WO1998034965B1 - Preparation de macromeres renfermant du vinyle - Google Patents
Preparation de macromeres renfermant du vinyleInfo
- Publication number
- WO1998034965B1 WO1998034965B1 PCT/US1998/002656 US9802656W WO9834965B1 WO 1998034965 B1 WO1998034965 B1 WO 1998034965B1 US 9802656 W US9802656 W US 9802656W WO 9834965 B1 WO9834965 B1 WO 9834965B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- vinyl
- transition metal
- olefin
- ratio
- Prior art date
Links
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims abstract 8
- 150000001336 alkenes Chemical class 0.000 claims abstract 7
- 239000000203 mixture Substances 0.000 claims abstract 7
- 229910052723 transition metal Inorganic materials 0.000 claims abstract 5
- 150000003624 transition metals Chemical class 0.000 claims abstract 5
- 239000003054 catalyst Substances 0.000 claims abstract 4
- 229920000642 polymer Polymers 0.000 claims abstract 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract 3
- UQFJIMBGIHVYIX-UHFFFAOYSA-N 1,2$l^{2}-oxaluminane Chemical compound C1CC[Al]OC1 UQFJIMBGIHVYIX-UHFFFAOYSA-N 0.000 claims abstract 2
- 125000004432 carbon atoms Chemical group C* 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims abstract 2
- 239000005977 Ethylene Substances 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 1
- 239000004711 α-olefin Substances 0.000 claims 1
Abstract
L'invention concerne des compositions polymériques de matière, ces compositions renfermant des chaînes de polymère d'oléfine dont la masse moléculaire moyenne en nombre (Mn) varie entre 400 et 75.000 environ, et dont le rapport entre les groupes vinyles et le nombre total de groupes oléfines est suivant la formule (1) dans laquelle a = -0,24 et b = 0,8, et dans laquelle le nombre total de groupes vinyles pour 1000 atomes de carbone est supérieur ou égal à 8000 Mn. Cette invention concerne également un procédé de préparation de ces produits polymères, ce procédé consistant à mettre un ou plusieurs comonomères d'oléfine en présence d'un système catalyseur renfermant un composé catalyseur de métal de transition et un alumoxane, dans lequel le rapport entre l'aluminium et le métal de transition est au moins égal à 10:1 et inférieur ou égal à 220:1 (Al:Me). Les conditions opératoires de cette invention permettent d'obtenir les caractéristiques de macromères prévues pour la masse moléculaire comme pour l'insaturation vinylique.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98906330.0A EP0958309B2 (fr) | 1997-02-07 | 1998-02-06 | Preparation de macromeres renfermant du vinyle |
ES98906330.0T ES2277381T5 (es) | 1997-02-07 | 1998-02-06 | Preparación de macrómeros que contienen vinilo |
DE69836415.5T DE69836415T3 (de) | 1997-02-07 | 1998-02-06 | Herstellung von vinyl enthaltenden polymeren |
CA002276214A CA2276214A1 (fr) | 1997-02-07 | 1998-02-06 | Preparation de macromeres renfermant du vinyle |
KR10-1999-7007118A KR100503523B1 (ko) | 1997-02-07 | 1998-02-06 | 비닐-함유 거대단량체의 제조방법 |
JP53504998A JP2001511214A (ja) | 1997-02-07 | 1998-02-06 | ビニル含有マクロマーの調製 |
BR9806952A BR9806952A (pt) | 1997-02-07 | 1998-02-06 | Preparação de macrÈmeros contendo vinila. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3732397P | 1997-02-07 | 1997-02-07 | |
US60/037,323 | 1997-02-07 |
Publications (3)
Publication Number | Publication Date |
---|---|
WO1998034965A1 WO1998034965A1 (fr) | 1998-08-13 |
WO1998034965B1 true WO1998034965B1 (fr) | 1998-11-12 |
WO1998034965A9 WO1998034965A9 (fr) | 1999-01-14 |
Family
ID=21893724
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/002656 WO1998034965A1 (fr) | 1997-02-07 | 1998-02-06 | Preparation de macromeres renfermant du vinyle |
Country Status (10)
Country | Link |
---|---|
US (2) | US6444773B1 (fr) |
EP (1) | EP0958309B2 (fr) |
JP (1) | JP2001511214A (fr) |
KR (1) | KR100503523B1 (fr) |
CN (1) | CN1246127A (fr) |
BR (1) | BR9806952A (fr) |
CA (1) | CA2276214A1 (fr) |
DE (1) | DE69836415T3 (fr) |
ES (1) | ES2277381T5 (fr) |
WO (1) | WO1998034965A1 (fr) |
Families Citing this family (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5276757B2 (ja) | 1998-11-02 | 2013-08-28 | ダウ グローバル テクノロジーズ エルエルシー | 剪断減粘性エチレン/α−オレフィンインターポリマーおよびそれらの製造法 |
US6372847B1 (en) | 2000-05-10 | 2002-04-16 | Exxon Mobil Chemical Patents, Inc. | Polyolefin compositions having improved low temperature toughness |
EP1264848B1 (fr) * | 2000-07-26 | 2006-06-21 | Mitsui Chemicals, Inc. | Copolymere d' ethylene et utilisations |
WO2002008306A1 (fr) * | 2000-07-26 | 2002-01-31 | Mitsui Chemicals, Inc. | Polymere et son procede de production |
EP1270603B1 (fr) * | 2001-06-20 | 2014-04-09 | Mitsui Chemicals, Inc. | Catalyseur de polymérisation d'oléfines, procédé de polymérisation d'oléfines |
WO2004046214A2 (fr) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Systeme catalyseur multiple pour la polymerisation d'olefines et polymeres ainsi produits |
CA2465479A1 (fr) * | 2003-04-28 | 2004-10-28 | Tosoh Corporation | Compose a base de polyethylene et methode de production dudit compose |
US9745461B2 (en) | 2005-06-22 | 2017-08-29 | Exxonmobil Chemical Patents Inc. | Vulcanized polymer blends |
US20060293462A1 (en) * | 2005-06-22 | 2006-12-28 | Sunny Jacob | Heterogeneous polymer blend and process of making the same |
US9644092B2 (en) | 2005-06-22 | 2017-05-09 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-situ polymer blend |
US7928164B2 (en) | 2005-06-22 | 2011-04-19 | Exxonmobil Chemical Patents Inc. | Homogeneous polymer blend and process of making the same |
US8022142B2 (en) * | 2008-12-15 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Thermoplastic olefin compositions |
US7951872B2 (en) * | 2005-06-22 | 2011-05-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous polymer blend with continuous elastomeric phase and process of making the same |
CA2717417A1 (fr) | 2008-03-13 | 2009-03-12 | Dow Global Technologies Inc. | Copolymeres blocs ou interconnectes d'ethylene, ramifies, a chaine longue, combines a un autre polymere |
US8283419B2 (en) * | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
US8399725B2 (en) | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
US8283428B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
ES2420117T3 (es) * | 2008-06-20 | 2013-08-22 | Exxonmobil Chemical Patents Inc. | Oligómeros basados en propileno terminado en vinilo superior |
US8093335B2 (en) * | 2008-12-15 | 2012-01-10 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin in-reactor blends and molded articles therefrom |
US8106127B2 (en) * | 2008-12-15 | 2012-01-31 | Exxonmobil Chemical Patents Inc. | Heterogeneous in-reactor polymer blends |
US8318648B2 (en) * | 2009-12-15 | 2012-11-27 | Exxonmobil Research And Engineering Company | Polyether-containing lubricant base stocks and process for making |
US8907034B2 (en) | 2010-09-30 | 2014-12-09 | Dow Global Technologies Llc | Comb architecture olefin block copolymers |
US8785562B2 (en) | 2011-03-25 | 2014-07-22 | Exxonmobil Chemical Patents Inc. | Amphiphilic block polymers prepared by alkene metathesis |
US8455597B2 (en) | 2011-03-25 | 2013-06-04 | Exxonmobil Chemical Patents Inc. | Catalysts and methods of use thereof to produce vinyl terminated polymers |
US8318998B2 (en) | 2011-03-25 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers |
US8841397B2 (en) | 2011-03-25 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
US8669326B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Amine functionalized polyolefin and methods for preparation thereof |
US8501894B2 (en) | 2011-03-25 | 2013-08-06 | Exxonmobil Chemical Patents Inc. | Hydrosilyation of vinyl macromers with metallocenes |
US8623974B2 (en) | 2011-03-25 | 2014-01-07 | Exxonmobil Chemical Patents Inc. | Branched vinyl terminated polymers and methods for production thereof |
US8669330B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Olefin triblock polymers via ring-opening metathesis polymerization |
US8426659B2 (en) | 2011-03-25 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
US8399724B2 (en) | 2011-03-25 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin copolymers and methods to produce thereof |
US8835563B2 (en) | 2011-03-25 | 2014-09-16 | Exxonmobil Chemical Patents Inc. | Block copolymers from silylated vinyl terminated macromers |
US8940839B2 (en) | 2011-03-25 | 2015-01-27 | Exxonmobil Chemical Patents Inc. | Diblock copolymers prepared by cross metathesis |
CN103443139B (zh) * | 2011-03-25 | 2016-10-12 | 埃克森美孚化学专利公司 | 乙烯基封端的高级烯烃聚合物及其生产方法 |
US8604148B2 (en) | 2011-11-29 | 2013-12-10 | Exxonmobil Chemical Patents Inc. | Functionalization of vinyl terminated polymers by ring opening cross metathesis |
US8796376B2 (en) | 2012-03-26 | 2014-08-05 | Exxonmobil Chemical Patents Inc. | Functionalized polymers and oligomers |
WO2014022012A1 (fr) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Polyéthylène terminé par un groupe vinyle avec des ramifications à longue chaîne |
WO2014022013A1 (fr) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Polyalphaoléfines préparées en utilisant des composés de catalyseur salan modifiés |
US9382349B2 (en) * | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
WO2014047542A1 (fr) * | 2012-09-24 | 2014-03-27 | Exxonmobil Chemical Patents Inc. | Production de polyéthylène à terminaison vinylique |
CN104428326A (zh) * | 2012-09-27 | 2015-03-18 | 埃克森美孚化学专利公司 | 乙烯基封端聚合物及其制造方法 |
EP2914636A4 (fr) * | 2012-11-02 | 2016-07-06 | Exxonmobil Chem Patents Inc | Catalyseurs salan supportés |
US9422385B2 (en) | 2013-01-30 | 2016-08-23 | Exxonmobil Chemical Patents Inc. | Polyethylene copolymers with vinyl terminated macromonomers as comonomers |
US9540465B2 (en) | 2013-11-19 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Boron-bridged metallocene catalyst systems and polymers produced therefrom |
US9290589B2 (en) | 2013-12-13 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
US9321856B2 (en) | 2013-12-19 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Process to produce functionalized polymer |
KR101792171B1 (ko) | 2014-12-08 | 2017-10-31 | 주식회사 엘지화학 | 우수한 용융 강도를 갖는 올레핀계 중합체 및 이를 포함하는 필름 |
JP6258496B2 (ja) | 2014-12-09 | 2018-01-10 | 三井化学株式会社 | プロピレン系樹脂組成物 |
US10882932B2 (en) | 2016-10-05 | 2021-01-05 | Exxonmobil Chemical Patents Inc. | Sterically hindered metallocenes, synthesis and use |
US10995166B2 (en) * | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
US20190135960A1 (en) * | 2017-11-07 | 2019-05-09 | Nova Chemicals (International) S.A. | Process to manufacture ethylene interpolymer products |
US11377560B2 (en) | 2018-12-18 | 2022-07-05 | ExxonMobil Technology and Engineering Company | Modified asphalts and methods for producing the same |
Family Cites Families (96)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3350723A (en) | 1965-04-27 | 1967-11-07 | Arthur M Dyer | Water volume control for water closet |
US3989768A (en) | 1971-02-22 | 1976-11-02 | Cpc International Inc. | Chemically joined phase separated thermoplastic graft copolymers |
BE793639A (fr) | 1972-01-03 | 1973-07-03 | Xerox Corp | Revelateur electrostatographique |
JPS52141888A (en) | 1976-05-21 | 1977-11-26 | Nippon I P Rubber Kk | Ethyleneepropylene copolymers rubber |
US4335225A (en) | 1978-06-20 | 1982-06-15 | E. I. Du Pont De Nemours And Company | Elastomeric polypropylene |
DE3127133A1 (de) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
DE3688258T3 (de) | 1985-01-31 | 2001-02-22 | Montell North America Inc | Polypropylen mit freier Langkettenverzweigung, Verfahren zur Herstellung und Verwendung davon. |
DE3508887A1 (de) | 1985-03-13 | 1986-09-25 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von optisch aktiven polyolefinen |
US4808561A (en) | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
US4665208A (en) | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
IL80888A (en) * | 1985-12-12 | 1991-12-12 | Exxon Chemical Patents Inc | Olefin polymerization catalysts,their preparation and use thereof |
US4752597A (en) * | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
DE3752260T2 (de) | 1986-09-24 | 1999-09-02 | Mitsui Chemicals | Verfahren zur Olefinpolymerisation |
JPH0780933B2 (ja) | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | オレフインの重合方法 |
KR910008277B1 (ko) | 1986-12-03 | 1991-10-12 | 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 | 올레핀 중합용 고체촉매 및 그 제조법 |
JP2618384B2 (ja) * | 1986-12-27 | 1997-06-11 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒およびその製法 |
US5391629A (en) | 1987-01-30 | 1995-02-21 | Exxon Chemical Patents Inc. | Block copolymers from ionic catalysts |
PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
JPH0742301B2 (ja) | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | 微粒子状アルミノオキサン、その製法およびその用途 |
DE8703096U1 (fr) | 1987-02-27 | 1987-08-20 | Soeffner, Georg, 8000 Muenchen, De | |
US4769910A (en) | 1987-03-30 | 1988-09-13 | Northern Telecom Limited | Cutting tool for cylindrical articles |
JP2538588B2 (ja) | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒の製法 |
US5206199A (en) | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
DE3742934A1 (de) | 1987-12-18 | 1989-06-29 | Hoechst Ag | Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung |
US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
US4871705A (en) | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
US4892851A (en) | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
US5155080A (en) | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
DE68919156T3 (de) | 1988-08-05 | 2002-08-14 | Fina Technology | Verfahren zur Herstellung grosser symmetrischer Polymerteilchen. |
US5091352A (en) | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
US4999403A (en) | 1988-10-28 | 1991-03-12 | Exxon Chemical Patents Inc. | Graft polymers of functionalized ethylene-alpha-olefin copolymer with polypropylene, methods of preparation, and use in polypropylene compositions |
EP0366411A3 (fr) | 1988-10-28 | 1991-04-24 | Exxon Chemical Patents Inc. | Polymères d'éthylène-propylène-diène greffés par du propylène, leur méthode de préparation et leur usage dans des compositions de polypropylène |
US4908463A (en) | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
US5047485A (en) | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
US5103031A (en) | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
DE3907964A1 (de) | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
US4968827A (en) | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
US5763549A (en) | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
CA2027123C (fr) | 1989-10-30 | 2001-09-04 | Michael J. Elder | Catalyseurs a base de metallocene pour la polymerisation d'olefines |
US5087809A (en) | 1990-11-26 | 1992-02-11 | Eastman Kodak Company | Spectrally selective dithering and color filter mask for increased image sensor blue sensitivity |
ES2072598T3 (es) | 1990-01-02 | 1995-07-16 | Exxon Chemical Patents Inc | Catalizadores ionicos de metaloceno soportados para la polimerizacion de olefinas. |
GB2241244B (en) | 1990-02-22 | 1994-07-06 | James C W Chien | Thermoplastic elastomers |
EP0476148B1 (fr) | 1990-04-09 | 1995-08-23 | MITSUI TOATSU CHEMICALS, Inc. | Copolymere de propylene |
WO1991017194A1 (fr) | 1990-05-07 | 1991-11-14 | Exxon Chemical Patents Inc. | COPOLYMERES INSATURES D'α-OLEFINE ET PROCEDE DE PREPARATION DE CES DERNIERS |
EP0670334A3 (fr) | 1990-06-22 | 1995-09-13 | Exxon Chemical Patents Inc. | Catalyseurs à base de métallocène monocyclopentadienylique dépourvus d'aluminium destinées à la polymérisation d'oléfines |
US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
CA2066247C (fr) | 1990-07-24 | 1998-09-15 | Ryuichi Sugimoto | Catalyseur de polymerisation pour .alpha.-olefines et methode pour preparer des poly-.alpha.-olefines a l'aide de ce catalyseur |
US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
JP3076619B2 (ja) | 1991-05-14 | 2000-08-14 | 三井化学株式会社 | ブロック共重合体の製造方法 |
DE4120009A1 (de) | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
TW300901B (fr) | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
DE4130299A1 (de) | 1991-09-12 | 1993-03-18 | Basf Ag | Verfahren zur herstellung von polypropylen unter hochdruck |
DE59210001D1 (de) | 1991-10-15 | 2005-02-17 | Basell Polyolefine Gmbh | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
ES2109473T3 (es) | 1991-12-13 | 1998-01-16 | Exxon Chemical Patents Inc | Copolimeros de etileno/alfa-olefinas superiores. |
AU3809893A (en) | 1992-03-16 | 1993-10-21 | Exxon Chemical Patents Inc. | Ionic catalyst for the production of poly-alpha-olefins of controlled tacticity |
US5329032A (en) | 1992-03-18 | 1994-07-12 | Akzo Chemicals Inc. | Polymethylaluminoxane of enhanced solution stability |
US5310794A (en) | 1992-03-31 | 1994-05-10 | Himont Incorporated | Theromoplastic blends containing graft copolymers of polyacrylates as impact modifiers |
ES2126647T3 (es) | 1992-04-20 | 1999-04-01 | Exxon Chemical Patents Inc | Copolimeros de etileno/olefinas ramificadas. |
EP0578838A1 (fr) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Catalysateur de polymérisation d'oléfines, procédé pour sa préparation et son utilisation |
US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
US5434115A (en) | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
EP0572034A2 (fr) | 1992-05-29 | 1993-12-01 | Idemitsu Kosan Company Limited | Copolymère éthylénique et composition de copolymères éthyléniques |
DE69224184T2 (de) | 1992-06-13 | 1999-06-02 | Targor Gmbh | Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl |
US5710222A (en) | 1992-06-22 | 1998-01-20 | Fina Technology, Inc. | Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems |
JPH07509752A (ja) | 1992-08-05 | 1995-10-26 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の担持されたイオン遷移金属触媒 |
US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
WO1994007930A1 (fr) | 1992-09-29 | 1994-04-14 | Exxon Chemical Patents Inc. | Polymeres a chaines ramifiees longues et leur procede de fabrication |
KR100287389B1 (ko) | 1992-10-02 | 2001-04-16 | 그래햄 이. 테일러 | 올레핀 중합반응을 위한 지지된 균일한 촉매(supported homogeneous catalyst complexes for olefin polymerization) |
US5608009A (en) | 1992-10-28 | 1997-03-04 | Idemitsu Kosan Co., Ltd. | Olefin copolymer and process for preparing same |
US5939346A (en) | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
WO1994019381A1 (fr) * | 1993-02-22 | 1994-09-01 | Idemitsu Kosan Co., Ltd. | Copolymere d'ethylene, composition de resine thermoplastique le contenant et procede de production de ce copolymere |
US5414027A (en) | 1993-07-15 | 1995-05-09 | Himont Incorporated | High melt strength, propylene polymer, process for making it, and use thereof |
WO1995011931A1 (fr) | 1993-10-26 | 1995-05-04 | Idemitsu Kosan Co., Ltd. | Macromonomere ethylenique ramifie et polymere produit a partir de ce dernier |
US5594080A (en) | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
US5539056A (en) | 1995-01-31 | 1996-07-23 | Exxon Chemical Patents Inc. | Thermoplastic elastomers |
DE69620760T2 (de) | 1995-07-06 | 2002-12-05 | Exxonmobil Chem Patents Inc | Verfahren zur herstellung von polymerisierten geträgerten metallocenkatalysatorsystemen |
US6084030A (en) | 1995-08-04 | 2000-07-04 | Dsm Copolymer, Inc. | Branched polymers with polyolefin arms |
EP0791626B1 (fr) | 1995-09-11 | 2004-06-09 | Mitsui Chemicals, Inc. | Compositions de resines et leurs utilisations |
US5914372A (en) | 1997-01-23 | 1999-06-22 | Jsr Corporation | Ethylene copolymer rubber composition |
US6184327B1 (en) | 1997-12-10 | 2001-02-06 | Exxon Chemical Patents, Inc. | Elastomeric propylene polymers |
-
1998
- 1998-02-06 EP EP98906330.0A patent/EP0958309B2/fr not_active Expired - Lifetime
- 1998-02-06 JP JP53504998A patent/JP2001511214A/ja not_active Ceased
- 1998-02-06 DE DE69836415.5T patent/DE69836415T3/de not_active Expired - Lifetime
- 1998-02-06 WO PCT/US1998/002656 patent/WO1998034965A1/fr active IP Right Grant
- 1998-02-06 CN CN98802127A patent/CN1246127A/zh active Pending
- 1998-02-06 KR KR10-1999-7007118A patent/KR100503523B1/ko not_active IP Right Cessation
- 1998-02-06 ES ES98906330.0T patent/ES2277381T5/es not_active Expired - Lifetime
- 1998-02-06 BR BR9806952A patent/BR9806952A/pt not_active IP Right Cessation
- 1998-02-06 CA CA002276214A patent/CA2276214A1/fr not_active Abandoned
-
2000
- 2000-03-08 US US09/521,043 patent/US6444773B1/en not_active Expired - Lifetime
-
2001
- 2001-11-06 US US09/992,768 patent/US6555635B2/en not_active Expired - Lifetime
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO1998034965B1 (fr) | Preparation de macromeres renfermant du vinyle | |
CA2018666C (fr) | Compositions a base de resine de polypropylene a syndiotacticite elevee; methode de preparation | |
CA1281843C (fr) | Produits intermediaires a base de copolymeres d'ethylene et d'alpha-olefines defaible masse moleculaire | |
US5241014A (en) | Process for the production of largely amorphous polyalphaolefins with a narrow molecular weight distribution | |
NZ332760A (en) | Polyolefin composition with molecular weight maximum occurring in that part of the composition that has the highest comonomer content | |
KR910005866B1 (ko) | 에틸렌-프로필렌 엘라스토머 조성물 | |
CA2005537A1 (fr) | Compositions a base de polypropylene possedant une bonne transparence et une meilleure resistance aux chocs | |
EP0727446A4 (fr) | Macromonomere ethylenique ramifie et polymere produit a partir de ce dernier | |
CA2206944A1 (fr) | Procede de polymerisation en solution a haute temperature | |
WO2003040195B1 (fr) | Catalyseurs sur support utilises pour produire des polymeres | |
BR9806952A (pt) | Preparação de macrÈmeros contendo vinila. | |
NO934729L (no) | Fremgangsmåte for fremstilling av en blanding som inneholder etylenpolymerer, blanding som inneholder etylenpolymerer, og anvendelse av blandingen | |
CA2130009A1 (fr) | Catalyseur et methode de polymerisation d'olefines pour la preparation de copolymeres a sequence de polypropylene et de propylene | |
KR950703587A (ko) | 비결정성 올레핀 중합체, 공중합체, 이들의 유도체 및 제조방법(amorphous olefin polymers, copolymers, methods of preparation and derivatives thereof) | |
BR0108150A (pt) | Copolìmeros de impacto de propileno | |
KR950003371A (ko) | 광택 감소된, 조사된 올레핀 중합체 물질 및 비조사된 올레핀 중합체 물질의 조성물 | |
RU2001117824A (ru) | Блоксополимеры на основе винилциклогексана | |
CA2316880A1 (fr) | Polymeres d'ethylene a densite moyenne, leur procede de preparation et agents de migration de chaine contenant des groupes carbonyle mis en oeuvre dans ce procede | |
CA2061963A1 (fr) | Preparation de polymeres olefiniques | |
US4622375A (en) | Amorphous ethylene/propylene polymers | |
DE60023011D1 (de) | Niederwertige frühübergangsmetallkatalysatoren für die polymerisation von olefinen enthaltend eine cyclopentadienylgruppe | |
AU2240999A (en) | Improved olefin polymerization process | |
EP0490353A2 (fr) | Composition de polymères résistant au choc | |
EP0603724B1 (fr) | Elastomères thermoplastiques et leur procédé de préparation | |
EP1124900A1 (fr) | Compositions polymeres elastomeres alpha-olefiniques d'ethylene avec une aptitude a l'extrusion amelioree |