WO1998002929B1 - Procede de preparation d'oxydes de vanadium amorphes melanges et leur utilisation en tant qu'electrodes de piles au lithium rechargeables - Google Patents
Procede de preparation d'oxydes de vanadium amorphes melanges et leur utilisation en tant qu'electrodes de piles au lithium rechargeablesInfo
- Publication number
- WO1998002929B1 WO1998002929B1 PCT/US1997/011285 US9711285W WO9802929B1 WO 1998002929 B1 WO1998002929 B1 WO 1998002929B1 US 9711285 W US9711285 W US 9711285W WO 9802929 B1 WO9802929 B1 WO 9802929B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrode material
- metal
- formula
- vanadium metal
- metal oxide
- Prior art date
Links
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 title abstract 2
- 229910001935 vanadium oxide Inorganic materials 0.000 title abstract 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title 1
- 229910052744 lithium Inorganic materials 0.000 title 1
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract 12
- 229910052720 vanadium Inorganic materials 0.000 claims abstract 11
- -1 vanadium metal oxides Chemical class 0.000 claims abstract 11
- 229910052751 metal Inorganic materials 0.000 claims abstract 10
- 239000002184 metal Substances 0.000 claims abstract 10
- 239000007773 negative electrode material Substances 0.000 claims abstract 5
- 239000007864 aqueous solution Substances 0.000 claims 5
- 239000002585 base Substances 0.000 claims 4
- 239000007774 positive electrode material Substances 0.000 claims 4
- 229910003002 lithium salt Inorganic materials 0.000 claims 3
- 159000000002 lithium salts Chemical class 0.000 claims 3
- 239000000243 solution Substances 0.000 claims 3
- 150000001447 alkali salts Chemical class 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims 2
- ALTWGIIQPLQAAM-UHFFFAOYSA-N metavanadate Chemical class [O-][V](=O)=O ALTWGIIQPLQAAM-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 2
- 239000011255 nonaqueous electrolyte Substances 0.000 claims 2
- 229910003006 LixMy Inorganic materials 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229910052803 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 230000000875 corresponding Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 239000007772 electrode material Substances 0.000 claims 1
- 230000002349 favourable Effects 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- 150000002823 nitrates Chemical class 0.000 claims 1
- 230000001376 precipitating Effects 0.000 claims 1
- 229910015916 LixMyVzO Inorganic materials 0.000 abstract 1
- 230000002687 intercalation Effects 0.000 abstract 1
- 238000009830 intercalation Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 238000001556 precipitation Methods 0.000 abstract 1
Abstract
Procédés de préparation d'oxydes métalliques de vanadium ternaires, lithiés et amorphes et d'oxydes métalliques non lithiés, binaires et amorphes de formule LixMyVzO¿(x+5z+ny)/z? et MyVzO¿(5z+ny)/z? respectivement. M est un métal, 0∫x∫3, 0∫y∫3, 1∫z∫4 et n=2 ou 3. Les oxydes métalliques de vanadium sont formés par des procédés de précipitation aqueuse. Des cellules de batteries intercalaires au lithium rechargeables dans lesquelles les matériaux ci-dessus utilisés comme des électrodes négatives sont également décrites.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97933196A EP0913007A1 (fr) | 1996-07-11 | 1997-06-27 | Procede de preparation d'oxydes de vanadium amorphes melanges et leur utilisation en tant qu'electrodes de piles au lithium rechargeables |
JP10506049A JP2000503622A (ja) | 1996-07-11 | 1997-06-27 | 混合非晶質酸化バナジウムの製造方法と再充電可能なリチウム電池の電極としての使用 |
IL12770797A IL127707A (en) | 1996-07-11 | 1997-06-27 | A method for making mixed amorphous oxides of vanadium and using them as electrodes in rechargeable lithium cells |
CA002259590A CA2259590C (fr) | 1996-07-11 | 1997-06-27 | Procede de preparation d'oxydes de vanadium amorphes melanges et leur utilisation en tant qu'electrodes de piles au lithium rechargeables |
AU36443/97A AU715258B2 (en) | 1996-07-11 | 1997-06-27 | A method for preparing mixed amorphous vanadium oxides and their use as electrodes in rechargeable lithium cells |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/678,210 | 1996-07-11 | ||
US08/678,210 US5700598A (en) | 1996-07-11 | 1996-07-11 | Method for preparing mixed amorphous vanadium oxides and their use as electrodes in reachargeable lithium cells |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1998002929A1 WO1998002929A1 (fr) | 1998-01-22 |
WO1998002929B1 true WO1998002929B1 (fr) | 1998-02-19 |
Family
ID=24721854
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1997/011285 WO1998002929A1 (fr) | 1996-07-11 | 1997-06-27 | Procede de preparation d'oxydes de vanadium amorphes melanges et leur utilisation en tant qu'electrodes de piles au lithium rechargeables |
Country Status (10)
Country | Link |
---|---|
US (1) | US5700598A (fr) |
EP (1) | EP0913007A1 (fr) |
JP (2) | JP2000503622A (fr) |
AU (1) | AU715258B2 (fr) |
CA (1) | CA2259590C (fr) |
ID (1) | ID17594A (fr) |
IL (1) | IL127707A (fr) |
MY (1) | MY133690A (fr) |
TW (1) | TW362296B (fr) |
WO (1) | WO1998002929A1 (fr) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
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US6277521B1 (en) | 1997-05-15 | 2001-08-21 | Fmc Corporation | Lithium metal oxide containing multiple dopants and method of preparing same |
ZA983867B (en) * | 1997-05-16 | 1998-11-13 | Henkel Corp | Lithium and vanadium containing sealing composition and process therewith |
DE69827700T2 (de) * | 1997-05-22 | 2005-10-06 | Matsushita Electric Industrial Co., Ltd., Kadoma | Sekundärbatterie mit nichtwässrigem Elektrolyten |
US6017654A (en) * | 1997-08-04 | 2000-01-25 | Carnegie Mellon University | Cathode materials for lithium-ion secondary cells |
US6517974B1 (en) * | 1998-01-30 | 2003-02-11 | Canon Kabushiki Kaisha | Lithium secondary battery and method of manufacturing the lithium secondary battery |
US5980855A (en) * | 1998-05-26 | 1999-11-09 | Rentech, Inc. | Method for preparing lithiated metal oxides |
US5939043A (en) * | 1998-06-26 | 1999-08-17 | Ga-Tek Inc. | Process for preparing Lix Mn2 O4 intercalation compounds |
US6267943B1 (en) | 1998-10-15 | 2001-07-31 | Fmc Corporation | Lithium manganese oxide spinel compound and method of preparing same |
AU1720000A (en) | 1998-11-13 | 2000-06-05 | Fmc Corporation | Layered lithium metal oxides free of localized cubic spinel-like structural phases and methods of making same |
TW438721B (en) | 1998-11-20 | 2001-06-07 | Fmc Corp | Multiple doped lithium manganese oxide compounds and methods of preparing same |
US6322928B1 (en) * | 1999-09-23 | 2001-11-27 | 3M Innovative Properties Company | Modified lithium vanadium oxide electrode materials and products |
US6579475B2 (en) | 1999-12-10 | 2003-06-17 | Fmc Corporation | Lithium cobalt oxides and methods of making same |
US6916578B2 (en) * | 2000-04-19 | 2005-07-12 | Japan Storage Battery Co., Ltd. | Positive electrode active material for secondary cell, method for producing the same and nonaqueous electrolyte secondary cell comprising the same |
EP1164649A1 (fr) * | 2000-06-13 | 2001-12-19 | Japan Storage Battery Company Limited | Matière active positive pour batterie secondaire, son procédé de préparation et batterie secondaire non aqueuse comprenant la matière active |
AU2002249557A1 (en) * | 2002-03-28 | 2003-10-13 | Council Of Scientific And Industrial Research | COMBUSTION PROCESS FOR THE PREPARATION OF LiCoVO4 |
US20030235761A1 (en) * | 2002-04-26 | 2003-12-25 | Prabaharan S.R. Sahaya | Rechargeable lithium-containing battery employing brannerite type LiVMoO5.5 cathode and method of preparing same |
US20040048157A1 (en) * | 2002-09-11 | 2004-03-11 | Neudecker Bernd J. | Lithium vanadium oxide thin-film battery |
US8026003B2 (en) * | 2003-08-21 | 2011-09-27 | Samsung Sdi Co., Ltd. | Negative active material for a non-aqueous electrolyte battery, and a non-aqueous electrolyte battery comprising the same |
US7682746B2 (en) * | 2005-03-31 | 2010-03-23 | Panasonic Corporation | Negative electrode for non-aqueous secondary battery |
US7399457B2 (en) * | 2005-04-12 | 2008-07-15 | Conocophillips Company | Process for the removal of heavy metals from gases, and compositions therefor and therewith |
KR100759410B1 (ko) * | 2006-11-20 | 2007-09-19 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 활물질, 그의 제조 방법 및 그를포함하는 리튬 이차 전지 |
KR100778450B1 (ko) * | 2006-11-22 | 2007-11-28 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 활물질, 이의 제조 방법 및 이를포함하는 리튬 이차 전지 |
KR100814880B1 (ko) * | 2006-11-22 | 2008-03-18 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 활물질, 이의 제조 방법 및 이를포함하는 리튬 이차 전지 |
US20080182171A1 (en) * | 2006-12-18 | 2008-07-31 | Hideaki Maeda | Composition for negative electrode of non-aqueous rechargeable battery and non-aqueous rechargeable battery prepared by using same |
JP5270089B2 (ja) * | 2006-12-18 | 2013-08-21 | 三星エスディアイ株式会社 | 非水二次電池用負極材料の製造方法及びそれを用いた非水二次電池の製造方法 |
KR100805123B1 (ko) * | 2007-02-15 | 2008-02-21 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
KR100953615B1 (ko) * | 2007-04-13 | 2010-04-20 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 활물질, 그의 제조 방법 및 그를포함하는 리튬 이차 전지 |
JP5511128B2 (ja) * | 2007-06-07 | 2014-06-04 | 三星エスディアイ株式会社 | 非水二次電池用負極材料及び非水二次電池 |
KR100918048B1 (ko) * | 2007-09-07 | 2009-09-22 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
KR100898291B1 (ko) * | 2007-09-12 | 2009-05-18 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
TW201002623A (en) * | 2008-05-30 | 2010-01-16 | Basf Se | Process for preparing lithium vanadium oxides and their use as cathode material |
KR101208910B1 (ko) | 2010-09-29 | 2012-12-06 | 전자부품연구원 | 이종금속이 치환된 리튬바나듐금속산화물을 이용한 비수계 리튬이차전지용 음극재료의 제조 방법 |
RU2453014C1 (ru) * | 2010-11-23 | 2012-06-10 | Государственное образовательное учреждение высшего профессионального образования Самарский государственный технический университет | Электролит для химического источника тока |
KR101418060B1 (ko) | 2012-02-20 | 2014-07-10 | 경북대학교 산학협력단 | 리튬 이차전지용 양극 활물질의 제조 방법 |
US10297855B2 (en) | 2012-05-29 | 2019-05-21 | Nutech Ventures | Rechargeable multi-cell battery |
CN103268964B (zh) * | 2013-05-09 | 2015-08-05 | 西安交通大学 | 一种钒酸钠组装水溶液锂离子电池体系的方法 |
KR20210108915A (ko) * | 2020-02-26 | 2021-09-03 | 주식회사 엘지에너지솔루션 | 비가역 첨가제, 상기 비가역 첨가제를 포함하는 양극, 상기 양극을 포함하는 리튬 이차전지 |
JP2024055325A (ja) * | 2022-10-07 | 2024-04-18 | 日本ケミコン株式会社 | リチウムバナジウム酸化物結晶体の製造方法、リチウムバナジウム酸化物結晶体、電極材料及び蓄電デバイス |
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US4675260A (en) * | 1984-11-12 | 1987-06-23 | Nippon Telegraph And Telephone Corporation | Lithium battery including vanadium pentoxide base amorphous cathode active material |
IT1231750B (it) * | 1989-05-12 | 1991-12-21 | Consiglio Nazionale Ricerche | Accumulatori al litio ad alta energia e potenza e relativo metodo di produzione |
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FR2685129B1 (fr) * | 1991-12-13 | 1994-03-25 | Centre Nal Etudes Spatiales | Utilisation de bronzes d'oxyde de vanadium au fer et/ou a l'aluminium comme materiau cathodique dans des generateurs electrochimiques. |
US5334334A (en) * | 1993-03-30 | 1994-08-02 | Valence Technology, Inc. | Method of preparing lithium battery electrode compositions |
JPH07122275A (ja) * | 1993-05-25 | 1995-05-12 | Wilson Greatbatch Ltd | 電気化学電池用のカソード、その調製方法および電気化学電池 |
-
1996
- 1996-07-11 US US08/678,210 patent/US5700598A/en not_active Expired - Lifetime
-
1997
- 1997-06-27 AU AU36443/97A patent/AU715258B2/en not_active Ceased
- 1997-06-27 EP EP97933196A patent/EP0913007A1/fr not_active Withdrawn
- 1997-06-27 IL IL12770797A patent/IL127707A/en not_active IP Right Cessation
- 1997-06-27 JP JP10506049A patent/JP2000503622A/ja active Pending
- 1997-06-27 CA CA002259590A patent/CA2259590C/fr not_active Expired - Fee Related
- 1997-06-27 WO PCT/US1997/011285 patent/WO1998002929A1/fr not_active Application Discontinuation
- 1997-07-08 MY MYPI97003089A patent/MY133690A/en unknown
- 1997-07-10 ID IDP972381A patent/ID17594A/id unknown
- 1997-07-11 TW TW086109800A patent/TW362296B/zh active
-
2002
- 2002-08-22 JP JP2002242077A patent/JP2003142096A/ja active Pending
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