WO1997014733B1 - Matieres de revetement composees d'un polymere fluorocarbone acrylique et d'un polyisocyanate fluore - Google Patents
Matieres de revetement composees d'un polymere fluorocarbone acrylique et d'un polyisocyanate fluoreInfo
- Publication number
- WO1997014733B1 WO1997014733B1 PCT/US1996/016289 US9616289W WO9714733B1 WO 1997014733 B1 WO1997014733 B1 WO 1997014733B1 US 9616289 W US9616289 W US 9616289W WO 9714733 B1 WO9714733 B1 WO 9714733B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- carbon atoms
- ofthe
- alkyl
- acrylic polymer
- Prior art date
Links
- 239000008199 coating composition Substances 0.000 title claims abstract 10
- 229920001228 Polyisocyanate Polymers 0.000 title claims abstract 7
- 239000005056 polyisocyanate Substances 0.000 title claims abstract 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims 2
- 229920002313 fluoropolymer Polymers 0.000 title 1
- 125000004432 carbon atoms Chemical group C* 0.000 claims abstract 15
- 125000000217 alkyl group Chemical group 0.000 claims abstract 11
- 239000011230 binding agent Substances 0.000 claims abstract 10
- 229920000058 polyacrylate Polymers 0.000 claims abstract 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract 8
- 125000003709 fluoroalkyl group Chemical group 0.000 claims abstract 7
- 239000000178 monomer Substances 0.000 claims abstract 6
- 239000000203 mixture Substances 0.000 claims abstract 5
- 125000005250 alkyl acrylate group Chemical group 0.000 claims abstract 3
- 239000003431 cross linking reagent Substances 0.000 claims abstract 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 2
- 239000001257 hydrogen Substances 0.000 claims abstract 2
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract 2
- 239000007788 liquid Substances 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 4
- -1 hydroxy alkyl methacrylates Chemical class 0.000 claims 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims 3
- 239000000758 substrate Substances 0.000 claims 3
- 125000005442 diisocyanate group Chemical group 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 230000003078 antioxidant Effects 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N butyl 2-methylprop-2-enoate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 238000005227 gel permeation chromatography Methods 0.000 claims 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims 1
- 239000004611 light stabiliser Substances 0.000 claims 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 abstract 2
Abstract
Cette invention concerne une matière de revêtement contenant de 45 à 80 % en poids d'un liant et de 20 à 55 % en poids d'un liquide organique. Ledit liant contient (A) environ 40 à 90 % en poids, par rapport au poids du liant, d'un polymère acrylique contenant des monomères polymérisés contenant des groupes hydroxyles, lesdits monomères appartenant au groupe constitué par un acrylate ou des méthacrylates d'hydroxy alkyle ayant de 1 à 4 atomes de carbone au niveau du groupe alkyle, et des acrylates et méthacrylates d'alkyle polymérisés ayant de 1 à 18 atomes de carbone au niveau des groupes alkyles, ou par du styrène ou tout mélange des composés ci-dessus et de 0,1 à 5,0 % en poids, par rapport au poids du polymère acrylique, d'un monomère polymérisé contenant un groupe fluoroalkyle, représenté par la formule (I), dans laquelle R est hydrogène ou un groupe alkyle ayant de 1 à 2 atomes de carbone, n est un entier compris entre 1 et 11 et Rf est un groupe contenant un fluoroalkyle et ayant au moins 4 atomes de carbone, et (B) environ 10 à 60 % en poids, par rapport au poids du liant, d'un agent de réticulation de polyisocyanate organique fluoré.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96936367A EP0856021B1 (fr) | 1995-10-16 | 1996-10-11 | Matieres de revetement composees d'un polymere fluorocarbone acrylique et d'un polyisocyanate fluore |
AU74392/96A AU706335B2 (en) | 1995-10-16 | 1996-10-11 | Coating compositions of an acrylic fluorocarbon polymer and a fluorinated polyisocyanate |
BR9611102A BR9611102A (pt) | 1995-10-16 | 1996-10-11 | Composição de revestimento e substrato revestido |
DE69603195T DE69603195T2 (de) | 1995-10-16 | 1996-10-11 | Beschichtungszusammensetzungen aus einem acryl-fluorkohlenwasserstoff-polymer und einem fluorierten polyisocyanat |
CA002234421A CA2234421C (fr) | 1995-10-16 | 1996-10-11 | Matieres de revetement composees d'un polymere fluorocarbone acrylique et d'un polyisocyanate fluore |
JP51588497A JP4074340B2 (ja) | 1995-10-16 | 1996-10-11 | アクリルフルオロカーボンポリマーおよびフルオロ化ポリイソシアナートのコーティング組成物 |
NZ321114A NZ321114A (en) | 1995-10-16 | 1996-10-11 | Coating compositions of an acrylic fluorocarbon polymer and a fluorinated polyisocyanate |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/543,721 US5597874A (en) | 1995-10-16 | 1995-10-16 | Coating compositions of an acrylic fluorocarbon polymer and a fluorinated polyisocyanate |
US08/543,721 | 1995-10-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1997014733A1 WO1997014733A1 (fr) | 1997-04-24 |
WO1997014733B1 true WO1997014733B1 (fr) | 1997-05-15 |
Family
ID=24169307
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1996/016289 WO1997014733A1 (fr) | 1995-10-16 | 1996-10-11 | Matieres de revetement composees d'un polymere fluorocarbone acrylique et d'un polyisocyanate fluore |
Country Status (9)
Country | Link |
---|---|
US (2) | US5597874A (fr) |
EP (1) | EP0856021B1 (fr) |
JP (1) | JP4074340B2 (fr) |
AU (1) | AU706335B2 (fr) |
BR (1) | BR9611102A (fr) |
CA (1) | CA2234421C (fr) |
DE (1) | DE69603195T2 (fr) |
NZ (1) | NZ321114A (fr) |
WO (1) | WO1997014733A1 (fr) |
Families Citing this family (23)
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US5914384A (en) * | 1997-11-21 | 1999-06-22 | E. I. Du Pont De Nemours And Company | Coating compositions containing a highly fluorinated hydroxyl containing additive |
US6168866B1 (en) | 1998-08-19 | 2001-01-02 | 3M Innovative Properties Company | Abrasion and stain resistant curable fluorinated coating |
US6586530B1 (en) | 2001-09-27 | 2003-07-01 | Ppg Industries Ohio, Inc. | Low surface tension (meth) acrylate containing block copolymer prepared by controlled radical polymerization |
US6583223B2 (en) | 2001-09-27 | 2003-06-24 | Ppg Industries Ohio, Inc. | Coating compositions which contain a low surface tension (meth) acrylate containing block copolymer flow control agent |
US6841641B2 (en) * | 2001-09-27 | 2005-01-11 | Ppg Industries Ohio, Inc. | Copolymers comprising low surface tension (meth) acrylates |
US7288282B2 (en) * | 2003-09-22 | 2007-10-30 | E. I. Du Pont De Nemours And Company | Coating compositions containing a fluorinated organosilane polymer |
US6933005B2 (en) * | 2003-09-22 | 2005-08-23 | E. I. Du Pont De Nemours And Company | Method for achieving recoat adhesion over a fluorinated topcoat |
US7348389B2 (en) * | 2003-09-22 | 2008-03-25 | E. I. Du Pont De Nemours And Company | Method for achieving recoat adhesion over a fluorinated topcoat |
EP1990659A1 (fr) * | 2007-05-05 | 2008-11-12 | LG Display Co., Ltd. | Film optique et polariseur, feuille à prismes, unité de rétroéclairage et dispositif d'affichage utilisant le film optique, et procédé pour sa fabrication |
US9464160B2 (en) | 2010-08-27 | 2016-10-11 | The Chemours Company Fc, Llc | Fluorinated ethoxylated polyurethanes |
CN104159944B (zh) | 2011-11-30 | 2015-11-25 | 涂层国外知识产权有限公司 | 清漆涂料组合物 |
WO2013081815A1 (fr) | 2011-11-30 | 2013-06-06 | U.S. Coatings Ip Co. Llc | Composition de revêtement pour couche transparente |
CN104204018B (zh) | 2011-11-30 | 2019-07-23 | 涂层国外知识产权有限公司 | 涂料组合物 |
WO2013081816A1 (fr) | 2011-11-30 | 2013-06-06 | U.S. Coatings Ip Co. Llc | Composition de revêtement pour couche transparente |
RU2494875C1 (ru) * | 2012-02-29 | 2013-10-10 | Закрытое акционерное общество по разработке и внедрению новых информационных материалов и технологий "БИТ" | Защитное покрытие для энергосберегающих пленок |
CN105765012B (zh) | 2013-11-20 | 2019-08-16 | 大阪有机化学工业株式会社 | 透明涂层组合物 |
JP6157442B2 (ja) * | 2013-12-25 | 2017-07-05 | 大阪有機化学工業株式会社 | クリヤーコート組成物 |
CA2967878C (fr) * | 2014-12-08 | 2021-05-25 | Basf Coatings Gmbh | Compositions de moyens de revetements non aqueux, revetements fabriques a partir de celles-ci avec une adherence et une resistance ameliorees et leur utilisation |
KR20170093898A (ko) * | 2014-12-08 | 2017-08-16 | 바스프 코팅스 게엠베하 | 코팅 물질 조성물 및 그로부터 제조된 코팅 및 그의 용도 |
CN104710557A (zh) * | 2014-12-31 | 2015-06-17 | 佛山市顺德区巴德富实业有限公司 | 含氟丙烯酸酯乳液及其制备方法 |
WO2016176389A1 (fr) | 2015-04-30 | 2016-11-03 | The Chemours Company Tt, Llc | Additifs d'uréthane fluoré réticulable pour revêtements extérieurs durables |
US20180371151A1 (en) | 2015-11-11 | 2018-12-27 | Solvay Specialty Polymers Italy S.P.A. | Novel hydroxy-terminated (per)fluoropolyether-urethane polymers and their use in clear-coat compositions |
CN109929066A (zh) * | 2017-12-15 | 2019-06-25 | 上海飞凯光电材料股份有限公司 | 一种紫外光固化树脂、制备方法、涂料 |
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-
1995
- 1995-10-16 US US08/543,721 patent/US5597874A/en not_active Expired - Lifetime
-
1996
- 1996-10-11 CA CA002234421A patent/CA2234421C/fr not_active Expired - Fee Related
- 1996-10-11 BR BR9611102A patent/BR9611102A/pt not_active IP Right Cessation
- 1996-10-11 WO PCT/US1996/016289 patent/WO1997014733A1/fr active IP Right Grant
- 1996-10-11 NZ NZ321114A patent/NZ321114A/xx unknown
- 1996-10-11 JP JP51588497A patent/JP4074340B2/ja not_active Expired - Fee Related
- 1996-10-11 AU AU74392/96A patent/AU706335B2/en not_active Ceased
- 1996-10-11 DE DE69603195T patent/DE69603195T2/de not_active Expired - Fee Related
- 1996-10-11 EP EP96936367A patent/EP0856021B1/fr not_active Expired - Lifetime
- 1996-10-28 US US08/698,983 patent/US5705276A/en not_active Expired - Fee Related
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