WO1986002862A1 - Method of internal chilling, an apparatus therefor, and internally chilled products - Google Patents
Method of internal chilling, an apparatus therefor, and internally chilled products Download PDFInfo
- Publication number
- WO1986002862A1 WO1986002862A1 PCT/JP1985/000619 JP8500619W WO8602862A1 WO 1986002862 A1 WO1986002862 A1 WO 1986002862A1 JP 8500619 W JP8500619 W JP 8500619W WO 8602862 A1 WO8602862 A1 WO 8602862A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- covered
- aluminum
- plating
- wrapping
- covering
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/0036—Casting in, on, or around objects which form part of the product gears
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/0009—Cylinders, pistons
Definitions
- the present invention relates to aluminum alloys, FRMs, iron and steel, Ti alloys, ⁇ ii alloys, C0 alloys, and the like, which are contained in aluminum alloys.
- Aluminum alloy products are lightweight and have large merit of high productivity such as die casting, melt forging and low pressure forging, but strength.
- its wear resistance is inferior to iron-based materials, so its application is limited.
- high-strength materials such as iron-based materials have been used to cover the necessary parts.However, if the material is simply used, for example, iron-based materials can be used. In the case where the aluminum alloy is rounded, an unwelded portion remains at the boundary of the iron-aluminum alloy.
- the present invention is an aluminum alloy, FRV! Water, degreasing, pickling, drying, etc. are not applied to the covered material such as iron, iron, metal plate, Ni metal, Co alloy, etc.
- the covered material is To the plating solution JP85 / 00619
- this covered material is made of a wool made of an aluminum alloy.
- the covering material is made of aluminum alloy, and the covering material is covered with the covering material. The material is completely welded and the two are diffusion bonded.
- the stuffed material and the affected stuffed material are firmly attached to each other, and a stuffed product with sufficient robbery can be obtained.
- the manufacturing operation is easy and the cost is low because it is only necessary to shake the plating liquid.
- FIG. 1 is a cross-sectional view showing a mounting device according to Example 1 of the present invention, and FIG. 2 is a taper foot manufactured by the wrapping method described in Example 1;
- Fig. 3 is a micrograph (100x magnification) of the boundary between the wrapped material and the wrapped material of the wrapped product according to the method of the present invention in Example 1 (100x magnification), and
- Fig. 4 is a comparative example. Without wrapping the wrapped material, it is wrapped, that is, one of the untreated, unprocessed wrapped materials in the table of the comparative examples.
- Boundary microscope with boundary material (approximately 100 times).
- Fig. 5 shows the boundary microscope between the piston body 13 and the wear ring ⁇ 2 of the kiston 2 FIG.
- FIG. 6 is a cross-sectional view of the mold die 9 of the fifth embodiment
- FIG. 7 is N.sub.0 of the fifth embodiment.
- 4 Microscope photograph (100 times) of the boundary between steel wire No. 4 and aluminum alloy 20
- Fig. 8 shows the steel wire of No. 0.6 test piece in Example 5.
- Fig. 9 is a cross-sectional view of the engine connection opening of Example 5.
- FIG. 5 is a perspective view showing the cam 8 of the sixth embodiment
- FIG. 11 is a cross-sectional view showing the force shaft of the sixth embodiment
- FIG. 12 is a sectional view of the seventh embodiment.
- Cross section of piston Fig. 13 shows cross section of cylinder head of embodiment 4
- Fig. 4 includes cylinder 7 cylinder of embodiment 8
- Fig. 15 is a front view of the rocker arm of the internal combustion engine to which the present invention is applied.
- J IS A 2 ⁇ 24 S Aluminum alloy material is used to form a covered material.
- the plating apparatus ⁇ consists of a solder melting furnace 2 and an ultrasonic oscillation apparatus 3, and the solder melting furnace 2 has a plating solution 4 at an upper part.
- the bathtub 5 includes a heating section (electrically heated coil) 6 which is provided at a lower portion of the bathtub 5 and heats the bathtub 1.
- 3 ⁇ 4 g oscillation device The device 3 has one end of a bifurcated diaphragm 8 fixed to the oscillation horn 7, and the other end of the diaphragm 8 is immersed in a mounting solution 4 for a bath 5. .
- the covering material 9 is inserted between the two diaphragms 8, and each of the diaphragms 8 is interposed between the two diaphragms 8 depending on the surface tension of the plating solution. It is located with a space between the electrodes.
- the to-be-wrapped material 9 coated with the Zn-5A alloy is set in a mold of a forging apparatus (not shown), and AC is formed as the to-be-wrapped material.
- Hot water of 4B aluminum alloy was poured to form a gravity structure, and a tapered foot 10 shown in FIG. 2 was formed.
- the tape shaft 10 is composed of a main body 11 made of AC4B and a covering material 9.
- JISA 20 24 Forming a covered material from S material, followed by unprocessed Zn plating, Sn plating, force plating, and molten aluminum After applying each of the solder holes, the AC 4B aluminum A tapered foot (similar to Example 1) was formed around the aluminum alloy.
- Table 1 shows the results of examining the welding conditions of Example 1 and the comparative example and the presence or absence of erosion of the covered material.
- Example 1 has a better welding condition than the conventional method, and there is no erosion of the covered material.
- a micrograph of a 100 times magnification microstructure of the boundary between the covered material 9 of Example 1 and the main body 1 shows that the comparative example was not treated and was not prematurely ripened.
- a comparison of the microscopic photograph (" Figure 4") of "00" magnification of the boundary between the covered material and the main body of the conductor shows that while applying ultrasonic vibrations, aluminum In Example 1 in which solder welding was performed, there was no unwelded portion between the covered material and the main holiday, whereas in the comparative example, there was no unwelded portion between the two. Yes, it is clear that the strength is weak.
- Example 2 In addition, ultrasonic vibration is applied to the covered material, and molten aluminum is applied to the covered material to remove the oxide film layer on the surface of the covered material. After removal, a uniform aluminum-aluminum eutectic layer is formed. This eutectic layer has a low melting point, is easily melted in a molten aluminum alloy, and is integrated with the molten metal.
- Example 2
- the wear ring of a piston with a wear ring for diesel as the covering material was then poured into the mold and poured into the mold to form a piston by pouring the AC8A aluminum alloy.
- the temperature is 700 ° C.
- the anti-friction ring is an ADC ADC0 aluminum base metal with S S34 powder dispersed.
- the microscopic structure photograph (No. 5) of the boundary area between the wear ring 12 and the main body 13 made of AC8A aluminum alloy is about 100 times larger than the boundary area. (Fig.) According to this, there is no unwelded portion between the wear-resistant ring 12 and the piston body 13, and both are completely welded.
- a cylinder liner was formed from an ADC 10 aluminum alloy in which Si 3 N 4 powder was dispersed, and as in Example 1, a Zn-5Ai alloy was used. I found an aluminum hand. Next, this cylinder liner is set in a mold, a molten aluminum alloy is poured, a cylinder block body is fabricated, and a cylinder block is formed. The cylinder block is formed around the cylinder liner by the main body.
- the roof member that forms the firing surface of the cylinder head combustion chamber is ripened.
- FR-M with high fatigue strength ie, JISA 6061 aluminum alloy
- the aluminum member was soldered as in Example 1 and the roof member was placed in a mold.
- the aluminum alloy which is a perforated material, was poured into the cylinder, the cylinder head body was fabricated, and as shown in FIG.
- the roof member 32 is pierced by the cylinder head body 31 to form the cylinder head 33.
- the JISZ 3281 aluminum was used by the ultrasonic plating device shown in Example 1.
- the aluminum solder was mounted on the aluminum arm AM350, and then the steel wire 14 was preheated to 30 CTC. 6
- the mold was placed in a mold ⁇ 9 shown in Fig. 6 and AC 4B aluminum alloy 20 was poured at 700 ⁇ , which was a wrapped material, to produce a solid. .
- Reference numeral 21 denotes a support for holding the steel wire 14 in the mold 9.
- a JIS No. 4 tensile test piece 15 (Fig. 6, two-dot chain line) was cut out using steel wire No. 4 as a center, and a tensile test was performed.
- the dimensions of the tensile test piece 15 are 7 ⁇ X32 (parallel part length 25 ') and the check part is M ⁇ 2, P1.5 thread. Eliminating the influence of the chucking in the tensile test on the hollow material.
- Almit AM 350 Aluminum solder made by Nippon Almit Co., Ltd. 9 5% Zn, 5% A &
- An aluminum solder was mounted on a 4.0 ⁇ MASIC steel 16 under the same conditions as the NJ 0.4 test piece of Example 4, and set in the mold after preheating at 300. Then, the ADC10 aluminum alloy was manufactured by a non-porous dy- cast method, and the connecting rod for a vehicle engine shown in Fig. 9 was manufactured. 17 was molded.
- the connecting rod 17 showed about 50% improvement in strength over the case without passing through the MASIC steel. Incidentally, the MASIC steel and the ADC0 material were completely joined through an aluminum solder.
- the inner engine cam 18 was formed from an iron-based sintered alloy, and the side face and inner peripheral face of the cam 8 were the same as in Example ⁇ .
- Pretreatment ⁇ The plating was performed as described above.
- the army After the pre-ripened cam 18 was pre-ripened to 300 C, it was set in a camshaft manufacturing mold of an internal combustion engine, and the ADC 10 aluminum alloy was used. Is poured into the mold described above, and is manufactured by a die casting method. As shown in FIG. 11, the cam 18 is squeezed by the shaft 19 as shown in FIG. N
- the aluminum ring 21 for D-Zelz-Zen, formed by the two-resist kin, is the same as the No.4 test piece of Example 5 and aluminum alloy.
- the ring is pre-heated at 300 and then set in a mold.Then, the ADC10 aluminum alloy is injected by gravity construction.
- a diesel engine piston 22 shown in FIG. 12 was molded.
- Plating thickness 50, m 4.
- Ultrasonic vibration conditions oscillation frequency 18 kHz, amplitude 20 ⁇ m, application time 2-3 seconds
- a cam of an internal combustion engine was formed from an iron-based sintered alloy in the same manner as in Example 6, and the pretreatment was performed as in Example 8, followed by pure zinc plating. It was. Next, after the cam is preheated to 300 ° C., it is set in a mold, the ADC 10 aluminum alloy is poured, and the power is passed through the cam. The craft was built by the die casting method.
- the bath temperature for the zinc plating was 500, the plating time was 5 minutes, and the ultrasonic vibration application time was 5 seconds. '
- the ultrasonic vibration frequency is about 8 kHz, but in the present invention, it is sufficient that the ultrasonic vibration frequency is in the range of 1 to about 1000 kHz. In this case, 1 to 100 kHz is preferable. If the frequency is less than 1 kHz, the number of repetitions per unit time is small, and the oxide film formed on the surface of the covering material cannot be removed. Is not completely carried out, and there is a risk of peeling, and a uniform haze is formed. It is something that cannot be achieved. In addition, when the pressure exceeds 100 kHz, the plating liquid can follow the vibration of the diaphragm, and the plating liquid peels off from the surface of the diaphragm, and the cavitation occurs. And damage the diaphragm.
- the plating film thickness is set to 50 ⁇ m and 100 m in the above embodiment, in the present invention, the plating film thickness is preferably 5 m or more and 300 m or less. In particular, 30 ⁇ (I! ⁇ 100 ⁇ m is preferable, and if it is less than 5 Xm, welding with the aluminum alloy at the time of wrapping is not possible. In addition, the wrapped material and the wrapped material are completely welded with a coating thickness of 300 ⁇ m or less, and the thickness exceeds 300 m. There is no need to brush.
- the amplitude of the diaphragm was set to 20 ⁇ m in the above embodiment, but the range of 5 m or more and 35 m or less is preferable. If it is less than 5 / m, sufficient energy cannot be given to the plating liquid, oxides formed on the surface of the covered material cannot be removed, and uniform plating cannot be performed. You can't get a layer. If the distance exceeds 35 m, the plating liquid cannot follow the movement of the diaphragm, and there is a possibility that the diaphragm may be damaged due to the occurrence of cavitation.
- the distance between the diaphragm and the mounting surface of the covering material is set to 0.
- the diaphragm and the thigh are set to 0.5 thigh or less. It is good if the filling liquid is filled between the covering material. If the thickness exceeds 0.5 mm, the vibration force of the diaphragm will not allow the wave force applied to the liquid to be transmitted sufficiently to the covered material, resulting in a uniform and strong plating. Is not obtained.
- Z ⁇ -A The alloy and pure zinc were used, but the aluminum specified in JISZ3281 was suitable for SAL-BQZ or SA-CRZ. Any can be applied. Pressurizing example by force de Mi ⁇ beam over a silver-based alloy [C d: 95%, A 9: 5% ( wt 0/0)] to not one zinc-based alloy [S n: 85%, Z n: 1 5% (% By weight)], etc.
- the material to be covered is aluminum alloy, stainless steel, high-strength steel, steel, FRM (carbon steel industry).
- Aluminum alloys), iron-based sintered alloys were used, but iron and steel (including stainless steel and heat-resistant steel), titanium alloys, nickel alloys, cobalt alloys, It is possible to use FRM or the like that uses aluminum alloy or zinc alloy as a matrix.
- the cylinder head, the cylinder block, the camshaft, the piston, the connection grid are used.
- other components of the internal twisting engine but also used as crankshafts, rocker arms, and suspension parts for automobiles (e.g., -Structural parts such as suspension arms), differential gear carriers, disk carriers, various gears, etc. This is what makes it possible.
- the rocker arm is made of iron-based sintered alloy chips 37 and aluminum, as shown in Fig. 15. It consists of a rocker arm body 36 made of a rubber alloy, and a chip 37 is slidably contacted with the cam. Apply Zu — A i. Gold or the like to the outer surface of this chip 37 while applying sonic vibration to the tip. Room 3 6
- the joint surface is clad by the method of the present invention, and a suspension arm is manufactured by circling these three members with an aluminum alloy: Defren
- a suspension arm is manufactured by circling these three members with an aluminum alloy: Defren
- Defren In the case of a char-gear carrier, use the method of the present invention in the same way as the suspension arm and the mounting push- ment to the vehicle body, and use 10-wire, FRM, etc. Is reinforced using the method of the present invention.
- the gear material is made by wrapping the FRM around the aluminum alloy. Next, the FRM is cut to form teeth.
- a sand mold, a metal, or the like can be used as a method of forming the covered material to be covered by the covered material provided in the present invention.
- the wrapping material before the wrapping was pre-ripened when the wrapping material was an iron-based material but it does not have to be pre-ripened.
- the 2 0 4 0 0 'C Oh Re may be in the following also for the Ru Oh 3 is found to Hikissaki cahoots seen material
- the plating liquid was subjected to ultrasonic vibration while being applied to the plating liquid. Then, the material and vibration
- the space between the board and the board is set at 0.1 thigh, but it is only necessary that the space between the two is less than 0.5 thigh and that there is a plating solution between the two. If this is less than 0.5 m, the vibration applied to the liquid by the diaphragm is reflected by the covering material, and the reflected wave is reflected by the diaphragm. The vibration energy is further given to the surface of the covered material as large energy; the oxide on the surface of the covered material is removed, and the uniform energy is removed. It is a material that can obtain a layer.
- the wave reflected by the covered material will be attenuated, and even if this attenuated reflected wave is vibrated by the diaphragm, sufficient vibration will not occur. Since the energy cannot hold the energy, the surface oxide of the covering material is not sufficiently removed, and a uniform plating layer cannot be obtained, and the covering material and the covering material cannot be obtained. ⁇ An unwelded part will occur between the wrapper and the material.
- This invention is based on the engine's cylinder head, piston, connector, connection socket, camshaft, piston, cylinder. Dub mouth, crank shaft, rocker arm, suspension arm, differential gear carrier, de It can be applied to the manufacture of disc brake gears and various gears:
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Electroplating Methods And Accessories (AREA)
- Molten Solder (AREA)
- Valve-Gear Or Valve Arrangements (AREA)
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19853590587 DE3590587C2 (de) | 1984-11-07 | 1985-11-07 | Verfahren und Vorrichtung zur Herstellung eines Verbundkörpers |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59/234595 | 1984-11-07 | ||
JP59234595A JPS61115658A (ja) | 1984-11-07 | 1984-11-07 | 鋳ぐるみ法 |
JP24766585A JPS62107854A (ja) | 1985-11-05 | 1985-11-05 | 鋳ぐるみ方法とその装置および鋳ぐるみ品 |
JP60/247665 | 1985-11-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1986002862A1 true WO1986002862A1 (en) | 1986-05-22 |
Family
ID=26531651
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1985/000619 WO1986002862A1 (en) | 1984-11-07 | 1985-11-07 | Method of internal chilling, an apparatus therefor, and internally chilled products |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0203198B1 (ja) |
AU (1) | AU574541B2 (ja) |
DE (2) | DE3590587C2 (ja) |
GB (1) | GB2184048B (ja) |
WO (1) | WO1986002862A1 (ja) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1989009669A1 (en) * | 1988-04-15 | 1989-10-19 | Sandvik Australia Pty. Limited | Composite hard metal-metal components |
FR2663250A1 (fr) * | 1990-06-19 | 1991-12-20 | Peugeot | Procede de fabrication de pieces en alliage d'aluminium coule comportant un insert et culasse de moteur a combustion interne obtenue par ce procede. |
FR2665383A1 (fr) * | 1990-07-31 | 1992-02-07 | Pechiney Recherche | Procede d'obtention par moulage de pieces bimateriaux. |
US6148515A (en) * | 1996-01-30 | 2000-11-21 | Suzuki Motor Corporation | Method of bonding aluminum members |
DE19650056A1 (de) * | 1996-12-03 | 1998-06-04 | Thyssen Guss Ag | Verfahren zur Herstellung einer Bremsscheibe, insbesondere als Achs- oder Radbremsscheibe für Schienenfahrzeuge |
DE19755557C1 (de) * | 1997-12-13 | 1999-02-04 | Vaw Alucast Gmbh | Gießform zur Herstellung eines Motorblocks |
FR2831845B1 (fr) * | 2001-11-07 | 2004-05-21 | Peugeot Citroen Automobiles Sa | Procede et dispositif de coulee d'une piece metallique comportant un element de renforcement |
DE10205798A1 (de) * | 2002-02-13 | 2003-09-04 | Federal Mogul Wiesbaden Gmbh | Einsatzteil in ein Ober-und/oder Unterteil oder eine Versteifungsrippe eines Lagerstuhls |
DE102005041410A1 (de) * | 2005-09-01 | 2007-03-08 | Mahle International Gmbh | Verfahren zum Beschichten der Außenfläche einer Zylinderlaufbuchse |
KR101374657B1 (ko) * | 2006-03-30 | 2014-03-17 | 젯트에프 프리드리히스하펜 아게 | 다층구조의 이중 재질 물품을 제조하는 방법 |
DE102006033770B4 (de) * | 2006-07-21 | 2014-01-16 | Bayerische Motoren Werke Aktiengesellschaft | Vorderwagen einer Kraftfahrzeugkarosserie mit einem Verbund aus einem Leichtmetallgussbauteil und mehreren Stahlbauteilen |
DE102008054007B4 (de) * | 2008-10-30 | 2019-09-12 | Volkswagen Ag | Verbrennungskraftmaschine und Verfahren zum Herstellen von Pleueln und Kolbenbolzen für eine Verbrennungskraftmaschine |
DE102020100640A1 (de) * | 2020-01-14 | 2021-07-15 | Stahlzentrum Freiberg e.V. | Verfahren zur Verbesserung der Korrosionsbeständigkeit von Befestigungs- und/oder Bewehrungsbauteilen aus hochlegierten Stählen und Befestigungs- und/oder Bewehrungsbauteile aus hochlegierten Stählen |
CN115971704B (zh) * | 2022-12-15 | 2023-07-14 | 兰州理工大学 | 一种铝/钛复合板及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05298621A (ja) * | 1992-04-15 | 1993-11-12 | Sumitomo Metal Ind Ltd | 薄膜磁気ヘッド及びその製造方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB651996A (en) * | 1947-06-19 | 1951-04-11 | Gen Motors Corp | Improved method of bonding aluminium or aluminium alloys to ferrous metals |
DE871096C (de) * | 1951-04-29 | 1953-03-19 | Siemens Ag | Einrichtung zum Herstellen von metallischen UEberzuegen |
GB708846A (en) * | 1951-09-28 | 1954-05-12 | Glacier Co Ltd | Improvements in or relating to plain bearings |
DE974552C (de) * | 1952-06-07 | 1961-02-02 | Aluminium Giesserei Villingen | Verfahren zur Vorbehandlung von Einsatzteilen aus Eisen oder Stahl fuer den Guss von Werkstuecken aus Aluminium oder Aluminiumlegierung |
DE1091712B (de) * | 1954-02-08 | 1960-10-27 | Metallgesellschaft Ag | Verfahren zum Angiessen von Leichtmetall an Eisen oder Stahl |
US2895845A (en) * | 1955-12-07 | 1959-07-21 | Aeroprojects Inc | Method for applying metallic coatings |
DE1100235B (de) * | 1958-03-26 | 1961-02-23 | Aluminiumwerke Nuernberg G M B | Verfahren zum fugenlosen Eingiessen von Einsatzteilen aus Schwermetall in Gussstuecke aus Aluminium und dessen Legierungen |
US3371703A (en) * | 1964-03-30 | 1968-03-05 | Gen Motors Corp | Sonic method and apparatus for tinning and casting metals |
US3401026A (en) * | 1966-01-19 | 1968-09-10 | Gen Motors Corp | Method of forming a bimetallic article |
US3969544A (en) * | 1975-02-14 | 1976-07-13 | Branson Ultrasonics Corporation | Method for plating metallic workpieces, particularly aluminum |
AU515375B2 (en) * | 1980-02-20 | 1981-04-02 | Nakamura Kinzoku Kogyosho | Manifold |
GB2074912A (en) * | 1980-05-01 | 1981-11-11 | Amsted Ind Inc | Ferrous metal castings with high hardness inserts |
AU543430B2 (en) * | 1981-09-22 | 1985-04-18 | Ae Plc | Pistons |
DE3511542A1 (de) * | 1985-03-29 | 1986-10-02 | Kolbenschmidt AG, 7107 Neckarsulm | Verbundgussverfahren |
-
1985
- 1985-11-07 GB GB08615801A patent/GB2184048B/en not_active Expired
- 1985-11-07 AU AU50680/85A patent/AU574541B2/en not_active Ceased
- 1985-11-07 DE DE19853590587 patent/DE3590587C2/de not_active Expired
- 1985-11-07 WO PCT/JP1985/000619 patent/WO1986002862A1/ja active IP Right Grant
- 1985-11-07 EP EP19850905667 patent/EP0203198B1/en not_active Expired - Lifetime
- 1985-11-07 DE DE19853590587 patent/DE3590587T1/de active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05298621A (ja) * | 1992-04-15 | 1993-11-12 | Sumitomo Metal Ind Ltd | 薄膜磁気ヘッド及びその製造方法 |
Non-Patent Citations (1)
Title |
---|
See also references of EP0203198A4 * |
Also Published As
Publication number | Publication date |
---|---|
EP0203198A1 (en) | 1986-12-03 |
AU5068085A (en) | 1986-06-03 |
GB8615801D0 (en) | 1986-08-06 |
AU574541B2 (en) | 1988-07-07 |
DE3590587T1 (de) | 1986-11-20 |
GB2184048A (en) | 1987-06-17 |
GB2184048B (en) | 1988-11-23 |
EP0203198A4 (en) | 1988-04-26 |
DE3590587C2 (de) | 1988-06-23 |
EP0203198B1 (en) | 1991-01-30 |
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