WO1990015550A1 - Pearlescent ornament and dress ornament - Google Patents

Pearlescent ornament and dress ornament Download PDF

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Publication number
WO1990015550A1
WO1990015550A1 PCT/JP1990/000649 JP9000649W WO9015550A1 WO 1990015550 A1 WO1990015550 A1 WO 1990015550A1 JP 9000649 W JP9000649 W JP 9000649W WO 9015550 A1 WO9015550 A1 WO 9015550A1
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WIPO (PCT)
Prior art keywords
luminescent material
artificial
pearls
synthetic resin
matrix
Prior art date
Application number
PCT/JP1990/000649
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French (fr)
Japanese (ja)
Inventor
Takuzi Siota
Original Assignee
Takuzi Siota
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Publication date
Application filed by Takuzi Siota filed Critical Takuzi Siota
Publication of WO1990015550A1 publication Critical patent/WO1990015550A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
    • A44C17/00—Gems or the like
    • A44C17/007—Special types of gems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F9/00—Designs imitating natural patterns
    • B44F9/08—Designs imitating natural patterns of crystalline structures, pearl effects, or mother-of-pearl effects

Definitions

  • the invention relates to ornaments and garments with pearl luster.
  • artificial pearl itself has been known as a product having pearl luster.
  • Artificial pearls for example, merely form a pearlescent coating layer on a matrix made of synthetic resin.
  • the present invention has been made to solve the problems of the related art, and a luminescent material is mixed in a matrix made of a synthetic resin, and an artificial surface is formed on the outer surface of the matrix.
  • the temple with the layer of pearls is called a temple.
  • Examples of products that are subject to the invention include decorations such as necklaces, earrings, breathlets, brooches, hair clasps, neck bins, and cow buttons. And clothing items such as clothing buttons.
  • a synthetic resin for example, a urea resin, a styrene resin, or the like may be used.
  • Luminescence (which refers to afterglow, including light and phosphorescence in this specification) is, for example, a long activator using copper as an activator. What consists of phosphorescent zinc sulfide (ZnS: Cu) which is a luster pigment having afterglow of time may be used.
  • ZnS phosphorescent zinc sulfide
  • the mixing ratio of the mother resin and the luminescent material is determined in consideration of the luminance of the luminescent material and the molding strength of the mother material.
  • the ratio of the synthetic resin and the luminescent material is 87 to 93 wt% of the synthetic resin and the luminescent material is 7 to 13 wt%, the And almost perfect pearl luster. If the proportion of the luminescent material exceeds 13 wt%, it will be lost sharply.
  • the luminous pigment absorbs and accumulates sunlight or electric light, gradually releases the luminous pigment to emit light, and the absorption, accumulation, and emission can be performed repeatedly. Is preferred.
  • the luminescent material should be selected to emit light in the dark as long as possible, and its luminous intensity should be constant even with stimulating light of relatively low illuminance. However, it is preferable to select a material that reaches a saturation value in a predetermined time regardless of the luminous intensity or the intensity of the stimulating light.
  • the coating of the coating layer may be performed, for example, as follows.
  • a resin containing a luminescent material is formed into a predetermined shape, and the molded product is made into, for example, an artificial pearl ether in a solution of nitrose cellulose. It should be immersed in a mixture of sensation (basic lead carbonate, etc.) or natural pearl essence (tachiwo scale, etc.).
  • the thickness of the coating layer is preferably from 0.01 to 0.10 mm, and more preferably from 0.03 to 0.05 mm. Within this range for example, a better pearl luster can be obtained and a better luminescence effect can be achieved.
  • the inventor of the present invention obtained an idea that if a luminescent material is added to a base made of a synthetic resin, an artificial pearl product having a unique taste can be obtained.
  • the present inventor further investigated the mixing ratio of the synthetic resin and the luminescent material, and found that the mixing ratio also affected the pearl luster. I found it. In other words, if the ratio of the synthetic resin to the luminescent material is 87 to 93 wt% and the luminescent material is 7 to 13 wt%, then in bright light Almost perfect pearl luster is obtained. If the proportion of the luminescent material exceeds 13 wt%, the pearlescent light is rapidly lost.
  • FIG. 1 is a sectional view showing an embodiment of the present invention
  • FIG. 2 is a perspective view showing an embodiment to which the artificial pearl shown in FIG. 1 is applied
  • FIG. 3 is a sectional view of a clothing button showing another embodiment.
  • 1 is an artificial pearl product (apparel button, artificial pearl), 2 is the mother body, 3 is a coating layer.
  • FIG. 1 shows an embodiment of the present invention.
  • An artificial pearl 1 is composed of a matrix 2 and a coating layer 3.
  • urea resin was used as the resin, and phosphorescent zinc sulfide (ZnS: Cu) was used as the luminescence material.
  • the resin was mixed at a ratio of 90 wt% and the luminescent material at a ratio of 1 wt%, and molded into the shape shown in FIG. Then, it was immersed 5 times in a mixture of a natural pearl essence (such as a scale of Tachiwo) in a solution of nitrocellulose to form a coating layer 3.
  • the thickness of the coating layer 3 was about 0.3 mm.
  • Fig. 2 shows the case where artificial pearl 1 shown in Fig. 1 is applied to neckless 4, and in this case, the connecting thread is used for molding artificial mother 2 on each artificial pearl 1.
  • a through hole is formed to allow the air to pass through.
  • Figs. 3 (a) and (b) show examples of clothing buttons.
  • the manufacturing method is the same as in Example 1.
  • the shape of the button is not limited to a spherical shape and a hemispherical shape, but may be any shape.
  • Example 4 Example 4
  • artificial pearls and intrinsic pearls are alternately connected to make them neckless.
  • the necklace was partially illuminated, giving it a unique taste.
  • a luminescent material is mixed with a base made of a synthetic resin, and a pearlescent coating layer is formed on the outer surface of the base, so that it becomes luminous.
  • a pearlescent coating layer is formed on the outer surface of the base, so that it becomes luminous.

Abstract

A pearlescent ornament or dress ornament composed of an artificial pearl (1) characterized by being formed of a base material (2) made of a synthetic resin containing a luminescent material and coated with a coating layer (3), thereby exhibiting luminous and gracious effects.

Description

B月 細 書  B month book
真珠光沢を有する装飾品および服飾品  Ornaments and garments with pearl luster
技術分野 Technical field
*発明は真珠光沢を有する装飾品および服飾品に関す る もの である。  * The invention relates to ornaments and garments with pearl luster.
背景技術 - 従来、 真珠光沢を有する製品と し ては、 人造真珠そ の も のが 知 られていた。 人造真珠は例えば合成樹脂か ら成る母体に单に 真珠光沢の被膜層を形成 していた に過ぎない。 Background Art-Conventionally, artificial pearl itself has been known as a product having pearl luster. Artificial pearls, for example, merely form a pearlescent coating layer on a matrix made of synthetic resin.
しか し なが ら、 かかる構成では、 .通常の真珠製品に比べて特 段の優越性を見い出 し難く 、 人造真珠製品の商品価値に不満が あ る と レ、 う 問題点がある。  However, in such a configuration, it is difficult to find a particular superiority compared to ordinary pearl products, and there is a problem that the commercial value of artificial pearl products is unsatisfactory.
発明の開示 Disclosure of the invention
本発明 はかか る従来技術の課題を解決すべ く な された もので あ り 、 合成樹脂か ら成 る母体 に ル ミ ネ ッ セ ン ス材料を混在さ せ、 該母体の外表面に人造真珠よ り なる被膜層を形成 し た こ と を 寺 と する。  The present invention has been made to solve the problems of the related art, and a luminescent material is mixed in a matrix made of a synthetic resin, and an artificial surface is formed on the outer surface of the matrix. The temple with the layer of pearls is called a temple.
太発明の対象 と なる製品と して は、 例えば、 ネ ッ ク レ ス、 ィ ァ リ ング、 ブ レス レ ッ ト 、 ブローチ、 髮止め、 ネ ク タ イ ビ ン、 カ ウス ボタ ン等の装飾品や、 服飾ボタ ン等の服飾品があげ られ る。  Examples of products that are subject to the invention include decorations such as necklaces, earrings, breathlets, brooches, hair clasps, neck bins, and cow buttons. And clothing items such as clothing buttons.
合成樹脂 と し て は、 例え ば尿素樹脂、 ス チ ロ ール樹脂等を用 レヽればよ レヽ。  As a synthetic resin, for example, a urea resin, a styrene resin, or the like may be used.
ル ミ ネ ッ セ ン ス （本明細書に おいて ほケィ光お よ び リ ン光を 含めた残光をい う ） 材料と し て は、 例えば銅を賦活剤と して長 時間の残光性を有する蓥光顔料である燐先性硫化亜鉛 ( Z n S ： C u ) か ら成る ものを用いればよい。 こ こ で、 母体の合成樹 脂と ルミ ネ ッ セ ン ス材料と の混合割合は、 ル ミ ネ ッ セ ン ス の発 光輝度や母体の成形強度等を考慮、して決め られる。 Luminescence (which refers to afterglow, including light and phosphorescence in this specification) is, for example, a long activator using copper as an activator. What consists of phosphorescent zinc sulfide (ZnS: Cu) which is a luster pigment having afterglow of time may be used. Here, the mixing ratio of the mother resin and the luminescent material is determined in consideration of the luminance of the luminescent material and the molding strength of the mother material.
た だ、 合成樹脂 と ル ミ ネ ッ セ ン ス材料の割合を、 合成樹脂 8 7 〜 9 3 w t %、 ル ミ ネ ッ セ ン ス材料 7 〜 1 3 w t % と すれ ば、 明光中に おいて ほぼ完全な真珠光沢が得られる。 ルミ ネ ッ セ ン ス材料の割合を 1 3 w t %を越えて含有せ しめる と真珠光 沢ほ急激に失われる。  However, if the ratio of the synthetic resin and the luminescent material is 87 to 93 wt% of the synthetic resin and the luminescent material is 7 to 13 wt%, the And almost perfect pearl luster. If the proportion of the luminescent material exceeds 13 wt%, it will be lost sharply.
ま た、 蓄光顔料は太陽光や電灯光を吸収して蓄積し、 こ れを 除々 に放出させて発光させる ものであ り 、 こ の吸収、 蓄積、 発 光は何度でも繰返して行い得る ものが好適である。  The luminous pigment absorbs and accumulates sunlight or electric light, gradually releases the luminous pigment to emit light, and the absorption, accumulation, and emission can be performed repeatedly. Is preferred.
さ ら に、 ル ミ ネ ッ セ ン ス材料の暗中での発光時間は可能な限 り 長いも のを選び、 そ の発光輝度は比較的低照度の剌激光で も 一定の値が得られる もの と し、 蓄光率ほ剌激光の強さ に は関係 な く 、 所定の時間で飽和値に達する よ う なものを選定する と好 適である。  In addition, the luminescent material should be selected to emit light in the dark as long as possible, and its luminous intensity should be constant even with stimulating light of relatively low illuminance. However, it is preferable to select a material that reaches a saturation value in a predetermined time regardless of the luminous intensity or the intensity of the stimulating light.
被覆層の被覆は例え ば次の よ う に し て行えばよい。 すなわ ち、 ル ミ ネ ッ セ ン ス材料を含有せ しめた樹脂を所定の形状に成 形加工し、 成形加工品を、 例えば、 ニ ト ロ セ ルロ ースの溶解液 に人工のパールエ ッ セ ン ス （塩基性炭酸鉛等） あるいは天然の パールエ ッ セ ン ス （ タ チ ウ ォ の う ろ こ等） を混合したも のの中 に浸漬すればよい。  The coating of the coating layer may be performed, for example, as follows. In other words, a resin containing a luminescent material is formed into a predetermined shape, and the molded product is made into, for example, an artificial pearl ether in a solution of nitrose cellulose. It should be immersed in a mixture of sensation (basic lead carbonate, etc.) or natural pearl essence (tachiwo scale, etc.).
被覆層の層厚 と し て ほ、 0 . 0 1 〜 0 . 1 0 m mが好ま し く 、 0 . 0 3 〜 0 . 0 5 m mがよ り 好ま しレヽ。 こ の範囲と すれ ば、 よ り 一層良好な真珠光沢が得られる と と も に よ り よ く ルミ ネ ッ セ ン ス効果が達成される。 The thickness of the coating layer is preferably from 0.01 to 0.10 mm, and more preferably from 0.03 to 0.05 mm. Within this range For example, a better pearl luster can be obtained and a better luminescence effect can be achieved.
作用 Action
以下に本発明の作用を本発明をなす に際して得た知見 と と も に説明する 。 '  Hereinafter, the function of the present invention will be described together with the knowledge obtained in making the present invention. '
本発明者は、 合成樹脂か ら なる母体にルミ ネ ッ セ ン ス材料を 含有せ しめれば独特の趣き がある人造真珠製品が得 られる の で はないか と の着想を得た。  The inventor of the present invention obtained an idea that if a luminescent material is added to a base made of a synthetic resin, an artificial pearl product having a unique taste can be obtained.
しか し、 母体にルミ ネ ッ セ ン材料を含有せ しめた場合、 真珠 特有の光沢が維持されるか ど う かが疑問であ り 、 ま た、 逆に、 被覆層の存在は、 母体の光吸収 ' 放出、 すなわ ち、 ル ミ ネ ッ セ ン効果を妨げるのでほないか と の疑問も あ っ た。  However, it is questionable whether the luster inherent to pearls is maintained when the mother body contains a luminescent material, and conversely, the presence of the coating layer is There was also the question of light absorption and emission, that is, the possibility of hindering the luminescence effect.
しか し、 各種実験を重ねた と こ ろ 、 母体にル ミ ネ ッ セ ン材料 を含有せ しめた場合であ つ て も真珠特有の光沢が維持さ れる こ と が判明 し本発明をなす にレ、た っ たものである。  However, after conducting various experiments, it was found that the luster inherent to pearls was maintained even when the mother body contained a luminescent material. Re, it is just something.
母体に含ま れたルミ ネ ッ セ ン ス材料に よ る光の吸収や放出は 被膜層を介 して行なわれ、 そのル ミ ネ ッ セ ン ス材料の残光、 す なわち母体のル ミ ネ セ ン ス に よ り 例えばネ ヅ ク レ ス のよ う な 人造真珠製品が夜光性のも の と な り 、 暗中で独特の趣き を発揮 する と と も に、 暗中での捜索が容易 と なる。 一方、 装着時にお ける人造真珠製品に趣き が生じ、 特有の美観を呈させる こ と が で き る 。  The absorption and emission of light by the luminescent material contained in the matrix is carried out through the coating layer, and the afterglow of the luminescent material, that is, the luminescent property of the matrix Depending on the essence, artificial pearl products such as e.g. Necklace become luminous, have a unique taste in the dark, and are easy to search in the dark. Become. On the other hand, the artificial pearl product at the time of wearing gives a taste and can give a unique aesthetic appearance.
本発明者は、 さ ら に、 合成樹脂と ル ミ ネ ッ セ ン ス材料 と の混 合割合について探究を行っ た と こ ろ、 こ の割合が、 真珠光沢に も影響を与え る こ と を知見 した。 すなわち、 合成樹脂とル ミ ネ ッ セ ン ス材料の割合を、 合成樹 脂 8 7 〜 9 3 w t %、 ル ミ ネ ッ セ ン ス材料 7 〜 1 3 w t % とす れば、 明光中においてほぼ完全な真珠光沢が得ら る。 ルミ ネ ッ セ ン ス材料の割合を 1 3 w t %を越えて含有せ しめる と真珠光 沢は急激に失われる。 The present inventor further investigated the mixing ratio of the synthetic resin and the luminescent material, and found that the mixing ratio also affected the pearl luster. I found it. In other words, if the ratio of the synthetic resin to the luminescent material is 87 to 93 wt% and the luminescent material is 7 to 13 wt%, then in bright light Almost perfect pearl luster is obtained. If the proportion of the luminescent material exceeds 13 wt%, the pearlescent light is rapidly lost.
図面の簡単な説明 BRIEF DESCRIPTION OF THE FIGURES
第 1 図は本発明の一実施例を示す断面図、 第 2 図は第 1 図に 示す人造真珠を応用 した実施例を示す斜視図である。 第 3 図は 他の実施例を示す服飾ボタ ン の断面図である。  FIG. 1 is a sectional view showing an embodiment of the present invention, and FIG. 2 is a perspective view showing an embodiment to which the artificial pearl shown in FIG. 1 is applied. FIG. 3 is a sectional view of a clothing button showing another embodiment.
1 は人造真珠製品 （服飾ボタ ン 、 人造真珠） 、 2 は母体、 3 ほ被膜層。  1 is an artificial pearl product (apparel button, artificial pearl), 2 is the mother body, 3 is a coating layer.
発明を実施する ための最良の形態 BEST MODE FOR CARRYING OUT THE INVENTION
[実施例 1 ]  [Example 1]
第 1 図ほ本発明の一実施例を示すものであ り 、 人造真珠 1 は 母体 2 および被膜層 3 か ら構成されている。  FIG. 1 shows an embodiment of the present invention. An artificial pearl 1 is composed of a matrix 2 and a coating layer 3.
本例において は、 樹脂と して尿素樹脂を用い、 ルミ ネ ッ セ ン ス村料と して憐光性硫化亜鉛 （ Z n S ： C u ) を用いた。 樹脂 を 9 0 w t %、 ル ミ ネ ッ セ ン ス材料を 1 O w t %の割合で混合 し、 第 1 図に示す形状に成形加工 し た。 次いで、 ニ ト ロ セル ロ ース の溶解液に天然のパールエ ッ セ ン ス （タ チ ウォの う ろ こ 等） を混合したものの中に 5 回浸漬し、 被膜層 3 を形成した。 被覆層 3 の層厚ほ 0 . 0 3 m mであ っ た。  In this example, urea resin was used as the resin, and phosphorescent zinc sulfide (ZnS: Cu) was used as the luminescence material. The resin was mixed at a ratio of 90 wt% and the luminescent material at a ratio of 1 wt%, and molded into the shape shown in FIG. Then, it was immersed 5 times in a mixture of a natural pearl essence (such as a scale of Tachiwo) in a solution of nitrocellulose to form a coating layer 3. The thickness of the coating layer 3 was about 0.3 mm.
以上の よ う に し て作製した製品につ きル ミ ネ ッ セ ン ス効果を 測定した。 ①光源と の距離 5 0 c m 光源 6 0 W白熱電球 照 射 時 間 残 光 時 間 The luminescence effect of the product manufactured as described above was measured. ① Distance from the light source 50 cm Light source 60 W Incandescent lamp Irradiation time Afterglow time
1 0 秒 3 分 3 0 秒 10 seconds 3 minutes 30 seconds
3 0 秒 6 分 3 0 秒  30 seconds 6 minutes 30 seconds
1 分 8 分 5 0 秒  1 minute 8 minutes 50 seconds
3 分 8 分 5 0 秒  3 minutes 8 minutes 50 seconds
5 分 8 分 5 0 秒  5 minutes 8 minutes 50 seconds
1 0 分 8 分 5 0 秒  10 minutes 8 minutes 50 seconds
②光源 と の距離 is 0 c m 光源 4 0 W X 2 本白色茧光灯 照 射 時 間 残 光 時 間 ②Distance from light source is 0 cm Light source 40 W X 2 white 茧 Light lamp Irradiation time Afterglow time
1 0 秒 2 8 分 3 0 秒  10 seconds 2 8 minutes 30 seconds
3 0 秒 3 3 分 3 0 秒  30 seconds 3 3 minutes 30 seconds
1 分 4 0 分 3 0 秒  1 minute 40 minutes 30 seconds
3 分 6 2分 3 0 秒  3 minutes 6 2 minutes 30 seconds
5 分 6 3 0 秒  5 minutes 6 30 seconds
1 0 分 6 2 分 4 0 秒  1 0 min 6 2 min 40 sec
[実施例 2 ] [Example 2]
第 2 図は、 第 1 図に示す人造真珠 1 をネ ッ ク レス 4 に適用 し た場合を示すものであ り 、 こ の場合、 各人造真珠 1 に ほ母体 2 の成形時に連結用の糸を揷通させる貫通孔を穿設 してお く 。 [実施例 3 ] 第 3 図 （ a ) , ( b ) は、 服飾ボタ ンの例を示している。 その製造方法は、 実施例 1 と 同様である。 なお、 ボタ ンの形状は、 球状、 半球状に限る も のではな く 、 任意の形状 と す る こ と ができ る。 [実施例 4 ] Fig. 2 shows the case where artificial pearl 1 shown in Fig. 1 is applied to neckless 4, and in this case, the connecting thread is used for molding artificial mother 2 on each artificial pearl 1. A through hole is formed to allow the air to pass through. [Embodiment 3] Figs. 3 (a) and (b) show examples of clothing buttons. The manufacturing method is the same as in Example 1. The shape of the button is not limited to a spherical shape and a hemispherical shape, but may be any shape. [Example 4]
本例では、 人造真珠と真性真珠と を交互に連ねてネ ッ ク レス と した。  In this example, artificial pearls and intrinsic pearls are alternately connected to make them neckless.
こ の場合、 部分的 に ネ ッ ク レ ス は発光 し、 独特の趣を与え た。  In this case, the necklace was partially illuminated, giving it a unique taste.
産業上の利用可能性 . Industrial applicability.
以上のよ う に、 本発明に よれば合成樹脂か ら成る母体にルミ ネ ッ セ ンス材料を混在させ、 該母体の外表面に真珠光沢の被膜 層を形成 したので、 夜光性のもの と なる こ と に よ り 、 特に暗所 での人造真珠製品の捜索 し易さや美観を向上させ、 人造真珠製 品の展示場所や人造真珠製品を装着 し た状態の趣きが魅惑的に な り 、 通常の真珠製品に優越 し得る ものが生じ、 装飾、 服飾業 界に おいて人造真珠製品の商品価値の向上に貢献する こ と がで き る。  As described above, according to the present invention, a luminescent material is mixed with a base made of a synthetic resin, and a pearlescent coating layer is formed on the outer surface of the base, so that it becomes luminous. This makes it easier to search for artificial pearl products, especially in dark places, and enhances the beauty of the pearl products. Some pearl products can be superior and contribute to the improvement of the commercial value of artificial pearl products in the decoration and clothing industries.

Claims

言青 求 の 範 函 Scope of the request
( 1 ) 合成樹脂か ら成 る母体 に ル ミ ネ ッ セ ン ス材料を混在さ せ、 該母体の外表面に人造真珠よ り なる被膜層を形成 し た こ と を特徴 と する真珠光沢を有する装飾品および服飾品。  (1) Luminescence material is mixed in a matrix made of synthetic resin, and a coating layer made of artificial pearls is formed on the outer surface of the matrix. Ornaments and clothing items.
( 2 ) 合成樹脂と ル ミ ネ ッ セ ン ス材料の割合を、 合成樹脂 8 7 〜 9 3 w t % 、 ル ミ ネ ッ セ ン ス材料 7 〜 1 . 3 w t % と し た こ と を特徴 と す る請求項 1 記載の人造真珠製装飾品お よ び服飾 (2) The ratio of the synthetic resin to the luminescent material is 87 to 93 wt%, and the luminescent material is 7 to 1.3 wt%. Artificial pearl ornaments and clothing according to claim 1
D D
o  o
( 3 ) 合成樹脂か ら成る母体 に ル ミ ネ ッ セ ン ス材料を混在さ せ、 該母体の外表面に人造真珠よ り なる被膜層を形成 し た こ と を特徴 と す る真珠光沢を有する珠を連ねて なる ネ ッ ク レ ス 。 ( 4 ) 合成樹脂か ら成る母体 に ル ミ ネ ッ セ ン ス材料を混在さ せ、 該母体の外表面に人造真珠よ り なる被膜層を形成し た こ と を特徴 と す る真珠光沢を有する珠 と真性真珠 と を交互に連ねて な る ネ ッ ク レ ス。  (3) A pearlescent luster characterized by the fact that a luminescent material is mixed in a matrix made of a synthetic resin and a coating layer made of artificial pearls is formed on the outer surface of the matrix. A necklace of pearls. (4) Luminescence material is mixed in a matrix made of synthetic resin, and a pearly luster characterized by forming a coating layer made of artificial pearls on the outer surface of the matrix. A necklace consisting of alternating pearls and intrinsic pearls.
PCT/JP1990/000649 1989-06-22 1990-05-22 Pearlescent ornament and dress ornament WO1990015550A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP1/73424U 1989-06-22
JP7342489 1989-06-22
JP1989121242U JPH0426005Y2 (en) 1989-06-22 1989-10-17
JP1/121242U 1989-10-17

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WO (1) WO1990015550A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000069303A1 (en) * 1999-05-15 2000-11-23 Richard Seidenbusch Luminescent ornamental object
CN101912186A (en) * 2010-07-31 2010-12-15 王玲瑞 Luminous pearl and processing technology thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4939630B1 (en) * 1971-07-12 1974-10-26
JPS60177090A (en) * 1984-02-21 1985-09-11 Takiron Co Ltd Luminescent material
JPS60160713U (en) * 1984-04-05 1985-10-25 松本　とし子 Luminous accessories

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6080402A (en) * 1983-10-07 1985-05-08 上田　直和 Artificial juery having luminescence and aurora film mixed therein
JPS60212104A (en) * 1984-04-09 1985-10-24 富士真珠工業株式会社 Artificial pearl and its production

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4939630B1 (en) * 1971-07-12 1974-10-26
JPS60177090A (en) * 1984-02-21 1985-09-11 Takiron Co Ltd Luminescent material
JPS60160713U (en) * 1984-04-05 1985-10-25 松本　とし子 Luminous accessories

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000069303A1 (en) * 1999-05-15 2000-11-23 Richard Seidenbusch Luminescent ornamental object
CN101912186A (en) * 2010-07-31 2010-12-15 王玲瑞 Luminous pearl and processing technology thereof

Also Published As

Publication number Publication date
JPH0426005Y2 (en) 1992-06-23
JPH0360517U (en) 1991-06-13

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