WO1997007886A1 - Mangan enthaltende polyoxometallate, synthese und verwendung - Google Patents

Mangan enthaltende polyoxometallate, synthese und verwendung Download PDF

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Publication number
WO1997007886A1
WO1997007886A1 PCT/EP1996/003669 EP9603669W WO9707886A1 WO 1997007886 A1 WO1997007886 A1 WO 1997007886A1 EP 9603669 W EP9603669 W EP 9603669W WO 9707886 A1 WO9707886 A1 WO 9707886A1
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WO
WIPO (PCT)
Prior art keywords
range
subscript
falls
group
manganiferous
Prior art date
Application number
PCT/EP1996/003669
Other languages
English (en)
French (fr)
Inventor
Bernd Scharbert
Peter Schulz
Bernt Krebs
Rainer BÖHNER
Christina THÜLIG
Original Assignee
Hoechst Research & Technology Deutschland Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Research & Technology Deutschland Gmbh & Co. Kg filed Critical Hoechst Research & Technology Deutschland Gmbh & Co. Kg
Priority to EP96930061A priority Critical patent/EP0847305A1/de
Priority to JP9509810A priority patent/JPH11511428A/ja
Priority to US09/011,986 priority patent/US6022986A/en
Priority to BR9610366-3A priority patent/BR9610366A/pt
Publication of WO1997007886A1 publication Critical patent/WO1997007886A1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B19/00—Selenium; Tellurium; Compounds thereof
    • C01B19/002—Compounds containing, besides selenium or tellurium, more than one other element, with -O- and -OH not being considered as anions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/006—Compounds containing, besides manganese, two or more other elements, with the exception of oxygen or hydrogen
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
    • D21C9/10—Bleaching ; Apparatus therefor
    • D21C9/1026—Other features in bleaching processes
    • D21C9/1036—Use of compounds accelerating or improving the efficiency of the processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Mangan enthaltende katalytisch aktive Polyoxometallate der Formel(1) (Q)q (MnpAaXxYyMmOdZz(H2O)b) c H2O und Verfahren zu deren Herstellung. Die Symbole Q, A, X, Y, M, Z, q, p, a, x, y, m, z, d, b und c haben folgende Bedeutung: Q steht für eines oder mehrere Kationen ausgewählt aus der Gruppe H, Li, K, Na, Rb, Cs, Ca, Mg, Sr, Ba, Al, PR?1R2R3R4 und NR1R2R3R4 mit R1, R2, R3 und R4¿ = H oder C¿1?-C20-Alkyl, C5-C8-Cycloalkyl oder Aryl; der Index q liegt im Bereich von 1 bis 60, insbesondere im Bereich von 1 bis 40 und beschreibt bei einwertigen Gegenkationen gleichzeitig die Ladung der anionischen Einheit; Mn ist Mangan; der Index p liegt im Bereich von 0,1 bis 10; A ist ein Heterometall und steht für eines oder mehrere Übergangsmetalle der 2. bis 8. Nebengruppe außer Zn, insbesondere Ru, V, Ti, Zr, Cr, Fe, Co, Cu, Sn, Ni, Re oder Os; der Index a liegt im Bereich von 0 bis 10; X steht für eines oder mehrere Elemente ausgewählt aus der Gruppe Ga, B, P, Si, Ge, As, F, Cl, Br und J; der Index x liegt im Bereich von 0 bis 10; Y steht für Sb, S, Se, Te oder Bi; der Index y liegt im Bereich von 0,1 bis 10; M steht für eines oder mehrere Übergangsmetalle ausgewählt aus der Gruppe Mo, W, Nb, Ta und V; der Index m liegt im Bereich von 0,5 bis 60; Z steht für eines oder mehrere Anionen ausgewählt aus der Gruppe OH?-, F-, Cl-, Br-, I-, N¿3-, NO3-, ClO4-, NCS-, SCN-, PF¿6?-, RSO3-, RSO4-, CF3SO3-, BR4-, BF4-, OAc-, mit R = H, C¿1?-C20-Alkyl, C5-C8-Cycloalkyl oder Aryl; der Index z liegt im Bereich von 0 bis 10; der Index d steht für die zum Ladungsausgleich notwendige Anzahl von Sauerstoffatomen und b und c sind Zahlen im Bereich von 0 bis 50. Die beschriebenen Oxidationskatalysatoren aktivieren besonders gut peroxidische Verbindungen und Sauerstoff.
PCT/EP1996/003669 1995-08-22 1996-08-20 Mangan enthaltende polyoxometallate, synthese und verwendung WO1997007886A1 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP96930061A EP0847305A1 (de) 1995-08-22 1996-08-20 Mangan enthaltende polyoxometallate, synthese und verwendung
JP9509810A JPH11511428A (ja) 1995-08-22 1996-08-20 マンガン含有ポリオキソメタルレート、その合成および使用
US09/011,986 US6022986A (en) 1995-08-22 1996-08-20 Manganiferous polyoxometallates, synthesis and use thereof
BR9610366-3A BR9610366A (pt) 1995-08-22 1996-08-20 Polioxometalatos contendo manganês, sìntese e emprego

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19530787.9 1995-08-22
DE19530787A DE19530787A1 (de) 1995-08-22 1995-08-22 Mangan enthaltende Polyoxometallate, Synthese und Verwendung

Publications (1)

Publication Number Publication Date
WO1997007886A1 true WO1997007886A1 (de) 1997-03-06

Family

ID=7770054

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1996/003669 WO1997007886A1 (de) 1995-08-22 1996-08-20 Mangan enthaltende polyoxometallate, synthese und verwendung

Country Status (8)

Country Link
US (1) US6022986A (de)
EP (1) EP0847305A1 (de)
JP (1) JPH11511428A (de)
KR (1) KR19990044004A (de)
BR (1) BR9610366A (de)
CA (1) CA2230078A1 (de)
DE (1) DE19530787A1 (de)
WO (1) WO1997007886A1 (de)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999028426A1 (en) * 1997-12-03 1999-06-10 U.S. Borax Inc. Bleaching compositions
US6051108A (en) * 1998-07-28 2000-04-18 Nalco Chemical Company Method of removing and preventing the buildup of contaminants in papermaking processes
WO2003083030A1 (en) * 2002-03-28 2003-10-09 Unilever N.V. Liquid cleaning compositions and their use
EP3409757A1 (de) 2017-06-01 2018-12-05 Henkel AG & Co. KGaA Bleichendes wasch- oder reinigungsmittel
EP3409756A1 (de) 2017-06-01 2018-12-05 Henkel AG & Co. KGaA Bleichendes wasch- oder reinigungsmittel
EP3409753A1 (de) 2017-06-01 2018-12-05 Henkel AG & Co. KGaA Bleichverstärkung beim waschen und reinigen
DE102017209336A1 (de) 2017-06-01 2018-12-06 Henkel Ag & Co. Kgaa Bleichverstärkung beim Waschen und Reinigen

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19530786A1 (de) * 1995-08-22 1997-02-27 Hoechst Ag Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichkatalysator
DE19620241A1 (de) * 1996-05-20 1997-11-27 Patt R Prof Dr Verfahren zum Delignifizieren von Zellstoffen und Verwendung eines Katalysators
US5904734A (en) * 1996-11-07 1999-05-18 S. C. Johnson & Son, Inc. Method for bleaching a hard surface using tungsten activated peroxide
IL120942A0 (en) 1997-05-29 1997-09-30 Yissum Res Dev Co A process for the epoxidation of alkenes
US6914029B2 (en) * 2001-11-02 2005-07-05 California Institute Of Technology Polyoxometallate catalysts and catalytic processes
US7514577B2 (en) * 2006-05-31 2009-04-07 Exxonmobil Chemical Patents Inc. Pd- and Pt-substituted polyoxometalates and process for their preparation
US7820868B2 (en) * 2007-01-19 2010-10-26 Exxonmobil Chemical Patents Inc. Transition metal substituted polyoxometalates and process for their preparation
MY145938A (en) * 2007-02-14 2012-05-31 Avantor Performance Mat Inc Peroxide activated oxometalate based formulations for removal of etch residue
US7645907B2 (en) * 2007-03-23 2010-01-12 Exxonmobil Chemical Patents Inc. Transition metal substituted polyoxometalates and process for their preparation
RU2478426C2 (ru) * 2007-04-25 2013-04-10 Хрд Корп. Катализатор и способ конвертации природного газа в высокоуглеродистые соединения
CN103797181A (zh) * 2011-08-25 2014-05-14 鞠承沅 多金属氧化物及利用其制备的功能性纤维或织物
DE102014002854A1 (de) * 2014-02-27 2015-08-27 Forschungszentrum Jülich GmbH Starke Festkörpersäure auf der Basis eines Polyoxometalats und Herstellungsverfahren
CN113292417B (zh) * 2021-05-24 2023-05-23 赣南医学院 制备羧酸的方法
CN114195194B (zh) * 2021-11-12 2022-11-22 河南大学 一种同多钨酸盐及其制备方法
CN114380336B (zh) * 2021-12-10 2022-11-18 华南理工大学 一种锰中心的Keggin型锰钨酸盐及其制备方法与应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987001615A1 (en) * 1985-09-24 1987-03-26 Catalytica Associates Olefin oxidation catalyst system
US4864041A (en) * 1987-02-04 1989-09-05 Emory University Transition metal-substituted polyoxometalates as catalysts for homogenous liquid-phase organic oxidation processes
EP0353722A2 (de) * 1988-08-02 1990-02-07 UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation) Carbonylierungsverfahren
EP0466471A1 (de) * 1990-07-11 1992-01-15 Sun Refining and Marketing Company Alkanoxydierungskatalysatoren

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4424625A1 (de) * 1994-07-13 1996-01-18 Degussa Mikroporöse Heteropolyoxometallate und Verfahren zu ihrer Herstellung
DE19530786A1 (de) * 1995-08-22 1997-02-27 Hoechst Ag Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichkatalysator

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1987001615A1 (en) * 1985-09-24 1987-03-26 Catalytica Associates Olefin oxidation catalyst system
US4864041A (en) * 1987-02-04 1989-09-05 Emory University Transition metal-substituted polyoxometalates as catalysts for homogenous liquid-phase organic oxidation processes
EP0353722A2 (de) * 1988-08-02 1990-02-07 UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation) Carbonylierungsverfahren
EP0466471A1 (de) * 1990-07-11 1992-01-15 Sun Refining and Marketing Company Alkanoxydierungskatalysatoren

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999028426A1 (en) * 1997-12-03 1999-06-10 U.S. Borax Inc. Bleaching compositions
US6326342B1 (en) * 1997-12-03 2001-12-04 U.S. Borax Inc. Bleaching compositions
US6051108A (en) * 1998-07-28 2000-04-18 Nalco Chemical Company Method of removing and preventing the buildup of contaminants in papermaking processes
WO2003083030A1 (en) * 2002-03-28 2003-10-09 Unilever N.V. Liquid cleaning compositions and their use
EP3409757A1 (de) 2017-06-01 2018-12-05 Henkel AG & Co. KGaA Bleichendes wasch- oder reinigungsmittel
EP3409756A1 (de) 2017-06-01 2018-12-05 Henkel AG & Co. KGaA Bleichendes wasch- oder reinigungsmittel
EP3409753A1 (de) 2017-06-01 2018-12-05 Henkel AG & Co. KGaA Bleichverstärkung beim waschen und reinigen
DE102017209333A1 (de) 2017-06-01 2018-12-06 Henkel Ag & Co. Kgaa Bleichendes Wasch- oder Reinigungsmittel
DE102017209335A1 (de) 2017-06-01 2018-12-06 Henkel Ag & Co. Kgaa Bleichverstärkung beim Waschen und Reinigen
DE102017209336A1 (de) 2017-06-01 2018-12-06 Henkel Ag & Co. Kgaa Bleichverstärkung beim Waschen und Reinigen
DE102017209332A1 (de) 2017-06-01 2018-12-06 Henkel Ag & Co. Kgaa Bleichendes Wasch- oder Reinigungsmittel
EP3415593A1 (de) 2017-06-01 2018-12-19 Henkel AG & Co. KGaA Bleichverstärkung beim waschen und reinigen

Also Published As

Publication number Publication date
US6022986A (en) 2000-02-08
CA2230078A1 (en) 1997-03-06
KR19990044004A (ko) 1999-06-25
JPH11511428A (ja) 1999-10-05
BR9610366A (pt) 2000-03-08
EP0847305A1 (de) 1998-06-17
DE19530787A1 (de) 1997-02-27

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