WO1998051396A1 - Heisssiegelfähiges filtermaterial mit biologisch abbaubaren polymeren - Google Patents

Heisssiegelfähiges filtermaterial mit biologisch abbaubaren polymeren Download PDF

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Publication number
WO1998051396A1
WO1998051396A1 PCT/EP1998/002553 EP9802553W WO9851396A1 WO 1998051396 A1 WO1998051396 A1 WO 1998051396A1 EP 9802553 W EP9802553 W EP 9802553W WO 9851396 A1 WO9851396 A1 WO 9851396A1
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WO
WIPO (PCT)
Prior art keywords
acid
acids
aliphatic
bifunctional
optionally
Prior art date
Application number
PCT/EP1998/002553
Other languages
German (de)
English (en)
French (fr)
Inventor
Ralf Timmermann
Ernst Grigat
Wolfgang Schulz-Schlitte
Sabine Schroft
Richard Grangladen
Günter Heinrich
Original Assignee
Bayer Aktiengesellschaft
Papierfabrik Schoeller & Hoesch Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Aktiengesellschaft, Papierfabrik Schoeller & Hoesch Gmbh & Co. Kg filed Critical Bayer Aktiengesellschaft
Priority to CA 2289739 priority Critical patent/CA2289739A1/en
Priority to EP98924249A priority patent/EP0981400A1/de
Priority to AU76511/98A priority patent/AU743370B2/en
Priority to JP54873898A priority patent/JP2001524873A/ja
Publication of WO1998051396A1 publication Critical patent/WO1998051396A1/de
Priority to NO995401A priority patent/NO995401D0/no

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/804Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package
    • B65D85/808Disposable containers or packages with contents which are mixed, infused or dissolved in situ, i.e. without having been previously removed from the package for immersion in the liquid to release part or all of their contents, e.g. tea bags
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1607Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
    • B01D39/1615Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of natural origin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/14Other self-supporting filtering material ; Other filtering material
    • B01D39/16Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
    • B01D39/1607Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
    • B01D39/1623Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous of synthetic origin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/46Applications of disintegrable, dissolvable or edible materials
    • B65D65/466Bio- or photodegradable packaging materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/12Polyester-amides
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266Natural fibres not provided for in group D04H1/425
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/435Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4374Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece using different kinds of webs, e.g. by layering webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00Other non-woven fabrics
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/08Filter paper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2230/00Compositions for preparing biodegradable polymers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/24Polyesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/20Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/26Polyamides; Polyimides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • D21H27/38Multi-ply at least one of the sheets having a fibrous composition differing from that of other sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

Definitions

  • the invention relates to a filter material consisting of at least one layer of natural fibers and at least a second layer of heat-sealable synthetic material which is biodegradable.
  • EP-A 0 380 127 A2 describes a heat-sealable teabag paper and the process for producing it, the heat-sealing phase containing polyethylene and / or polypropylene and / or a copolymer of nylon chloride and vinyl acetate and the weight per unit area of this material between 10 and 15 g / m 2 .
  • EP-A 656 224 (application number 94 107 709.1) describes a filter material, in particular for the production of tea bags and coffee bags or filters, with a basis weight between 8 and 40 g / m 2 , in which the heat-sealing layer consists of plastic fibers, preferably polypropylene or polyethylene, which is placed in the heated state on the first layer consisting of natural fibers.
  • the German application DE-A 2 147 321 (US priority 23.09.70, US 74 722) describes a thermoplastic, heat-sealable composition which consists of a polyolefin powder (polyethylene or polypropylene) which is composed of a nylon chloride / Vinyl acetate copolymer is embedded. This material is also used for the heat-sealable finishing of paper-based fiber material.
  • All of the filter materials mentioned require a proportion of at least 20 to 30% by weight of thermoplastic material, based on the total weight per unit area of the filter material, in order to produce a filter bag by heat sealing.
  • the used filter materials for example tea bags, coffee bags or other filters
  • a compost heap or in the organic waste bin After a certain period of time, which depends on other parameters such as temperature, air humidity, microorganisms, etc., the natural fiber components of the filter bag disintegrate and biodegrade, while the thermoplastic polymer fiber network is preserved and the quality of the compost is reduced.
  • thermoplastic, non-biodegradable polymer i.e. the used filter bag should be sent to the non-recyclable waste (gray bin).
  • the aim of the invention is therefore to create a completely biodegradable, heat-sealable filter material that is compostable and therefore also represents the cheapest and most economical and ecological solution.
  • ner processes for the production of such filter materials are to be described.
  • the invention relates to a filter material consisting of an at least two-layer structure, at least one layer containing natural fibers and one layer of biodegradable thermoplastic fibers, the thermoplastic
  • Fibers are selected from the group of aliphatic or partially aromatic polyester amides, aliphatic or partially aromatic polyesters, aliphatic or partially aromatic polyester urethanes, aliphatic or aliphatic-aromatic polyester carbonates and can also be a mixture of two or more of these polymers.
  • thermoplastic fibers can be placed on the layer of natural fibers both in one operation on the paper machine, and, in the heated state, can be deposited on this layer of paper made of natural fibers by meltblowing and melted, and both with and with each other the paper layer are fused.
  • the first layer of the filter material generally has a basis weight between 8 and 40 g / m 2 , preferably from 10 to 20 g / m 2 and an air permeability of 300 to 4,000 l / m 2 -sec (DI ⁇ 53 887), preferably from 500 to 3,000 l / m 2 -sec.
  • the second layer of the filter material preferably has a basis weight of 1 to 15 g / m 2 , preferably 1.5 to 10 g / m 2 .
  • the first layer of the filter material made of natural fibers is preferably designed to be wet-strength.
  • the filter material is used, for example, for the production of tea bags, coffee bags or tea or coffee filters.
  • the filter material can be produced as follows:
  • an aqueous suspension of the natural fibers is applied to a paper machine screen and in a second stage the heat-sealable, biodegradable polymer fibers are deposited on the natural fiber layer in such a way that they partially penetrate the natural fiber layer, the penetration of the two
  • Known natural fibers such as hemp, manila, jute, sisal and other long-fiber wood pulp are used for the first layer and are produced in a manner known per se on a paper machine.
  • a biodegradable thermoplastic polymer or a mixture of the following polymers in fiber form is used for the second layer, which is selected from the group of aliphatic or partially aromatic polyester amides, aliphatic or partially aromatic polyesters, aliphatic or partially aromatic polyester urethanes, aliphatic or aliphatic -aromatic polyester carbonates.
  • Suitable biodegradable and compostable polymers are aliphatic or partially aromatic polyesters, thermoplastic aliphatic or partially aromatic polyester urethanes, aliphatic or aliphatic-aromatic polyester carbonates, aliphatic or partially aromatic polyester amides.
  • the following polymers are suitable:
  • A) aliphatic bifunctional alcohols preferably linear C 2 to o-dialcohols such as ethanediol, butanediol, hexanediol or particularly preferably butanediol and / or optionally cycloaliphatic bifunctional alcohols, preferably having 5 or 6 carbon atoms in the cycloaliphatic ring, such as cyclohexanedimethanol , and / or partially or completely instead of the diols monomeric or oligomeric polyols based on ethylene glycol, propylene glycol, tetrahydrofuran or copolymers thereof with molecular weights up to 4000, preferably up to 1000, and / or optionally small amounts of branched bifunctional alcohols, preferably C 3 -C 1 2- alkyldiols, such as neopentylglygol, and in addition, if appropriate, small amounts of higher-functional alcohols, such as 1,2,3
  • aromatic acids not more than 50 wt .-%, based on all
  • C) aliphatic bifunctional alcohols preferably linear C 2 to cio dialcohols such as ethanediol, butanediol, hexanediol, particularly preferably butanediol and / or optionally cycloaliphatic bifunctional alcohols, preferably with a C 5 - or C ⁇ -cycloaliphatic ring, such as for example Cyclohexanedimethanol, and / or partially or completely instead of the diols, monomeric or oligomeric polyols based on ethylene glycol, propylene glycol, tetrahydrofuran or copolymers thereof with molecular weights up to 4000, preferably up to 1000, and / or optionally small amounts of branched bifunctional alcohols, preferably C 3 - C 2 -alkyldiols, such as neopentylglygol, and additionally optionally small amounts of higher-functional alcohols, preferably C 3 -
  • aromatic acids making up no more than 50% by weight, based on all acids
  • ester content C) and / or D) is at least 75% by weight, based on the sum of C), D) and E).
  • aliphatic bifunctional alcohols preferably linear C 2 to cio dialcohols such as, for example, ethanediol, butanediol, hexanediol or particularly preferably butanediol and / or optionally cycloaliphatic bifunctional alcohols, preferably having 5 to 8 C atoms in the cycloaliphatic ring, such as, for example, cyclohexanedimethanol , and / or partially or completely instead of the diols monomeric or oligomeric polyols based on ethylene glycol,
  • G from acid- and alcohol-functionalized building blocks, preferably with 2 to 12 carbon atoms in the alkyl chain, for example hydroxybutyric acid, hydroxyvaleric acid, lactic acid, or their derivatives, for example ⁇ -caprolactone or dilactide,
  • aromatic acids making up no more than 50% by weight, based on all acids
  • ester fraction F) and / or G) at least 70% by weight, based on the sum of
  • aliphatic bifunctional alcohols preferably linear C 2 to Cio dialko- hols such as ethanediol, butanediol, hexanediol, particularly preferably butanediol, and / or optionally cycloaliphatic bifunctional Alcohols, preferably with 5 to 8 carbon atoms, such as cyclohexanedimethanol, and / or partially or completely instead of the diols, monomeric or oligomeric polyols based on ethylene glycol, propylene glycol, tetrahydrofuran or copolymers thereof with molecular weights up to 4,000, preferably up to 1,000, and / or optionally small amounts of branched bifunctional alcohols, preferably C 3 -C 12 alkyldiols, such as neopentylglygol and additionally optionally small amounts of higher functional alcohols, preferably C 3 -C 12 alkylpolyols, such as
  • K from acid- and alcohol-functionalized building blocks, preferably with 2 to 12 carbon atoms in the carbon chain, for example hydroxybutyric acid, hydroxyvaleric acid, lactic acid, or their derivatives, for example ⁇ -caprolactone or dilactide,
  • aromatic acids making up no more than 50% by weight, based on all acids
  • Hexamethylenediamine and from linear and / or cycloaliphatic bifunctional acids, preferably with 2 to 12 carbon atoms in the alkyl chain or C5 or C ⁇ ring in the case of cycloaliphatic acids, preferably adipic acid, and / or possibly small amounts of branched bifunctional and / or optionally aromatic bifunctional acids such as, for example, terephthalic acid, isophthalic acid, naphthalenedicarboxylic acid and additionally optionally small amounts of higher functional acids, preferably with 2 to 10 carbon atoms, or
  • the ester fraction I) and / or K) is at least 30% by weight, based on the sum of I), K), L) and M), preferably the weight fraction of the ester structures is 30 to 70
  • the proportion of the amide structures is 70 to 30% by weight.
  • the synthetically biodegradable heat-sealing fibers of the second layer partially penetrate the first layer and, during the drying process on the paper machine, envelop the natural fibers in the molten state. The necessary pores for filtration are left free.
  • Filter material made of natural fibers and synthetic fibers in a general, roughly schematic representation.
  • Fig. 1 the formation of the filter material according to the invention is shown in a schematic representation.
  • the formation of a first fiber layer is shown in FIG.
  • Natural fibers 1 and the formation of a second fiber layer of synthetic, biodegradable heat-sealable fibers 2 is shown.
  • the formation of the second Layer with the fibers 2 thus takes place by deposition over the first layer, which is formed by the natural fibers 1.
  • the natural fibers 1 are hatched horizontally to distinguish them, while the synthetic fibers 2 are hatched approximately vertically.
  • Fig. Lb shows how a partial penetration of the two layers is achieved by the described dewatering of the two layers, in particular the second layer with the fibers 2, so that the synthetic fibers 2 get between the natural fibers 1.
  • the partially penetrating layers 1 and 2 are dried and heated in such a way that the synthetic fibers 2 melt and, during re-consolidation, lay around the fibers 1 in such a way that they are at least partially covered.
  • the filter material has thus become heat sealable (Fig. Lc).
  • Fig. 2 shows the basic structure of a paper machine, as it can be used to produce a filter material according to the invention.
  • a suspension "A” is formed from the ground natural fibers and water, and also a suspension “B” from the partially ground synthetic fibers and water.
  • the suspension A is passed onto the screen 5, via the first two dewatering chambers 6, via suitable pipelines and pumping devices, which are not shown in more detail, the water being sucked off through the chambers 6 and the dewatering line.
  • a first fiber layer of natural fibers 1 is formed on the moving sieve 5.
  • the sieve 5 is moved further over the dewatering chambers 7, the second suspension B is fed in, Washing chambers 7 the second layer of synthetic fibers is deposited on the first layer.
  • the drainage takes place via the drainage line.
  • dewatering takes place via the dewatering chambers 8, as a result of which the two layers partially penetrate one another. By setting the drainage accordingly, the penetration can be more or less strong.
  • the material 9 now formed from natural fibers and synthetic fibers is removed from the sieve and fed to drying.
  • This drying can be done in different ways, e.g. by contact drying or through-flow drying.
  • the elements 10 only give a rough schematic indication of corresponding drying elements.
  • drying cylinders 10 are drawn, over which the shaped paper web is dried in the contact process.
  • the heating of the two-layer fiber material causes the synthetic fibers 2 in the mixed layer 9 to melt.
  • the synthetic fibers at least partially envelop the natural fibers and the heat-sealable filter material is rolled up on a roll 11.
  • biodegradable polymer is in the form of granules, it can be removed using the
  • Melt-blown fibers process formed into fibers and still hot adhesive state on a support, such as a paper made of natural fibers.
  • the dried granulate 12 is transported to an extruder 13, in which it is melted and heated to the temperature required for fiber formation.
  • This molten and heated polymer then reaches the MB nozzle 14.
  • This nozzle has a large number of small openings through which the molten polymer is forced and drawn into fibers.
  • These fibers 15 are caught by a strong air stream directly below this nozzle, stretched further, torn into different lengths and placed on a support, e.g. a paper 16, which lies on a suction roller 17, deposited. Since these fibers are still hot and sticky, they stick to the natural fibers of the paper.
  • the material is then rolled up on the winder 18 in the cooled state.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Laminated Bodies (AREA)
  • Filtering Materials (AREA)
  • Paper (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Packages (AREA)
PCT/EP1998/002553 1997-05-13 1998-04-30 Heisssiegelfähiges filtermaterial mit biologisch abbaubaren polymeren WO1998051396A1 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CA 2289739 CA2289739A1 (en) 1997-05-13 1998-04-30 Heat-sealable filter material with biodegradable polymers
EP98924249A EP0981400A1 (de) 1997-05-13 1998-04-30 Heisssiegelfähiges filtermaterial mit biologisch abbaubaren polymeren
AU76511/98A AU743370B2 (en) 1997-05-13 1998-04-30 Heat-sealable filter material with biodegradable polymers
JP54873898A JP2001524873A (ja) 1997-05-13 1998-04-30 生分解性のポリマーを含有するヒートシール性フィルター材料
NO995401A NO995401D0 (no) 1997-05-13 1999-11-04 Varmforseglbart filtermateriale med biologisk nedbrytbare polymerer

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19719807.4 1997-05-13
DE1997119807 DE19719807A1 (de) 1997-05-13 1997-05-13 Heißsiegelfähiges Filtermaterial mit biologisch abbaubaren Polymeren

Publications (1)

Publication Number Publication Date
WO1998051396A1 true WO1998051396A1 (de) 1998-11-19

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JP2000336570A (ja) * 1999-05-28 2000-12-05 Kuraray Co Ltd 生分解性を有するコーヒー抽出用シート材料
US6475618B1 (en) 2001-03-21 2002-11-05 Kimberly-Clark Worldwide, Inc. Compositions for enhanced thermal bonding
EP2730523B1 (en) 2012-11-12 2016-04-06 2266170 Ontario, Inc. Beverage capsule and process and system for making same
US10343838B2 (en) 2012-06-18 2019-07-09 K-Fee System Gmbh Portion capsule and use of same for producing a beverage
US10472165B2 (en) 2012-12-14 2019-11-12 K-Fee System Gmbh Portion capsule and method for producing a beverage by means of a portion capsule
US10669093B2 (en) 2015-02-27 2020-06-02 K-Fee System Gmbh Single serve capsule comprising a filter element connected thereto by sealing
US10737876B2 (en) 2015-07-13 2020-08-11 K-Fee System Gmbh Filter element having a cut-out
US10858176B2 (en) 2010-07-22 2020-12-08 K-Fee System Gmbh Portion capsule having an identifier
US11045035B2 (en) 2015-09-18 2021-06-29 K-Fee System Gmbh Adapter for a single serve capsule
US11084650B2 (en) 2015-06-10 2021-08-10 K-Fee System Gmbh Portion capsule with a three-ply nonwoven fabric

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JP4659226B2 (ja) * 2001-02-01 2011-03-30 大王製紙株式会社 包装用袋用紙
EP1325979A1 (en) * 2002-01-03 2003-07-09 Ahlstrom Windsor Locks LLC Non-heat seal infusion package material
DE10206924B4 (de) * 2002-02-19 2005-12-15 Papierfabrik Schoeller & Hoesch Gmbh & Co. Kg Heisssiegelfähige Filtermaterialien
DE10206926B4 (de) * 2002-02-19 2005-12-15 Papierfabrik Schoeller & Hoesch Gmbh & Co. Kg Heisssiegelfähige Filtermaterialien
DE10231403B3 (de) * 2002-07-11 2004-02-05 Papierfabrik Schoeller & Hoesch Gmbh & Co. Kg Heisssiegelfähiges Filtermaterial
DE10342416A1 (de) 2003-09-13 2005-04-07 Outlast Technologies, Inc., Boulder Filtermaterial
US20080302682A1 (en) * 2007-06-11 2008-12-11 Radi Medical Biodegradable Ab Pouch for tobacco or tobacco substitute
DE102009050447A1 (de) 2009-10-23 2011-04-28 Mahle International Gmbh Filtermaterial
CN102154953B (zh) * 2011-05-10 2012-05-23 衡水国威滤纸有限公司 一种适用于国ⅳ标准汽车燃油滤纸及制备方法
CN102154952A (zh) * 2011-05-10 2011-08-17 张赫廷 一种适用于潮湿环境汽车空气滤纸及制备方法
BE1020895A3 (nl) 2012-07-05 2014-07-01 Papierindustrie Maasmond B V Verbeterd geseald papieren sachet.
JP5852542B2 (ja) 2012-10-10 2016-02-03 綾羽株式会社 炭素繊維強化複合材用織物およびその製造方法
CN105498550A (zh) * 2015-12-10 2016-04-20 华南理工大学 一种无纺布复合纳滤膜及其制备方法与应用
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CN116082835A (zh) * 2023-02-24 2023-05-09 郑州圣莱特空心微珠新材料有限公司 一种低密度尼龙及其制备方法

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JP2000336570A (ja) * 1999-05-28 2000-12-05 Kuraray Co Ltd 生分解性を有するコーヒー抽出用シート材料
US6475618B1 (en) 2001-03-21 2002-11-05 Kimberly-Clark Worldwide, Inc. Compositions for enhanced thermal bonding
US6946195B2 (en) 2001-03-21 2005-09-20 Kimberly-Clark Worldwide, Inc. Compositions for enhanced thermal bonding
US11919703B2 (en) 2010-07-22 2024-03-05 K-Fee System Gmbh Portion capsule having an identifier
US10858177B2 (en) 2010-07-22 2020-12-08 K-Fee System Gmbh Portion capsule having an identifier
US11548722B2 (en) 2010-07-22 2023-01-10 K-Fee System Gmbh Portion capsule having an identifier
US11542094B2 (en) 2010-07-22 2023-01-03 K-Fee System Gmbh Portion capsule having an identifier
US11667465B2 (en) 2010-07-22 2023-06-06 K-Fee System Gmbh Portion capsule having an identifier
US11465830B2 (en) 2010-07-22 2022-10-11 K-Fee System Gmbh Portion capsule having an identifier
US10858176B2 (en) 2010-07-22 2020-12-08 K-Fee System Gmbh Portion capsule having an identifier
US11554910B2 (en) 2010-07-22 2023-01-17 K-Fee System Gmbh Portion capsule having an identifier
US10870531B2 (en) 2010-07-22 2020-12-22 K-Fee System Gmbh Portion capsule having an identifier
US20210086986A1 (en) 2010-07-22 2021-03-25 K-Fee System Gmbh Portion capsule having an identifier
US10994923B2 (en) 2010-07-22 2021-05-04 K-Fee System Gmbh Portion capsule having an identifier
US11820586B2 (en) 2010-07-22 2023-11-21 K-Fee System Gmbh Portion capsule having an identifier
US11465829B2 (en) 2010-07-22 2022-10-11 K-Fee System Gmbh Portion capsule having an identifier
US11230430B2 (en) 2010-07-22 2022-01-25 K-Fee System Gmbh Portion capsule having an identifier
US11254491B2 (en) 2010-07-22 2022-02-22 K-Fee System Gmbh Portion capsule having an identifier
US11312567B2 (en) 2012-06-18 2022-04-26 K-Fee System Gmbh Portion and method for producing a beverage by means of a portion capsule
US11702276B2 (en) 2012-06-18 2023-07-18 K-Fee System Gmbh Portion capsule for preparing a beverage
US10343838B2 (en) 2012-06-18 2019-07-09 K-Fee System Gmbh Portion capsule and use of same for producing a beverage
US9688465B2 (en) 2012-11-12 2017-06-27 2266170 Ontario Inc. Beverage capsule and process and system for making same
EP2730523B1 (en) 2012-11-12 2016-04-06 2266170 Ontario, Inc. Beverage capsule and process and system for making same
US10472165B2 (en) 2012-12-14 2019-11-12 K-Fee System Gmbh Portion capsule and method for producing a beverage by means of a portion capsule
US10669093B2 (en) 2015-02-27 2020-06-02 K-Fee System Gmbh Single serve capsule comprising a filter element connected thereto by sealing
US11084650B2 (en) 2015-06-10 2021-08-10 K-Fee System Gmbh Portion capsule with a three-ply nonwoven fabric
US11498750B2 (en) 2015-07-13 2022-11-15 Gcs German Capsule Solution Gmbh Filter element having a cut-out
US10737876B2 (en) 2015-07-13 2020-08-11 K-Fee System Gmbh Filter element having a cut-out
US11045035B2 (en) 2015-09-18 2021-06-29 K-Fee System Gmbh Adapter for a single serve capsule

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EP0981400A1 (de) 2000-03-01
KR20010012495A (ko) 2001-02-15
TW505722B (en) 2002-10-11
NO995401L (no) 1999-11-04
DE19719807A1 (de) 1998-11-19
AU743370B2 (en) 2002-01-24
JP2001524873A (ja) 2001-12-04
CA2289739A1 (en) 1998-11-19
CN1255072A (zh) 2000-05-31
NO995401D0 (no) 1999-11-04
AU7651198A (en) 1998-12-08

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