BR9610366A - Polioxometalatos contendo manganês, sìntese e emprego - Google Patents
Polioxometalatos contendo manganês, sìntese e empregoInfo
- Publication number
- BR9610366A BR9610366A BR9610366-3A BR9610366A BR9610366A BR 9610366 A BR9610366 A BR 9610366A BR 9610366 A BR9610366 A BR 9610366A BR 9610366 A BR9610366 A BR 9610366A
- Authority
- BR
- Brazil
- Prior art keywords
- range
- index
- group
- chosen
- synthesis
- Prior art date
Links
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 title 1
- 239000011572 manganese Substances 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 229910052787 antimony Inorganic materials 0.000 abstract 1
- 229910052785 arsenic Inorganic materials 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052797 bismuth Inorganic materials 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052792 caesium Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000008602 contraction Effects 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- 229910052711 selenium Inorganic materials 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 229910052712 strontium Inorganic materials 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- 229910052714 tellurium Inorganic materials 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B19/00—Selenium; Tellurium; Compounds thereof
- C01B19/002—Compounds containing, besides selenium or tellurium, more than one other element, with -O- and -OH not being considered as anions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/006—Compounds containing, besides manganese, two or more other elements, with the exception of oxygen or hydrogen
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1026—Other features in bleaching processes
- D21C9/1036—Use of compounds accelerating or improving the efficiency of the processes
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/86—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by NMR- or ESR-data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Patente de Invenção<B>"POLIOXOMETALATOS CONTENDO MANGANêS, SìNTESE E EMPREGO"<D>. Polioxometalatos cataliticamente ativos contendo manganês da fórmula (1) e processos para a sua preparação (Q)~ q~(Mn~ p~ A~ a~ X~ x~Y~ y ~M~ m~ o~ d~ Z~ z~(H~ 2~o)~ b~)cH~ 2~o) (1), Os símbolos Q, A, X, Y, M, Z, q, p, a, x, y, m, z, d, b, e c têm o seguinte significado: Q representa um ou vários cátions escolhidos do grupo H, Li, K, Na, Rb, Cs, Ca, Mg, Sr, Ba, Al, PR^ 1^R^ 2^R^ 3^R^ 4^ e NR^ 1^, R^ 2^, R^ 3^ e R^ 4^ com R^ 1^, R^ 2^, R^ 3^ e R^ 4^ = H ou C~ 1~C~ 20~-alquila, C~ 5~-C~ 8~-cicloalquila ou arila; o índice q encontra-se na faixa de 1 até 60, especialmente na faixa de 1 até 40 e descreve nos contracátions monovalentes simultaneamente a carga das unidades aniónicas; Mn é manganês; o índice p encontra-se na faixa de 0,1 até 10; A é um heterometal e representa um ou vários metais de transição do 2° até 8° subgrupo além de Zn, especialmente Ru, V, Ti, Zr, Cr, Fe, Co, Cu, Sn, Ni, Re ou os; o índice a encontra-se na faixa de 0 até 10; X representa um ou vários elementos escolhidos do grupo Ga, B, P, Si, Ge, As, F, Cl, Br e J; o índice x encontra-se na faixa de 0 até 10; Y representa Sb, S, Te, Se e Bi; o índice Y encontra-se na faixa de 0,1 até 10; M representa um ou vários metais de transição escolhidos do grupo Mo, W, Nb, Ta e V; o índice m encontra-se na faixa de 0,5 até 60; Z representa um ou vários ânions escolhidos do grupo oH^ -^, F^ -^, Cl^ -^, Br^ -^, I^ -^, N~ 3~^ -^, No^ -^, Clo~ 4~^ -^, NCS-, SCN-, PF~ 6~^ -^, RSo~ 3~^ -^, CF~ 3~So~ 3~^ -^, BR~ 4~^ -^, BF~ 4~^ -^oAc^ -^, com R = H, C~ 1~-C~ 20~-alquila, C~ 5~-C~ 8~-cicloalquila ou arila; o índice z encontra-se na faixa de 0 até 10; o índice d representa o número de átomos de oxigênio necessário para o equilíbrio da carga e b e c são números na faixa de 0 até 50. os catalisadores de oxidação descritos ativam particularmente bem compostos peroxídicos e oxigênio.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19530787A DE19530787A1 (de) | 1995-08-22 | 1995-08-22 | Mangan enthaltende Polyoxometallate, Synthese und Verwendung |
| PCT/EP1996/003669 WO1997007886A1 (de) | 1995-08-22 | 1996-08-20 | Mangan enthaltende polyoxometallate, synthese und verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9610366A true BR9610366A (pt) | 2000-03-08 |
Family
ID=7770054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9610366-3A BR9610366A (pt) | 1995-08-22 | 1996-08-20 | Polioxometalatos contendo manganês, sìntese e emprego |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6022986A (pt) |
| EP (1) | EP0847305A1 (pt) |
| JP (1) | JPH11511428A (pt) |
| KR (1) | KR19990044004A (pt) |
| BR (1) | BR9610366A (pt) |
| CA (1) | CA2230078A1 (pt) |
| DE (1) | DE19530787A1 (pt) |
| WO (1) | WO1997007886A1 (pt) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19530786A1 (de) * | 1995-08-22 | 1997-02-27 | Hoechst Ag | Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichkatalysator |
| DE19620241A1 (de) * | 1996-05-20 | 1997-11-27 | Patt R Prof Dr | Verfahren zum Delignifizieren von Zellstoffen und Verwendung eines Katalysators |
| US5904734A (en) * | 1996-11-07 | 1999-05-18 | S. C. Johnson & Son, Inc. | Method for bleaching a hard surface using tungsten activated peroxide |
| IL120942A0 (en) | 1997-05-29 | 1997-09-30 | Yissum Res Dev Co | A process for the epoxidation of alkenes |
| GB9725614D0 (en) * | 1997-12-03 | 1998-02-04 | United States Borax Inc | Bleaching compositions |
| US6051108A (en) * | 1998-07-28 | 2000-04-18 | Nalco Chemical Company | Method of removing and preventing the buildup of contaminants in papermaking processes |
| US6914029B2 (en) * | 2001-11-02 | 2005-07-05 | California Institute Of Technology | Polyoxometallate catalysts and catalytic processes |
| GB0207430D0 (en) * | 2002-03-28 | 2002-05-08 | Unilever Plc | Liquid cleaning compositionsand their use |
| US7514577B2 (en) * | 2006-05-31 | 2009-04-07 | Exxonmobil Chemical Patents Inc. | Pd- and Pt-substituted polyoxometalates and process for their preparation |
| US7820868B2 (en) * | 2007-01-19 | 2010-10-26 | Exxonmobil Chemical Patents Inc. | Transition metal substituted polyoxometalates and process for their preparation |
| MY145938A (en) * | 2007-02-14 | 2012-05-31 | Avantor Performance Mat Inc | Peroxide activated oxometalate based formulations for removal of etch residue |
| US7645907B2 (en) * | 2007-03-23 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Transition metal substituted polyoxometalates and process for their preparation |
| CA2684896A1 (en) * | 2007-04-25 | 2008-11-06 | Hrd Corp. | Catalyst and method for converting natural gas to higher carbon compounds |
| WO2013028035A2 (ko) * | 2011-08-25 | 2013-02-28 | Kook Seung Won | 신규 금속다중산화물과 금속다중산화물을 이용하여 제조된 기능성 섬유 또는 직물 |
| DE102014002854A1 (de) * | 2014-02-27 | 2015-08-27 | Forschungszentrum Jülich GmbH | Starke Festkörpersäure auf der Basis eines Polyoxometalats und Herstellungsverfahren |
| DE102017209335A1 (de) | 2017-06-01 | 2018-12-06 | Henkel Ag & Co. Kgaa | Bleichverstärkung beim Waschen und Reinigen |
| DE102017209332A1 (de) | 2017-06-01 | 2018-12-06 | Henkel Ag & Co. Kgaa | Bleichendes Wasch- oder Reinigungsmittel |
| DE102017209336A1 (de) | 2017-06-01 | 2018-12-06 | Henkel Ag & Co. Kgaa | Bleichverstärkung beim Waschen und Reinigen |
| DE102017209333A1 (de) | 2017-06-01 | 2018-12-06 | Henkel Ag & Co. Kgaa | Bleichendes Wasch- oder Reinigungsmittel |
| CN113292417B (zh) * | 2021-05-24 | 2023-05-23 | 赣南医学院 | 制备羧酸的方法 |
| CN114195194B (zh) * | 2021-11-12 | 2022-11-22 | 河南大学 | 一种同多钨酸盐及其制备方法 |
| CN114380336B (zh) * | 2021-12-10 | 2022-11-18 | 华南理工大学 | 一种锰中心的Keggin型锰钨酸盐及其制备方法与应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4720474A (en) * | 1985-09-24 | 1988-01-19 | Catalytica Associates | Olefin oxidation catalyst system |
| US4864041A (en) * | 1987-02-04 | 1989-09-05 | Emory University | Transition metal-substituted polyoxometalates as catalysts for homogenous liquid-phase organic oxidation processes |
| US5218140A (en) * | 1988-08-02 | 1993-06-08 | Union Carbide Chemicals & Plastics Technology Corporation | Carbonylation reaction and catalyst therefor |
| US5091354A (en) * | 1988-10-07 | 1992-02-25 | Sun Refining And Marketing Company | Alkane oxidation catalysts |
| DE4424625A1 (de) * | 1994-07-13 | 1996-01-18 | Degussa | Mikroporöse Heteropolyoxometallate und Verfahren zu ihrer Herstellung |
| DE19530786A1 (de) * | 1995-08-22 | 1997-02-27 | Hoechst Ag | Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichkatalysator |
-
1995
- 1995-08-22 DE DE19530787A patent/DE19530787A1/de not_active Withdrawn
-
1996
- 1996-08-20 BR BR9610366-3A patent/BR9610366A/pt not_active Application Discontinuation
- 1996-08-20 WO PCT/EP1996/003669 patent/WO1997007886A1/de active IP Right Grant
- 1996-08-20 KR KR1019980701236A patent/KR19990044004A/ko active IP Right Grant
- 1996-08-20 CA CA002230078A patent/CA2230078A1/en not_active Abandoned
- 1996-08-20 US US09/011,986 patent/US6022986A/en not_active Expired - Fee Related
- 1996-08-20 JP JP9509810A patent/JPH11511428A/ja active Pending
- 1996-08-20 EP EP96930061A patent/EP0847305A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP0847305A1 (de) | 1998-06-17 |
| DE19530787A1 (de) | 1997-02-27 |
| JPH11511428A (ja) | 1999-10-05 |
| US6022986A (en) | 2000-02-08 |
| KR19990044004A (ko) | 1999-06-25 |
| WO1997007886A1 (de) | 1997-03-06 |
| CA2230078A1 (en) | 1997-03-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| TC | Change of name | ||
| FB36 | Technical and formal requirements: requirement - article 36 of industrial property law | ||
| FA8 | Dismissal: dismissal - article 36, par. 1 of industrial property law |