WO1997033332A1 - Verfahren zur herstellung einer kathode durch oxidation in einer schmelzkarbonat-brennstoffzelle - Google Patents
Verfahren zur herstellung einer kathode durch oxidation in einer schmelzkarbonat-brennstoffzelleInfo
- Publication number
- WO1997033332A1 WO1997033332A1 PCT/EP1997/001094 EP9701094W WO9733332A1 WO 1997033332 A1 WO1997033332 A1 WO 1997033332A1 EP 9701094 W EP9701094 W EP 9701094W WO 9733332 A1 WO9733332 A1 WO 9733332A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cathode
- fuel cell
- molten carbonate
- precursor
- oxidation
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M8/141—Fuel cells with fused electrolytes the anode and the cathode being gas-permeable electrodes or electrode layers
- H01M8/142—Fuel cells with fused electrolytes the anode and the cathode being gas-permeable electrodes or electrode layers with matrix-supported or semi-solid matrix-reinforced electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8621—Porous electrodes containing only metallic or ceramic material, e.g. made by sintering or sputtering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8892—Impregnation or coating of the catalyst layer, e.g. by an ionomer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
- H01M2004/8689—Positive electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M2008/147—Fuel cells with molten carbonates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0048—Molten electrolytes used at high temperature
- H01M2300/0051—Carbonates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/53—Means to assemble or disassemble
- Y10T29/5313—Means to assemble electrical device
- Y10T29/532—Conductor
- Y10T29/53204—Electrode
Definitions
- the invention relates to a method for producing a cathode for a molten carbonate fuel cell by electrochemical oxidation of a porous metallic precursor electrode and contact with molten carbonate, and to a cathode produced by the method.
- Porous cathodes made from lithiated nickel oxide are generally used in molten carbonate fuel cells. From the book: Fuel Cell Handbook, by A. J. Appleby and F.R. Foulkes, Van Nostrand Reinhold, New York, p. 546 it is known to make these cathodes in the fuel cell itself from porous nickel precursor electrodes that are in contact with the
- Melt flow electrolytes are to be formed by oxidation with atmospheric oxygen at 600 to 650 ° C. when the cells or the cell stack are started up. During the chemical reaction
- lithium oxide from the melt is built into the nickel oxide, which finally gives the nickel oxide the p-semiconductor property necessary for its function (specific conductivity: around 20 S em " 1 at 650 ° C).
- the speed of this formation process determines the morphological properties of the cathode, which in turn decisively influence the functionality and quality of the cathode.
- Nickel oxide crystals and the formation of relatively large pores between the agglomerates should have a diameter of a few tenths of a micrometer, while the average diameter of the agglomerates and coarse pores should ideally be between 1 and 7 micrometers.
- a relatively high reaction rate of the oxidation favors the formation of the desired cathode structure and morphology, while a too slow oxidation of the metal, which can extend over periods of more than 10 hours, for example 1 Formation of very coarse nickel oxide crystals, which can then measure several micrometers in diameter, and the formation of the desired agglomerates does not occur.
- the rate of oxidation of the nickel metal can be influenced by the oxygen content and the flow rate of the forming gas.
- Leakages of the cell at locally narrowly limited places to a small extent pass the reducing anode gas to the cathode side and there, in the vicinity of the point of passage, delay the oxidation of the nickel metal, so that due to the slow oxidation of the nickel there is a locally limited formation of undesirable or coarse nickel oxide structures , and in cell operation for training very low
- the invention is based on the problem of specifying a method for producing a cathode 5 for a molten carbonate fuel cell by means of which heat-free oxidation with an adjustable oxidation rate is possible, and to provide a cathode produced by the method.
- Precursor electrode a matrix layer with molten carbonate and a cell containing porous anode with a predeterminable course of the current density are anodically oxidized and doped by contact with molten carbonate.
- anodic i.e. Electrochemical, oxidation are generated on the precursor electrode, which is connected as an anode, from oxygen molecules by the absorption of electrons
- the structure of the nickel oxide layer essentially depends on the level and duration of the current load. It has been shown that with the anodic oxidation over the entire surface of the precursor electrode of a fuel cell and all Fuel cells in a stack can achieve an oxidation rate that is homogeneous in area.
- a higher current density is impressed at the beginning of the anodic oxidation than towards the end of the oxidation of the precursor electrode. It is possible by impressing the current density, i.e. by means of a control of the current density to specify the oxidation rate precisely, so that the reaction rate can be adapted to the reaction time. At the beginning of the formation, high current densities result in high reaction rates, while at the end of the formation low current densities and therefore a low one
- the rate of post-oxidation in order to increase the lithium absorption and improve the conductivity of the nickel oxide is particularly favorable.
- precursor cathodes made of porous, sintered nickel sponge are used in particular
- foils made of carbonyl nickel are heated in situ after installation in cells of a fuel cell stack and then anodically oxidized.
- the melt electrolyte is preferably melted in the respective fuel cell with the precursor electrode and, during the anodic oxidation, the cathode compartment is flushed with nitrogen and / or carbon dioxide and the anode compartment with a mixture of water vapor and carbon dioxide.
- the gas in the cathode compartment during the anodic oxidation is composed in particular of nitrogen and carbon dioxide in a ratio of 1.0 / 0.0 to 0.0 / 1.0 volume percent and in the anode compartment of water vapor and carbon dioxide in a ratio of 0.1 / 0.9 to 0.9 / 0.1 percent by volume together.
- double-layer electrodes can be produced by anodic oxidation of double-layer precursor electrodes made of carbonyl cobalt and
- Carbonyl nickel or made of disperse cobalt and nickel corresponding distribution Furthermore, the method is favorable for the production of alloy cathodes from Ni / Co, Ni / Fe, Co / Mn, Co / Fe / Mn and Fe / Mn.
- precursor cathodes are first produced.
- Nickel powder becomes e.g. by adding binders, plasticizers and other auxiliaries, a slip is produced from which a thin film is produced.
- a thin, porous nickel sponge is produced from this foil by sintering.
- a film of loose carbonyl nickel can be used as another starting material.
- the precursor electrodes made of thin, porous sintered nickel sponge or
- Loose carbonyl nickel foils that are baked in situ are built into the fuel cells of a stack.
- the melt electrolyte is then melted in the matrix.
- the cathode compartment of the respective fuel cell is included Flushed with nitrogen, which is expedient for heat transfer and for taking up the carbon dioxide released in accordance with the following equation (4) in the anodic nickel oxidation,
- the precursor electrode is made of nickel as an anode in one
- the DC circuit arranged with which an impressed current can be generated.
- the DC circuit contains a current regulator, the output current of which is set according to a reference variable.
- the anodic oxidation of the cathode-side nickel sponge - coupled with the anode-side cathodic reduction of water (equation (2)) - is then started by impressing current densities which are between 10 and 1000 mA / cm 2 .
- current densities between 100 and 500 mA / cm 2 are impressed, the oxidation of the nickel precursor cathode takes place, which usually has a specific nickel load of approx. 0.2 g / cm 2 , in a few hours and the formation can by a
- This method can in particular be used in the same way for the production of cathodes from lithium cobaltite (LiCoO 2 ), lithium ferrite (LiFeO 2 ), from double-layer cathodes, as described in DE 43 03 136 C2, from LiCoO 2 and lithiated nickel oxide and from so-called alloy cathodes ( from eg Ni and Co, Ni and Mn or Co or Fe and Mn) from porous metallic precursor electrodes of appropriate composition and structure.
- LiCoO 2 lithium cobaltite
- LiFeO 2 lithium ferrite
- alloy cathodes from eg Ni and Co, Ni and Mn or Co or Fe and Mn
- Example 1 Production of lithiated NiO cathodes by means of anodic oxidation
- the fuel cell is built in: the anode, the matrix, the pre-sintered cathode precursor made of porous nickel and an electrolyte foil if the required amount of electrolyte is not already contained in the aforementioned components.
- the cell is covered on the ground and cathode sides with a 1 reductive gas mixture (in volume percentages: 10/5/85 H 2 / CO 2 / N 2 ) is charged.
- a 1 reductive gas mixture in volume percentages: 10/5/85 H 2 / CO 2 / N 2
- the fuel cell anode H 2 O / CO 2 in a ratio of 1: 2 (in volume percent) is fed to the cathode precursor (in volume percent :) 95/5 N 2 / CO 2 gas mixture.
- the cathode precursor is now anodically loaded with 200 mA / cm 2 .
- the cathode precursor is completely oxidized and sufficiently lithiated for three hours so that the fuel cell can now be put into operation with the usual operating gases.
- cathodes with a polarization resistance of 0.25 ⁇ cm 2 or an IR-free overvoltage of 37.5 mV at 150 mA / cm 2 are obtained.
- the fuel cell is equipped with an anode, matrix, electrolyte foil and a cathode precursor, which consists of pre-sintered porous cobalt oxide CoO with Li 2 CO 3 as a pore former.
- anode-side gas mixture 10/5/85 5 H 2 / CO 2 / N 2 , (volume percent)
- cathode-side 95/5 N 2 / CO 2 (volume percent)
- the anodic oxidation of the cathode precursor is carried out for five hours at a current density of 300 mA / cm 2 .
- This gives LiCoO 2 cathodes with 0 a polarization resistance of 0.2 ⁇ cm 2 or an IR-free ( cleaned of the ohmic internal resistance) overvoltage of 30 mV at 150 mA / cm 2 .
- Example 3 Production of double-layer cathodes (LiCoO 2 / (Li) NiO) by means of anodic oxidation 5
- the fuel cell is equipped with an anode, matrix, electrolyte film and the double-layer cathode precursor, as described in WO 94/18713.
- anode-side gas mixture 10/5/85 H 2 / CO 2 / N 2 (volume percent)
- cathode-side 5/5/90 H 2 / CO 2 / N 2 (volume percent)
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Inert Electrodes (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP53145997A JP3513516B2 (ja) | 1996-03-09 | 1997-03-05 | 溶融炭酸塩型燃料電池のためのカソードの製造方法およびこの方法で製造されたカソードを用いた溶融炭酸塩型燃料電池 |
US09/142,410 US6063141A (en) | 1996-03-09 | 1997-03-05 | Cathode for a molten carbonate fuel cell and method for manufacturing same |
EP97906164A EP0916165A1 (de) | 1996-03-09 | 1997-03-05 | Verfahren zur herstellung einer kathode durch oxidation in einer schmelzkarbonat-brennstoffzelle |
CA002248341A CA2248341C (en) | 1996-03-09 | 1997-03-05 | Method of producing a cathode by oxidation in a molten carbonate fuel cell |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19609313.9 | 1996-03-09 | ||
DE19609313A DE19609313C1 (de) | 1996-03-09 | 1996-03-09 | Verfahren zur Herstellung einer Kathode für eine Schmelzkarbonat-Brennstoffzelle und eine nach dem Verfahren hergestellte Kathode |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997033332A1 true WO1997033332A1 (de) | 1997-09-12 |
Family
ID=7787817
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1997/001094 WO1997033332A1 (de) | 1996-03-09 | 1997-03-05 | Verfahren zur herstellung einer kathode durch oxidation in einer schmelzkarbonat-brennstoffzelle |
Country Status (5)
Country | Link |
---|---|
US (1) | US6063141A (de) |
EP (1) | EP0916165A1 (de) |
JP (1) | JP3513516B2 (de) |
DE (1) | DE19609313C1 (de) |
WO (1) | WO1997033332A1 (de) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19603918C2 (de) * | 1996-02-03 | 2000-10-05 | Mtu Friedrichshafen Gmbh | Verfahren zur Herstellung einer Elektrode für eine Schmelzkarbonat-Brennstoffzelle und deren Verwendung |
DE19731772C2 (de) * | 1996-07-26 | 1999-08-26 | Mtu Friedrichshafen Gmbh | Verfahren zur Herstellung einer porösen Kathode für eine Schmelzkarbonat-Brennstoffzelle |
DE10045912C2 (de) * | 2000-09-16 | 2002-08-01 | Mtu Friedrichshafen Gmbh | Verfahren zur Herstellung einer Schmelzcarbonat-Brennstoffzelle sowie Schmelzcarbonat-Brennstoffzelle |
CN103746103B (zh) * | 2014-01-15 | 2016-01-13 | 合肥国轩高科动力能源有限公司 | 一种钛酸锂薄膜的制备方法 |
KR102662253B1 (ko) | 2018-11-30 | 2024-04-29 | 퓨얼셀 에너지, 인크 | Co2 이용률이 향상된 용융 탄산염 연료 전지의 증가된 압력 작동 |
US11211621B2 (en) | 2018-11-30 | 2021-12-28 | Exxonmobil Research And Engineering Company | Regeneration of molten carbonate fuel cells for deep CO2 capture |
WO2020112895A1 (en) | 2018-11-30 | 2020-06-04 | Exxonmobil Research And Engineering Company | Reforming catalyst pattern for fuel cell operated with enhanced co2 utilization |
US11695122B2 (en) | 2018-11-30 | 2023-07-04 | ExxonMobil Technology and Engineering Company | Layered cathode for molten carbonate fuel cell |
US11476486B2 (en) | 2018-11-30 | 2022-10-18 | ExxonMobil Technology and Engineering Company | Fuel cell staging for molten carbonate fuel cells |
WO2020112812A1 (en) | 2018-11-30 | 2020-06-04 | Exxonmobil Research And Engineering Company | Operation of molten carbonate fuel cells with enhanced co 2 utilization |
JP2023503473A (ja) | 2019-11-26 | 2023-01-30 | エクソンモービル・テクノロジー・アンド・エンジニアリング・カンパニー | 高電解質充填レベルでの溶融炭酸塩型燃料電池の作動 |
JP2023503995A (ja) | 2019-11-26 | 2023-02-01 | エクソンモービル・テクノロジー・アンド・エンジニアリング・カンパニー | 燃料電池モジュールのアセンブリおよびそれを使用するシステム |
US11978931B2 (en) | 2021-02-11 | 2024-05-07 | ExxonMobil Technology and Engineering Company | Flow baffle for molten carbonate fuel cell |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6074272A (ja) * | 1983-09-30 | 1985-04-26 | Agency Of Ind Science & Technol | 溶融炭酸塩型燃料電池の製造方法 |
JPH04280069A (ja) * | 1991-03-06 | 1992-10-06 | Sumitomo Metal Mining Co Ltd | 溶融炭酸塩燃料電池用空気極材料 |
JPH05109413A (ja) * | 1991-10-11 | 1993-04-30 | Sumitomo Metal Mining Co Ltd | 溶融炭酸塩燃料電池用空気極及びその製造方法 |
DE4224290A1 (de) * | 1992-07-23 | 1994-01-27 | Deutsche Aerospace | Verfahren zur Herstellung einer lithiumoxidhaltigen Nickeloxid-Kathode für eine Schmelzcarbonatbrennstoffzelle |
DE4302347C1 (de) * | 1993-01-28 | 1994-06-23 | Deutsche Aerospace | Carbonatschmelzen-Brennstoffzelle und Verfahren zu deren Herstellung |
WO1994018713A1 (de) * | 1993-02-04 | 1994-08-18 | Mtu Motoren- Und Turbinen-Union Friedrichshafen Gmbh | Verfahren zur herstellung der kathoden-schicht von schmelzkarbonat-brennstoffzellen |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1241857B (it) * | 1990-06-01 | 1994-02-01 | Ansaldo Spa | Procedimento per la fabbricazione di catodi per celle a carbonati fusi |
DE4030944A1 (de) * | 1990-09-29 | 1992-04-02 | Siemens Ag | Karbonatschmelzen-brennstoffzelle |
US5589287A (en) * | 1993-10-18 | 1996-12-31 | Matsushita Electric Industrial Co., Ltd. | Molten carbonate fuel cell |
IT1269334B (it) * | 1994-04-19 | 1997-03-26 | Finmeccanica Spa Azienda Ansal | Metodo per la fabbricazione di catodi per celle a combustibile |
-
1996
- 1996-03-09 DE DE19609313A patent/DE19609313C1/de not_active Expired - Fee Related
-
1997
- 1997-03-05 US US09/142,410 patent/US6063141A/en not_active Expired - Lifetime
- 1997-03-05 JP JP53145997A patent/JP3513516B2/ja not_active Expired - Fee Related
- 1997-03-05 WO PCT/EP1997/001094 patent/WO1997033332A1/de not_active Application Discontinuation
- 1997-03-05 EP EP97906164A patent/EP0916165A1/de not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6074272A (ja) * | 1983-09-30 | 1985-04-26 | Agency Of Ind Science & Technol | 溶融炭酸塩型燃料電池の製造方法 |
JPH04280069A (ja) * | 1991-03-06 | 1992-10-06 | Sumitomo Metal Mining Co Ltd | 溶融炭酸塩燃料電池用空気極材料 |
JPH05109413A (ja) * | 1991-10-11 | 1993-04-30 | Sumitomo Metal Mining Co Ltd | 溶融炭酸塩燃料電池用空気極及びその製造方法 |
DE4224290A1 (de) * | 1992-07-23 | 1994-01-27 | Deutsche Aerospace | Verfahren zur Herstellung einer lithiumoxidhaltigen Nickeloxid-Kathode für eine Schmelzcarbonatbrennstoffzelle |
DE4302347C1 (de) * | 1993-01-28 | 1994-06-23 | Deutsche Aerospace | Carbonatschmelzen-Brennstoffzelle und Verfahren zu deren Herstellung |
WO1994018713A1 (de) * | 1993-02-04 | 1994-08-18 | Mtu Motoren- Und Turbinen-Union Friedrichshafen Gmbh | Verfahren zur herstellung der kathoden-schicht von schmelzkarbonat-brennstoffzellen |
Non-Patent Citations (3)
Title |
---|
CHEMICAL ABSTRACTS, vol. 103, no. 14, 7 October 1985, Columbus, Ohio, US; abstract no. 107690, AGENCY OF INDUSTRIAL SCIENCES AND TECHNOLOGY, JAPAN: "Manufacture of molten-carbonate fuel cell" XP002032358 * |
CHEMICAL ABSTRACTS, vol. 119, no. 12, 20 September 1993, Columbus, Ohio, US; abstract no. 121300, YAMANAKA, ATSUSHI ET AL: "Air cathodes for molten-carbonate fuel cell and their manufacture" XP002032357 * |
PATENT ABSTRACTS OF JAPAN vol. 017, no. 081 (E - 1321) 18 February 1993 (1993-02-18) * |
Also Published As
Publication number | Publication date |
---|---|
EP0916165A1 (de) | 1999-05-19 |
JPH11506263A (ja) | 1999-06-02 |
JP3513516B2 (ja) | 2004-03-31 |
US6063141A (en) | 2000-05-16 |
DE19609313C1 (de) | 1997-09-25 |
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