WO2000037337A1 - Fiber filled chain link for a modular conveyer chain - Google Patents

Fiber filled chain link for a modular conveyer chain Download PDF

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Publication number
WO2000037337A1
WO2000037337A1 PCT/US1999/029635 US9929635W WO0037337A1 WO 2000037337 A1 WO2000037337 A1 WO 2000037337A1 US 9929635 W US9929635 W US 9929635W WO 0037337 A1 WO0037337 A1 WO 0037337A1
Authority
WO
WIPO (PCT)
Prior art keywords
chain
link
modular
chain link
molded
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1999/029635
Other languages
English (en)
French (fr)
Inventor
James C. Stebnicki
Peter J. Ensch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zurn LLC
Original Assignee
Rexnord LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22810302&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2000037337(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Rexnord LLC filed Critical Rexnord LLC
Priority to AT99967311T priority Critical patent/ATE226912T1/de
Priority to BR9916455-8A priority patent/BR9916455A/pt
Priority to EP99967311A priority patent/EP1140672B2/en
Priority to DE69903752T priority patent/DE69903752T3/de
Priority to DK99967311T priority patent/DK1140672T4/da
Priority to CA002355733A priority patent/CA2355733C/en
Priority to JP2000589421A priority patent/JP4628546B2/ja
Publication of WO2000037337A1 publication Critical patent/WO2000037337A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65GTRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G17/00Conveyors having an endless traction element, e.g. a chain, transmitting movement to a continuous or substantially-continuous load-carrying surface or to a series of individual load-carriers; Endless-chain conveyors in which the chains form the load-carrying surface
    • B65G17/06Conveyors having an endless traction element, e.g. a chain, transmitting movement to a continuous or substantially-continuous load-carrying surface or to a series of individual load-carriers; Endless-chain conveyors in which the chains form the load-carrying surface having a load-carrying surface formed by a series of interconnected, e.g. longitudinal, links, plates, or platforms
    • B65G17/08Conveyors having an endless traction element, e.g. a chain, transmitting movement to a continuous or substantially-continuous load-carrying surface or to a series of individual load-carriers; Endless-chain conveyors in which the chains form the load-carrying surface having a load-carrying surface formed by a series of interconnected, e.g. longitudinal, links, plates, or platforms the surface being formed by the traction element
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65GTRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G17/00Conveyors having an endless traction element, e.g. a chain, transmitting movement to a continuous or substantially-continuous load-carrying surface or to a series of individual load-carriers; Endless-chain conveyors in which the chains form the load-carrying surface
    • B65G17/06Conveyors having an endless traction element, e.g. a chain, transmitting movement to a continuous or substantially-continuous load-carrying surface or to a series of individual load-carriers; Endless-chain conveyors in which the chains form the load-carrying surface having a load-carrying surface formed by a series of interconnected, e.g. longitudinal, links, plates, or platforms
    • B65G17/08Conveyors having an endless traction element, e.g. a chain, transmitting movement to a continuous or substantially-continuous load-carrying surface or to a series of individual load-carriers; Endless-chain conveyors in which the chains form the load-carrying surface having a load-carrying surface formed by a series of interconnected, e.g. longitudinal, links, plates, or platforms the surface being formed by the traction element
    • B65G17/086Conveyors having an endless traction element, e.g. a chain, transmitting movement to a continuous or substantially-continuous load-carrying surface or to a series of individual load-carriers; Endless-chain conveyors in which the chains form the load-carrying surface having a load-carrying surface formed by a series of interconnected, e.g. longitudinal, links, plates, or platforms the surface being formed by the traction element specially adapted to follow a curved path
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65GTRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G2201/00Indexing codes relating to handling devices, e.g. conveyors, characterised by the type of product or load being conveyed or handled
    • B65G2201/02Articles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S198/00Conveyors: power-driven
    • Y10S198/957Conveyor material

Definitions

  • This invention relates to a modular conveyer chain, and more particularly to an improved chain link for use in construction of a modular conveyer chain.
  • Manufacturing and production facilities utilize modular conveyer chains to transport products or articles of production from one location to another.
  • Conventional modular conveyor chains are typically comprised of multiple thermoplastic chain links or modules.
  • the links making up the modular conveyer chain typically have a plurality of spaced link ends which intermesh with complementary spaced link ends projecting from a link or links in an adjacent row.
  • the individual chain links are usually similar in width and may be arranged in a bricked configuration.
  • the intermeshing link ends are joined or hinged together by a connecting pin that permits the adjacent chain links to pivot with respect to each other.
  • the chain links are typically joined together to form an endless conveyor chain that is usually driven by a drive sprocket.
  • the modular conveyor chains are subjected to tensile forces that tend to separate the individual chain links when the chain is placed under a load.
  • Chain links are typically made of thermoplastic (e.g. acetal, polyester, nylon and polypropylene).
  • the choice of the polymer used for the chain link usually depends on the physical properties which are desired (i.e. high tensile strength, high fatigue strength, low friction, chemical resistance and/or suitability for use under extreme cyclic temperatures) in the chain link.
  • the tensile strength and fatigue strength of the chain link are especially important because a chain link having these increased mechanical properties increases the overall tensile strength of the modular conveyor chain and reduces chain stretch due to loading.
  • Modular conveyer chains are often used to carry goods from one location to another location where the temperature of the environment at the two locations is significantly different.
  • the individual chain links expand as the temperature of the chain increases, and contract as the temperature of the chain decreases. As the individual chain links expand or contract, the overall length of the conveyer chain varies significantly as a result of a high coefficient of thermal expansion that is commonly associated with most thermoplastics .
  • a typical application where a modular conveyor belt is subject to extreme cyclic temperatures is in a conveyor chain used to transport cans or bottles through pasteurizers in breweries.
  • the high temperatures in a pasteurizer combined with the slow movement of the cans or bottles through the pasteurizer when the chain is under a tensile load may cause the chain to stretch such that the bottom canteary section of an endless conveyer chain sags.
  • This chain stretching may also effect the performance of the interaction between the drive sprocket and chain links.
  • the sagging can become so great that the bottom canteary section of the top conveyor of an endless conveyer chain interferes with bottles located on a lower conveyor chain.
  • thermoplastic chain links In combination with the thermoplastic chain links.
  • the combination of thermoplastic links and metal links causes the loads on the modular conveyer to be carried primarily by the metal links.
  • One of the problems associated with combining links made from two different materials to form a modular conveyor is that there are significant bending stresses generated within the thermoplastic chain links due to the differences in the modulus of elasticity, coefficient of friction and coefficient of thermal expansion between the thermoplastic chain links and the metal chain links.
  • Plastics manufacturers have increased the tensile strength of thermoplastics by adding filler to the polymer as the raw polymer is being manufactured.
  • the filler is typically in the form of long fibers.
  • Manufacturers of long fiber reinforced thermoplastics such as Ticona and DuPont, provide technical literature to their customers which indicates that increasing the amount of filler within the raw polymer increases the tensile strength of the molded polymer.
  • the technical literature also provides results for tensile tests performed on different thermoplastics where the percentage of filler within the polymer varies. The tests were performed in accordance with ASTM standards and indicate -that the tensile strength of the thermoplastics increases as the weight percent of filler within the raw polymer increases.
  • the technical literature shows test results for polymers that include up to 60 weight percent filler within the polymer.
  • the present invention is an improved chain link for use in constructing a modular conveyor chain.
  • the chain link includes a plurality of spaced link ends that extend from the body of the chain link.
  • the link ends are adapted to intermesh with complementary spaced link ends projecting from a link or links in an adjacent row.
  • the link ends include openings which are axially aligned and adapted to receive a connecting pin that runs through the openings to pivotally connect the link with an adjacent chain link or links.
  • the chain link is molded from a thermoplastic material that includes a filler, preferably glass fiber, which improves the mechanical properties of the chain link.
  • the amount of filler within the molded thermoplastic material should maximize the fatigue strength and tensile strength of the molded chain link in environments where the temperature can vary significantly.
  • the chain link comprises less than about 30 weight percent of filler based on the weight of the molded chain link; and preferably between the range of about 5 to 25 weight percent; and more preferably between the range of about 10 to 20 weight percent.
  • the filler is preferably in the form of long strands which have a length between 0.125 inches and 0.5 inches.
  • the modular chain link is preferably injection molded from a strong base polymer in order to provide ample strength and corrosion resistance to the chain link.
  • the links are preferably molded in a die having a relatively high temperature because during molding a layer consisting of unfilled polymer forms near the surface of the link and increasing the temperature of the die causes the layer to be thicker.
  • Positioning the fibers as far as possible from the surface of the link is crucial because the fibers can be very abrasive and during operation of the modular conveyor chain there is commonly point contact between the connecting pins and the internal edges of the link ends. The point contact results in a significant amount of relative motion between the connecting pins and link ends. This type of motion can cause extreme wear, especially when the abrasive fibers are near the outer surface of the links.
  • the orientation of the fibers within the molded chain link can be manipulated by locating the gates which supply liquid polymer into the molding die in a particular configuration.
  • the gates on the molding die are preferably located such that the fibers are oriented within the chain link in substantially the same direction as the direction of the travel of the modular conveyor chain. Orienting the fibers within the modular chain link in the direction of chain travel significantly increases the tensile strength and the fatigue strength of a modular conveyor chain that is assembled from the individual chain links.
  • An object of this invention is to provide a chain link for use in constructing a modular conveyor chain that has a low friction surface, high tensile strength, high fatigue strength, minimal coefficient of thermal expansion and a more stable modulus of elasticity as the operating temperature increases. Increasing the strength of thermoplastic modular conveyor chains is critical because many conveyor applications require a high strength conveyor chain.
  • Another object of this invention is to provide a chain link for use in constructing a modular conveyor chain that has increased fatigue strength and tensile strength over a range of operating temperatures. Increasing the useful range of operating temperatures where a modular conveyor chain can function effectively allows the chain to be used in a greater number of applications.
  • a further object of this invention is to provide a chain link for use in constructing a modular conveyor chain that is more effective in the types of applications where modular conveyor chains are typically used.
  • Modular conveyor chains are typically used in pasteurizers, bottle and can warmers, industrial microwave ovens, shrink wrap tunnels and freezers .
  • Yet another object of the invention is to provide a modular conveyor chain that will resist stretching due to mechanical loading in a variety of environmental conditions including high temperatures and corrosive environments .
  • Fig. 1 is a partially exploded perspective view of a portion of a modular conveyor chain.
  • Fig. 2 is a bottom plan view of a portion of the modular conveyor chain of Fig. 1.
  • FIG. 1 A portion of a typical modular conveyor chain is shown in FIG. 1.
  • a modular chain link 13 embodying the present invention is shown intermeshed with a substantially identical adjacent chain link 15.
  • a connector pin 17 pivotally connects the chain link 13 with the adjacent chain link 15.
  • the chain link 13 typically comprises a link body 16 that includes a series of link ends 25 extending from opposite sides of the link body 16.
  • the link ends 25 are transversely spaced from each other to define therebetween a series of spaces 27.
  • the series of link ends 25 include openings 33 that are axially aligned with respect to each other.
  • the openings 33 in the link ends 25 can be cylindrical or elongated in the direction of travel of the modular conveyor belt.
  • the adjacent chain link 15 is preferably the same shape as the chain link 13.
  • the adjacent chain link 15 also includes a series of link ends 65 that are axially spaced from each other to define a series of spaces 67.
  • the series of spaces 67 are adapted to receive the series of link ends 25 located on one side of the chain link 13.
  • the link ends 65 extend into the spaces 27 between the link ends 25 of the chain link 13.
  • the link ends 65 in the adjacent link 15 also include openings 69 that are axially aligned with respect to each other as well as the openings 33 in chain link 13 when the adjacent link 15 is assembled to the chain link 13.
  • the openings 69 may be cylindrical or elongated in the travel direction of the modular conveyor chain.
  • the modular chain links can take any conventional shape.
  • a conventional link shape is shown FIGS. 1 and 2.
  • Other typical chain link configurations are described and illustrated in U.S. Patent Nos. 5,335,768 and 5,215,185, both of which are assigned to the assignee of the present invention.
  • the chain link of the present invention is comprised of an injection molded polymer having a filler material added to the polymer to increase strength and other properties of the polymer.
  • the link 13 includes less than about 30 weight percent of filler based on the weight of the molded chained link; and preferably between the range of about 5 to 25 weight percent; and more preferably between the range of about 10 to 20 weight percent.
  • the filler used is preferably in the form of glass fibers, although stainless steel, aramide and carbon fibers may also be used.
  • the fibers e. ⁇ e preferably one-eighth to one-half inches long and oriented within the molded chain link in predominantly the same direction as the direction of travel of the modular conveyor chain.
  • the direction of travel of the chain is denoted as X (see FIG. 2).
  • the base polymer of the chain link is molded from acetal. In other arrangements the chain link could be molded from other moldable polymer materials used for molding chain links.
  • the literature includes test results for tests performed according to ASTM standards which indicate that the tensile strength of a filled polymer product increases as the weight percent of the filler material within the plastic increases.
  • ASTM standards which indicate that the tensile strength of a filled polymer product increases as the weight percent of the filler material within the plastic increases.
  • this is not the case when filled polymer is used to mold modular conveyor links for use in constructing a modular conveyor chain.
  • the mechanical properties of the chain links improve when the chain link comprises less than about 30 weight percent of filler based on the weight of the molded chain link; and preferably between the range of about 5 to 25 weight percent; and more preferably between the range of about 10 to 20 weight percent. Maximizing the desirable mechanical properties of the chain links increases the overall strength of the modular conveyor chain.
  • thermoplastic chain links that have less than 30 weight percent of filler was done by tensile testing chain links where the weight percent of the filler within the links varied from one test chain to another.
  • Each test chain included seven chain links that were six inches wide.
  • the chain links were assembled using connecting pins that were cut to seven inches long.
  • the links were molded from Celstran® polypropylene filled with long glass fiber produced by Ticona of Winona, MN, and the pins used were one- quarter inch diameter pultruded PBT rod.
  • Three different test chains were tested at each temperature (70°F, 140°F and 180°F) in order to determine an average value. The test was done by inserting one test chain into the pull test fixture and the other two test chains on the floor of the test chamber. All three test chains were held at 70°F for at least one hour before testing the first test chain.
  • test chains After testing the first test chain, the next preheated test chain was secured and held at 70 °F for about 15 minutes before testing. Once the second test was complete, the final test chain was secured and held at 70 °F for about 15 minutes before testing. This testing process was repeated for test chains at 140°F and 180°F. The results of these tests are provided below.
  • the fatigue strength of modular conveyor links should be higher when the links are molded from thermoplastics that include a higher weight percent of filler (at least up to 60 weight percent according to published technical literature).
  • fatigue testing done using modular conveyor links molded from filled polymer having less than 30 weight percent filler demonstrates that the fatigue strength (in addition to the tensile strength) of modular chain links is greater when the chain links are molded from a polymer that has less than 30 weight percent filler.
  • the fatigue tests were performed on test chains that included 15 chain links.
  • the chain links were assembled using connecting pins that were cut to 7 inches long.
  • the links were molded from Ticona 's Celstran® long glass reinforced polypropylene, and the pins used were one-quarter inch diameter pultruded PBT rod.
  • the pins used to connect the adjacent chain links were retained by using push nuts on the ends of the pins.
  • the tests were done at different load levels on thermoplastic test chains where the weight percent of filler within the molded chain links has varied for each load level.
  • One test chain was analyzed at each load level for each of the different weight percentages of filler that were tested. The fatigue failure values are shown in the table below.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chain Conveyers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Ropes Or Cables (AREA)
PCT/US1999/029635 1998-12-21 1999-12-14 Fiber filled chain link for a modular conveyer chain Ceased WO2000037337A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
AT99967311T ATE226912T1 (de) 1998-12-21 1999-12-14 Fasergefülltes kettenglied für eine modulare förderkette
BR9916455-8A BR9916455A (pt) 1998-12-21 1999-12-14 Elo de corrente modular para uso na construção de uma estreira rolante modular
EP99967311A EP1140672B2 (en) 1998-12-21 1999-12-14 Fiber filled chain link for a modular conveyer chain
DE69903752T DE69903752T3 (de) 1998-12-21 1999-12-14 Fasergefülltes kettenglied für eine modulare förderkette
DK99967311T DK1140672T4 (da) 1998-12-21 1999-12-14 Fiberfyldt kædeled til modulopbygget transportörkæde
CA002355733A CA2355733C (en) 1998-12-21 1999-12-14 Fiber filled chain link for a modular conveyer chain
JP2000589421A JP4628546B2 (ja) 1998-12-21 1999-12-14 繊維を充填したモジュラコンベヤチェイン用チエインリンク

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/217,259 1998-12-21
US09/217,259 US6247582B1 (en) 1998-12-21 1998-12-21 Fiber filled chain link for a modular conveyer chain

Publications (1)

Publication Number Publication Date
WO2000037337A1 true WO2000037337A1 (en) 2000-06-29

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ID=22810302

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1999/029635 Ceased WO2000037337A1 (en) 1998-12-21 1999-12-14 Fiber filled chain link for a modular conveyer chain

Country Status (11)

Country Link
US (2) US6247582B1 (enExample)
EP (1) EP1140672B2 (enExample)
JP (1) JP4628546B2 (enExample)
KR (1) KR100649796B1 (enExample)
AT (1) ATE226912T1 (enExample)
BR (1) BR9916455A (enExample)
CA (1) CA2355733C (enExample)
DE (1) DE69903752T3 (enExample)
DK (1) DK1140672T4 (enExample)
ES (1) ES2186432T5 (enExample)
WO (1) WO2000037337A1 (enExample)

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EP1264785A1 (en) * 2001-05-29 2002-12-11 Habasit AG Modular conveyor belt
US6696003B2 (en) 2001-05-29 2004-02-24 Habasit Ag Methods for manufacturing a module for a modular conveyor belt having a sandwich layer construction
US6880696B2 (en) 2001-05-29 2005-04-19 Habasit Ag Module for a modular conveyor belt having a sandwich layer construction and method of manufacture
EP2601081B1 (de) * 2010-08-03 2018-09-19 Takata AG Gurtaufroller mit strafferantrieb

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US6247582B1 (en) * 1998-12-21 2001-06-19 Rexnord Corporation Fiber filled chain link for a modular conveyer chain
US6749059B2 (en) * 2001-08-28 2004-06-15 Laitram, L.L.C. Modular conveyor belt with two-part hinge pin
AU2003217771A1 (en) 2002-11-14 2004-06-03 Ramsey Products Corporation End protector link for conveyor chain
US7267221B2 (en) * 2003-04-28 2007-09-11 Ramsey Products Corporation Silent modular conveyor and conveyor links
US7080729B2 (en) 2004-08-25 2006-07-25 Habasit Ag Belt module with oblong pivot hole
US7802675B2 (en) * 2005-05-13 2010-09-28 Ramsey Products Corporation End protector link for conveyor chain
US7284651B2 (en) * 2005-06-20 2007-10-23 Durr Systems, Inc. Conveyor system and method of conveying elements
DK1928766T3 (da) * 2005-09-02 2013-07-08 Span Tech Llc Slidbestandig konnektor til en båndtransportør med modulforbindelsesled
US7364036B2 (en) * 2006-02-09 2008-04-29 Habasit Ag Module for a perforated flat top belt with hinge gap for better fluid flow
ATE512103T1 (de) 2006-04-03 2011-06-15 Span Tech Llc Produktförderer mit pulverbeschichteten förderkomponenten
US7438179B2 (en) * 2006-08-30 2008-10-21 Laitram, L.L.C. Abrasion-resistant hinge rods in modular plastic conveyor belts
US8322522B2 (en) * 2010-03-22 2012-12-04 Ramsey Products Corporation Nested end link and multi-link conveyor chain
US8474607B2 (en) 2010-11-19 2013-07-02 Ramsey Products Corporation Integrated multi-functional links for chain link conveyor and method
NL2007860C2 (nl) * 2011-11-24 2013-05-27 Rexnord Flattop Europe Bv Modulaire transportmat en transporteur voorzien van een modulaire transportmat.
DE102012203392A1 (de) 2012-03-05 2013-09-05 Robert Bosch Gmbh Montageverfahren zum Herstellen einer Förderkette und Förderkette
DE102012203391A1 (de) 2012-03-05 2013-09-05 Robert Bosch Gmbh Fertigungsverfahren zum Herstellen einer Förderkette und Förderkette
WO2015059598A1 (en) 2013-10-21 2015-04-30 Ticona Gmbh Intrinsic low friction polyoxymethylene
DE102015105660A1 (de) 2015-04-14 2016-10-20 Bvm Brunner Gmbh & Co. Kg Verpackungsmaschinen Transportvorrichtung
DE102015105882B4 (de) 2015-04-17 2017-06-08 Delfortgroup Ag Umhüllungspapier mit hohem Kurzfaseranteil und Rauchartikel
KR102353150B1 (ko) * 2015-08-24 2022-01-20 한국자동차연구원 내열성 및 내유성이 우수한 폴리케톤 조성물 및 이의 제조방법
US10196577B2 (en) 2015-09-30 2019-02-05 Celanese Sales Germany Gmbh Low friction squeak free assembly
EP3348497B1 (en) 2017-01-11 2020-06-24 Pennine Industrial Equipment Limited Conveyor chain
BR112019014531B1 (pt) * 2017-01-30 2023-04-25 Daido Kogyo Co., Ltd Corrente para transportador a vácuo
WO2018163098A1 (en) 2017-03-10 2018-09-13 Celanese Sales Germany Gmbh Polyester polymer compositions

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DK1140672T3 (da) 2003-02-24
EP1140672B2 (en) 2007-05-09
DE69903752D1 (de) 2002-12-05
ATE226912T1 (de) 2002-11-15
ES2186432T3 (es) 2003-05-01
US20010025771A1 (en) 2001-10-04
JP4628546B2 (ja) 2011-02-09
DK1140672T4 (da) 2007-09-03
EP1140672A1 (en) 2001-10-10
JP2002532361A (ja) 2002-10-02
US6360881B2 (en) 2002-03-26
ES2186432T5 (es) 2007-12-01
CA2355733C (en) 2008-02-26
BR9916455A (pt) 2001-09-04
DE69903752T3 (de) 2008-01-24
KR100649796B1 (ko) 2006-11-24
KR20010093209A (ko) 2001-10-27
CA2355733A1 (en) 2000-06-29
DE69903752T2 (de) 2003-03-20
EP1140672B1 (en) 2002-10-30
US6247582B1 (en) 2001-06-19

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