5 酚氧樹脂 m 鹼及中和劑 CROD ATERI C 兩性界面活性 C YN A 劑 NATIONAL P V A (水溶液） 接受之黏著性位準。值 之組成物塗覆到具有少 ，在膜與成像塗層間傺 明：在此項技藝中，與 之材料與結構係對去積 黏滯彈性聚合物（如實 2 8 - 3 2克乾重每平方公 ，以如下所示之配方而 重量 乾重 6 9 . 6重量％ 7 7 . G重量％ 0 . 8 重量 ％ ... 1.7重量％ 2. 5重量％ 13. 9重量％ 9. 7重量％ 072-0202 GLASCOL DP6- 陽性聚合物 1 1 . 6重量％ 1 0 · 8重量％ 7 13 2 去離子水 （稀釋劑） 該成像紀錄層像澱積於分離性 轉移到形成於載體膜上之黏滯彈 2 . 4 重量 ％ ... 襯裡上。將成像紀錄層 性材料層。將成像列印 請 先 閱 讀 背 -28 之 注 意 事 項Example 3B Ingredient Description Weight Dry Weight WICTBOND (Polyacrylate) 43.48% by weight 45.66% by weight 232-22 LUISKOL VA64 (Vinyl pyrrolidine 18.60% by weight 48.83% by weight Ketone Vinyl Ester Copolymer) KLUCEL E (Modified Cellulose> 1.8 2% by weight 4 · 77% by weight Deionized water (diluent) 34 · 98% by weight LUMITEN IRA (surfactant) 0 · 56% by weight 0 · 74% by weight The ink absorbent (blend of the positive polymer) of Example 3A was further blended with an equivalent amount of cellulose ether, and Example 3B was pseudo-equivalent to Example 3A. According to Example 3B, the better imaging The dry weight limit of the layer coating is between 28 and 3 Q grams per square meter, preferably on the DEEP CRYSTAL or CRYSTAL MATT carrier film as described above. This individual produces gloss and matte products. Simple The gloss effect can be obtained by coating a polyester film with a thickness of about 50 microns. In this specific example, the dry weight percentage of polyurethane can be in the range of 4 Q to 50%. Mixed positive polymer pseudo can be in the range of 45 ~ 50%, while fiber The ether ether can be in the range of 3 to 10%. The effective shaking weight range can be in the range of about 25 to 35, more preferably between 2 8 to 30 grams per square meter. 4 Use a polyester film treated with electric discharge as a carrier film, and apply 35 grams of dry weight per square meter of ink absorbing layer material on it. The formula of the imaging recording layer material is as follows: -23- The size of this paper is applicable to China National Standard (CNS) A4 (210 X 297 mm) ----------- Packing-^-Order --------- (Please read the Note: Please fill in this page again) 524758 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 2 2 V. Description of the invention () Composition description Weight dry weight CROD AL AM (59.6 wt% of vinyl ester 5 7.2 wt% -29 -188 polymer) LUISK 0 LVA 6 4 (vinylpyrrolidine 15.8% by weight 36 · 1% by weight ketovinyl ester copolymer) deionized water (diluent) 15 -8% by weight ... GLASCOL DP6- (positive Polymer) 7.9% by weight 5.7% by weight 7 13 2 LUMITEN AFK (surfactant) 0.9% by weight 1 · 卩% by weight The ink absorbing layer The material is dried at a temperature lower than 5 8 ° C. Then, using the method described previously, the printable laminate is printed and laminated to a 3 cm thick foamed board and a 3 cm thick expanded sheet. PVC board. Peel tests show that the adhesion of this laminate to both the expanded PVC board and the expanded board is very high. Examples 1-4 support the presence of at least one having thermoplastic adhesive properties (eg, LUISK 0 LVA 6 4 vinyl pyrrolidin vinyl ester copolymer, PVP / VA S-630 and Collacol VL, Klucel E and poly Oxazole) absorbent material. Example 5 As in the above embodiment, a printable laminated sheet was prepared by forming an image-recording layer on a polyester film subjected to an electric discharge treatment. The imaging record layer had a dry weight of 35 grams per square meter and was dried at temperatures below 58 ° C. The formula of the material of the imaging record layer is as follows: -2 4 A paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page > ----- ^ — Order --------- Line · Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 524758 A7 B7 2 3 Description of the invention () Composition description Weight dry weight ACRONAL 290D (vinyl ester Total 30.3% by weight 76.9% by weight Polymer) LUISKOL K90 (vinylpyrrolidine 4 · 2% by weight 2 1 · 3% by weight ketone vinyl ester copolymer) Deionized water (diluent) 6 4 · 8% by weight LU Μ ITEN IRA (surfactant) 0.7% by weight 1.8% by weight As in the previous examples, printable printable layers were printed with an imager and dried, and the first sample was laminated to a 3 cm thick hair Foam board, and the second sample was laminated to a 3 cm thick expanded PVC board. Peel test showed that the adhesion of this laminate to both expanded PVC board and foam board was very high. Fen Shi Example 6 A component mixture for forming an ink absorbing layer is deposited On an electro-discharge-treated polyester film. The dry weight of the ink and layer is 35 grams per square meter. After applying the material, the ink-absorbing layer is dried at a temperature below 58 ° C. The formula of ink absorbing mixture is as follows: Ingredient Description Weight Dry Weight WI CT B0 ND 7 5 5 (Polyurethane 3 1. 9% by weight 5 7 • 9% by weight ester) MO WI 0 L 8 -88 ( Polyvinyl alcohol) 1 3 · 4% by weight 4 0 • 6% by weight deionized water (diluent) 5 3. 8% by weight · · LUMI TEN AFK (surfactant) 0 · 9% by weight 1 • 5% by weight -25- This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) ----------- installed ----- ^ ---- order ----- ---- Line (Please read the precautions on the back before filling this page) 524758 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5. Description of the invention (2 4 As listed in the previous example, it will be listed The printed layer was printed by an inkjet printer. The first sample of the layer was rolled onto a 3 cm-thick foam board, and the second sample was . To 3 cm thickness of the expanded board P V C peel test was demonstrated: This laminated to the expanded adhesion both P V C and the foam board panels are very high. Other printable laminated samples having a layer of viscoelastic material according to the present invention are shown in Examples 7, 8 and 9.窨 旆 Example 7 A printable laminate including a carrier film, a viscoelastic polymer layer, and an imaging recording layer was prepared as follows: A polyester film having a thickness of 23 microns was coated with an acrylic strip copolymer, and Forms a layer of viscoelastic material. The acrylic strip polymer is commercially available from the National Starch and Chemical Co., Ltd. in the United Kingdom, and is labeled 1 8 13-1 8 4 6. The viscoelastic material was applied at a dry weight of 30 grams per square meter. The imaging recording layer 傺 is formed of the following composition: Description (modified cellulose) (vinyl resin) (diluent) (surfactant) (surfactant) Ingredients KLUCELE WBV 110 deionized water LUMITEN AFK P LURO NICPE 6 1 0 0 Ammonia, specific gravity 0 · 8 8 (neutralizing agent) dry weight 7.6 wt% 38.9 wt% 28.8 wt% 57.1 wt% 6 8.1 wt% .. 0.7% by weight 0.4% by weight 0.4% by weight 2.1% by weight 1.9% by weight First of all, release liners (such as those available from Rick Hill Separator Company, Ape-26- Applicable to China National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling out this page> Binding --------- · 524758 Employees ’Cooperatives, Intellectual Property Bureau, Ministry of Economic Affairs Printed Α7 Β7 heart 2 5 V. Description of the invention () PNOLY-SLIK 1 1 0-8 0) obtained by De Novo, Netherlands, falsely coated with 2 4-28 grams per square meter. And then directly deposited on the imaging record layer. Then, the ink record layer is laminated on the extensible polymer layer, And the release liner was removed. After that, the ink absorbing layer was printed using a GS ink set CHR 0 Μ A 2 4 inkjet printer. After the image was dried, it was laminated using a laminating press at a setting of 100 ° C, 8Qpsi pressure, at a feed rate of 2 feet per minute, the printable laminate is then attached to the target substrate of the foamed board. It was found that: Acceptable level of adhesion. Example 8 In this example, a 50 micron thick polyester film is conventionally used as a stretchable polymer of polyurethane (WICTB 0 Ο 2 3 2-2 2) The dispersion is coated in an amount equal to 2 G grams of dry weight per square meter. The imaging record layer is prepared by the following formula: Ingredient description weight dry weight LUVISK0L (vinyl pyrrolidine 15.0 weight % 97 · 4% by weight ketone) Deionized water (diluent) 8 4 · 2% by weight ... LUMITEN IRA (surfactant) 0.8% by weight 2.6% by weight The imaging recording layer is pseudo-formed on the dry weight of the coating 1 4-18 grams per square meter of separable liner, then, transfer to First formed on the viscoelastic material layer on the carrier film. As described in Example 17 above, the image is printed on the outer surface of the recording layer, and then the sample is laminated to the method described previously. Foam board. In the peel test, it was found that -21-This paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) (Please read the precautions on the back before filling this page). Loading ---- l · — Order --------- Line 0. 524758 A7 B7 Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs V. Invention Description (2 6: What can be noticed between the imaging surface and the board is that when A negligible level of adhesion was obtained on a polyester film with the same ink recording amount of a viscoelastic primer. It is said that the layering of the present invention has a larger resistance compared to other known materials. 窨 例 9 In this embodiment, the carrier film is coated with N ati na 1 1 8 0-1 8 4 6) in an amount in the range of ruler and dried. The imaging record layer is made of phenolic resin: Composition Description P K H W-3 5 Phenolic resin m Base and neutralizing agent CROD ATERI C Amphoteric interface activity C YN A agent NATIONAL P V A (aqueous solution) Accepted adhesion level. The value of the composition is small, and it is clear between the film and the imaging coating: In this technique, the material and structure are anti-deposited viscoelastic polymers (actually 2 8-3 2 g dry weight) Per square metre, dry weight is 69.6 weight% 7 7. G weight% 0.8 weight% ... 1.7 weight% 2. 5 weight% 13. 9 weight% 9. 7 % By weight 072-0202 GLASCOL DP6-positive polymer 1 1.6% by weight 1 0 · 8% by weight 7 13 2 Deionized water (diluent) The image-recording layer is deposited by separation and transferred to a carrier film The viscous bomb 2.4% by weight ... on the lining. The layered material layer will be imaged. Please read the notes on back-28 before printing.
本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） 524758 經濟部智慧財產局員工消費合作社印製 A7 _B7 心 2 7 五、發明說明（） 於 紀錄 層 之 上 妖 後 以 實 施 例 7 之 條 件 積 層 到 發 泡 板 上 〇 則得 到 在 成 像 層 和 發 泡 板 間 可 接 受 之 黏 著 性 位 準 〇 對熟 習 此 項 技 藝 者 而 言 > 很 顯 妖 /ON 的 ， 以 上 所 描 逑 的 材 料 與結 構 之 各 種 不 同 的 修 飾 例 和 修 正 例 9 在 不 脫 離 本 發 明 之精 神 與 範 圍 下 將 變 得 簡 act 早 明 瞭 〇 付 號之 説 明 10,2 0 . 可 列 印 積 層 12.. 載 體 膜 14.. 成 像 紀 錄 層 16.. 油 墨 澱 積 圖 樣 2 5.. 黏 滯 wo 5早 性 材 料 層 3 0.. 固 著 板 3 2.. 膨 化 的 聚 苯 乙 烯 層 3 4.. 紙 層 3 6.. 積 層 棍 3 8.. 箍 縮 棍 (請先閱讀背面之注意事項再填寫本頁)This paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 524758 Printed by the Consumers' Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 _B7 Heart 2 7 V. Description of the invention () After the demon on the record layer to implement The conditions of Example 7 were laminated on the foam board. The acceptable adhesion level between the imaging layer and the foam board was obtained. For those skilled in the art, it is very demon / ON, as described above. Various modified examples and modified examples of materials and structures of 9 will become simple without departing from the spirit and scope of the present invention. The description of the number 10, 2 0. Printable laminate 12. Carrier film 14. Imaging recording layer 16. Ink deposition pattern 2 5. Sticky wo 5 Premature material layer 3 0. Fixing plate 3 2. Expanded polystyrene layer 3 4. Paper 36 .. 38 .. laminate stick pinch bar (Read precautions and then fill the back side of this page)
T . ϋ. ·ϋ —HI 1 ·ϋ ΒΙΒ1 ·ϋ ·ϋ ϋ I 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐）T. Ϋ. · Ϋ —HI 1 · ϋ ΒΙΒ1 · ϋ · ϋ ϋ I This paper size applies to China National Standard (CNS) A4 (210 X 297 mm)