WO1998005504A1 - Procede d'enregistrement par jet d'encre au moyen de deux liquides - Google Patents
Procede d'enregistrement par jet d'encre au moyen de deux liquides Download PDFInfo
- Publication number
- WO1998005504A1 WO1998005504A1 PCT/JP1997/002683 JP9702683W WO9805504A1 WO 1998005504 A1 WO1998005504 A1 WO 1998005504A1 JP 9702683 W JP9702683 W JP 9702683W WO 9805504 A1 WO9805504 A1 WO 9805504A1
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- liquid
- ink composition
- intermediate transfer
- recording medium
- ink
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/0057—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material where an intermediate transfer member receives the ink before transferring it on the printing material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/005—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
- B41J2/01—Ink jet
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
- B41M5/0017—Application of ink-fixing material, e.g. mordant, precipitating agent, on the substrate prior to printing, e.g. by ink-jet printing, coating or spraying
Definitions
- the present invention relates to an ink jet recording method for performing printing by adhering a first liquid and an ink composition to a recording medium, and a recording apparatus used for the method.
- the ink jet recording method is a printing method in which a small droplet of an ink composition is made to fly and adhere to a recording medium such as paper to perform printing. This method has a feature that high-resolution and high-quality images can be printed at a high speed with a relatively inexpensive apparatus.
- the ink composition usually used for ink jet recording is mainly composed of water as a main component, and further contains a coloring component and a wetting agent such as glycerin for the purpose of preventing clogging.
- an ink jet recording method a method has recently been proposed in which a polyvalent metal salt solution is applied to a recording medium and then an ink composition containing a dye having at least one carboxyl group is applied (for example, Japanese Patent Application Laid-Open No. 5-202328 is disclosed. According to this method, an insoluble complex is formed from a polyvalent metal ion and a dye, and the presence of the complex is capable of obtaining high-quality images having water resistance and no color bleed.
- the present inventors have recently proposed that in such an ink jet recording method for printing two liquids, a good image can be obtained by attaching the first liquid to a recording medium via an intermediate transfer medium. Was obtained.
- the present invention is based on this finding.
- an object of the present invention is to provide an ink jet recording method for printing two liquids capable of forming a good image.
- the ink jet recording method according to the present invention comprises:
- An ink jet recording method in which a first liquid containing a reactant and an ink substance are attached to a recording medium and printing is performed,
- FIG. 1 shows an ink jet recording apparatus for carrying out the ink jet recording method according to the present invention, in which a first liquid is once adhered to the surface of an intermediate transfer drum 1 by a first liquid adhering means 2, and the first liquid is Thereafter, the image is transferred to the recording medium 3.
- the ink jet recording method includes a step of temporarily adhering a first liquid to an intermediate transfer medium, and then transferring the first liquid on the intermediate transfer medium to the recording medium.
- the present invention is advantageous in that a good image can be realized with a smaller amount of the first liquid as compared with a mode in which the first liquid is directly attached to a recording medium. Specifically, it is possible to reduce the amount of the first liquid used to about 1 Z 2 to 1/10 with respect to the amount of the ink composition used. Further, in the method according to the present invention, it is possible to apply the first liquid thinly and uniformly on the surface of the recording medium, so that wrinkling and curling of the recording medium can be prevented. Also, the occurrence of printing unevenness is suppressed.
- the amount of the reactant in the first liquid that may cause clogging of the nozzle by the precipitate can be reduced, and the surface tension of the first liquid can be increased. Therefore, it is advantageous in that the physical properties of the first liquid can be made suitable for ejection by the ink jet recording method.
- the attachment of the first liquid to the intermediate transfer medium may be performed by an ink jet recording method in which the droplets are formed, and the droplets are made to fly and adhere to the intermediate transfer medium. It may be performed by coating on a transfer medium.
- the former method since the first liquid is applied only to a limited area where the ink is applied, printing can be efficiently performed with a small amount of the first liquid, and wrinkling and curling of the recording medium can be effectively prevented.
- a certain degree of accuracy is required for the position where both the first liquid and the ink composition are attached.
- the first liquid is strong enough to adhere thinly and uniformly only to the recording medium surface, and the wrinkles of the recording medium are strong. It is necessary from the viewpoint of preventing curling.
- good printing power can be realized by contact between the first liquid and the ink composition. Sand That is, when the first liquid and the ink material come into contact with each other, the reactant in the first liquid destroys the dispersion state of the colorant and the like in the ink composition and causes the colorant component and the like to aggregate.
- the aggregates adhere to the recording medium and realize printing with high color, bleeding, and unevenness. Further, in a color image, there is an advantage that uneven color mixing in a boundary region of different colors, that is, color bleeding can be effectively prevented. Therefore, even in the present invention, the first liquid is brought into contact with the ink. Specifically, the step of recording an image by discharging droplets of the ink composition on a recording medium is performed after the step of transferring the first liquid adhered on the intermediate transfer medium to the recording medium, The step of recording an image by ejecting ink droplets onto a recording medium is performed before the step of transferring the first liquid adhering on the intermediate transfer medium to the recording medium.
- FIG. 1 shows a recording apparatus according to the present invention, which includes an intermediate transfer drum 1 as an intermediate transfer medium,
- the intermediate transfer drum 1 is configured to be rotated by driving means (not shown), and the surface thereof can be pressed against the recording medium 3.
- the first liquid adhering means 2 is an ink jet recording head, which forms droplets of the first liquid and causes them to fly and adhere to the intermediate transfer drum 1. Let The first liquid adhering to the intermediate transfer drum 1 is transferred according to the rotation of the intermediate transfer drum 1, and is transferred to the recording medium 3 due to the pressure contact between the recording medium 3 and the intermediate transfer drum 1.
- the printing is performed so that the printing position of the ink composition by the ink jet recording means described later matches the adhesion position of the first liquid transferred from the intermediate transfer medium to the recording medium 3 on the recording medium 3. Force controlled force preferred.
- the first liquid applying means 2 is means for applying the first liquid to the surface of the intermediate transfer drum 1.
- the adhesion according to this embodiment is performed by pressing a water-absorbing porous body such as a sponge impregnated with the first liquid onto the intermediate transfer drum 1.
- the first liquid is applied to the intermediate transfer drum 1 uniformly or non-uniformly by spraying, and the first liquid is dropped on the intermediate transfer drum 1 and then regulated with a blade. May be.
- the first liquid adhering to the intermediate transfer drum 1 is transported according to the rotation of the intermediate transfer drum 1, and is transferred to the recording medium 3 when the recording medium 3 is pressed against the intermediate transfer drum 1.
- the surface of the intermediate transfer drum 1 preferably has a non-liquid-absorbing property in order to enhance the transfer efficiency on the recording medium
- the surface of the intermediate transfer drum 1 is made of polyethylene, polypropylene, polystyrene, polyester, polyvinyl chloride, or the like. It is preferably formed of a water-insoluble resin, a metal such as Fe, Ni, Si, Al, Sn, or Zn or an oxide thereof, or an alloy such as brass or stainless steel.
- the surface of the intermediate transfer drum 1 on which the transfer of the first liquid to the recording medium 3 has been completed is cleaned by the cleaning means 4.
- an ink jet recording head When recording with the ink composition after attaching the first liquid to the recording medium 3, an ink jet recording head is provided at a position 5a in the figure. On the other hand, when recording with the ink composition is performed before the first liquid is applied to the recording medium 3, an ink jet recording head is provided at a position 5b in the drawing.
- These ink jet recording heads may be the same as ordinary ink jet recording heads.
- the first liquid used in the present invention contains a reactant having a property of destroying the dispersion state of the colorant and the like in the ink composition as described above and aggregating the colorant component and the like.
- Examples of the first liquid used in the present invention include those containing a polyvalent metal salt, a polyamine, a polyamine derivative, an acidic liquid, a cationic surfactant, or the like as a reactant.
- the reactant is a polyvalent metal salt
- preferred examples thereof include divalent or higher polyvalent gold. It is composed of a group ion and an anion bonded to these polyvalent metal ions, and includes salts soluble in water.
- Specific examples of polyvalent metal ions include divalent metal ions such as Ca ⁇ + , Cu 2+ , Ni 2+ , Mg 2+ , and ZB a ⁇ "A 13 + , Fe 3+ , and Cr Sl Anions include C 1—, NO q— , I—, Br 1, C 10—, and CH 3 COO—.
- a metal salt composed of Ca 2+ or Mg 2+ gives favorable results from the two viewpoints of the pH of the first liquid and the quality of the obtained printed matter.
- the concentration of these polyvalent metal salts in the first liquid may be appropriately determined within a range in which the effect of preventing printing quality and clogging can be obtained, but is preferably about 0.1 to 40% by weight, more preferably. It is about 5 to 25% by weight.
- the polyvalent metal salt contained in the first liquid is composed of a divalent or higher polyvalent metal ion and an ion or nitrate ion binding to the polyvalent metal ion. , It is soluble in water.
- the carboxylate ion is preferably a saturated fat having 1 to 6 carbon atoms! ⁇ Derived from monocarboxylic acid or carbocyclic monocarboxylic acid having 7 to 11 carbon atoms.
- Preferred examples of the saturated aliphatic monocarboxylic acid having 1 to 6 carbon atoms include formic acid, acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, isovaleric acid, pivalic acid, and hexanoic acid. Particularly, formic acid and acetic acid are preferred.
- Hydrogen atoms on the saturated fatty acid hydride group of the monocarboxylic acid may be substituted with a hydroxyl group, and a preferred example of such a carboxylic acid is lactic acid.
- a preferred example of such a carboxylic acid is lactic acid.
- preferred examples of the carbon-monocarboxylic acid having 6 to 10 carbon atoms include benzoic acid and naphthoic acid, and more preferably benzoic acid.
- Polyallylamine and polyallylamine derivatives preferably used as a reactant are cationic polymers which are soluble in water and positively charged in water.
- cationic polymers which are soluble in water and positively charged in water.
- formulas (II), (III), and (IV) are mentioned.
- X— represents chloride ion, bromide ion, iodide ion, nitrate ion, phosphate ion, sulfate ion, acetate ion, etc.
- the content of these polyallylamine and polyallylamine derivatives is preferably 0.5 to 10% by weight of the reaction solution.
- the first liquid may contain a wetting agent comprising a high-boiling organic solvent.
- High boiling organic solvents prevent head clogging by preventing the first solution from drying.
- Preferred examples of the high-boiling organic solvent include ethylene glycol, diethylene glycol, triethylene glycol
- Polyhydric alcohols such as coal, polyethylene glycol, polypropylene glycol, propylene glycol, butylene glycol, 1,2,6-hexanetriol, thioglycol, hekinlen glycol, glycerin, trimethylolethane, and trimethylolpropane; Ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, dimethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, etc.
- the amount of the high-boiling organic solvent to be added is not particularly limited, but is preferably about 0.5 to 40% by weight, and more preferably about 2 to 20% by weight.
- the first liquid may contain a low-boiling organic solvent.
- the low-boiling organic solvent include methanol, ethanol, n-propyl alcohol, is 0-propyl alcohol, n-butanol, sec-butanol, tert-butanol, iso-butanol, n —Pen-Yu Nol.
- a monohydric alcohol is preferable.
- Low boiling organic solvents have the effect of shortening the drying time of the ink.
- the amount of the low-boiling organic solvent added is preferably 0.5 to 10% by weight, more preferably 1.5 to 6% by weight.
- the first liquid may include a penetrant.
- the penetrant include various surfactants such as anionic surfactants, cationic surfactants and amphoteric surfactants, alcohols such as methanol, ethanol and iso-propyl alcohol, ethylene glycol monomethyl ether and diethylene glycol monoethyl ether.
- alcohols such as methanol, ethanol and iso-propyl alcohol
- ethylene glycol monomethyl ether and diethylene glycol monoethyl ether.
- One ter, diethylene glycol monobutyl ether, triethylene glycol And lower alkyl ethers of polyhydric alcohols such as alcohol monobutyl ether, propylene glycol monobutyl ether, and dipyrene pyrene glycol monobutyl ether.
- the first liquid may be colored by adding a colorant described in the section of the ink composition described later, and may have the function of the ink composition.
- the ink composition means a black ink composition when performing monochrome printing, and a color ink composition when performing color printing, specifically, a yellow ink composition or a magenta ink. Composition, and cyan ink composition, and in some cases, black ink composition.
- the ink composition used in the present invention contains at least a colorant and water.
- the colorant contained in the ink composition used in the present invention may be a dye or a pigment, but the colorant may be misaligned.
- the dispersed pigment is more advantageous than the dye dissolved in the aqueous medium.
- dyes that are usually used for ink jet recording, such as direct dyes, acid dyes, food dyes, basic dyes, reactive dyes, materials, vat dyes, soluble vat dyes, and reaction materials are used as dyes. can do.
- inorganic pigments and organic pigments can be used without any particular limitation.
- the inorganic pigment in addition to titanium oxide and iron oxide, black carbon black produced by a known method such as a contact method, a furnace method, or a thermal method can be used.
- Organic pigments include azo pigments (including azo lakes, insoluble azo pigments, condensed azo pigments, chelate azo pigments, etc.) and polycyclic pigments (for example, phthalocyanine pigments, perylene pigments, perinone pigments, anthraquinone pigments) , Kinak Ridone pigments, dioxazine pigments, thioindigo pigments, isoindolinone pigments, quinoflurone pigments, etc., dye chelates (eg, basic dye chelates, acidic dye chelates, etc.), nitro pigments, nitroso pigments, aniline black, etc. Can be used.
- azo pigments including azo lakes, insoluble azo pigments, condensed azo pigments, chelate azo pigments, etc.
- polycyclic pigments for example, phthalocyanine pigments, perylene pigments, perinone pigments, anthraquinone pigments
- these pigments are preferably added to the ink as a pigment dispersion obtained by dispersing the pigment in an aqueous medium with a dispersant or a surfactant.
- a dispersant commonly used for preparing a pigment dispersion for example, a high molecular weight I ⁇ can be used.
- the dispersant or surfactant include polyacrylic acid, polymethacrylic acid, acrylic acid-acrylonitrile copolymer, vinyl acetate-acrylic acid ester copolymer, acrylic acid monoacrylate alkyl ester copolymer, Styrene-acrylic acid copolymer, styrene-methacrylic acid ⁇ polymer, styrene-acrylic acid-acrylic acid alkyl ester copolymer, styrene-methacrylic acid-acrylic acid alkyl ester copolymer, styrene- ⁇ -methylstyrene-acrylic acid Copolymer, styrene- ⁇ -methylstyrene-acrylic acid-acrylic acid alkyl ester copolymer, styrene-maleic acid copolymer, vinylnaphthalene-maleic acid copolymer, vinyl acetate-ethylene copolymer, vinyl acetate-vinyl a
- these copolymers have a weight average molecular weight.
- a force of about 3,000 to 5,000 is preferred, more preferably about 5,000 to about 3,000, and most preferably about 7000 to 5,000. It is about 0.
- the dispersant and surfactant contained in the pigment dispersion will also function as the dispersant and surfactant of the ink composition. It is preferably about 0.5 to 25% by weight, more preferably about 2 to 15% by weight.
- the ink composition used in the present invention can contain a dispersant or a surfactant.
- a dispersant or a surfactant examples include various surfactants described in the description of the resin emulsion.
- the ink composition is strongly preferred because it comprises a resin emulsion.
- the resin emulsion means an emulsion in which the continuous phase is water and the dispersed phase is the following resin component.
- Resin components of the dispersed phase include acrylic resin, vinyl acetate resin, styrene-butadiene resin, vinyl chloride resin, acryl-styrene resin, butadiene resin, styrene resin, cross-linked acrylic resin, cross-linked styrene resin, Benzoguanamine resin, phenol resin, silicone resin, epoxy resin, and the like.
- the resin is preferably a polymer having both a hydrophilic part and a hydrophobic part.
- the particle size of these resin components is not particularly limited as long as it forms an emulsion, but is preferably about 150 nm or less, more preferably about 5 to about L O nm.
- resin emulsions can be obtained by dispersion polymerization of resin monomers in water, optionally with a surfactant.
- a surfactant for example, an emulsion of an acrylic resin or a styrene-acrylic resin can be obtained by dispersing and polymerizing (meth) acrylic acid ester or (meth) acrylic acid ester and styrene together with a surfactant in water. be able to.
- the mixing ratio of the resin component and the surfactant is usually preferably about 10: 1 to 5: 1.
- Surfactant When the amount of used is within the above-mentioned range, the c- surfactant capable of obtaining better water resistance and penetrability of the ink is not particularly limited.
- the ratio of the resin to water as a component is preferably in the range of 60 to 400 parts by weight of water, preferably 100 to 200 parts by weight, based on 100 parts by weight of the resin.
- the ink used in the present invention preferably contains a resin emulsion such that the resin component is 0.1 to 40% by weight of the ink, more preferably 1 to 25% by weight.
- Resin emulsion can penetrate colored ⁇ by interaction with polyvalent metal ions. It has the effect of suppressing and further facilitating fixing to the recording medium. Further, depending on the type of the resin emulsion, a film is formed on the recording medium, which also has the effect of improving the abrasion resistance of the printed matter.
- the ink composition preferably comprises a thermoplastic resin in the form of a resin emulsion.
- the thermoplastic resin has a softening temperature of 50 ° C. to 250 ° C., preferably 60 ° C. to 200 ° C.
- MFT film formation temperatures
- the water-insoluble thermoplastic resin include polyacrylic acid, polymethacrylic acid, polymethacrylic acid ester, polyethylacrylic acid, styrene-butadiene copolymer, polybutenegen, and acrylonitrile- Butadiene copolymer, octaprene copolymer, fluororesin, vinylidene fluoride, polyolefin resin, cellulose, styrene-acrylic acid copolymer, styrene-methacrylic polymer, polystyrene, styrene-acrylamide copolymer Polymer, polyisobutyl acrylate, polyacrylonitrile, polyvinyl acetate, polyvinyl acetal, polyamide, rosin resin, polyethylene,
- thermoplastic resin examples include polyethylene wax and montan. Waxes, alcohol waxes, synthetic oxidized waxes, ⁇ -olefin-maleic anhydride copolymers, animal and plant-based waxes such as carnaubax, lanolin, paraffin wax, microcrystalline wax, and the like.
- resin emulsions known resin emulsions can be used.
- Japanese Patent Publication No. Sho 62-142 Japanese Patent Laid-Open Publication No. Hei 3-56573, Japanese Patent Laid-Open Publication No. Hei 3-7967 No. 8, JP-A-3-16006, JP-A-4-184462, etc., can be used as they are.
- the ink composition preferably contains an alginic acid derivative.
- alginic acid derivative include alkali metal alginates (eg, sodium salt, potassium salt), organic alginates (eg, triethanolamine salt), and ammonium alginate.
- the amount of the alginic acid derivative to be added to the ink fiber is preferably 0.01 to 1% by weight, and more preferably about 0.05 to 0.5% by weight.
- the presence of t ⁇ is present in the first liquid, but in particular, the polyvalent metal salt reacts with the alginic acid derivative in the ink composition to form a coloring agent. This is considered to be due to the fact that the dispersion state of the colorant is changed, and the fixation of the colorant to the recording medium is promoted.
- the ink composition used in the present invention may contain an inorganic oxide colloid.
- Preferred examples of the inorganic oxide colloid include colloidal silica and alumina colloid. These are generally S i 0.
- a colloids solution containing dispersed ultrafine particles such as A 1 2 0 3 in water or an organic solvent.
- the free machine colloidal oxide which is commercially available, the dispersion medium is water, methanol, 2-propanol, n- propanol, xylene and the like, the particle size of the S i 0 2, A 1 2 0 3 or the like of the particles 5 What is 110 O nm is generally strong.
- the pH of the inorganic oxide colloid solution is often not adjusted to be in the neutral region, but is adjusted to ⁇ 1 ⁇ 2 or 1 ⁇ 2. This is, This is because the inorganic oxide colloid has a stable dispersion region on the acidic side or the alkaline side, and when added to the ink composition, the pH of the inorganic oxide colloid stable dispersion region and the ink Must be added in consideration of the pH of the solution.
- the inorganic acid colloid colloid in the ink composition in an amount of 0.1 to 15% by weight, and two or more kinds can be added.
- the ink composition preferably comprises an organic solvent.
- the organic solvent is preferably a low boiling organic solvent, and preferred examples thereof include methanol, ethanol, n-propyl alcohol, iso-propyl alcohol, n-butanol, sec-butanol, tert-butanol, iso-butanol, n-pentanol and the like. Particularly, a monohydric alcohol is preferable. Low boiling organic solvents have the effect of shortening the drying time of the ink.
- the ink composition used in the present invention preferably further contains a wetting agent comprising a high-boiling organic solvent.
- a wetting agent comprising a high-boiling organic solvent.
- the high-boiling organic solvent include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, polypropylene glycol, propylene glycol, butylene glycol, 1,2,6-hexanetriol, and thioglycol.
- Polyhydric alcohols such as xylene glycol, glycerin, trimethylolethane, trimethylolpropane, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether , Triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, triethylene glycol Alkyl ethers of polyhydric alcohols such as Nopuchiru ether, urea, 2-pyrrolidone, N- methyl one 2 - pyrrolidone, 1, 3 - dimethyl one 2-imidazolidinone, etc. triethanolamine ⁇ Min and the like.
- the addition amount of these wetting agents is preferably 0.5 to 40% by weight of the ink, more preferably 2 to 20% by weight.
- the amount of the low-boiling organic solvent added is preferably 0.5 to 10% by weight of the ink, more preferably 1.5 to 6% by weight.
- the ink composition Preferably comprises sugar.
- saccharides include monosaccharides, disaccharides, oligosaccharides (including trisaccharides and tetrasaccharides) and polysaccharides, preferably glucose, mannose, fructose, ribose, xylose, arabinose, galactose, Aldonic acid, glucosyl, (sorbit), maltose, cellobiose, lactose, sucrose, trehalose, maltotriose, and the like.
- the polysaccharide means a sugar in a broad sense, and is used to include a substance which is widely present in nature, such as alginic acid, -cyclodextrin, and cellulose.
- Examples of the derivatives of these saccharides include reducing sugars of the above-mentioned saccharides (for example, sugar alcohols (general formula: HOCH 2 (CHOH) n CH 2 OH, where n represents an integer of 2 to 5)).
- Oxidized sugars eg, aldonic acid, peronic acid, etc.
- amino acids e.g., amino acids, thiosaccharides, etc.
- sugar alcohols e.g, aldonic acid, peronic acid, etc.
- Particularly preferred are sugar alcohols, and specific examples include maltitol, sorbitol and the like.
- the content of these saccharides is suitably in the range of 0.1 to 40% by weight, preferably 0.5 to 30% by weight of the ink.
- pH adjusters preservatives, fungicides, and the like may be added as necessary.
- the first liquid was obtained by mixing the above components with the remaining amount of ion-exchanged water.
- Carbon black MA 7 (Mitsubishi Chemical Corporation) 5% by weight
- the carbon black and the mixture were mixed and dispersed in a sand mill (Yaskawa Seisakusho) together with glass beads (1.7 mm in diameter, 1.5 times the weight (weight) of the mixture) for 2 hours. Thereafter, the glass beads were removed, other additives were added, and the mixture was stirred at room temperature for 20 minutes. The mixture was filtered through a 5 / zm membrane filter to obtain an ink for ink jet recording.
- cyan ink composition magenta ink A yellow ink composition was prepared according to the above black ink production method.
- Printing in the examples was basically performed as follows. Using the inkjet head used in the MJ 700 V2 C printer (manufactured by Seiko Epson Corporation), the first liquid was sprayed onto the PET film at a density of 360 dpi at a discharge rate of 0.028 / (101 This PET film was pressed against the recording paper, and the reaction solution was transferred to a printing paper.After that, the reaction solution was transferred to the printing paper using a head also used in the MJ 700V2C. The above black ink and color ink were printed at a density of 360 dpi and a discharge amount of 0.06 / zg / dot.
- the first liquid was used in the same ink jet head as above. Was applied directly on the recording medium at 0.02 gZd 0 t or 0.06 g / dot, and then printing was performed on the recording medium in the same manner as described above. Print evaluation test
- Printing was performed on two sheets of recording paper, Xerox 4024 3R 721 (manufactured by Xerox Corporation) and Xerox R (manufactured by Xerox Corporation, recycled paper). After printing the reaction liquid at 100% duty on the recording medium, dots were printed with the ink composition.
- the roundness due to the ink composition was defined as 4 rSZL2 (where S is the dot area and L is the circumference of the dot), the roundness was evaluated as follows. . That is, the roundness is
- Xer0XP paper manufactured by Xerox Corporation was used as recording paper. First, the reaction solution was adhered to the recording paper at 100% duty, and then characters were printed with black ink. After drying, the characters were examined for bleeding. Evaluate the results as follows
- XerO XP paper Using XerO XP paper as recording paper, a single color of 100 duty of cyan color ink and a red color of 100% each of magenta and cyan were printed at a size of 3 cm x 3 cm.
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- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97933879A EP0876914B1 (en) | 1996-08-01 | 1997-08-01 | Ink jet recording method using two liquids |
US09/051,096 US6196674B1 (en) | 1996-08-01 | 1997-08-01 | Ink jet recording method using two liquids |
DE69703927T DE69703927T2 (de) | 1996-08-01 | 1997-08-01 | Tintenstrahldruckverfahren welches zwei flüssigkeiten verwendet |
JP50780498A JP3658765B2 (ja) | 1996-08-01 | 1997-08-01 | 二液を用いたインクジェット記録方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP20385396 | 1996-08-01 | ||
JP8/203853 | 1996-08-01 |
Publications (1)
Publication Number | Publication Date |
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WO1998005504A1 true WO1998005504A1 (fr) | 1998-02-12 |
Family
ID=16480787
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1997/002683 WO1998005504A1 (fr) | 1996-08-01 | 1997-08-01 | Procede d'enregistrement par jet d'encre au moyen de deux liquides |
Country Status (5)
Country | Link |
---|---|
US (1) | US6196674B1 (ja) |
EP (1) | EP0876914B1 (ja) |
JP (1) | JP3658765B2 (ja) |
DE (1) | DE69703927T2 (ja) |
WO (1) | WO1998005504A1 (ja) |
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US6383612B1 (en) | 1998-06-19 | 2002-05-07 | 3M Innovative Properties Company | Ink-drying agents for inkjet receptor media |
US6514599B1 (en) | 1999-04-16 | 2003-02-04 | 3M Innovative Properties Company | Inkjet receptor medium having a multi-staged ink migration inhibitor and method of making and using same |
US6537650B1 (en) | 1998-06-19 | 2003-03-25 | 3M Innovative Properties Company | Inkjet receptor medium having ink migration inhibitor and method of making and using same |
US6632510B1 (en) | 1997-07-14 | 2003-10-14 | 3M Innovative Properties Company | Microporous inkjet receptors containing both a pigment management system and a fluid management system |
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63299970A (ja) * | 1987-05-30 | 1988-12-07 | Ricoh Co Ltd | インクジェット記録方法 |
JPS6485766A (en) * | 1987-09-29 | 1989-03-30 | Canon Kk | Ink jet recorder |
JPH0356573A (ja) | 1989-07-25 | 1991-03-12 | Seiko Epson Corp | 画像記録用インク及び画像記録方法 |
JPH0379678A (ja) | 1989-08-22 | 1991-04-04 | Kao Corp | インクジエット記録用水性インク組成物 |
JPH0392351A (ja) * | 1989-09-05 | 1991-04-17 | Canon Inc | インクジェット記録装置 |
JPH03240557A (ja) | 1990-02-20 | 1991-10-25 | Seiko Epson Corp | 印写方法 |
JPH03240558A (ja) | 1990-02-20 | 1991-10-25 | Seiko Epson Corp | 印写方法 |
JPH05202328A (ja) | 1991-09-23 | 1993-08-10 | Hewlett Packard Co <Hp> | 印刷画像の作成方法 |
JPH06106735A (ja) | 1992-09-24 | 1994-04-19 | Canon Inc | 液滴噴射記録方法および記録装置 |
JPH0820720A (ja) * | 1994-07-11 | 1996-01-23 | Canon Inc | 液体組成物、インクセット及びこれを用いた画像形成方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE885711A (fr) * | 1979-07-02 | 1981-02-02 | Milliken Res Corp | Procede et appareil d'impression d'un support par un champ electrique |
US5006862A (en) * | 1989-10-27 | 1991-04-09 | Hewlett-Packard Company | Fixation of reactive dyes to paper by ink-jet printing |
JP3223927B2 (ja) * | 1991-08-23 | 2001-10-29 | セイコーエプソン株式会社 | 転写式記録装置 |
DE69318815T2 (de) | 1992-07-02 | 1998-12-03 | Seiko Epson Corp., Tokio/Tokyo | Tintenstrahlaufzeichnungsverfahren durch zwischenübertragung |
EP0583168B1 (en) * | 1992-08-12 | 1998-10-28 | Seiko Epson Corporation | Method and device for ink jet recording |
US5805191A (en) * | 1992-11-25 | 1998-09-08 | Tektronix, Inc. | Intermediate transfer surface application system |
US5790160A (en) * | 1992-11-25 | 1998-08-04 | Tektronix, Inc. | Transparency imaging process |
EP0657849B1 (en) * | 1993-11-30 | 2000-01-05 | Hewlett-Packard Company | Method and apparatus for colour inkjet printing using a colourless precursor |
US5796422A (en) * | 1995-10-17 | 1998-08-18 | Hewlett-Packard Company | Direct toner projection printing using an intermediate transfer medium |
-
1997
- 1997-08-01 JP JP50780498A patent/JP3658765B2/ja not_active Expired - Lifetime
- 1997-08-01 WO PCT/JP1997/002683 patent/WO1998005504A1/ja active IP Right Grant
- 1997-08-01 EP EP97933879A patent/EP0876914B1/en not_active Expired - Lifetime
- 1997-08-01 DE DE69703927T patent/DE69703927T2/de not_active Expired - Lifetime
- 1997-08-01 US US09/051,096 patent/US6196674B1/en not_active Expired - Lifetime
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63299970A (ja) * | 1987-05-30 | 1988-12-07 | Ricoh Co Ltd | インクジェット記録方法 |
JPS6485766A (en) * | 1987-09-29 | 1989-03-30 | Canon Kk | Ink jet recorder |
JPH0356573A (ja) | 1989-07-25 | 1991-03-12 | Seiko Epson Corp | 画像記録用インク及び画像記録方法 |
JPH0379678A (ja) | 1989-08-22 | 1991-04-04 | Kao Corp | インクジエット記録用水性インク組成物 |
JPH0392351A (ja) * | 1989-09-05 | 1991-04-17 | Canon Inc | インクジェット記録装置 |
JPH03240557A (ja) | 1990-02-20 | 1991-10-25 | Seiko Epson Corp | 印写方法 |
JPH03240558A (ja) | 1990-02-20 | 1991-10-25 | Seiko Epson Corp | 印写方法 |
JPH05202328A (ja) | 1991-09-23 | 1993-08-10 | Hewlett Packard Co <Hp> | 印刷画像の作成方法 |
JPH06106735A (ja) | 1992-09-24 | 1994-04-19 | Canon Inc | 液滴噴射記録方法および記録装置 |
JPH0820720A (ja) * | 1994-07-11 | 1996-01-23 | Canon Inc | 液体組成物、インクセット及びこれを用いた画像形成方法 |
Non-Patent Citations (1)
Title |
---|
See also references of EP0876914A4 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6632510B1 (en) | 1997-07-14 | 2003-10-14 | 3M Innovative Properties Company | Microporous inkjet receptors containing both a pigment management system and a fluid management system |
US6383612B1 (en) | 1998-06-19 | 2002-05-07 | 3M Innovative Properties Company | Ink-drying agents for inkjet receptor media |
US6537650B1 (en) | 1998-06-19 | 2003-03-25 | 3M Innovative Properties Company | Inkjet receptor medium having ink migration inhibitor and method of making and using same |
US6703112B1 (en) | 1998-06-19 | 2004-03-09 | 3M Innovative Properties Company | Organometallic salts for inkjet receptor media |
US6677007B1 (en) | 1999-02-12 | 2004-01-13 | 3M Innovative Properties Company | Image receptor medium and method of making and using same |
US6514599B1 (en) | 1999-04-16 | 2003-02-04 | 3M Innovative Properties Company | Inkjet receptor medium having a multi-staged ink migration inhibitor and method of making and using same |
JP2012192607A (ja) * | 2011-03-16 | 2012-10-11 | Ricoh Co Ltd | インクジェット印字方法 |
WO2015093050A1 (en) * | 2013-12-18 | 2015-06-25 | Canon Kabushiki Kaisha | Method for manufacturing a pattern, manufacturing apparatus for manufacturing a pattern, method for manufacturing structural body and manufacturing apparatus therefor |
US9789704B2 (en) | 2013-12-18 | 2017-10-17 | Canon Kabushiki Kaisha | Method for manufacturing a pattern, manufacturing apparatus for manufacturing a pattern, method for manufacturing structural body and manufacturing apparatus therefor |
US9919537B2 (en) | 2013-12-18 | 2018-03-20 | Canon Kabushiki Kaisha | Method for manufacturing a pattern, manufacturing apparatus for manufacturing a pattern, method for manufacturing structural body and manufacturing apparatus therefor |
Also Published As
Publication number | Publication date |
---|---|
US6196674B1 (en) | 2001-03-06 |
DE69703927T2 (de) | 2001-05-10 |
EP0876914A1 (en) | 1998-11-11 |
EP0876914A4 (en) | 1999-03-31 |
JP3658765B2 (ja) | 2005-06-08 |
EP0876914B1 (en) | 2001-01-17 |
DE69703927D1 (de) | 2001-02-22 |
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