WO1990015550A1 - Pearlescent ornament and dress ornament - Google Patents
Pearlescent ornament and dress ornament Download PDFInfo
- Publication number
- WO1990015550A1 WO1990015550A1 PCT/JP1990/000649 JP9000649W WO9015550A1 WO 1990015550 A1 WO1990015550 A1 WO 1990015550A1 JP 9000649 W JP9000649 W JP 9000649W WO 9015550 A1 WO9015550 A1 WO 9015550A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- luminescent material
- artificial
- pearls
- synthetic resin
- matrix
- Prior art date
Links
- 239000000463 material Substances 0.000 claims abstract description 29
- 239000011247 coating layer Substances 0.000 claims abstract description 14
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 14
- 239000000057 synthetic resin Substances 0.000 claims abstract description 14
- 239000011049 pearl Substances 0.000 claims description 37
- 239000002932 luster Substances 0.000 claims description 12
- 239000011159 matrix material Substances 0.000 claims description 12
- 238000004020 luminiscence type Methods 0.000 claims description 7
- 230000000694 effects Effects 0.000 abstract description 4
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229910052984 zinc sulfide Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000004936 stimulating effect Effects 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- VQTGUFBGYOIUFS-UHFFFAOYSA-N nitrosylsulfuric acid Chemical compound OS(=O)(=O)ON=O VQTGUFBGYOIUFS-UHFFFAOYSA-N 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C17/00—Gems or the like
- A44C17/007—Special types of gems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F9/00—Designs imitating natural patterns
- B44F9/08—Designs imitating natural patterns of crystalline structures, pearl effects, or mother-of-pearl effects
Definitions
- the invention relates to ornaments and garments with pearl luster.
- artificial pearl itself has been known as a product having pearl luster.
- Artificial pearls for example, merely form a pearlescent coating layer on a matrix made of synthetic resin.
- the present invention has been made to solve the problems of the related art, and a luminescent material is mixed in a matrix made of a synthetic resin, and an artificial surface is formed on the outer surface of the matrix.
- the temple with the layer of pearls is called a temple.
- Examples of products that are subject to the invention include decorations such as necklaces, earrings, breathlets, brooches, hair clasps, neck bins, and cow buttons. And clothing items such as clothing buttons.
- a synthetic resin for example, a urea resin, a styrene resin, or the like may be used.
- Luminescence (which refers to afterglow, including light and phosphorescence in this specification) is, for example, a long activator using copper as an activator. What consists of phosphorescent zinc sulfide (ZnS: Cu) which is a luster pigment having afterglow of time may be used.
- ZnS phosphorescent zinc sulfide
- the mixing ratio of the mother resin and the luminescent material is determined in consideration of the luminance of the luminescent material and the molding strength of the mother material.
- the ratio of the synthetic resin and the luminescent material is 87 to 93 wt% of the synthetic resin and the luminescent material is 7 to 13 wt%, the And almost perfect pearl luster. If the proportion of the luminescent material exceeds 13 wt%, it will be lost sharply.
- the luminous pigment absorbs and accumulates sunlight or electric light, gradually releases the luminous pigment to emit light, and the absorption, accumulation, and emission can be performed repeatedly. Is preferred.
- the luminescent material should be selected to emit light in the dark as long as possible, and its luminous intensity should be constant even with stimulating light of relatively low illuminance. However, it is preferable to select a material that reaches a saturation value in a predetermined time regardless of the luminous intensity or the intensity of the stimulating light.
- the coating of the coating layer may be performed, for example, as follows.
- a resin containing a luminescent material is formed into a predetermined shape, and the molded product is made into, for example, an artificial pearl ether in a solution of nitrose cellulose. It should be immersed in a mixture of sensation (basic lead carbonate, etc.) or natural pearl essence (tachiwo scale, etc.).
- the thickness of the coating layer is preferably from 0.01 to 0.10 mm, and more preferably from 0.03 to 0.05 mm. Within this range for example, a better pearl luster can be obtained and a better luminescence effect can be achieved.
- the inventor of the present invention obtained an idea that if a luminescent material is added to a base made of a synthetic resin, an artificial pearl product having a unique taste can be obtained.
- the present inventor further investigated the mixing ratio of the synthetic resin and the luminescent material, and found that the mixing ratio also affected the pearl luster. I found it. In other words, if the ratio of the synthetic resin to the luminescent material is 87 to 93 wt% and the luminescent material is 7 to 13 wt%, then in bright light Almost perfect pearl luster is obtained. If the proportion of the luminescent material exceeds 13 wt%, the pearlescent light is rapidly lost.
- FIG. 1 is a sectional view showing an embodiment of the present invention
- FIG. 2 is a perspective view showing an embodiment to which the artificial pearl shown in FIG. 1 is applied
- FIG. 3 is a sectional view of a clothing button showing another embodiment.
- 1 is an artificial pearl product (apparel button, artificial pearl), 2 is the mother body, 3 is a coating layer.
- FIG. 1 shows an embodiment of the present invention.
- An artificial pearl 1 is composed of a matrix 2 and a coating layer 3.
- urea resin was used as the resin, and phosphorescent zinc sulfide (ZnS: Cu) was used as the luminescence material.
- the resin was mixed at a ratio of 90 wt% and the luminescent material at a ratio of 1 wt%, and molded into the shape shown in FIG. Then, it was immersed 5 times in a mixture of a natural pearl essence (such as a scale of Tachiwo) in a solution of nitrocellulose to form a coating layer 3.
- the thickness of the coating layer 3 was about 0.3 mm.
- Fig. 2 shows the case where artificial pearl 1 shown in Fig. 1 is applied to neckless 4, and in this case, the connecting thread is used for molding artificial mother 2 on each artificial pearl 1.
- a through hole is formed to allow the air to pass through.
- Figs. 3 (a) and (b) show examples of clothing buttons.
- the manufacturing method is the same as in Example 1.
- the shape of the button is not limited to a spherical shape and a hemispherical shape, but may be any shape.
- Example 4 Example 4
- artificial pearls and intrinsic pearls are alternately connected to make them neckless.
- the necklace was partially illuminated, giving it a unique taste.
- a luminescent material is mixed with a base made of a synthetic resin, and a pearlescent coating layer is formed on the outer surface of the base, so that it becomes luminous.
- a pearlescent coating layer is formed on the outer surface of the base, so that it becomes luminous.
Landscapes
- Adornments (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7342489 | 1989-06-22 | ||
| JP1/73424U | 1989-06-22 | ||
| JP1989121242U JPH0426005Y2 (enrdf_load_stackoverflow) | 1989-06-22 | 1989-10-17 | |
| JP1/121242U | 1989-10-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1990015550A1 true WO1990015550A1 (en) | 1990-12-27 |
Family
ID=26414563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP1990/000649 WO1990015550A1 (en) | 1989-06-22 | 1990-05-22 | Pearlescent ornament and dress ornament |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH0426005Y2 (enrdf_load_stackoverflow) |
| WO (1) | WO1990015550A1 (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000069303A1 (de) * | 1999-05-15 | 2000-11-23 | Richard Seidenbusch | Lumineszierender schmuckgegenstand |
| CN101912186A (zh) * | 2010-07-31 | 2010-12-15 | 王玲瑞 | 一种夜光珍珠及其加工工艺 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4939630B1 (enrdf_load_stackoverflow) * | 1971-07-12 | 1974-10-26 | ||
| JPS60177090A (ja) * | 1984-02-21 | 1985-09-11 | Takiron Co Ltd | 発光性線材 |
| JPS60160713U (ja) * | 1984-04-05 | 1985-10-25 | 松本 とし子 | 蓄光性アクセサリ− |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6080402A (ja) * | 1983-10-07 | 1985-05-08 | 上田 直和 | ルミネツセンスとオ−ロラ−フイルム等混合の人工宝石 |
| JPS60212104A (ja) * | 1984-04-09 | 1985-10-24 | 富士真珠工業株式会社 | 人工真珠、及びその製造法 |
-
1989
- 1989-10-17 JP JP1989121242U patent/JPH0426005Y2/ja not_active Expired
-
1990
- 1990-05-22 WO PCT/JP1990/000649 patent/WO1990015550A1/ja unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4939630B1 (enrdf_load_stackoverflow) * | 1971-07-12 | 1974-10-26 | ||
| JPS60177090A (ja) * | 1984-02-21 | 1985-09-11 | Takiron Co Ltd | 発光性線材 |
| JPS60160713U (ja) * | 1984-04-05 | 1985-10-25 | 松本 とし子 | 蓄光性アクセサリ− |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000069303A1 (de) * | 1999-05-15 | 2000-11-23 | Richard Seidenbusch | Lumineszierender schmuckgegenstand |
| CN101912186A (zh) * | 2010-07-31 | 2010-12-15 | 王玲瑞 | 一种夜光珍珠及其加工工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0426005Y2 (enrdf_load_stackoverflow) | 1992-06-23 |
| JPH0360517U (enrdf_load_stackoverflow) | 1991-06-13 |
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