GB1382640A - Oxidation of sulphur and sulphur compounds to so2 - Google Patents

Oxidation of sulphur and sulphur compounds to so2

Info

Publication number
GB1382640A
GB1382640A GB3057472A GB3057472A GB1382640A GB 1382640 A GB1382640 A GB 1382640A GB 3057472 A GB3057472 A GB 3057472A GB 3057472 A GB3057472 A GB 3057472A GB 1382640 A GB1382640 A GB 1382640A
Authority
GB
United Kingdom
Prior art keywords
catalyst
oxidation
sulphur
alumina
nickel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3057472A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of GB1382640A publication Critical patent/GB1382640A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/48—Sulfur dioxide; Sulfurous acid
    • C01B17/50—Preparation of sulfur dioxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

1382640 Oxidation catalyst INSTITUT FRANCAIS DU PETROLE 29 June 1972 [1 July 1971] 30574/72 Heading B1E [Also in Division C1] A catalyst for the oxidation of sulphur compounds in waste gas streams comprises a mixed oxide of the spinal type formed with iron and/or chromium and zinc and/or nickel, any other divalent metals present in the catalyst being at most 20% of the total metal content. At least 60% by weight of the catalyst has the spinel structure. The catalyst may be of the formula M x Cr z Fe 2-z O u where 0.2#x #2; 0.1#z #1.9; and 3.2 #u #9 and wherein M is a divalent metal either zinc and/ or nickel and may contain optionally a minor proportion of copper, cobalt, magnesium or cadmium. The catalyst may be supported on a carrier such as alumina, alumina-silica, aluminates and silicon carbide.
GB3057472A 1971-07-01 1972-06-29 Oxidation of sulphur and sulphur compounds to so2 Expired GB1382640A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7124194A FR2144148A5 (en) 1971-07-01 1971-07-01

Publications (1)

Publication Number Publication Date
GB1382640A true GB1382640A (en) 1975-02-05

Family

ID=9079705

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3057472A Expired GB1382640A (en) 1971-07-01 1972-06-29 Oxidation of sulphur and sulphur compounds to so2

Country Status (7)

Country Link
JP (1) JPS4828364A (en)
BE (1) BE785069A (en)
DE (1) DE2232027A1 (en)
FR (1) FR2144148A5 (en)
GB (1) GB1382640A (en)
IT (1) IT956890B (en)
NL (1) NL7208967A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4382912A (en) 1981-09-10 1983-05-10 Gulf Research & Development Company Selective combusting of hydrogen sulfide in carbon dioxide injection gas
EP0033424B1 (en) * 1980-01-02 1988-05-11 Exxon Research And Engineering Company Removal of sulfur and/or sulfur compound from industrial process streams using metal alumina spinel
FR2626784A1 (en) * 1988-02-09 1989-08-11 Inst Kataliza Sibirskogo Otdel PROCESS FOR PURIFYING GAS CONTAINING HYDROGEN SULFIDE
EP0385123A2 (en) * 1989-02-07 1990-09-05 W.R. Grace & Co.-Conn. Thermally stable ferrites for reduction of hydrogen sulfide emissions from automobile exhaust
EP0851787A1 (en) * 1995-05-17 1998-07-08 Parsons Process Group Inc. Process for selective oxidation
US6682638B1 (en) 1999-11-19 2004-01-27 Perkin Elmer Llc Film type solid polymer ionomer sensor and sensor cell
WO2004088280A2 (en) 2003-03-26 2004-10-14 Perkinelmer Life And Analytical Sciences Method and apparatus for improved gas detection
US6929735B2 (en) 1999-11-19 2005-08-16 Perkin Elmer Instruments Llc Electrochemical sensor having improved response time
US7013707B2 (en) 1999-11-19 2006-03-21 Perkinelmer Las, Inc Method and apparatus for enhanced detection of a specie using a gas chromatograph
US7404882B2 (en) 1999-11-19 2008-07-29 Perkinelmer Las, Inc. Film-type solid polymer ionomer sensor and sensor cell
US8048682B2 (en) 2007-04-30 2011-11-01 Ut-Battelle, Llc Device and method for detecting sulfur dioxide at high temperatures
WO2012037113A1 (en) * 2010-09-13 2012-03-22 Conocophillips Company Low temperature sulfur tolerant tar and sulfur removal with contomitant synthesis gas conditioning

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0039266B1 (en) * 1980-04-23 1984-10-24 Rhone-Poulenc Specialites Chimiques Oxidation process of hydrogen sulfide and organic compounds of sulfur
SU1219134A1 (en) * 1983-05-26 1986-03-23 Азербайджанский Институт Нефти И Химии Им.М.Азизбекова Catalyst for gas-phase oxidation of hydrogen sulphide to sulphur

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0033424B1 (en) * 1980-01-02 1988-05-11 Exxon Research And Engineering Company Removal of sulfur and/or sulfur compound from industrial process streams using metal alumina spinel
US4382912A (en) 1981-09-10 1983-05-10 Gulf Research & Development Company Selective combusting of hydrogen sulfide in carbon dioxide injection gas
FR2626784A1 (en) * 1988-02-09 1989-08-11 Inst Kataliza Sibirskogo Otdel PROCESS FOR PURIFYING GAS CONTAINING HYDROGEN SULFIDE
EP0385123A2 (en) * 1989-02-07 1990-09-05 W.R. Grace & Co.-Conn. Thermally stable ferrites for reduction of hydrogen sulfide emissions from automobile exhaust
EP0385123A3 (en) * 1989-02-07 1990-09-12 W.R. Grace & Co.-Conn. Thermally stable ferrites for reduction of hydrogen sulfide emissions from automobile exhaust
EP0851787A1 (en) * 1995-05-17 1998-07-08 Parsons Process Group Inc. Process for selective oxidation
EP0851787A4 (en) * 1995-05-17 1998-12-09 Parsons Process Group Inc Process for selective oxidation
US7404882B2 (en) 1999-11-19 2008-07-29 Perkinelmer Las, Inc. Film-type solid polymer ionomer sensor and sensor cell
US6929735B2 (en) 1999-11-19 2005-08-16 Perkin Elmer Instruments Llc Electrochemical sensor having improved response time
US7013707B2 (en) 1999-11-19 2006-03-21 Perkinelmer Las, Inc Method and apparatus for enhanced detection of a specie using a gas chromatograph
US7237430B2 (en) 1999-11-19 2007-07-03 Perkinelmer Las, Inc. Method and apparatus for enhanced detection of a specie using a gas chromatograph
US6682638B1 (en) 1999-11-19 2004-01-27 Perkin Elmer Llc Film type solid polymer ionomer sensor and sensor cell
US7429362B2 (en) 1999-11-19 2008-09-30 Perkinelmer Las, Inc. Method and apparatus for improved gas detection
WO2004088280A2 (en) 2003-03-26 2004-10-14 Perkinelmer Life And Analytical Sciences Method and apparatus for improved gas detection
US8048682B2 (en) 2007-04-30 2011-11-01 Ut-Battelle, Llc Device and method for detecting sulfur dioxide at high temperatures
WO2012037113A1 (en) * 2010-09-13 2012-03-22 Conocophillips Company Low temperature sulfur tolerant tar and sulfur removal with contomitant synthesis gas conditioning
GB2498292A (en) * 2010-09-13 2013-07-10 Phillips 66 Co Low temperture sulfur tolerant tar and sulfur removal with contomitant synthesis gas conditioning
AU2011302289B2 (en) * 2010-09-13 2017-01-05 Lummus Technology Llc Low temperature sulfur tolerant tar and sulfur removal with concomitant synthesis gas conditioning
GB2498292B (en) * 2010-09-13 2017-11-08 Lummus Technology Inc Low temperature sulfur tolerant tar and sulfur removal with concomitant synthesis gas conditioning

Also Published As

Publication number Publication date
JPS4828364A (en) 1973-04-14
FR2144148A5 (en) 1973-02-09
BE785069A (en) 1972-12-19
IT956890B (en) 1973-10-10
NL7208967A (en) 1973-01-03
DE2232027A1 (en) 1973-01-11

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee