WO1999004900A1 - Mousse de carbure de silicium a surface specifique elevee et a caracteristiques mecaniques ameliorees - Google Patents
Mousse de carbure de silicium a surface specifique elevee et a caracteristiques mecaniques ameliorees Download PDFInfo
- Publication number
- WO1999004900A1 WO1999004900A1 PCT/FR1998/001579 FR9801579W WO9904900A1 WO 1999004900 A1 WO1999004900 A1 WO 1999004900A1 FR 9801579 W FR9801579 W FR 9801579W WO 9904900 A1 WO9904900 A1 WO 9904900A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- foam
- resin
- silicon
- temperature
- specific surface
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/20—Carbon compounds
- B01J27/22—Carbides
- B01J27/224—Silicon carbide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0081—Uses not provided for elsewhere in C04B2111/00 as catalysts or catalyst carriers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/20—Mortars, concrete or artificial stone characterised by specific physical values for the density
Definitions
- the invention relates to a silicon carbide foam with a specific surface and high porosity having improved mechanical characteristics, in particular crushing resistance, this foam essentially serving as a catalyst support, for example in the chemical or petrochemical industry and in exhaust pipes from internal combustion engines, or filters.
- catalyst supports in particular SiC, with a high specific surface (greater than 15 m2 / g), having a bi-modal porosity in which a first family of pores of average diameter between 1 to 1 00 ⁇ m allows a gas to have access to a second family of pores with an average diameter of less than 0.1 ⁇ m responsible for the specific surface and the catalytic activity.
- This support is obtained by mixing an Si powder or one of its reducible compounds in a polymeric or polymerizable organic resin with optionally adjuvants, shaping the mixture, crosslinking and polymerization of the resin, obtaining a skeleton porous carbon containing Si or its compound, by carbonization in a non-oxidizing atmosphere at a temperature between 500 and 1000 ° C, and finally carburizing the Si at a temperature between 1000 and 1400 ° C always in a non-oxidizing atmosphere.
- Such a support has good crush resistance and has a rather high density, generally of the order of 0.6 to 0.8 g / cm 3, but it does not have the usually aerated appearance of a foam, but rather that of a more massive porous body; therefore it does not have sufficient permeability to process large volumes of gas per unit weight of support and sees its field of use limited. In other words, as soon as the support has large dimensions, its center is difficult to access by the gases to be treated and represents an unused dead mass.
- Patent FR 2,684,092 describes an SiC foam obtained by carburetion reaction from a volatile Si compound with an activated carbon foam.
- This activated carbon foam can result from a polyurethane foam reinforced by impregnation with a resin, hardening of the resin, carbonization and activation.
- the carbide foam obtained has a specific surface of at least 20 m2 / g thanks to macropores having edges whose lengths can vary from 50 to 500 ⁇ m and mainly to mesopores whose diameter is usually between 0.03 and 0.05 ⁇ m, this more generally being approximately three times larger than that of the pores of activated carbon foam.
- the carbide foam obtained has a specific surface of at least 5 m2 / g, which depends in particular on the final temperature reached. It has a bi-modal porosity comprising macropores with an average diameter between 100 and 150 ⁇ m and mesopores between 0.0275 and 0.035 ⁇ m.
- This foam can be used as a catalyst support or as a diesel engine filter.
- the Applicant has therefore tried to make the use of said SiC foam supports safer, in particular in exhaust pipes or for regeneration treatments, by significantly improving their mechanical properties without penalizing their catalytic properties. , in particular their specific surface or their bimodal porosity, which is not obvious because generally one is obtained at the expense of the other, while retaining their permeability.
- the invention is a foam based on silicon carbide for catalytic applications, having a high specific surface, typically its BET surface is at least 5 m2 / g, characterized in that it has a compressive strength greater than 0.2 MPa (2 bar), but generally at least 0.4 MPa (4 bar).
- the foam according to the invention generally has a bimodal porosity, measured with mercury, essentially comprising a family of pores whose average diameter is between 10 and 200 ⁇ m allowing easy access to the gases to be treated towards the mesoporosity whose pores have a diameter medium between 0.005 and 1 ⁇ m and which allows catalytic activity.
- This bimodal porosity is added to the porous structure of the foam which is typically in the form of a network that could be described as "fibrous" comprising kinds of communicating cages delimited by carbide edges (or bridges) , generally between 50 and 500 ⁇ m thick, linked together by knots.
- the mega pores of this network visible to the naked eye, have dimensions which can be between 0.4 and 1.6 mm and correspond to a pore volume of
- the foam most often has a specific surface greater than 10 m2 / g.
- Its density is typically between 0.06 and 0.2 and preferably between 0.08 and 0.1 5.
- Compressive strength is measured by a hardness test well known in the field of material resistance. It consists in applying a force to a cylindrical punch of known plane section and to measuring the force necessary to make it penetrate into the foam over a height of 1 cm, the sample having at least two parallel flat faces distant by at least 5 cm.
- the foam according to the invention also has very good resistance to thermal shock.
- the SiC content of the foam is typically greater than 95%, or better 98%, the residual Si content generally not exceeding 0.1% That of residual C does not exceed 3%, usually 2%; the latter can moreover be eliminated by oxidation in air at a controlled temperature of around 600 ° C. to 850 ° C.
- an organic starting foam is impregnated, usually of polyurethane, using a suspension of a silicon powder in a resin; this resin contains oxygen, has a carbon yield greater than 30%, and is added with a crosslinking catalyst in a proportion of 1 to 10% (by weight), preferably 5%; in general it is a furfuryl resin and the crosslinker of hexamethylenetetramine, the weight ratio silicon to resin being between 0.6 and 1, 2.
- the weight ratio of the total mass of impregnated foam to the mass of the starting foam is greater than 10 and less than 20, which generally corresponds to a resin to foam weight ratio greater than 5 and not exceeding 1 1 to avoid the risk of blocking the porous structure of the foam.
- the impregnated foam is heat treated so that the resin is incompletely crosslinked at the time of degradation of the organic foam, then the organic foam and the resin are carbonized by bringing the temperature to 1200 ° C. under an inert atmosphere; the silicon is carburetted, always under an inert atmosphere, by bringing the temperature from 1,200 ° C. to 1,370 ° C. to obtain a carbide foam with a high specific surface or at a higher temperature when obtaining a very high specific surface area is less critical, for example when carbide foam is used as a filter in a diesel engine.
- the starting organic foam is generally a shaped part.
- it can comprise a doping element making it possible to improve the resistance of the SiC foam to oxidation at high temperature, for example a powder of at least one easily oxidizable metal, such as Al, Ca, Y ..., or of an alloy containing these metals, this doping element being introduced into the mass of the foam, for example, during its manufacture.
- a doping element making it possible to improve the resistance of the SiC foam to oxidation at high temperature
- a powder of at least one easily oxidizable metal such as Al, Ca, Y ..., or of an alloy containing these metals
- this doping element being introduced into the mass of the foam, for example, during its manufacture.
- we unexpectedly notice that the addition of these dopants generally improves the mechanical characteristics of the final carbide foam, in particular its resistance to crushing.
- the permeability of said organic foam can be improved by a preliminary treatment, for example with sodium hydroxide when it is a polyurethane.
- the invention also includes starting from the components making it possible to obtain the foam (for example monomeric or copolymeric agents, porogenic adjuvants, hardeners, crosslinking agents or others) possibly added with said doping element and optionally add to this mixture the suspension of silicon in the resin.
- This mixture can then be shaped by molding, injection. , before obtaining the foam and being heat treated.
- the suspension of Si in an organic resin can contain various adjuvants: solvent (for example alcohol), filler (for example carbon black) to adjust the viscosity, plasticizer, surfactant, etc.
- solvent for example alcohol
- filler for example carbon black
- a step of heating at moderate temperature to remove the solvents can be carried out, while maintaining the thermal regime under the conditions mentioned above.
- the silicon powder generally has a grain size passing the sieve 50 ⁇ and preferably has an average particle diameter of less than 10 ⁇ m; it can be introduced in the form of an alloy comprising said doping elements making it possible to improve the resistance to oxidation of the SiC foam; these can also be introduced in the form of a metallic powder or in the form of a decomposable salt mixed with said Si powder.
- the proportion of doping elements does not typically exceed 10% relative to the silicon introduced into the resin.
- the polymé ⁇ sée resin typically contains at least 5% by weight of oxygen and preferably 1 5%.
- the rate of incomplete polymerization can be characterized by measuring the glass transition temperature (Tg) of the partially polymerized resin.
- Tg glass transition temperature
- this temperature is less than 110 ° C. and corresponds to the appropriate degree of polymerization at the time of starting carbonization; it is also greater than 70 ° C so that the shaped part has sufficient hold during the heat treatment.
- the controlled polymerization heat treatment can be carried out in different ways; it is generally adapted to the size of the parts treated.
- the poiymé ⁇ sée resin typically contains at least 5% (by weight) of oxygen and preferably 1 5%.
- the high proportion of resin, and therefore of impregnation suspension, introduced into the organic foam contributes to the increase in mechanical characteristics, in particular of crushing, without that the specific surface, which characterizes the catalytic properties of carbide foam, be affected.
- Such a well crushable carbide foam can be used as a catalyst support in the divided form of stacked pieces; but it is particularly well suited to be used as a piece of monolithic shape, for example in exhaust pipes; it is sufficient to cover it with a deposit of the desired catalyst according to conventional methods.
- the process can also be completed by a stabilization heat treatment step, in an oxidizing atmosphere.
- This treatment can be carried out during the removal of the residual carbon; it is particularly advantageous to practice it when the foam contains a doping element II is usually carried out between 850 and 1,200 ° C for a period between 5 min and 24 h or preferably between 950 and 1,100 ° C for 1 5 min at 10 a.m., the longer the longer the temperature is low. It results in a coating of the foam with an oxide film comprising at least one of the silicon oxides or doping elements, the silicon oxide generally containing that of the doping elements.
- the foam can also be impregnated, for example under vacuum, using a solution of a decomposable salt of at least one of said doping elements, heat treatment to decompose the salt, then advantageously complete with the previous stabilizing treatment to obtain the corresponding protective film.
- This example relates to a silicon carbide foam obtained according to a process of the state of the art.
- a piece of cylindrical polyurethane foam 14 cm in diameter and 8 cm high with a density of 0.028 was impregnated with a suspension containing Si powder with an average grain diameter of 5 ⁇ m in 95% d furfuryl alcohol and 5% hexamethylenetetramine serving as a polycondensation catalyst.
- the ratio of the mass of silicon to that of the resin is 0.7.
- the ratio of the weight of resin to the weight of said foam is 4.1, and the ratio of the total mass of impregnated foam to the mass of polyurethane is 7.8.
- the polymerization was carried out by increasing the temperature to 250 ° C at a speed of 5 ° C / min for 45 min, with a plateau at 250 ° C with a duration of 5 min to polymerize the resin.
- the glass transition temperature (Tg) of this resin under these conditions is 1 1 8 ° C.
- the carbonization was then carried out by bringing the temperature from 250 ° to 1000 ° C under an Ar atmosphere at a speed of 1 ° C / min.
- the heat treatment continued by increasing the temperature to 1,350 ° C. at a speed of 3 ° C./min with a temperature level of 2 hours at 1,350 ° C., still under an inert atmosphere.
- the resulting carbide foam was then treated at 800 ° C with pure air to destroy the residual carbon.
- the BET specific surface is then 1 0.8 m2 / g and the crushing resistance measured by the hardness test is 0.08 MPa.
- a silicon powder with an average grain diameter of 5 ⁇ m was used in furfuryl alcohol with 5% of crosslinking catalyst (hexamethylenetetramine).
- the mass ratio of Si to resin mass is 0.7.
- the ratio of the mass of impregnated foam to the mass of polyurethane is 1 6
- the incomplete polymerization was carried out by steaming, bringing the impregnated foam to 200 ° C. with a temperature rise rate of 5 ° C./min. The duration did not exceed 35 min.
- the Tg value is 103 ° C.
- the hardened product was then introduced into an oven under an Ar atmosphere, the temperature of which was brought to 1,200 ° C. with a speed of 3 ° C./min., To carry out carbonization.
- the heat treatment was continued by increasing the temperature to 1350 ° C. under the same conditions, with the final temperature held constant for 2 h to carry out the carburetion of the silicon.
- the Si carbide foam shaped part has a BET specific surface area of 1 1, 2 m2 / g and a crushing strength of 0.6 MPa, which makes it particularly suitable for being impregnated with a catalyst for be used as an exhaust catalyst.
- This example illustrates the production of a carbide foam with dopant according to the invention.
- the starting polyurethane foam is impregnated using the same suspension as in Example 2, containing Si in furfuryl alcohol with crosslinking catalyst; however, aluminum nitrate monohydrate was added thereto in a proportion such that 0.75% (weight) of AI was obtained relative to the weight of final SiC.
- the SiC foam obtained has a specific surface of 11.7 m 2 / g, of the same order of magnitude as that of Example 2; on the other hand, the crush resistance of 0.9 MPa is significantly higher.
- the SiC foam piece was separated into two pieces. One of them underwent a stabilization treatment at 1000 ° C for 2 h in air; however both have then subjected to an oxidation resistance test by exposure to air at 1100 ° C. for 5 h.
- the same undoped foam exhibits, under the same conditions, a weight gain of 15.8% when it is not stabilized and of 6.7% when it is stabilized.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Catalysts (AREA)
- Ceramic Products (AREA)
- Carbon And Carbon Compounds (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Filtering Materials (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98939711A EP1007207A1 (fr) | 1997-07-25 | 1998-07-20 | Mousse de carbure de silicium a surface specifique elevee et a caracteristiques mecaniques ameliorees |
AU88129/98A AU735809B2 (en) | 1997-07-25 | 1998-07-20 | Silicon carbide foam with high specific surface area and improved mechanical properties |
US09/446,135 US6251819B1 (en) | 1997-07-25 | 1998-07-20 | Silicon carbide foam with high specific surface area and improved mechanical properties |
CA002297766A CA2297766C (fr) | 1997-07-25 | 1998-07-20 | Mousse de carbure de silicium a surface specifique elevee et a caracteristiques mecaniques ameliorees |
JP2000503935A JP4647778B2 (ja) | 1997-07-25 | 1998-07-20 | 比表面積が大きく力学特性が向上した炭化珪素フォーム |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9709743A FR2766389B1 (fr) | 1997-07-25 | 1997-07-25 | Mousse de carbure de silicium a surface specifique elevee et a caracteristiques mecaniques ameliorees |
FR97/09743 | 1997-07-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999004900A1 true WO1999004900A1 (fr) | 1999-02-04 |
Family
ID=9509838
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR1998/001579 WO1999004900A1 (fr) | 1997-07-25 | 1998-07-20 | Mousse de carbure de silicium a surface specifique elevee et a caracteristiques mecaniques ameliorees |
Country Status (8)
Country | Link |
---|---|
US (1) | US6251819B1 (fr) |
EP (1) | EP1007207A1 (fr) |
JP (2) | JP4647778B2 (fr) |
KR (1) | KR100518063B1 (fr) |
AU (1) | AU735809B2 (fr) |
CA (1) | CA2297766C (fr) |
FR (1) | FR2766389B1 (fr) |
WO (1) | WO1999004900A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003014042A1 (fr) * | 2001-08-07 | 2003-02-20 | National Institute Of Advanced Industrial Science And Technology | Materiau structural poreux super-leger et resistant a la chaleur a base de carbure de silicium |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6749652B1 (en) * | 1999-12-02 | 2004-06-15 | Touchstone Research Laboratory, Ltd. | Cellular coal products and processes |
JPWO2003035577A1 (ja) * | 2001-10-22 | 2005-02-10 | 独立行政法人産業技術総合研究所 | 炭化ケイ素系多孔質構造材及びその製造方法 |
US20040158112A1 (en) * | 2003-02-10 | 2004-08-12 | Conocophillips Company | Silicon carbide-supported catalysts for oxidative dehydrogenation of hydrocarbons |
EP1656985A4 (fr) | 2003-04-23 | 2008-10-29 | Nat Inst Of Advanced Ind Scien | Filtre photocatalyseur structure a cellules fines tridimensionnelles sensibles a la lumiere visible, procede de production de ce filtre et dispositif de clarification |
FR2860993B1 (fr) | 2003-10-16 | 2006-06-16 | Sicat | Filtre catalytique a base de carbure de silicium (b-sic) pour la combustion des suies issues des gaz d'echappement d'un moteur a combustion |
FR2860992B1 (fr) * | 2003-10-16 | 2006-06-16 | Sicat | Filtre catalytique a base de carbure de silicium (b-sic) pour la combustion des suies issues des gaz d'echappement d'un moteur a combustion |
FR2864532B1 (fr) * | 2003-12-31 | 2007-04-13 | Total France | Procede de transformation d'un gaz de synthese en hydrocarbures en presence de sic beta et effluent de ce procede |
KR101309476B1 (ko) * | 2004-12-13 | 2013-09-23 | 비피 코포레이션 노쓰 아메리카 인코포레이티드 | 방향족 카르복실산의 정제 방법 |
FR2889080B1 (fr) * | 2005-07-28 | 2007-11-23 | Saint Gobain Ct Recherches | Support et filtre catalytique a base de carbure de silicium et a haute surface specifique |
US8105649B1 (en) | 2007-08-09 | 2012-01-31 | Imaging Systems Technology | Fabrication of silicon carbide shell |
JP2010201362A (ja) * | 2009-03-04 | 2010-09-16 | National Institute Of Advanced Industrial Science & Technology | 触媒担体とその製造方法及び触媒 |
US8136571B2 (en) * | 2009-05-19 | 2012-03-20 | Debruin Mark | Carbidic outer edge ductile iron product, and as cast surface alloying process |
DE102009049173A1 (de) | 2009-10-13 | 2011-04-21 | Süd-Chemie AG | Reaktoranordnung zur katalytischen Gasphasenoxidation |
FR2965191A1 (fr) | 2010-09-23 | 2012-03-30 | Centre Nat Rech Scient | Reacteur a plaques pour la synthese fischer-tropsch |
AU2013283037B2 (en) | 2012-06-26 | 2017-05-25 | Centre National De La Recherche Scientifique | Catalyst supports made from silicon carbide covered with TiO2 for fischer-tropsch synthesis |
US9327472B1 (en) | 2013-07-19 | 2016-05-03 | Integrated Photovoltaics, Inc. | Composite substrate |
KR101954067B1 (ko) * | 2017-11-28 | 2019-03-06 | 한국과학기술연구원 | 촉매 금속이 담지된 다공질 탄화규소 구조체의 제조방법 |
CN116023787B (zh) * | 2022-11-11 | 2023-08-22 | 武汉中科先进材料科技有限公司 | 一种具有双峰泡孔结构的有机硅泡沫及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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DE3516587A1 (de) * | 1984-05-29 | 1985-12-05 | Ibiden K.K., Oogaki, Gifu | Poroeser siliciumcarbidsinter und verfahren zu seiner herstellung |
EP0511919A1 (fr) * | 1991-04-29 | 1992-11-04 | PECHINEY RECHERCHE (Groupement d'Intérêt Economique régi par l'Ordonnance du 23 Septembre 1967) | Système catalytique, notamment pour la combustion de gaz d'échappement et procédé pour le fabriquer |
EP0543752A1 (fr) * | 1991-11-21 | 1993-05-26 | PECHINEY RECHERCHE (Groupement d'Intérêt Economique régi par l'Ordonnance du 23 Septembre 1967) Immeuble Balzac | Procédé de préparation de carbures métalliques à grande surface spécifique à partir de mousses de carbone activées |
EP0624560A2 (fr) * | 1993-05-13 | 1994-11-17 | PECHINEY RECHERCHE (Groupement d'Intérêt Economique régi par l'Ordonnance du 23 Septembre 1967) Immeuble Balzac | Fabrication de mousse de carbure de silicium a partir d'une mousse de polyuréthane imprégnée de résine contenant du silicium |
WO1997026988A1 (fr) * | 1996-01-26 | 1997-07-31 | Pechiney Recherche | SUPPORTS DE CATALYSEUR EN MOUSSE DE SiC REVETUE D'OXYDE METALLIQUE ET SYSTEMES CATALYTIQUES CORRESPONDANTS |
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JPS624446A (ja) * | 1985-06-29 | 1987-01-10 | Ibiden Co Ltd | 触媒担体 |
JPS6241777A (ja) * | 1985-08-16 | 1987-02-23 | 黒崎窯業株式会社 | 炭化珪素焼結体の接合方法 |
JPH0624636B2 (ja) * | 1985-08-26 | 1994-04-06 | 工業技術院長 | 触媒担体及びその製造方法 |
JP2603139B2 (ja) * | 1989-08-24 | 1997-04-23 | 東海カーボン株式会社 | 多孔質セラミックス構造体の製造方法 |
FR2657603B1 (fr) * | 1990-01-29 | 1993-07-09 | Pechiney Electrometallurgie | Procede d'obtention de corps solides poreux a base de carbure refractaire a l'aide de composes organiques et de metal ou metallouide. |
JPH07115964B2 (ja) * | 1990-10-29 | 1995-12-13 | 東海カーボン株式会社 | 低抵抗性SiC多孔体 |
FR2680984B1 (fr) | 1991-09-06 | 1993-11-05 | Pechiney Recherche | Preparation de catalyseur a partir d'oxydes metalliques par reduction et carburation partielle par les gaz reactionnels. |
JP3278681B2 (ja) * | 1992-05-20 | 2002-04-30 | 東海高熱工業株式会社 | 多孔質炭化けい素焼結体の製造方法 |
JPH0826848A (ja) * | 1994-07-21 | 1996-01-30 | Tokai Carbon Co Ltd | 多孔質SiC成形体の製造方法 |
JP3642836B2 (ja) * | 1995-09-06 | 2005-04-27 | 東京窯業株式会社 | 炭化珪素ハニカム構造体及びその製造方法 |
JPH09118566A (ja) * | 1995-10-25 | 1997-05-06 | Oji Paper Co Ltd | 炭化珪素繊維構造体の製造方法 |
FR2754741B1 (fr) * | 1996-10-21 | 1998-11-20 | Pechiney Recherche | Support de catalyseur en mousse de sic a peau renforcee et systemes catalytiques correspondants |
-
1997
- 1997-07-25 FR FR9709743A patent/FR2766389B1/fr not_active Expired - Fee Related
-
1998
- 1998-07-20 KR KR10-2000-7000368A patent/KR100518063B1/ko not_active IP Right Cessation
- 1998-07-20 US US09/446,135 patent/US6251819B1/en not_active Expired - Lifetime
- 1998-07-20 WO PCT/FR1998/001579 patent/WO1999004900A1/fr active IP Right Grant
- 1998-07-20 CA CA002297766A patent/CA2297766C/fr not_active Expired - Fee Related
- 1998-07-20 AU AU88129/98A patent/AU735809B2/en not_active Ceased
- 1998-07-20 EP EP98939711A patent/EP1007207A1/fr not_active Withdrawn
- 1998-07-20 JP JP2000503935A patent/JP4647778B2/ja not_active Expired - Fee Related
-
2010
- 2010-02-18 JP JP2010033357A patent/JP2010155241A/ja active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3516587A1 (de) * | 1984-05-29 | 1985-12-05 | Ibiden K.K., Oogaki, Gifu | Poroeser siliciumcarbidsinter und verfahren zu seiner herstellung |
EP0511919A1 (fr) * | 1991-04-29 | 1992-11-04 | PECHINEY RECHERCHE (Groupement d'Intérêt Economique régi par l'Ordonnance du 23 Septembre 1967) | Système catalytique, notamment pour la combustion de gaz d'échappement et procédé pour le fabriquer |
EP0543752A1 (fr) * | 1991-11-21 | 1993-05-26 | PECHINEY RECHERCHE (Groupement d'Intérêt Economique régi par l'Ordonnance du 23 Septembre 1967) Immeuble Balzac | Procédé de préparation de carbures métalliques à grande surface spécifique à partir de mousses de carbone activées |
FR2684092A1 (fr) * | 1991-11-21 | 1993-05-28 | Pechiney Recherche | Procede de preparation de carbures metalliques a grande surface specifique a partir de mousses de carbone activees. |
EP0624560A2 (fr) * | 1993-05-13 | 1994-11-17 | PECHINEY RECHERCHE (Groupement d'Intérêt Economique régi par l'Ordonnance du 23 Septembre 1967) Immeuble Balzac | Fabrication de mousse de carbure de silicium a partir d'une mousse de polyuréthane imprégnée de résine contenant du silicium |
FR2705340A1 (fr) * | 1993-05-13 | 1994-11-25 | Pechiney Recherche | Fabrication de mousse de carbure de silicium à partir d'une mousse de polyuréthane imprégnée de résine contenant du silicium. |
WO1997026988A1 (fr) * | 1996-01-26 | 1997-07-31 | Pechiney Recherche | SUPPORTS DE CATALYSEUR EN MOUSSE DE SiC REVETUE D'OXYDE METALLIQUE ET SYSTEMES CATALYTIQUES CORRESPONDANTS |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003014042A1 (fr) * | 2001-08-07 | 2003-02-20 | National Institute Of Advanced Industrial Science And Technology | Materiau structural poreux super-leger et resistant a la chaleur a base de carbure de silicium |
Also Published As
Publication number | Publication date |
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JP2010155241A (ja) | 2010-07-15 |
JP2001510729A (ja) | 2001-08-07 |
JP4647778B2 (ja) | 2011-03-09 |
AU8812998A (en) | 1999-02-16 |
CA2297766C (fr) | 2009-01-20 |
EP1007207A1 (fr) | 2000-06-14 |
US6251819B1 (en) | 2001-06-26 |
KR20010021804A (ko) | 2001-03-15 |
AU735809B2 (en) | 2001-07-19 |
FR2766389A1 (fr) | 1999-01-29 |
KR100518063B1 (ko) | 2005-09-28 |
FR2766389B1 (fr) | 1999-09-03 |
CA2297766A1 (fr) | 1999-02-04 |
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