EP0858913A1 - Film de transfert - Google Patents

Film de transfert Download PDF

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Publication number
EP0858913A1
EP0858913A1 EP97305655A EP97305655A EP0858913A1 EP 0858913 A1 EP0858913 A1 EP 0858913A1 EP 97305655 A EP97305655 A EP 97305655A EP 97305655 A EP97305655 A EP 97305655A EP 0858913 A1 EP0858913 A1 EP 0858913A1
Authority
EP
European Patent Office
Prior art keywords
transfer film
film
heat
transfer
ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97305655A
Other languages
German (de)
English (en)
Inventor
Colin John Cook
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunt Europe Ltd
Original Assignee
Hunt Europe Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunt Europe Ltd filed Critical Hunt Europe Ltd
Priority to EP97305655A priority Critical patent/EP0858913A1/fr
Priority to DK98904294T priority patent/DK0961695T3/da
Priority to PCT/GB1998/000481 priority patent/WO1998035840A1/fr
Priority to PT98904294T priority patent/PT961695E/pt
Priority to AU62238/98A priority patent/AU6223898A/en
Priority to DE69805507T priority patent/DE69805507T2/de
Priority to AT98904294T priority patent/ATE217841T1/de
Priority to ES98904294T priority patent/ES2178156T3/es
Priority to EP98904294A priority patent/EP0961695B1/fr
Priority to US09/367,417 priority patent/US6346313B1/en
Publication of EP0858913A1 publication Critical patent/EP0858913A1/fr
Priority to HK00102889A priority patent/HK1023755A1/xx
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/0256—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0036—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers dried without curing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5227—Macromolecular coatings characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/914—Transfer or decalcomania
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/24405—Polymer or resin [e.g., natural or synthetic rubber, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable

Definitions

  • This invention relates to an ink-printable transfer film on which an image may be printed.
  • Transfer materials have been available for many years and typically consist of a polymeric or wax film which is supported on a carrier sheet. An image is printed on the film before the film is transferred from the carrier sheet to a substrate usually by applying pressure or heat to the back of the carrier sheet.
  • a method for decorating an substrate with an image which has first been printed on a transfer material.
  • a digital image from a conventional video camera is printed using an ink jet printer onto the transfer material which comprises a plastic support and a heat-sensitive adhesive coating onto which the ink is printed.
  • the printed side of the transfer material is placed in contact with the substrate and heat applied to activate the support.
  • the plastic support can be removed once the adhesion between the coating and the substrate is greater than that between the coating and the plastic support.
  • FR 2 715 607 does not disclose the composition of the coating which accepts the printing ink.
  • known heat-sealable coatings are essentially continuous films deposited from a polymer solution in organic solvent or water, or from a dispersion of polymer in water with emulsifiers.
  • the inks of jet printers are solutions of dyes in solvent which, in use, are sprayed through nozzles onto the surface to be printed.
  • volatile organic solvents are employed and quick drying of the ink is achieved by evaporation of the solvent.
  • non-volatile solvents such as water and glycol mixtures must be used to avoid premature drying of the ink and clogging of the spray nozzles. With non-volatile solvents, the ink is held by absorption into the substrate instead of evaporation.
  • non-volatile solvents work well with absorbent substrates such as paper, but tend to sit on the surface of non-porous substrates such as the known heat-sealable coatings.
  • absorbent substrates such as paper
  • non-porous substrates such as the known heat-sealable coatings.
  • filmic substrates such as overhead projection transparencies
  • these polymers are not sufficiently thermoplastic to be transferable by heat to another substrate, nor are they sufficiently waterproof to produce permanent graphics.
  • a transfer film for transferring an ink comprising at least one liquid component, the film comprising a porous matrix of particles of a heat activatable adhesive bound together by an absorber, the absorber being at least partly soluble in the said liquid component within the porous matrix, and the absorber preferably being within the pores of the matrix.
  • the porous matrix of adhesive particles is carried by a carrier film.
  • the film is described as comprising a matrix of particles of adhesive with an absorber within the matrix, it will be appreciated that in isolation the structure could also be described as comprising particles of adhesive within a matrix formed by the absorber.
  • the absorber has the double function of binding the matrix of heat activatable adhesive and at least partially absorbing the liquid component of the ink.
  • the transfer material can be used with inks that comprise a pigment or mixture of pigments and a liquid component that acts as a vehicle for the pigment.
  • vehicular components are non volatile solvents such as water and glycol.
  • the absorber should be at least partially soluble in the vehicle of the ink with which the transfer film is to be used.
  • the absorber component is at least partially dissolved by the vehicular component of the ink and on application of the ink a viscous solution of absorber and vehicular component is formed.
  • the viscous solution holds the ink pigment preventing spreading of the ink and blurring of the transferred image formed by the ink.
  • the absorber forms a viscous solution of viscosity at least 1500 cp preferably at least 1800 cp, when partially dissolved in the ink vehicle.
  • non-volatile solvent is used to describe the vehicular component of the ink but is not meant to imply that the solvent does not evaporate at all when the ink is incorporated on to the surface of the substrate.
  • non-volatile implies that the retention of the dye component of the ink on the substrate is primarily by absorption of the solvent into the substrate and subsequent deposition of the dye component on to the substrate. This is in contrast to other types of ink where the dye is deposited onto the substrate by evaporation of a volatile solvent.
  • the matrix of particles of adhesive has a porous structure into which ink can be drawn by capillary action.
  • the film thus provides an absorption surface for the vehicular components used in inks and overcomes the tendency of the ink to form droplets on the film surface. Such droplet formation will result in the ink drying on the surface of the film with consequent reduction of the surface task required to transfer the film to the chosen substrate; this problem is avoided by transfer films according to the present invention.
  • the absorber is a water soluble or hydrophilic absorber and the transfer film is used with an ink that contains water as a vehicular component.
  • a water-soluble absorber within the porous matrix of the transfer film moderates the porosity of the film, reducing the spread of ink in the film, and increases overall strength.
  • the water-soluble absorber component holds the ink by interacting with the non volatile ink components (for example water or glycol) and hence allows high definition images to be printed by preventing ink drawn into the film by capillary action from migrating noticeably beyond the point of initial contact.
  • the water soluble absorber is acrylate copolymer, cellulose ether, polyvinyl pyrollidone or a combination of two or more of these.
  • the ink printable transfer film is supported on a carrier.
  • the absorber binds the transfer film to the carrier.
  • the carrier is a resin coated paper or polymer film, for example polyethylene coated paper, or polyester or polypropylene film.
  • the choice of carrier depends on the surface finish desired.
  • the transfer film further comprises a stabiliser such as Tinuvin 213, which will prevent fading of the dye and retard degradation of polymers in the transfer film.
  • a stabiliser such as Tinuvin 213, which will prevent fading of the dye and retard degradation of polymers in the transfer film.
  • the transfer film further comprises a thickener, for example a polyacrylate such as Latekoll D.
  • a thickener for example a polyacrylate such as Latekoll D.
  • Such thickeners aid in production of the transfer film by thickening the formulation mix so it can be applied more easily to a carrier material.
  • the transfer further comprises a wetting agent.
  • the transfer material further comprises an alkaline component such as sodium hydroxide or ammonia solution that stabilises the transfer material formulation when it is being made and applied to the carrier.
  • an alkaline component such as sodium hydroxide or ammonia solution that stabilises the transfer material formulation when it is being made and applied to the carrier.
  • the transfer material further comprises a weak acid such as boric acid.
  • a weak acid such as boric acid.
  • Boric acid acidifies the finished transfer material which aids in complexation and absorption of components of printing inks, thereby preventing migration of the ink and increasing resolution of the final image.
  • Boric acid being a weak acid, will not interfere with the alkaline components of the transfer material sufficiently to prevent stabilization of the transfer formulation when it is being made and applied to a carrier.
  • the heat activatable adhesive in the ink printable transfer film has a heat activation temperature also known as the film formation temperature.
  • the heat activatable adhesive when placed in contact with a substrate and heated the heat activatable adhesive forms a layer of adhesive over substantially the whole surface of the transfer film.
  • the transfer film is thus attached to a substrate over substantially the whole surface of the transfer film.
  • the absorber is a softenable absorber to allow greater interaction between the adhesive of the transfer film and the substrate.
  • the heat-activatable adhesive is selected such that the minimum film forming temperature of the transfer sheet is in excess of about 20 degrees C above a typical ambient workshop temperature. More preferably, the heat-activatable adhesive is selected such that the minimum film forming temperature is below about 125°C. More preferably the heat-activatable adhesive is selected such that the minimum film forming temperature is below about 75°C.
  • the film of heat activatable adhesive forms over a temperature interval. Preferably the interval is within the range 75° and 125°C. The particles will not then have a tendency to coalesce when stored in the workshop, but will start to form a continuous film when the adhesive is fully activated, when heat is applied to transfer the coating from the carrier sheet to the chosen substrate.
  • Figure 1 shows a sheet of printed transfer material 10, which consists of a carrier sheet 12 and an ink-printable transfer film 14 according to the invention.
  • the transfer film 14 bears an image 18 printed using an ink jet printer (not shown).
  • the manufacture of one example of a transfer material according to the invention is as follows.
  • the following ink print transfer film 14 formulation was applied to a 50 micron polyester film carrier 12.
  • REAGENT FUNCTION COMPOSITION 1. Vinnol Dispersion CE35 Dispersed Phase/Matrix 61.45% 2.
  • Glascol LS41 Soluble Absorber 24.58% 3.
  • Boric Acid Acidulant/Neutraliser 5.53% 4.
  • 20% Aqueous Sodium Hydroxide Neutraliser and Solubiliser 5.31% 5.
  • Latekoll D Thickener 1.47% 6. Tinuvin 213 Dye Stabiliser 1.14% 7.
  • Lumiten IRA Wetting Agent 0.52%
  • the mixture is made up as a dispersion in water.
  • the heat activatable adhesive forms a matrix which contains the absorber.
  • the absorber holds the matrix together and aids in adhesion of the mixture to the carrier film.
  • Neutralisers or pH adjusters such as Ammonium hydroxide or Sodium hydroxide are used to make the mixture alkaline and stabilize the adhesive in the mixture formulation.
  • Boric acid is used to acidify the dried coating which results in improved absorption of printer ink and hence reduced ink migration and a higher resolution image. Boric acid is advantageous in that, as it is weak, it does not neutralize NH 4 OH or NaOH in the coating process in which alkaline pH is needed.
  • the ink printable transfer film 14 is deposited on the carrier sheet 12 by any coating method. Examples of such coating methods are reverse roll, Meyer bar or slot die.
  • the film is dried at a temperature that is not sufficiently high to activate the heat activatable adhesive (that is at a temperature below the minimum film forming temperature of the adhesive).
  • the resulting coating is opaque after deposition on the carrier sheet but the coating becomes transparent when the adhesive is activated by heat.
  • the surface 16 of the printed transfer material 10 is placed in contact with the substrate 20 which is to receive the transfer film 14. Heat and pressure are applied through the carrier sheet 12 using for example a smoothing iron to activate the adhesive and encourage the formation of a bond between the transfer film 14 and the substrate 20. The transfer film 14 is then allowed to cool and the carrier sheet 12 is peeled away to leave a reversed image on the substrate 20.
  • the heat and pressure activate the adhesive which clarifies it and produces a layer of resin over the image which seals the image.
  • the carrier sheet is used as a protective laminate to the transferred image.
  • the transfer film and the carrier are not separable when the finished image has been produced.
  • the transfer material is sealed onto the substrate 120 by application of heat and pressure to the carrier sheet.
  • the carrier sheet is a clear film such as polyester or polypropylene film, and provides a further protective coating to the image in the substrate.
  • transfer films of the present invention provide a transfer film that can be printed with a high definition image. Additionally transfer films of the present invention have good adhesion to a substrate when applied.

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Laminated Bodies (AREA)
EP97305655A 1997-02-17 1997-07-28 Film de transfert Withdrawn EP0858913A1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
EP97305655A EP0858913A1 (fr) 1997-02-17 1997-07-28 Film de transfert
DE69805507T DE69805507T2 (de) 1997-02-17 1998-02-16 Übertragungsfolie
PCT/GB1998/000481 WO1998035840A1 (fr) 1997-02-17 1998-02-16 Film de transfert
PT98904294T PT961695E (pt) 1997-02-17 1998-02-16 Pelicula de decalque
AU62238/98A AU6223898A (en) 1997-02-17 1998-02-16 Transfer film
DK98904294T DK0961695T3 (da) 1997-02-17 1998-02-16 Overføringsfilm
AT98904294T ATE217841T1 (de) 1997-02-17 1998-02-16 Übertragungsfolie
ES98904294T ES2178156T3 (es) 1997-02-17 1998-02-16 Pelicula de transferencia.
EP98904294A EP0961695B1 (fr) 1997-02-17 1998-02-16 Film de transfert
US09/367,417 US6346313B1 (en) 1997-02-17 1998-02-16 Transfer film
HK00102889A HK1023755A1 (en) 1997-02-17 2000-05-16 Transfer film

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP97301012 1997-02-17
EP97301012 1997-02-17
EP97305655A EP0858913A1 (fr) 1997-02-17 1997-07-28 Film de transfert

Publications (1)

Publication Number Publication Date
EP0858913A1 true EP0858913A1 (fr) 1998-08-19

Family

ID=56289785

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97305655A Withdrawn EP0858913A1 (fr) 1997-02-17 1997-07-28 Film de transfert

Country Status (3)

Country Link
EP (1) EP0858913A1 (fr)
ES (1) ES2178156T3 (fr)
PT (1) PT961695E (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000041891A1 (fr) * 1999-01-15 2000-07-20 Hunt Graphics Europe Ltd. Stratifie pouvant etre imprime
EP1484194A1 (fr) * 2002-03-12 2004-12-08 Nobuo Sugino Procede de transfert et feuille de transfert
DE102007031121B3 (de) * 2007-06-29 2008-09-25 Schäfer, Konstanze, Dr. Verfahren zur Fixierung von Digitalbildern in Kunststoffen und fixiertes Digitalbild
ES2321265A1 (es) * 2007-09-18 2009-06-03 Jose Castañ Centelles Procedimiento para la obtencion de lapidas impresas y lapida asi obtenida.
WO2021138360A1 (fr) * 2019-12-29 2021-07-08 Avery Dennison Retail Information Services, Llc Stratifié imprimé thermosoudable et procédés associés
CN114701275A (zh) * 2022-03-16 2022-07-05 珠海天威新材料股份有限公司 可数码打印水披覆膜、墨水、水转印方法及水转印产品

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2101932A (en) * 1981-07-13 1983-01-26 John Laurence Bowen Heat transfer
GB2153833A (en) * 1984-02-03 1985-08-29 Jin An Ind Co Transfer adhesive composition and process for manufacturing transfer sheets using such composition
JPS62271777A (ja) * 1986-05-21 1987-11-26 Canon Inc 転写シ−ト原紙
EP0414135A2 (fr) * 1989-08-21 1991-02-27 Hänsel Textil GmbH & Co. Procédé et appareil pour l'impression d'adhésif à matrice de points
US5271990A (en) * 1991-10-23 1993-12-21 Kimberly-Clark Corporation Image-receptive heat transfer paper
EP0588716A2 (fr) * 1992-09-17 1994-03-23 Minnesota Mining And Manufacturing Company Feuille réceptrice pour l'enregistrement par transfert thermique et procédé d'utilisation
EP0657309A1 (fr) * 1993-12-02 1995-06-14 Cookson Matthey Print Limited Procédé pour la production de feuilles de transfert
US5501902A (en) * 1994-06-28 1996-03-26 Kimberly Clark Corporation Printable material

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2101932A (en) * 1981-07-13 1983-01-26 John Laurence Bowen Heat transfer
GB2153833A (en) * 1984-02-03 1985-08-29 Jin An Ind Co Transfer adhesive composition and process for manufacturing transfer sheets using such composition
JPS62271777A (ja) * 1986-05-21 1987-11-26 Canon Inc 転写シ−ト原紙
EP0414135A2 (fr) * 1989-08-21 1991-02-27 Hänsel Textil GmbH & Co. Procédé et appareil pour l'impression d'adhésif à matrice de points
US5271990A (en) * 1991-10-23 1993-12-21 Kimberly-Clark Corporation Image-receptive heat transfer paper
EP0588716A2 (fr) * 1992-09-17 1994-03-23 Minnesota Mining And Manufacturing Company Feuille réceptrice pour l'enregistrement par transfert thermique et procédé d'utilisation
EP0657309A1 (fr) * 1993-12-02 1995-06-14 Cookson Matthey Print Limited Procédé pour la production de feuilles de transfert
US5501902A (en) * 1994-06-28 1996-03-26 Kimberly Clark Corporation Printable material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 012, no. 152 (M - 695) 11 May 1988 (1988-05-11) *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000041891A1 (fr) * 1999-01-15 2000-07-20 Hunt Graphics Europe Ltd. Stratifie pouvant etre imprime
EP1484194A1 (fr) * 2002-03-12 2004-12-08 Nobuo Sugino Procede de transfert et feuille de transfert
EP1484194A4 (fr) * 2002-03-12 2008-09-03 Nobuo Sugino Procede de transfert et feuille de transfert
DE102007031121B3 (de) * 2007-06-29 2008-09-25 Schäfer, Konstanze, Dr. Verfahren zur Fixierung von Digitalbildern in Kunststoffen und fixiertes Digitalbild
WO2009003727A2 (fr) 2007-06-29 2009-01-08 Schaefer Konstanze Procédé de fixation d'images dans des matières synthétiques, couche adhésive et images ainsi fixées
DE102008030991A1 (de) 2007-06-29 2009-01-15 Schäfer, Konstanze, Dr. Verfahren zur Fixierung von Bildern in Kunststoffen, Haftschicht und fixiertes Bild
US8414978B2 (en) 2007-06-29 2013-04-09 Coyando Gmbh Method for fixing images in plastics, adhesive layer, and fixed image
ES2321265A1 (es) * 2007-09-18 2009-06-03 Jose Castañ Centelles Procedimiento para la obtencion de lapidas impresas y lapida asi obtenida.
WO2021138360A1 (fr) * 2019-12-29 2021-07-08 Avery Dennison Retail Information Services, Llc Stratifié imprimé thermosoudable et procédés associés
CN114701275A (zh) * 2022-03-16 2022-07-05 珠海天威新材料股份有限公司 可数码打印水披覆膜、墨水、水转印方法及水转印产品
CN114701275B (zh) * 2022-03-16 2023-09-05 珠海天威新材料股份有限公司 可数码打印水披覆膜、墨水、水转印方法及水转印产品

Also Published As

Publication number Publication date
PT961695E (pt) 2002-10-31
ES2178156T3 (es) 2002-12-16

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