WO1996005901A1 - Verfahren und vorrichtung zur regelung und steuerung einer destillations- oder kondensationsapparatur - Google Patents
Verfahren und vorrichtung zur regelung und steuerung einer destillations- oder kondensationsapparatur Download PDFInfo
- Publication number
- WO1996005901A1 WO1996005901A1 PCT/DE1995/001176 DE9501176W WO9605901A1 WO 1996005901 A1 WO1996005901 A1 WO 1996005901A1 DE 9501176 W DE9501176 W DE 9501176W WO 9605901 A1 WO9605901 A1 WO 9605901A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cooling water
- temperature
- cooling
- controller
- interference signal
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/42—Regulation; Control
Definitions
- the invention relates to a method and a device for regulating and controlling a distillation or condensation apparatus, which comprises a boiling vessel, a heating source and a cooler.
- a mixture is placed in a reaction flask over a heating source, e.g. a magnetic stirrer with heating device, a heating mushroom, an electric hotplate or the like, heated to boiling.
- a heating source e.g. a magnetic stirrer with heating device, a heating mushroom, an electric hotplate or the like
- the resulting steam is condensed on a heat sink through which the coolant flows and, in the case of distillation, placed in a receiver.
- the steam or gas only condenses and drips back into the reaction flask. The latter enables a chemical reaction to be carried out at constant temperature.
- a temperature sensor integrated in the heating plate usually serves to monitor the temperature of the heating device.
- Modern magnetic stirrers with a heating device also have another thermometer for precise temperature control of the material to be stirred, which is designed in the form of a cross-silver contact thermometer or a thermometer based on semiconductors or resistance and projects directly into the material to be stirred or the heating bath surrounding the reaction flask .
- This thermometer can be connected to the electronics of the magnetic stirrer device via a plug connection.
- Distillation or condensation apparatus such as Liebig coolers, descending reflux coolers or Allihn, Friedrichs, Graham, Dimroth coolers, are regularly connected to a cooling water inlet valve via a hose connection, while the cooling water flowing through the cooler is directly connected to another piece of hose the drain is derived.
- a cooling water flow subjectively appropriate to the size of the cooler is then set.
- drinking water quantities 0.6 1 / min to well over 3 1 / min are used.
- thermostats are known in the laboratory, which can be connected to condensation apparatus.
- Thermostats that work with methanol or other organic solutions such as R 134a as a coolant have a closed cooling circuit and thus the disadvantage that the required cooling must be carried out via a heat exchanger, which is associated with high energy losses.
- these facilities do not have sufficient security functions.
- the devices are very voluminous and take up a large part of the available laboratory or production area.
- the invention has for its object to provide a method and a device of the type mentioned that allow a significant reduction in the cooling water consumption.
- This object is achieved in the process according to the invention in that the cooling water flowing through the cooler of the distillation or condensation apparatus is conducted in a circuit, its temperature is recorded in the circuit and, when an upper temperature value is reached, it is replaced by supplying cold water until a lower temperature value is reached is.
- Distillation apparatuses are already known from DD 290 587 A5 and DD 150 984, in which the cooling water flow is regulated as a function of the temperature of the cooling water flowing through. In contrast to the present invention, the cooling water is not circulated in these known apparatuses.
- the invention is based on the knowledge that the temperature difference between the cooler and the steam to be condensed need only be a few degrees Celsius in order to ensure complete condensation. So it is neither necessary nor useful, for example toluene to be condensed with a temperature difference of almost 90 ° C. A larger cooling surface would only be required to compensate for the reduced cooling capacity in the limit range of the temperature difference. This is already the case in the properly operated reaction routines, because normally only about 10 - 20% of the available cooling surface is used for the condensation. The same applies to the condensation in Liebig coolers.
- a method is proposed in which, after the cooling device has been filled once, the cooling water circulates in a circuit until it has warmed up to a freely selectable temperature. Only then does a cooling water exchange take place until the circulating cooling water has cooled down again to a certain predetermined temperature. Through these intervals, cooling water savings of well over 80% can be achieved.
- the method consists in recording the time profile of the cooling water temperature and in the event of a positive temperature gradient exceeding a predefinable limit value and / or an interference signal being triggered in the case of a negative temperature gradient.
- the positive limit value is always exceeded if the solution or suspension is heated too much. On the other hand, falling below the negative limit value occurs in the event of an intentional or unwanted termination of the distillation or condensation.
- Another safety function which reduces the risk of an accident can consist in that an interference signal is triggered if, despite the supply of cold water, there is no decrease in the cooling water temperature.
- Another advantageous development is characterized in that the power consumption of a pump arranged in the cooling water circuit is detected and an interference signal is triggered when a predeterminable upper target value is exceeded and / or when a predeterminable lower target value is undershot.
- the cooling water flow in the cooling circuit and the pump can be monitored.
- the pump's power consumption will be too high if an overflow device provided in the cooling water circuit is blocked or if the hose connections are kinked; on the other hand, the power consumption will be too low if the hose connections have burst or torn off or if the cooling water supply line is inadequate.
- the interference signals mentioned can advantageously be used for a defined shutdown of the distillation or condensation apparatus. For example, if an interference signal occurs, the heating source and / or after a specific, predefinable duration, the
- a further advantageous embodiment consists in that a valve connected to the cooling water circuit is opened for a predetermined period of time when an interference signal occurs and, if the interference signal is still present, a pump arranged in the cooling water circuit and possibly an agitator of the apparatus are switched off.
- a valve connected to the cooling water circuit is opened for a predetermined period of time when an interference signal occurs and, if the interference signal is still present, a pump arranged in the cooling water circuit and possibly an agitator of the apparatus are switched off.
- the course of the cooling water temperature over time is recorded and the heating power of the heating source is controlled as a function of the temperature gradient.
- the optimal heating bath temperature can be set independently for each solution or suspension.
- the device according to the invention solves the problem of high cooling water consumption by means of a cooling water regulator which can be connected to the cooler of the distillation or condensation apparatus to form a cooling water circuit and a valve which can be connected to a cold water line and is controlled by a regulator and a temperature sensor arranged in the cooling water circuit has, the controller controls the valve such that it is opened when an upper cooling water temperature is reached until the cooling water temperature reaches a lower value.
- An expedient embodiment of the device according to the invention consists in the arrangement of a pump within the cooling water circuit. This configuration should be chosen because the differences in density that occur during heating are not sufficient for a natural circulation of the cooling water.
- Another advantageous embodiment is that the cooling water circuit is designed as an open system with an overflow device. This ensures that the pressure inside the device does not rise when the cooling water is heated. In contrast to domestic water heating devices, the device is therefore not subject to the provisions of the pressure container regulation.
- FIG. 1 shows a side view of a partially broken open condensation apparatus with a device according to the invention, which comprises a magnetic stirrer, a heating source and a cooling water regulator;
- FIG. 4 shows a circuit diagram for the heating source, the stirrer and the power pack of a device according to the invention according to FIG. 1;
- FIG. 5 shows a circuit diagram of a pump control
- Fig. 6 is a circuit diagram of a valve control
- FIG. 7 shows a functional circuit diagram of a switching amplifier and a switch-off plan which is designed to be flexible when certain interference signals occur.
- FIG. 1 schematically shows a condensation apparatus which has a boiling vessel 13 arranged in a heating bath 19 and a reflux condenser 8.
- the apparatus is regulated and controlled by a device according to the invention, which comprises a magnetic stirrer 200, a heating source 10 and a cooling water regulator 100.
- the cooling water regulator 100 essentially consists of a controllable cold water line valve 1, a pump 2, an overflow device 3, a temperature sensor 4, a control connection 5 and an inlet and an outlet connection 6a, 6b. At these connecting pieces 6a, 6b, the cooling water regulator 100 is connected to the cooler 8 via hose pieces 7a, 7b to form a cooling water circuit. In addition, one or more sensors (not shown in their design) for measuring the cooling water level and / or the cooling water circulation are provided in the cooling water regulator 100 or the cooling water circuit.
- the magnetic stirrer 200 has a base plate 9 with a heating source 10. Below the mounting plate 9 there is a temperature sensor 12 connected to the heating source 10 and a device suitable for generating a magnetic rotating field which rotates a magnetic stirring rod 14 located in the boiling vessel 13. For regulation and control, there is an electronic unit, generally referred to as a regulator, in the interior of the agitator housing. On the case back On the side there is a connection socket 17a for a safety thermometer 16 and a second connection socket 17b for the cooling water regulator 100.
- Potentiometers 15a and 15b are arranged on the front of the housing.
- the power of the heating source 10 and thus the heating bath temperature can be controlled manually via the potentiometer 15a.
- the potentiometer 15b enables the setting of an upper target value ⁇ max cooling for the cooling water temperature.
- a lower setpoint ⁇ min cooling for the cooling water temperature can be specified in the controller via a further potentiometer 15b.
- the device is designed such that after the device is switched on, the controller first opens the valve 1 of the cooling water regulator 100, which is connected to a cold water line, for a specific time.
- cold tap water flows into the cooling water regulator 100, which is conveyed to the cooler 8 via the pump 2 and the lower hose section 7a, also fills the latter and enters the cooling water regulator 100 again via the other hose section 7b. Excess cooling water and the air present in the cooling water circuit are displaced via the overflow device 3.
- valve 1 After the cooling water circuit has been filled, valve 1 is closed. Then both the pump 2 and the temperature sensor 4 deliver their respective signals to the controller via the connecting line. At the same time, the heat source 10 of the magnetic stirrer 200 is activated. The liquid in the boiling vessel 13 is heated via the heating bath 19 and begins to filter after some time (cf. FIGS. 2 and 3, point A). The rising steam is condensed in the reflux condenser 8 and thus drips then back into the boiling vessel 13. This cools the cooling water in cooler 8. When a maximum cooling water temperature (point B) is reached, valve 1 is opened again. Now fresh cooling water flows into the cooling water circuit until the cooling water temperature reaches a lower limit (point C). As soon as this limit value is reached, valve 1 is closed again and the cooling water can heat up again. This process is repeated until the device is switched off manually.
- FIGS. 2a and 2b show the cooling water temperature-time curve for methanol (2a) and diethyl ether (2b). It can be seen that with normal condensation, the temperature of the cooling water in the
- cooling water consumption is plotted in liters over time in minutes in FIGS. 2a and 2b.
- FIG. 4 shows a possible circuit diagram for the magnetic stirrer, the heat source and an electronic power supply unit for the, without specifying the final design Shown controller.
- the circuit also enables the connection of an external heating source.
- an IEC socket with protective contact L 20 and a bridge BR 20 are provided, via which the controller of the internal heating source 10 can be short-circuited.
- the power supply unit 20 is a direct voltage power supply unit which is designed on the primary side for 220 volts 50 Hz alternating voltage. On the secondary side, the power supply unit 20 supplies smoothed, stabilized, short-circuit-proof direct voltages of 24 volts for the cold water supply valve 1 and 12 volts for the pump 2 as well as a reference voltage of 2.95 volts. All voltages present at the cooling water regulator are thus low voltages that are harmless to humans.
- the pump 2 is controlled by an amplifier V5 via a shunt resistor Rjj (shunt).
- the voltage drop of the shunt resistor serves as an analog value for the
- the filters F 4 and Fs which have a predominantly integrating effect, detect larger deviations in the pump outputs as interference signals, the interference signal Spl being triggered when the power consumption is too high and the interference signal Sp2 being triggered when the power consumption is too low.
- the interference signal Spl is triggered when the pressure in the cooling water regulator 100 is too high, which occurs, for example, in the case of blockages in the cooling water circuit or in the case of kinked hose connections 7a, 7b.
- the interference signal Sp2 on the other hand, is triggered when the amount of cooling water is too low, for example in the event of burst or torn off hose sections 7a, 7b or inadequate cooling water supply. In this way, the cooling water flow in the cooler 8 is monitored intrinsically safe.
- the preamplifier V 4 is used to switch the pump 2 on and off.
- the cooling water temperature is regulated by a temperature sensor 4, the characteristic of which is linearized and adapted in a amplifier Vi and is given as a signal ⁇ to a window discriminator V2.
- OS denotes the via potentiometer 15b (see. Fig. 1)
- T max cooling is a bistable RS flip-flop flip-flop set and the solenoid-controlled valve 1 opened via a short-circuit proof switching amplifier V 3 . If the cooling value falls below T m , the flip-flop is reset and valve 1 is closed.
- the time course of the cooling water temperature is monitored by filters F] _, F2 and F 3 .
- the inputs of the filters Fi and F2 have predominantly differentiating behavior (d ⁇ / dt).
- the filter F2 triggers the interference signal Sw2 when the cooling water temperature gradient takes on negative values. This case occurs when the first component has been distilled out in a fractional distillation of a mixture (FIG. 3 point X); but also if the liquid to be condensed was evaporated to a minimum during distillation or heating under reflux.
- the filter F] _ triggers the interfering signal Sy ⁇ l when the cooling water temperature gradient takes on positive values that are too high.
- the filter F 3 supplies the interference signal S 3 when a manipulated variable limitation occurs. This is the case if, despite the incoming cold water, the cooling water temperature is not below the upper setpoint T max cooling 9 e_ can be brought. This case occurs, for example, when the cold water supply is restricted or has failed.
- the course of the cooling water temperature is thus continuously recorded and used to control and secure the distillation or condensation apparatus.
- a switching amplifier SV1 is shown schematically in FIG. 7, which controls the filling of the cooling water circuit and possibly the reset phase (reset) of the device according to the invention and also monitors the safety thermometer 16 arranged in the heating bath 19 and controls the heating source 10 via a connection d4.
- the heating power is regulated until the set maximum heating bath temperature T max heating bath is reached so that the temperature gradient of the heating bath 19 is largely constant between 3 and 5 ° C./min. In this way, an energy-optimal heating of the liquid to be condensed is achieved.
- the safety thermometer 16 is preferably designed as a semiconductor or resistance thermometer.
- the switching amplifier SV1 initiates the shutdown processes described below when the interference signals Spl, Sp2, Sjl, S ⁇ 2 and / or Sw3 occur.
- the interference signals Spl Sp2, S ⁇ l, Sw2 or Sw3 occur, the heating source 10 is switched off immediately in all cases and an optical and / or acute signal is triggered with corresponding signal transmitters 21 or 22.
- the signals of the safety thermometer 16 cause the heating source 10 to be switched on and off, depending on whether the heating bath temperature set on the potentiometer 15a has been reached or fallen below. If an external magnetic stirrer with a heater and a safety thermometer is connected to the controller 11, its signals are passed on unchanged to the safety device of this external device.
- a new start pulse is triggered, which opens the valve 1 for a certain period. If a new interference signal occurs after this process, then a switch-off plan 2 is followed, in which the valve 1 is not opened again, but rather the pump 2 and then the magnetic stirrer are switched off after a certain period. Since the occurrence of the interference signals Spl and Sp2 always means a malfunction of the cooling water supply, valve 1 is not opened again in the shutdown schedule 2.
- the heating source 10 is likewise first switched off and the valve 1 is opened for a specific duration. If the fault cannot be remedied within this time, then switch-off plan 1 is followed; i.e. valve 1 is opened and closed after, for example, 8 minutes. Pump 2 is then switched off after approx. 16 min and the agitator after approx. 32 min.
- the switching amplifier SV1 is connected to counters ZI and Z2.
- the heating source remains switched off and the optical and / or acoustic signal continues to be switched on.
- the faults can be reset with a reset button.
- a start pulse is triggered and the device is brought into the starting position.
- the embodiment of the invention is not limited to the preferred embodiment described above. example. Rather, a number of variants are conceivable which make use of the solution shown, even in the case of fundamentally different types.
- the implementation is not limited to implementation with discrete logic modules, but can also advantageously be implemented with programmed logic, preferably using a microprocessor.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95929731A EP0725667A1 (de) | 1994-08-25 | 1995-08-24 | Verfahren und vorrichtung zur regelung und steuerung einer destillations- oder kondensationsapparatur |
US08/632,478 US5976323A (en) | 1994-08-24 | 1995-08-24 | Method and a device for the control of a distillation or condensation apparatus |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4431400.0 | 1994-08-25 | ||
DE4431400A DE4431400C1 (de) | 1994-08-25 | 1994-08-25 | Verfahren und Vorrichtung zur Regelung und Steuerung einer Destillations- oder Kondensationsapparatur |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996005901A1 true WO1996005901A1 (de) | 1996-02-29 |
Family
ID=6527331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE1995/001176 WO1996005901A1 (de) | 1994-08-24 | 1995-08-24 | Verfahren und vorrichtung zur regelung und steuerung einer destillations- oder kondensationsapparatur |
Country Status (5)
Country | Link |
---|---|
US (1) | US5976323A (de) |
EP (1) | EP0725667A1 (de) |
CA (1) | CA2174853A1 (de) |
DE (1) | DE4431400C1 (de) |
WO (1) | WO1996005901A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008051364A1 (de) | 2008-10-15 | 2010-04-22 | Ika-Werke Gmbh & Co. Kg | Rotationsverdampfer |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6409882B1 (en) * | 1999-10-22 | 2002-06-25 | Westvaco Corporation | Tall oil refining improvement |
NZ511502A (en) * | 2001-05-04 | 2002-03-01 | Wen Sen Shih | Two-chamber water distillation apparatus |
KR100528498B1 (ko) * | 2002-09-26 | 2005-11-15 | 동양제철화학 주식회사 | 증류-적하 반응장치를 이용한 히드로실릴화 반응 방법 |
US20080011598A1 (en) * | 2006-07-13 | 2008-01-17 | Chun Jung Chen | Freshwater Recycling System |
DE102012008612A1 (de) * | 2012-04-27 | 2013-10-31 | Ika-Werke Gmbh & Co. Kg | Temperaturmessvorrichtung |
CN102974115B (zh) * | 2012-12-18 | 2014-07-23 | 济南大学 | 自动控制的分馏装置 |
US10000723B2 (en) * | 2014-01-28 | 2018-06-19 | Young Living Essential Oils, Lc | Distillation system |
CN111114969B (zh) * | 2020-02-03 | 2020-11-13 | 烟台海市葡萄酒有限公司 | 一种双模式蒸馏液体存储设备 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4344826A (en) * | 1980-06-20 | 1982-08-17 | Vaponics, Inc. | Distillation system and process |
DE3248501A1 (de) * | 1982-12-29 | 1984-07-05 | Peter W. D. van der 4926 Dörentrup Heijden | Kuehlvorrichtung fuer vakuum-destillierapparate und verfahren zur durchfuehrung der destillationskuehlung |
DE3001995C2 (de) * | 1980-01-21 | 1989-06-22 | Peter 7600 Offenburg De Huber |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD150984A3 (de) * | 1980-05-15 | 1981-09-30 | Lothar Hertzsch | Destillationsapparatur mit geregeltem kuehlwasserdurchlauf und darauf abgestimmter destillatmenge |
IT8253837V0 (it) * | 1982-10-21 | 1982-10-21 | Gaggia Brevetti | Apparecchio distillatore particolarmente per uso domestico |
DD290587A5 (de) * | 1989-12-21 | 1991-06-06 | Veb Werk F. Technisches Glas Ilmenau,De | Destillationsapparatur mit reduziertem kuehlwasserdurchlauf |
-
1994
- 1994-08-25 DE DE4431400A patent/DE4431400C1/de not_active Expired - Fee Related
-
1995
- 1995-08-24 CA CA002174853A patent/CA2174853A1/en not_active Abandoned
- 1995-08-24 EP EP95929731A patent/EP0725667A1/de not_active Withdrawn
- 1995-08-24 WO PCT/DE1995/001176 patent/WO1996005901A1/de not_active Application Discontinuation
- 1995-08-24 US US08/632,478 patent/US5976323A/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3001995C2 (de) * | 1980-01-21 | 1989-06-22 | Peter 7600 Offenburg De Huber | |
US4344826A (en) * | 1980-06-20 | 1982-08-17 | Vaponics, Inc. | Distillation system and process |
DE3248501A1 (de) * | 1982-12-29 | 1984-07-05 | Peter W. D. van der 4926 Dörentrup Heijden | Kuehlvorrichtung fuer vakuum-destillierapparate und verfahren zur durchfuehrung der destillationskuehlung |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008051364A1 (de) | 2008-10-15 | 2010-04-22 | Ika-Werke Gmbh & Co. Kg | Rotationsverdampfer |
DE102008051364B4 (de) * | 2008-10-15 | 2012-03-15 | Ika-Werke Gmbh & Co. Kg | Rotationsverdampfer |
US8894822B2 (en) | 2008-10-15 | 2014-11-25 | Ika-Werke Gmbh & Co. Kg | Rotary evaporator |
Also Published As
Publication number | Publication date |
---|---|
DE4431400C1 (de) | 1995-10-19 |
US5976323A (en) | 1999-11-02 |
CA2174853A1 (en) | 1996-02-29 |
EP0725667A1 (de) | 1996-08-14 |
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