WO1994026857A1 - Melanges detergents aqueux - Google Patents
Melanges detergents aqueux Download PDFInfo
- Publication number
- WO1994026857A1 WO1994026857A1 PCT/EP1994/001399 EP9401399W WO9426857A1 WO 1994026857 A1 WO1994026857 A1 WO 1994026857A1 EP 9401399 W EP9401399 W EP 9401399W WO 9426857 A1 WO9426857 A1 WO 9426857A1
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- Prior art keywords
- alkyl
- anionic
- cationic
- nonionic
- amphoteric
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
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- C—CHEMISTRY; METALLURGY
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
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- C—CHEMISTRY; METALLURGY
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/06—Ether- or thioether carboxylic acids
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/126—Acylisethionates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/16—Sulfonic acids or sulfuric acid esters; Salts thereof derived from divalent or polyvalent alcohols
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/32—Protein hydrolysates; Fatty acid condensates thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
Definitions
- the invention relates to aqueous detergent mixtures containing alkyl and / or alkenyl oligoglycoside isethionates and other surfactants, surface-active agents which contain these mixtures and the use of the mixtures for the preparation of the surface-active agents.
- Alkyl oligoglycosides and especially alkyl oligoglucosides are non-ionic surfactants, which are becoming increasingly important due to their natural raw material base - fatty alcohol and sugar - and are used, for example, in manual detergents or cosmetic products [cf. Tens. Surf.Det. 28, 413 (1991)].
- anionic surfactants with a related structure that can be used advantageously in conjunction with other classic surfactants in surface-active agents and whose performance synergistically exceeds that of the individual substances.
- the object of the invention was therefore to develop synergistic detergent mixtures based on anionically modified alkyl and / or alkenyl oligoglycosides with further improved properties.
- the invention relates to aqueous detergent mixtures comprising a) alkyl and / or alkenyl oligoglycoside isethionates and b) further anionic, nonionic, cationic and / or ampholytic or zwitterionic surfactants.
- the detergent mixtures according to the invention have a washing, rinsing, foaming and cleaning ability and a skin-cosmetic tolerance which exceeds that of the individual substances in the sense of a synergistic reinforcement.
- the mixtures are particularly suitable for use in the cosmetics sector.
- Mixtures of alkyl oligoglucoside isethionates and the corresponding alkyl oligoglucosides, as well as fatty acid N-methylglucamides and vegetable protein hydrolysates or fatty acid condensates (for example based on soy protein) have proven to be particularly skin-friendly.
- Alkyl and / or alkenyl oligoglycoside isethionates are anionic surfactants and follow the formula (I),
- Alkyl oligoglucoside isethionates of the formula (I) are particularly preferred, in which R 1 for an alkyl radical having 12 to 18 carbon atoms, X for sodium or magnesium, G for a glucose radical and p for numbers from 1 to 3, in particular 1.1 to 1.9 stands.
- anionic surfactants are alkyl benzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfate, hydroxymix ether sulfates, monoglyceride sulfate sulfate ether sulfate, sulfate ether sulfate, sulfate fatty acid Sarcosinates, taurides, alkyl oligoglucoside sulfates, alkyl (ether) phosphates and vegetable or animal protein hydrolyzates or their condensation products with fatty acids. If the anionic surfactants contain polyglycol ether chains, they can have polyglycol
- nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, alk (en) yl oligoglycosides, fatty acid glucamides, polyol fatty acid esters and sugar esters, sorbitan sorbitan. If the nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
- cationic surfactants are quaternary ammonium compounds and quaternized difatty acid trialkanolamine esters.
- amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
- the surfactants mentioned are exclusively known compounds. With regard to the structure and manufacture of these substances, reference is made to relevant reviews, for example, J.Falbe (ed.), “Surfactants in Consumer Products”, Springer Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), “Catalysts, Tenside und Mineralöladditive ", Thieme Verlag, Stuttgart, 1978, pp. 123-217.
- the aqueous detergent mixtures according to the invention can contain the alkyl and / or alkenyl oligoglycoside isethionates in amounts of 1 to 99, preferably 30 to 75% by weight, based on the solids content of the mixtures.
- the aqueous detergent mixtures can be prepared by simple mechanical mixing of the aqueous solutions of the components, if appropriate at elevated temperatures of 30 to 50 ° C; a chemical reaction does not take place here.
- Powdered universal detergent containing 10 to 30 wt .-% - based on the agent - a mixture of alkyl and / or alkenyl oligoglycoside isethionates and anionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants and optionally other auxiliaries and additives .
- Liquid mild detergent containing 10 to 5C% by weight, based on the detergent, of a mixture of alkyl and / or alkenyl oligoglycoside isethionates and of nonionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants and optionally other auxiliaries. and additives.
- Liquid cleaning and disinfecting agents containing 10 to 30% by weight, based on the agent, of a mixture of alkyl and / or alkenyl oligoglycoside isethionates and anionic, nonionic, cavionic and / or amphoteric or zwitterionic surfactants and, if appropriate other auxiliaries and additives.
- hair shampoos containing 10 to 30% by weight, based on the composition, of a mixture of alkyl and / or alkenyl oligoglycoside isethionates and anionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants and optionally other auxiliaries and additives.
- Hair conditioners containing 10 to 30% by weight, based on the composition, of a mixture of alkyl and / or alkenyl oligoglycoside isethionates and anionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants and optionally other auxiliaries and
- Syndet soaps containing 10 to 50% by weight, based on the agent, of a mixture of alkyl and / or alkenyl oligoglycoside isethionates and anionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants and optionally other auxiliaries and additives.
- Flotation aids containing 10 to 95% by weight, based on the composition, of a mixture of alkyl and / or alkenyl oligoglycoside isethionates and anionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants and optionally other auxiliaries and additives.
- Detergents and cleaning agents based on the detergent mixture according to the invention can contain, for example, builders, salts, bleaches, bleach activators, optical brighteners, graying inhibitors, solubilizers, defoamers and enzymes as auxiliaries and additives.
- Common builders are sodium aluminum silicates (zeolites), phosphates, phosphonates, ethylenediaminetetraacetic acid, nitrilotriacetate, citric acid and / or polycarboxylates.
- Suitable salts or adjusting agents are, for example, sodium sulfate, sodium carbonate or sodium silicate (water glass).
- Typical individual examples of further additives are sodium borate, starch, sucrose, polydextrose, TAED, stilbene compounds, methyl cellulose, toluenesulfonate, cumene sulfonate, long-chain soaps, silicones, mixed ethers, lipases and proteases.
- Hair shampoos, hair lotions or foam baths based on the detergent mixtures according to the invention can contain, for example, emulsifiers, oil components, fats and waxes, thickeners, superfatting agents, biogenic agents, film formers, fragrances, dyes, pearlescent agents, preservatives and pH regulators as auxiliaries and additives.
- Common oil components are substances such as paraffin oil, vegetable oils, fatty acid esters, squalane and 2-octyldodecanol, while fats and waxes are used, for example, as walrus, beeswax, montan wax, paraffin and cetylstearyl alcohol.
- Substances such as, for example, polyethoxylated lanolin derivatives, lecithin derivatives and fatty acid alkanolamides can be used as superfatting agents, the latter also serve as foam stabilizers.
- Suitable thickeners are, for example, polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, furthermore higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinyl pyrrolidone and ammonium chloride such as sodium chloride.
- Biogenic active substances are understood to mean, for example, plant extracts, protein hydrolyzates and vitamin complexes.
- Common film formers are, for example, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives and similar compounds.
- Suitable preservatives are, for example, formaldehyde solution, p-hydroxybenzoate or sorbic acid.
- Suitable pearlizing agents are, for example, glycol distearic acid esters such as ethylene glycol distearate, but also fatty acid monoglycol esters.
- the dyes which can be used are those substances which are suitable and approved for cosmetic purposes, as compiled, for example, in the publication "Cosmetic Dyes" by the Dye Commission of the German Research Foundation, published by Verlag Chemie, Weinheim, 1984. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
- the detergent mixtures according to the invention are notable for excellent washing, rinsing, foaming and cleaning performance and for advantageous skin-cosmetic and ecotoxicological compatibility.
- Another object of the invention therefore relates to their use for the production of washing, rinsing, cleaning and flotation aids, products for hair and body care, in which they are present in amounts of 1 to 99, preferably 10 to 30,% by weight on the means - may be included.
- NV network assets
Abstract
Des mélanges détergents aqueux contenant a) des alkyl- et/ou alkényloligoglucosidiséthionates et b) d'autres tensio-actifs anioniques, non ioniques, cationiques et/ou ampholytiques ou zwitterioniques présentent des effets synergiques du point de vue de leur capacité de lavage, de rinçage, de production de mousse et de nettoyage ainsi que de leur tolérance cutanée. Ils conviennent donc pour la préparation d'un grand nombre de produits tensio-actifs.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4315810.2 | 1993-05-12 | ||
DE4315810A DE4315810A1 (de) | 1993-05-12 | 1993-05-12 | Wäßrige Detergensgemische |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994026857A1 true WO1994026857A1 (fr) | 1994-11-24 |
Family
ID=6487872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1994/001399 WO1994026857A1 (fr) | 1993-05-12 | 1994-05-03 | Melanges detergents aqueux |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE4315810A1 (fr) |
WO (1) | WO1994026857A1 (fr) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU698964B2 (en) * | 1994-11-23 | 1998-11-12 | Colgate-Palmolive Company, The | Microemulsion light duty liquid cleaning compositions |
WO2005120442A1 (fr) * | 2004-06-05 | 2005-12-22 | Henkel Kommanditgesellschaft Auf Aktien | Utilisation de derives d'oligoglucosides d'alkyle/alcenyle dans des produits destines au traitement de fibres keratiniques |
DE102013218616A1 (de) | 2013-09-17 | 2015-03-19 | Henkel Ag & Co. Kgaa | Verwendung von Alkyl-/Alkenyl-Oligoglykosidderivaten zur Textilbehandlung |
DE102014223885A1 (de) | 2014-11-24 | 2016-05-25 | Henkel Ag & Co. Kgaa | Flüssigwaschmittel enthaltend Zitronensäure und Niotensid |
DE102015201698A1 (de) | 2015-01-30 | 2016-08-04 | Henkel Ag & Co. Kgaa | Saures Flüssigkompaktwaschmittel enthaltend Hydroxycarbonsäure, Niotensid und a-Amylase |
DE102015201702A1 (de) | 2015-01-30 | 2016-08-04 | Henkel Ag & Co. Kgaa | Saures Flüssigkompaktwaschmittel enthaltend Hydroxycarbonsäure, Niotensid und Enzym |
DE102015215591A1 (de) | 2015-08-14 | 2017-02-16 | Henkel Ag & Co. Kgaa | Wasserarme, zweiphasige Flüssigwaschmittel mit saurem pH-Wert |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4425449A1 (de) * | 1994-07-19 | 1996-01-25 | Henkel Kgaa | Detergensgemische mit verbesserter Reinigungsleistung |
DE19544453A1 (de) * | 1995-11-29 | 1997-06-05 | Henkel Kgaa | Syndet-Seifenmassen |
DE19723763C2 (de) * | 1997-06-06 | 2000-02-24 | Goldwell Gmbh | Haarwaschmittel |
DE19942539A1 (de) * | 1999-09-07 | 2001-03-08 | Cognis Deutschland Gmbh | Waschmittel |
US6562874B1 (en) | 1999-12-07 | 2003-05-13 | Unilever Home & Personal Care Usa Division Of Conopco, Inc. | Compositions comprising combination of DEFI and modified DEFI and methods of making |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4536319A (en) * | 1983-10-04 | 1985-08-20 | The Procter & Gamble Company | Compositions comprising alkylpolysaccharide detergent surfactant |
US4545898A (en) * | 1983-05-27 | 1985-10-08 | Berol Kemi Ab | Process for froth flotation |
EP0219057A2 (fr) * | 1985-10-17 | 1987-04-22 | Henkel Kommanditgesellschaft auf Aktien | Utilisation d'agents tensioactifs non-ioniques comme réactifs pour la flottation de minerais non sulfurés |
WO1988001640A1 (fr) * | 1986-09-05 | 1988-03-10 | A.E. Staley Manufacturing Company | Derives ioniques de mono et polyglycosides d'alkyle |
DE3918135A1 (de) * | 1989-06-03 | 1990-12-13 | Henkel Kgaa | Sulfierte alkenylglykoside als tenside |
DE4136783A1 (de) * | 1991-11-08 | 1993-05-13 | Henkel Kgaa | Alkyl- und/oder alkenyloligoglykosid-isethionate |
-
1993
- 1993-05-12 DE DE4315810A patent/DE4315810A1/de not_active Ceased
-
1994
- 1994-05-03 WO PCT/EP1994/001399 patent/WO1994026857A1/fr active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4545898A (en) * | 1983-05-27 | 1985-10-08 | Berol Kemi Ab | Process for froth flotation |
US4536319A (en) * | 1983-10-04 | 1985-08-20 | The Procter & Gamble Company | Compositions comprising alkylpolysaccharide detergent surfactant |
EP0219057A2 (fr) * | 1985-10-17 | 1987-04-22 | Henkel Kommanditgesellschaft auf Aktien | Utilisation d'agents tensioactifs non-ioniques comme réactifs pour la flottation de minerais non sulfurés |
WO1988001640A1 (fr) * | 1986-09-05 | 1988-03-10 | A.E. Staley Manufacturing Company | Derives ioniques de mono et polyglycosides d'alkyle |
DE3918135A1 (de) * | 1989-06-03 | 1990-12-13 | Henkel Kgaa | Sulfierte alkenylglykoside als tenside |
DE4136783A1 (de) * | 1991-11-08 | 1993-05-13 | Henkel Kgaa | Alkyl- und/oder alkenyloligoglykosid-isethionate |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU698964B2 (en) * | 1994-11-23 | 1998-11-12 | Colgate-Palmolive Company, The | Microemulsion light duty liquid cleaning compositions |
WO2005120442A1 (fr) * | 2004-06-05 | 2005-12-22 | Henkel Kommanditgesellschaft Auf Aktien | Utilisation de derives d'oligoglucosides d'alkyle/alcenyle dans des produits destines au traitement de fibres keratiniques |
DE102013218616A1 (de) | 2013-09-17 | 2015-03-19 | Henkel Ag & Co. Kgaa | Verwendung von Alkyl-/Alkenyl-Oligoglykosidderivaten zur Textilbehandlung |
DE102014223885A1 (de) | 2014-11-24 | 2016-05-25 | Henkel Ag & Co. Kgaa | Flüssigwaschmittel enthaltend Zitronensäure und Niotensid |
DE102015201698A1 (de) | 2015-01-30 | 2016-08-04 | Henkel Ag & Co. Kgaa | Saures Flüssigkompaktwaschmittel enthaltend Hydroxycarbonsäure, Niotensid und a-Amylase |
DE102015201702A1 (de) | 2015-01-30 | 2016-08-04 | Henkel Ag & Co. Kgaa | Saures Flüssigkompaktwaschmittel enthaltend Hydroxycarbonsäure, Niotensid und Enzym |
US10329517B2 (en) | 2015-01-30 | 2019-06-25 | Henkel Ag & Co. Kgaa | Acid liquid compact washing agent including hydroxycarboxylic acid, non-ionic surfactant, and an-amylase |
US10577562B2 (en) | 2015-01-30 | 2020-03-03 | Henkel Ag & Co. Kgaa | Acid liquid compact washing agent including hydroxycarboxylic acid, non-ionic surfactant, and an enzyme |
DE102015215591A1 (de) | 2015-08-14 | 2017-02-16 | Henkel Ag & Co. Kgaa | Wasserarme, zweiphasige Flüssigwaschmittel mit saurem pH-Wert |
Also Published As
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DE4315810A1 (de) | 1994-11-17 |
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